Part 10: Bulk Transfer of Dangerous Goods

PART 10: BULK TRANSFER OF DANGEROUS GOODS

CHAPTER 10.1 - TRANSFER EQUIPMENT 10.1.1 APPLICATION AND DEFINITIONS

10.1.1.1 Application This Part applies to the transfer by gravity, pump or pressure differential of liquid, solid or gaseous dangerous goods into or out of a tank vehicle, or into or out of a portable tank, demountable tank, bulk container, pressure drum, tube, MEGC or IBC that is on a vehicle, utilising pipework and/or hose assembly.

10.1.1.2 Definitions For the purposes of this Part: Maximum delivery pressure means the maximum pressure that can occur in a system regardless of whether or not it is under pump pressure or at zero flow, including the effects of dead heading and system back pressure; Maximum design pressure means the maximum pressure for which hose assembly has been designed and tested; Transfer out of a vehicle includes transfer out of the tank of a tank vehicle or from a portable tank, demountable tank, bulk container, pressure drum, tube, MEGC or IBC that is on a vehicle; Transfer into a vehicle includes transfer into the tank of a tank vehicle or into a portable tank, demountable tank, bulk container, pressure drum, tube, MEGC or IBC that is on a vehicle. 10.1.2 TRANSFER EQUIPMENT AND HOSE ASSEMBLIES

10.1.2.1 General Transfer equipment and hose assemblies used for transfer of dangerous goods must be fit for purpose.

10.1.2.2 Hose assemblies for Class 2 (other than LP Gas or anhydrous ammonia) A hose assembly used to transfer dangerous goods of Class 2, other than LP Gas or anhydrous ammonia (UN 1005), must have a maximum design pressure of not less than 1.5 times the maximum delivery pressure of the transfer system in which the hose is used.

10.1.2.3 Hose assemblies for LP Gas A hose assembly used to transfer LP Gas must: (a) comply with AS/NZS 1869 or UL 21; (b) be tested in accordance with AS/NZS 1869; and (c) be retested in accordance with AS/NZS 1596.

10.1.2.4 Hose assemblies for anhydrous ammonia (UN 1005) A hose assembly used to transfer anhydrous ammonia (UN 1005) must: (a) comply with AS/NZS 2022; and (b) be tested in accordance with AS/NZS 2022. PART 10: BULK TRANSFER OF DANGEROUS GOODS

10.1.2.5 Hose assemblies for Class 3 petroleum products

10.1.2.5.1 A hose assembly used to transfer dangerous goods of Class 3 petroleum products must: (a) comply with AS 2683; and (b) be tested in accordance with AS 2683.

10.1.2.5.2

10.1.2.6 Hose assemblies for liquid dangerous goods other than Class 2 or Class 3 petroleum products A hose assembly used to transfer dangerous goods in liquid form other than Class 2 or Class 3 petroleum products must: (a) comply with AS 2594; (b) be tested in accordance with AS 2594; and (c) have a rated maximum design pressure of not less than 1.5 times the maximum delivery pressure of the transfer system in which the hose is used. 10.1.3 HOSE TESTING

10.1.3.1 Periodic inspection A hose assembly must be inspected for damage over its entire length at intervals of not more than one month.

10.1.3.2 Electrical continuity testing

10.1.3.2.1 This clause applies to a hose assembly used to transfer: (a) dangerous goods of Class 3 or 4; or (b) dangerous goods (other than Class 2) with a Subsidiary Hazard of 3 or 4.

10.1.3.2.2 The hose assembly must be tested in accordance with AS 1180.13B for electrical continuity before it is first used to transfer dangerous goods. The resistance of the hose assembly must comply with the resistance values specified for electrical properties in AS 2683 for the kind of hose assembly being tested.

10.1.3.2.3 The hose assembly must be retested in accordance with AS 1180.13B, and, where applicable to the kind of hose assembly being tested, for electrical continuity in accordance with AS 1180.13C at intervals of no more than 6 months. The resistance of the hose assembly must comply with the resistance values specified for electrical properties in AS 2683 for the kind of hose assembly being tested.

10.1.3.2.4 If a hose assembly consists of two or more Kind 1 hose assemblies1 coupled together, it must be constructed, assembled and maintained, so that the resistance between the end couplings does not exceed 10 ohms.

1 Kind 1 hose as described in AS 2683. PART 10: BULK TRANSFER OF DANGEROUS GOODS

10.1.3.2.5 If a hose assembly consists of two or more hose assemblies which are not of Kind 1, it must be constructed, assembled and maintained so that the resistance between the couplings does not exceed the resistance values for electrical properties in AS 2683 for the relevant kind of hose assembly.

10.1.3.3 Hydrostatic pressure testing Unless otherwise specified in this Code or a relevant Standard, a hose assembly used to transfer dangerous goods must be hydrostatically tested at the pressure required by this Code, which must be not less than the rated maximum working pressure: (a) not more than 12 months before its initial use; and (b) thereafter at the intervals required by the relevant standard, or, otherwise, on or before each anniversary of its first use.

10.1.3.4 Keeping records

10.1.3.4.1 Each hose assembly must be marked with a distinctive identifying number.

10.1.3.4.2 An accurate record must be kept for the life of each hose assembly of: (a) the date on which each test required to be carried out by this Chapter is carried out; (b) the nature of the test carried out; (c) the date on which maintenance work is carried out on the hose assembly; and (d) the nature of the maintenance work.

PART 10: BULK TRANSFER OF DANGEROUS GOODS

CHAPTER 10.2 - TRANSFER REQUIREMENTS 10.2.1 WHERE TO TRANSFER DANGEROUS GOODS

10.2.1.1 Position of vehicle during transfer of Division 2.1 or Class 3

10.2.1.1.1 Dangerous goods of Division 2.1, Class 3, or with a Subsidiary Hazard 2.1 or 3, must not be transferred into or out of a road vehicle unless the vehicle is positioned: (a) so that it can be driven away in a forward direction; or (b) if it is not reasonably practicable to drive the vehicle in a forward direction owing to the layout of the site so that it can be driven away with minimal manoeuvring.

10.2.1.1.2 The area through which the vehicle needs to move or manoeuvre in order to leave the premises on which the transfer takes place must, as far as practicable, be kept clear while the vehicle is on the premises.

10.2.1.2 Transfer in a public area

10.2.1.2.1 This sub-section applies at any place that is: (a) in a built up area with public access; or (b) within 15 metres of any building or any other place where there is likely to be a concentration of people, other than a building on the premises where the transfer takes place.

10.2.1.2.2 Dangerous goods of packing group I or Division 2.3 [other than ammonia, anhydrous (UN 1005) or ammonia solution (UN 3318)] must not be transferred out of a road vehicle in a place described in 10.2.1.2.1.

10.2.1.2.3 Dangerous goods must not be transferred out of one vehicle into another vehicle in a place described in 10.2.1.2.1.

10.2.1.3 Transfer operation within a designated transfer area If dangerous goods are to be transferred into or out of a vehicle, and the occupier of premises has marked or otherwise designated an area on the premises in which a transfer operation is to take place, the vehicle must be parked within the designated area during the transfer operation.

10.2.1.4 Transfer in enclosed space Dangerous goods must not be transferred into or out of a vehicle that is in an enclosed space if the transfer is likely to give rise to dangerous concentrations of dusts, mists or vapours.

10.2.1.5 Positioning of hose assembly during transfer If dangerous goods are to be transferred into or out of a vehicle in an area which is accessible to other vehicles, all reasonably practicable measures must be taken to prevent any vehicle from driving over the hose assembly or striking its connections.

PART 10: BULK TRANSFER OF DANGEROUS GOODS

10.2.2 PREVENTING FIRE DURING A TRANSFER OPERATION

10.2.2.1 Distance from ignition sources During a transfer operation into or out of a vehicle, there must be no source of ignition: within any hazardous area determined in accordance with AS/NZS 60079.10.11 .

10.2.2.2 Engine precautions

10.2.2.2.1 During transfer of dangerous goods of Class, Division or Subsidiary Hazard 2.1, 3 or 4 out of a road vehicle, the engine of the vehicle must remain stopped unless the transfer involves the use of a pump or compressor driven by the vehicle’s engine. This does not prevent the minimal necessary use of the engine to clear the contents of hoses back into the tank following the transfer.

