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JD 2008

2. Definitions and Methods

2.1 ROCK PHYSICS DEFINITIONS Volumetrics: , Porosity, Saturation

3D of sandstone (left) and a sandstone thin section (right). The pore space is blue due to epoxy that impregnated the samples.

Equations for density, porosity, and saturation

Bulk Density ρBulk = MTotal /VTotal

Total Porosity φTotal = VPore /VTotal ≡ φ M is mass Saturation SFluid = VFluid /VPore V is volume

SWater + SOil + SGas =1

Bulk Density ρBulk = (1− φ)ρSolid + φρFluid =

(1− φ)ρSolid + φ(SWater ρWater + SOil ρOil + SGasρGas )

Porosity strongly depends on the scale of measurement because rock is € heterogeneous at all scales.

1 Porosity .5

0 Radius

2.2 ROCK PHYSICS DEFINITIONS Velocity

2.3 ROCK PHYSICS BASICS Normal Reflection

1200 (ms) 1300 Time A reflection seismogram is a superposition of 1400

Travel signals reflected from interfaces between earth

1500 layers of different elastic properties.

1600 It is useful, therefore, to examine reflection at a single interface between two elastic half-spaces. 1700

1800

1900

2000

Two important elastic parameters that affect reflection are derived from velocity and density. They are the acoustic (or P-) impedance Ip and Poisson’s ratio ν

1 (V / V )2 − 2 I = ρV ν = p s p p 2 (V / V )2 1 p s −

Normal Incidence. The reflection amplitude of a normal-incidence P-wave at the interface between two infinite half-spaces depends on the difference between the impedances of the half-spaces. The same law applies to S-wave reflection.

Normal Reflection R I − I dI 1 R(0) = p2 p1 = p = d ln I I I 2I 2 p p2 + p1 p T Zoeppritz (1919)

Normal reflection forms a full differential. Therefore, it can be integrated to arrive at the absolute values of P-wave impedance. This procedure is called impedance inversion.

2.4 ROCK PHYSICS BASICS Reflection at an Angle

The reflection amplitude of a wave propagating at an angle to an interface not only depends on the P-wave elastic properties of the half-spaces but also on the S-wave properties. The rigorous Zoeppritz equations can be linearized to express the reflected amplitude through the P-wave impedance and Poisson’s ratio difference.

Incident Reflected P-Wave S-Wave Reflected P-Wave

Φ1 Θ1

Θ2 Transmitted P-Wave Zoeppritz (1919) Φ2

Transmitted S-Wave

A possible simplification for AVO computation. There are many other approximate expressions for reflection at an angle.

1 R(θ) ≈ R(0)cos2 θ + d( )sin2 θ 1−ν

The exact Zoeppritz equations do not form a full differential. However, their various linearizations do. As€ a result, these full differentials can be integrated to arrive at a quantity that is called the elastic impedance. It is important to remember that in most cases, the units of the elastic impedance are not the same as of the acoustic impedance.

The equation below may serve as a definition of the elastic impedance Ie.

Def 1 1 R(θ) ≡ dlnI ≈ R(0)cos2 θ + d( )sin2 θ = 2 e 1−ν 1 1 1 dlnI + d( − lnI )sin2 θ 2 p 1−ν 2 p 2 ⇒ lnI = lnI + ( − lnI )sin2 θ e p 1−ν p

Parameters commonly used to characterize reflection at an angle are intercept and gradient. € lnI 1 lnI R(θ) ≈ d( p ) + d( − p ) sin2 θ 2 1−ν 2 Intercept Gradient 2.5

€ ROCK PHYSICS BASICS Reflection at an Angle

A convenient approximation for reflection at an angle belongs to Hilterman (1989). It assumes that, on average, Poisson's ratio is 1/3.

