Binary Energy Source of the HH 250 Outflow
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Large Molecules in the Envelope Surrounding IRC+10216
Mon. Not. R. Astron. Soc. 316, 195±203 (2000) Large molecules in the envelope surrounding IRC110216 T. J. Millar,1 E. Herbst2w and R. P. A. Bettens3 1Department of Physics, UMIST, PO Box 88, Manchester M60 1QD 2Departments of Physics and Astronomy, The Ohio State University, Columbus, OH 43210, USA 3Research School of Chemistry, Australian National University, ACT 0200, Australia Accepted 2000 February 22. Received 2000 February 21; in original form 2000 January 21 ABSTRACT A new chemical model of the circumstellar envelope surrounding the carbon-rich star IRC110216 is developed that includes carbon-containing molecules with up to 23 carbon atoms. The model consists of 3851 reactions involving 407 gas-phase species. Sizeable abundances of a variety of large molecules ± including carbon clusters, unsaturated hydro- carbons and cyanopolyynes ± have been calculated. Negative molecular ions of chemical 2 2 formulae Cn and CnH 7 # n # 23 exist in considerable abundance, with peak concen- trations at distances from the central star somewhat greater than their neutral counterparts. The negative ions might be detected in radio emission, or even in the optical absorption of background field stars. The calculated radial distributions of the carbon-chain CnH radicals are looked at carefully and compared with interferometric observations. Key words: molecular data ± molecular processes ± circumstellar matter ± stars: individual: IRC110216 ± ISM: molecules. synthesis of fullerenes in the laboratory through chains and rings 1 INTRODUCTION is well-known (von Helden, Notts & Bowers 1993; Hunter et al. The possible production of large molecules in assorted astronomi- 1994), the individual reactions have not been elucidated. Bettens cal environments is a problem of considerable interest. -
Organics in the Solar System
Organics in the Solar System Sun Kwok1,2 1 Laboratory for Space Research, The University of Hong Kong, Hong Kong, China 2 Department of Earth, Ocean, and Atmospheric Sciences, University of British Columbia, Vancouver, B.C., Canada [email protected]; [email protected] ABSTRACT Complex organics are now commonly found in meteorites, comets, asteroids, planetary satellites, and interplanetary dust particles. The chemical composition and possible origin of these organics are presented. Specifically, we discuss the possible link between Solar System organics and the complex organics synthesized during the late stages of stellar evolution. Implications of extraterrestrial organics on the origin of life on Earth and the possibility of existence of primordial organics on Earth are also discussed. Subject headings: meteorites, organics, stellar evolution, origin of life arXiv:1901.04627v1 [astro-ph.EP] 15 Jan 2019 Invited review presented at the International Symposium on Lunar and Planetary Science, accepted for publication in Research in Astronomy and Astrophysics. –2– 1. Introduction In the traditional picture of the Solar System, planets, asteroids, comets and planetary satellites were formed from a well-mixed primordial nebula of chemically and isotopically uniform composition. The primordial solar nebula was believed to be initially composed of only atomic elements synthesized by previous generations of stars, and current Solar System objects later condensed out of this homogeneous gaseous nebula. Gas, ice, metals, and minerals were assumed to be the primarily constituents of planetary bodies (Suess 1965). Although the presence of organics in meteorites was hinted as early as the 19th century (Berzelius 1834), the first definite evidence for the presence of extraterrestrial organic matter in the Solar System was the discovery of paraffins in the Orgueil meteorites (Nagy et al. -
Electronic Spectroscopy of Free Base Porphyrins and Metalloporphyrins