10.2.2.2.1A During transfer of dangerous goods of Class, Division or Subsidiary Hazard 2.1, 3 or 4 into a road vehicle, the engine of the vehicle must remain stopped unless the vehicle is a vacuum tank vehicle.

10.2.2.2.2 The engine of the vehicle, and any internal combustion auxiliary engine on the vehicle, must be stopped while hose connections for the transfer of dangerous goods of Division or Subsidiary Hazard 2.1 are coupled to or uncoupled from the vehicle or tank on the vehicle.

10.2.2.3 Electrical bonding

10.2.2.3.1 Before LP Gas is transferred into or out of a vehicle, the supplying receptacle must be electrically bonded to the receiving receptacle in accordance with AS/NZS 1596.

10.2.2.3.2 Where dangerous goods of Division 2.1 (other than LP Gas) are transferred into or out of a vehicle and the receiving receptacle is not an underground tank, the supplying receptacle must be electrically bonded to the receiving receptacle before the transfer commences. The bonding must remain in place until all hose assemblies have been uncoupled and all closures have been closed.

10.2.2.3.3 Before dangerous goods of Class 3 are transferred into or out of a vehicle, the supplying receptacle must be electrically bonded to the receiving receptacle in accordance with AS 1940.

10.2.2.4 Loading spear for Class 3 If a tank is filled from the top with dangerous goods of Class or Subsidiary Hazard 3, and is not filled through a tight fill connection and fill pipe in accordance with AS 1692, the loading spear must be in contact with the bottom of the tank while the goods are being transferred.

1 AS/NZS 60079.10.1 is an internationally based Standard that has now replaced the AS/NZS 2430 series of Standards. These Standards are recognised nationally as defining hazardous areas. They prescribe distances both in text and pictorially. These distances vary with the type of dangerous goods and, in the case of tanker loading, are different for installations with or without vapour recovery. PART 10: BULK TRANSFER OF DANGEROUS GOODS

10.2.2.5 Heater restrictions Except where permitted by 13.1.3.5, if a road tank vehicle is equipped with a burner or other means to heat the cargo, the heater must not be operated during a transfer operation. 10.2.3 TRANSFER OF DANGEROUS GOODS - GENERAL REQUIREMENTS

10.2.3.1 Dangerous goods must not be transferred into or out of a vehicle, unless the vehicle is secured against movement.

10.2.3.2 If dangerous goods are transferred into or out of a vehicle, a person must: (a) remain in proximity with the vehicle during the transfer operation; and (b) be in a position to observe all relevant valves, fittings, gauges and hose connections that are used or may be used during the transfer operation; and (c) have access to all equipment necessary to stop the transfer operation in the event of an escape, leak or spill.

10.2.3.3 Dangerous goods must not be transferred into or out of a road vehicle, while the cabin of the vehicle is occupied.

10.2.3.4 The level of light at all valves, fittings, gauges and hose connections that are used or may be used during a transfer operation must be adequate to allow the transfer operation to be conducted safely.

10.2.3.5 If dangerous goods are transferred under gas pressure into or out of a vehicle: (a) the design pressure of the supplying receptacle must not be exceeded; and (b) the gas used in the transfer operation must be chemically inert to the dangerous goods being transferred; and (c) air must not be used to transfer dangerous goods of Class 3 or 4 or with a Subsidiary Hazard of 3 or 4.

10.2.3.6 A hose used in connection with a transfer operation should be handled so as to avoid excessive curvature, stress, abrasion or kinking that may damage the hose or its connections.

10.2.3.7 Despite 10.2.3.1 and 10.2.3.3, if a bitumen tank vehicle is coupled with road making plant, bitumen may be transferred between the vehicles by a connecting hose while the vehicles are in motion and while the cabins are occupied. However the tank vehicle drive away protection system required by AS2809 may only be overridden by the road making plant coupled to the bitumen tank vehicle to allow the coupled units to be moved.

PART 10: BULK TRANSFER OF DANGEROUS GOODS

10.2.4 TRANSFER OF GAS

10.2.4.1 LP Gas must be transferred into or out of a vehicle in accordance with AS/NZS 1596.

10.2.4.2 Liquefied gas must not be transferred into a storage tank or other receptacle housed within a building unless: (a) the building is designed and used solely for the purpose of storing dangerous goods of Class 2; or (b) the building may be used for that purpose under a law of the State of Territory in which the building is located that relates to the storage and handling of dangerous goods.

10.2.4.3 Subject to 10.2.4.1, when dangerous goods of Division 2.1 or Division 2.3 are transferred out of a vehicle into a storage receptacle and if: (a) the line of sight between the vehicle, portable tank or MEGC and the filling point of the storage container is obstructed so that one cannot be seen from the other; or (b) the transfer is at a place described in 10.2.1.2.1: a person capable of using the transfer equipment must remain at the vehicle and another person capable of using the transfer equipment must remain at the storage container.

10.2.4.4 A person must not transfer liquefied oxygen into or out of a road vehicle unless, during the transfer operation, all surfaces within a distance of 1 metre of the transfer hose are made of concrete or other non- combustible material. 10.2.5 TRANSFER OF DANGEROUS GOODS OF CLASS 3

10.2.5.1 Dangerous goods of Class or Subsidiary Hazard 3 must be transferred out of a vehicle into a storage receptacle, in accordance with AS 1940. Direct transfer of these goods out of the vehicle into drums or smaller packagings is not permitted except at facilities designed or designated for the purpose, taking into account the requirements of AS 1940 and AS/NZS 60079.10.

10.2.5.2 If a pump is fitted to or carried on the vehicle to or from which dangerous goods of Class or Subsidiary Hazard of 3 are transferred: (a) the propulsion engine of the vehicle must not be used to power the pump unless: (i) the engine is a compression-ignition engine; and (ii) the pump and all associated pipework are shielded from the engine of the vehicle by the provision of a fire shield or by equally effective means; and (iii) the pump driving engine requirements of AS 2809.2 are complied with; and (b) a spark ignition engine must not be used to power an auxiliary or portable pumping unit; and (c) an auxiliary or portable pumping unit powered by a compression- ignition engine must not be used unless the unit is approved by a Competent Authority for that purpose and is operated in accordance with the approval; and PART 10: BULK TRANSFER OF DANGEROUS GOODS

(d) an electric motor must not be used to power the pump unless the motor and all associated electrical fittings and equipment are suitable for use in a Zone 1 hazardous area as defined in AS/NZS 60079.10.

10.2.5.3 All valves and closures that were removed or opened to enable the transfer to take place must be reinstated or closed after the transfer is completed.

10.2.5.4 Manner of filling

10.2.5.4.1 Except where 10.2.5.4.2 applies, when dangerous goods of Class or Subsidiary Hazard 3 are transferred into or out of a vehicle, the receptacle on the vehicle and the receiving tank or storage receptacle must be connected by pipeline and hose connection.

10.2.5.4.2 A hand-held nozzle may be used for the transfer of dangerous goods of Class or Subsidiary Hazard 3 into or out of a vehicle if: (a) the transfer: (i) takes place on premises which are a farm or mine site; or (ii) is into or out of a tank described in AS 1940 as a minor storage tank; and (b) the receiving tank or storage container is fitted with a fill pipe at the tank or container opening.

PART 10: BULK TRANSFER OF DANGEROUS GOODS

CHAPTER 10.3 - ULLAGE AND MAXIMUM PERMITTED FILLING RATIO

NOTE: This Chapter applies only to the filling of tank vehicles. Portable tanks and MEGCs must be filled only in accordance with the provisions for use in Chapter 4.2, as referenced: (a) for portable tanks, –from the portable tank instructions and special provisions for the particular dangerous goods in Columns (10) and (11) of the Dangerous Goods List in Chapter 3.2; or (b) for MEGCs, –from packing instruction P200 in Chapter 4.1. Bulk containers must be filled in accordance with the provisions for use in Chapter 4.3., as referenced from Column (10) of the Dangerous Goods List. IBCs must be filled in accordance with the provisions of 4.1.1, 4.1.2 and the relevant IBC packing instructions and special packing provisions in 4.1.4.2, as referenced from Columns (8) and (9) of the Dangerous Goods List. 10.3.1 ULLAGE

10.3.1.1 Liquid dangerous goods (other than Class 2) Unless elsewhere specified in this Code or a relevant code or standard referenced in this Code, the ullage in a tank vehicle containing liquid dangerous goods (other than dangerous goods of Class 2) must not be less than: (a) 2%- for dangerous goods having a coefficient of expansion of not more than 90 x 10-5 per degree Celsius; (b) 3%- for dangerous goods having a coefficient of expansion of more than 90 x 10-5 but not more than 135 x 10-5 per degree Celsius; (c) 4%- for dangerous goods having a coefficient of expansion of more than 135 x 10-5 but not more than 180 x 10-5 per degree Celsius; or (d) 5%- for dangerous goods having a coefficient of expansion of more than 180 x 10-5 per degree Celsius.