R(θ) ≈ R(0)cos2 θ + 2.25Δν sin2 θ

It follows from this approximation that if the change in Poisson's ratio is negative, the amplitude€ should decrease with offset. This is what happens between shale and sand. Depending on the rock properties, 3 AVO classes have been defined.

Zoeppritz P-wave reflection coefficients for a shale over gas sand interface for a range of normal reflectivity values. The Poisson’s ratio and density were assumed to be 0.38 and 2.4 g/cc for shale and 0.15 and 2.0 g/cc for gas sand (from Rutherford and Williams, 1989).

2.6 ROCK PHYSICS BASICS Relative Impedance Inversion

2 2 Rpp (θ) ≈ Rpp (0) cos θ + 2.25Δν sin θ 2 ≈ Rpp (0) + [2.25Δν − Rpp (0)]sin θ,

I p 2 − I p1 dI p 1 Rpp (0) = = = d ln I p , I p 2 + I p1 2I p 2

I exp[2 R (0)dz]. p = ∫ pp

R (θ )− R (0) cos2 θ Δν = pp pp , 2.25sin 2 θ R (θ )− R (0) cos2 θ ν = pp pp dz. ∫ 2.25sin 2 θ

€ 2.7 ROCK PHYSICS BASICS Relative Impedance Example

Relative seismically-derived impedance and Poisson's ratio do not provide the absolute values of these elastic constants. However, they are often useful in obtaining spatial shapes of impedance and Poisson's ratio. 2.8 ROCK PHYSICS BASICS and strain. Forces acting within a mechanical body are mathematically characterized by the stress tensor which is a 3x3 matrix. By using a stress tensor we can find the vector of traction acting on an elemental plane of any orientation within the body (figure on the left). The within the body is characterized by the strain tensor. This tensor is formed by the derivatives of the components of the displacement of a material point in the body (figure on the right).

Stress Tensor Strain Tensor x1 x1 n T u

x2 x2

1 ∂ui ∂u j Ti = σ ijn j ε = ( + ) ij 2 x x x3 x3 ∂ j ∂ i

Both stress and strain tensors are symmetrical matrices. i j; i j. σ ij = σ ji ≠ εij = ε ji ≠ Hooke’s law relates stress to strain. It postulates that this relation is linear. In general, there are 21 independent elastic constants that linearly relate stress to strain. c e ; c c c c , c c . σ ij = ijkl kl ijkl = jikl = ijlk = jilk ijkl = klij Fortunately, if a body is isotropic, only two independent elastic constants are required. These constants are called elastic moduli. 2 ; [(1 ) ]/ E. σ ij = λδijεαα + µε ij εij = + ν σij − νδ ijσαα

Commonly used constants are: λ and µ -- Lame's constants; ν -- Poisson's ratio; E -- Young's modulus. The elastic moduli are determined by the experiment performed. For example, the is measured in the hydrostatic compression experiment. The is measured in the shear deformation experiment.

Bulk Modulus Shear Modulus Compressional Modulus

Hydrostatic Loading Z Distortion, no volume No lateral deformation change K = λ + 2µ / 3 X Shear Y M = K + (4 /3)µ

σ xz = 2µε xz

ε xx = εyy = εzz = ε xy = 0 € Elastic moduli derived from loading experiments are called static moduli 2.9 ROCK PHYSICS BASICS Elastic-Wave Velocity

An elastic stress wave can propagate through an elastic body and generate stress and strain disturbance. The magnitude of deformation generated by a propagating wave is usually very small, on the order of 10-7. As a result, the stress perturbation is also very small, much smaller than the ambient state of stress.

The speed of an elastic wave is related to the elastic moduli via the wave equation (below) where u is displacement, t is time, z is the spatial coordinate, M is the , and ρ is the density.

u(z)

σ(z) σ(z+dz) z ∂ 2u M ∂ 2u A dz = ∂t2 ρ ∂z2

It follows from the wave equation that the speed of wave propagation is

M / ρ

Vp = M / ρ = (K + 4G / 3) / ρ

Vs = G / ρ

2 2 2 2 2 2 M = ρV p ; G = ρVs ; K = ρ(V p − 4Vs / 3); λ = ρ(Vp − 2Vs ).

