Camphor Hazard Summary Identification Reason For
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Common Name: CAMPHOR CAS Number: 76-22-2 DOT Number: UN 2717 RTK Substance number: 0334 DOT Hazard Class: 4.1 (Flammable Solid) Date: April 1998 Revision: June 2005 ------------------------------------------------------------------------- ------------------------------------------------------------------------- HAZARD SUMMARY * Camphor can affect you when breathed in. * ODOR THRESHOLD = 0.079 ppm. * Contact can irritate the skin and eyes. * The range of accepted odor threshold values is quite * Breathing Camphor can irritate the nose and throat broad. Caution should be used in relying on odor alone as causing coughing and wheezing. a warning of potentially hazardous exposures. * Exposure can cause headaches, nausea, stomach pain, mental confusion, and seizures (fits). Higher exposures WORKPLACE EXPOSURE LIMITS can cause unconsciousness and death. OSHA: The legal airborne permissible exposure limit * Camphor may affect the kidneys and nervous system. (PEL) is 2 mg/m3 averaged over an 8-hour workshift. IDENTIFICATION Camphor is a colorless to white crystalline (sand-like) solid NIOSH: The recommended airborne exposure limit is 3 with an odor like mothballs. It is used in making plastics, 2 mg/m averaged over a 10-hour workshift. lacquers and paints, as a moth repellant, and in flavorings and pharmaceuticals. ACGIH: The recommended airborne exposure limit is 12 mg/m3 averaged over an 8-hour workshift and 3 REASON FOR CITATION 19 mg/m as a STEL (short term exposure limit). * Camphor is on the Hazardous Substance List because it is regulated by OSHA and cited by ACGIH, DOT, NIOSH WAYS OF REDUCING EXPOSURE and NFPA. * Where possible, enclose operations and use local exhaust * Definitions are provided on page 5. ventilation at the site of chemical release. If local exhaust ventilation or enclosure is not used, respirators should be HOW TO DETERMINE IF YOU ARE BEING worn. EXPOSED * Wear protective work clothing. * Wash thoroughly immediately after exposure to The New Jersey Right to Know Act requires most employers Camphor. to label chemicals in the workplace and requires public * Post hazard and warning information in the work area. In employers to provide their employees with information and training concerning chemical hazards and controls. The addition, as part of an ongoing education and training federal OSHA Hazard Communication Standard, 1910.1200, effort, communicate all information on the health and requires private employers to provide similar training and safety hazards of Camphor to potentially exposed information to their employees. workers. * Exposure to hazardous substances should be routinely evaluated. This may include collecting personal and area air samples. You can obtain copies of sampling results from your employer. You have a legal right to this information under OSHA 1910.1020. * If you think you are experiencing any work-related health problems, see a doctor trained to recognize occupational diseases. Take this Fact Sheet with you. CAMPHOR page 2 of 6 This Fact Sheet is a summary source of information of all WORKPLACE CONTROLS AND PRACTICES potential and most severe health hazards that may result from exposure. Duration of exposure, concentration of the substance Unless a less toxic chemical can be substituted for a hazardous and other factors will affect your susceptibility to any of the substance, ENGINEERING CONTROLS are the most potential effects described below. effective way of reducing exposure. The best protection is to --------------------------------------------------------------------------- enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also HEALTH HAZARD INFORMATION reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is Acute Health Effects sometimes necessary. The following acute (short-term) health effects may occur immediately or shortly after exposure to Camphor: In evaluating the controls present in your workplace, consider: (1) how hazardous the substance is, (2) how much of the * Contact can irritate the skin and eyes. substance is released into the workplace and (3) whether * Breathing Camphor can irritate the nose and throat causing harmful skin or eye contact could occur. Special controls coughing and wheezing. should be in place for highly toxic chemicals or when * Exposure can cause headaches, nausea, stomach pain, significant skin, eye, or breathing exposures are possible. mental confusion, and seizures (fits). Higher exposures can In addition, the following control is recommended: cause unconsciousness and death. Chronic Health Effects * Where possible, automatically transfer Camphor from drums or other storage containers to process containers. The