10.3.1.2 Ullage of large tank or compartment

10.3.1.2.1 This clause applies to liquids having a viscosity less than 2,680 mm2/s at 20°C, or the maximum temperature of the substance during transport in the case of the heated substance, that are either: (a) dangerous goods; or (b) liquids other than dangerous goods that are transported in the same tank, or in another tank on the same vehicle or combination vehicle, as dangerous goods.

10.3.1.2.2 Any liquid described in 10.3.1.2.1, must not be transported in a large compartment tank as defined in AS 2809.1, if the ullage in the large compartment is more than 20% but less than 85%. PART 10: BULK TRANSFER OF DANGEROUS GOODS

NOTE 1: 10.3.1.2.2 applies only to those tanks or compartments of a road tank vehicle that individually exceed 8,600 L. It does not apply to portable tanks, or to smaller tanks or compartments on the same vehicle.

NOTE 2: This ullage requirement corresponds to a restriction on the transport of a large compartment tank having a degree of filling of more than 15% but less than 80%.

NOTE 3: Different limits apply to the compartment sizes and degree of filling of portable tanks in 4.2.1.9.6.

10.3.1.2.3 10.3.1.2.2 does not apply to liquefied gases, or to TARS, LIQUID (UN 1999), or to elevated temperature liquids (UN 3256 and 3257), or to waste dangerous goods transported in vacuum tank vehicles.

10.3.1.3 Ullage—Class 2 refrigerated liquid If dangerous goods of Class 2 in the form of a refrigerated liquid are transferred into a tank vehicle, the tank must not be filled with liquid to the extent that, when the liquid is uniformly at the temperature which corresponds to the start-to-discharge pressure of: (a) the safety relief valve of the tank; or (b) where the tank is fitted with a pressure control valve in addition to a safety relief valve— the pressure control valve; the ullage below the inlet to the valve is less than 2% when the tank is level.

NOTE: Consideration should also be given to Portable Tank Instruction T75 and any Portable Tank Special Provisions specified for the substance in Column (11) of the Dangerous Goods List in Chapter 3.2. 10.3.2 MAXIMUM PERMITTED FILLING RATIO - CLASS 2 LIQUID

10.3.2.1 The maximum permitted filling ratio for a tank vehicle containing dangerous goods of Class 2 in a liquefied form (other than refrigerated liquid) is: (a) for goods covered under AS/NZS 1596, as specified in the filling instructions set out in that Standard; (b) for tank vehicles with a capacity of 5000L or more transporting propane, 0.45, as determined in accordance with Table 2.1 of AS 2809.3; (c) in all other circumstances, the relevant ratio specified in Portable Tank Instruction T50 in Chapter 4.2; (d) if paragraph (c) applies but no ratio is specified in Portable Tank Instruction T50 – the ratio determined by a Competent Authority in relation to goods of that type when transferred into a tank of that type.

PART 11: DOCUMENTATION

Note: The numbering and structure of Chapter 11 was revised in 2019 to align with that of the UN Model Regulations. This was necessary to facilitate future updates to the Code.

CHAPTER 11.1 - TRANSPORT DOCUMENTATION Introductory Notes

NOTE 1: Documentation prepared in accordance with this Part may not be acceptable for sea or air transport. See the relevant modal code or Chapter 5.4 of the UN Model Regulations for details of documentation required for intermodal transport by sea or air.

NOTE 2: The IATA “Shipper’s Declaration for Dangerous Goods” will also be acceptable under this Code as a transport document if all the required information is inserted.

NOTE 3: Division 11.1 of the Regulations specifies who must provide and carry dangerous goods transport documentation.

11.1.1 DANGEROUS GOODS TRANSPORT INFORMATION

11.1.1.1 General

11.1.1.1.1 Except as otherwise provided, the consignor who offers dangerous goods for transport shall give to the carrier the information applicable to those dangerous goods, including any additional information and documentation as specified in this Code. This information may be provided on a dangerous goods transport document or, with the agreement of the carrier, by EDP or EDI techniques.

11.1.1.1.2 When dangerous goods transport information is given to the prime contractor by EDP or EDI techniques, documentation must be carried in the vehicle in hard copy form.

11.1.1.1.3 When the dangerous goods transport information is given to the prime contractor by EDP or EDI techniques, the consignor shall be able to produce the information without delay as a paper document, with the information in the sequence required by this Chapter. 11.1.1.2 FORM OF THE TRANSPORT DOCUMENT

11.1.1.2.1 A dangerous goods transport document may be in any form, provided it contains all of the information required by this Code.

11.1.1.2.2 If both dangerous and non-dangerous goods are listed in one document, the dangerous goods must be listed first.

11.1.1.2.3 A dangerous goods transport document may consist of more than one page, provided pages are consecutively numbered.

11.1.1.2.4 The information on a dangerous goods transport document must be in English, easy to identify, legible and durable. PART 11: DOCUMENTATION

11.1.1.2.5 The form shown in Figure B1 in Appendix B is an example of the intermodal dangerous goods transport document included in UN20, the IMDG Code and ADR, that may be suitable for sea or land transport. It may be used for transport in accordance with this Code if all information required by this Chapter is inserted in the spaces provided. This does not preclude the use of other formats that meet the requirements of this Chapter. 11.1.1.3 CONSIGNOR, CONSIGNEE AND DATE

11.1.1.3.1 The name and address of the consignor and the consignee of the dangerous goods must be included on the dangerous goods transport document, including the consignor’s contact telephone number which: (i) for dangerous goods transported in bulk containers, portable tanks, tank vehicles, or receptacles with a capacity of more than 500 kg(L), should be the number of the ‘telephone advisory service’ provided under Regulation 14.2.1; or (ii) whenever practicable, should be a number at which the consignor, or a person acting on behalf of the consignor, is accessible to answer questions relating to the goods consigned, whenever the goods are being transported; and

11.1.1.3.2 The date the dangerous goods transport document or an electronic copy of it was prepared or given to the initial carrier must be included. 11.1.1.4 INFORMATION REQUIRED ON THE DANGEROUS GOODS TRANSPORT DOCUMENT 11.1.1.4.1 Dangerous Goods Description

The dangerous goods transport document must contain the following information for each type of dangerous good or article offered for transport: (a) the UN Number of the goods; (b) the proper shipping name of the goods or the name of the goods that appears on the packaging, article or other receptacle in which the goods are contained1 ; (c) the Class or Division of the goods; (d) each Subsidiary Hazard (if any) of the goods; (e) the packing group (if any) for the goods; (f) a description of each type of package or other receptacle to be transported, for example: (i) “drum” or “DRM”; and (ii) “intermediate bulk container” or “IBC”; (g) the number of packages or receptacles of each type to be transported; and (h) except for empty uncleaned packagings, the aggregate quantity of dangerous goods covered by the description of each item of dangerous goods bearing a different proper shipping name, UN number or packing group. For dangerous goods transported in

1 When entered as part of a character string (e.g. on the intermodal dangerous goods form), the proper shipping name, supplemented where necessary by the technical name, must be used. PART 11: DOCUMENTATION

salvage packagings, an estimate of the quantity of dangerous goods must be given. NOTE 1: The number, type and capacity of each inner packaging within the outer packaging of a combination packaging is not required to be indicated.

NOTE 2: The aggregate quantity of a type of dangerous goods required by 11.1.1.4.1(h) may be described by stating: (a) if the goods are a gas: (i) the total capacity in litres of all gas receptacles in which those goods will be transported; or (ii) if more convenient, the number of each type of receptacle in which the goods will be transported [as required by 11.1.1.4.1(g)] together with the capacity of each of those receptacles; or (b) if the goods are a liquid or a solid: (i) the total amount, expressed in litres or kilograms, of dangerous goods of that type to be transported; or (ii) if more convenient, the number of each type of package or other receptacle in which the goods will be transported [as required by 11.1.1.4.1(g)] together with the amount of dangerous goods each contains. 11.1.1.4.2 Placement and Sequence of the Dangerous Goods Description

11.1.1.4.2.1 When describing a type of dangerous goods, the UN Number, name, Class or Division, Subsidiary Hazard and the packing group for the goods must appear before the other elements of the description.

