Fmpc Hazard Communication Standard Written Program 08/25/87 Wmco:Eh(Ih)

526

FMPC HAZARD COMMUNICATION STANDARD WRITTEN PROGRAM

08/25/87

WMCO:EH(IH):87:150 WMCO 100 MANUAL a--m a--m - G-000-1105.6 -

FMPC Hazard Communication Standard Written Program

Westinghouse Materials Company of Ohio

Topical Manual FMPC-2086 1 Y

WMCO

HAZARD COMMUNICATION STANDARD PROGRAM

In Compliance With

OSHA 29 CFR 1910.1200 526

The following is the Written Hazard Communication Program for the Westinghouse Materials Company of Ohio. Its purpose is to provide information in order for you to understand and comply with the various requirements defined in the Occupational Safety and Health Administrations’ Hazard Communication standard. Questions or comments regarding the contents of this manual should be referred to the Industrial Hygiene Subsection of the Environment, Safety and Health Department. As with many documents, changes and updates are expected. This manual will be reviewed and revised as necessary to reflect these changes.

Effective Date June 15, 1987 TABLE OF CONTENTS 528

I ntrodu tion ...... 1

1. A List of Hazardous Materials Known to be Present in the Workplace...... 3

2. Methods to be Used as to How Employees Will be Notified of the

Hazards of Non-routine Tasks...... 4

3. Methods to be Used as to How Employees Will be Notified of the

Hazards of Unlabeled Pipes in Their Work Area...... 5

4. Methods to be Used as to How Subcontractor Employees Will be notified of the Hazardous Materials They May be Exposed to

While Performing Their Work and Any Suggestions for

Appropriate Protective Measures...... 6

5. Methods to be Used to Ensure That Each Hazardous Material Container is Labeled...... 7

6. Methods to be Used to Ensure that Material Safety Data Sheets

(MSDS) Will be Maintained...... 9

7. A Description of How MSDS and Labeling Requirements Will be Explained...... 10

8. A Description of How Employees Will be Notified of New Hazards in the Workpl ace...... 11 TABLE OF C 0 N T E N T S (contd.) 526

9. A Descripti‘on of How the Training/Informing Requirements Will beHandled...... 11

Appendix I - Occupational Safety and Health Administration‘s Hazard Communication Standard, 29 CFR 1910.1200 ...... 14

Appendix 11 - Department of Energy Environment, Safety, and Health Bulletin, Issue No. 14, DOE/EH-0003, Sept. 1985 ...... 31

Appendix I11 - List of Hazardous Materials ...... 34

Appendix IV - Label and Rating Criteria ...... 55

Appendix V - Responsibilities for Implementing the Hazard Communication Standard ...... 63

Appendix VI - Material Safety Data Sheet Request Form...... 72

Appendix VI1 - Material Safety Data Sheet Plant Locations . . . . . 74

Appendix VI11 - Initial Training Topics ...... 76

Appendix IX - Specific Chemical Category Topics ...... 80

0 Appendix X - Supervisor’s Training Form ...... 88 HAZARD COMMUNICATION STANDARD PROGRAM 528

Introduction

The Occupational Safety and Health Administration’s Hazard Communication Standard (29 CFR 1910.1200) requires a written program be maintained for each facility. This program will address the following:

1. A.list of hazardous materials known to be present in the workplace.

2. Methods to be used as to how employees will be notified of the hazards of non-routine tasks.

3. Methods to be used as to how employees will be notified of the hazards of unlabeled pipes in their work area.

4. Methods to be used as to how subcontractor employees will be notified of the hazardous materials they may be exposed to while performing their work and any suggestions for appropriate protective measures.

5.. Methods to be used to ensure that each hazardous material container is labeled.

6. Methods to be used to ensure that Material Safety Data Sheets (MSDS) will be maintained. r. 6 526 7. A description of how MSDS and labeling requirements will be expl ai ned.

8. A description of how employees will be notified of new hazards in the workpl ace.

9. A description of how the training/informing requirements will be hand1 ed.

. This document is WMCO’s Written Program and will discuss each of these items in detail and explain how the FMPC will comply with these requirements.

-I ).) 2 0 1. A List of Hazardous Materials Known to be Present in the Workplace 52s

The list of hazardous materials used at the FMPC is attached as Appendix I11 of this program. The list is prepared by Industrial Hygiene personnel and i nvol ves reviewing a1 1 purchase orders, entering appropriate information from the purchase order to a data base, and then generating the list of hazardous materials. All chemicals and mixtures received since 1/1/84 are listed. The complete list, maintained by Industrial Hygiene, shall be kept current by periodic updates. The receipt of an MSDS from a supplier is the first step in determining if a material is hazardous or not. Requests for additional information from manufacturers and WMCO Environment, Safety, and Health resources are also used to determine if materials are hazardous. If no information is available on a chemical or chemical mixture, the material is considered hazardous. Industrial Hygiene has primary responsibility for this requirement. The Requistioner must obtain a MSDS for any new material and supply this to Industrial Hygiene prior to ordering the material. The Requistioner and Purchasing must order a MSDS, as a line item, if the material is a "rush" item and a MSDS is not available.

3 r. 8 2. Methods to be Used as to How Employees Will be Notified of the Hazar-626

of Non-routine Tasks.

There are non-routine tasks performed at the FMPC which may result in

employee exposure to hazardous materials. Non-routine tasks are defined

as those not covered by an SOP or some other defined criteria such as

construction projects, work permit jobs, work performed under a Plant

Test Authorization (PTA), testing of new products, or other work which

introduces new potentially hazardous material to the workplace or causes

untrained workers to handle a material. Employees should be alert to

these possibilities. It is the responsibility of all supervision to

recognize that these hazards may be associated with the non-routine task

to be performed and to determine, with the assistance of personnel from

Industrial Hygiene, if necessary, or other ES&H personnel, the

precautions to be taken. Prior to performing the work, involved

employees must be informed of the hazardous materials they may encounter

and the necessary protective measures that must be used. Supervision

and involved employees shall review the hazards associated with these

materials. Industrial Hygiene shall be contacted if there are

additional questions. Documentation of this training is required and

shall be reported on the form found in Appendix X. *Review of other

safety matters concerning a non-routine task would also be appropriate

at this time. Work Permits shall be obtained by supervision, as

required, and will also serve to inform employees of hazards of

non-routine tasks. Larger projects, such as those requiring engineering

support, are reviewed by personnel from Industrial Hygiene in the

planning stages and the.necessary steps are taken to ensure that those

4 P ,*

a. 9 employees assigned to this project are informed of the hazardous 525 materials they may encounter and that the proper protection is used. It is often difficult to foresee every possible situation during the planning stages of projects. The construction engineer, production, or maintenance supervisor, as well as employees, must be constantly alert for potential problems and inform Industrial Hygiene when the potential for hazardous material/chemical exposure exists. All employees should refer to and be familiar with established Environment, Safety, and Health procedures already in place to ensure safe working conditions such as those described in the current Health and Safety Manual and all requirements listed in applicable FMPC standard operating procedures

(SOPS).

3. Methods'to be Used as to How Employees Will be Notified of the Hazards of Unlabeled Pipes in Their Work Area.

It is the responsibility of supervision to ensure that employees are aware of the hazards (if any) of unlabeled pipes in their work area. Supervision must contact other plant personnel, the utility engineer, or other knowledgeable persons if they are uncertain of the contents of pipes in their work area, then contact Industrial Hygiene if, after' reviewing the hazards associated with this material with employees, more information s requ red. Refer also to Section 9 of this program. 5 c 10 525 4. Methods to be Used as to How Subcontractor Employees Will be notified of the Hazardous Materials They May be Exposed to While Performing Their Work and Any Suggestions for Appropriate Protective Measures.

Subcontractor employees shall be informed of the hazardous materials they may encounter while performing work at the FMPC by providing the subcontractor with a list of hazardous materials for that work area. Subcontractors shall be informed of the presence of these items before beginning work, at prebid or at preconstruction meetings, and the necessary MSDS will also be provided at this time. Any requirements for personal protective equipment, respirator fit testing, or other items will be provided at this time. This will allow the subcontractor time to train/inform his/her employees of these items. It is the responsibility of the project manager to ensure that this information has been provided to the subcontractor by ES&H in regard to materials encountered at the FMPC. Similarly, it will be the responsibility of the project manager to ensure that Rust Safety has obtained MSDS from the sub-contractor for hazardous materials which the sub-contractor will use in the project and has forwarded the MSDS to WMCO Industrial Hygiene. This must be written into the contract. These must be in the Industrial Hygiene office at least one week prior to the materials arrival at the FMPC. This will allow time to communicate this information to WMCO employees who may'be in the project work or storage areas, or who may be emergency response team members.

6 SZk 5. Methods to be Used to Ensure That Each Hazardous Material Container is Labeled.

Incoming conta ners of hazardous materials, which are properly labe do not have to be relabeled with the FMPC in-plant label (described

later). A properly labeled ncoming container has the foll owing information:

A. Name of the material B. Name and address of the manufacturer or supplier. C. Some type of hazard warning.

If that label is unreadable or partially destroyed, then the material must be set aside in a designated safe area until the proper label can be obta ned and placed on the container. The label to use for this purpose can be one supplied by the manufacturer or an in-plant label can be used The in-plant label to use for this purpose is a diamond label, color coded, with space to indicate hazards. This in-plant label is used for labeling stationary containers (e.g. tanks) and other unmarked containers (e.g. drums or pails) into which a hazardous material has

been transferred from a labeled container. A numerical hazard rating scheme has been adopted to provide the user with hazard information. Each color represents a different hazard and is rated on a scale 0

through 4, with 4 as the most serious hazard rating. The bottom portion of the diamond label is reserved for indicating special hazards such as ''OXY" for oxidizing materials, "+"indicating not to use water, and indicating a possible radiation hazard. The top portion of the e 7 12 526 label, above the diamond, must identify the hazardous material. The bottom portion of the label can contain additional information about the material. It is not necessary, when labeling in-plant, to include the manufacturers' name and address, only the identification of the material and hazard warnings are necessary. See Appendix IV for a diagram of the label and the criteria used by Industrial Hygiene for rating hazardous materials. Unless the container is emptied, all containers of hazardous materials, with the exception of those items listed in the referenced sources (e.9. hazardous waste which is regulated by EPA), must be labeled and no label should be removed or defaced.

All employees, who work with hazardous materials, must be aware of the need to have proper labels on all containers. Employees must label unmarked containers into which they have transferred a hazardous material. Employees are also responsible for attending the training sessions concerning the Hazard Communication Standard, reading and understanding the in-plant labeling system as well as labeling systems used by suppliers of hazardous materials which they use, following established procedures for handling that material, and reporting unlabeled containers to supervision. Receiving Group supervision is responsible for ensuring incoming containers are properly labeled, as described above, and reporting improperly labeled containers to the buyer and Industrial Hygiene. Shipping Group supervision is responsible for ensuring containers shipped by the FMPC offsite are properly labeled. These labels will be supplied to the Shipping Group by Industrial Hygiene. Production supervision is responsible for ensuring that all containers located in or leaving their area are properly labeled with FMPC in-plant labels or labels provided by the 8 '* '* 13 manufacturer. These supervisors should notify Industrial Hygiene 528 personnel whenever they receive any containers of hazardous materials that are unlabeled. Stores supervi s on should ensure that all containers of hazardous materials are properly labeled before distribution to the requester. Improperly labeled conta ners, from outside vendors, should be reported to Purchasing and to Industrial Hygiene. Purchasing should be aware of the importance of dealing only with manufacturers and suppliers who abide by the OSHA Hazard Communication Standard (most are required to do so as of November 25, 1985). Industrial Hygiene has overall responsibility for implementing the standard and, with the assistance of supervision, will ensure all the necessary stationary containers of hazardous materia s are abeled. See Appendix V for the responsibilities of the various groups of the WMCO.

6. Methods to be Used to Ensure that Material Safety Data Sheets (MSDS) Will be Maintained.

Upon receipt of a MSDS, Industrial Hygiene will ensure that a copy of the MSDS is distributed to those areas of the FMPC using or storing this material Binders or file cabinets marked "Material Safety Data Sheets" will be maintained by that area's supervision for filing of these MSDS. A form is provided in Appendix VI for requesting MSDS for materials .e which are in a work area but do not have MSDS. Purchase order 9 . 14 5 26 information and Stores issue data will be used to determine which areas of the FMPC need a particular MSDS. Industrial Hygiene will maintain a master file of MSDS’s. Appendix VI1 lists areas at the FMPC where the binders or files of MSDS’s are located and the responsible individual in that area for maintaining the MSDS’s.

7. A Description of How MSDS and Labeling Requirements Will be Explained.

Each employee, who works with hazardous materials or who may be potentially exposed to a hazardous material, will be trained in understanding the MSDS and labeling requirements. This will be accomplished in general employee training sessions by reviewing categories of hazardous materials, by describing to the employees, the NFPA, DOT, HMIS, and other labeling systems, and by a specific review of a MSDS for a particular hazardous material. In addition, supervisors or ES&H personnel will review MSDS with empl oyees. Literature and audiovisual techniques may also be used.

10 15 526 8. A Description of How Employees Will be Notified of New Hazards in the Workpl ace.

When a new hazard is introduced into the workplace, the supervisor shall review the hazard with the employee, with assistance from ES&H personnel. If the new hazard requires that engineering or other controls be used to prevent exposure, then additional training, such as reviewing the MSDS, shall be provided (see Appendix X).

a 9. A Description of How the Training/Informing Requirements Will be Hand1 ed.

The following requirements are intended to ensure that all employees of the FMPC are aware of the requirements of this standard and are appropriately trained for their job. In addition to hazardous materials, the DOE standard requires training of employees who work in areas where physical and biological hazards exist and controls are in place to limit exposure. The following describes areas of responsibility in meeting the training requirements, frequency of training, and a guide for training and informing employees. Industrial Hygiene is responsible for implementing and managing the training requirements of the Hazard Communication Standard. This includes 11 16 526 maintaining training records and assisting supervision in training/informing employees. Supervision is responsible for ensuring that their employees are informed and trained. Employees are responsible for complying with all applicable aspects of the standard, especially attending and understanding the training/informing sessions, understanding MSDS’s, and following established instructions and procedures.

Training must be conducted at the time of initial assignment and whenever a new hazard is introduced into the work area. Employees must also be informed and trained according to this standard for all hazardous materials that are currently used. Retraining will be conducted periodically.

The depth of training provided will depend on the employee’s potential for exposure. Employees will be divided into at least two groups by Industrial Hygiene personnel; those employees that only need to know the basics of the standard, such as office workers, and those employees who actually work with hazardous materials. Training for the first group will consist of the employee reviewing a booklet describing the Hazard Communication Standard, attending a short training session which includes providing the employee with contacts of where to go for additional information, and signing an attendance form. Training for’ the second group will consist of the information described for Group One plus training by Industrial Hygiene on the topics listed and described in Appendix VIII. The additional training provided by Industrial Hygiene will be classroom training using slide/tape presentations or other audiovisual presentations. After this training, Group Two

12 - 17 employees will be further divided into smaller groups and train'ed in%% specific topics of hazardous materials which they use (See Appendix IX). An attendance form or a quiz will be given in order to serve as documentation of this training. Supervision is also required to train employees on certain topics. The hazards associated with materials contained in pipes in a work area, for example, must be explained to workers in that area by supervision. The form, found in Appendix X, will serve as a guide for supervisors to follow in conducting this training for all employees and will also serve as documentation of the training. This form will be explained and distributed to supervision at a later date.

This program has been written to ensure that the FMPC is in compliance with the Hazard Communication Standard. Any questions regarding the program should be addressed to Industrial Hygiene of the Environment, Safety, and Health Department, telephone number - 6816.

C' 18 APPENDIX I

Occupational Safety and Health Administration’s Hazard Communication Standard, 29 CFR 1910.1200

14 - 19 STANDARDS AND ISTERPR 529;s

191 0.1200-HAZARD COMMUNICATION

(4pw-. (2) This section applies to any chemical which is known to be present in the workplace in (\)The purpose of this section is to ensure such a manner that employees may be exposed that the hazards of all chemicals produced or under normal conditions of use or in a foresee- imported by chemical manufacturers or im- able,emergency . porters are evaluated. and that infomation concerning their hazards is transmitted to af- (3) This section applies to laboratories only as. fected employers and employees within the follows: manufacturing sector. This transmittal of information is to be accomplished by means of (i) Employers shall ensure that labels on in- comprehensive hazard communication pro- coming containers of hazardous chemicals grams, which are to include container labeling are not removed or defaced; and other forms of warning, material safety data sheets and employee training. (ii) Employers shall maintain any material safety data sheets that are received with in- (2) This occupational safety and health stand- coming shipments of hazardous chemicals, ard is intended to adress comprehensively the and ensure that they are readily accessible issue of evaluating and communicating chemi- to laboratory employees; and, cal hazards to employees in the manufacturing sector. and to preempt any state law per- (iii) Employers shall ensure that laboratory taining to this subject. Any state which de- employees are apprised of the hazaqis of the sires to assume responsibility in thia area may chemicals in their workplaces in accordance only do so under the provisions of 9 18 of the with paragraph (h) of this section. Occupational Safety and Health Act (29 U.S.C. 661 et. seq.) which deab with state ju- (4) This section does not require labeling of the risdiction and state plans. following chemicals:

(b) Sapo and application. (i) Any pesticide as such term is defined in the Federal Insecticide, Fungicide. and . (1) This section requires chemical manufactur- Rodenticide Act (7 U.S.C. 136 et seq.). ers or importers to assess the hazards of when subject to the labeling requirements of chemicals which they produce or impoR, and *that Act and labeling regulations issued un- all employers in SIC Codes 20 through 39 (Di- der that Act by the Environmental Protec- vision D. Standard Industrial Classification tion Agency; Manual) to provide information to their employees about the hazardous chemicals to (ii) Any food, food additive, color additive. which they are exposed, by means of a hszard drug, or cosmetic, including materials in- communication program, labels and other tended for use aa ingredients in such prod- forms of warning, material safety data sheets, ucts (e.g., flavors and fragrances), as such and information and training. In addition, this terms are defined in the Federal Food. section requires distributors to transmit the Drug, and Cosmetic Act (21 U.S.C. 301 et required information to employers in SIC seq.) and regulations issued under that Act. Codes 20-39. when they are subject to the labeling re- a 15 - 20 quirements of that Act and labeling regula- (iii) which does not release. or othedke re- tions issued under that Act by the Food and sult in exposure to, a hazardous chemical Drug Administration; under normal conditions of use.

(iii) Any distilled spirits (beverage alcohols), “Assistant Secretary” means the Assistant wine. or malt beverage intended for nonin- Secretary of Labor for Occupational Safety dustrial use. as such terms are defined in and Health, U.S. Department of Labor. or the Federal Alcohol Administration Act (27 designee. U.S.C.201 et seq.) and regulations issued under that Act, when subject to the labeling “Chemical” means any element. chemical requirements of that Act and labeling regu- compound or mixture of elements andlor lations issued under that Act by the Bureau compounds. of Alcohol, Tobacco, and Firearms; and, “Chemical manufacturer“ means an employ- (iv) Any consumer product or hazardous sub- er in SIC Codes 20 through 39 with a work- stance as those terms are defined in the place where chemical(s) are produced for use Consumer Product Safety Act (15 U.S.C. or distribution. 2051 et seq.) and Federal Hazardous Sub- stances Act (15 U.S.C. 1261 et seq.) respec- “Chemical name” means the scientific desig- tively, when subject to a consumer product nation of a chemical in accordance with the no- safety standard or labeling requirement of menclature system developed by the Interna- those acts, or regulations issued under those tional Union of Pure and Applied Chemistry Acts by the Consumer Product Safety (IUPAC) or the Chemical Abstracts Service Commission. (CAS) rules of nomenclature. or a name which will cleariy identify the chemical for the pur- (5) This section does not apply to: pose of conducting a hazard evaluation.

