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Environmental, Health, and Safety Guidelines for Cement and Lime Manufacturing
Environmental, Health, and Safety Guidelines CEMENT AND LIME MANUFACTURING WORLD BANK GROUP DRAFT FOR PUBLIC CONSULTATION—AUGUST 2018 Environmental, Health, and Safety Guidelines for Cement and Lime Manufacturing Introduction 1. The Environmental, Health, and Safety (EHS) Guidelines are technical reference documents with general and industry-specific examples of Good International Industry Practice (GIIP).1 When one or more members of the World Bank Group are involved in a project, these EHS Guidelines are applied as required by their respective policies and standards. These industry sector EHS guidelines are designed to be used together with the General EHS Guidelines document, which provides guidance to users on common EHS issues potentially applicable to all industry sectors. For complex projects, use of multiple industry sector guidelines may be necessary. A complete list of industry sector guidelines can be found at www.ifc.org/ehsguidelines. 2. The EHS Guidelines contain the performance levels and measures that are generally considered to be achievable in new facilities by existing technology at reasonable costs. Application of the EHS Guidelines to existing facilities may involve the establishment of site-specific targets, with an appropriate timetable for achieving them. 3. The applicability of the EHS Guidelines should be tailored to the hazards and risks established for each project on the basis of the results of an environmental assessment in which site-specific variables, such as host country context, assimilative capacity of the environment, and other project factors, are taken into account. The applicability of specific technical recommendations should be based on the professional opinion of qualified and experienced persons. -
96 Quality Control of Clinker Products by SEM and XRF Analysis Ziad Abu
ACXRI '96 Quality Control of Clinker Products By SEM and XRF Analysis Ziad Abu Kaddourah and Khairun Azizi MY9700786 School of Materials and Mineral Resources Eng., Universiti Sains Malaysia 31750 Tronoh, Perak, Malaysia. ABSTRACT The microstructure and chemical properties of industrial Portland cement clinkers have been examined by SEM and XRF methods to establish the nature of the clinkers and how variations in the clinker characteristics can be used to control the clinker quality. The clinker nodules were found to show differences in the chemical composition and microstructure between the inner and outer parts of the clinker nodules. Microstructure studies of industrial Portland cement clinker have shown that the outer part of the nodules are enriched in silicate more than the inner part. There is better crystallization and larger alite crystal 9ize in the outer part than in the inner part. The alite crystal size varied between 16.2-46.12um. The clinker chemical composition was found to affect the residual >45um, where a higher belite content causes an increase in the residual >45um in the cement product and will cause a decrease in the concrete strength of the cement product. The aluminate and ferrite crystals and the microcracks within the alite crystal are clear in some clinker only. The quality of the raw material preparation, burning and cooling stages can be controlled using the microstructure of the clinker product. INTRODUCTION Examination of manufactured industrial clinkers using the Scanning Electron Microscope (SEM) is usually conducted to study problems that can't be defined by the normal quality control procedures. Such a study can be used to give better information and knowledge about clinkers characteristics and how variations in the clinker characteristics are affected by variations in the various stages during the manufacturing process. -
Industrial Scale Kiln Problems and Their Solution with Controlling Different Operating Parameters
Open Access Austin Chemical Engineering Research Article Industrial Scale Kiln Problems and Their Solution with Controlling Different Operating Parameters Fazeel Ahmad* Department of Chemical Engineering, University of Wah, Abstract Wah Engineering College, Pakistan The chemical composition homogeneity of kiln feed has an important *Corresponding author: Fazeel Ahmad, Department relationship to fuel consumption, kiln operation, clinker formation and cement of Chemical Engineering, University of Wah, Wah strength. Kiln operation can be made stable and smooth. The basis for this Engineering College, Pakistan property is a well-burned clinker with consistent chemical composition and free lime. The main reason for the clinker free lime to change in situation with Received: April 19, 2020; Accepted: May 12, 2020; stable kiln operation is variation in the chemical composition of the kiln feed. Published: May 19, 2020 This variation in chemical composition is related to raw mix control and the homogenization process. To ensure a constant quality of the product and maintain a stable and continuous operation of the kiln, the attention must be paid to storage and homogenization of raw materials and kiln feed. Due to variations in the kiln feed chemical compositions that affect its burn ability and the fuel consumption. The objective of this research paper is to provide solutions of the problems occurring in well burned clinker through stable kiln operation and efficient cooler heat transfer. The quality of cement is assessed typically from its -
CBA® Quality/Strength-Enhancing Additive