Absorption and Fluorescence Spectroscopy of Tetraphenylporphyrin§ and Metallo-Tetraphenylporphyrin Introduction The word porphyrin is derived from the Greek porphura meaning purple, and all porphyrins are intensely coloured1. Porphyrins comprise an important class of molecules that serve nature in a variety of ways. The Metalloporphyrin ring is found in a variety of important biological system where it is the active component of the system or in some ways intimately connected with the activity of the system. Many of these porphyrins synthesized are the basic structure of biological porphyrins which are the active sites of numerous proteins, whose functions range from oxygen transfer and storage (hemoglobin and myoglobin) to electron transfer (cytochrome c, cytochrome oxidase) to energy conversion (chlorophyll). They also have been proven to be efficient sensitizers and catalyst in a number of chemical and photochemical processes especially photodynamic therapy (PDT). The diversity of their functions is due in part to the variety of metals that bind in the “pocket” of the porphyrin ring system (Fig. 1). Figure 1. Metallated Tetraphenylporphyrin Upon metalation the porphyrin ring system deprotonates, forming a dianionic ligand (Fig. 2). The metal ions behave as Lewis acids, accepting lone pairs of electrons ________________________________ § We all need to thank Jay Stephens for synthesizing the H2TPP 2 from the dianionic porphyrin ligand. Unlike most transition metal complexes, their color is due to absorption(s) within the porphyrin ligand involving the excitation of electrons from π to π* porphyrin ring orbitals. Figure 2. Synthesis of Zn(TPP) The electronic absorption spectrum of a typical porphyrin consists of a strong transition to the second excited state (S0 S2) at about 400 nm (the Soret or B band) and a weak transition to the first excited state (S0 S1) at about 550 nm (the Q band). -
Implications for Extraterrestrial Hydrocarbon Chemistry: Analysis Of
The Astrophysical Journal, 889:3 (26pp), 2020 January 20 https://doi.org/10.3847/1538-4357/ab616c © 2020. The American Astronomical Society. All rights reserved. Implications for Extraterrestrial Hydrocarbon Chemistry: Analysis of Acetylene (C2H2) and D2-acetylene (C2D2) Ices Exposed to Ionizing Radiation via Ultraviolet–Visible Spectroscopy, Infrared Spectroscopy, and Reflectron Time-of-flight Mass Spectrometry Matthew J. Abplanalp1,2 and Ralf I. Kaiser1,2 1 W. M. Keck Research Laboratory in Astrochemistry, University of Hawaii at Manoa, Honolulu, HI 96822, USA 2 Department of Chemistry, University of Hawaii at Manoa, Honolulu, HI 96822, USA Received 2019 October 4; revised 2019 December 7; accepted 2019 December 10; published 2020 January 20 Abstract The processing of the simple hydrocarbon ice, acetylene (C2H2/C2D2), via energetic electrons, thus simulating the processes in the track of galactic cosmic-ray particles penetrating solid matter, was carried out in an ultrahigh vacuum surface apparatus. The chemical evolution of the ices was monitored online and in situ utilizing Fourier transform infrared spectroscopy (FTIR) and ultraviolet–visible spectroscopy and, during temperature programmed desorption, via a quadrupole mass spectrometer with an electron impact ionization source (EI-QMS) and a reflectron time-of-flight mass spectrometer utilizing single-photon photoionization (SPI-ReTOF-MS) along with resonance-enhanced multiphoton photoionization (REMPI-ReTOF-MS). The confirmation of previous in situ studies of ethylene ice irradiation -
Interstellar Dust Within the Life Cycle of the Interstellar Medium K
EPJ Web of Conferences 18, 03001 (2011) DOI: 10.1051/epjconf/20111803001 C Owned by the authors, published by EDP Sciences, 2011 Interstellar dust within the life cycle of the interstellar medium K. Demyk1,2,a 1Université de Toulouse, UPS-OMP, IRAP, Toulouse, France 2CNRS, IRAP, 9 Av. colonel Roche, BP. 44346, 31028 Toulouse Cedex 4, France Abstract. Cosmic dust is omnipresent in the Universe. Its presence influences the evolution of the astronomical objects which in turn modify its physical and chemical properties. The nature of cosmic dust, its intimate coupling with its environment, constitute a rich field of research based on observations, modelling and experimental work. This review presents the observations of the different components of interstellar dust and discusses their evolution during the life cycle of the interstellar medium. 