Hydrogen Energy Storage: New Techno-Economic Emergence Solution Analysis
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Hydrogen Storage for Mobility: a Review
materials Review Hydrogen Storage for Mobility: A Review Etienne Rivard * , Michel Trudeau and Karim Zaghib * Centre of Excellence in Transportation Electrification and Energy Storage, Hydro-Quebec, 1806, boul. Lionel-Boulet, Varennes J3X 1S1, Canada; [email protected] * Correspondence: [email protected] (E.R.); [email protected] (K.Z.) Received: 18 April 2019; Accepted: 11 June 2019; Published: 19 June 2019 Abstract: Numerous reviews on hydrogen storage have previously been published. However, most of these reviews deal either exclusively with storage materials or the global hydrogen economy. This paper presents a review of hydrogen storage systems that are relevant for mobility applications. The ideal storage medium should allow high volumetric and gravimetric energy densities, quick uptake and release of fuel, operation at room temperatures and atmospheric pressure, safe use, and balanced cost-effectiveness. All current hydrogen storage technologies have significant drawbacks, including complex thermal management systems, boil-off, poor efficiency, expensive catalysts, stability issues, slow response rates, high operating pressures, low energy densities, and risks of violent and uncontrolled spontaneous reactions. While not perfect, the current leading industry standard of compressed hydrogen offers a functional solution and demonstrates a storage option for mobility compared to other technologies. Keywords: hydrogen mobility; hydrogen storage; storage systems assessment; Kubas-type hydrogen storage; hydrogen economy 1. Introduction According to the Intergovernmental Panel on Climate Change (IPCC), it is almost certain that the unusually fast global warming is a direct result of human activity [1]. The resulting climate change is linked to significant environmental impacts that are connected to the disappearance of animal species [2,3], decreased agricultural yield [4–6], increasingly frequent extreme weather events [7,8], human migration [9–11], and conflicts [12–14]. -
Thermal Storage Impact on CHP Cogeneration Performance with Southwoods Case Study Edmonton, Alberta Michael Roppelt C.E.T
Thermal Storage Impact on CHP Cogeneration Performance with Southwoods Case Study Edmonton, Alberta Michael Roppelt C.E.T. CHP Cogeneration Solar PV Solar Thermal Grid Supply Thermal Storage GeoExchange RenewableAlternative & LowEnergy Carbon Microgrid Hybrid ConventionalSystemSystem System Optional Solar Thermal Option al Solar PV CNG & BUILDING OR Refueling COMMUNITY Station CHP Cogeneration SCALE 8 DEVELOPMENT Hot Water Hot Water DHW Space Heating $ SAVINGS GHG OPERATING Thermal Energy Cool Water Exchange & Storage ElectricalMicro Micro-Grid-Grid Thermal Microgrid Moving Energy not Wasting Energy Natural Gas Combined Heat and Power (CHP) Cogeneration $350,000 2,500,000 kWh RETAILINPUT OUTPUT VALUE NATURAL GAS $400,000. $100,000.30,000 Gj (85% Efficiency) CHP $50,000 Cogeneration15,000 Energy Gj Technologies CHP Unit Sizing Poorly sized units will not perform optimally which will cancel out the benefits. • For optimal efficiency, CHP units should be designed to provide baseline electrical or thermal output. • A plant needs to operate as many hours as possible, since idle plants produce no benefits. • CHP units have the ability to modulate, or change their output in order to meet fluctuating demand. Meeting Electric Power Demand Energy Production Profile 700 Hourly Average 600 353 January 342 February 500 333 March 324 April 400 345 May 300 369 June 400 July 200 402 August 348 September 100 358 October 0 362 November 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Meeting Heat Demand with CHP Cogeneration Energy Production Profile Heat Demand (kWh) Electric Demand (kWh) Cogen Heat (kWh) Waste Heat Heat Shortfall Useable Heat CHP Performance INEFFICIENCY 15% SPACE HEATING DAILY AND HEAT 35% SEASONAL ELECTRICAL 50% IMBALANCE 35% 50% DHW 15% Industry Studies The IEA works to ensure reliable, affordable and clean energy for its 30 member countries and beyond. -
Renewable Carbohydrates Are a Potential High-Density Hydrogen Carrier
international journal of hydrogen energy 35 (2010) 10334e10342 Available at www.sciencedirect.com journal homepage: www.elsevier.com/locate/he Review Renewable carbohydrates are a potential high-density hydrogen carrier Y.