Ilmenite and Rutile
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.. & METEORITIC RUTILE Peter R. Buseck Departments of Geology and Chemistry Arizona State University Tempe, Arizona Klaus Keil Space Sciences Division National Aeronautics and Space Administration Ames Research Center Mof fett Field, California r ABSTRACT Rutile has not been widely recognized as a meteoritic constituent. show, Recent microscopic and electron microprobe studies however, that Ti02 . is a reasonably widespread phase, albeit in minor amounts. X-ray diffraction studies confirm the Ti02 to be rutile. It was observed in the following meteorites - Allegan, Bondoc, Estherville, Farmington, and Vaca Muerta, The rutile is associated primarily with ilmenite and chromite, in some cases as exsolution lamellae. Accepted for publication by American Mineralogist . Rutile, as a meteoritic phase, is not widely known. In their sunanary . of meteorite mineralogy neither Mason (1962) nor Ramdohr (1963) report rutile as a mineral occurring in meteorites, although Ramdohr did describe a similar phase from the Faxmington meteorite in his list of "unidentified minerals," He suggested (correctly) that his "mineral D" dght be rutile. He also ob- served it in several mesosiderites. The mineral was recently mentioned to occur in Vaca Huerta (Fleischer, et al., 1965) and in Odessa (El Goresy, 1965). We have found rutile in the meteorites Allegan, Bondoc, Estherville, Farming- ton, and Vaca Muerta; although nowhere an abundant phase, it appears to be rather widespread. Of the several meteorites in which it was observed, rutile is the most abundant in the Farmington L-group chondrite. There it occurs in fine lamellae in ilmenite. The ilmenite is only sparsely distributed within the . meteorite although wherever it does occur it is in moderately large clusters - up to 0.5 mn in diameter - and it then is usually associated with chromite as well as rutile (Buseck, et al., 1965), Optically, the rutile has a faintly bluish tinge when viewed in reflected, plane-polarized light with immersion objectives. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Developments in Uranium Resources, Production, Demand and the Environment
IAEA-TECDOC-1425 Developments in uranium resources, production, demand and the environment Proceedings of a technical committee meeting held in Vienna, 15–18 June 1999 January 2005 IAEA-TECDOC-1425 Developments in uranium resources, production, demand and the environment Proceedings of a technical committee meeting held in Vienna, 15–18 June 1999 January 2005 The originating Section of this publication in the IAEA was: Nuclear Fuel Cycle and Materials Section International Atomic Energy Agency Wagramer Strasse 5 P.O. Box 100 A-1400 Vienna, Austria DEVELOPMENTS IN URANIUM RESOURCES, PRODUCTION, DEMAND AND THE ENVIRONMENT IAEA, VIENNA, 2004 IAEA-TECDOC-1425 ISBN 92–0–112904–1 ISSN 1011–4289 © IAEA, 2005 Printed by the IAEA in Austria January 2005 FOREWORD Globalization has led to the growing importance of the uranium production industries of the world’s developing countries. Though trade restrictions continue to impede completely free access to the worldwide uranium market, the uranium resources and production capabilities of the developing countries are becoming increasingly important in assuring the adequacy of uranium supplies to meet projected worldwide demand. Therefore, papers presented at this meeting provide an important overview of uranium production operations in developing countries as well as offering insight into future production plans and potential. Along with their increasing contribution to worldwide uranium supply, the environmental impact of uranium production in developing countries has come under increasing scrutiny -
Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine
nanomaterials Review Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine Daniel Ziental 1 , Beata Czarczynska-Goslinska 2, Dariusz T. Mlynarczyk 3 , Arleta Glowacka-Sobotta 4, Beata Stanisz 5, Tomasz Goslinski 3,* and Lukasz Sobotta 1,* 1 Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 2 Department of Pharmaceutical Technology, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 3 Department of Chemical Technology of Drugs, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 4 Department and Clinic of Maxillofacial Orthopedics and Orthodontics, Poznan University of Medical Sciences, Bukowska 70, 60-812 Poznan, Poland; [email protected] 5 Department of Pharmaceutical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] * Correspondence: [email protected] (T.G.); [email protected] (L.S.) Received: 4 January 2020; Accepted: 19 February 2020; Published: 23 February 2020 Abstract: Metallic and metal oxide nanoparticles (NPs), including titanium dioxide NPs, among polymeric NPs, liposomes, micelles, quantum dots, dendrimers, or fullerenes, are becoming more and more important due to their potential use in novel medical therapies. Titanium dioxide (titanium(IV) oxide, titania, TiO2) is an inorganic compound that owes its recent rise in scientific interest to photoactivity. After the illumination in aqueous media with UV light, TiO2 produces an array of reactive oxygen species (ROS). The capability to produce ROS and thus induce cell death has found application in the photodynamic therapy (PDT) for the treatment of a wide range of maladies, from psoriasis to cancer. -
Electronic Structure and Optical Properties of Prominent Phases of Tio2: First-Principles Study
Pramana – J. Phys. (2017) 89:5 © Indian Academy of Sciences DOI 10.1007/s12043-017-1400-5 Electronic structure and optical properties of prominent phases of TiO2: First-principles study SANTOSH SINGH and MADHVENDRA NATH TRIPATHI∗ Department of Pure and Applied Physics, Guru Ghasidas Vishwavidyalaya (Central University), Koni, Bilaspur 495 009, India ∗Corresponding author. E-mail: [email protected] Published online 19 June 2017 Abstract. First-principles study based on density functional theory (DFT) of two prominent phases, the rutile and the anatase phases, of titanium dioxide (TiO2) are reported within the generalized gradient approximation (GGA). Our calculated band structure shows that there is a significant presence of O-2p and Ti-3d hybridization in the valence bands. These bands are well separated from the conduction bands by a direct band gap value of 1.73 eV in the rutile phase and an indirect band gap value of 2.03 eV in the anatase phase, from to X. Our calculations reproduced the peaks in the conduction and valence band, are in good agreement with experimental observations. Our structural optimization for the rutile and anatase phase led to lattice parameter values of 4.62 Å and 2.99 Å rutile and 3.80 Å and 9.55 Å for anatase for a and c. The static dielectric values 7.0 and 5.1 for the rutile and anatase phases respectively are in excellent agreement with experimental results. Our calculation of optical properties reveals that maximum value of the transmittance in anatase phase of TiO2 may be achieved by considering the anisotropic behaviour of the optical spectra in the optical region for transparent conducting application. -
The I\,Iagnetic Separation of Soi'ie Alluvial I,Iinerals in I'ialaya*
THE AMERICAN MINERAI,OGIST, VOL. 41, JULY AUGUST, 1959 THE I\,IAGNETIC SEPARATION OF SOI'IE ALLUVIAL I,IINERALS IN I'IALAYA* B. H. FnNrant, Minerals Eramination Diaision, GeologicalSurttey D epartment, F'ederotion of M al,aya. Assrnlcr This paper presents the results of a seriesof magnetic separationswhich have been in- vestigated {or a number of minerals occurring in X{alayan alluvial concentrates.The pur- pose of the investigations was to establish,by the isolation of individual mineral species,a reproducible and reliable method for the identification and quantitative estimation of minerals in alluvial concentrates examined by the Geological Survey in Malaya In par- ticular was sought the isolation of columbite from ubiquitous ilmenite. All the separations were made on the small, highly sensitive Frantz Isodynamic Model L-1 laboratory separa- tor, The minerals which have been successfully separated include ailanite, anatase, andalu- site (and chiastolite), arsenopyrite, brookite, cassiterite,columbite, epidote, gahnite, garnet (pink), ilmenite, manganeseoxide (51.6/e Mn), monazite, pyrite, rutile, scheelite,siderite, staurolite, thorite, topaz, tourmaline, uranoan monazite, wolframite, xenotime, and zircon. PnocBpunp When using an inclined feed, the Frantz Isodynamic separator (see Figs. 1(A) & (B)) hasthree inherent variables. These are the field strengLh (current used),the sideslope, and the forward slope. 