1. INTRODUCTION Interstellar dust grains are found everywhere in the Universe: in the Solar System, around stars at all evolutionary stages, in interstellar clouds of all kind, in galaxies and in the intergalactic medium. Cosmic dust is intimately mixed with the gas-phase and represents about 1% of the gas (in mass) in our Galaxy. The interstellar extinction and the emission of diffuse interstellar clouds is reproduced by three dust components: a population of large grains, the BGs (Big Grains, ∼10–500 nm) made of silicate and a refractory mantle, a population of carbonaceous nanograins, the VSGs (Very Small Grains, 1–10 nm) and a population of macro-molecules the PAHs (Polycyclic Aromatic Hydrocarbons) [1]. These three components are more or less abundant in the diverse astrophysical environments reflecting the coupling of dust with the environment and its evolution according to the physical and dynamical conditions. -
Spectrum and the Technological Transformation of the Satellite Industry Prepared by Strand Consulting on Behalf of the Satellite Industry Association1
Spectrum & the Technological Transformation of the Satellite Industry Spectrum and the Technological Transformation of the Satellite Industry Prepared by Strand Consulting on behalf of the Satellite Industry Association1 1 AT&T, a member of SIA, does not necessarily endorse all conclusions of this study. Page 1 of 75 Spectrum & the Technological Transformation of the Satellite Industry 1. Table of Contents 1. Table of Contents ................................................................................................ 1 2. Executive Summary ............................................................................................. 4 2.1. What the satellite industry does for the U.S. today ............................................... 4 2.2. What the satellite industry offers going forward ................................................... 4 2.3. Innovation in the satellite industry ........................................................................ 5 3. Introduction ......................................................................................................... 7 3.1. Overview .................................................................................................................. 7 3.2. Spectrum Basics ...................................................................................................... 8 3.3. Satellite Industry Segments .................................................................................... 9 3.3.1. Satellite Communications .............................................................................. -
Laboratory Astrophysics: from Observations to Interpretation
April 14th – 19th 2019 Jesus College Cambridge UK IAU Symposium 350 Laboratory Astrophysics: From Observations to Interpretation Poster design by: D. Benoit, A. Dawes, E. Sciamma-O’Brien & H. Fraser Scientific Organizing Committee: Local Organizing Committee: Farid Salama (Chair) ★ P. Barklem ★ H. Fraser ★ T. Henning H. Fraser (Chair) ★ D. Benoit ★ R Coster ★ A. Dawes ★ S. Gärtner ★ C. Joblin ★ S. Kwok ★ H. Linnartz ★ L. Mashonkina ★ T. Millar ★ D. Heard ★ S. Ioppolo ★ N. Mason ★ A. Meijer★ P. Rimmer ★ ★ O. Shalabiea★ G. Vidali ★ F. Wa n g ★ G. Del-Zanna E. Sciamma-O’Brien ★ F. Salama ★ C. Wa lsh ★ G. Del-Zanna For more information and to contact us: www.astrochemistry.org.uk/IAU_S350 [email protected] @iaus350labastro 2 Abstract Book Scheduley Sunday 14th April . Pg. 2 Monday 15th April . Pg. 3 Tuesday 16th April . Pg. 4 Wednesday 17th April . Pg. 5 Thursday 18th April . Pg. 6 Friday 19th April . Pg. 7 List of Posters . .Pg. 8 Abstracts of Talks . .Pg. 12 Abstracts of Posters . Pg. 83 yPlenary talks (40') are indicated with `P', review talks (30') with `R', and invited talks (15') with `I'. Schedule Sunday 14th April 14:00 - 17:00 REGISTRATION 18:00 - 19:00 WELCOME RECEPTION 19:30 DINNER BAR OPEN UNTIL 23:00 Back to Table of Contents 2 Monday 15th April 09:00 { 10:00 REGISTRATION 09:00 WELCOME by F. Salama (Chair of SOC) SESSION 1 CHAIR: F. Salama 09:15 E. van Dishoeck (P) Laboratory astrophysics: key to understanding the Universe From Diffuse Clouds to Protostars: Outstanding Questions about the Evolution of 10:00 A. -
Infrared Astronomy Break: Sara and Rebeka