(i) Any hazardous waste as such term is de- “Combustible liquid” means any liquid hav- fined by the Solid Waste Disposal Act, as ing a flashpoint at or above 1WF (37.800, but amended by the Resource Conservation and below 200°F (93.3’C), except any mixture hav- Recovery Act of 1976, as amended (42 ing components with flashpoints of 200°F U.S.C.6901 et seq.), when subject to regu- (93.3“C), or higher, the total volume of which lations issued under that Act by the Envi- make up 99 percent or more of the total ronmental Protection Agency; volume of the mixture.

(ii)Tobacco or tobacco products: “Common name” means any designation or identification such as code name, code num- (iii) Wood or wood products; ber, trade name, brand name or generic name used to identify a chemical other than by its (iv) Akicles; and, chemical name.

(v) Foods, drugs, or cosmetics intended for “Compressed gas” means: personal consumption by employees while in the workplace. (i) A gas or mixture of gases having, in a container, an absolute pressure exceeding (c) Dofinitiorrr. 40 psi at 7WF (21.1”C); or

“Article” means a manufactured item: (ii) A gas or mixture of gases having, in a container, an absolute pressure exceeding (i) Which is formed to a speciAc shape or de- 104 psi at 13VF (54.4”C) regardless of the sign during manufacture; pressure at 7VF (21. 1°C); or

(ii) which has end use function(s) dependent (iii) A liquid having a vapor pressure ex- in whole or in part upon its shape or design ceeding 40 psi at IWF (37.800 as deter- during end use; and mined by ASTM D-323-72.

Islo.l2aMe, 806.16 Change 34

16 21 dT AS D A R Dd AS D IS T E R P R ET .\T It IS:

"Container" means any bag, barrel, bottle. "Flammable" means a chemical that falls intn box. can, cylinder. drum. reaction vessel. one .of the following categories: storage tank. or the like that contains a hat- ardous chemical. For purposes of this section. (i) "Aerosol. flammable" means an ierosu pipes or piping systems are not considered to that. when tested by the method describer be containers. in 16 CFR 1500.45. yields a flame projectior exceeding 18 inches at full valve opening. 01 "Designated representative" means any indi- a flashback (a flame extending back to thf vidual or organization to whom an employee valve) at any degree of valve opening: gives written authorization to exercise such employee's rights under this section. A recog- (ii) "Gw, flammable" means: nized or certified collective bargaining agent shall be treated automatically as a designated (e) A gas that. at ambient temperature representative without regard to written em- and pressure, forms a flammable mixture ployee authorization. with air at a concentration of thirteen (13; precent by volume or less; or "Director" means the Director. National In- stitute for Occupational Safety and Health. (b) A gas that, at ambient temperature U.S. Department of Health and Human.Serv- and pressure, foms a range of flammable ices, or designee. mixtures with air wider than twelve (12) percent of volume. regardless of the lower "Distributor" means a business. other than a limit: chemical manufacturer or importer, which supplies hazardous chemicals to other distrib- (iii)"Liquid. flammable" means any liquid utors or to manufacturing purchasers. having a flashpoint below 100°F (37.8"C). except any mixture having components with "Employee" means a worker employed by an flashpoints of 1WF (37.8'C) or higher. the employer in a workplace in SIC Codes 20 total of which make up 99 percent or more ol through 39 who may be exposed to hazardous the total volume of the mixture. chemicals under normal operating conditions or foreseeable emergencies. including, but not (iv) "Solid; flammable" means a solid. other limited to production workers, line supervi- than a blasting agent or explosive as defined sors. and repair or maintenance personnel. Of- in 4 1910.109(a). that is liable to cause tire fice workers, ground maintenance personnel. through friction, absorption of moisture. security personnel or non-resident manage- spontaneous chemical change, or retained ment are generally not included, unless their heat from manufacturing or processing. or job performance routinely involves potential which can be ignited readily and when ig- exposure to hazardous chemcials. nited burns so vigoroudy and persistently as to create a serious hazard. A chemical "Employer" means a person engaged in a shall be considered to be a flammable solid business within SIC Codes 20 through 39 if, when tested by the method described in where chemicals are either used, or are pro- 16 CFR 1500.44, it ignites and bums with a duced for use or distribution. self-sustained flame at a rate greater than one-tenth of an inch per second along its ma- "Explosive" means a chemical that causes a jor axis. sudden, almost instantaneous release of pressure, p,and heat when subjected to sudden " Flashpoint" means the minimum tempera- shock, ,pressure. or high temperature. tun at which a liquid gives off a vapor in sufficient concentration to ignite when tested as "Exposure" or "exposed" means that an em- follows: ployee is subjected to a hazardous chemical in the cburse of employment through any route (i) Tagliabue Closed Tester (See American of entry (inhalation. ingeston. skin contact or National Standard Method of Test for Flash absorption, etc.). and includes potential (e.&, Point by Tag Closed Tester, 211.24-1979 accidental or possible) exposure. (ASTM D 56-79)) for liquids with a viscosity

C han gr :U 806.1 7 1910.12~~:

17 22 of less than 45 Saybolt Universial Seconds to determine whether or not a chemical is to (SUS)at 100°F (37.8”C).that do not contain be considered hazardous for purposes of this zuspendetl solids and do not have a tendency standard. to fnrm ii zurface film under test; or “Identity” means any chemical or common (ii) Pensky-Martens Closed Tester (see name which is indicated on the material safety American National Standard Method of test data sheet (MSDS) for the chemical. The iden- for Flash Point by Pensky-Martens Closed tity used shall permit cross-references to be Tester. 211.7-1979 (ASTM D 93-79)) for made among the required list of hazardous liquids with a viscosity equal to or greater chemicals. the label and the MSDS. than 45 SUS at 100°F (37.8OC). or that contain =uspentled solids, or that have a tend- ”Immediate use” means that the hazardous ency to form il surface film under test; or chemical will be under the control of and used only by the person who transfers it from a la- (iii) Setanash Closed Tester (see American beled container and only within the work shin National Standard Method of Test for Fluh in which it iy transferred. Point by Setanash Closed Tester (ASTM D 3278-78) ). “Importer“ means the first business with employees within the Customs Territory of Organic perosides. which undergo autoaccel- the United States which receives hazardous erating thermal decomposition, are excluded chemicals produced in other countries for the from any of the flashpoint determination purpose of supplying them to distributors or niethotlz specified above. manufacturing purchasers within the United States. “Foreseeable emergency” means any potential occurrence such as, but not limited to. “Label” means any written, printed. or equipment failure, rupture of containers. or graphic material displayed on or mxed to failure of control equipment which could result containers of hazardous chemicals. in an uncontrolled release of a hazardous chrmical into the workplace. “Manufacturing purchaser‘’ means an employer with a-workplace classified in SIC .*Hazard warning* means any words, pic- Codes 20 through 39 who purchases a hazard- ‘tures. symbols. or combination thereof ap- oua chemical for use within that workplace. paring on a label or other appropriate form of warning which convey the hazards of the “Material safety data sheet (MSDSY’ means chemical(s) in the container($). written or printed material concerning a hazardous chemical which is prepared in accord- ”Hazardous chemical” means any chemical ance with paragraph (g) of this section. which is aphysical hazard or a health hazard. “Kixture” means any combination of two or “Health hazard” means a chemical for which more chemicals if the combination is not. in there is statistically significant evidence based whole or in part, the result of a chemical on at least one study conducted in accordance reaction. with established scientific principles that acute or chronic health effects may occur in exposed employees. The tern ”health hotord” “Organic peroxide” meam an organic com- iticlutles chemicals which are carcinogens. tox- pound that contains the bivalent-0-0- ic or highly toxic agents. reproductive toxins. StNCtUre and which may be consided to be a irritants. corrosives. sensitizers, hepato- structural derivative of hydrogen peroxide toxins. nephrotoxins, neurotoxins. agents where one or both of the hydrogen atom has which act on hematopoietic system, and been replaced by an organic radical. agents which damage the lungs, skin, eyes, or mucous membranes. Appendix A provides hu- “Oxidizer” meinn a chemical other than a ther definitions and explanations of the scope blasting agent or explosive as defined in $ of health hazards covered by this section, and 1910.109(a), that initiates or promotes com- Appendix B describes the criteria to be used bustion in other materids thereby causing fue

I9Io.lzo(wc) 806.1 8 Change 34

23 (11 -cc PAT lo S A I. SAFETY A s n HE A LT H 1910.1200(c~

STANDARDS AND INTERPRETAT105 26

either of itself or through the release of “Workplace” means an establishment at one oxygen or other gases. geographical location containing one or more work areas. “Physical hazard” means a chemical for which there is scientifically valid evidence that (d) Hazard &tomination. it is a combustible liquid. a compressed gas, explosive. flammable. an organic peroxide, an (1) Chemical manufacturers and importers oxidizer. pyrophoric, unstable (reactive) or shall evaluate chemicals produced in their water-reactive. workplaces or imported.by them to determine if they are hazardous. Employers are not re- “Produce” meand :o manufacture, process, quired to evaluate chemicals unless they formulate, or repackage. choose not to rely on the evaluation performed by the chemical manufacturer or importer for “F‘yrophoric” means a chemical that will ig- the chemical to satisfy this requirement. nite spontaneously in air at a temperature of 130” F (54.4” or below. (2) Chemical manufacturers, importers or em- C) ployers evaluating chemicals shall identify and consider the availabile ecientillc evidence con- “Responsible party” means someone who can cerning such hazard& For health hazards, evi- provide additional information on the hazard- dence which is statistically significant and ous chemical and appropriate emergency pro- which ie bdon at leest one positive study cedures, if necessary. conducted in accordance with established sei- entide principlea is considered to be sufficient “Specific chemical identity” mew the chem- to eatabliah a hazardous effect if the results of ical name, Chemical Abstracts Service (CAS) the study meet the dednitions of health haz- Registry Number, or any other information arde in this section. Appendix A shall be that reveals the precise chemical designation consulted for the ecope of health hazruds cov- of the substance. ered, and Appendix B shall be consulted for the criteria to be followed with respect to the “Trade secret” means any confidential for- completeness of the evaluation, and the data mula, pattern, process, device, information or to be reported. compilaation of information that is used in an employer’s business, and that gives the em- @)The che&al manufacturer, importer or ployer an opportunity to obtain an advantage employer evaluating chemicals shall treat the over competitors who do not know or use it. following sources as establishing that the Appendix D seta out the criteria to be used in chemicale listed in them hazardous: evaluating trade secrets. are (i) CFR Part 1910, Subpart 2, Toxic and “Unstable (reactive)” means a chemical Hslcardoua Substancee, Occupational Safety which in the pure state, or as produced or and Health Adminiatration (OSHA); or, transported, will vigorouely polymerize, decompose, condense, or will become self- (ii) Threehold Limit Values for Chemical reactive under conditions of shocb preesure Subetancse and Phyeical Agente in the or temperature. Work Enwinmmsnt, American Conference of Governmental Industrial Hygienists “Use” means to package, handle, react, or (ACCIH) (lateat edition). transfer. The chemical manufacturer, importer, or “Water-reactive” means a chemical that re- employer ia still responsible for evaluating acta with water to release a gas that is either the hazards aeeociated with the chemicals in flammable or presents a health hazard. these somliste in accordance with the re- quiremente of the standard. “Work area” means a room or defined space in a workplace where hazardous chemicals are (4) Chemical manufacturers, importers and produced or used. and where employees are employere evaluating chemicale shall treat the present. following sources es establishing that a chemi-

Change 41 806.19 1#10.13200(d~(0

13 - 24 1910.IZ00(d)(J) 0CCCP.iTIONAL SAFETY A’XD HEAN6

STANDARDS AND INTERPRETATIONS

cal is a carcinogen or potential carcinogen for cent) coulG be released in concentrations hazard communication purposes: which would exceed an established OSHA permissible exposure limit or ACGIH Threshold Limit Value. could present a (i) National Toxicology Program (NTP), An- or . nual Report on Carcinogens (latest edition); health hazard to employees in those concentrations. the mixture shall be assumed to (ii) International Agency for Research on present the same hazard. Cancer (IARC) Monograph8 (latest editions); or (6)Chemical manufacturers, importers, or employers evaluating chemicals shall describe in (iii) 29 CFR Part 1910, Subpa% 2, Toxic and writing the procedures they use to determine Hazardous Substances, Occupational Safety the hazards of the chemical they evaluate. The and Health Administration. written procedures are to be made available, upon request, to employees, their designated Note.-The Registry of Tozie Effect8 of representatives, the Assistant Secretary and Chemical Sub8tcmces published by the Na- the Director. The written description may be tional Institute for Occupational Safety and incorporated into the written hazard commu- Health indicates whether a chemical has nication program required under paragraph been found by NTP or IARC to be a poten- (e) of this section. tial carcinogen. (0)Writton harard communbtion program. (S)The chemical manufacturer, importer or employer shall determine the hazards of mix- (1) Employers shall develop and implement a tures of chemicals as follows: written hazard communication program for their workplaces which at least describes how (I) If a mixture has been tested as a whole to the criteria specified in paragraphs (0,(g). determine its hda,the results of such and (h) of this section for labels and other testing shall be used to determine whether forme of warning, material safety data sheets, the mixture is hazardous; and employee information and training will be met, and which also includes the following: (ii) If a mixture has not been teated as a whole to determine whether the mixture is a (i) A list of the hazardous chemicals known . health hazard. the mixture shall be assumed to be present using an identity that is refer- to present the same health hazards as do the enced on the appropriate material safety components which comprise one percent (by data sheet (the liat may be compiled for the weight or volume) or greater of the mixture, workplace as a whole or for individual work except that the mixture! shall be aeeumed to areas); present a carcinogenic hazard if it contains a component in concentrations of 0.1 percent (ii) The methods the employer will use to in- or greater which is conaidered to be a car- form employees of the hazards of non- cinogen under paragraph (d)(4) of this routine tasks (for example. the cleaning of ‘ section; reactor veseels). and the hazards associated with chemicals contained in unlabeled pipes (iii) If a mixture haa not been tested as a in their work areas; and, whole to determine whether the mixture is a physical hazard, the chemical manufacturer, (iii) The methods the employer will use to in- importer, or employer may use whatever form any contractor employers with employ- scientidcally valid data is available to evalu- ees working in the employer‘s workplace of ate the physical hazard potential of the mix- the hazardous chemicals their employees ture; and may be exposed to while performing their work, and any suggestions for appropriate (iv) If the employer haa evidence to indicate protective measures. that a component present in the mixture in concentrations of less than one percent (or (2) The employer may rely on an existing haz- in the case of carcinogens, less than 0.1 per- ard communication program to comply with

1~10.1300(rWt) 806.20 Change 34 a

20 528 OCCUPATIONAL SAFETY ASD HEALTH 1910. iiom

.STASDARDS AXD ISTE KPRET,\Tlt IS..

these requirements. provided that it meets process sheets. batch tickets. operating proce- the criteria established in this paragraph (e). dures. or other such written materials in lieu of affixing labels to individual stationary proc- (3) The employer shall make the written haz- ess containers. as long as the alternative ard communication program available, upon method identifies the containers to which it is request, to employees. their designated repre- applicable and conveys the information re- sentatives, the Assistant Secretary and the quired by paragraph (O(4) of this section to be Director. in accordance with the requirements on a label. The written materials shall be read- of 29 CFR 1910.2Me). ily accessible to the employees in their work area throughout each work shift. (f) labels and othor forms of warning. (6)The employer is not required to label port- (1) The chemical manufacturer. importer. or able containers into which hazardous cherni- distributor shall ensure that each container of cals are transferred hmlabeled containers. hazardous chemicals leaving the workplace is and which are intended only for the immediate labeled, tagged or marked with the following use of the employee who performs the information: transfer.

(i) Identity of the hazardous chemical(s); (7)The employer shall not remove or deface existing labels on incoming containers of haz- (ii) Appropriate hazard warnings; and ardous chemicals, unless the container is irn- mediately marked with the required (iii)Name and address of the chemical manu- information. facturer, importer, or other responsible Party. ((i)The employer shall ensure that labels or other forms of warning are legible, in English. (2) Chemical manufacturers, importers, or dis- and prominently displayed on the container. or tributors shall ensure that each container of readily available in the work area throughout hazardous chemicals leaving the workplace is each work shift. Employers having employees labeled, tagged, or marked in accordance with who speak otKer languages may add the infor- this section in a manner which does not con- mation in their language to the material pre- flict with the requirements of the Hazardous sented, as long as the information is presented Materials Transportation Act (18 U.S.C. 1801 in English as well. et seq.) and regulations issued under that Act by the Department of Transportation. (9)The chemical manufacturer. importer. distributor or employer need n6t affix new labels (3) If the hazardous chemical is regulated by to comply with this section if existing labels OSHA in-a substancespecific health standard, already convey the required information. the chemical manufacturer, importer, distributor or employer shall ensure that the labels (9) Material safety data sheets. or other forms of warning used are in accordance with the requirements of that standard. (11 Chemical manufacturers and importers shall obtain or develop a material safety data (4) Except as provided in paragraphs (M5) and sheet for each hazardous chemical they pro- (fN6) the employer shall ensure that each con- duce or import. Employers shall have a rnate- tainer of hazardous chemicals in the workplace rial safety data sheet for each hazardous is labeled, tagged. or marked with the follow- chemical which they uw. ing infomation: (2) Each material safety data sheet shall be in (i)Identity of the hazardous chemical(s) con- English and shall contain at least the following tained therein: and information.

(ii) Appropriate hazard warnings. (i)The identity used on the label. and. except as provided for in paragraph (0of this (5) The employer may use signs. placards. section on trade secrets:

Change 34 806.21 1910.1200( gJ( 2 )I i I

21 26 tn) If the himmlous rhrmicitl is a single (NTP) AM~~IIU~Report OII Carcittogens (lat- substance. its chemical and common est edition) or has been found to be a poten- nameb): tial carcinogen in the International Agency for Research on Cancer (IARC) Mono- tb) If thc hazardous chemical is a mix- yrupka (latest editions). or by OSHA; ture which has been tested as a whole to determine its hazards. the chemical and (viii) Any generally applicable precautions common name(s) of the ingredients for safe handling and use which are known which contribute to these known haz- to the chemical manufacturer, importer or ards. and the common name(s) of the employer preparing the material safety data mixture itself; or, sheet, including appropriate hygienic practices, protective measures during repair and (c) If the hazardous chemical is a mix- maintenance of contaminated equipment, ture which has not been tested as a and procedures for clean-up of spills and whole: leaks;

( 1) The chemical and common name(s) of (ix) Any generally applicable control meas- all ingredients which have been deter- ures which are known to the chemical manu- mined to be health hazards, and which facturer. importer or employer preparing comprise 1% or greater of the composi- the material safety data sheet, such as ap tion, escept that chemicals identified as propriate engineering controls, work prac- carcinogens under paragraph (d)(4) of tices, or personal protective equipment; this section shall be listed if the concentrations are 0.1% or greater; and. (I) Emergency and first aid procedures;

(2) The chemical and common name(s) of (xi) The date of preparation of the material all ingredients which have been deter- safety data sheet or the last change to it; mined to present a physical hazard and, when present in the mixture; (xii) The name, address and telephone nun- (ii) Physical and chemical characteristics of ber of the chemical manufarturer, importer, the hazardous chemical (such as vapor pres- employer or other responsible party sure. flash point); preparing or distributing the material safety data sheet, who can provide additional infor- (iii) The physical hazards of the hazardous mation on the hazardous chemical and ap chemical. including the potential for fire, ex- propriate emergency procedures, if plosion. and reactivity; necessary.

(iv) The health hazards of the hazardous (1)If no relevant information is found for any chemical. including signs and symptoms of given. category on the material safety data espsure. and any medical conditions which sheet, the chemical manufacturer, importer or arc generally recognized as being aggra- employer preparing the material safety data vated by exposure to the chemical; sheet shall mark it to indicate that no applicable information was found. (4The primary route(s) of entry; (4) Where complex mixtures have similar haz- (vi) The OSHA permissible exposure limit, ards and contents (i.e. the chemical ingredi- ACCIH Threshold Limit Value, and any ents are essentially the same, but the specific other exposure limit uaed or recommended composition varies from mixture to mixture), by the chemical manufacturer, importer, or the chemical manufacturer, importer or em- employer preparing the material safety data ployer may prepare one material safety data sheet. where available; sheet to apply to all of these similar mixtures.