5;6s $lope wdrd 511)Pe (A) (B) Irc. 1. Diagrammatic representation of side slope and forward slope. The field strength is increasedby means of a rheostat which raises the current from zero in stagesof 0.05 amps. to 1.4 amps. Early in the investigationsit was decidedthat stepsof 0.1 amp. would be sufficiently gradual. -
Uranium and Thorium Resources in India: UNFC System
Uranium and thorium resources in India: UNFC system P.S.Parihar Atomic Minerals Directorate for Exploration and Research Department of Atomic Energy Government of India 1 21/08/2013 Government of India’s Policy on Atomic Minerals The federal status of the DAE and the powers invested in it under the Indian Atomic Energy Act (1948 and 1962) as amended from time to time, bestow upon it several rights to facilitate atomic mineral exploration. The more significant ones are- . Exclusive rights to conduct exploration for uranium, thorium and other prescribed minerals such as beryllium, lithium, niobium, tantalum and rare-earth elements all over the country . Exclusive rights to buy prescribed minerals from private mine owners produced incidental to mining of other economic minerals. 30/10/2013 - . Rights to access to surface and sub-surface data on areas under exploration or mining/recovery for oil, coal, minerals and ground water by Government or Public Sector Organisations. The facility includes carrying out of gamma-ray logging of boreholes and checking of mine workings and collection of samples etc. 2 UNFC workshop, New Delhi workshop, UNFC Government of India’s Policy on Atomic Minerals Uranium exploration, production and utilisation are under the control of Central Government. Only public sector companies under Government of India are allowed to explore and mine atomic minerals viz. U, Th, etc. Present system of reporting of uranium reserves in India is as per the IAEA system of uranium resource classification . Indicated – [Reasonable -
Arizona Department of Mines and Mineral Resources
Arizona Department of Mines and Mineral Resources 1502 West Washington, Phoenix, AZ 85007 Phone (602) 255-3795 1-800-446-4259 in Arizona FAX (602) 255-3777 www.admmr.state.az.us Titanium Circular 9, August 1982 by Michael N Greeley, Mining Engineer Titanium is a lightweight metal that is virtually as strong as steel. As our technologies and industries have become increasingly sophisticated, demand for this relatively scarce, but highly desirable metal has increased rapidly. This information circular is written to acquaint the prospector and miner with titanium and its uses. A resume of typical geologic environments and production possibilities in Arizona is given. Uses phisticated needs will vie for a greater share of the The largest market for titanium is in the manufacture world's supply of this unique metal. of pigments. Because of its high refractive index, titanium dioxide pigment imparts whiteness, opacity, Geology and Mineralogy and brightness to paints, varnishes, and lacquers. The most important titanium minerals are anatase Titanium pigment is also used greatly in paper coat (Ti0 ), ilmenite (FeTi0 ), perovskite (CaTi03), ru- 2 3 ings and as paper fillers. Many plastic products such tile (Ti0 ), sphene (CaTiSiOS), and leucoxene. Leu as polyethylene, polyvinyl chloride, and polystyrene 2 coxene, a mineraloid, is an alteration product of il incorporate titanium pigment because of its resis menite, from which a portion of the iron has been tance to degradation by ultraviolet light and its leached. Currently the minerals of commercial inter chemical inertness. est are ilmenite, leucoxene, and rutile. Production historically has come from three types of deposits: Titanium dioxide pigment and other titanium com Beach and stream placers, massive deposits of titani pounds are used in many miscellaneous applications, ferous iron ore, and igneous complexes in which ru including rubber tires, floor and wall coverings, tile occurs in association with anorthosite and simi glass fibers, ceramic capacitors, carbide cutting lar, mafic crystalline rocks. -