Astro 121, Spring 2014 Week 13 (April 24) Topic: Infrared astronomy Break: Sara and Rebeka Reading for this week: As we switch to looking at observing at wavelengths other than visible light, we’re moving beyond what Chromey covers. For this week, I’ve suggested reading from two sources. Glass gives a good introduction to the infrared and covers much of the practical material about filter systems, etc. McLean then fills in more details of practicalities of instrumentation for the infrared and how it is different from the optical. • Chromey briefly discusses the main broadband IR filter system in Section 10.4.3. • Glass, Handbook of Infrared Astronomy. In the same series as the book by Howell, this is a relatively new book with excellent coverage of infrared astronomy. Reading: Chapter 2 (The Infrared Sky); Chapter 3 (Photometry) through 3.2; and Chapter 6 (Instrumentation). You may also want to skim the rest of Chapter 3 and all of Chapter 4; they concentrate on applications of infrared photometry and spectroscopy, respectively. • McLean, Electronic Imaging in Astronomy (second edition). Ian McLean was one of the people most closely involved in the development and use of the early infrared arrays, and this is an area where this book stands out. Read Chapter 11, skipping pp. 400–404 (and in general reading the chapter for understanding of concepts rather than lots of details). One bit of physics that is worth reviewing for this week is the concept from thermodynamics that good absorbers are also good emitters, and correspondingly that the reflectivity R of some object is related to its emissivity ε by ε = 1 – R. -
Imaging the Circumstellar Envelope of OH 26.5+0.6
A&A 396, 581–587 (2002) Astronomy DOI: 10.1051/0004-6361:20021272 & c ESO 2002 Astrophysics Imaging the circumstellar envelope of OH 26.5+0.6 D. Fong1, K. Justtanont2,M.Meixner1, and M. T. Campbell1 1 Department of Astronomy, University of Illinois, 1002 W. Green Street Urbana, IL 61801, USA 2 SCFAB, Stockholm Observatory, Department of Astronomy, 106 91 Stockholm, Sweden Received 10 July 2002 / Accepted 28 August 2002 Abstract. Using the Berkeley-Illinois-Maryland-Association (BIMA) Millimeter Array, we were able to map the extreme OH/IR star, OH 26.5+0.6, in the 12CO J = 1–0 line transition. The CO emission is partially resolved with a deconvolved source size of 8:500 5:500. The spectrum shows that the blue-shifted emission is missing, most likely due to interstellar absorption. By × 6 1 modelling the infrared spectral energy distribution, we derive a dust mass loss rate of 1:9 10− M yr− .Fromthisweareable × to place an upper limit on the extent of the dusty envelope of 1016 cm while our BIMA map shows that the CO photodissociation radius extends out to about 7 1016 cm. To best fit the BIMA observations and the higher CO rotational transitions using our full radiative transfer code, we needed× to include a second, more tenuous AGB wind, outside the high density superwind to account for the observed flux. From our model, we conclude that up to 80% of the CO flux comes from the unresolved superwind. Key words. stars: AGB and post-AGB – stars: circumstellar matter – stars: individual : OH 26.5+0.6 – stars: late-type – stars: mass loss 1. -
Habitable Environments in Late Stellar Evolution
Habitable Environments in Late Stellar Evolution Conditions for Abiogenesis in the Planetary Systems of White Dwarfs Author: Dewy Peters Supervisor: Prof. dr. F.F.S. van der Tak A thesis submitted in fulfillment of the requirements for the degree BSc in Astronomy Faculty of Science and Engineering University of Groningen The Netherlands March 2021 Abstract With very high potential transit-depths and an absence of stellar flare activity, the planets of White Dwarfs (WDs) are some of the most promising in the search for detectable life. Whilst planets with Earth-like masses and radii have yet to be detected around WDs, there is considerable evidence from spectroscopic and photometric observations that both terrestrial and gas-giant planets are capable of surviving post-main sequence evolution and migrating into the WD phase. WDs are also capable of hosting stable Habitable Zones outside orbital distances at which Earth-mass plan- ets would be disintegrated by tidal forces. Whilst transition- ing to the WD Phase, a main-sequence star has to progress along the Asymptotic Giant Branch (AGB), whereby orbit- ing planets would be subjected to atmospheric erosion by its harsh stellar winds. As a trade-off, the Circumstellar En- velope (CSE) of an AGB star is found to be rich in organics and some of the simple molecules from which more complex prebiotic molecules such as amino acids and simple sugars can be synthesised. It is found that planets with initial or- bital distances equivalent to those of Saturn and the Kuiper Belt would be capable of accreting a mass between 1 and 20 times that of the Earth’s atmosphere from the CSE and as a result, could obtain much of the material necessary to sustain life after the AGB and also experience minimal at- mospheric erosion. -