11.1.1.4.2.2: Where the transport document is in the form of the Multimodal Dangerous Goods Form shown at Figure B11 in Appendix B, or any other format where the dangerous goods description is entered as a character string, the first five elements of the dangerous goods description specified in 11.1.1.4.1 must be shown in the order listed above (i.e. (a), (b), (c), (d), (e) with no information interspersed, except as provided in this Code.. e.g: “UN1098 ALLYL ALCOHOL 6.1 (3) I”; or “UN1098, ALLYL ALCOHOL, Division 6.1, (Class 3), PG I”.

NOTE 1: Knowledge of the actual location of dangerous goods within the cargo transport unit can be invaluable in an emergency. The inclusion of a sketch or other representation is encouraged where practicable.

NOTE 2: In addition to the requirements of this Code, other elements of information may be required by the competent authority or for certain modes of transport (e.g. flash point for sea transport). Unless permitted or required by this Code, additional information must be placed after the dangerous goods description. 11.1.1.4.3 Information which supplements the proper shipping name in the dangerous goods description

1 This form may be printed from this Code using Appendix B as a proforma. PART 11: DOCUMENTATION

The proper shipping name in the dangerous goods description must be supplemented as follows: (a) Technical names for “n.o.s.” and other generic descriptions: Proper shipping names that are assigned special provision 274 or 318 in Column 6 of the Dangerous Goods List must be supplemented with their technical or chemical group names as described in 3.1.2.8; (b) Empty uncleaned packagings, bulk containers and tanks: Empty means of containment (including packagings, IBCs, bulk containers, portable tanks, tank-vehicles and tank-wagons) which contain the residue of dangerous goods of classes other than Class 7 must be described as such by, for example, placing the words “EMPTY UNCLEANED” or “RESIDUE LAST CONTAINED” before or after the dangerous goods description specified in 11.1.1.4.1 (a) to (e);

Empty, as yet unused dangerous goods prelabelled packagings should be clearly identified as such on documentation, outer packaging or vehicle to avoid inappropriate emergency response.[DK1][DK2] (c) Wastes: For waste dangerous goods (other than radioactive wastes) which are being transported for disposal, or for processing for disposal, the proper shipping name must be preceded by the word “WASTE”, unless this is already a part of the proper shipping name; (d) Elevated temperature substances: If the proper shipping name of a substance which is transported or offered for transport in a liquid state at a temperature equal to or exceeding 100 °C, or in a solid state at a temperature equal to or exceeding 240 °C, does not convey the elevated temperature condition (for example, by using the term “MOLTEN” or “ELEVATED TEMPERATURE” as part of the shipping name), the word “HOT” must immediately precede the proper shipping name. 11.1.1.5 INFORMATION REQUIRED IN ADDITION TO THE DANGEROUS GOODS DESCRIPTION In addition to the dangerous goods description the following information must be included after the dangerous goods description on the dangerous goods transport document. 11.1.1.5.2

11.1.1.5.3 Salvage packagings including large salvage packagings and salvage pressure receptacles For dangerous goods transported in salvage packagings including large salvage packagings or salvage pressure receptacles, the words “SALVAGE PACKAGING” or “SALVAGE PRESSURE RECEPTACLE” must be included. 11.1.1.5.4 Substances stabilised by temperature control

If the word “STABILISED” is part of the proper shipping name (see also 3.1.2.6), when stabilisation is by means of temperature control, the PART 11: DOCUMENTATION

control and emergency temperatures (see 7.1.5.3) must be indicated in the transport document, as follows: “Control temperature: .... °C Emergency temperature: .... °C”

11.1.1.5.5 Self-reactive substances, polymerizing substances and organic peroxides

For self-reactive substances, organic [DK3]peroxides or polymerizing substances which require temperature control during transport, the control and emergency temperatures (see 7.1.5.3) must be indicated on the dangerous goods transport document, as follows: “Control temperature: .... °C Emergency temperature: .... °C”

11.1.1.5.5.1 When for certain self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 the competent authority has permitted the “EXPLOSIVE” subsidiary hazard label (model No. 1) to be dispensed with for the specific package, a statement to this effect must be included.

11.1.1.5.5.2 When organic peroxides or self-reactive substances are transported under conditions where a determination is required (for organic peroxides, see 2.5.3.2.5, 4.1.7.2.2, 4.2.1.13.1 and 4.2.1.13.3; for self- reactive substances, see 2.4.2.3.2.4 and 4.1.7.2.2), a statement to this effect must be included in the dangerous goods transport document. A copy of the classification determination and conditions of transport for non-listed organic peroxides and self-reactive substances must be attached to the dangerous goods transport document.

11.1.1.5.5.3 When a sample of an organic peroxide (see 2.5.3.2.5.1) or a self- reactive substance (see 2.4.2.3.2.4(b)) is transported, a statement to this effect must be included in the dangerous goods transport document.[DK4]

11.1.1.5.6 Infectious substances

When substances of division 6.2 are transported, the full address of the consignee must be shown on the document, together with the name and telephone number of a responsible person.

11.1.1.5.7

11.1.1.5.8

11.1.1.5.9 Transport of IBCs or portable tanks after the date of expiry of the last periodic test or inspection

For transport in accordance with 4.1.2.2 (b), 6.7.2.19.6 (b), 6.7.3.15.6 (b) or 6.7.4.14.6 (b), a statement to this effect must be included in the transport document, as follows: - "Transport in accordance with 4.1.2.2(b)"; - "Transport in accordance with 6.7.2.19.6(b)"; - "Transport in accordance with 6.7.3.15.6(b)" or - "Transport in accordance with 6.7.4.14.6(b)" as appropriate.

11.1.1.5.10 PART 11: DOCUMENTATION

11.1.1.5.11 Classification where new data is available (see 2.0.0.2) For transport in accordance with 2.0.0.2, a statement to this effect shall be included in the transport document, as follows “Classified in accordance with 2.0.0.2”.

11.1.1.5.12 Transport of UN Nos. 3528, 3529 and 3530 For transport of UN Nos. 3528, 3529 and 3530, the transport document, when required according to special provision 363, shall contain the following additional statement “Transport in accordance with special provision 363”.

11.1.1.5.13 Actual holding time In the case of portable tanks carrying refrigerated liquefied gases the consignor shall enter in the transport document the date at which the actual holding time ends, in the following format: “END OF HOLDING TIME: ………….. (DD/MM/YYYY)”. 11.1.1.6 11.1.2 SPECIAL DOCUMENTATION PROVISIONS

11.1.2.1 Combination road vehicles When dangerous goods are transported in a placard load on a combination road vehicle, the transport documentation must indicate which dangerous goods are stowed in each vehicle forming part of the combination.

11.1.2.2 Amending documentation after unloading When part of a load of dangerous goods is unloaded from a vehicle, or transferred out of a tank, bulk container or freight container on the vehicle, the transport documentation must where practicable be amended to reflect the types and quantities of dangerous goods remaining on the vehicle.

NOTE: 11.1.2.2 cannot be applied to tanks containing dangerous goods of Class 2 where the aggregate quantity in the tank is determined by the capacity of the tank and is not dependent on the degree of filling.

11.1.2.3 Certain Limited Quantities 11.1.2.3.1 Where dangerous goods are transported in accordance with the Concessional Limited Quantities requirements, Section 3.4.10, transport documentation in the form, or to the effect, of Figure B 21 in Appendix B, with all details completed, may be provided instead of the transport documentation otherwise specified in this Chapter.

11.1.2.4 Goods Not Subject to this Code

1 This form may be printed from this Code using Appendix B as a proforma. PART 11: DOCUMENTATION

11.1.2.4.1 This sub-section applies to goods which are mentioned in the Dangerous Goods List in Chapter 3.2 that are not subject to this Code because of a Special Provision referenced from Column (6) or because they have been determined by the Competent Authority not to be dangerous goods.

11.1.2.4.2 Goods described in 11.1.2.4.1 that are legitimately marked or labelled as dangerous goods under the IMDG, ICAO or IATA Code for transport by sea or air, may be described on transport documentation in accordance with the relevant Code.