(vii) Whether the hazardous chemical is (5) The chemical manufacturer, importer or listed in the National Toxicology Program employer preparing the material safety data

1910. IzuuIglls) 006.22 Change 34

27 STANDARDS ASD ISTERPRETATION:

sheet shall ensure that the information re- (10) Material safety data sheets shall also k corded accurately reflects the scientific evi- made readily available, upon request, to des dence used in making the hazard determina- ignated representatives and to the Assistanl tion, If the chemical manufacturer, importer Secretary, in accordance with the require- or employer becomes newly aware of any sig- ments of 29 CFR 1910.20(e). The Director nificant information regarding the hazards of a shall also be given access to material safet) chemical. or ways to protect against the haz- data sheets in the same manner. ards, this new information shall be added to the material safety data sheet within three (h) Imployn information and training. Employ months. If the chemical is not currently being ers shall provide employees with information produced or imported the chemical manufac- and training on hazardous chemicals in theh turer or importer shall add the information to work area at the time of their initial assignment, the material safety data sheet before the and whenever a new hazard is introduced intc chemical is introduced into the workplace their work area. again.

(6)Chemical manufacturers or importers shall (1) ~nhrmotion. Employees shall be informed ensure that distributors and manufacturing OE purchasers of hazardous chemicals are provided an appropriate material safety data sheet (i) The requirements of this section; with their initial shipment, and with the Arst shipment after a material safety data sheet is (ii) Any operations in their work area where updated. The chemical manufacturer or im- hwouschemicals are present; and, porter shall either provide material safety data sheets with the shipped containers or (iii) The location and availability of the writ- send them to the manufacturing purchaser ten hazard communication program, includ- prior to or at the time of the shipment. If the ing the required list(s) of hazardous chemi- material safety data sheet is not provided with cals, and material safety data sheets the shipment, the manufacturing purchaser required by this section. shall obtain one hmthe chemical manufacturer, importer, or distributor as soon as (2) ?mining. Employee training shall include at possible. least: .

(7) Distributors shall ensure that material safe- (i)Methods and observations that may be ty data sheets. and updated information, are used to detect the presence or release of a provided to other distributors and manufac- hazardous chemical in the work area (such as turing purchasers of hazardous chemicals. monitoring conducted by the employer, continuous monitoring devices, visual appear- (,)The employer shall maintain copies of the ance or odor of hazardous chemicals when required material safety data sheets for each being releaaed, etc.); hazardous chemical in the workplace, and shall ensure that they are readily accessible during (ii)The physical and health hazards of the each work shift to employees when they are in chemicals in the work area; their work area(s). (iii) The measures employees can take to pro- (9)Material safety data sheets may be kept in tect themselves from these hazards, includ- any form, including operating procedures, and ing specific procedures the employer hae im- may be designed to cover pupsof hazardous plemented to protect employees from chemicals in a work area where it may be more exposure to hazardous chemicals. such aa ag appropriate to address the hazards of a process propriate work practices, emergency proce- rather than individual hazardous chemicals. dures, and personal protective equipment to However, the employer shall ensure that in all be used; and, cases the required information is provided for each hazardous chemical, and is readily acces- (ir) The details of the hazard communication sible during each work shift to employees program developed by the employer, includ- when they are in their work area(s). ing an explanation of the labeling system and

Change 34 806.23 1~10.1208(hHtMli)

23 28 I'~CCL'PA1'IONAL SAFETY AND32L& STAXDARDS AND ISWItPHETATIOSJ

the material safety data sheet. aid how em- (i) the req'iest is in writing; ployecs can obtain and use the appropriate hazard information. (ii) The request describes with reasonabll detail one or more of the following occupa (i)fmdo -rots. tional health needs for the information:

(1) The chemical manufacturer. importer or (a) To assess the hazards of the chemi employer may withhold the specific chemical cals to which employees will be exposed identity. including the chemical name and other specific identification of a hazardous (b) To conduct or assess sampling of thc chemical, from thP material safety data sheet, workplace atmosphere to determine em provided that: ployee exposure levels;

(i) The claim that the infomation withheld is (e) To conduct pre-assignment or period a trade secret can be supported; ic medical surveillance of exposec employees: (ii) Information contained in the material safety data sheet concerning the properties (d) To provide medical treatment to ex and effects of the hazardous chemical is posed employees; disclosed; (e) To select or assess appropriate per (iii) The material safety data sheet indicates sonal protective equipment for exposec that the specific chemical identity is being employees; withheld as a trade secret; and, (iv) The specific chemical identity is made (D To design or assess engineering con available to health professionals, employees, trols or other protective measures lo and designated representatives. in accordance exposed employees; and, with the applicable provisions of this paragraph. (I() To conduct studies to determine thc I health effects of exposure. (2) Where 3 treating physician or nurse determines that a medical emergency exists and the specific chemical identity of a hazardous chem- (iii) The request explains in detail why thc ical is necessary for emergency or first-aid disclosure of the specific chemical identity it treatment, the chemical manufacturer, im- essential and that. in lieu thereof, the disclo porter. or employer shall immediately disclose sure of the following information to the healtt the specific chemical identity of a trade secret professional, employee, or designated repre chemical to that treating physician or nurse, sentative. would not satisfy the purposes de regardless of the existence of a written state- scribed in paragraph (i)(3)(ii) of this section: ment of need or a confidentiality agreement. The chemical manufacturer. importer. or em- (8) The properties and effects of thc ployer may require a written statement of chemical; need and confidentiality agreement, in accod- anee with the provisions of paragraphs (i) (3) (b) Measures for controlling workers' ex and (4) of this section, as soon as circum- posure to the chemical; stances permit. (3) In non-emergency situations. a chemical (e) Methods of monitoring and analyzinl manufacturer. importer. or employer shall, upon worker exposure to the chemical; and, request. disclose a' specific chemical identity, otherwise permitted to be withheld under para- (d) Methods of diagnosing and treatin} gnph (i)(l) of this section, to a health profes- harmful exposures to the chemical; sional (Le. physician, industrial hygienist. toxi- cologist, epidemiologist). providing medical or other occupatiunal health services to exposed (iv) The request includes a description of tb employee(s). and to employees or designated procedures to be used to maintain the cond representatives. if: dentiality of the disclosed information; and,

24 29 526 OCCCPhTIOXAL SAFETY ASD HE.\LTH 1910. !Zoo( i 11 3 11 iv I

3ThSDARDS ASD INTERPRETATIOSS

(v) The health prrrfecsional. and the employer (iv) State the specific reasons why the re- or contractor of the services of the health pro- quest is being denied; and, fessional ii.e. tlo\cnctream employer. labor organization. or iiitliridual employee). employee. (v) Explain in detail how alternative infor- or designated reprpsentative. agree in a wit- mation may satisfy the specific medical or ten confidentiality agreement that the health occupational health need without revealing professional. employee, or designated repre- the specific chemical identity, sentative. will not use the trade secret information for any purpose other than the health (8)The health professional. employee. or desig- need(s) asserted and aqee not to release the nated representative. whose request for infor- information under any circumstances other mation is denied under paragraph tiK3) of this than to OSHA. as provided in paragraph liN6) section may refer the request and the written of this section. except as authorized by the denial of the request to OSHA for consideration. terms of the agreement or by the chemical manufacturer. importer. or employer. (9)When a health professional. employee. or (4) The confidentiality agreement authorized designated representative refers the denial to by paragraph (iN3Niv) of this section: OSHA under paragraph (iM8) of this section. OSHA shall consider the evidence to determine (i) May restrict the use of the information to if the health purposes indicated in the written statement of need; (i) The chemical manufacturer. importer. or employer has supported the claim that the (ii) May provide for appropriate legal reme- specific chemical identity is a trade secret; dies in the event of a breach of the agreement, including stipulation of a reasonable (ii) The health professional, employee. or des- pre-estimate of likely damages; and, ignated representative. has supported the (iii) May not include requirements for the claim that there is a medical or occupational . posting of a penalty bond. health need for the information: 'and (5) Nothing in this standard is meant to pre- (iii) The health professional, employee, or des- clude the parties from pursuing non- ignated representative. has demonstrated ad- contractual remedies to the extent permitted equate means to protect the confidentiality. by law. (6)If the health professional. employee. or des- (10) ignated representative receiving the trade secret information decides that there is a need to (i) If OSHA determines that the specific disclose it to OSHA. the chemical manufacturer, chemical identity requested under paragraph importer, or employer who provided the infor- (i)(3)of this section is not a bonafide trade se- mation shall be informed by the health profes- cret. or that it is a trade secret. but the re- sional. employee. or designated representative questing health professional. employee. or prior to, or at the same time as. such disclosure. designated representative has a legitimate medical or occupational health need for the in- . (7)If the chemical manufacturer, importer, or formation. has executed a written employer denies a written request for disclo- confidentiality agreement, and has shown ade-, sure of a specific chemical identity, the denial quate means to protect the confidentiality of must: the information. the chemical manufacturer. importer. or employer will be subject to cita- (i) Be provided to the health professional. em- tion by OSHA. ployee. or designated representative. within thirty days of the request: (ii) If a chemical manufacturer, importer, or (ii) Be in writing; employer demonstrates to OSHA that the (iii) Include evidence to support the claim execution of a confidentiality agreement that the specific chemical identity is a trade would not provide sufficient protection secret; against the potential harm from the unau-

25 30 526 OCCUPATIONAL SAFETY AND HEALTI

STANDARDS AND INTERPRETATIONS

thorized disclosure of a trade secret specific cluding initial training for all curren chemical identity, the Assistant Secretary employees. may issue such orders or impose such additional limitations or conditions upon the disclosure of the requested chemical information as may be appropriate to assure that ACWNDIX A TO 5 1910.1200-HIALTH the occupational health services are provid- HAZARD DWlNlTlONS (MANDATORY) ed without an undue risk of harm to the chemical manufacturer, importer, or employer. Although safety hazards related to the physical churcteri tics of a chemical can be objectively dehed in terns t testing requirements (e.g. flammability). health hazard del (II) If, following the issuance of a citation and nitions M less precise and more subjective. Health huvd any protective orders, the chemical rnanufac- may cause meMurable changes in the body-ouch M di turer, importer, or employer continues to credpulmonary function. ”hew changes are genedy it died by the occurrence of signa and symptoms in the eJ withhold the information, the matter is refer- posed employees-such as shortness of breath, rable to the Occupational Safety and Health non-meuunble. subjective feeling. Employees expo& t Review Commission for enforcement of the ci- such hazards must be appW of both the change in bod tation. In accordance with Commission rules, function and the signa and symptoms that nuy occur to sit the Administrative Law Judge may review the nal that change. citation and supporting documentation in cam- The determination of oeeupational health hazards is eon cm or iaeue appropriate protective orders. plied by the fact that many of the eff- or signa an symptom, occur commonly in nonorrupvionally ex- (11) Notwithstanding the existence of a trade pop~latio~,no that effcets of expure M dMeult to wp rate frotom normally occurring illneclwi. Oeersionally. a SUI secret claim, a chemical manufacturer, import- stance causes an effect that is ruely soen in the populath er, or employer shall, upon request, disclose at large, such M angiosucomaa ea& by vinyl chloride e: to the Assistant Secretary any information posure. thus making it emier to rscertain that the occup which this section requires the chemical manu- tional expure WM the primary causative feetor. More o facturer, importer, or employer to make avail- ten. however, the effect8 are common. such M lung canee The situation is further complicated by the fact that ma able. Where there is a trade secret claim, such chemic& have not been adequately tested to dctermit claim shall be made no later than at the time their health hrurd potential. and data do not exist to SUI the information is provided to the Assistant stantiatn theweffccts. Secretary so that suitable determinations of trade secret statue can be made and the neces- Them have been many attempts to categorize eff- a~ to define them in various ways. Generally. the tern sary protections can be implemented. “acute” and “chronic“ are used to delineate between effsc (13) Nothing in this paragraph shall be con- on the %is of severity or duration. “Acute” effcets usual oceur rapidly M a result of short-tern expures. and M strued aa requiring the disclosure under any short duration. “Chronic” effects generrlly occur M a resu circumstancee of procesa or percentage of mix- of long-term exporure, and are of long duration. ture information which is trade secret. The acute effects referred to moat frequently are th defined by the American National Standards Institul (1) Woeivo dotn. Employers shall be in compli- (ANSI) standard for Reeautionary Labeling of Hazard01 ance with thh section within the following time Industrial Chemic& (2129. I-lW)--imtation. comivit periods: sensitization and lethal done. Although these are imp0rt.l health effects. they do not adequately cover the consider ble range of acute eZects which may occur a8 a result of o (1) Chemical manufacturers and importers cupationd expure. such M. for example. nucoais. shall label containem of hazardous chemicals leaving their workplaces, and provide material Similarly. the term chronic effect is often used to COV, eafety data sheets with initial shipment8 by only carcinogenicity. tentogenicity, and mutagenicit November 26,1986. Thew effects are obvious P concern in the workplace. b again. do not adequately cover the area of chronic effect excluding, for example, blood dy8crMiM (such M anemii (1)Dttributom ahall be in compliance with all chronie bronchitis and liver atrophy. provisions of thin section applicable to them by November 26, 1986. The god of defining precisely. in meanurable terms. eve possible health effect that may occur in the workplace M result of chemical exporures cannot redistically be ~ceo!

(3) Employera shall be in compliance with all plished. This does not negate the need for employees to I provisions of this section by May 25, 1986, in- informed of such effects and protected from them.

1#10.1200 APPENDIX A 806.26 Chanae i

26 3.f .ST:\S D.4 R 0s AS D I STE I? PR ET?. T I I IT:

Appendix B. which 1.- alsa8 mandatnry. .nutliner the princi. 1. Irrilanl: .A chemical, which is not rnrrosive. nut uhicl plr. and procedures of hazard rszes.Gment. cause> a reversible inflammatory effect nn living II~~UQb! chemical action at the site of contact. A chrmical is a .skin ir For purpozej of !his .-ectinn. any chemic& whirh mcct ritint if. when tested nn the intact .-kin of albinn rdbhit> h! any of the followinr definitions. 1s drtermined bx :he crite- the mehtods ni 16 CFR 1500.41 for four hour: expo>ure 01 ria :et funh in Appendix 9 are health haurds: by other appropriate techniques. it result.< in an rmpirira score of five or more. A chemical IS an eye irritant if >o de 1. Carcinoaen: A chemical is considrred to be a carcino- termined under the procedure listed in I6 CFR ljo1).42 nl

2. Corrosive: A chemical that causes v (a1 A chemical that ha a median lethal dose ILD,.) n of. or irreversible alterations in. living ti mnre than 50 millimams per kilogram but not more than .ioc action at the site of contact. For example. a chemiral i.. coil. milligrnms per kilogram of body weight when administeref sided to be corrosive if. when testrci on the intart ..kin of nrally tn albinn rdts weighing between 200 snd :to0 crm. albino rabbits by the methnd described hy 132 U.6. D-part- rach. ment of Transponation in Appendix A to 4Y CFR Part 173. it drstmyr or changes irreversibly the itruriure of the tir- lh) h chemiral that has a median lethal ~III.-CiI.D,,,) 18 sue at the site of rontact following an e'cptrurr priocl of more than 200 milligrams per kilogram but not more thar four hours. This term .hall not refer to artion nn inanimate 1.ooO milligrams per kilogrvm of body weight when adminis. surface.. tered by continuous contact for 24 hours (or le*.. if dwth oc. run within 24 hours) with the bare skin of albinn rahbit: 3. Hiihly toxic: A chemical falling within any of the fol- weighing betwern two and three kilngrams rrch. Inwing categorip-:

la) A chemical that has a median lethal dose tl.D,.) nf 50 IC) A chemical that has a median lethal roncentratior milligrsms or less per kiloyrum of body weight when admin. (LC,.) in air of more than 200 parts per million but not morf istered orally to dihiirn rats weighing between 200 and ROO than 2.000 parts per million by volume of pa8 or vapor. 01 grams euch. more than two milligrams per liter but not more than 20 mil. ligrams per litei of mist. fume. or dust. when administered lb) A chemical that has a meftiun lethal dow (LD,.) of 900 by continuous inhalation for one hour (or lest if death occurs miligrams or le+, per kilogram of body *.eight when admin- within one hour) to rlbino rats weighing between 200 and istered by continuous contact for 24 hours (or leu if derth 300 gmseuch. wcun within 24 hours) with the bare skin of albino rabbits weighing between tu0 and three kilograms each. 7. Target organ efYcctr. The following is a target organ categorization of eflceta which may occur. including exam- IC) A chemical that has a median lethal'concentration ples of signs and symptoms and chemicals which have been (LC,.) in air of 200 parts per million by volume or less of gas bund to cause such effects. These examples are presented or vapor. or 2 milligrams per liter or leju of mist. fume. or to illustrate the range and diversity of effects and hazards dut. wheh administered by continuous inhallation for one found in the workplace. and the broad scope employers must hour (or leis if death oecun within nne hour) to alhino rats consider .in this area. but are not intended to be weighing between 200 and 800 grums rrch. all-inclusive. a. Hepatotoxins ...... Chemicals which produce liver damage. Signs and Symptoms: ...... Jaundice: iiver enlargement. Chemic& ...... Carbon tetrachloride: nitrosamines. b. Nephmtoxins: ...... Chemicals which produce kidney damage. Signs and Symptomx ...... Edema; proteinuria. Chernicala: ...... Halogenated hydrocarbons: uranium. c. Neurotoxins: ...... Chemicah which produce their primary toxic effects on the nervous sys- tern. Signs and Symptoms: ...... Sarcosis: behavimal changes: decreade in motor functions. Chemicals:...... Mercurv: rarbon disulfide. d. Agents which act on the bldof hematopoietic system: ...... Decrease- hemoglobin function: deprive the body tissues of oxygen. Sims and Symptomd: ...... Cyanosis: loss of consciournew. Chemicals:...... (.arbon monoxide: cyanides. e. Agents which damage the lung: ...... ('hemirals which irritate or tlarnage the pulmonary tissue.