2 1 (Vp / Vs ) − 22 1 (Vp /Vs) − 2 Poisson’s Ratioν = ν = 2 2 (V /2V(V )/V−)21−1 p s p s

M is the compressional modulus o€r M-modulus G (or µ) is the shear modulus K is the bulk modulus E is Young’s modulus ν is Poisson’s ratio λ is Lame’s constant

Elastic moduli derived from velocity data are called dynamic moduli

2.10 ROCK PHYSICS BASICS Relations between Elastic Constants

Poisson’s ratio relates to the ratios of various elastic moduli and elastic- wave velocities.

2 1 (V p / Vs ) − 2 1 M / G − 2 1 K / G − 2 / 3 1 λ / G ν = 2 = = = 2 (V p / Vs ) −1 2 M / G −1 2 K / G +1 / 3 2 λ / G +1

Theoretically, PR may vary between -1 and 0.5

−1 ≤ ν ≤ 0.5

4 2 2 ν = −1 ⇒ M = G; V = V ; K = 0; λ = − G 3 p 3 s 3

2 ν = 0 ⇒ M = 2G; V = 2V ; K = G; λ = 0 p s 3

ν = 0.5 ⇒ Vs = 0|K = ∞

Sometimes, the dynamic PR of dry sand at low may appear negative.

Plot below shows PR versus porosity in dry unconsolidated sand at low differential pressure. This may mean (a) wrong data or (b) anisotropic rock.

Room-Dry Sands 0.1 5 MPa Ratio Poisson's

0.0

0.2 0.3 0.4 Porosity 2.11 ROCK PHYSICS BASICS Static and Dynamic Moduli

By definition, the dynamic moduli of rock are those calculated from the elastic- wave velocity and density. The static moduli are those directly measured in a deformational experiment.

The static and dynamic moduli of the same rock may significantly differ from each other. The main reason is likely to be the difference in the deformation (strain) amplitude between the dynamic and static experiments.

In the dynamic wave propagation experiment the strain is about 10-7 while static strain may reach 10-2.

Radial Stress σ Strain E = σ / εa εr

ν = εr / εa εa Axial Strain

Typical Plastic Behavior

Load Stress

DYNAMIC STATIC Unload

10-2 10-7

Log Strain 2.12 ROCK PHYSICS BASICS Need for Static Moduli

Static moduli are often used in wellbore stability and in-situ stress applications to evaluate the possibility of breakouts, elevated pore pressure, and tectonic stress distribution. For example, a common method of calculating the horizontal stress in earth is by assuming that the earth is elastic and does not deform in the horizontal direction.

Poisson’s Horizontal Ratio S Stress V ν S = S H V 1 − ν Vertical (Overburden) SH Stress

Hydrofracture can be approximated by a 2D elliptical crack who's dimensions depend on the static Young's modulus and Poisson's ratio.

1 − ν2 Importance of Static Young's b = 2c (P − SH ) Modulus and Poisson's Ratio E min for Hydrofracture Design

P 2b

2c

SHmin

2.13 ROCK PHYSICS BASICS Static and Dynamic Moduli in Sand

0.40 1.8 POMPONIO 1.6 0.39 POMPONIO 1.4 SAND 0.38 1.2 1.0

Porosity 0.37 0.8

Velocity (km/s) 0.6 0.36 0.4 SAND CREEP 0.2 0.35 0 5 10 15 20 0 5 10 15 20 Pressure (MPa) Pressure (MPa)

Porosity (left) and velocity (right) versus pressure in high-porosity room-dry sand sample from the Gulf of Mexico.