-H. Percival Zhang a,b,c,* a Biological Systems Engineering Department, 210-A Seitz Hall, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA b Institute for Critical Technology and Applied Sciences (ICTAS), Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA c DOE BioEnergy Science Center (BESC), Oak Ridge, TN 37831, USA article info abstract Article history: The possibility of using renewable biomass carbohydrates as a potential high-density Received 14 February 2010 hydrogen carrier is discussed here. Gravimetric density of polysaccharides is 14.8 H2 mass% Received in revised form where water can be recycled from PEM fuel cells or 8.33% H2 mass% without water recycling; 21 July 2010 volumetric densities of polysaccharides are >100 kg of H2/m3. Renewable carbohydrates Accepted 23 July 2010 (e.g., cellulosic materials and starch) are less expensive based on GJ than are other hydrogen Available online 21 August 2010 carriers, such as hydrocarbons, biodiesel, methanol, ethanol, and ammonia. Biotransfor- mation of carbohydrates to hydrogen by cell-free synthetic (enzymatic) pathway biotrans- Keywords: formation (SyPaB) has numerous advantages, such as high product yield (12 H2/glucose Biomass unit), 100% selectivity, high energy conversion efficiency (122%, based on combustion Cell-free synthetic pathway energy), high-purity hydrogen generated, mild reaction conditions, low-cost of bioreactor, biotransformation few safety concerns, and nearly no toxicity hazards. Although SyPaB may suffer from Carbohydrate current low reaction rates, numerous approaches for accelerating hydrogen production Hydrogen carrier rates are proposed and discussed. -
A Comprehensive Review of Thermal Energy Storage
sustainability Review A Comprehensive Review of Thermal Energy Storage Ioan Sarbu * ID and Calin Sebarchievici Department of Building Services Engineering, Polytechnic University of Timisoara, Piata Victoriei, No. 2A, 300006 Timisoara, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-256-403-991; Fax: +40-256-403-987 Received: 7 December 2017; Accepted: 10 January 2018; Published: 14 January 2018 Abstract: Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included. Keywords: storage system; phase-change materials; chemical storage; cold storage; performance 1. Introduction Recent projections predict that the primary energy consumption will rise by 48% in 2040 [1]. On the other hand, the depletion of fossil resources in addition to their negative impact on the environment has accelerated the shift toward sustainable energy sources. -
Hydrogen Adsorption by Perforated Graphene
http://www.diva-portal.org Postprint This is the accepted version of a paper published in International journal of hydrogen energy. This paper has been peer-reviewed but does not include the final publisher proof-corrections or journal pagination. Citation for the original published paper (version of record): Baburin, I A., Klechikov, A., Mercier, G., Talyzin, A., Seifert, G. (2015) Hydrogen adsorption by perforated graphene. International journal of hydrogen energy, 40(20): 6594-6599 http://dx.doi.org/10.1016/j.ijhydene.2015.03.139 Access to the published version may require subscription. N.B. When citing this work, cite the original published paper. Permanent link to this version: http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-104374 Hydrogen adsorption by perforated graphene Igor A. Baburin1, Alexey Klechikov2, Guillaume Mercier2, Alexandr Talyzin2*, Gotthard Seifert1* 1 Technische Universität Dresden, Theoretische Chemie, Bergstraße 66b, 01062 Dresden Tel.: (+49) (351) 463 37637. Fax: (+49) (351) 463 35953. *Corresponding author e-mail: [email protected]. 2 Department of Physics, Umeå University, SE-901 87 Umeå, Sweden Tel.: +46 90 786 63 20. Fax: *Corresponding author e-mail: [email protected]. 1 Abstract We performed a combined theoretical and experimental study of hydrogen adsorption in graphene systems with defect-induced additional porosity. It is demonstrated that perforation of graphene sheets results in increase of theoretically possible surface areas beyond the limits of ideal defect-free graphene (~2700 m2/g) with the values approaching ~5000 m2/g. This in turn implies promising hydrogen storage capacities up to 6.5 wt% at 77 K, estimated from classical Grand canonical Monte Carlo simulations. -
Hydrogen Storage a Brief Overview of Hydrogen Storage Options Rich Dennis Technology Manager – Advanced Turbines and SCO2 Power Cycles
Hydrogen Storage A brief overview of hydrogen storage options Rich Dennis Technology Manager – Advanced Turbines and SCO2 Power Cycles Ref:(https://www.greencarcongre ss.com/2016/09/20160911- doe.html) 2nd workshop on Thermal, Mechanical and Chemical Energy Storage OmniPresentation William to Penn; Pittsburgh PA; February 4, 2020 Sponsored by Elliot Group; Co-organized with SwRI and NETL 2/6/2020 1 Presentation Outline Small-scale to large-scale hydrogen storage provides attractive options • H2 physical properties Months Hydrogen • Overview H2 production, transportation & utilization Weeks Texas, US • H2 storage technologies • Compressed storage Days • Liquid storage CAES • Materials based storage • Chemical hydrogen storage Hours • Vehicle & portable applications Pumped Hydro • Storage in NG pipelines Minutes 0.1 1 10 100 1000 • Summary GWh Ref: 1. Crotogino F, Donadei S, Bu¨ nger U, Landinger H. Large-scale hydrogen underground storage for securing future energy supplies. Proceedingsof 18thWorld Hydrogen Energy Conference (WH2C2010), Essen, Germany;May 16e21, 2010. p. 37e45. 