Change 34 806.27 1910.1200 APPESDlX A

27 32 526

ST AS U.\ R Db AS D I S T E R P R ET AT It 1 S 5

Sign.' and symptom^...... Cnuuh: tightness in chest: ..hwtness of breath. ('hemicals: ...... Silica; asbestos. 1. Reproductive toxin..: ...... Chemicals which affect the reproductive capabilities including chromosn- mal damage tmutation*l and effects on fetuses (feratogenesisl. Sips mil Symptom.<: ...... Birth defects; sterility. Chemical.<:...... Lead: DBCP. y. Cutaneous hazard?;: ...... Chemical which affect the dermal layer of the body. Sign> And Symptoms: ...... Defatting of the skin; rashes: irritation. Chemicala: ...... Ketones; chlorinated compounds. h. Eye hazards: ...... Chemicals which affect the eye or visual capacity. Sign> and Symptoms: ...... Conjunctivitis: corneal damage. Chemicals:...... Organic >olvents: acids.

chemical manuficturer. importer. or employer may also report the results nf other scientifically valid studies which APPENDIX B TO $ 191 0.120O-blAURD tend to refute the findings of harnnl. DtTERMINATION (MANDATORY)

The quality of a hazard communication program is largely APPINDIX C TO $ 1910.1200-INK)RMATlON dependent upon the adequacy and accuracy of the hazard de- SOURCIS (ADVISORY) termination. The hazard determination requirement of this standard is perfonnancr-oriented. Chemical manufacturers. Importers. and employers evaluating chemicals are not required to follow any specific mehtods for determining hazards, but they must be able to demonmate that they have The following is a list of available data sources which the adequately aacertained the hazards of the chemicals pro- chemical manufacturer. importer. or employer may wish to duced or imported in accordance with the criteria set fonh eondult to evaluate the hnurdr of chemicals they produce or in this Appendix. import:

Hazard evaluation is a process which relies heavily on the - Any information in their own company files such as professional judgment of the evaluator, particularly in the toxicity testing results or illnesl experience of company area uf chronic hazards. The performance-orientation of the employees. hazard determination doer diminish the duty of the chemical manufacturer. importer or employer to conduct a thorough - Any information obtained from the supplier of the rv;iluatiim. rumininp all relevant data and producing a sei. chemical. Juch aa material safety data sheets or product rntificnlly defensible evaluation. For purposes of this stand- safety bulletin;. ard. the following critcria shall be used in making horvd dc terminations that meet the requirements of thh standard. - Any pertinent information obtained from the following source list (latest editions should be used): I. Careinorenieity: As described in paragraph (dH4) and Appendix A of this section. a determination by the National condenred Chemical Dlrtbruq Toxicology Program. the International Agency for Research Van Nostrand Reinhold Co.. 135 West SOch Street. New on Cancer. or OSHA that a chemical is a carcinogen or PO- York. YY loosd tenth1 carcinogen will be considered conclusive evidence for The .Werrk Index: An Err#cloprdla of Chemitalr and purposes of this section. Drug8 Merck and Company. Inc.. 126 E. Llncoln Avenue. 2. Human data: Where available. epidemiologlcal studies Rahray. NJ 07086 rnd case reports of adverse health effects shall be eonsid- IARC .Wonogmph on the Evaluallor d the Carelnopenit ered in the evaluation. Rlrk ofChenlcol8 ta Mar Geneva: World Health O~nlutlon.International :1. Animal datn: Human evidence of health effects in ex- Arency for Research on Cancer. 1972-1977. posed populations is generally not available for the majority t Multivolume work). 49 Sherldan Stmet. Albany. of chemicals produced or used in the workplace. Therefore. New York the available results of toxicological testing in animal popu- lndutrial H##&re arl TorM.o#. b# P. A. Patt# lations shall be used to predict the health effects that may John Wlley & Sons. Inc.. New York. NY tllre ~olum8s) be experienced by exposed workers. In particular. the dell- Cllnkal Taxitolsg# d Conrdcal Prodrrtr nitiona of certain acute hazards refer to speciAc animal Cleuon. Cowlln and Hod- testing results (see Appendix A). Camrrtt and Dall's Tu&&##; The Eade Sekree d P&U 1. Adcpicy and nportlng of data. The results of any Doull, Klurun. and Amdur. Msemillan Publlshlng studies which are designed and conducced according to es- Co.. Inc.. New York. NY tablished scientiAc principles. and which report statktically lndutrial Torieol8##. b# Allcw HanUtor and Harriet L. significant conclusions regarding the health enects of a Hard# chemical. shall be a sufficient basis for a hazard determina- Publlihlnr Sciences Croup. Inc.. Aeton. MA tion and reported on any material sdety data sheet. The Torimlo## J the Ew. b# W. M.rt.r Grant

191O.lZoO APPENDIX C 806.28 Change 34

28 0CCUPATIOS.AL SAFETY hSD HEALTH 1910.1200 APPESDIS C

STASDARDS ASD ISUTERPRET;\TIOSS

Charles C. Thomas. 301327 East Lawrence Avenue. DRUG ISFORMATIOS 526 Springfield. IL MEDLARS Remgnition of Health Hazards in Industry MEWC William A. Burgess. John Wiley and Sons. 605 Third STIS Avenue. Sew York. SY 10158 POLLLTION ABSTRACTS Chemical Hazardr of tAe Workplace SCIENCE CITATIOS INDEX Nick H. Proctor and James P. Hughes. J. P. Lipincott SSIE Company. 6 Winchester Terrace. New York. SY 10022 Lackheed-DIALOG. Loekheed Missiles 81 Space Compa- Handbook ot Chemirtry and Physics ny. Inc.. P.O. Box 44481. San Francisco. CA 94144 Chemical Rubber Company. 18901 Cranwood Parkway. AGRICOLA Cleveland. OH 44128 BIOSIS PREV. 1972-PRESENT Threshold Limit Valuer tor Chemical Substances and BIOSlS PREV. 1969-71 Phyrical Agent8 in the Workroom Environment with CA CONDENSATES 1970-11 Intended Changes CA SEARCH 197z-76 American Conference of Governmental Industrial Hy- CA SEARCH 1977-PRESENT gienists. 6500 Glenway Avenue. Bldg. D-5. CHEMNAME Cincinnati. OH 4521 CONFERENCE PAPERS INDEX FOOD SCIENCE & TECH. ABSTR. Note.-The following documents arc on sale by the Su- FOODS ADLIBRA perintendent of Documents. U.S. Government Printing INTL. PHARMACEUTICAL ABSTR Office. Washington. D.C. 20402. NTIS POLLUTION ABSTRACTS Occupational Health Guideliner SCISEARCH 1978-PRESENT NIOSWOSHA (NIOSH Pub. NO. 81-123) SCISEARCH 1974-77 .VIOSHIOSHA Pocket Guide to Chemical Hazardr SSIE CURRENT RESEARCH NIOSH Pub. No. 78-210 SDC-ORBIT. SDC Search Service. Department No. Regirtrv d Tax& Effect. ot Chemical Subrtancer 2230. Pasadena, CA 91061 US. Department of Health and Buman Servicer. Public AGRICOLA Health Service. Center for DLeare Control. National BIOCODES Instltute for Occupational Ssfety and Health (NIOSH B10S1S1B106973 Pub. NO. 80-102) CAS677llCAS7216 The fndvrtriol Environment-Ita Ewluation and Control CAS17 US. Department of Health and Human Services. Public CH E M D E X Health Service. Center for Diseare Control. National CONFERENCE Institute for Occupational Safety and Health (NIOSH ENVIROLINE Pub. NO.74-117) LABORDOC .Ubcellancocu Doeumenta-National Institute for Oecu- NTIS patlonal Safety and Health POLLUTION 1. Criteria for a recommended standard *** Occupa- SSIE tional Exposure to *‘-” Chemical Information System (CIS).Chemizal Informa- 2. Special Hazard Reviews tlbn Systems Inc.. 7215 Yorke Road. Baltimore. MD 3; Occupatlonal Hazard Aasesament 21212 4. Current Intellligence Bulletins Structure & Nomeclature Search System Acute Toxlcity (RTECS) Blbiliographic Data Barer Cllnical Toxlcolo~gof Commercial Products Oil and Hazardous Materials Technical Assistance Servke Prooider and We Name Data Sgitem Natlonal Library of Medlclne. Department of Health and Bibliographic Retrieval Services (BRS). Corporation Human Services. Public Health Service. Yational In- Park. Bldg. 702. Scotia. New York 12302 stitutes of Health, Bethesda. MD 20209 Toxicology Data Bank (TDB) . AGRICOLA MEDLIN BIOSIS PREVIEWS TOXLINE CA CONDENSATES CANCERLIT CA SEARCE RTECS APPENDIX D TO 1910.1200-DEF1NlTl0N OF “TRADE SECRET” (MANDATORY)

A trade secret may consist of any formula, pat- a chemical compound. a process of manufacturing. ten, device or compilation of information which is treating or preserving materials. a pattern for a used in one’s business. and which gives him an op- machine or other device. or a list of customers. It portunity to obtain an advantage over competitors differs from other secret information in a business who do not know or use it. It may be a formula for (see Si59 of the Restatemejit of Twta which is not

Change 41 806.29 1910.1200 APPENDIX D

-’ 34 IY111.1200 APPESDIS D OCCC'PI\TIOS.\L S.-\FETS ASIJ HE.-\LTH

STASDARDS ASD INTERPRET.-\TIOSS ' 528 included in this Appendis) in that it is not simply not be that. It may be a device or process which is information as to single or ephemeral events in the clearly anticipated in the prior art or one which is conduct of the business. as. for example. the merely a mechanical improvement that a good me- amount or other terms of a secret bid for a con- chanic can make. Sovelty and invention are not tract or the salary of certain employees. or the se- requisite for a trade secret as they are for curity investments made or contemplated, or the patentability. These requirements are essential to date fixed for the announcement of a new policy or patentability because a patent protects against for bringing out a new model or the like. h trade unlicensed use of the patented device or process secret is a process or device for continuous use in even by one who discovers it properly through in- the operations of the business. Generally it relates dependent research. The patent monopoly is a re- to the production of goods. as. for example. a ma- ward to the inventor. But such is not the case with chine or formula for the production of an article. It a trade secret. Its protection is not based on a pol- may. however. relate to the sale of goods or to icy of rewarding or otheiwise encouraging the de- other operations in the business. such as a code for velopment of secret processes or devices. The pro- determining discounts. rebates or other conces- tection is merely against breach of faith and sions in a price list or catalogue, or a list of special- reprehensible means of learning another's secret. ized customers. or a method of bookkeeping or For this limited protection it is not appropriate to other office management. require also the kind of novelty and invention which is a requiste of patentability. The nature of Secrecy. The subject matter of a trade secret the secret is, however, an important factor in de- must be secret. Matters of public knowledge or of termining the kind of relief that is appropriate general knowledge in an industry cannot be appro- against one who is subject to liability under the priated by one as his secret. Matters which are rule stated in this Section. Thus. if the secret completely disclosed by the goods which one mar- consists of a device or process which is a novel in- kets cannot be his secret. Substantially, a trade vention, one who acquires the secret wrongfully is secret is known only in the particular business in ordinarily enjoined from further use of it and is re- which it is used. It is not requisite that only the quired to account for the profits derived from his proprietor of the business know it. He may. with- past use. if, on the other hand, the secret consists out losing his protection. communicate it to em- of mechanical improvements that a good mechanic ployees involved in its use. He may likewise com- can make without resort to the secret, the wrong- municate it to others pledged to secrecy. Others doer's liability may be limited to damages, and an may also know of it independently. as. for exam- injunction.against future use of the improvements . ple, when they have discovered the process or for- made with. the aid of the secret may be mula by independent invention and are keeping it inappropriate. secret. Nevertheless. a substantial element of secrecy must exist. so that. except by the use of im- Information not a trade secret. Although gven proper means, there would be difficulty in information is not a trade secret, one who receives acquiring the information. An exact definition of a the information in a confidential relation or discov- trade secret is not possible. Some factors to be ers it by improper means may be under some duty considered in determining whether given informa- not to disclose or use that information. Because of tion is one's trade secret are: (1) The extent to the confidential relation or the impropriety of the which the information is known outside of his busi- means of discovery. he may be compelled to go to ness: (21 the extent to which it is known by em- other sources for the information. As stated in ployees and others involved in his business: (3) the Comment a. even the rule stated in this Section extent of measures taken by him to guard the se- rests not upon a view of trade secrets as physical ' crecy of the information; (4) the value of the infor- objects of property but rather upon abuse of confi- mation to him and his competitors; (5) the amount dence or impropriety in learning the secret. Such of effort or money expended by him in developing abuse or impropriety may exist also where the in- the information: (6) the ease or difficulty with formation-is not a trade secret and may be equally which the information could be properly acquired a basis for liability. The rules relating to the liabil- or duplicated by others. ity for duties arising from confidential relation- ships generally are not within the scope of the Re- Novelty and prior art. A trade secret may be a statement of this Subject. As to the use of device or process which is patentable; but it need improper means to acquire information, see Pi59.

1910.1Mo AF'PENDIX D 806.30 Change 41

30 35 526

APPENDIX I1

Department of Energy Environment, Safety, and Heal th Bull et i n, Issue No. 14, DOE/EH-0003, Sept. 1985

31 U.S. Depanment of Energy ENVIRONMENT, SAFETY & HEALTH Washington, D.C. 2

Assistant Secretary for Environment, Safety, 81 Health Office of the Depun/ Assistant Secretary for Environment, Safety, 81 Health

DOE/EH-0003 Issue No. 14 September 1985

HOW OSHA'S NEW "HAZARD COMMUNICATION" STANDARD AFFECTS DOE CONTRACTORS

OSHA's new standard, "Hazard communication" referenced on an appropriate material safety (29 CFR 1910.1200) will go into effect November 25. data sheet. How material safety data sheets are 1985. for certain chemical manufacturers and made accessible to all employees must bc distributors and on May 25, 1986. for certain other described; employers, At this time, those that fall under the jurisdiction of the standard are specified by their c) a description of the methods used to inform and Standard Industrial Classifications (SIC). However, train employees and on-site contractor and OSHA has been ordered by the Third Circuit Coun of subcontractor personnel about unlabeled Appeals to expand the standard to include all employers hazards (exposure to metal fumes during and it is expected that OSHA will comply. welding operations, for example). As it is. the standard is confusing as it applies to DOE. It 2) Employers must maintain copies of material safety clearly applies to DOE contractors that are designated by data sheets for each hazardous material in the their SIC codes; those in SIC codes 20-39. But what workplace and make themaccessible during all work about others. like universities, that do not fall under an shifts. applicable SIC code but that. under contract with DOE, 3) Employers must provide formal training on the make and, or UK hazardous toxic chemicals? hazardous chemicals in the workplace. It must at Two DOE Orders that apply to contractors prescribe the least include information about: standard'; thus. all DOE contractors must compl) with a) which operations involve hazardous chemicals; the Hazard Communication standard whether or not b) where the list of hazardous chemicals and the they fall under the SIC coder referenced in the current material safety data sheets pre located; OSHA standard. c) what physical and health hazards are associated THE BASIC REQUIREMENTS with any hazardous chemical; Thr hasic requirements of the OSHA standard are: d) what the purpose of any control. (Le.. 1) Employers must develop and implement a written ventilation. personal protective equipment. or a Hazard Communication Program. It must at least specific work practice) is and how to ux that contain: control properly; a) a description of how chemical containers will be e) , what methods are used to detect the hazard (Le.. labeled. tagged, or otherwise marked to identify recognizing odors, monitors. alarms. the hazardous material contained and warn of symptoms of overexposure). hazards; b) a list of the hazardous chemicals known to be present using an identity for each that is FAClLlTlES THAT MANUFACTURE CHEhllCALS - The manufacturer of a chemical for either internal use or DOE J48J. IA. Ol-ruparionol Sajri? and Hrolih Prrqronrfor DOE for further distribution to others is responsible for: Cuniroa lor fnlp/iJ.Irr~01 Gownnvnrowud Cunirarrur-oprroird Forrlrrrr~. and DOf J480.4. fnm.rronntrni. SaJril. and Heolih a) labeling the container with the identify of the Sranrlord~. chemical and a warning of its hazards.

32 .- 37 b) producing a material safety data sheet for that 5480. IO. Conrracror Indusrrial Hygiene Program. 6 2.fi chemical. requirements analogous to those in the OSHA standard. The material safety data sheet should be based on a They are: hazard analysis. How to determine whether a chemical is An inventory must be maintained of potential hazardous for hazard communication purpose is covered physical and biological health hazards as well as in paragraph (d) of the OSHA standard. chemical hazards. Those hazards are to be listed by location and/or the job category of those who would Exceptions be affected with an indication of when those ha~ards The production. use. sale, or transfer of radioisotopes would be present. To avoid duplication. the list of within or between DOE facilities and the sale or transfer chemicals required by the OSHA standard may be of radioisotopes to a Nuclear Regulatory Commission or incorporated in this hazards inventory; agreement state licensee are exempt from this standard. An employee education program must be initiated Requirements for labeling. employee education. and whenever controls (i.c:, personal protecti\e radiation protection are covered in separate Orders, quipment, engineered systems, or administrative standards and regulations. procedures) are used; Laboratories (any operation equipped for the testing. Contractors' industrial hygiene staffs must assist in analysis. or experimental use of chemicals) are not developing the information and training programs Labels required to develop material safety data shetts. for physical and biological health hazards a5 well ab must be provided for all chemical containers being used for chemical hazards. Included is the requirement in laboratories in accordance with NFPA 45. Fire that employees be notified in writing when Prorecrion lor LoborarorieJ Using Chemicals. environmental monitoring indicates that they have ken exposed above permksible limits. The applicabilit) of the OSHA standard to an The Order recommends rhat training include operation or to material should be determined by information about: the operations which ma\- lead to the rsfet) and health staffs based on the definition exposure; the poiential health affects; the of the terms used in the standard. requirements of the applicable standard: and rhc purpose and results of workplace monitoring. TECHNICAL ASSISTANCE IS AVAILABLE FACILITIES WITH CLASSIFIED CHEMICALS The Ccnter for Assessment of Chemical and Physical DOE facilities where the identities of materials are Hazards, Brookhaven Natbnal Laboratory, operates a classified should keep the lists of hazardous chemicals Toxic Material Advisory Program for the Depanment. and material safety data sheets required by this standard Questions about all aspects of hazard recognition. in a secure location in accordance with security including toxicology, will be answered by contacting Dr . requirements. However, any employee working with a James Brower, FTS: 666-5057; Comm: (516) hazardous chemical is considered to have a need to know 282-5057. its identity and the nature of the hazards involved (of course. access to classified information requires an The Center is building a data base of material safety data appropriate current DOE security clearance). The sheets SO that DOE contractors can share them when documented Hazard Communication Program must appropriate. This data system is expected IO beconlc a descri be how employees can access applicable classified module of the Safety Performance Measurement System information. If the employer is required to develop a before the end of this year. Copies of material safet) data lakl. the label must contain a warning of the nature of sheets for thox materials king used in your facility the hazard and a name that can be cross-referenced to would be appreciated. Please note whether the! ha\e classiried information about the material's chemical been reviewed for accuracy and thoroughness and send identity. them to The Center for Assasment of Chemical and Physical Hazards, Brookhaven National Laborator!. REQUIREMENTS OF DOE 5480.10 Upton, New York 83401. OSHA's "Hazard Communication" Standard covers If you have questions about the OSHA standard or how chemical hazards only: DOE Orders cover other hazards DOE is implementing it. contact Donald M. Ross or as well, noisy machines and lasers, for example. DO& Paul Wambach; FTS: 233-3331. Comm.: (301 )35.7-3?.7 I.