11.1.2.4.3 When goods described in 11.1.2.4.1 are transported in a cargo transport unit that is placarded indicating the presence of dangerous goods and there is no documentation in accordance with 11.1.2.4.2, the transport documentation should indicate, in lieu of the dangerous goods description required by 11.1.1.1.4, that the goods are not subject to the ADG Code.

11.1.3 ROAD TRANSPORT DOCUMENTATION

11.1.3.1 Transport documentation must be carried in the cabin of each road vehicle transporting dangerous goods.

11.1.3.2 Every road vehicle transporting a placard load of dangerous goods must be fitted with an emergency information holder in accordance with Chapter 11.2 and the transport documentation must be carried with the emergency information in that holder.

11.1.3.3 Every road vehicle transporting less than a placard load of dangerous goods must carry the documentation: (a) in any emergency information holder fitted in the cabin of the vehicle; or (b) where no emergency information holder is fitted, elsewhere in the cabin in a prominent location.

11.1.3.4 Despite 11.1.1.2, the documentation must be of a size, and be in a form, that is suitable for carrying in the emergency information holder.

11.1.3.5 The documentation must not be in a sealed envelope or be otherwise kept in a way that would prevent it from being able to be read by the driver, while it is in the vehicle. 11.1.4 RAIL TRANSPORT DOCUMENTATION For the rail journey, a train manifest may be used instead of transport documentation required by this Chapter provided: (a) the train manifest contains, for each type of dangerous goods to be transported, the proper shipping name, the Class or Division and any Subsidiary Hazard, the UN Number, the packing group (if any), the aggregate quantity, the wagon number and the location on the train where the goods are loaded; (b) provision is made for the train manifest to be updated when the attachment or detachment of vehicles loaded with dangerous goods occurs; and PART 11: DOCUMENTATION

(c) while ever the train is transporting dangerous goods, all of the information required by this Chapter to be included on the documentation is available from a central location provided by the rail operator for which contact details are provided on or with the manifest.

CHAPTER 11.1 - TRANSPORT DOCUMENTATION Introductory Notes

NOTE 2: The form shown in Figure B1 in Appendix B is an example of the intermodal dangerous goods transport document included in UN20, the IMDG Code and ADR, that may be suitable for sea or land transport. It may be used for transport in accordance with this Code if all information required by this Chapter is inserted in the spaces provided. This does not preclude the use of other formats that meet the requirements of this Chapter.

NOTE 3: The IATA ”Shipper’s Declaration for Dangerous Goods” will also be acceptable under this Code as a transport document if all the required information is inserted.

NOTE 4: Division 11.1 of the Regulations specifies who must provide and carry dangerous goods transport documentation.

11.1.1 FORM OF THE TRANSPORT DOCUMENT [UN 5.4.1.2]

11.1.1.1 A dangerous goods transport document may be in any form, provided it contains all of the information required by this Code.

11.1.1.2 If both dangerous and non-dangerous goods are listed in one document, the dangerous goods must be listed first.

11.1.1.3 A dangerous goods transport document may consist of more than one page, provided pages are consecutively numbered.

11.1.1.4 The information on a dangerous goods transport document must be in English, easy to identify, legible and durable.

11.1.1.5 The contents of transport documentation may be transmitted to the prime contractor or driver by electronic data interchange, but documentation must be carried in the vehicle in hard copy form. PART 11: DOCUMENTATION

11.1.2 CONTENT

11.1.2.1 Except where 11.1.3.4 applies, each dangerous goods transport document must contain: (a) the consignor’s name and contact telephone number which: (i) for dangerous goods transported in bulk containers, portable tanks, tank vehicles, or receptacles with a capacity of more than 500 kg(L), should be the number of the ‘telephone advisory service’ provided under Regulation 14.2.1; or (ii) whenever practicable, should be a number at which the consignor, or a person acting on behalf of the consignor, is accessible to answer questions relating to the goods consigned, whenever the goods are being transported; and (b) a description in accordance with 11.1.2.2 of the dangerous goods to be transported.

11.1.2.2 Dangerous goods description

11.1.2.2.1 For each type of dangerous goods to be transported, the description in the transport document, as required by 11.1.2.1(b), must include: (a) the UN Number of the goods; (b) the proper shipping name of the goods or the name of the goods that appears on the packaging, article or other receptacle in which the goods are contained1 ; (c) the Class or Division of the goods; (d) each Subsidiary Hazard (if any) of the goods; (e) the packing group (if any) for the goods; (f) a description of each type of package or other receptacle to be transported, for example: (i) “drum” or “DRM”; and (ii) “intermediate bulk container” or “IBC”; (g) the number of packages or receptacles of each type to be transported; and (h) the aggregate quantity of the goods.

NOTE: The number, type and capacity of each inner packaging within the outer packaging of a combination packaging is not required to be indicated.

11.1.2.2.2 When describing a type of dangerous goods, the UN Number, name, Class or Division, Subsidiary Hazard and the packing group for the goods must appear before the other elements of the description.

NOTE 1: Where the transport document is in the form of the Multimodal Dangerous Goods Form shown at Figure B12 in Appendix B, or any other format where the dangerous goods description is entered as a

character string, the above sequence (a), (b), (c), (d), (e) must be employed. e.g: “UN1098 ALLYL ALCOHOL 6.1 (3) I”; or “UN1098, ALLYL ALCOHOL, Division 6.1, (Class 3), PG I”. On such forms, as in the above examples, the UN Number should be preceded by the letters “UN” and any subsidiary hazard should be enclosed in parenthesis. No other information should be interspersed except as included in the examples.

NOTE 2: Where the transport document is printed with the elements of the dangerous goods description in clearly defined, individually headed columns, the actual sequence of items (a) to (e) inclusive is not critical for the purposes of this Code, provided they precede the other elements. Such documents, however, may not be acceptable transport documentation for sea or air transport of dangerous goods.

11.1.2.2.3 The aggregate quantity of a type of dangerous goods required by 11.1.2.2.1(h) may be described by stating: (a) if the goods are a gas: (i) the total capacity in litres of all gas receptacles in which those goods will be transported; or (ii) if more convenient, the number of each type of receptacle in which the goods will be transported [as required by 11.1.2.2.1(g)] together with the capacity of each of those receptacles; or (b) if the goods are a liquid or a solid: (i) the total amount, expressed in litres or kilograms, of dangerous goods of that type to be transported; or (ii) if more convenient, the number of each type of package or other receptacle in which the goods will be transported [as required by 11.1.2.2.1(g)] together with the amount of dangerous goods each contains.

11.1.2.2.4 The transport document may contain other information about the dangerous goods to be transported if the information is not inconsistent with, and is placed after, the information included in the document in accordance with 11.1.2.2.

NOTE: Knowledge of the actual location of dangerous goods within the cargo transport unit can be invaluable in an emergency. The inclusion of a sketch or other representation is encouraged where practicable.

11.1.2.3 Additional information required for certain dangerous goods

11.1.2.3.1 “N.O.S.” and other generic entries

[UN 5.4.1.4.3(a)] Proper shipping names that are assigned special provision 274 in Column 6 of the Dangerous Goods List must be supplemented with their technical or chemical group names as described in 3.1.2.8.

11.1.2.3.2 Elevated temperature substances PART 11: DOCUMENTATION

[UN 5.4.1.4.3(d)] If the proper shipping name of a substance which is transported or offered for transport in a liquid state at a temperature equal to or exceeding 100 °C, or in a solid state at a temperature equal to or exceeding 240 °C, does not convey the elevated temperature condition (for example, by using the term “MOLTEN” or “ELEVATED TEMPERATURE” as part of the shipping name), the word “HOT” must immediately precede the proper shipping name. 11.1.2.3.3 Substances stabilised by temperature control

[UN 5.4.1.5.4] If the word “STABILISED” is part of the proper shipping name (see also 3.1.2.6), when stabilisation is by means of temperature control, the control and emergency temperatures (see 7.1.4.3.1) must be indicated in the transport document, as follows: “Control temperature: .... °C Emergency temperature: .... °C”

11.1.2.3.4 Self-reactive substances, polymerizing substances and organic peroxides

[UN 5.4.1.5.5] For self-reactive substances of Division 4.1, and for organic [DK5]peroxides and polymerizing substances which require temperature control during transport, the control and emergency temperatures (see 7.1.4.3.1) must be indicated on the dangerous goods transport document, as follows: “Control temperature: .... °C Emergency temperature: .... °C”

11.1.2.3.4.1 When for certain self-reactive substances of Division 4.1 and organic peroxides of Division 5.2 the competent authority has permitted the “EXPLOSIVE” subsidiary hazard label (model No. 1) to be dispensed with for the specific package, a statement to this effect must be included.

