Blue LED and Solid State Lighting Hyeonsik Cheong Department of Physics Sogang University Nobel Prize in Physics 2014
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Blue LED and Solid State Lighting Hyeonsik Cheong Department of Physics Sogang University Nobel Prize in Physics 2014 Isamu Akasaki (1929) Hiroshi Amano (1960) Shuji Nakamura (1954) “for the invention of efficient blue light-emitting diodes which has enabled bright and energy-saving white light sources” 2 Isamu Akasaki Born in 1929 1952 B.S. Kyoto Univ. 1959 Research Associate, Assistant and Associate Professor, Nagoya Univ. 1964 Dr. Eng., Nagoya Univ. 1964 Matsushita Research Institute 1981 Professor, Nagoya Univ. 1992 Professor Emeritus, Nagoya Univ. and Professor, Meijo Univ. 3 Hiroshi Amano Born in 1960 1983 B.E. Nagoya Univ. 1989 Dr. Eng. Nagoya, Univ. 1988 Research Associate, Nagoya Univ. 1992 Assistant, Associate, Professor, Meijo Univ. 2010 Professor, Nagoya Univ. 4 Shuji Nakamura Born in 1954 1977, 1979, BE and ME, Tokushima Univ. 1979 Nichia Corporation 1988 Visiting Scientist, Univ. of Florida 1994 Dr. Eng. Tokushima Unvi. 1999 Professor, UC Santa Barbara 5 Blue LED 6 7 Full-color Display (RGB) 8 Is it worth a Nobel Prize? History of Lighting 10 Electrical Lighting Incandescent lamp . Edison’s lamp: Carbon filament Tungsten filament . Electricity Heat Light Arc lamp (HID) . Electricity Gas Molecule Light Fluorescent lamp . Electricity Mercury vapor UV light Visible light LED . Electricity Light 11 Historical Development of Lighting 12 Comparison of Lamps Cost Comparison for 60 watt incandescent equivalent light bulb (U.S. residential electricity prices) LED LED Incandescent Halogen CFL LED (Cree) (EcoSmart clear) (Philips) Purchase price $0.41 $1.17 $0.99 $3.66 $1.50 $4.99 Watts 60 43 14 6.5 8.5 9.5 lumens (mean) 860 750 775 800 800 815 lumens/watt 14.3 17.4 55.4 123.1 94.1 85.8 Lifespan (hours) 1,000 1,000 10,000 15,000 10,000 25,000 Energy cost over 20 $289 $207 $67 $31 $41 $46 years @ 11 cents/kWh Total cost per 860 $307 $297 $78 $45 $52 $59 lumens over 20 years Comparison based on 6 hours use per day (43,800 hours over 20 yrs) 13 Energy Consumption 14 15 LED Monitor: LCD Display + White LED Lamp 16 Fluorescent Lamp 17 LED Lamp (White LED) Blue LED UV LED + + RGB LED Yellow Phosphor RGB Phosphor 18 LED Lighting 19 LED Lighting for Major League Baseball 20 21 History of Blue LED History of LED (Light Emitting Diode) 1907, H. J. Round (Marconi Electronics) . Observed light emission from SiC upon voltage 1927, Oleg Losev . Systematic study of electrical light emission from SiC Phil. Mag. 6, 1024 (1928). 23 History of LED 24 Visible Spectrum Wavelength Energy 25 Light Emitting Diode (LED) 26 Principle of LED p type n type Electrons (–) Band gap Hole(+) Photon Energy ~ Band Gap Energy 27 Elements for Semiconductors Band Gap . C (diamond), Si, Ge . GaAs, GaP, InP, GaN, AlN… . ZnO, ZnS, ZnSe, CdS, CdSe… 28 Band Gap Energy of Semiconductors 29 First Blue LED 1979 Matsushita Electric 30 High Power Blue LED Motivation: Blue Laser Diode (LD) Structure of Laser Laser Diode 31 High Power Blue LED Motivation: Blue Laser Diode (LD) Why Blue Laser Diode? . Optical Data Storage: CD, DVD, etc. 32 High Power Blue LED Motivation: Blue Laser Diode (LD) Why Blue Laser Diode? . Optical Data Storage: CD, DVD, etc. Data capacity ~ 1/휆 • Diffraction Limit Numerical Aperture (N.A.) 푁. 퐴. = 푛 sin 휗 33 High Power Blue LED Motivation: Blue Laser Diode (LD) Why Blue Laser Diode? . Optical Data Storage: CD, DVD, etc. 34 High Power Blue LD 35 High Power Blue LED For High Efficiency Light Emission . High quality semiconductor crystal . Easy doping: both n and p types Limitations of GaN . Difficult (almost impossible) to grow single crystals . No appropriate substrates Difficult to obtain high quality materials . Difficult to obtain p-type doping 36 Growth of High Quality GaN Metal Organic Vapor Phase Epitaxy (MOVPE, MOCVD) 37 Growth of High Quality GaN Low-Temperature Buffer Layer 38 P-type Doping 39 P-type Doping Mg doping followed by heat treatment 40 First High Brightness Blue LED 41 Blue Laser Diode! 42 Unfortunately,… Laser diodes are not as important as expected… 43 But, Solid state lighting exceeded everyone’s expectation! 44 Shuji Nakamura Born in 1954 1977, 1979, BE and ME, Tokushima Univ. 1979 Nichia Corporation 1988 Visiting Scientist, Univ. of Florida 1994 Dr. Eng. Tokushima Unvi. 1999 Professor, UC Santa Barbara 2000 Becomes US citizen 2001 Files lawsuit for $180 million against Nichia (settles for $9 million) 45 Words from the winners “Hold on to your dream. Don’t be afraid to make mistakes – experience is the best teacher.” – Isamu Akasaki “I think the most important thing is students have to find out is what you like, what I like, you know. And almost it's like a dream. And then, just work hard for your dream. I think that's the best way, you know, to a good invention.” – Shuji Nakamura 46 47.