&//rim IS publirhcd to provide DOE IMN~CNand conimors with infornution rrlcvrnt io DOE prolnmr adopentiom For more ininrmmn contacl %ON Gilbert Shcpard. Editor. EH-121. Ofrtu of Ihc Ikpul) ALLISIJnl Secrcur) for Environment. Efrc) & Health. U S Rpartmrnt 01 tnerp kashington. D C 205d5 lclcphon FTS 233-29511. Comm (341) 353-2958

33 '. 38 526

APPENDIX I11

List of Hazardous Materi a1 s

34 39 Date: 05/18/87 P8QC: 1

UPOATE LIST Of ALL PURE CHEMICALS WRClUSED FRO( 01/01/84 TO 05/18/87 526

Pure thaicrt Y-

...... _.I...... ACE1IC ACID, (1,2-CYCLOHEXYLEWEDIWI TRlLO) TETRA. (M:CDTA) ACETIC ACID, GLACIAL 99.5% ACETCUE ACETONITRILE, HPLC GRADE ACID POTASSIUI PMTMUTE ALCOHOL, ETHYL (MA: ETHANOL) ALCOHOL , ISOPROPYL (MA: 2-PRCPANOL) ALCOHOL, METHYL ABSOLUTE (MA: ETHANOL) ALUIINA, ACTIVATED ALWINA, HYDRATED ALUIINW METAL ALWINW NITRATE REAGENT GRADE ALWINW SULFATE I-HYDRATE (ALUM) AMMONIA, ANHYDROUS AnnOwlUl CHLORIDE AWNlUn CITRATE Acv1oNIUI HYDROXIDE 58% NHlOH MNIW IWIDE CRYSTAL AMWNIUl HOLY BDATE AMMONIUM OXALATE AcuK)wIuI PYRROLIDINE DITHIOCARBONATE AncloNIW SULFATE ANT IRONY ASBESTOS ASCARITE POWER 20-30 MESH a ASBESTOS FIBER ASCORBIC ACID BARIUM CHLORIDE BORIC ACID BROClOCRESOL GREEN BRUCINE SULFATE, ACS REAGENT GR~DE CADMlUl METAL CALClUI CHLORIDE CALCllM FLWRIDE CALCIUI HYDROXIDE, HYDRATED LIME CALCIUI HYPOCHLORITE CALCllM OXIDE, BULK PEBBLE LIME CALCILW OXIDE, REAGENT CALClUl SULFATE (IWDICATING DRIERITE) CALMCITE, METALLOCHROIIC INDICATOR CELLULOSE, SWIW CARBOXYMETHYL ETHER CMLOROFORM CHROnlC ACID CRYSTAL (AKA: CHROnlUH TRIOXIDE) CITRIC ACID COBALTIC FLWRIDE COF3 COPPER METAL CREATININE CUPRIC SULFATE PENTAHYDRATE CUSCU.SH20 CYCLOHEXANE DlBUTYLAnlNE a DICHLORODIMETHLSILANE REAGENT DIOCTYLPHTH~LATE, DOP DISOOIW PHOSPHATE (AKA: SOD11RI PHOSPHATE DIBASIC) 35 p. 40 Date: 05/18/87 Page: 2

UPOATE LIST OF ALL PURE CHEMICALS PlRCIUSED FROM 01/01/w TO 05/18/87 528 Pure Chaicd Yam

.-.--.I.-...... -.--.I.-...... ETIUWL, 1,1,2- TRICHLm-2,2,1 -TI1F LWRO- ETHYL ACETATE ETHYUWINE (ANHYDR-) ETHYLENE GLYCOL ETHYLENEDIAMINE ANHYDRWS FERRIC CHLORIDE, REAGENT WE FERRIC NITRATE FE(Na)3 FER- CHLORIDE FERRQlS SULFATE CRYSTAL FERROZINE IRON, 3(2-PYRlDYL)-5,6-BIS(~-PHENYL~LFONlC ACID.. FLUORESCEIN SOOIUM SALT (URANINE) FORMIC ACID 88% GALLIC ACID POIlOER CLUCOWIC ACID (50% IN WATER) GLYCERINE GRAPHITE, VARIOUS SHAPES HEXANE HYDRAZINE HYDROCHLORIC ACID, 20 DEGREES BE HYDROCHLORIC ACID, SP.G.4.18 HYDROFLUORIC ACID, 48% SOLUTIW HYDROGEN FLUORIDE, ANHYDROUS HYDROGEN PEROXIDE, 30% REAGENT HYDR~ENPEROXIDE, 35% TECHNICAL GRADE HYDROXY NAPTHOL BLUE CALCIUM INDICATOR HYDROXYLAMINE HYDROCHLORIDE INDlUn METAL I RON ImTANE, PESTICIDE GRADE KEROSENE KETONE, METHYL ETHYL (AKA: 2-BUTANOIE) KETONE, METHYL ISO-BUTYL (AKA:2-PENTAN011E, 4-METliYL) LACTIC ACID WTWCHLORIDE WTWNITRATE LEAD DIOXIDE (AKA: LEAD PEROXIDE) LEAD SHOT, ASSORTED SIZES LITHIUI CARBONATE, 98.7 % TECHNICAL GRADE LITHIUM CHLORIDE LITHIUM HYDROXIDE MAGNESIUM METAL, CHIPPED MAGNESIW OXIDE MGNESIUM PERCHLORATE, ANHYDROUS MAGNESIUM SULFATE MERCAPTOACETIC ACID am AQUEOUS SOLON (THIcmYcoLic ACID) MERCURY, INSTRUMENT GRADE METHYL SULFOXIDE (DIMETHYL SULFOXIDE) METHYLENE CHLORIDE MOLYBDIC ACID, 85 % WER NICKEL NITRATE, NI(N03)2.(H20)6 NIOBIUM METAL NITRIC ACID, 100% BASIS 36 .-- 4 1 Date: 05/18/87 Page: 3

UPOATE LIST OF ALL PURE CHEMICALS PURCHASED FROl 01/01/64 TO 05/18/87 526

Pure Chatcat Nm

...... I...... _...... I...... _.... NITRIC ACID, ANALYTICAL REAGENT GRADE OXALIC ACID PERCHLORIC ACID, 70.72% ANALYT. REAGENT PHENMTHROLINE MOUOHYDRATE PHEWANTHROLINE, 1,lO- 2,9-DlHETHYL (AKA: NEOQIPROINE HCL) PHENOL, 2-(5-BROIO-2-PYRIDYUZO)-5-(DIETHYUIIIYO) PHENOLPHTHALEIN REAGENT PHOSPHORIC ORTHO ACID, 85 X ANALYTICAL REAGENT POTASSIW ACID PHTHALATE POTASSIW CARBOWATE POTASSIW CHLORIDE POTASSIW CHROMATE POTASSILM DICHROMATE CRYSTAL POTASSllH FLWRIDE POTASSIW HYDROXIDE POTASSIUM HYDROXIDE, 45% AOUEWS SOLUTIO11 POTASSIUM IaOIDE POTASSIUM NITRATE POTASSIUM OXALATE POTASSIUM PHOSPHATE HONOBASIC CRYSTAL POTASSIUM PYROSULFATE (AKA: POTASSIUM HYDROGEN SULFATE1 POTASSIUM SULFATE PYRIMIDINE, 4-M1110-2,6-DIHYDROXY-5-NlTROSO PYRROLID1NECARBaOITHIOlC ACID, 1- MHWlW SALT RHENlUIl S-DIPHENYL CARBAZIDE SILICA GEL SILICA SAND, BLACKHAWK BRAND, OTTAUA, OR EOUAL SILICON METAL POWER SILVER SULFATE WDIW BICHROMATE, REAGENT mIW BORATE sQ)IW BOROHYDRIDE 98% NABH4 SOOIW BROlIDE WDIW CARBOWATE WDIW CHLORIDE SODIW CITRATE WDIW CYANIDE SaOIW FLUORIDE SaOlW FORMATE SaOlW GLUTACUTE (MONO) SaO1UM HYDROSULFITE SaOlW HYDROXIDE SOOlUM HYDROXIDE, 50% AOUEWS SOLUTION SaOlUM HYPOCHLORITE 12.5% AVAILABLE CHLORINE SaOIUn NITRATE, PURIFIED GRADE SODlUn NITRITE, CRYSTAL sQ)IlH OXALATE SODIW PEROXIDE, REAGENT GRADE SOOIW PHOSPHATE, MONOBASIC MONOHYDRATE CRYSTAL SOOIW SULFATE SOOIW SULFITE 37 '- 42 Oat.: 05/16/87

ClPOATE LIST OF ALL PURE CHEMICALS PURCHASED FROl 01/01/64 TO OS/16/67 526

sQ)lu( TETRAEORATE DECAHYORATE (BORAX) STIo1TIu1 CARBOIATE REAGENT WllDER SULCMIC ACID SULFosALlCYLIC ACID QnFUR SULFURIC ACID, 83.2% SULFIRIC ACID, ANALYTICAL REAGENT A.C.S. SULFURIC ACID, BATTERY ELECTROLYTE SP.GR.=l .so TETRA ACE1 IC ACID, l82-CYCLWEXYLENEDINI TRI LO- TETRACHLOROETHYLENE (AKA: PERCHLORCETHYLENE) THENOYLTRIFLUOROACETOlE (ITA) THlROl (D1S001Un-l82-DIHYDR0XYBENZENE-3,5-DISULFOUATE) THYMOLPHTHALEI N TIN METAL, GRANULAR REAGENT TOLUENE TRIBLJTYL PHOSPHATE (TBP) TRICHLOROETMNE, l,l,l- (AKA: METHYL CHLOROFORM) TRICHLOROETHYLENE TRIETHANOLAWINE TRIOCTYLPHOSPHINE OXIDE TRISCOIUM PHOSPHATE (AKA: SODlUn PHOSPHATE TRIBASIC) TUNGSTEN METAL URANYL NITRATE, CRYSTAL UREA, FLAKED, SHOTTED, OR PRILLED VANADIUM SULFATE, DIHYDRATE XYLENE (XYLOL) YTTRIUI OXIDE PAINT YTTRIUI OXIDE POWER 90.99% PURE . ZINC ACETATE CRYSTAL ZINC CHLORIDE ZINC, HIGH PURITY ZIRCCUlUl OXIDE POWER

38 43 Date: 05/18/87 pa@@: 1

UPOATE LlST OF ALL CHEMlCAL IIlXTURES PlRCllASEO FROM 01/01/64 TO 05/18/87 528 ...... ACCELERATOR, COPPER LECO 601-w LECOCEL LECO n65-266 FQI CARBON AllALYZER ADHESIVE, 8520 W.BRA#, STYLE EC 1300 W SUPER 77 SPRAY MSWESIVE kr SUPER SPRAY ADHESlVE ASPHALT CUT BACK - MSTlC HENRY Nz ASPLIT UI CARBON MR ASPLIT CN rOLuI101 CARBOWSTIC 15 DECO-RE2 EPOXY CRACK FlLLER & ADHESIVE A + B ELMERS GLUE F-181 BOLT ANCHOR SULFASET GLUE FOR CElLlNG TJLE HARDMAN EXTRA FAST SETTlNG RED LABEL EPOXY 1NSULATIOW ADHESIVE LlQUlD NAlL CONTSTRUCTlo11 ADHESIVE LOCKWELD 600 BRUSHABLE CWTACT ISHESIVE LOCTlTE SUPER BONDER 4% MASTIC - HENRY #232, ASPHALT CUTBACK . PERMABOWD 910 ADHESIVE PLIWD I20 INDUSTRIAL PRAlRlE BOND ZOO0 REPLACEMENT PART FOR HALOGEN LEAK DETECTOR 0 REZ-N-BOIID PLASTIC GLUE RTV 102 SILICOWE RUBBER SPRAY 3H SUPER 77 HlGH COVERAGE THINNER FOR UGRIPPITm RUBBER CEMENT EL-00094 TRA-BOND 2101 GENERAL WRPOSE EPOXY TUFF-BUUD GENERAL WRPOSE WAX - ADHESIVE USE IN C0Q)KIN COATER WAYLOCI ADHESIVE AlBl HARDNER UELD-OU PLASTIC AIR FRESHENER, DEOZOUE coo0 SENSE GUW SENSE 7 QK# CMlTERACT DlSC SPRING GREEN QKR-DISCS AIR FRESHNER, CAN SCENT DEDDORUlT lUSK ASBESTOS BOARD, ASBESTOS BOARD OR CAREY-MINERITE ASBESTOS CEMENT MRRUGATED BOARD, TRAMSITE ASBESTOS CEMENT LEGS, XKlD TRANSITE FOR REMELT FURNACE COIL ASBESTOS FLEXlTALLIC GASKETS ASBESTOS GASKET, #10 MANHOLE GASKET 11 304 SS AND STYLE ELIPTICAL ASBESTOS MNHOLE GASKET HONE1 ENVELOPE DWBLE JACKETED SINGLE,DWBLE JACKETED L SPIRAL HXlND STYLE 655 RING GASKET CDWPANIOW FLANGE STYLE 736 AFRICAN BLUE GASKET WASHER-SWIVEL NUT-STYLE U-16 ASBESTOS PACKING, GARLOCK ASBESTOS SHEET PACKING

39 I- ’ 44 Dit.: 05/18/87 P.0.: 2

UPDATE LIST Of ALL CHEMICAL IIIXTlRES aCHASU) fKU 01/01/& TO 05/18/87 526 Cheder1...... Mlrtu. category wrnr 8A TREAT, MIXllRE Of %FATE RUST IYHfBIT~A#) STABIL.AGENT BELT DRESSING, CHESTERTOW SPRA-GRIP BLASTING an,Bua BEALIIY ~w0-16 BUFFER, BUFFER SOLUTION - PH 1.00 - 2.00 BUFFER SOLUTIOW - PH 3.00, 4.00, & 5.00 BUFFER SOLUTICU - PH 6.00 - 8.00, W~-BEC#Ay BUFFER SOLUTION - PH 9.00 - 11.0 BUFFER SOLUTION, WNC. FOWl BUFFER SOLUTION, FLURAll I BUFFER SOLUTION, FOR HARD UATER SAWPLES COLOR-KEYED (RED) 4.01PH, 20 LITER HYDRION PH 1.00 TO 10.00, 50-B-%,97,98,99,101,102,104...140 PH 10.00 COLOR KEYED BLUE, BECW P/N 188097 POWER FOR PH 10.00, HACH 22271-95 POWER FOR PH 4.01, HACH 22269-95 PMER FOR PH 7.00, HACH 22270-95 RED SOLUTIOW 6.01 PH, FISHER CAT# 508-101 CAULK, CAULKING COnPWND IN CARTRIDGES FOR HANDICALK GUN DAP WHITE ACRYLIC LATEX CEMENT, U501 AIR SETTING ACIDSILL LIWlD ACIOSILL POWER ALUMINLM BOND BESTLINE RUBBER CEMENT THINNER COLUMBIA PORTLAND

CPVC PIPE CEMENT firzpo53 ~ CPVC PIPE PRIMER m55 Duco HOUSEHOLD ELECTRCOE JOINT #U-7130 EPOXY GLUE #lo-347 FIBREX SUPER KOTE PIPE INSULATING CEMENT FIRECRETE P-R-RIP 1110-115 LlQUlO RUBBER CEMENT, K-103 13 WICK COTE CEMENT, P.K. WICK-STIK #lo-114 SACKRETE WORTAR WREISEN ELECTRIC RESISTOR NO. 78 SERVICE CEMENT- WICK DRYING AND WATERPROOF TASlL THERnOIi BRAND HEAT TRANSFER GRADE STD. 11-3 WATERPLUG WEATHER STRIP NAPA a061 8001 CHUCKHOLE PATCH, PRIMER FOR F-230-S RANDUSTRIAL F-23O.S TRUHOLD PATCHING ClATERJAL CLEANER, "CONTACT RE-NU' AEROSOL 1208 LENS CLEANING FLUID 1-LENS-M OR KLEAR GLASS #21 WINTERGREEN, TEXOPHENE, OR PHILOGREEN DlSlNFCT a-67 CAR SHAMPOO DUPOUT 1634 - 45 40 UPDATE LIST 06 ML CHEMICAL MIXfURES PURCWD fRo( 01/01/84 TO 05/18/87 526

ACID( AWL, NL uo, OR ma n ALQ1100( ASH- TOLUENE CLEANER LIQUID BET2 #I-2 RESIN BLEACH yo. 4ZlPSHC55 BRUSH CLEANER SOLuIlol (SILICOI CLEANER) BUTCHER'S SUWDMCE CAL-CLEAN LIQUID DETERGENT CAR s)IAwpoo 0420 PENRAY CARPET AND FABRIC PROTECTa CULK BOARD CLEANER (PHILLIPS) CCUET CWERAGE 256 DECREASING AGENT, HAGNU-SPRAY 205 DECREASING AGENT, HAGNUS 905-XX DRI-IT DISHWASHING AID DU PAN PMERED DETERGENT SOAP DUBOIS COMBAT DISHWASHING COMPOUND DUBOIS FABRIC SOFTENER WBOlS FLOW DYNA SPREX ENMY - GERMICIDAL CLEANER EWW INSTANT SPRAY FORT 1 FY FRANKLIN FREEDW SPEED STRIPPER GLASS CLEANER, SILICLENE bR SSS BLUE )IAy) CLEANER, KO-REC-TYPE, P/N A7.21-L HlLLCO EXTRACTIOW SHAMPOO IN PLACE CLEANER HI PCUER JOHNNY RING0 GENERAL PURPOSE CLEANER JOHMSOW UAX PROWTO, FAST DRY FINISH JO(RISOW'5 CCUPLETE FLOOR FINISH JOHNSOW'S SHINE-UP LIWID L P S SPRAY CONTACT CLEANER WAILKERWRD CLEANER N.F. CLEANER/DEGREASER tUEC BATHROCU PERJ PLATE SAV-UR PCWER BLEACH &UP DRY PCWER KEY #6394-85 RES-35 CONCENTRATE CLEANING AGENT RID - LIME ROLWARK SOLVENT 8 CLEANER RUSTOLEW SURFA ETCH, 108 ETCHING SOLUTION SANITUFF BOOY SHAMPOO SPARTAN DC-13 ALL-PURPOSE 0 SPRAY BUFF - JOHNSON SNAPBACK SPREX, TEXO AC, OR TROJAN #145 P SR-44 SPOT REMOVER 41 46 Date: 05/18/87