following chronic (long-term) health effects can occur at some time after exposure to Camphor and can last for months or years: Good WORK PRACTICES can help to reduce hazardous exposures. The following work practices are recommended: Cancer Hazard * Workers whose clothing has been contaminated by * According to the information presently available to the New Camphor should change into clean clothing promptly. Jersey Department of Health and Senior Services, * Do not take contaminated work clothes home. Family Camphor has been tested and has not been shown to cause members could be exposed. cancer in animals. * Contaminated work clothes should be laundered by individuals who have been informed of the hazards of Reproductive Hazard exposure to Camphor. * According to the information presently available to the New * Eye wash fountains should be provided in the immediate Jersey Department of Health and Senior Services, work area for emergency use. Camphor has not been tested for its ability to affect * If there is the possibility of skin exposure, emergency reproduction. shower facilities should be provided. * On skin contact with Camphor, immediately wash or Other Long-Term Effects shower to remove the chemical. * Camphor may affect the kidneys and nervous system. * Do not eat, smoke, or drink where Camphor is handled, processed, or stored, since the chemical can be swallowed. MEDICAL Wash hands carefully before eating, drinking, smoking, or using the toilet. Medical Testing * Use a vacuum or a wet method to reduce dust during clean- If symptoms develop or overexposure is suspected, the up. DO NOT DRY SWEEP. following are recommended: PERSONAL PROTECTIVE EQUIPMENT * Kidney function tests. * Exam of the nervous system. WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT. However, for Any evaluation should include a careful history of past and some jobs (such as outside work, confined space entry, jobs present symptoms with an exam. Medical tests that look for done only once in a while, or jobs done while workplace damage already done are not a substitute for controlling controls are being installed), personal protective equipment exposure. may be appropriate. Request copies of your medical testing. You have a legal right OSHA 1910.132 requires employers to determine the to this information under OSHA 1910.1020. appropriate personal protective equipment for each hazard and to train employees on how and when to use protective equipment. CAMPHOR page 3 of 6 The following recommendations are only guidelines and may HANDLING AND STORAGE not apply to every situation. * Prior to working with Camphor you should be trained on Clothing its proper handling and storage. * Avoid skin contact with Camphor. Wear protective gloves * Camphor must be stored to avoid contact with and clothing. Safety equipment suppliers/manufacturers can OXIDIZING AGENTS (such as PERCHLORATES, provide recommendations on the most protective PEROXIDES, PERMANGANATES, CHLORATES, glove/clothing material for your operation. NITRATES, CHLORINE, BROMINE and FLUORINE); * All protective clothing (suits, gloves, footwear, headgear) and especially POTASSIUM PERMANGANATE and should be clean, available each day, and put on before CHROMIC ANHYDRIDE, since violent reactions occur. work. * Camphor is not compatible with NAPHTHALENE; 2- NAPHTHOL; DICHLOROBENZENE; and STRONG Eye Protection BASES (such as SODIUM HYDROXIDE and * Wear eye protection with side shields or goggles. POTASSIUM HYDROXIDE). * Store in tightly closed containers in a cool, well-ventilated Respiratory Protection area away from HEAT, SPARKS, FLAMES and IMPROPER USE OF RESPIRATORS IS DANGEROUS. COMBUSTIBLES. Such equipment should only be used if the employer has a * Sources of ignition, such as smoking and open flames, are written program that takes into account workplace conditions, prohibited where Camphor is used, handled, or stored in a requirements for worker training, respirator fit testing and manner that could create a potential fire or explosion medical exams, as described in OSHA 1910.134. hazard. * Where the potential exists for exposure over 2 mg/m3, use a MSHA/NIOSH approved full facepiece respirator with an QUESTIONS AND ANSWERS organic vapor cartridge and high-efficiency particulate prefilters. Increased protection is obtained from full Q: If I have acute health effects, will I later get chronic facepiece powered-air purifying respirators. health effects? * If while wearing a filter or cartridge respirator you can A: Not always. Most chronic (long-term) effects result from smell, taste, or otherwise detect Camphor, or if while repeated exposures to a chemical. wearing particulate filters abnormal resistance to breathing is experienced, or eye irritation occurs