4 1.8 P POMPONIO SAND 1.6 3 1.4 SAND

1.2 S POMPONIO 1.0 2

0.8 Dynamic Velocity (km/s)

0.6 Bulk Modulus (GPa) 1

0.4 2 1 (Vp / Vs ) − 2 0.2 Static ν = 2 2 (V / V 0) − 1 0.36 0.38 0.4 p s 0 5 10 15 20 Porosity Pressure (MPa)

Velocity versus porosity (left) and dynamic and static bulk moduli calculated for the same sample.

Zimmer, M., 2003, Doctoral Thesis, Stanford University . 2.14 ROCK PHYSICS BASICS Compaction Effects in Sand/Shale

SAND/CLAY SAND/CLAY

Load

Unload

Unload

Load

SAND/CLAY

Load

Load Unload

Unload SAND/CLAY

Velocity in shale depends on stress and porosity and deformation history.

Yin, H., 1992, Doctoral Thesis, Stanford University . 2.15 ROCK PHYSICS BASICS Elastic Composites and Elastic Bounds

Most physical bodies in nature are elastically heterogeneous, I.e., they are made of components that have different elastic moduli. The effective elastic moduli of a composite depend on (a) properties of individual components and (b) geometrical arrangement of these components in space. It is often very hard, if not impossible, to theoretically calculate the effective elastic moduli of a composite. However, elastic bounds help us contain the exact values of the effective elastic moduli. The simplest bounds are the Voigt (stiffest) and Reuss (softest) bound. No matter how complex the composite is, its effective elastic moduli are contained within these bounds.

Composite Voigt Reuss

For an elastic modulus that may be either bulk or shear modulus of an N-component

composite where the i-th component has modulus Mi and occupies volume fraction fi, the Voigt (upper) bound is: N MV = ∑ fi Mi i =1 The Reuss (lower) bound is:

N −1 −1 MR = (∑ f i Mi ) i=1 Hill’s average is simply the average between the Voigt and Reuss bounds: N N MV + MR 1 −1 −1 MH = = [∑ f i Mi + (∑ f i Mi ) ] 2 2 i=1 i=1 The graph on the right shows the Voigt and 20 Reuss bounds and Hill’s average of a two- 18 component composite. Voigt Hill 16 Modulus Reuss The elastic modulus of the soft component is 10 14 and that of the stiff component is 20. The Elastic horizontal axis is the concentration of the stiff 12 component. 10 0 0.2 0.4 0.6 0.8 1 2.16 Volume Concentration ROCK PHYSICS BASICS Hashin-Shrikman Elastic Bounds

For an isotropic composite, the effective elastic bulk and shear moduli are contained within rigorous Hashin-Shtrikman bounds. These bounds have been derived for the bulk and shear moduli. The Hashin-Shtrikman bounds are tighter than the Voigt-Reuss bounds. N f 4 N f 4 [ i ]−1 − G ≤ K ≤ [ i ]−1 − G , ∑ 4 min eff ∑ 4 max i =1 Ki + 3 Gmin 3 i =1 Ki + 3 Gmax 3 N f G  9K + 8G  [ i ]−1 − min  min min  ≤ G ≤ ∑     eff i =1 G 9K + 8G 6  K + 2G  min  min min  min min Gi +   6  K min + 2Gmin  N f G  9K +8G  [ i ]−1 max  max max  , ∑   −   i =1 G 9K + 8G 6  K + 2G  max  max max  max max Gi +   6  K max + 2Gmax 

In the Hashin-Shtrikman equations, the subscript “eff” is for the effective elastic bulk and shear moduli. The subscripts “min” and “max” are for the softest and stiffest components, respectively. A physical realization of the Hashin-Shtrikman bounds for two components is the entire space filled by composite spheres of varying size. The outer shell of each sphere is the softest component for the lower bound and the stiffest component for the upper bound. If one of the components is void (empty pore) the lower bound is zero.