11.1.2.3.4.2 When organic peroxides, andself-reactive substances are transported under conditions where a determination is required (for organic peroxides, see 2.5.3.2.5, 4.1.7.2.2, 4.2.1.13.1 and 4.2.1.13.3; for self- reactive substances, see 2.4.2.3.2.4 and 4.1.7.2.2), a statement to this effect must be included in the dangerous goods transport document. A copy of the classification determination and conditions of transport for non-listed organic peroxides and self-reactive substances must be attached to the dangerous goods transport document.

11.1.2.3.4.3 When a sample of an organic peroxide (see 2.5.3.2.5.1) or a self- reactive substance (see 2.4.2.3.2.4(b)) is transported, a statement to this effect must be included in the dangerous goods transport document.[DK6]

11.1.2.3.5 Infectious substances

[UN 5.4.1.5.6]When substances of division 6.2 are transported, the full address of the consignee must be shown on the document, together with the name and telephone number of a responsible person. 11.1.3 SPECIAL DOCUMENTATION PROVISIONS

11.1.3.1 Empty receptacles 1

1 See also Chapter 7.2 PART 11: DOCUMENTATION

11.1.3.1.1 Empty uncleaned IBCs, bulk containers, portable tanks, tank- [UN 5.4.1.4.3(b)] vehicles and tank-wagons which contain the residue of dangerous goods must, to the extent practicable, be described as such on the transport document by, for example, placing the words “EMPTY UNCLEANED” or “RESIDUE LAST CONTAINED” before or after the dangerous goods description specified in 11.1.2.2.1 (a) to (e).

NOTE: The purpose of this requirement is to facilitate appropriate incident response. When using computer generated documentation, where there may be field size or content limitations that may preclude that approach, another method should be adopted that unambiguously conveys the nature of the contents, such as: (a) using the field allocated to the Technical Name that must supplement the Proper Shipping Name where SP 274 applies; (b) adopting a unique receptacle descriptor (see 11.1.2.2.1(f)) such as “M/T TANK”; (c) making an alpha entry, such as “RESIDUE” or “DREGS”, in the quantity field; (d) inserting a hand-written descriptor.

11.1.3.1.2 In transport documentation for a load of empty packagings that have not been freed of dangerous goods, words to the effect that the load contains empty receptacles of dangerous goods (for example “EMPTY D/G DRUMS”; or “D/G RESIDUE” or “RETURN EMPTY D/G PACKAGES”) may be used in the documentation instead of the information required to be included under 11.1.2.2.

NOTE: Empty, as yet unused dangerous goods prelabelled packagings should be clearly identified as such on documentation, outer packaging or vehicle to avoid inappropriate emergency response.

11.1.3.2 Combination road vehicles When dangerous goods are transported in a placard load on a combination road vehicle, the transport documentation must indicate which dangerous goods are stowed in each vehicle forming part of the combination.

11.1.3.3 Amending documentation after unloading When part of a load of dangerous goods is unloaded from a vehicle, or transferred out of a tank, bulk container or freight container on the vehicle, the transport documentation must where practicable be amended to reflect the types and quantities of dangerous goods remaining on the vehicle.

NOTE: 11.1.3.3 cannot be applied to tanks containing dangerous goods of Class 2 where the aggregate quantity in the tank is determined by the capacity of the tank and is not dependent on the degree of filling.

PART 11: DOCUMENTATION

11.1.3.4 Certain Limited Quantities 11.1.3.4.1 Where dangerous goods are transported in accordance with the Concessional Limited Quantities requirements, Section 3.4.10, transport documentation in the form, or to the effect, of Figure B 21 in Appendix B, with all details completed, may be provided instead of the transport documentation otherwise specified in this Chapter.

11.1.3.4.2 Dangerous goods that are transported in accordance with sections 3.4.11, 3.4.12 or 3.5 do not require transport documentation under this part.

11.1.3.5 Goods Not Subject to this Code

11.1.3.5.1 This sub-section 11.1.3.5 applies to goods which are mentioned in the Dangerous Goods List in Chapter 3.2 that are not subject to this Code because of a Special Provision referenced from Column (6) or because they have been determined by the Competent Authority not to be dangerous goods..

11.1.3.5.2 Goods described in 11.1.3.5.1 that are legitimately marked or labelled as dangerous goods under the IMDG, ICAO or IATA Code for transport by sea or air, may be described on transport documentation in accordance with the relevant Code.

11.1.3.5.3 When goods described in 11.1.3.5.1 are transported in a cargo transport unit that is placarded indicating the presence of dangerous goods and there is no documentation in accordance with 11.1.3.5.2, the transport documentation should indicate, in lieu of the dangerous goods description required by 11.1.2.2, that the goods are not subject to the ADG Code.

11.1.3.6 Transport of IBCs or portable tanks after the date of expiry of the last periodic test or inspection

[UN 5.4.1.5.9] For transport in accordance with 4.1.2.2(b), 6.7.2.19.6(b), 6.7.3.15.6(b) or 6.7.4.14.6(b), a statement to this effect must be included in the transport document, as follows: - "Transport in accordance with 4.1.2.2(b)"; - "Transport in accordance with 6.7.2.19.6(b)"; - "Transport in accordance with 6.7.3.15.6(b)" or - "Transport in accordance with 6.7.4.14.6(b)" as appropriate.

11.1.4 ROAD TRANSPORT DOCUMENTATION

11.1.4.1 Transport documentation must be carried in the cabin of each road vehicle transporting dangerous goods.

1 This form may be printed from this Code using Appendix B as a proforma. PART 11: DOCUMENTATION

11.1.4.2 Every road vehicle transporting a placard load of dangerous goods must be fitted with an emergency information holder in accordance with Chapter 11.2 and the transport documentation must be carried with the emergency information in that holder.

11.1.4.3 Every road vehicle transporting less than a placard load of dangerous goods must carry the documentation: (a) in any emergency information holder fitted in the cabin of the vehicle; or (b) where no emergency information holder is fitted, elsewhere in the cabin in a prominent location.

11.1.4.4 Despite 11.1.1.1, the documentation must be of a size, and be in a form, that is suitable for carrying in the emergency information holder.

11.1.4.5 The documentation must not be in a sealed envelope, or be otherwise kept in a way that would prevent it from being able to be read by the driver, while it is in the vehicle. 11.1.5 RAIL TRANSPORT DOCUMENTATION For the rail journey, a train manifest may be used instead of transport documentation required by this Chapter provided: (a) the train manifest contains, for each type of dangerous goods to be transported, the proper shipping name, the Class or Division and any Subsidiary Hazard, the UN Number, the packing group (if any), the aggregate quantity, the wagon number and the location on the train where the goods are loaded; (b) provision is made for the train manifest to be updated when the attachment or detachment of vehicles loaded with dangerous goods occurs; and (c) while ever the train is transporting dangerous goods, all of the information required by this Chapter to be included on the documentation is available from a central location provided by the rail operator for which contact details are provided on or with the manifest.

PART 11: DOCUMENTATION

CHAPTER 11.2 - EMERGENCY INFORMATION 1 11.2.1 DEFINITIONS In this Chapter: Emergency information, in relation to dangerous goods transported on a vehicle, means: (a) the Dangerous Goods – Initial Emergency Response Guide2 ; or (b) an emergency procedure guide for the dangerous goods transported on the vehicle and the emergency procedure guide in relation to vehicle fire; or (c) for use on trains transporting dangerous goods, the rail operator’s Dangerous Goods Emergency Instructions for train crews which provides contact numbers for dangerous goods emergencies or (d) a relevant international or foreign standard, legible and in English, that is equivalent to the information provided by Standards Australia publication HB763. Any use of an international or foreign standard must be approved by the Competent Authority.

Note 1: An example of a relevant international or foreign standard is the 2012 Emergency Response Guidebook (ERG2012) developed jointly by Transport Canada (TC), the U.S. Department of Transportation (DOT), the Secretariat of Transport and Communications of Mexico (SCT) and with the collaboration of CIQUIME (Centro de Informaciòn Quìmica para Emergencias) of Argentina.