PRODUCT DATA SHEET CBA® Quality/strength-enhancing additive Product Description The CBA® series of additives is a new concept in grinding aids - significantly different from any previous GCP product for the cement industry. The difference is that it is a “Grinding Aid Plus”. CBA additives offer all the benefits of traditional grinding aids, such as increased grinding efficiency and cement flowability. In addition, they offer a unique ability to improve cement strengths which might otherwise be deficient due to mechanical, physical or chemical shortcomings. Advantages include either reduced cost of production or increased cement strengths. Physical Properties Product specifications for the most widely used CBA formulations are as follows: Product SG pH CBA 1102 1.06 (±0.01) 7 - 9 CBA 1104 1.07 (±0.01) 8 - 12 CBA 1115 1.10 (±0.01) 6 - 8 Specifications for other CBA formulations not shown above are available through GCP Applied Technologies Field Engineers. • Increased early and long-term compressive strengths for production of better quality cements. Primary Benefit • Reduced cost of cement production through reduced unit grinding The CBA series of additives consists of tailor-made formulations costs and through replacement of clinker with reactive additions to optimise performance and meet specific requirements at each such as pozzolans, blast furnace slag and fly ash or with fillers such plant. as limestone. The use of CBA allows the cement producer to reduce fineness • CBA additives are most effective in enhancing compressive and achieve lower unit power costs without sacrificing strength. strengths of blended cements using up to 40% limestone filler. Compared with conventional grinding aids, CBA offers unit power • When cement particle size is not reduced, the addition of CBA savings of up to 25% with no loss of strength. -
Separate Calcination in Cement Clinker Production
Separate Calcination in Cement Clinker Production A laboratory scale study on how an electrified separate calcination step affects the phase composition of cement clinker Amanda Vikström Master thesis, 30 hp M.Sc. in Energy Engineering, 300 hp Department of Applied Physics and Electronics, Spring term 2021 Separate Calcination in Cement Clinker Production A laboratory scale study on how an electrified separate calcination step affects the phase composition of cement clinker Amanda Vikström [email protected] Master Thesis in Energy Engineering Department of Applied Physics and Electronics Umeå University Examiner: Robert Eklund Supervisors: Matias Eriksson, José Aguirre Castillo and Bodil Wilhelmsson Performed in collaboration with Cementa AB and the Centre for Sustainable Cement and Quicklime Production at Umeå University 31 may 2021 Abstract Cement production is responsible for around 7% of the global anthropogenic carbon dioxide emissions. More than half of these emissions are due to the unavoidable release of carbon dioxide upon thermal decomposition of the main raw material limestone. Many different options for carbon capture are currently being investigated to lower emissions, and one potential route to facilitate carbon capture could be the implementation of an electrified separate calcination step. However, potential effects on the phase composition of cement clinker need to be investigated, which is the aim of the present study. Phases of special interest are alite, belite, aluminate, ferrite, calcite, and lime. The phase composition during clinker formation was examined through HT-XRD lab-scale experiments, allowing the phase transformations to be observed in situ. Two different methods of separate calcination were investigated, one method in which the raw meal was calcined separately, and one method where the limestone was calcined separately. -
Equivalent Cement Clinker Obtained by Indirect Mechanosynthesis Process
materials Article Equivalent Cement Clinker Obtained by Indirect Mechanosynthesis Process Rabah Hamzaoui * and Othmane Bouchenafa * Institut de Recherche en Constructibilité IRC, ESTP, Université Paris-Est, 28 Avenue du Président Wilson, 94234 Cachan, France * Correspondence: [email protected] (R.H.); [email protected] (O.B.); Tel.: +33149080334 (R.H.); +33149082327 (O.B.) Received: 23 September 2020; Accepted: 6 November 2020; Published: 9 November 2020 Abstract: The aim of this work is to study the heat treatment effect, milling time effect and indirect mechanosynthesis effect on the structure of the mixture limestone/clay (kaolinite). Indirect mechanosynthesis is a process that combines between mechanical activation and heat treatment at 900 ◦C. XRD, TGA, FTIR and particle size distribution analysis and SEM micrograph are used in order to follow thermal properties and structural modification changes that occur. It is shown that the indirect mechanosynthesis process allows the formation of the equivalent clinker in powder with the main constituents of the clinker (Alite C3S, belite C2S, tricalcium aluminate C3A and tetracalcium aluminoferrite C4AF) at 900 ◦C, whereas, these constituents in the conventional clinker are obtained at 1450 ◦C. Keywords: cement clinker; clinkerization; indirect mechanosynthesis; nanostructured materials; crystalline structures 1. Introduction Portland cement is manufactured from raw material obtained by mixing and grinding limestone and minerals rich in silica and alumina (clay or kaolin) and other additives. This mixture is then calcined at 1450 ◦C to obtain the clinker. The clinker is finely crushed and blended with a source of sulfate (gypsum or anhydrite) and other minerals to form the cement [1]. However, the production of cement is responsible for high energy consumption. -