Hashin-Shtrikman Bounds: Realization

20 Voigt 18 Reuss 16 Modulus

14 Hashin-

Elastic Shtrikman 12

10 0 0.2 0.4 0.6 0.8 1 Volume Concentration 2.17 ROCK PHYSICS BASICS Elastic Bounds for -Saturated Sand

Unfortunately, if the elastic moduli of the two components of the composite are very different, the bounds lie very far apart. They cannot be used for practical velocity prediction.

In the example below, plotted is velocity versus porosity as calculated for a quartz/water mixture using the elastic bounds. The data points are for water- saturated sandstones. The data lie within the elastic bounds curves.

6

5 Voigt

4 Upper (km/s) 3 Hashin-Shtrikman

Vp Reuss

2

1 0 0.2 0.4 0.6 0.8 1 Porosity

The bounds can still be used to quality control of the data.

In the example below, the red data points lie below the lower bound curve for the quartz/water mix. The reason is that these data are for gas-saturated sands.

6

5 Voigt

4 Upper (km/s) 3 Hashin-Shtrikman

Vp Reuss

2

1 0 0.2 0.4 0.6 0.8 1 Porosity 2.18 ROCK PHYSICS BASICS Mixing

The main difference between and is that fluid’s shear modulus is zero. Therefore, the shear-wave velocity in fluid is zero. The P-wave velocity in fluid depends on the bulk modulus and density as

K V = P ρ

If several types of fluid coexist in the same space (but are not mixed at the molecular level) the effective bulk modulus does not depend on the geometrical arrangement of the components. It is exactly the Reuss (isostress) average of the individual bulk moduli:

1 N f = ∑ i KFluid i =1 Ki

The same equation but written in terms of (β = 1/K) is:

N βFluid = ∑ fi βi i =1

This is why even small fractions of free gas make the pore fluid very compressible (figure below, on the right).

3 2

Mineral (GPa) Water 2 (km/s) Mixture

Oil of 1 Gas

1 Velocity Modulus Bulk 0 0 0 0.2 0.4 0.6 0.8 1 0 0.2 0.4 0.6 0.8 1 Water Saturation Water Saturation

2.19 ROCK PHYSICS BASICS Pressure and Rock Properties

When rock is extracted from depth and re-loaded in the lab, it exhibits a strong velocity-pressure dependence, especially at low confining pressure. The primary reason is microcracks that open during in-situ stress relief. Below: Vp and Vs versus confining pressure in room-dry sandstone samples. The in-situ effective stress is about 15 MPa. Different colors correspond to different samples.

4.0

3.5

3.0 Vp In-Situ (km/s) Stress

2.5 Velocity

2.0

Vs

1.5 0 5 10 15 20 25 Confining Pressure (MPa)

2.20 ROCK PHYSICS BASICS Pressure and Rock Properties

Phenomenology of pressure effect on velocity in room-dry sandstone dataset. The velocity-porosity trends become sharper as pressure increases.

6

5 MPa 20 MPa 40 MPa (km/s) Vp

5

4

3

2 0 0.1 0.2 0.3 0 0.1 0.2 0.3 0 0.1 0.2 0.3 Porosity Porosity Porosity

2.21 ROCK PHYSICS BASICS Pressure and Rock Properties

Phenomenology of pressure effect on velocity in room-dry sandstone dataset.

Both Vp and Vs may significantly change with changing pressure.

6 4

5

3

4 (km/s) (km/s) MPa MPa 40 40 at at Vp at 40 MPa 3 Vs at 40 MPa Vs Vp 2

2 Vp Vs

1 1 1 2 3 4 5 6 1 2 3 4 Vp Vpat 5at MPa 5 MPa (km/s) Vs Vsat 5 at MPa 5 MPa (km/s)

2.22 ROCK PHYSICS BASICS Pressure and Rock Properties

The Vp and Vs versus pressure changes are not necessarily scalable -- the Vp/Vs ratio and Poisson's ratio change as well.