UPDATE LIST OF ALL CHEMICAL MIXTLRES PURCHASED FRCU 01/01/84 TO 05/18/87 526 a Chemical...... Mixture Cat- Me SSS METAL CLEANER SUPER DESOIL THERlUTlC SMR CLEANER THOUS LIQUID CLEANER, PHOSPHATE FREE NINKLE STAINLESS STEEL CLEANER & POLISH MSTAL CREME CLEANSER MSTAL DEFOAltER CONCENTRATE m65-08 VESTAL DCUELE BARREL CLEANER VIN WICX CLEANER UATERLESS STRIPPER COAL - ANTHRACITE FILTER GRADE COATING, CLEAR IHTERIOR, CVC CQ)E 1160170, 11160662 WATER REDU. EZE PEEL (SPRAY 80071 COATING) FIBRATED ROOF HEAVY DUTY EPOXY COATING HEAVY DUTY GRAY FLOOR COATING KOPPERS BITWASTIC NO. 50 MAGNA-MASTIC PERFORATED FELT TERRAPAINT 550 HOLD COATING TEXO L.P. 21U TEXO L.P. 781 WAX PRONTO WORKABLE FIXATIVE KRYLOW SPRAY COATING a YTTRIW OXIDE COATING COMPOUND, a20 GRINDING AND LAPPING COMPOUND 3M EDGE SEALING COMPOUND FOR WALKS + TREADS AQUASET DAMP DEK LIQUID DAMP DEK PLASTIC DOU CORNING 11 GLAZING CCUFalND, DAP 103 OR TREMCO a26 GRADE 1 - U-47 HYPREZ - DIAMOND POLISHING ColWuwD GREEN LABEL HILITE FOR HILW OIL RECUIWER HYPRES F/OS DIA31011D ColWwlD FLUID NO. 100 'PULL IN' MINERALLAC PADD 1NG PETRA-SET RELEASE AGENT SPACKLE WWD YORK'S SPAT-R-PRUF WELDING COMPOUND 106 CONCENTRATE, UIS COWTRAD 70 DEOZONE LlCUlD WITH CONDITIONER NP, . COOLANT, 0/50 OXCEDOT CAHPBELLENE CQK BLUE DE-FOAMER EMULSI F I ER HYDRO1 L INGERSOLL RAND SSR a OXCEDOf PIN 39118296, FOR INGERSOLL RAND HWEL 1SOOL WSW 42 - 47 Datr: 05/18/87 Pege: 5 UPOATE LIST Of ALL CHEMICAL ll1XWS PIRCHASED FRa Ol/Ol/bi, TO 05/16/87 526 Chatcrl...... lllrturr Catwry Wrr mRM1s-5 COPIER FLUID, k BRAND OUAIITIMTIC TolIR TYP€ 748F COlVERSIQl SOLLITION PART W-5-101241 DMLOQER P/W %-148, fOR 1055 XEROX COPIER ELECTROSTATIC SOLUTION P/y =5-1-10&0% UEEPEZE SOLUTION, PART Roo-726-2A LIWID DISPERSANT P/W 83-4-104416 LlWlD WASTER DEVELOPER PIY 83-1-101241 P/W 5R-130 FOR XERCM #DEL 3450 REPELEX SOLUTION PART # 200-722-U TONER AND DISPERSANT FOR SAVIN CUPIERS TONER TYPE 7481 FOR 3M ENLARGER/PRINTER XEROX #SR- 142 DEVELOPER XEROX rKRl2 DEVELOPER XEROX #6R-121 DRY INK PLUS XEROX #6R- 149 TONER XEROX 1055 DEVELOPER IIRR-116 XEROX 1055 DRY INK PLUS W.82 XEROX 1075 DEVELOPER 1SR-302 XEROX 1075 DRY INK #&-Sol XEROX 2600/3100 DRY IMAGER a-68 XEROX DEVELOPER P/N 5R-127 XEROX DEVELOPER P/N 51-129 XEROX DEVELOPER P/N 5R-283 XEROX DEVELOPER P/N SR139 XEROX DEVELOPER, P/N 5R-111 XEROX DEVELOPER, P/N 5R130 XEROX DRY INK PLUS P/N 6R113 XEROX DRY INK PLUS P/N SR112 XEROX NSER LUBRICANT #8R-983 XEROX FUSER/LUBRICANT P/N a111 COPIER LUBRICANT, XEROX P/N 8R-111 CUTTING 6 GRINDING FLUID, TAPMATIC CUTTING #2 TAPMATIC CUTTING FLUID I1 TRIM so1 WNCENTRATE DASH POT OIL, GENERAL ELECTRIC I! W7A1 FOR CIRCUIT BREAKERS DETECTOR, CASOLINE/OIL P/N lOTBTl7 UATER DETECTOR FOR CAS#INE/OIL TANKS P/N 1078714 DEVELOPER, el-101-2 DEVELOPER 34 34 CD-5 COLOR KEY AH INTERNAT'L FOR 7100 VORO PROCESSOR KODAK DEFOAMER, PROCESS E-6 KODAK INDUSTREX MNUAL DEVELOPER AND REP.lOO-3623 KODAKLITH LlWlD PART A 11157-1900 KOOALITH LIQUID PART B H57-1918 LASER IMAGER P/N S690039 LASER P/N S69082C PREMIX FOR 9 ENLARGER XEROX P/N 5R-110 DIATCMACEOUS EARTH, DlCALlTE FILER AID SIL-FLO FILTER AID GRADE cC3 43 '' 45 Doto: 05/16/07 Poge: 6 UPDATE LIST OF ALL CHEMICAL MIXTURES WRCMSEO FRCU 01/01/04 TO 8/16/07 526 chcalul Illxtur, cat- Yr, -...I...... - a -...I...... - DRW aTING, CLEM INTERlOR DRY ICE (a) DRY IMAGER FlXER, 3M 028 FITING SLUT101 YC W, 3M l.D.n8-9020-0160-7 3M n-1 All INTERNAT'L FOR 7100 WRD PROCESSUR KOOAK WID FIXER, PARTS A 8 E FLOCWLAYT, FLUID, "ASBESTOS UET. UETTING SOluIIW CORRECTIW FOR INK ROTEX 1NTERNATlOWAL #)00153R HYDROLlC BRAKE FLUID I21 LENS CLEANlNG #208 LlWlD PAPER CORRECTIOW FLUID LlWlO PAPER CORRECTIOW FLUID THINNER LlWlD PHOTO MSKOID SNOW LEAK DETECTOR SNOPAKE ERASING FLUlD SPRAYOW BLUE LAYOUT FLUID FLUX, DUPONT UCLOW F. DUPWT UCLOW HV OXVELD BRAZING STAY-SILV BLACK/UHITE FLUX DIESEL #2 LIGHTERS GAS - WRELIGHT, #2001 a FUEL* GAS, 10-30% HYDROGEN 111 ARGON AIR, HYDROCARBON FREE, 20-21% 02 ARGON %%, METHANE 5% CHLORINE FREOll TYPE 11 FREON TYPE 12, LABCRAFT BRAND AIR-IT FREON TYPE 22 FREON, R22 HELIW HYDROGEN HYDROGEN t% IN AIR HYDROGEN 2% lN AIR LlWEFlED PETROLEW GAS METHANE METHANE 2% IN AIR NITROCEN NITROUS OXIDE 98% P-10 (10% METHANE 90% ARGON) TEST 1%: CO, COZ, CH4, H2, 02 IN N2 TEST 25% CO2 AND 75% ARGON TEST 5 TO 9.9 PPH HCL lN NITROGEN TEST 72% HE2, 5% CO, 5% N2, 4% CH4, 4% H2, 5% 02, 5x02 TEST 75% H2, 25% N2 TEST 96% LIZ, 4% 02 . TEST 9n N2, 3% H2 TEST 98.8% N2, 0.6% H2, 0.6% 02 TEST 99% N2, 1% OZ 44 49 Oat.: 05/18/87 P.0.: 7

UPDATE LIST OF ALL CHEMICAL MIXTURES PURCHA#o FRO( 01/01/& TO 05/18/87 526

TEST GAS AELERosoc FOR PIRotlKIIICS P/W GC-7 CASomK REWUR UILEADED CEL, TlGHT lull1 PURPOSE GEL P/W 51604 GREASE, )LP-Ob-4121 TYPE .Em GREASE AP€IZ(Y DW CORNING SlLICOlE WLFCROW, E. P. NO. 2 GREASE INDUSTRIAL - POLY-- LUBRIPUTE 11550-M GREASE HPG.2 GREASE PLASTIC TUBE - FALK LONG TERM GREASE SlLlCOWE (TUBE) P/N U-102b2 SILICONE IMPACTIOW GREASE STOPCOCK GREASE, LUBRISEAL TRIBOLUBE 130 - SYNTHETIC GREASE GROUT, EMBECO 636 HERBICIDE, BRUSHKILLER 170 (2,b-D) PRAMIT01 25E (25% PRCUETOW) HYDRAULIC FLUID, BRWUS VERSALENE 650 FYREQUEL #lSO FIRE RESISTANT FYREWEL FIRE RESISTANT INK, BLACK (LITHOGRAPHIC) INK COLOR BLACK R-BK COLOR BLUE COLOR GREEN COLOR RED COLOR WHITE R-W PANTONE 285 BLUE INK SPEC 1 - RUBBER BASE VAN SON BLACK Vs-100 VAN SON RUBBER BASE IVY GREEN #VS-338 VAN SON RUBBER BASE KQ)AK PROCESS YELLW 201 M-301 INSECTICIDE, BUG WSTER 0.1PYRETHRIN. 1PIPEROIIL BUIaXlDE PHILLIPS HIGH PRESSURE BCUB EPA U7405-52-17W4 #VIM SOY (CARBARYL) INSUUT101, KAOKXK RIGIDIZER JOINT SEALER, SEAL TIGHT RUBBER KITS, SHURE-BOWD CONCRETE REPAIR LIMESTONE, CRUSHED LINSEED orL, RAW LUBRICANT, #995 WLTlFAK EP 2 6 #1922 MOLYTEX EP 2, PEW 12 CONDUCTO-LUBE CML AnP POWER GOW, HIGH WRITY THREAD LUBRICANT KLINGFAST GEAR, SOHITAC, WHITMORE OR TENACE SPRAY L P S INSTANT SPRAY I(OB1LGEAR 629 NEVER-SEE2 ANTI-SEIZE 6 SEALING CCWCUND POLY-CON PL-2 INDUSTRIAL GREASE ,POLY-CoW PL80-90 GEAR LUBE SI11 SPRAY (SILICON LUBRICANT) 110-600 SUN-WAY (WAYLUBE 11180) 45 50 Drto: 05/18/87 Page: 8

UPOATE LIST OF ALL CHEMICAL MIXTURES PURCIUSED FRU4 01/01/84 TO 05/18/87 526 Cheder1 Mixtwo ktmry Mrr

......

VAC GWP THREAD LUBRICMT UATER PUO LUBE Alo ANTI-RUST ERNATEX 3& Y)-40 METAL, ALLW1IIL)I IRON #TAL WY)ER A-UO MIXTURE, CARBOW ACTIVATED PELLETS HOLD QlATIMG, CERAWCO ZUR-ZoA CEWTE U-BE CEWCOTE ZUR TERRAPAINT 550 TERRAPAINT 559 OIL SORBENT, OIL-DRY ALL PURPOSE 3-IN-1 OIL 310 SOVAC MOTOR OIL (LUBRITE HOTOR OIL SA€ 10) A49796 SEAL OIL CALCOW ZEROL REFRIGERATIOW OIL CHESTERTOW #3W CUTTING OIL UIP- 37 CUTTING OIL, SHELL GARlA HSL7026 BLEND #3 DRAD CONCENTRATED OIL VALVE LUBRICATIOW OW) SEAL pu(P VACUM ENDURA AIR TOO1 OIL, EXTRA LIGHT FUSER OIL HOOKER FLUOROLUBE TYPE HO-10 HWCHTOW WENCH K OR BEACON K-9 ICOIERSIW, MICRO SLIDE MERRIAH UNITY OIL SPEC D-2969 IK)81L 427 AIR CCUPRESm OIL. WIL DELVAC, 1110, SA€ 10 HIGH DETERGENT HOBIL DTE 24 MmIL DTE EXTRA HEAW MmlL DTE OIL 26 -11 LUBRITE 1130 SA€ 30 MmILE DELUAC 1130 (LUBRITE SA€ 30) MmILGEAR 11632 OIL MmILlSE Do0 OIL FOR eUI0 -RES##, SIB-AQUATICS P/N 1230 OIL FOR SILENT EOlPRESSOR my-ax PL-30 INDUSTRIAL OIL REXLUBE SPINDLE LIGHT H29 RIGID DARK THREAD CUTTING SAE 2OU-20 NO)(-DETERGENT MOTOR OIL SEAL 111678 C/R SHELL ROTELLA OIL T MULTI-GRADE SAE 15Y/CO SHELL TURBO OIL a3 SUN OIL CO. SUN SOLUBLE OIL 31 TRANE REFRIGERATIOW OIL PAINT REHOVER, KLEAN-KUTTER CWE 115 KLEAN-STRIP HEAVY BQ)IED TEXO 404 THICK #lOO-lO PERHA-BO)(D 46 Dit.: 05/18/87 Pag8: 9

UPOATE LIST OF ALL CHUlICAL NIXTIRES PURCIUtED FRCU 01/01/64 TO 05/16/87 526 ...... NlXtWe C8i89Q~ 1101-1 A L B IIWSTRIAL tWRl WtTE 1101-2S08 EMEWL CATMIST, B 1116-11 ACRYLIC uia PIIIER IIZOI-A GLrPTa RED EML 11500 LATEX FIRE RET-1 PAINT m-11 BLACK FILLER ma 1164 GREEN EXTERIOR ENAMEL OR FED. SPEC. 114110 (1168 QUICK DRY IND. RUST INHIBITIVE PRIMER 1177 EPOXY HARDENER 1178 EPOXY THINNER 118 ROYAL BLUE SPRAY OR CLARK #437 BRITE BLUE 11801 KRYLOW, CLARK 436 YELLW !PRAY 1181 EPOXY RUST INHIBITIVE PRIMER 1182 CHEMICAL I UATER RESISTANT EPOXY BASE 11900 PERMITE HOT SEAL HIGH HUT ALWINUI 11902 HIGH TEMPERATURE SILICONE ALWlNW 1205 RED FEDERAL COLOR SPEC 111105 121 PERMITE UHITE, KRYLOW 1501, OR CLARK 451 12101 KRYLOW, CLARK 444, #362 CHINESE RED SPRAY CAN 122 CRYSTAL CLEAR PERMITE OR CLARK #4ss 1250 PLASTIC-KOTE, KRYLON 1601, CLARK 452, WEEKEND358 #31-424 DURONOOIC URETHANE SATIN ENAWEL a-80 FLAT PAINT ln5-111 HARDIG RUST SCAT INHIBITIVE PRIMER a513 DECO-REG EPOXY MASTIC #363 ALL PURPOSE GRAY PRIMER #393-10 MISURE CURED POLYURETHANE #4-37 ACRYLIC SEMI-GLOSS M-SONARY COATING a0-11 UHITE LATEX PRIMER #408 PORTER UHITE TRAFFIC PAINT #409 PORTER YELLW TRAFFIC 14302 MCR EPOXY BUCK: 4302-P1.A AND 4346-P1.B 14306 CRAY EPOXY: #43so-PART A A#) UW-PART B 1431 ALUIIW SPRAY, SE'I)(QR LUSTRE CHRo(E CLARK a310 WCR UHITE EPOXY: 4310-P1.A AWD 4316-P1.B 1435, -9, CLARK OR EQUAL GREEN SPRAY ENAMEL a361 HIGH WILD WITE 14372 RED EPOXY: 4372-P1.A 4346-P1.B 14374 MCR GLOSS POLWIDE YELLW: 4374-P1.A + 4347-P.B #49 UHITE SEMI-GLOSS ENAMEL 15001 RUST BLOCK ALLUlNM 1504 NLO LATEX LIGHT GREEN SEMI-GLOSS LnOSO PERMITE OR #7018-01 MIRROUC ALUMINUM FINISH a10 ILLINOIS BRONZE GLASS FROSTING #925-147 HARDIG WICK DRY RUST INDUST. INHIB. PRIMER -940 RED ENAMEL #965 HARDIG'S GREEN ENAMEL lOIp0 HARDIG'S WHITE RUBBER BASE CEMENT PAINT #07-36P VANILLA BEAN LATEX INTERIOR #S-128 TUF-N-HARD LIGHT GRAY POLYURETHANE ENAMEL m-943 BLACK #S-945 HARDIG'S WHITE 47 '. 52 Date: 05/18/87 P8ge: '10

UPOATE LIST Of ALL CHEMICAL MIXTURES PWCIu#D Fm 01/01/84 TO 05/18/87 528 chemical Mlxtv. category Na

...... B-969 MCHINERY PRIRR e-9n mw wry OIL PoLIUETIullf cI[R# YELLQY rlS-900 1150 PRIER 12-1 cORo(AD0 ACRYLIC WlTE SUI-6LOSS 6-11 CDlKMDO ACRYLIC PRIER AERo#K wc !PRAY BIN 3-PIR- PRIIIER/SEALER CARBOLINE 190 FD-COLOR GRAY C-a CARBOLINE THINNER 115 COLOR# 07-6P FREE SPIRIT, SEMI GLOSS CORONADO SEAL IT CRYSTAL CLEAR KRYLOW ACRYLIC SPRAY DRUn BLACK ENAMEL - WATER REDUCIBLE, CVC CODE 1 38295 DRUM BLACK ENAMEL CVC CaDE m884 DRLM CLEAR LINER DRUM RED ENAMEL DRUM RED ENAMEL - WATER REDUCIBLE, CVC CWE lr38363 DRUM WHITE ENAMEL . ENMEL - BROW FEEL FILMITE FREE SPIRT LATEX SEMI GLOSS COLOR 07-6P HARDICS lrs-941 ORANGE INTERIOR ACRYLIC SEMI GLOSS LATEX, ENAMEL (BEIGE) JAPAN DRYER LATEX BEIGE ENAMEL COLOR 23717 LATEX BRWN ENAMEL COLOR 20117 LATEX SEMI GLOSS (FREE SPRIT) LATEX SEMI-GLOSS WALL PAINT LATEX WHITE INTERIOR FLAT LATEX WITE INTERIOR SEMI-GLOSS LIGHT GREEN OIL BASE PAINT MAPLE STAIN - OIL MEK THINNER mism CURED URETHANE MOJAVE TAN URETHANE ALKYD SEMI-GLOSS EWL13-38 NO. 164 GREEN EXTERIOR ENAMEL OAK STAIN - OIL OIL BASE VOQ) PAINT PRIMER PENNATROL ENAMEL THINNER PERMA-BOID THINNER PLATINUI WHITE 1-31-3P INTERIOR WALL PORTER HIGH BUILD EPOXY (GRAY) PORTER HIGH BUILD EPOXY (WHITE) PORTER MC43 PRIMER PORTER U-PRIME PRIMER OR EWAL GRAY PORTER U-PRIME UNIVERSAL l282 WHITE PORTER WHITE TRAFFIC PORTER YELLW TRAFFIC WICK DRY ENAMEL (FRIED WSHROOO RUSTOLEUI, SURFA ETCH a SHERWIN WILLIAMS INTERIOR ALKYD EWAMEL,#W-39- 13 SHERWIN WILLIAMS INTERIOR ANTIQUE WHITE,XBC(-C1-8 42 - 53 Date: 05/16/87 P.0.: 11 UPOATE LIST OF ALL CHEMICAL MIXTURES RRCluSED fRo( 01/01/W TO 05/18/87 528 a Chcntcrl...... Wtxturo Catsgoy I- SHERWIN WILLIAMS, IWTERIOR, AwTl9lE WHITE !5HERWIN WILLINS, IITERIOR/EXIERIOR ALKYD EWL PINGLE PACKAGE EWL- PAMTOHE BLUE PUR-PREP IV WUCRETE ETCH 1-13 THINNER TARSET 1-3 THINNER 1-5 THINNER IURETHANE LT. GRAY VINYL-ACRYLIC MASTIC GREY CHILDERS CP-10 UALWT STAIN - OIL JHITE LATEX CEILING PAINT JHlTlNG ' KYLOL OR XYLENE THINNER ZYNOLYTE BLACK PVC AEROSOL PASTE, Y1113 SOLDER FLUX PASTE COLD WATER, PLAST 1 C WCO, DAP yo00 DOUGH (ALL COLORS) NATURAL I1 OR DAP DURATITE vo00 DOUGH POWER, ASCARITE (NOT LESS THAN 20-30 MESH) ASBESTOS MER CALClA STABILIZED ZIRCONIA PLASlU SPRAY POWER DC FILTROL DRY CLEANING GREEN GLO-RAY WER LECO M11-139 DlALLY PHTHLATE-COPPER FILLER PWDER ORANGE GLO-RAY mER POZZALIMETM CALCIC WER, POZULIME TYPE I VISOLITE GREEN FLUORESCEIN P/N 03500483 VISOLITE ORANGE FLUORESCEIN P/N 03500482 VISOLITE ORANGE FLUORESCEIN P/N 3500288 PRESERVATIVE, STEVENS WATER TANK PRESERVER PRINTING SOLON, 3M TYPE PLATE R PROCESS Gu)c . VARN INK READY VARN VSP 23 WASH VARN VSP-44 ROLLER DETERGENT VARN VSP-CEL DEGLAZER VARY-36 ALL PURPOSE FWUTAIN SOLUTION PVC, CEMENT TPI-R-4003 CLEANER TPI-R-6001 HEAVY WTY SOLVENT CEMENT PRIMER TPI -1-4002 PURPLE PRIMER PYROTRONICS, FIRE 6 -E DETECTOR SPRAY RADIONUCLIDES, COBALT-60 RADIOGRAPHIC SOURCE NP-237 OXIDE PLUTONILW TRACER SOLUTION IN M HMO3 58-125. EU-154, EU-155 IN 4M. HCL SOLUTION TC-99 SOLUTION TECHNETIW-99, SRM-4288 UF6 WITH A 23611 CONTENT OF 0.906 +/- 0.003 ZEACENT, AMINO ACID 804-99 e AnnONIA ELECTRWE FILLING SOLUTION, #13-641-928 CHLORIllE TlTRATlNG CODE 285 49 54 Date: 05/18/87 P.0.: 12 UPOATE LIST Of ALL CHEMICAL MIXTURES PCRCMSEO FRW Ol/Ol/W TO 05/16/87 526 chemical mixtwo category Nra,

