Sediment Geochemistry of the Yamuna River System in the Himalaya: Implications to Weathering and Transport
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Geochemical Journal, Vol. 38, pp. 441 to 453, 2004 Sediment geochemistry of the Yamuna River System in the Himalaya: Implications to weathering and transport TARUN K. DALAI,1,2* R. RENGARAJAN2 and P. P. PATEL3 1Ocean Research Institute, University of Tokyo, Tokyo 164-8639, Japan 2Physical Research Laboratory, Ahmedabad - 380 009, India 3M.S. University of Baroda, Vadodara - 390 002, India (Received October 23, 2003; Accepted March 24, 2004) Bed sediments of the Yamuna River and its tributaries in the Himalaya (Yamuna River System, YRS) have been analyzed for major elements and trace metals (Sr, Ba, Ni, Cu, Co, Zn, Pb and Cr). These results have been used to charac- terize chemical weathering and transport in the Himalaya, to assess relative mobility of elements during weathering and to understand heavy metal association. Concentrations of major and trace elements of YRS sediments vary between 20 and 50%. In general, elemental variability reduces when data are analyzed individually for the major rivers, suggesting that tributaries draining diverse lithology contribute significant variations. Comparison of sediment chemistry with composi- tion of source rocks and average Upper Continental Crust (UCC) suggests significant loss of Na, K, Ca and Mg from source rocks during weathering, the degree of loss being more for Ca and Na. Chemical index of alteration (CIA) for YRS sediments averages at 59, indicating that weathering in the basin is of moderate intensity. This inference is also supported by major ion chemistry of YRS waters and is attributed to steep gradient and enhanced physical erosion in the basin. Available results seem to indicate that Na and Sr are effectively more mobile than Ba, which is thought to be a combined effect of higher solubility of Na and Sr, and the affinity of Ba to be adsorbed onto solid phase. Heavy metals show significant positive correlation with Al and weak correlation with Fe, Mn and P. These observations suggest that metal concentrations are controlled mainly by clay mineral abundances, and that Fe-Mn oxides and organic matter may be playing less significant role. Heavy metal concentrations of YRS sediments are lower than those of suspended particulates of the Yamuna river, presumably due to higher clay mineral abundances in the latter. Strong association of metals with Al, and lower metal concentrations in bed sediments compared to suspended matter underscores the importance of sediment transport and mineral sorting in influencing the YRS sediment chemistry. Enrichment factor and geo-accumulation index calculated for heavy metals in YRS sediments suggest that they are mainly of natural origin and that anthropogenic activi- ties exert little influence on their abundances. Keywords: Yamuna River, Himalaya, chemical weathering, sediment chemistry, elemental mobility ing the Himalaya (Krishnaswami et al., 1992; Sarin et INTRODUCTION al., 1992; Pande et al., 1994; Galy and France-Lanord, The rivers draining the Himalaya contribute signifi- 1999; Dalai et al., 2002a, 2002b, 2002c, 2003). These cantly to the global sediment and water discharge studies are based mainly on isotopic and major ion com- (Milliman and Meade, 1983). They have recently attracted position of dissolved load of rivers. Available geochemical attention of several workers because of the possible con- studies of river sediments in the Indian Himalaya include nection between chemical weathering in the Himalaya and reconnaissance survey of the Ganga and the Yamuna global climate (Raymo and Ruddiman, 1992) as silicate (Subramanian, 1987; Jha et al., 1990; Chakrapani and weathering is thought to be a global sink for CO2 on geo- Subramanian, 1996; Subramanian and Ramanathan, 1996; logic time scales (Walker et al., 1981; Berner, 1995). Such Ramesh et al., 2000) and the Indus (Ahmad et al., 1998). a hypothesis has led to a number of studies on rivers drain- Geochemical studies of sediments in the headwaters of rivers in the Himalaya are limited. The river Yamuna, draining the southern slopes of the *Corresponding author (e-mail: [email protected]) Himalaya in its upper reaches, is the largest tributary of *Present address: Department of Geology and Geophysics, SOEST, the Ganga (Negi, 1991). At the confluence, water dis- University of Hawaii, Manoa 712 POST, 1680 East-West Road., charge of the Yamuna is one and half times that of the Honolulu, HI 96822, U.S.A. Ganga (Rao, 1975). The Yamuna and its major tributaries Copyright © 2004 by The Geochemical Society of Japan. in the Himalaya constitute the Yamuna River System 441 o o o o 68 76 84 92 780 13 0 0 HIGHER o Are a of 77 50’E 78 13’ 32 N G a Stu d y HIMALAYA R New Delhi n anuman h a tti Y g H C a a m R s u . n Gan o a ga R n R . 