2/6/2020 2 2. Kepplinger J, Crotogino F, Donadei S, Wohlers M. Present trends in compressed air energy and hydrogen storage in Germany. Solution Mining Research Institute SMRI Fall 2011 Conference, York, United Kingdom; October 3e4, 2011. Physical Properties of H2 vs CH4 H2 has a very low density and energy density, and a high specific volume Hydrogen 0.085 120 11.98 10,050 Density Lower Heating Value Specific Volume Energy Density Property 3 3 3 (kg/m ) (kJ/kg) m /kg kJ/m 0.65 50 1.48 32,560 Methane 1 atm,15°C 1 atm, 25°C 1 atm, 21°C 1 atm, 25°C 3 Laminar Flame Speeds Hydrogen burns ten times as fast as methane H2 CO CH4 0.4 1 2 3 meter/second 0.3 Ref: NACA Report 1300 4 Flammability Limits In Air Hydrogen has broad flammability limits compared to methane H2 4 to 75 CO 12 to 75 CH4 5 to 15 0 25 50 75 100 % in Air 5 Diffusivity in Air In air, hydrogen diffuses over three times as fast compared to methane H2 CO CH4 0.2 0.5 0.7 1 cm2/sec Ref: Vargaftik, N. -
Energy and the Hydrogen Economy
Energy and the Hydrogen Economy Ulf Bossel Fuel Cell Consultant Morgenacherstrasse 2F CH-5452 Oberrohrdorf / Switzerland +41-56-496-7292 and Baldur Eliasson ABB Switzerland Ltd. Corporate Research CH-5405 Baden-Dättwil / Switzerland Abstract Between production and use any commercial product is subject to the following processes: packaging, transportation, storage and transfer. The same is true for hydrogen in a “Hydrogen Economy”. Hydrogen has to be packaged by compression or liquefaction, it has to be transported by surface vehicles or pipelines, it has to be stored and transferred. Generated by electrolysis or chemistry, the fuel gas has to go through theses market procedures before it can be used by the customer, even if it is produced locally at filling stations. As there are no environmental or energetic advantages in producing hydrogen from natural gas or other hydrocarbons, we do not consider this option, although hydrogen can be chemically synthesized at relative low cost. In the past, hydrogen production and hydrogen use have been addressed by many, assuming that hydrogen gas is just another gaseous energy carrier and that it can be handled much like natural gas in today’s energy economy. With this study we present an analysis of the energy required to operate a pure hydrogen economy. High-grade electricity from renewable or nuclear sources is needed not only to generate hydrogen, but also for all other essential steps of a hydrogen economy. But because of the molecular structure of hydrogen, a hydrogen infrastructure is much more energy-intensive than a natural gas economy. In this study, the energy consumed by each stage is related to the energy content (higher heating value HHV) of the delivered hydrogen itself. -
Hydrogen from Biomass Gasification
Hydrogen from biomass gasification Biomass harvesting, Photo: Bioenergy2020+ IEA Bioenergy: Task 33: December 2018 Hydrogen from biomass gasification Matthias Binder, Michael Kraussler, Matthias Kuba, and Markus Luisser Edited by Reinhard Rauch Copyright © 2018 IEA Bioenergy. All rights Reserved ISBN, 978-1-910154-59-5 Published by IEA Bioenergy IEA Bioenergy, also known as the Technology Collaboration Programme (TCP) for a Programme of Research, Development and Demonstration on Bioenergy, functions within a Framework created by the International Energy Agency (IEA). Views, findings and publications of IEA Bioenergy do not necessarily represent the views or policies of the IEA Secretariat or of its individual Member countries. Executive Summary Hydrogen will be an important renewable secondary energy carrier for the future. Today, hydrogen is predominantly produced from fossil fuels. Hydrogen production from biomass via gasification can be an auspicious alternative for future decarbonized applications, which are based on renewable and carbon-dioxide-neutral produced hydrogen. This study gives an overview of possible ways to produce hydrogen via biomass gasification. First, an overview of the current market situation is given. Then, hydrogen production based on biomass gasification is explained. Two different hydrogen production routes, based on biomass gasification, were investigated in more detail. Hydrogen production was investigated for steam gasification and sorption enhanced reforming. Both routes assessed, appear suitable for hydrogen production. Biomass to hydrogen efficiencies (LHV based) of up to 69% are achieved and a techno-economic study shows, hydrogen selling prices of down to 2.7 EUR·kg-1 (or 79 EUR·MWh-1). Overall it can be stated, that governmental support and subsidies are necessary for successful implementation of hydrogen production based on biomass gasification technologies. -
Hydrogen Energy Storage: Grid and Transportation Services February 2015