Delayed Ettringite Formation
Ettringite Formation and the Performance of Concrete In the mid-1990’s, several cases of premature deterioration of concrete pavements and precast members gained notoriety because of uncertainty over the cause of their distress. Because of the unexplained and complex nature of several of these cases, considerable debate and controversy have arisen in the research and consulting community. To a great extent, this has led to a misperception that the problems are more prevalent than actual case studies would indicate. However, irrespective of the fact that cases of premature deterioration are limited, it is essential to address those that have occurred and provide practical, technically sound solutions so that users can confidently specify concrete in their structures. Central to the debate has been the effect of a compound known as ettringite. The objectives of this paper are: Fig. 1. Portland cements are manufactured by a process that combines sources of lime (such as limestone), silica and • to define ettringite and its form and presence in concrete, alumina (such as clay), and iron oxide (such as iron ore). Appropriately proportioned mixtures of these raw materials • to respond to questions about the observed problems and the are finely ground and then heated in a rotary kiln at high various deterioration mechanisms that have been proposed, and temperatures, about 1450 °C (2640 °F), to form cement compounds. The product of this process is called clinker • to provide some recommendations on designing for durable (nodules at right in above photo). After cooling, the clinker is concrete. interground with about 5% of one or more of the forms of Because many of the questions raised relate to cement character- calcium sulfate (gypsum shown at left in photo) to form portland cement. -
Alite Calcium Sulfoaluminate Cement: Chemistry and Thermodynamics
This is a repository copy of Alite calcium sulfoaluminate cement: chemistry and thermodynamics. White Rose Research Online URL for this paper: http://eprints.whiterose.ac.uk/144183/ Version: Accepted Version Article: Hanein, T. orcid.org/0000-0002-3009-703X, Duvallet, T.Y., Jewell, R.B. et al. (5 more authors) (2019) Alite calcium sulfoaluminate cement: chemistry and thermodynamics. Advances in Cement Research, 31 (3). pp. 94-105. ISSN 0951-7197 https://doi.org/10.1680/jadcr.18.00118 © 2019 ICE Publishing. This is an author produced version of a paper subsequently published in Advances in Cement Research. Uploaded in accordance with the publisher's self-archiving policy. Reuse Items deposited in White Rose Research Online are protected by copyright, with all rights reserved unless indicated otherwise. They may be downloaded and/or printed for private study, or other acts as permitted by national copyright laws. The publisher or other rights holders may allow further reproduction and re-use of the full text version. This is indicated by the licence information on the White Rose Research Online record for the item. Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing [email protected] including the URL of the record and the reason for the withdrawal request. [email protected] https://eprints.whiterose.ac.uk/ Abstract: Calcium sulfoaluminate (C$A) cement is a binder of increasing interest to the cement industry and as such is undergoing rapid development. Current formulations do not contain alite; however, it can be shown that hybrid C$A-alite cements can combine the favourable characteristics of Portland cement with those of C$A cement while also having a lower carbon footprint than the current generation of Portland cement clinkers. -
Reactions Accompanying Stabilization of Clay with Cement A
Reactions Accompanying Stabilization Of Clay with Cement A. HERZOG, Senior Lecturer in Civil Engineering, University of New South Wales, Newcastle, Australia, and J. K. :MITCHELL, Assistant Professor of Civil Engineering, and Assistant Research Engineer, Institute of Transportation and Traffic Engineering, University of California, Berkeley This paper reports the results of an investigation aimed at de lineating the nature of the reactions accompanying the stabili zation of clay with portland cement. Consideration of the nature of cement hydration, the physico-chemical character istics of clays and lime-clay interaction leads to the hypothesis that during the hydration of a clay-cement mixture, hydrolysis and hydration of cement could be regarded as primary reac tions which form usual cement hydration products, increase the pH, and liberate lime. The high pH and Ca(OHh concen tration could initiate attack of the clay particles and also cause breakdown of amorphous silica and alumina which then could combine with calcium to form secondary cementitious material. A clay-cement skeleton and a clay matrix are likely. Mechanical, X-ray diffraction, and chemical tests on kao linite and montmorillonite stabilized with portland cement and with pure tricalcium silicate (C3S), the major strength-producing compound in portland cement, gave results in agreement with this hypothesis. Compacted clay-cement mixtures were cured at 100 percent relative humidity and at 60 C (to accelerate hardening) and studied at different times after molding. X-ray analyses showed that calcium hydroxide was formed in hydrat ing clay-cement, but was rapidly used up in reaction with the clay. Minor alteration of the kaolinite-cement X-ray pattern and marked alteration of the montmorillonite-cement X-ray pattern were indicated after curing periods of 12 weeks, sug gesting clay mineral structure breakdown and/or interaction with cement at particle surfaces. -