Note 2: Such international or foreign standards that are acceptable must be supplemented by correct Australian emergency contact information. Emergency procedure guide, in relation to particular dangerous goods, is a guide outlining procedures to be taken in the event of an emergency involving the goods which is either: (a) in the form, or substantially in the form, of an emergency procedure guide for the goods published by Standards Australia; or (b) in a form approved by a Competent Authority in relation to goods of that kind. Emergency procedure guide, in relation to vehicle fire, means a guide outlining procedures to be taken in the event of a fire on a road vehicle which is either: (a) in the form, or substantially in the form, of the emergency procedure guide for vehicle fire published by Standards Australia; or (b) in a form approved by a Competent Authority. Emergency information holder means a holder: (a) of a size and shape suitable for carrying emergency information and transport documentation; and

1 Division 11.2 of the Regulations requires emergency information to be carried on each road vehicle or train transporting dangerous goods in a placard load. 2 Standards Australia publication HB 76 ‘Dangerous Goods – Initial Emergency Response Guide’. 3 Standards Australia publication HB 76 ‘Dangerous Goods – Initial Emergency Response Guide’. PART 11: DOCUMENTATION

(b) marked with the words “emergency procedure guides” or “emergency information” in red letters at least 10 millimetres high on a white background. 11.2.2 PLACEMENT OF EMERGENCY INFORMATION HOLDER

11.2.2.1 An emergency information holder must be securely placed on a road vehicle: (a) on the inside of a door of the cabin; or (b) immediately adjacent to a door of the cabin; or (c) if the construction of the vehicle does not allow the holder to be attached to the inside of or adjacent to a cabin door - elsewhere in the cabin of the vehicle, provided that the position of the holder is identified on a notice affixed to the inside of the driver’s door of the cabin.

11.2.2.2 Any emergency information holder that is located other than as specified in 11.2.2.1(a) must be visible and accessible.

PART 12: SAFETY EQUIPMENT FOR ROAD VEHICLES

CHAPTER 12.1 - SAFETY EQUIPMENT FOR ROAD VEHICLES 12.1.1 APPLICATION Every road vehicle transporting a placard load of dangerous goods must be equipped with: (a) fire extinguishers in accordance with 12.1.2; and (b) at least three portable warning devices that comply with AS 3790 and are clean and in good condition; and (c) personal protective equipment and safety equipment in accordance with 12.1.3. 12.1.2 FIRE EXTINGUISHERS

12.1.2.1 A road vehicle transporting a placard load of dangerous goods must be equipped with a fire extinguisher or fire extinguishers in good working order and in accordance with Table 12.1.

12.1.2.2 On a combination vehicle, each separate unit on which a placard load of dangerous goods is transported must be equipped with fire extinguishers in good working order and in accordance with Table 12.1.

12.1.2.3 A fire extinguisher required by this Section must comply with: (a) AS/NZS 1841.1 and AS/NZS 1850 and AS1851; and (b) AS/NZS 1841.4 or 5 as appropriate for the vehicle and load being carried.

12.1.2.4 Each fire extinguisher required by this Section must be mounted securely by means of a quick-release attachment.

12.1.2.5 Extinguisher Location

12.1.2.5.1 Each fire extinguisher required by this Section must be located so as to be readily accessible for use.

12.1.2.5.2 On road tank vehicles, fire extinguishers must be located and stowed in accordance with AS 2809.1.

12.1.2.5.3 Where two or more fire extinguishers are required for the load area of any vehicle, one should be located on the left (near) side towards the rear of the vehicle and, wherever practicable, another should be mounted on the right (off) side towards the front of the vehicle.

12.1.2.5.4 Except in the case of a combination vehicle, if only one fire extinguisher is required for any vehicle, wherever practicable it should be located: (a) on the discharge side of a road tank vehicle; or (b) in the cabin for all other vehicles.

12.1.2.5.5 If 12.1.2.5.4 or Table 12.1 requires that a fire extinguisher be located in the cabin, as an alternative to being located in the cabin the fire extinguisher may be located directly behind the cabin or may be mounted on the rear of the cabin.

PART 12: SAFETY EQUIPMENT FOR ROAD VEHICLES

Table 12.1: Minimum Fire Extinguisher Requirements for Road Vehicles Transporting a Placard Load of Dangerous Goods

Load: All types of dangerous goods packed in: • packages, drums, overpacks, segregation devices • intermediate bulk containers (IBCs) containing non-flammables – any quantity • IBCs containing flammables with up to (and including) 10,000 L total capacity or containing up to (and including) 10,000 kg in total

Required extinguishers: 1 x 30B dry powder that is to be placed in the cabin (see 12.1.2.5.5), or at the front of any trailer transporting a placard load

Load: Non-flammable goods packed in: pressure drums, tubes, multiple element gas containers (MEGCs), tanks, bulk containers (solids)

Required extinguishers: 1 x 60B dry powder, or 2 x 30B dry powder, in the load area 1 x 10B dry powder in the cabin (see 12.1.2.5.5)

Load: Flammable goods packed in: • pressure drums, tubes, MEGCs, tanks, bulk containers (solids) • IBCs > 10,000 L total capacity or containing >10,000 kg. in total

Required extinguishers: 2 × 60B dry powder, or 1x 80B dry powder and 1 x 20B foam, in the load area 1 x 10B dry powder in the cabin (see 12.1.2.5.5)

NOTE 1: In this table "flammable goods" means dangerous goods of Division 2.1, Class 3 or Class 4, or having a subsidiary hazard of 2.1, 3 or 4.

NOTE 2: In cases of combination vehicles, these directions apply to every separate trailer transporting a placard load.

NOTE 3: If more than one dry powder fire extinguisher is required in the load area, one may be replaced with a foam fire extinguisher of at least 9L capacity. If a foam fire extinguisher is used it must be suitable for the types of fire scenarios likely to be encountered and selected with the aim of preventing the spread of fire to the load.

NOTE 4: A firefighting system designed for the load using compressed air foam system (CAFS) may be used in place of portable fire extinguishers in the load area. The CAFS must be operational even when the engine of the vehicle is turned off and must be suitable for the types of fire scenarios likely to be encountered with the aim of preventing the spread of fire to the load. PART 12: SAFETY EQUIPMENT FOR ROAD VEHICLES

12.1.3 PERSONAL PROTECTIVE EQUIPMENT AND SAFETY EQUIPMENT

12.1.3.1 Table 12.2 specifies the minimum personal protective and safety equipment that must be provided, based on the classification of the dangerous goods being transported.

12.1.3.2 A road vehicle transporting a placard load of dangerous goods must carry the personal protective equipment and safety equipment specified in Table 12.2 for all the dangerous goods in the load, based on their primary hazards and any subsidiary hazard, subject to any conditions incorporated in the table and its explanatory notes.

12.1.3.3 All personal protective equipment and safety equipment provided in accordance with this section must be: (a) clean; and (b) suitable for purpose; and (c) in sound operating condition, ready for use.

12.1.3.4 Personal protective equipment provided in accordance with this section must be in sufficient quantities for and suitable for use by: (a) the driver of the vehicle; and (b) where required for escape purposes, any other persons travelling in the vehicle.

12.1.3.5 Respiratory protection equipment required to be carried for escape purposes must be carried securely and in an accessible position in the cabin of the vehicle.