Saraf Agencies Private Ltd Kolkata
SARAF AGENCIES PRIVATE LTD KOLKATA TECHNO ECONOMIC FEASIBILITY REPORT FOR INTEGRATED 36000 TPA HIGH TITANIUM SLAG, 20,000 TPA PIG IRON, 30000 TPA TITANIUM DIOXIDE PIGMENT PLANT IN ODISHA NOVEMBER 2014 DEVELOPMENT CONSULTANTS PRIVATE LIMITED CONSULTING ENGINEERS 24 PARK STREET, KOLKATA 700016 PHONE: (91) 33 4012 4500, 2249 7603 /05/09/10/12 FAX: (91) 33 4012 4545, 2249 2340 /289 E-mail: [email protected] KOLKATA MUMBAI DELHI CHENNAI SARAF DCPL TABLE OF CONTENTS : PROJECT AT A GLANCE : SECTION – 1 : INTRODUCTION & EXECUTIVE SUMMARY SECTION – 2 : MARKET SCENARIO SECTION - 3 : PLANT SITE & INFRASTRUCTURE SECTION - 4 : PROCESS & PLANT PARTICULARS SECTION – 5 : RAW MATERIALS, PRODUCTS, UTILITY & AUXILIARY SERVICES SECTION – 6 : PLANT LAYOUT & CIVIL WORK SECTION – 7 : POLLUTION & ENVIRONMENTAL CONTROL SECTION – 8 : MAN-POWER SECTION – 9 : PROJECT IMPLEMENTATION SCHEDULE SECTION – 10 : COST ESTIMATES & FINANCIAL ANALYSIS 1 SARAF DCPL PROJECT AT A GLANCE Î Project Title : 36000 TPA HIGH TITANIUM SLAG, 20,000 TPA PIG IRON, 30000 TPA TITANIUM DIOXIDE PIGMENT PLANT Î Owner : SARAF AGENCIES PVT LTD Î Project Location : Chhatrapur, Dist. Ganjam, Odisha - Nearest Rail Station : Chhatrapur (5 Km) - Nearest Highway NH-16 (0.6 Km) - Nearest Town : Chhatrapur (4 Km) - Nearest Port : Paradeep : 260 Km. Vizag : 250 Km. Gopalpur Port –under construction (12 Km) - Nearest Airport : Bhubaneswar : 150 Km. - Survey of India Map : 74 A/15 Î Capacity of Plant : 36000 TPA Titanium Slag, 20,000 TPA Pig Iron, 30000 TPA Titanium Dioxide (both Anatase & Rutile Grade) Î Technology Source/know- : CHINA how for Titanium Project : HPWY (CHINA) for Titanium Slag Plant : Chong Qung Chemical Engineering Design and Research Institute (CCDRI) will supply Process Technology, Basic & Detailed Engineering for Titanium Dioxide Plant. -
CRYSTAL SRUKTUR of CALCIUM TITANATE (Catio3) PHOSPHOR DOPED with PRASEODYMIUM and ALUMINIUM IONS
CRYSTAL SRUKTUR OF CALCIUM TITANATE (CaTiO3) PHOSPHOR DOPED WITH PRASEODYMIUM AND ALUMINIUM IONS STRUKTUR KRISTAL FOSFOR KALSIUM TITANIA DIDOPKAN DENGAN ION PRASEODYMIUM DAN ALUMINIUM IONS Siti Aishah Ahmad Fuzi1* and Rosli Hussin2 1 Material Technology Group, Industrial Technology Division, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor Darul Ehsan, Malaysia. 2 Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310 Skudai, Johor 1*[email protected], [email protected] Abstract The past three decades have witnessed rapid growth in research and development of luminescence phenomenon because of their diversity in applications. In this paper, Calcium Titanate (CaTiO3) was studied to find a new host material with desirable structural properties for luminescence-based applications. Solid state reactions o 3+ methods were used to synthesis CaTiO3 at 1000 C for 6 hours. Crystal structure of CaTiO3 co-doped with Pr 3+ and Al were investigated using X-Ray Diffraction (XRD) method. Optimum percentage to synthesis CaTiO3 was 3+ obtained at 40 mol%CaO-60 mol%TiO2 with a single doping of 1 mol%Pr . However, a crystal structure of 4 mol% of Al3+ co-doped with Pr3+ was determined as an optimum parameter which suitable for display imaging. Keywords: calcium titanate, anatase, rutile Abstrak Semenjak tiga dekad yang lalu telah menunjukkan peningkatan yang ketara bagi kajian dan pembangunan dalam bidang fotolumiscen. Peningkatan ini berkembang dengan meluas disebabkan oleh kebolehannya untuk diaplikasikan dalam pelbagai kegunaan harian. Dalam manuskrip ini, kalsium titania (CaTiO3) telah dikaji untuk mencari bahan perumah dengan sifat struktur yang bersesuaian bagi aplikasi luminescen. Tindak balas keadaan o pepejal telah digunakan bagi mensintesis CaTiO3 pada suhu 1000 C selama 6 jam. -