24 . o 0 T INDIA 77 50 E 0 16o . Mori 30 49 N s R on R T r 27 LESSER Kuthnaur a b 26 28 G Hanuman C hatti HIMALAYA a o Mori R P Tiuni d d R. u a a P a Gad G n u n . i u Purola r Tiuni R l m o mu . 29 a a l R a P Y a a Purola l Y s o 18 R arkot Sh n r 19 Did B ej o u ar Ga Kh T P 20 d ad 22 Naugaon d 21 25 0 rni Ga 31 Barkot 30 49’ Ba 30 Naugaon S R Minas 14 Kuwa h . Barni G ad s e R n . j 12 13 o R K T a Kuwa h w a . a Mina s a n R l u d G s ir m i R. n m o Kalsi A a T Y A 5 8 m Bata R. 32 9 lawa Paonta 6 Aglar R. 2 R Dakpathar Sahib R lar R Mussoorie a g 1 A 3 n A u sa Batamandi 4 n N m R. a Y 300 11’ N Tajewala 11 Dehradun Mussoorie 300 11 R R a Giri n R Kalsi u a m n Ya u m Dehradun a km Y 0 15 To Saharanpur ( # 33) Sampling Locations Crysta lline s boundary Towns LH-HH Carbonates Fig. 1. Map showing sediment sampling locations in the Yamuna Oth e r Sedimentaries and its tributaries in the Himalaya. Fig. 2. General lithology of the YRS drainage basin. Only some of the tributaries are shown. (Negi, 1991). This work, which builds on our earlier stud- ies (Dalai et al., 2002a, b, c), forms a part of detailed fractions were powdered either in an agate mortar or in a geochemical and isotopic investigation of the Yamuna Spex ball mill with acrylic container and methylacrate River System (YRS) in the Himalaya. Reported here are balls, and were sieved to <100 mesh size using nylon the concentrations of major and trace elements in sieves. Samples >100 mesh size were repeatedly pow- sediments of the Yamuna and its tributaries in the dered to bring all the materials to <100 mesh size. Dur- Himalaya. Results obtained in this study, in conjunction ing powdering, care was taken to ensure that samples did with those available on bed rocks in the basin and dis- not come in contact with any metal surface. After thor- solved load of the YRS (Dalai et al., 2002a, b), are used ough homogenization, powdered samples were stored in to (i) characterize chemical weathering in the YRS basin, clean plastic bottles. About 500 mg of sample was (ii) assess relative mobility of elements during weather- weighed and dissolved in PTFE dish by repeatedly treat- ing and transport, and (iii) determine the origin and asso- ing with hot HF-HCl-HNO3-HClO4 mixture and finally ciation of heavy metals in river sediments. dissolving in 1N HNO3. These solutions were used for elemental analysis after suitable dilution. Some samples were digested in replicates and analyzed to assess the pre- SAMPLING AND ANALYSIS cision of measurements. Reagents used for sample disso- Riverbed sediments were collected from the Yamuna lution were analyzed to assess their blank contribution. mainstream and its tributaries (Fig. 1) during October USGS rock standard (G-2) and an in-house laboratory 1998. Details of the sampling and analysis are given in standard (NOVA, prepared from the Pacific sediments, Dalai (2001) and Dalai et al. (2002a, b). Samples were Agnihotri, 2001) were also dissolved along with the sam- collected in zip-lock polythene bags using a plastic scoop. ples and analyzed to check the accuracy of the measure- In the laboratory, they were oven-dried at ~90°C and ments. Ca, Mg, Al, Sr, Ba, Fe, P, Ti, Pb, Zn and Cr were sieved to <1 mm size using nylon sieves. The <1 mm size measured by ICP-AES (Jobin Yvon 38S), and Na, K, Mn, 442 T. K. Dalai et al. Table 1. Results of analysis of reference standards G-2 and NOVA G-2 NOVA Element Measured Reported* Measured ICP-AES** ICP-MS** Cu 10.13 12 407 ± 2 392 ± 20 403 Ni 20.7 ± 0.9 13.7 244 ± 1 206 ± 15 224 Co 33.95 20.7 134 104 ± 7 101 Ti n.m. n.m. 3787 ± 234 3810 ± 245 4076 P n.m. n.m. 2009 ± 87 1875 ± 34 1702 Cr 5.89 ± 0.11 9 61 ± 2 63 ± 484 Zn 77 ± 2 85 137 ± 5 152 ± 10 146 Pb 23.3 ± 0.4 31 33.4 ± 1.2 n.m. 35.5 *Reported value from Potts et al. (1992). **ICP-AES and ICP-MS data of NOVA from Agnihotri (2001). n.m.: not measured. Cu, Ni and Co by flame-AAS (Perkin Elmer 4000). Car- river flows past the Higher Himalaya, it drains quartz- bonate contents were determined by coulometric titration.