...-...-I.--...... -...-I.--...... DPO FREE CHLORINE REAGENT #ILI)ER PILLWS F-CL MSRBENT FILLING 3oLuIloY FOR CALOQL REFERENCE ELEC1lKX)E I[Du-QIIo( STAIN foLUTlOW HF ELECTROLYTE lll0RANAL C#WZITE/5, CAT. 10. cc uBo5-1 HYDROGEN PEROXIDE SOLUIIW 3U% ACS SP. GR. IsoTOi II KARL FISCHER NITRAVER 5 NITRATE REAGENT NITRIVER 2 NITRITE REAGENT WERPILLOWS NOCHROHIX CRYSTALS, CAT. NO. 19040 SCWTZE REAGENT, CAT. NO. 761.747 SILVER CHLORIDE - LITHIlM FLWRIDE CARRIER SJCFAVER 4 SULFATE REAGENT REFRACTORY, PTB THERHO LlTH BATCH CHRCUE REFRACTORY SHEET PRODUCTS, ZIRCAR RESIN, AGSW-XO CATION EXCHANGE RESIN ANION EXCHANGE DOVEX COMMRCL. GRADE 1-X8, 100-200nESH ANION EXCHANGE RESIN AG1-X8, CAT.# 9991111-NI MIXED BED RESIN FOR DEMINERALIZER SALT, BULK ROCK SALT LIQUID CALCIUM CHLORIDE, DE-ICING AGENT NU-SAL HEAT TREATING (SODIUI CHL. + WTASS.CHLORIDE) SALT-AWAY SEALANT, DUXSEAL PUTTY TYPE COCIPWND LEAK-LOCK PIPE THREAD SEAL LocpUlC ACTIVATOR (707) . LOCTITE PIPE SEALANT Y. TEFLON LOCTITE PIPE SEALANT YITH TEFLON P/N 59231 LOCTITE RED A PERMATEX ill FAST DRYING PERMATEX #2 SLW DRYING PERMATEX HEAT RESISTANT SEALING CWWUND PERMATEX SPRAY A GASKET RECTORSEAL 115 PIPE SEALANT SILICONE RUBBER SEALANT (SILIUP) SUM, ANAEROBIC PIPE THREAD SEALANT SHELLAC, WHITE SHOE POLISH, BOTTLE LIQUID WAX HARD CAN WAX SOAP, DERCUWOTH SKIN CARE LOTION EXTRA FOAMING POWERED SOAP #02030 HAND SOAP U420C0550N KuTa COWPLYING WITH NLO s~~c.11~7WATERLESS HAND CLNR NLO SPEC #1134 STIGLER'S LIQUID HAND SOAP POWERED NLO SPEC 11133 DATED 1/21/69 RUBARS DUBOIS BAR SOAP SBS-CO MEDICATED SKIN CREN SEPTI-SOFT CWCENTRATE SODA ASH, ~ERCIALGRADE SOLDER BRAZE, SILVER #403 CADMIUM FREE 50 55 Date: 8/16/67 PIO.: 13

UPDATE LIST OF ALL EllOlICAL MIXTURES PURCHASED FW01/01/84 TO 05/18/67 526 a acllicrtMixturr Cat.- wrr .-.--..I.....-...... --...... -.--..I.....-...... --...... SOLDER FLUID, RUBY SQ#RIYG FLUID =DER FLUX, 3059 mya- COLDER NLX (FLUX-ALW HARDY SILVER J.Y. WRIS SILVER lJIC CERTWIUI ALLOY SOLDER 3060 STAYBRIGHT SILVER BEARING SOLDER 3100 %/5 =IO YIRE SOLDER 50/50 YIRE SULDER , SOLID WRE 60/40 TIN/LEAD ROSIN CURE SILVER ALLOY ERSIY FIVE WRE LMP SILVER, CADMIlW- FREE SOLVENT, ALL PURPOSE DEGREASER FORWLA 111 P/N C-2466 AND CLEANER FOR FWNTAIN BRUSH AND CLEANER FOR INK RHS BROOKS VERSALENE 650 CONTACT CLEANER - MILLER-STEPHEN- FREON "MS-190" DEGLAZINC SOLVENT, AM CAT.#83-4-788004 FLUSHING SOLVENT AH225 FOR CAST VACU)I WPS FREON TF =VENT, MS-180 HEAW DUTY QI(CRETE DEGREASER WULTILITH DEGlAZlNG P/N 83-7-788001 PERMATEX GASKET REMOVER SOLVENT STOODARD VARN FAST UASH WC-21 STANDARD, ALKALINITY STANDARD SOLUTIONS, NO. 1C27S-10 AMMONIA 150 MG/L CAT 12128410 AQUEOUS SPECTRCUETRIC SOLN. FOR ANTIMONY, ARSENIC, AQUEOUS SPECTROIETRIC #KN. FOR BA, CA, WG, SR BOO CAT #14&5-10 CALCIW STAy)ARD SOLUTION AS CACO3, 121-16 CARBOY DIOD(1DE STANDARD 400 HG/L CHLORINE TOTAL 50 WG/L CL2 CAT #14268-10 CHRCMIUI 12.5 MG/L CR6 CAT #14256-10 CHROIIW WUVALEWT 50 MG/L 810-14 COPPER 12.5 NG/L W2UT R1126-10 EP TOXICITY (-1 STAWARD FLORIDE STAY)- SOLWION 1.0 PPW AS F FLUWRIDE 10 P/N 302 COLD ATOIIC ABSORPTIOII a137 HEXAVALENT OIROWIW 12.5 MC/L NITRATE (NITROCEN) STANDARD SOLUTION 10 PPI( NO3 NITROGEN A)+CYIA 1 WC/L NITROCEN AWYIA 160 WC/L NITROCEN,YIT1UTE STANDARD SOL. 100OMG/L 12Tp2-11 ORTHO PHOPHATE LW RANGE 50 MG/L Po4 CAT11171-10 PHOSPHATE 30 ffi/L REFERANCE STAJfDARD SOLUTION FOR SULFATE REFERENCE !STMARD SOLUTION FOR ALWINLM REFERENCE STANDARD SOLUTION FOR MIUI 0 REFERENCE STAJiDARD SOLUTION FOR ANTIMONY REFERENCE STANDARD SOLUTIOW FOR ARSENIC REFERENCE SIAYDARD SOLUTION FOR EARIW 51 .- 56 Date: OW1487 Pw: 15

LJPDATE LIST W ALL CHEMICAL MIXTURES PURCHASED FRQ( 01/01/84 TO 05/18/87 528 0 Chedcal...... Mixtwo Catw N- SOLDER FLUID, RUY SOLDERING FLUID SOLDER FLLIX, 3059 STAY CLUT WLDER MX(FLLIX-ALUI) MYSILVER J.U. MRRIS SILVER #%E CERTAWIUI ALLOY SOLDER 3060 STAYBRIGHT SILVER EEARIYG #KDER 5100 95/5 =ID WIRE SOLDER 50/50 WIRE SOLDER , SOLID CORE 64/10 TIN/LW RQSII CORE SlLVER ALLOY ERSlI FIVE CORE UIP SILVER, CADHIW-FREE SOLVENT, ALL PURPOSE DEGREASER FORWLA 111 P/N E-2466 AND CLEANER FOR FWNTAIN BRUSH AND CLEANER FOR INK RMS 6RmS VERSALENE 650 CONTACT CLEANER - HILLER-STEPHENSON FREON WS- 190" DEGLAZING SOLVENT, An CAT.y83-4-788004 FLUSHING SOLVENT AH225 FOR CAST VACUM PLWPS FREON TF SOLVENT, HS-180 HEAW DUTY CONCRETE DECREASER WLTILITH DEGLAZING P/N 83-7-788001 PERMTEX GASKET REMOVER SOLVENT STOODARD VARN FAST UASH VK-21 STANDARD, ALKALINITY STANDARD SOLUTIONS, NO. 14278-10 MWlA 150 MG/L CAT 12128410 AWEOUS SPECTROWETRIC SOLN. FOR ANTIWNY, ARSENIC, AWEOUS SPECTROWETRIC SOLN. FOR BA, CA, MG, SR BOD CAT (114865-10 CALCIUn STANDARD SOLUTION AS CACO3, 121-16 CARBOW DIOXIDE STANDARD 400 HG/L CHLORINE TOTAL 50 ffi/L CL2 CAT (114268-10 CHROMIUI 12.5 ffi/L CR+6 CAT tl4256-10 CHROMIUl HEXAVALENT 50 MG/L 810-14 CUPPER 12.5 MG/L W+Z CAT 821126-10 EP TOXICITY (RCRA) STANDARD FLORIDE STANDARD SOLUTION 1.0 PPH AS F FLWURIDE 10 PPM P/I 302 GOLD ATOMIC ABSORPTIQI 64137 HEXAVALENT CHRCUIW 12.5 HG/L NITRATE (NITROGEN) STANDARD SOLUTION 10 PPH NO3 NITROGEN An)rOWIA 1 UG/L NITROGEN AMMONIA 160 MG/L NlTRffiEN,NITRATE STANDARD SOL. 1000nG/L 12792-11 ORTHO PHOPHATE LOU RANGE 50 MG/L PO4 CAT#171-10 PHOSPHATE 30 HG/L REFERANCE STANDARD SOLUTION FOR SULFATE REFERENCE STANDARD SOLUTION FOR ALWINLRI REFERENCE STANDARD SOCUTIOW FOR A191owllin REFERENCE STANDARD SOLUTION FOR ANTIWOWY REFERENCE STANDARD SOLUTION FOR ARSENIC REFERENCE STANDARD SOLUTION FOR BARIIM 52 - 57 Dater 05/18/87 Pw: 14

UPDATE LIST OF ALL CHENIUL MIXTURES PURCHASED FRQl 01/01/64~TO 05/18/87

0 Chemical Mixture Yr, ..I...... -...... I...... -...... REFERENQ STAY)- SQLUtION FOR BIOUlH REFEREYCL STAY)- #KUtION FOR SRQlIDE REFERENCE STAY)- SOLUTION FOR WlUI REFERENCE STWD- SOLUTION FOR CALCIUl REFERENCE STWD- SOLUTIO1 FOR CHLORIDE REFERENCE STWD- tOLUTION FOR CI(R0IIUI REFERENCE STAYDAW) SOLUTION FOR COBALT REFERENCE STA#)LuID SOLUTION FOR QIPPER REFERENCE STANDARD SOLUTION FOR LEAD REFERENCE STANDARD #KUTION FOR LlTHIUl REFERENCE STANDARD SOLUTION FOR WGNESIW REFERENCE STANDARD SOLUTION FOR I(ANGANESE REFERENCE STANDARD SOLUTION FOR MERCURY REFERENCE STANDARD SOLUTION FOR MOLYBDENW REFERENCE STANDARD SOLUTION FOR NICKEL REFERENCE STANDARD SOLUTION FOR NITRATE REFERENCE STANDARD SOLUTION FOR NITRATE REFERENCE STANDARD SOLUTION FOR OIL 6 GREASE REFERENCE STANDARD SOLUTION FOR PHOSPHATE REFERENCE STANDARD SOLUTION FOR POTASSIW REFERENCE STANDARD SOLUTION FOR SELENIW REFERENCE STANDARD SOLUTIOU FOR SILICON REFERENCE STANDARD SOLUTION FOR SILVER REFERENCE STANDARD SOLUTION FOR SOOIW REFERENCE STANDARD SOLUTION FOR STRONTIUI REFERENCE STANDARD SOLUTION FOR TIN REFERENCE STANDARD SOLUTION FOR TITANIW REFERENCE STANDARD SOLUTION FOR TRACE METALS REFERENCE STANDARD SOLUTION FOR VANADIUI REFERENCE STANDARD SOLUTION FOR ZINC WDIW CHLORIDE STANDARD SOLUTION, 183-11 SULFITE STANDARD SOLUTIONS (R2674-10/16 PK) TOTAL HARDUESS 10 C/L CAW CAT 82187-10 ZIRCOHIW ATCUIC ABSURPTIOW 22875 SURFACTANT, DETER MIcRo8OwD 1101OA SWEEPING COCIPUJND, CLEAN WEP WST-BAN 7977 WST COlTROL RED REWLAR VARNISH, FORMlLA ;I 1501 KNUR VARNISH KRYLON WATER TREATMENT, BETZ 11 10 POLY - FLOC BETZ 2020 BETZ 2040 BET2 CORROCEN BET2 NEUTRAMEEN NA-9 BET2 PERMACOL BET2 POLYMER 1110 BETZ POLYMER 1117 D - TAC DEPRESS 11Y DUBOIS MlR DUSHIELD - 125 DUCIDE 20 53 ,. 58 Date: 05/18/87 Pa#.: 1s

UPDATE LIST OF ALL CHEMICAL M1mES PURCHASED CRol 01/01/64 TO 05/18/87

Cheaical Mlxturr Category NW

.....__...... I...... __...... I...... FERIKISPLRSE WATHERPROOFING, tADALOW BlACIC UELD m, 1 6011 11 CHAMFEATRODE foR MTING STAINLESS STEEL a233 XWER MECTIC nro S.S. SLD RQ) n16 S.S. UELDING RQ) n17 ELC 5.3. MELD 17018 LINCOLN COATED SLDIIC RQ) 2% THORIA CENTERLESS GROUND TWGSTEN ELECTRODE 6010 B.I. REVERSE POLARITY FLEETMELD SP CERTAINIW COATED WELD RODS 1307SP CLASS E6012 011 6013 STEEL, FLUX COATED EUTECTIC CASTOLIN 12233 CAST IRON WELDING ROD EUTECTIC CASTOLIN, x680 COATED EUTECTIC CHMFERTRODE FLEETUELD 1180 MILD STEEL (LINCOLN) FLEETWELD #35 MILD STEEL UELDING ROD HASTELLOY "CH ELECTRODE HI TEST STEEL INCO-ROD J.U. HARRIS 125-M BROUZE MGNESIW TYPE, A292A, WELD ROD OXWELD 125-M BRONZE STAINLESS STEEL 316 STAINLESS STEEL AB-308-16 ELC TITANIA COATED STAINLESS STEEL AB-316'-16 TITANIA COATED STAINLESS STEEL AM-1-547-16 TITANIW COATED STELLITE 116 STULZ MANGANESE XL COATED TITANIA COATED STAINLESS STEEL ELECTRGOE TYPE ALUWINW TYPE ERtO S-6 TYPE INCONEL A UELDlNt ROD -EL 190

54 - 59 APPENDIX IV

Label and Rating Criteria

55 60 FMPC HAZARD WARNING LABEL

SPECIAL .

56 61 528

The following criteria are guidelines only. Professional judgement and the unique characteristics of each chemical must be considered when assigning hazard ratings. In general, a "4" Health hazard rating is reserved for materials which cause immediate & severe health effects, are normally a gas, or is a liquid material which readily penetrates the skin, and/or are known human carcinogens. This criteria takes precedent over other data and may reduce some materials with low TLV's, for example, to only a "3" health hazard rating. In no case will the ratings be less than those listed by the current NFPA 704-M System. Questions concerning the rating of materials should be addressed to Industrial Hygiene at 6816.

57 62 TABLE V-1 528

RELATIVE TOXICITY RATING FOR HAZARDOUS MATERIALS (Human Exposure by Any Route)

Rating Key Words Acute Chronic (Single Exposure, (Repeated Exposure) immediate or delayed effects)

4 EXTREME HEALTH HAZARD Death Death*

3 HIGH HEALTH HAZARD Major temporary or Major permanent injury permanent injury (Includes mutagens May threaten life and teratogens)

2 MODERATE HEALTH HAZARD Minor temporary or Minor temporary or permanent injury** permanent injury (Includes nonlife (Includes skin threatening sub- carcinogens) stances which sensitize the majority of exposed workers)

1 SLIGHT HEALTH HAZARD ' Minor injury Minor injury readily reversible** readily reversible

0 NO SIGNIFICANT Materials which produce toxic effects only HEALTH HAZARD . under the most unusual conditions or by overwhelming dosage.

*Includes substances which bear a significant relationship to the development of cancer in man, but excluding the common varieties of skin cancer. **Allergens are rated according to their sensitizing potential rather than the severity of an allergic reaction upon reexposure to a substance by a sensitized worker.

58 - 63 526

TABLE V-2

RELATIVE ACUTE TOXICITY CRITERIA *

Rating Key Words LD50 Single* LC50 Inhalation* LD5O-Skin* Oral Dose: Vapor Exposure: Rabbits : Rats mg/kg Rats ppm mg/kg less than less than less than or equal to or equal to or equal to

4 EXTREMELY 1 10 .5 HAZARDOUS

3 HIGHLY 50 100 43 HAZARDOUS

2 MODERATELY 500 1,000 340 HAZARDOUS

1 SLIGHTLY ~ 5,000 10,000 2,800 HAZARDOUS

0 NO SIGNIFICANT 5,000 10,000 2,800 ...... HAZARD or greater or greater or greater * See Appendix I11 for the source of these data and test methods.

'- 64 52s

RELATIVE HEALTH HAZARD CRITERIA BASED ON TLV'S

Ratinq Common Term PPM mq/m3 4 Extreme Health Hazard <1 (0.25

3 High Health Hazard 2 - 10 0.26 - 2.5

2 Moderate Health Hazard 11 - 250 2.57 - 5.0

1 S1 ight Health Hazard. 251 - 1000 5.1 - 10.0

0 No Significant Health Hazard > 1000 > 10

60 65 526

325M-8 PYOPERTICS OF FLAMMABLE LIQUIDS. GASES, SOLIDS around legs, arms and waist should be provided. Materials which (in thcmrclves) are normally No skin surface should be exposed. unstable and readily undergo violent chemical 2 Materials hazardous to health. but areas may be change but do not detonate. lncludtr materials entered freely with full-faced mask self.contained which can undergo chemical change with rapid breathing apparatus which provider eye protection. release of energy at normal temperatures and 1 Materials only slightly hazardous to health. It may pressures or which can undergo violent chemical be desirable to wear self-contained breathing ap- change at elevated temperatura and .prcsures. paratus. Also includes those materials which may reaci violently with water or which may form potentially 0 Materials which on exposure under fire conditions explosive mixtures with water. In advanced or would offer no hazard beyond that of ordinary massive fires. fire fighting should be done from a combustible material. dedistance or from a protected location. Materials which (in themselves) arc normally stable Flammability. but which may become unstable at clevatcd tcm. peraturer and pressures or which may react with Susceptibility to burning is the basis for assigning water with some release of energy but not violcntly. degrees within chis category. The method of attacking the Caution must be wdin approaching the fire and fire is influenced by this sweptibility factor. For further applying water. information on this subject. refer to the column on “Er. Materials which (in themselves) are normally stable tinguishing Method” and to iu explanation on pages 5 even under fire exposure conditions and which are and 6. not reactive with water. Normal fire fighting procedures may be wd. Very flammable gases or very volatile flammable liquids. Shut off flow and keep cooling water streams on expod tanks or containers. Additional Markings. Materials which can be ignited under almost all A fourth space in the identification symbol is reserved normal temperature conditions. Water may be infor additional information when such may be of value to effective becaw of the low flash poim. the fire fighter. For example, any material which will Materials which must be moderately heated before react violently with water should carry the symbol *to ignition will occur. Water spray may be used to ex. indicate “avoid w of water.” Radioactivity could be tinguish the fire because the material can be cooled identified in this space as well as special information con. below its flash point. tained within the “Extinguishing Method” column. Materials which porvrr oxidizing properties can be iden- Materials that must be preheated before ignition tified by the letters OX. can occur. Water may caw frothing if it gets below the surface of the liquid and iurnr to steam. Hazardous Chernicab Data However, water fog gently applied to the surface will cause a frothing which will extinguish the fire. In various paru of chis tabulation references will be Materials that will not burn. found to the Hazardow ChcmicaL Dora. This material is published in the Narionol Frre Codes@ and is also available in pamphlet form from the National Fire Reactivity (Stability). Prevention Asociation (NFPA 49). The assignment of degrm in the reactivity category is Oxygen - Mixtura based upon the sweptibility of materials to release energy either by thcmlvcs or in combination with water. The values in this Table, except where otherwise in. Fire exposure was one of the factors considered along dicated. arc based upon ex rimenu in normal air. In with conditions of shock and pressure. oxygen the values may be Gferent and an incrcav in 4 Materials which (in thcmlvn) are readily capable hazard is probable. Mixturn of two or more flammable of detonation or of explosive decomposition or ex- materials may have properties different from their come plosive reaction at normal temperatures and ponenu. In the cuc of mixtures it is common practice to prerrures. Includes materials which arc unsitivc to base precautions on the properties of the more hazardous mechanical or localized thermal shock. If a component. chemical with this hazard rating is in an advanced or massive fire, the area should be evacuated. Muu and Froths f Materials which (in thcmulves) arc capable of In finely divided form such as a mist or spray. liquids detonation or of cxplmiw decomposition or of ex- can be ignited at temperatures below their flash poinu. pIm+e reaction but which require a strong in- As in the cuc of vapors a minimum concentration of itiating source or which mwt be heated under dropleu must be preunt to support combustion. Froths confinement before initiation. Includes materials also may be ignited below flash point temperatures. which are sensitive to thermal or mechanical shock ai elevated temperatures and pressures or which Indexing react explosively with water without requiring heat or confinement. Fire fighting should be done from The chemicals in the Table are listed alphabetically. an cxplmion~reristantlocation. Data for a chemical is listed under the name considered

61 66 526

62 67 APPENDIX V

Responsibilities for Implementing the Hazard Communication Standard

63 68 526

64 69 65 525

I: H 0 c

66 - 71 67 72 ’ 526

68 - 73 I I

69 - 74 70 75 526

71 526

APPENDIX VI

' Material Safety Data Sheet Request Form

72 77 MATERIAL SAFETY DATA SHEET REQUEST FORH 525

NAME OF MATERIAL AS IT APPEARS ON THE ONTAINEB:

ANY MANUFACIWEE?S INFORMATION SUCH AS NAME, ADDRESS, CODES, R.