OK™ Cement Mill the Most Energy- Efficient Mill for Cement Grinding
OK™ cement mill The most energy- efficient mill for cement grinding WE DISCOVER POTENTIAL Quality and profit-improving features Application advantages Design advantages Proven commercially, the OK™ mill is the premier roller mill for The OK mill uses a hydro-pneumatic system to press its grinding finish grinding of Portland cement, slag and blended cements. The rollers against the material bed on the rotating grinding table. mill consistently uses five to ten percent less power than other The patented grooved roller profile has two grinding zones, an cement vertical roller mills, and in comparison with traditional ball inner and an outer. The inner zone prepares the grinding bed by mill operations, the energy requirements for the OK cement mill is compressing the feed material as it moves under the rollers into the 30-45 percent lower for cement grinding and 40-50 percent lower high-pressure grinding zone. The center groove allows air to for slag. The OK mill can contribute significantly to profitability and escape from the material. Grinding pressure is concentrated under competitiveness. the outer zone of the roller, allowing for most efficient operation. Segmented roller wear parts are made of the hardest possible The design combines the drying, grinding, material conveying and material without risk of cracking and are very well suited for hard separation processes into just one unit, thus simplifying the plant facing. Re-positioning of rollers is possible for evening out wear. layout. These features ensure maximum longevity. The OK mill incorporates unique patented design elements in the Operating advantages roller and table profile that improve operating stability and reliability, The rollers are in a lifted position when the mill is started, ensuring giving a typical availability of 90 to 95 percent of scheduled ope- trouble-free start-up. -
Item 421 Hydraulic Cement Concrete
421 Item 421 Hydraulic Cement Concrete 1. DESCRIPTION Furnish hydraulic cement concrete for concrete pavements, concrete structures, and other concrete construction. 2. MATERIALS Use materials from prequalified sources listed on the Department website. Provide coarse and fine aggregates from sources listed in the Department’s Concrete Rated Source Quality Catalog (CRSQC). Use materials from non-listed sources only when tested and approved by the Engineer before use. Allow 30 calendar days for the Engineer to sample, test, and report results for non-listed sources. Do not combine approved material with unapproved material. 2.1. Cement. Furnish cement conforming to DMS-4600, “Hydraulic Cement.” 2.2. Supplementary Cementing Materials (SCM). Fly Ash. Furnish fly ash, ultra-fine fly ash (UFFA), and modified Class F fly ash (MFFA) conforming to DMS-4610, “Fly Ash.” Slag Cement. Furnish Slag Cement conforming to DMS-4620, “Slag Cement.” Silica Fume. Furnish silica fume conforming to DMS-4630, “Silica Fume.” Metakaolin. Furnish metakaolin conforming to DMS-4635, “Metakaolin.” 2.3. Cementitious Material. Cementitious materials are the cement and supplementary cementing materials used in concrete. 2.4. Chemical Admixtures. Furnish admixtures conforming to DMS-4640, “Chemical Admixtures for Concrete.” 2.5. Water. Furnish mixing and curing water that is free from oils, acids, organic matter, or other deleterious substances. Water from municipal supplies approved by the Texas Department of Health will not require testing. Provide test reports showing compliance with Table 1 before use when using water from other sources. Water that is a blend of concrete wash water and other acceptable water sources, certified by the concrete producer as complying with the requirements of both Table 1 and Table 2, may be used as mix water. -
TDA Cement Additive
Product Data Sheets TDA ® Quality Improvers A Family of Strength Enhancing Cement Additives Product Description TDA ® Quality Improvers are a family of cement additives that improve the strength or other performance characteristics of cement. They are aqueous compositions of grinding aids with set accelerating, water reducing or strength enhancing compounds, all carefully controlled and accurately blended for constant quality and optimum performance. Product specifications for the most widely used TDA ® formulations are as follows: S.G.S.G. PHPH TDA ® J 1.22 (±0.01) 6 - 8 TDA ® N 1.21 (±0.01) 8 - 10 TDA ® 710 1.34 (±0.02) 8 - 10 TDA ® 770 1.17 (±0.01) 8 - 10 TDA ® 1223 1.15 (±0.05) 6 - 8 TDA ® 7014 1.03 (±0.02) 9 - 12 Product specifications for other TDA ® formulations are available through GCP Field Engineers. Product Advantages One of the key benefits of TDA ® additives is their ability to increase both the grinding efficiency and cement strengths to a degree unequalled by conventional grinding aids. Increased early and long-term compressive strengths for the production of better quality cements. Reduced cost of cement production through reduced unit grinding costs and through replacement of clinker with reactive additions such as pozzolans, blast furnace slag and fly ash, or with fillers such as limestone. The chemical action of TDA ® additives decreases the interparticle attraction between cement grains both in dry form and in water, and increases the rate of hydration of cements. Additional advantages of TDA ® additives include: Page 1 of 5 Product Data Sheets Increased grinding efficiency resulting in increased mill output, higher cement fineness and reduced unit power input and grinding costs.