INCLUSIONS in AQUAMARINE from AMBATOFOTSIKELY, MADAGASCAR Fabrice Danet, Marie Schoor, Jean-Claude Boulliard, Daniel R
NEW Danet G&G Fall 2012_Layout 1 9/27/12 11:31 AM Page 205 RAPID COMMUNICATIONS INCLUSIONS IN AQUAMARINE FROM AMBATOFOTSIKELY, MADAGASCAR Fabrice Danet, Marie Schoor, Jean-Claude Boulliard, Daniel R. Neuville, Olivier Beyssac, and Vincent Bourgoin grams of translucent to transparent beryl were pro- duced, as well as several tonnes of opaque material In January 2012, aquamarine crystals containing for industrial use. While only a very small percentage interesting inclusions were extracted from the Am- was suitable for faceting, several hundred aqua- batofotsikely area northwest of Antsirabe, Mada- marines in the 1–35 ct range have been cut. In April gascar. These specimens displayed various types 2012, one of the authors (FD) traveled to the locality of eye-visible and microscopic inclusions, and and obtained representative samples. some had an unusual form. Raman microspec- troscopy identified reddish brown plate lets as Location and Geologic Setting. The workings are lo- hematite, while ilmenite was found as black cated less than 1 km north of Ambatofotsikely (a village platelets, black needles, and distinctive dark gray now locally known as Ambatofotsy Carole), 22 km dendrites. Similar inclusions are known in beryl north-northwest of Ankazomiriotra, and 74 km north- from Brazil, India, Mozambique, and Sri Lanka. west of Antsirabe. The deposit is centered at coordinates 19°27.662¢S, 46°27.450¢E, at an elevation of 1,010 m. The site is accessed by a paved road (RN 34) from ining activity near the central Malagasy village Antsirabe to a point 16 km west of Ankazomiriotra. of Ambatofotsikely was first documented nearly From there, a trail extends 15 km to Ambatofotsikely. -
Info Sheet This Is Followed by Heliborne Gamma-Ray Studies of Ore, As a Prelude to Commercial Mining
Research and Development: In order to multidisciplinary geoscientific skills. AMD will understand the genesis and controls of uranium continue its exploration efforts to fullfil the atomic ATOMIC MINERALS DIRECTORATE FOR mineralisation, basic research in the fields of minerals requirement of country’s nuclear power geology, geophysics, geochemistry and also programme. EXPLORATION AND RESEARCH (AMD) in allied topics such as physics, chemistry and electronics is being carried out. Atomic Minerals Directorate for Exploration spectrometric and geophysical surveys1 to identify Other Activities: and Research (AMD) is one of the oldest units potential targets with abnormal radioelemental *AMD is also entrusted to carry out geological / of Department of Atomic Energy (DAE) and plays concentration. geotechnical studies related to site selection for an important role in the front and back end of nuclear power plants and repositories for the the nuclear fuel cycle. AMD was established as The potential areas delineated by heliborne disposal of radioactive wastes generated from Rare Minerals Survey Unit in 1949, subsequently surveys are taken up for ground reconnaissance these plants. renamed as Raw Materials Division (RMD) and radiometrics2 using portable gamma-ray *AMD provides professional and analytical brought under the Atomic Energy Commission measuring instruments such as Scintillometer, services. on October 3, 1950. RMD was later renamed as Gamma Ray Spectrometer etc., regional/detailed *AMD Studentship Programme has been initiated Atomic Minerals Division in 1958 and rechristened geological, geochemical (rock, soil, radon, water to impart basic field training and to encourage as Atomic Minerals Directorate for Exploration and and stream sediments) and ground-geophysical university students to take up their dissertation Research (AMD) in 1998.