02 Hydrogen Energy Storage: Grid and Transportation Services February 2015 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy EfficiencyWorkshop Structure and Renewable / 1 Energy, operated by the Alliance for Sustainable Energy, LLC. Hydrogen Energy Storage: Grid and Transportation Services February 2015 Hydrogen Energy Storage: Grid and Transportation Services Proceedings of an Expert Workshop Convened by the U.S. Department of Energy and Industry Canada, Hosted by the National Renewable Energy Laboratory and the California Air Resources Board Sacramento, California, May 14 –15, 2014 M. Melaina and J. Eichman National Renewable Energy Laboratory Prepared under Task No. HT12.2S10 Technical Report NREL/TP-5400-62518 February 2015 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 303-275-3000 www.nrel.gov NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government or any agency thereof. -
Energy Storage Analysis
Energy Storage Analysis Chad Hunter, Evan Reznicek, Michael Penev, Josh Eichman, Sam Baldwin National Renewable Energy Laboratory Thursday, May 21, 2020 DOE Hydrogen and Fuel Cells Program 2020 Annual Merit Review and Peer Evaluation Meeting Project ID SA173 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Overview: Hydrogen grid energy storage analysis Timeline Barriers (4.5) Start: October 2019 A. Future Market Behavior End: June 2020 • Assessing competitiveness of hydrogen for grid storage C. Inconsistent Data, Assumptions & Guidelines 50% complete • Consistent modeling methodology using established DOE cost/price and performance targets D. Insufficient Suite of Models and Tools • Develop hydrogen grid storage techno-economic tool Budget Partners Total Project Funding: $155k Project Management EERE Strategic Priorities and Impacts Analysis (SPIA) • FY20: $155k Collaborators and Peer Reviewers (alphabetical) Total DOE funds received to Ballard, Bioenergy Technology Office, Fossil Energy, NREL (Paul Denholm, Wesley Cole), Office of date: $50k Electricity, Solar Energy Technology Office, Water Power Technology Office NREL | 2 Relevance (1/3): HFTO Systems Analysis Framework Hydrogen Grid Energy Storage Analysis • H2@Scale • DOE Fuel Cell • SPIA/HFTO hydrogen Technologies Office Integrates System Analysis Framework: energy storage • DOE Strategic • ANL bulk hydrogen Priorities and • Leverages and expands existing storage analysis Impacts Analysis systems analysis models • PNNL hydrogen -
Grid Energy Storage
Grid Energy Storage U.S. Department of Energy December 2013 Acknowledgements We would like to acknowledge the members of the core team dedicated to developing this report on grid energy storage: Imre Gyuk (OE), Mark Johnson (ARPA-E), John Vetrano (Office of Science), Kevin Lynn (EERE), William Parks (OE), Rachna Handa (OE), Landis Kannberg (PNNL), Sean Hearne & Karen Waldrip (SNL), Ralph Braccio (Booz Allen Hamilton). Table of Contents Acknowledgements ....................................................................................................................................... 1 Executive Summary ....................................................................................................................................... 4 1.0 Introduction .......................................................................................................................................... 7 2.0 State of Energy Storage in US and Abroad .......................................................................................... 11 3.0 Grid Scale Energy Storage Applications .............................................................................................. 20 4.0 Summary of Key Barriers ..................................................................................................................... 30 5.0Energy Storage Strategic Goals .......................................................................................................... 32 6.0 Implementation of its Goals ............................................................................................................... -
Summary of Hydrogen Production and Storage Systems
Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The view and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. An Overview of Hydrogen Production and Storage Systems with Renewable Hydrogen Case Studies May 2011 Prepared by: Timothy Lipman, PhD 1635 Arrowhead Drive Oakland, California 94611 (510) 339-1449 [email protected] Prepared for: Clean Energy States Alliance 50 State Street, Suite 1 Montpelier, VT 05602 Conducted under US DOE Grant DE-FC3608GO18111 A000, Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Program This page intentionally blank Summary Hydrogen is already widely produced and used, but it is now being considered for use as an energy carrier for stationary power and transportation markets. Approximately 10-11 million metric tonnes of hydrogen are produced in the US each year, enough to power 20-30 million cars or 5-8 million homes.1 Major current uses of the commercially produced hydrogen include oil refining (hydro-treating crude oil as part of the refining process to improve the hydrogen to carbon ratio of the fuel), food production (e.g., hydrogenation), treating metals, and producing ammonia for fertilizer and other industrial uses.