Molecular Dust Precursors in Envelopes of Oxygen-Rich AGB Stars
Why Galaxies Care About AGB Stars: A Continuing Challenge through Cosmic Time Proceedings IAU Symposium No. 343, 2018 c 2018 International Astronomical Union F. Kerschbaum, H. Olofsson & M. Groenewegen, eds. DOI: 00.0000/X000000000000000X Molecular dust precursors in envelopes of oxygen-rich AGB stars and red supergiants Tomasz Kami´nski Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 Submillimeter Array Fellow, email: [email protected] Abstract. Condensation of circumstellar dust begins with formation of molecular clusters close to the stellar photosphere. These clusters are predicted to act as condensation cores at lower temperatures and allow efficient dust formation farther away from the star. Recent observations of metal oxides, such as AlO, AlOH, TiO, and TiO2, whose emission can be traced at high angular resolutions with ALMA, have allowed first observational studies of the condensation process in oxygen-rich stars. We are now in the era when depletion of gas-phase species into dust can be observed directly. I review the most recent observations that allow us to identify gas species involved in the formation of inorganic dust of AGB stars and red supergiants. I also discuss challenges we face in interpreting the observations, especially those related to non- equilibrium gas excitation and the high complexity of stellar atmospheres in the dust-formation zone. Keywords. stars: AGB and post-AGB; circumstellar matter; stars: mass loss; stars: winds, outflows; dust, extinction; ISM: molecules 1. Dust formation and seed particles in O-rich stars Galaxies certainly care about AGB stars | in the local Universe, galaxies owe huge amounts of dust to these unexhaustive factories of cosmic solids. -
Assessment of Spatial and Temporal Properties of Ka/Q Band Earth-Space Radio Channel Across Europe Using Alphasat Aldo Paraboni
Received: 28 February 2018 Revised: 19 April 2019 Accepted: 27 April 2019 DOI: 10.1002/sat.1313 SPECIAL ISSUE PAPER Assessment of spatial and temporal properties of Ka/Q band earth‐space radio channel across Europe using Alphasat Aldo Paraboni payload Spiros Ventouras1 | Antonio Martellucci11 | Richard Reeves1 | Emal Rumi1 | Fernando P. Fontan2 | Fernando Machado2 | Vicente Pastoriza2 | Armando Rocha3 | Susana Mota3 | Flavio Jorge3 | Athanasios D. Panagopoulos4 | Apostolos Z. Papafragkakis4 | Charilaos I. Kourogiorgas4 | Ondrej Fiser5 | Viktor Pek5 | Petr Pesice5 | Martin Grabner6 | Andrej Vilhar7 | Arsim Kelmendi7 | Andrej Hrovat7 | Danielle Vanhoenacker‐Janvier8 | Laurent Quibus8 | George Goussetis9 | Alexios Costouri9 | James Nessel10 1 STFC Rutherford Appleton Laboratory, RAL Space, Oxford, UK Summary 2 Escola de Enxeñaría de Telecomunicación, The upcoming migration of satellite services to higher bands, namely, the Ka‐ and University of Vigo, Vigo, Spain Q/V‐bands, offers many advantages in terms of bandwidth and system capacity. 3 Dep. Elect. Telec. e Informática, Instituto de However, it poses challenges as propagation effects introduced by the various atmo- Telecomunicações, Aveiro, Portugal 4 School of Electrical and Computer spheric phenomena are particularly pronounced in these bands and can become a Engineering, National Technical University of serious constraint in terms of system reliability and performance. This paper presents Athens, Athens, Greece the goals, organisation, and preliminary results of an ongoing large‐scale European 5 Meteorological Department, Institute of Atmospheric Physics ASCR, Prague, Czech coordinated propagation campaign using the Alphasat Aldo Paraboni Ka/Q band sig- Republic nal payload on satellite, performed by a wide scientific consortium in the framework 6 TESTCOM, Czech Metrology Institute, Prague, Czech Republic of a European Space Agency (ESA) project.