APPROXIMATE QUANTITY AND 03NTAfNER TYPE

WKX SrOREs CATALOG # IF AVAILABLE

LOCATION hHERE HATERIAL IS SKlRED OR USED: BE.##

SUPERVISOR FOR THIS AREA:

TODAYS DATE

SEND CXXPL,ETED MSDS RnQuEsr FORM TO THE INDUSTRIAL HYGIPCE GROUP - FOR INDUSTRIAL HYGIENE USE -

DATE VvRYI'E OR CONTACTED COMPANY DATE MSDS RECEIVED

DATE CONTACTED SUPERVISOR DATE HSDS SENT rn wm AREA a 78 73 APPENDIX VI1

Material Safety Data Sheet Plant Locations

74 -. 79 MATERIAL SAFETY DATA SHEETS 526

PLANT LOCATIONS

# AREA LOCATION RESPONSIBLE PERSON

1 CARPENTRY SHOP SUPERVISORS OFFICE P.H. RAAB 2 TECH. LAB BLDG. OFFICE E.S. CULVER 3 PLANT 1 PLANT 1 OFFICE R.C. DICKEN 4 PLANT 2/3 PLANT 2/3 OFFICE T.N. HUEY 5 PLANT 4, TANK FARM PLANT 4, 2nd FLOOR OFFICE R.J. PERKINS 6 PLANT 5 PLANT 5 SHIFT SUP'S OFFICE ' SHIFT SUP'S 7 PLANT 6 PLANT 6 OFFICE K.M. INMAN 8 PLANT 8 PLANT 8 OFFICE T.N. HUEY 9 PLANT 9 PLANT 9 SUP. OFFICE H. COLE 10 PILOT PLANT PILOT PLANT OFFICE R.J. HIESTAND 11 MECHANICAL, BLDG. 12 OFF ICE M.V. CARLE 12 BOILER, WATER TRT. BOILER PLANT DESK L . PENN INGTON 13 ES&H/ADMINISTRATION IH OFFICE #53-8 G.J. FOLTZ 14 SERV ICES/LAUNDRY LAUNDRY AREA C.J. MIZE 15 PAINT SHOP SUPERVISORS OFFICE P.H. RAAB 16 PIPE SHOP SUPERVISORS OFFICE P.C. HARSH 17 WELDING SHOP SUPERVISORS OFFICE R.L. YOUNG 18 SCALE AND INSTR. SHOP SUPERVISORS OFFICE H.J. EBBING 0 19 DECONTAMINATION BLDG. 69 OFFICE T.L. KLEIN 20 EMERGENCY BRIGADE FIRE INSP. OFFICE G.J. JONES 2 1 REC E IV ING/STORES RECEIVING STORAGE AREA J.E. ALLEN 22 PLANT 4, TANK FARM, MAINT. PLANT 4 MAINT. OFFICE D.A. MOORE 23 TANK FARM TANK FARM OFFICE R.J. PERKINS

75 528

APPENDIX VI11

Initial Training Topics

76 81 HAZARD COMMUN ICAT ION STANDARD 526 a Studies show that one of every four workers in the.U.S. is exposed to hazardous chemicals on the job. If used properly, most of these chemicals are harmless. In order to keep worker exposures to hazardous chemcials to a minimum, OSHA has requested that all chemical and manufacturing companies participate in a Hazard Communication Program. The objectives of this program are out1 ined in the Federal OSHA Hazard Communication Standard.

IMPORTANT PROVISIONS OF THE HAZARD COMMUNICATION STANDARD

A. Hazard Evaluation OSHA has called for all chemicals and mixtures to be evaluated for potential hazards. Chemical producers or importers have the primary responsibility for evaluating whether a chemical is a potential health hazard (e.g., carcinogen, irritant, or sensitizer), or a physical hazard (explosive or flammable substance). If a sutdy reveals a connection between a chemical and a harmful health effect, the chemical is to be regarded as a potential health hazard. Procedures that are used to determine a chemical’s potential hazard will be written and made available to workers upon request. B. Warning Label s 0 Labels should be placed on all containers of substances that are potentially hazardous. Chemical producers or importers will label containers before they leave the facility for transport. This warning label should include the identity of the chemical, hazard warnings, and the name and address of the producer/importer. If a chemical is transferred from its original container to another, this new container must also be properly labeled. C. Material Safety Data Sheets (MSDSl. Material Safety Data Sheets (MSDS) provide a source of health and safety information on hazardous chemicals for workers. These sheets will be supplied by the chemical producer. The information’on the MSDS includes any potential health hazards related to the use of the chemical, precautions for use, hand1 ing, and storage, and emergency procedures for leaks, spills, and fires. Also included is specific information on the chemical and physical properties of the substance. MSDS will be kept on file in the work place and will be available to workers.

77 82 HAZARD COMMUNICATION STANDARDS (continued) 528

9 D. Training Companies will provide training and information to all workers who are involved in any operations where hazardous substances are present. This training includes such topics as methods to use in the detection of hazardous chemicals in the work environment, physical and health hazards of the chemical, and protective measures to take against these hazards. The company will also provide information as to the location and availability of the Written Hazard Communication Program. E. Written Proqram A Written Hazard Communication Program will be provided by the company and made available to workers upon request. This program will include a list of all hazardous chemicals known to be at the facility, a plan to ensure all containers of hazardous materials are labeled, the location of the MSOS file, and details on the worker training and information program.

' 83 78 INTRODUCTION TO CHEMICAL SAFETY 525

This audiovisual program presents a general introduction to chemical safety in the workplace. The program is designed to encourage employe awareness and understanding of the kinds of hazards that can result from working with chemical processes. Among the points covered in the program are health hazards posed by chemicals, safe handling of materials, safe work practices, proper use and storage, safety information contained on warning labels and Material Safety Data Sheets (MSDS), personal protective equipment, and emergency response procedures. Emphasis is placed, in this videotape, on the three states of matter (solids, liquids, and gases) since this provides a method of reviewing problems associated with the containment of chemical substances. Knowledge of the states of matter can be of benefit when transporting chemicals from one location to another. Also, this concept helps employes to focus attention on the different routes of exposure. The various routes of entry through which chemicals can come in contact with the body are reviewed. These routes include direct contact with the skin, accidental swallowing, and inhalation. The signs and symptoms experienced from exposure to a hazardous chemical can vary, depending on the type of chemical and its entry route into the body. Labels are used to identify the contents of chemical containers. The OSHA standard requires that, in addition to the chemical identity, the label must provide hazard warnings and the name and address of the manufacturer. The OSHA standard also requires that chemical manufacturers and importers obtain or develop MSDS for each hazardous chemical that they produce or import. Various types of personal protective equipment are discussed and their usage depends on the severity of the hazard.

79 84 APPENDIX IX

Specific Chemical Category Topics

80 85 OX ID IZERS 526

0 Oxidation is the reaction of a material with oxygen. Some common oxidation reactions which involve our atmospheric oxygen are respiration, combustion , and slow oxidation processes like rusting.

Oxidizers are substances that release oxygen as they react and therefore pt-ovide a self-contained source of energy to fuel the reaction. Some . oxidizers contain no oxygen (e.g., chlorine). This property is important in promoting usefule chemical reactions, but can also be a hazard source. Oxidizers are very reactive compounds; the kinds of reactions that can occur depend upon the other reactants with which they contact and upon the reaction conditions. When oxidizers combine with combustible materials, they will burn f iet-cely. Contact between some materials can result in spontaneous combustion. Oxidizers may cause immediate combustion or explosion with extremely reactive substances. Organic peroxides are a special class of oxidizers, and when involved in fire, they react violently.

Oxidizers are defined as a safety hazard due to the fire and explosion potential either from the compound itself or from the reaction with other materials. Many oxidizers are health hazards and have been identified as being carcinogens, corrosives, toxins, irritants, sensitizers, and substances affecting target organs. The information about the health hazard of a chemical compound should be indicated on the hazard label and on the Material Safety Data Sheet (MSDS). The safe handling and use of oxidizers should be based upon no physical contact with them and if there is a probability of contact, an analysis for the routes of'entry (e.g.,.inhalation, reaction with mucous tissues) is needed. The use of protective gear should be discussed with the employees. Since oxidizers react with most other chemicals, it is important to make sure the storage containers do not leak and that they are stored away from materials with which they could react.

Planning and training for emergency response procedures should be conducted before an emergency occurs. Oxidizers involved in fires can react with explosive violence. It is important to remember that these compounds can react with other chemicals and release toxic vapors, causing a fire or explosion.

81 - 86 PO I SONS 525 0 Poisons are substances that may cause death or serious injury-- if swallowed, inhaled,'or if they come in contact with the skin. The degree of hazard posed by a poison depends on its physiological action, its route of attack, and its

reactivity in addition to the concentration of the chemcial and the duration ' of exposure. A wide range of physiological effects is possible when exposed to poisons. For example, they can interfere with the oxygen distribution system of the body, paralyze muscles, and affect nervous system activity.

A toxic substance is defined by its effects on test animals. The two major categories for health hazards, as defined by the OSHA standard, are "highly toxic materials" and ''toxic materials." Each of these categories is discussed in the videotape. Irritants and sensitizers are also classified as health hazards by the OSHA standard. Although irritants are not corrosive, they will cause a reversible inflammatory effect on living tissue by chemical action at the site of contact. Repeated contact with a sensitizer can result in the development of an allergic reaction in normal tissue. Because poisions are specific in their harmful effects, it is necessary to ensure that'they are properly contained and labeled. It is important to make sure the containers do not leak and that they are stored away from materials that could degrade them. Safe handling of poisons should be based upon the elimination of human contact with them. If there is a probability of contact, an analysis of body entry routes is needed. The hazards-of toxic vapor inhalation and reaction with or absorption through the skin may exist. The need for protective equipment should also be discussed with employes. a P1 anning and training for emergency response procedures should be conducted before the emergency occurs. It is necessary to be familiar with emergency response procedures for individual chemicals before accidents occur. These procedures will be given on the Materials Safety Data Sheet (MSDS) for the speci f i c chemical compound.

82 -' 87 CORROSIVES 526 Corrosives are chemical compounds that destroy the structural integrity of other materials. Some corrosive materials can eat'away metals, others cause severe injury and death to living tissue. The name or structure of a chemical alone is not sufficient to identify a substance as a corrosive. For example. strong acids are corrosives, but not all acids are corrosives. Boric acid, for example, is used as an eyewash. If a substance is defined as a corrosive, this will be recorded on the warning labels and on the Material Safety Data Sheet (MSDS). Some corrosives are extremely dangerous and can cause skin destruction in less than three minutes after exposure. Others are regarded as presenting a medium hazard if they cause skin destruction within three to 60 minutes after exposure. Other corrosives are regarded as presenting a minor degree of hazard. The degree of hazard or damage a corrosive can inflict is dependent upon its reactivity, the concentration of the chemical, and the duration of exposure. . Corrosives can present multiple threats to humans. Some can be hazardous not only as corrosives, but are toxic a1 so through inhalation and skin absorption. They can react with other chemicals, causing an increased hazard situation. Some may decompose at high temperatures and release toxic gases or react with water or moisture in the air and release hazardous substances. Certain corrosives are also flammable liquids or oxidizing materials. Because corrosives are so reactive, their containers must be made of materials that cannot corrode. It is important to make sure that corrosives do not leak and that they are stored away from materials with which they could react violently. The safe handling and use of corrosives should be based upon avoiding contact with them. If there is a possibility of contact, the chemical should be analyzed for any vapor inhalation hazards or reaction with mucous tissues. Protective equipment must a1 so be used when hand1 ing corrosives. In emergency situations involving corrosives, immediate action is essential because the longer the contact, the greater the damage to body tissues. Planning and training for emergency response procedures should be conducted before the emergency occurs.

a3 - 88 SOLVENTS 525 Although no single chemical class can be defined as a solvent, it is natural to consider solvents as a group because of their common characteristics for handling, use, and storage. Because solvents are used to dissolve other materials, they are used as cleaning fluids, for degresing agents, and for extracting soluble materials from raw materials. Solvents are also important in chemical processing, and many different types are used in industry. Water is the most common solvent; it dissolves a wide range of substances. Many solvents are flammable liquids and, as such, they present a safety hazard. Because vapors may form combust i bl e or explosive atmospheres , precautions must be taken to eliminate electrical sparks or other forms or ignition. The storage area for solvents should be constructed of fireproof materials and designed to contain fire. Solvents should be stored away from other chemicals (e.g. oxidizers) with which they could react. In addition to safety hazards, solvents can pose any of the health hazards identified in the OSHA Standard. These include carcinogens, corrosives, highly toxic substances, irritants, sensitizers, toxic substances, and compounds with target organ effects. All substances posing one of these health hazards should have a warning label, and information will also be avi a1 able on the Materials Safety Data Sheet (MSDS). Because almost all organic solvents, if inhaled, will have an anesthetic effect leading to wooziness, sleepiness, or unconsciousness, adequate ventilation must be provided in work areas where solvents are used. Chemical contact with the skin should be avoided because solvents remove the protective 0 oils in the skin, and some are capable of penetrating the,skin. Exposure to many of the solvents can result in systemic or target-organ damage, particularly to the liver and blood-forming organs. The use of protective equipment should be djscussed with all employes working with solvents.

84 A 89 GASES

A gas is a physical state of matter that tends to fil the available space. If it is confined in a container, it will expand to f 11 the total container: if it is free in the air, it will diffuse to fill the confining space, such as a room or building. Gases can pose the same physical hazards associated with materials which are kept at high pressure or are read ly flammable. Gases can be liquified by subjecting them to higher pressure or by lowering their temperature. The ease with which this can be done depends on the molecular weight and the chemical structure of the material. The health hazards identified by the OSHA Hazard Communication Standard are carcinogens, corrosives, toxins, irritants, sensitizers, and substances affecting target organs. If a gaseous'substance presents one of these health hazards, the OSHA Standard requires this to be listed on the hazard label and on the Material Safety Data Sheet (MSDS). When a substance is in a gaseous state, the exposure hazard automatically is increased because of the greater possibility of inhalation and of eye and skin contact. Many gases are heavier than air, and, therefore, they will form layers at the lowest level they can reach. Concentrations at the floor level or in equipment wells may reach high levels. Inert or non-toxic gases can displace air and collect in concentrations which can be suffocating. Working with pressurized substances can present problems-if care is not exercised. Leakage of flammable gases can result in the formation of explosive atmospheres; therefore, precautions should be taken to eliminate static or electrical sparks in the work place. Flammable gases should be stored away from combustible materials, oxidizers, and explosives. Planning and training.for emergency response procedures should be conducted before an emergency occurs. There are recommended general actions, including removing employes from the contamination source and diluting the compounds. Other emergency response measures inculde isolating and containing the gaseous materials. A special cleanup may be required because it may be unsafe to vent the hazardous gases to the atmosphere.

85 - 90 EXPLOS I VES 528 e An explosive is a chemical compound or mixture of compounds which suddenly undergoes a rapid chemical transformation with the simultaneous production of large quanitites of heat and gases. Explosive reactions can be initiated by ignition or shock. The severity of the reaction depends upon the specific compound and upon the conditions present. In addition to the actual hazards of an explosion, there is a hazard of explosive conditions in the work place. Concentrations of vapor from flammable substances may build up to form combustible or explosive atmospheres. There is a lower concentration limit called the lower explosion limit (LEL) which must be reached before the mixture becomes explosive. There is also an upper explosion concentration, called the upper explosion limit (UEL). This upper concentration denotes the level where the mixture becomes too fuel-rich to burn (not a significant consideration in a safety program). Although mixtures of gases and vapors with air are t,he prinicipal hazards associated with fire and explosion, explosive mixtures can also be formed with dust particles. Flour mills have a serious problem controlling airborne particles in order to reduce the risk of dust explosions. The use of chemical equipment can also pose explosive hazards; for example, pressure can build up in pumping operations or in distillation columns and cause an explosion. Also, many chemical reactions result in a release of heat; the heat will, in turn, accelerate the reaction which eventually may cause an explosive blast. The primary hazard posed by explosives is the physical one of detonation. Some explosive compounds have additional health risks (e.g., nitroglycerin and 0 dinitrophenol are toxic). Hazard warning information must be available on container labels and on the Material Safety Data Sheet (MSDS). When working with explosives, it is essential to have a good fire prevention program. Areas where explosives are handled and stored must be free of ignition sources. Non-sparking tools must be used and electrical circuits must be safeguarded against short circuits and sparking. Routine personal equipment is not likely to be effective against an explosion, but will be required in fire-fighting operations or in toxic atmospheres.

86 ' 91 CARCINOGENS 525 Carcinogens are chemical substances that cause cancer or are suspected as 0 causing cancer as defined by OSHA. According to the OSHA standard, a chemical compound is considered to be a carcinogen if it has been (1) evaluated by the International Agency for Research on Cancer and found to be a carcinogen or potential carcinogen, (2) listed in the Annual Report on Carcinoqens published by the National Toxicology Program as a carcinogen or potential carcinogen, or (3) regulated by OSHA as a carcinogen. Cancerous body cells start reproducing and continue to do so out of control, leading to the formation of tumors. The causes of cancer are not definitely known, although many of them are thought to be attributable to lifestyle or environmental factors. Exposure to some compounds is correlated with cancer development. There is a broad range of effects which are dependent upon the dose levels and the duration of exposure. The problem of cancer initiation is extremely complex because the causes are uncertain and include a combination of factors, for example, individual susceptibility. In addition, some cancers may not become active for twenty years or more, so it is difficult to trace the cause to the effect. In some cases, correlations have been shown to exist between exposure to certain chemicals and the occurence of cancer in particular organs. The liver, which is the body’s principal detoxification organ, is particularily susceptible. According to the OSHA standard, if a carcinogen effects target organs, this fact must be noted on hazard warning labels and on Material 0 Safety Data Sheets (MSDS). A mandatory system of controls has been establ ished for regulated substances. Some of these provisipns are reviewed in the videotape (e.g., establishment of a controlled area for any work environment where carcinogens are processed, used, handled, or stored). Further measures, such as the use of personal protective clothing and equipment, may be required. It is important to remember that carcinogens should be stored away from other materials and access to them should be s t ri ct1 y control 1 ed.

87 92 APPENDIX X

Supervisor's Training Form

88 - 93 528 HAZARD COMMUNICATION STANDARD TRAINING REQUIREMENTS RECORD

Employee's Name Badge #

Job Title Dept. Name

Initial Hire Date Date Started hrk In This Job. month/ year month/day/year

Training For Employees hho May Be Exposed To Hazardous Chemicals Under Normal Operating Conditions or Foreseeable Emergencies

1. Employee knows the location of the MSDS for his/her work area.

2. Employee knows any operation, process, or piping in hisher work area where hazardous materials are present.

3. Employee knows emergency procedures in case of exposure or release of a hazardous material in his/her work area.

4. Employee knows to ask hidher supervisor if any questions arise concerning hazardous materials or conditions.

5. Employee has reviewed MSDS on the following materials: e

Employee initial Date Supervisor initial

Instructions: 1. This form must be completed by the supervisor for all new employees, transferees, and all current employees.

2. This form must be completed by the supervisor for each employee whenever a new hazardous material that requires some type of control, ie. ventilation or use of a respirator, is introduced into the employee's work area.

. .. cc: 1. Industrial Hygiene 94 2. Supervisor 89