Two-Dimensional Characterization of Three-Dimensional Magnetic Bubbles in Fe3sn2 Nanostructures 1 1,2 3 4 1
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National Science Review RESEARCH ARTICLE 8: nwaa200, 2021 doi: 10.1093/nsr/nwaa200 Advance access publication 28 August 2020 PHYSICS Two-dimensional characterization of three-dimensional magnetic bubbles in Fe3Sn2 nanostructures 1 1,2 3 4 1 Jin Tang , Yaodong Wu , Lingyao Kong , Weiwei Wang , Yutao Chen , Downloaded from https://academic.oup.com/nsr/article/8/6/nwaa200/5898680 by guest on 25 September 2021 1Anhui Province Key 1 5 1 1,3 1,4,∗ Laboratory of Yihao Wang ,Y.Soh , Yimin Xiong , Mingliang Tian and Haifeng Du Condensed Matter Physics at Extreme Conditions, High ABSTRACT Magnetic Field Laboratory of the We report differential phase contrast scanning transmission electron microscopy (TEM) of nanoscale Chinese Academy of magnetic objects in Kagome ferromagnet Fe3Sn2 nanostructures. This technique can directly detect the Sciences, and deflection angle of a focused electron beam, thus allowing clear identification of the real magnetic structures University of Science of two magnetic objects including three-ring and complex arch-shaped vortices in Fe3Sn2 by Lorentz-TEM and Technology of imaging. Numerical calculations based on real material-specific parameters well reproduced the China, Hefei 230031, experimental results, showing that the magnetic objects can be attributed to integral magnetizations of two China; 2Universities types of complex three-dimensional (3D) magnetic bubbles with depth-modulated spin twisting. Magnetic Joint Key Laboratory configurations obtained using the high-resolution TEM are generally considered as two-dimensional (2D) of Photoelectric magnetic objects previously. Our results imply the importance of the integral magnetizations of Detection Science and underestimated 3D magnetic structures in 2D TEM magnetic characterizations. Technology in Anhui Province, Hefei Keywords: skyrmion, skyrmion bubbles, three-dimensional magnetic structures, differential phase Normal University, contrast scanning transmission electron microscopy, micromagnetics Hefei 230601, China; 3School of Physics and Materials INTRODUCTION sure cylinder domain wall contributing to a similar Science, Anhui integer topological winding number as a skyrmion; Magnetic skyrmions are topologically nontrivial University, Hefei type-I magnetic bubbles are thus renamed skyrmion nanometric spin whirls that are expected to be 230601, China; bubbles [25–28]. The other one is a type-II mag- 4 information carriers in future energy-efficient Institute of Physical netic bubble stabilized by a tilted magnetic field spintronic devices [1–19]. They were first found in Science and with magnetization in the partially reversed cylinder Information non-centrosymmetric magnetic compounds, where domain wall, with all domain wall magnetizations Technology, Anhui chiral Dzyaloshinskii–Moriya interactions (DMIs) pointing toward the in-plane field component. University, Hefei bend the magnetic moments [20–23]. The unique However, such a domain wall in a type-II magnetic 230601, China and feature of magnetic skyrmions is their nontrivial 5 bubble contributes to a zero winding number and is Paul Scherrer topology defined by unit topological charge [24]. topologically trivial [27]. The first wave of interest Institute, 5232 Unlike the chiral DMI-induced skyrmions, magnetic Villigen, Switzerland in magnetic bubbles occurred in the 1970s–1980s, bubbles originate from the interplay of four types motivated by experimental and theoretical studies of of interactions, including ferromagnetic exchange ∗ potential bubble memory [29,30]. The detection of Corresponding coupling, dipolar–dipolar interaction (DDI), uni- author. E-mail: skyrmion bubbles renewed the interest in magnetic axial anisotropy and Zeeman energy. Competition [email protected] bubbles in the last decade [25–28,31–35]. among the first three interactions leads to stripe Although these two types of bubbles are well domains, which may change into a magnetic bubble Received 23 understood within the theoretical framework when applying an external field. There are two types February 2020; describing uniaxial ferromagnets, a recent study of magnetic bubbles according to the rotation sense Revised 4 June 2020; on a typical uniaxial ferromagnet Fe Sn found of the cylinder domain wall (Fig. S1). One is a type-I 3 2 Accepted 4 August new exotic spin whirls beyond conventional mag- magnetic bubble stabilized by a perpendicular 2020 netic bubbles by Lorentz transmission electron magnetic field with a clockwise or anticlockwise clo- C The Author(s) 2020. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. This is an Open Access articleder distributedun the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. Natl Sci Rev, 2021, Vol. 8, nwaa200 microscopy (Lorentz-TEM) [25,28]. Two typical Here, we investigate the magnetic objects in examples of such new spin whirls are three-ring and an Fe3Sn2 nanodisk using differential phase con- complex arch-shaped vortices characterized by a trast scanning transmission electron microscopy series of concentric circular stripe domains and one (DPC-STEM) combined with micromagnetic or multiple bound pairs of rotating magnetic whirls, simulations. The observed magnetic objects are clar- respectively. Such magnetic structures were also ob- ified as 2D integral magnetizations of complex 3D served in other uniaxial ferromagnets [26,31]. These type-I and type-II bubbles with depth-modulated objects are nanoscale size, which implies that they configurations. The characterization is considered can be applied as information carriers in spintronic further such that the origin of the artificial mag- devices [17]. However, they are neither detected by netic configurations detected in Lorentz-TEM is other magnetic imaging methods nor in simulations explained. Downloaded from https://academic.oup.com/nsr/article/8/6/nwaa200/5898680 by guest on 25 September 2021 conducted under realistic conditions. Moreover, a recent study demonstrated that the improper filter parameter in the transport of intensity equation RESULTS AND DISCUSSION (TIE) analysis of Lorentz-TEM imaging of type-II bubbles can lead to artificial biskyrmion structures Identification of a multi-ring vortex [33]. We first focus on the three-ring vortex inan Three-dimensional (3D) magnetic structures Fe3Sn2 uniaxial ferromagnet. An Fe3Sn2 nanodisk have become an active research topic because (diameter ∼1550 nm; thickness ∼140 nm) with they are important in understanding novel exper- (001)-oriented out-of-plane direction is chosen for imental phenomena and potential applications DPC-STEM measurements (Fig. 1f; Fig. S3) [4,23,36–40]. It has been suggested that the chiral and micromagnetic simulations (see the simula- exchange interactions play important roles in tion method in the Supplementary Data) [42]. tailoring 3D magnetic structures in synthetic anti- Lorentz-TEM is also performed for comparison. ferromagnets for potential 3D spintronic systems TEM magnetic imaging is discussed in detail in [39,40]. 3D magnetic skyrmions in B20 magnets the Supplementary Data [11–13,15,43–49]. Stripe induced by DMI have been proposed to understand domains are observed at zero field, which transfer the stability of zero-field target skyrmions and into circular domains when a magnetic field is attractive interactions between skyrmions4 [ ,23]. applied out of plane (Fig. 1a–c). However, once Magnetic skyrmion bubbles have also been pre- the circular domains are formed, they may persist dicted with depth-modulated spin twisting induced as the field decreases (Fig. 1d). In such a case, the by DDI [41]. One typical characteristic of 3D Lorentz-TEM image gives rise to a three-ring vortex magnetic skyrmion bubbles is that skyrmions near at low field (Fig. 1e) that transfers into a normal two surfaces have nearly contrary Neel´ twisting. This bubble skyrmion when the field is increased. In characteristic has been observed in magnetic multi- Fig. 2a, a field-driven process of one bubble by layers by some surface-sensitive magnetic detection Lorentz-TEM is shown as an example. At a low methods [36–38]. TEM is a real-space imaging of field, a black dot in the center is surrounded by integral magnetic field over depth with ultrahigh outer rings, which is different from a conventional spatial resolution. Magnetic configurations in thin skyrmion image [7,13,19]. The Lorentz contrast nanostructures have been typically considered of a normal skyrmion is composed of only a black as quasi-two-dimensional (quasi-2D) magnetic or white circle [5,6,19]. Such distinctness implies objects using TEM [19,25,26,28,31]. However, one complexity in the magnetic objects. When using may clarify real 3D magnetic structures from the the TIE method, the reconstructed magnetic difference in integral magnetization over depth. This configuration is characterized by a series of con- rule has been used to identify 3D chiral bobbers centric stripe domains with opposite rotation sense from integral phase shifts weaker than skyrmion between neighboring magnetic rings (Fig. 2b1–b3), tubes using TEM [3]. The depth-modulated 3D forming a three-ring vortex. At a high field, a normal magnetic bubbles are also expected to show more skyrmion-like image is observed (Fig. 2b4 and b5). complex integral magnetizations over the depth and Assuming these nanoscale magnetic objects are detected using