A Multi-Technique Provenance Study of the Oligocene – Recent Nile Cone Sediments and River Nile Hinterland

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A Multi-Technique Provenance Study of the Oligocene – Recent Nile Cone Sediments and River Nile Hinterland A multi-technique provenance study of the Oligocene – Recent Nile cone sediments and River Nile hinterland Thesis submitted in accordance with the requirements of Lancaster University for the degree of Doctor of Philosophy Laura Diane Fielding, MESci September 2015 Abstract This thesis presents the first detailed multiproxy provenance study of the modern Nile catchment, together with Oligocene-Recent sediments of the offshore Nile cone, and demonstrates for the first time that the palaeodrainage of the Nile has remained relatively stable over the last 30 Ma. Detrital mineral and bulk-rock analyses of modern river, wadi and bedrock samples demonstrate the role of basement lithology, sedimentary recycling, and modern geomorphological features in controlling the composition of sediment reaching the Nile cone. The bulk provenance signature of the modern Nile is dominated by the input of basic detritus from the Cenozoic Ethiopian Large Igneous Province. Detrital zircon signatures are dominated by variations in bedrock lithology, and the availability of easily-eroded Phanerozoic cover sediments. These represent an important source of detritus to the river and are characterised by the presence of strongly negative εHf populations at c. 600 and 1000 Ma, and significant populations of pre-Neoproterozoic grains. Young zircon grains derived from Ethiopian Cenozoic volcanic rocks are also recognised in samples from the Blue Nile, Atbara and Nile trunk. The Sr, Nd and Hf signature of Oligocene Nile cone sediments can only be explained if there is significant input of mafic material being received from the hinterland. The Ethiopian Large Igneous Province represents the only possible source for this detritus, indicating that the Nile has been connected to the Ethiopian Highlands since this time. Zircons with U-Pb ages and hafnium isotope signatures compatible with the Ethiopian LIP have been supplied to the Nile cone since at least the Miocene (16 Ma). Such zircons were not observed in Oligocene 2 delta sediments, but Sr, Nd and Hf isotope data for Oligocene delta muds as old as 31 Ma require significant mafic input. The combined U-Pb and Hf-isotope zircon dataset for Nile catchment and cone sediments represents a significant archive that documents the evolution of the North African crust, in particular highlighting phases in the development of the Arabian Nubian Shield and amalgamation of Gondwana in late Neoproterozoic times. 3 Acknowledgments This thesis would not have been possible without the guidance, friendship, support and enthusiasm of my supervisors Yani Najman and Ian Millar. I would like to thank them for the many adventures had whilst on fieldtrips – both good and bad, and the many hours spent reading drafts, discussions on Skype, tweaking the Nu Attom and teaching me how to cook! I would also like to thank Peter Butterworth and Ben Kneller for their help both early on in the project and their valuable contributions in the final stages of thesis and paper writing. The project would not have been possible without funding from both the Natural Environment Research Council and BP Egypt, which has allowed me to conduct an exhaustive methodology and in turn produce a dataset to be proud of. The multiple analytical techniques used in this project also mean that it is the product of a collaboration from many different individuals, laboratories, universities and companies whom I would also like to thank. Invaluable technical support from Carlyn Stewart, Vanessa Pashley and Nick Roberts (NIGL), Eduardo Garzanti, Sergio Ando, Marta Padoan and Giovanni Vessoli (University of Milano-Bicocca), Dan Barfod (SUERC), Ursula Rehfeld (Corex), Mohamed Saleh (BP Egypt) and my rock crushers Laura Hobbs and Tamsin Blayney. I would also like to thank those who helped make our sample collection trips to Ethiopia, Sudan, the Red Sea Hills and the Western Desert possible (and fun!), including: Tadesse Berhanu (Addis Ababa University); Mhadia Ibrahim and her family in Sudan for their kindness and hospitality; the Mashansharti tour company in Khartoum and of course, Mr Sunshine, Mr Frank and Ibrahim for a once (twice) in a lifetime eventful desert expedition. Last but not least, I would like to thank my friends and family, particularly my husband Sam for his support and understanding over the past 4 years, and our dog, Juno. 4 Chapter 1: Introduction ........................................................................................................................ 13 1.1 Aims & Approach ........................................................................................................................ 14 1.2 Thesis Structure .......................................................................................................................... 18 1.3 The Nile Catchment Area ............................................................................................................ 20 Chapter 2: Geology of the Nile Source Regions & Nile Delta Cone Sediments.................................... 23 2.1 Geology of the Nile Source Regions ............................................................................................ 24 2.1.1 Precambrian cratons ............................................................................................................ 24 2.1.2 Arabian Nubian Shield .......................................................................................................... 25 2.1.3 The Pan-African Orogeny ..................................................................................................... 26 2.1.4 Phanerozoic cover sequences .............................................................................................. 27 2.1.5 Cenozoic uplift and eruption of flood basalts ...................................................................... 28 2.2 The Nile Cone .............................................................................................................................. 30 2.3 Previous work on the evolution of the Nile ................................................................................ 32 2.3.1 Late Eocene Palaeodrainage ................................................... Error! Bookmark not defined. 2.3.2 Oligocene Palaeodrainage ...................................................... Error! Bookmark not defined. 2.3.3 Miocene Palaeodrainage ........................................................ Error! Bookmark not defined. 2.3.4 Pliocene Palaeodrainage ......................................................... Error! Bookmark not defined. 2.3.5 Pleistocene Palaeodrainage .................................................... Error! Bookmark not defined. 2.4 Previous work on the isotope signature of Nile sediments ........................................................ 37 Chapter 3: Analytical Methods ............................................................................................................. 40 3.1 Major and Trace Element Analysis .............................................................................................. 41 5 3.2 Heavy Mineral Analysis ............................................................................................................... 42 3.2.1 Nile Cone Sands.................................................................................................................... 42 3.2.2 Nile Cone Muds .................................................................................................................... 44 3.3 Petrography ................................................................................................................................ 46 3.4 Separation Preparation for Isotope Geochemistry ..................................................................... 47 3.4.1 Sample preparation ............................................................................................................. 47 3.4.2 Weighing and leaching ......................................................................................................... 47 3.4.3 Sample dissolution ............................................................................................................... 47 3.4.4 Primary column separation .................................................................................................. 48 3.4.5 Separation of Hf ................................................................................................................... 49 3.4.6 Separation of Rb and Sr ....................................................................................................... 49 3.4.7 Separation of Sm, Nd and Lu from the bulk REE fraction .................................................... 50 3.5 Mass Spectrometry ..................................................................................................................... 50 3.5.1 Lu and Hf Analysis ................................................................................................................ 50 3.5.3 Sm and Nd analysis .............................................................................................................. 52 3.5.5 Rb and Sr analysis ................................................................................................................. 53 3.6 U-Pb Geochronology – Zircon and Rutile .................................................................................... 54 3.6.1 Laser Ablation Plasma Ionisation Mass Spectrometry ......................................................... 54 3.6.2 Data selection
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