0.3

0.2 MPa 40 at PR PR at 40 MPa

0.1

Poisson's Ratio

0 0 0.1 0.2 0.3 PRPR atat 5 5 MPa MPa

2.23 ROCK PHYSICS BASICS Pressure and Rock Properties

The effect of pressure on porosity is not as large as on velocity. The main reason is that rock's elasticity is affected by thin compliant cracks that do not occupy much of the pore space volume.

40 MPa .01 .3 MPa .2 40 Increase at

.1 Porosity Porosity

0 .1 .2 .3 .1 .2 .3 Porosity at 5 MPa Porosity at 5 MPa

.2 5 MPa to 40 MPa

Δφ Change .1 Relative Reduction φ

0 Relative .1 .2 .3 Porosity at 5 MPa €

2.24 ROCK PHYSICS BASICS Stress-Induced

Thomsen's anisotropic formulation (weak )

2 2 4 Vp (θ) ≈ α(1+ δ sin θ cos θ + εsin θ) θ α 2 V (θ) ≈ β[1+ (ε −δ)sin2 θ cos2 θ] sV β 2 2 VsH (θ) ≈ β[1+ γ sin θ]

Vp (π /2) −Vp (0) V (π /2) −V (π /2) V (π /2) −V (0) ε = γ = sH sV = sH sH Vp (0) VsV (π /2) VsH (0) €

Z Vzz € V Y zx Vzz Vzy X

V Vxz yx V Vyy V yy Vxx xy Vyz Vxx

Ottawa sand. Uniaxial compression. Pxx = Pyy = 1.72 bar. Yin (1992).

Vyz Vzy

Vxz Vzx Vyx Vxy

Anisotropic stress field induces anisotropy in otherwise isotropic rock. 2.25 ROCK PHYSICS BASICS Permeability

Permeability is a fluid flow property of a porous medium. Its definition comes from Darcy’s law which states that the flow rate is linearly proportional to the pressure gradient.

Sample PERMEABILITY Cross-Section Pressure A ΔP Head Q = −k µ L Flow Sample Rate Length

2.26 ROCK PHYSICS BASICS Permeability -- Kozeny-Carman Equation

Permeability depends on porosity and grain size.

Kozeny-Carman Equation (SI UNITS)

Permeability Porosity

k 1 φ 3 = d 2 72 (1− φ)2τ 2

Grain Size Tortuosity

€ Drastic drop in permeability as porosity increases but clay content increases too (grain size decreases). Yin (1992).

Permeability may be almost zero in carbonate where large vuggy pores are not connected. This pore geometry is a topological inverse of the pore geometry of clastic sediment. Permeability equations that work in clastics may not work in carbonates .

Permeability depends on porosity and grain size and also (critically) on the pore-space geometry. 2.27 ROCK PHYSICS BASICS Permeability and Stress

Permeability in medium-to-high porosity clastic sediment is weakly dependent on stress.

Ali Mese (1998) Ali Mese (1998) 0.3 100

0.2 10 Porosity at 4000 psi Permeability (mD) at 4000 psi

1 0.1

a 0.1 0.2 0.3 b 1 10 100 Porosity at 400 psi Permeability (mD) at 400 psi

Permeability in tight sandstone samples. Porosity 0.03 to 0.07.

Walls (1982)

Relative changes of high permeability with pressure are smaller than those for low permeability. Both may have implications for fluid transport. 2.28 DEFINITIONS OF RESISTIVITY

U1 U2 I

U = U1 −U2 € Resistance € R = U /I ρ = RA /l Electrical Potential€ Current Drop Resistivity

€ € [R] = Ω ≡ Ohm σ =1/ρ

[ρ] = Ω⋅ m ≡ Ohm⋅ m Conductivity

€ 150

100 GR 50

0 6000 6500 7000 7500 8000 Depth (ft)

100

m) 10

(Ohm 1 Rt

0.1 6000 6500 7000 7500 8000 Depth (ft)

2.29