12.1.3.6 Other personal protective equipment and safety equipment provided for occupants of a road vehicle transporting dangerous goods must be carried securely and in a readily accessible position in the vehicle. PART 12: SAFETY EQUIPMENT FOR ROAD VEHICLES

Table 12.2: Minimum Personal Protective and Safety Equipment on Road Vehicles transporting a Placard Load Class, Division or Subsidiary Hazard of Dangerous Goods in Load Minimum Equipment Required 2.1 2.2 2.3 3 4 5.1 5.1 5.2 6.1 6.2 8 9 [a] (solids) (liquids)

Respiratory protection equipment for escape purposes No No [b] No No No No No [b] No [b] No Gas tight goggles or full face shield as appropriate [c] [c] Yes No No No Yes Yes Yes No Yes No Eye-wash kit [d] No No Yes Yes Yes Yes Yes Yes Yes No Yes Yes Chemically resistant gloves or gauntlets No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes Thermally insulated gloves or gauntlets Yes Yes Yes No No No No No No No No [e] Chemically resistant suit or coveralls No No No No No No Yes Yes Yes No Yes No Chemically resistant boots No No No No No No Yes Yes Yes No Yes No Any electric torch No Yes Yes No No Yes Yes No Yes Yes Yes Yes Electric torch complying with AS/NZS 60079.11 or other recognised Yes No No Yes Yes No No Yes No No No No CodeStandard Table notes: [a] A vehicle transporting unodourised LP Gas, Butane or Propane must additionally be equipped with a gas detector suitable for detection of LP Gas, in accordance with AS 1596. [b] The minimum requirement is air supplied short term breathing apparatus suitable for escape purposes, except when, even in an emergency, the dangerous goods will not give rise to harmful vapours, gases or dust. Note that where a driver attends to the loading or transfer of goods, SCBA with a duration of greater than 15 minutes may be required by other (e.g. health and safety) legislation. The minimum requirement is a compressed air or compressed oxygen self contained breathing apparatus, or chemical oxygen self-contained self-rescuer, certified to comply with AS/NZS 1716 and providing breathable air for not less than 15 minutes. Respiratory protection equipment is not required where the dangerous goods will not give rise to harmful vapours, gases or dust, even in an emergency, [c] Yes – if the goods are in receptacles with a capacity > 500 L or the goods are cryogenic liquids. No – – otherwise “Gas tight goggles” means face hugging goggles with increased facial seal.[DK7] PART 12: SAFETY EQUIPMENT FOR ROAD VEHICLES

[d] Where an eyewash kit is required, it must be of at least 250 mL capacity, filled and ready for use. [e] Yes – if the goods are elevated temperature substances or dry ice. No – otherwise.

NOTE 1: Where an item of Personal Protective or Safety Equipment is required based on the primary hazard or subsidiary hazardof any item of dangerous goods in the load, that item must be carried, except that where thermally insulated gloves or gauntlets are required and carried, any requirement for chemically resistant gloves or gauntlets may be ignored

NOTE 2: Under other legislation, it may be necessary to carry additional Personal Protective Equipment where it is specified for the purpose on the Safety Data Sheet.

PART 13: PROCEDURES DURING ROAD TRANSPORT

CHAPTER 13.1 - PROCEDURES DURING TRANSPORT 13.1.1 APPLICATION This Chapter applies only to road vehicles transporting a placard load of dangerous goods. 13.1.2 BREAKDOWNS

13.1.2.1 General Measures If a road vehicle transporting dangerous goods is disabled on a road or street, or has stopped and constitutes a traffic hazard, other road users must be alerted by: (a) if: (i) the battery has not been disconnected to prevent danger and there are flashing hazard lights on the vehicle—turning the hazard lights on and leaving them on while the vehicle is stopped; or (ii) the battery has not been disconnected to prevent danger and there are no flashing hazard lights on the vehicle— turning the parking lights on and leaving them on while the vehicle is stopped; and (b) placing a portable warning device in a manner required by 13.1.2.2

13.1.2.2 Placement of portable warning triangles The portable warning triangles must be placed as follows: (a) if the speed limit for the road is 80 kilometres per hour or more: (i) 1 triangle at least 200 metres, but not over 250 metres, behind the vehicle; and (ii) if the vehicle is on a one-way or divided road, 1 triangle between the triangle required by paragraph (i) and the vehicle; and (iii) if the vehicle is not on a one-way road or divided road, 1 triangle at least 200 metres, but not over 250 metres, in front of the vehicle or fallen load; and (iv) 1 triangle at the side of the vehicle closer to traffic; (b) if the speed limit for the road is less than 80 kilometres per hour: (i) 1 triangle at least 50 metres, but not over 150 metres, behind the vehicle; and (ii) if the vehicle is on a one-way or divided road, 1 triangle between the triangle required by paragraph (i) and the vehicle; and (iii) if the vehicle is not on a one-way road or divided road, 1 triangle at least 50 metres, but not over 150 metres, in front of the vehicle or fallen load; and (iv) 1 triangle at the side of the vehicle closer to traffic.

NOTE: Regulation 13.1.1 of the Model subordinate instrument provides that a driver who complies with an Australian Road Rule requiring the placement of portable warning triangles does not need to comply with the requirements in Part 13 with respect to portable warning devices. PART 13: PROCEDURES DURING ROAD TRANSPORT

13.1.3 GENERAL PRECAUTIONS DURING TRANSPORT

13.1.3.1 Passengers No person apart from the following may ride in the cabin of a road vehicle transporting dangerous goods: (a) an authorised officer, police officer or officer of an emergency service, or a person authorised to ride in the vehicle by such a person; or (b) an employee of, or other person authorised to ride in the vehicle by, the owner of the vehicle or the prime contractor.

13.1.3.2 Parking requirements

13.1.3.2.1 On parking a road vehicle transporting dangerous goods: (a) the parking brake must be fully applied; and (b) if the vehicle is powered by a compression ignition engine, the vehicle must not be parked in gear unless: (i) the vehicle is fitted with a device to prevent the engine from starting if the vehicle moves; and (ii) the device is engaged.

13.1.3.2.2 Where a vehicle may be parked

13.1.3.2.2.1 A road vehicle transporting dangerous goods must not be parked or left standing: (a) in a built-up area with public access; or (b) within 15 metres of any building in which there is or is likely to be a concentration of people (other than a building on premises where the vehicle is loaded or unloaded); or (c) at any other place in which there is or is likely to be a concentration of people; or (d) within 8 metres of another vehicle which is transporting placarded dangerous goods.

13.1.3.2.2.2 Despite 13.1.3.2.2.1, a vehicle may be parked or left standing in circumstances mentioned in 13.1.3.2.2.1 if: (a) it is reasonably necessary to do so: (i) for the purpose of loading or unloading dangerous goods onto or from the vehicle; or (ii) because the vehicle has broken down; or (iii) because of a dangerous situation involving the vehicle; or (iv) to comply with the requirement of any law; or (v) for a brief rest or refreshment break; or (vi) for the normal operation of the vehicle, such as a bitumen spray vehicle; and the vehicle is not parked or left standing for any longer than is necessary and the dangerous goods are kept secure; or (b) the Competent Authority or other local, State or Territory authority responsible for regulating the use or parking of vehicles has PART 13: PROCEDURES DURING ROAD TRANSPORT

approved the place as a place in which vehicles transporting dangerous goods may be parked or left standing.

13.1.3.2.2.3 A vehicle transporting dangerous goods of Division 2.1 or Class 3, 4 or 5 or with a Subsidiary Hazardof 2.1, 3, 4 or 5 must not be parked or left standing within 15 metres of a naked flame.

13.1.3.2.2.4 13.1.3.2.2.1(d) does not apply to a road vehicle transporting dangerous goods that is parked or left standing in an area to which there is no public access.

13.1.3.2.2.5 Despite 13.1.3.2.2.1, a vehicle carrying BATTERIES, WET, FILLED WITH ACID, electric storage (UN 2794) of Packing Group III that each have a gross mass of 65kg or less, and that together have a gross mass of 5000 kg or less, may: (a) park in a public place if: (i) in the case of an enclosed vehicle, the load area is locked; or (ii) in the case of a tray-sided vehicle, the load is covered, or the vehicle is supervised; and (b) be garaged in a residential area if: (i) in the case of an enclosed vehicle, the load area is locked; or (ii) in the case of a tray-sided vehicle, the garage is locked.

13.1.3.2.2.6 However, 13.1.3.2.2.5 only applies if the transport documentation for the load states the number of batteries in the load, and if that number is adjusted after each delivery so that it accurately states the number of batteries in the load at all times.

13.1.3.3 Unloading the vehicle1 Other than for transfer to another vehicle or to another mode of transport, dangerous goods must not be unloaded from a road vehicle unless: (a) the consignee, or a person acting on the consignee’s behalf, is present and receives the goods; or (b) if the driver, prime contractor or consignor has agreed with the consignee for the goods to be unloaded into a secure place, the goods are unloaded into that place.

13.1.3.4 Detaching a trailer from a prime mover or combination road vehicle A trailer containing dangerous goods must not be detached from a prime mover or a combination road vehicle other than: (a) at a vehicle marshalling area, designated by a local, State or Territory authority, where the loading and unloading of goods is permitted; or (b) at a transport depot designed for the loading and unloading of goods; or

1 The Regulations may allow for unloading in emergency situations. PART 13: PROCEDURES DURING ROAD TRANSPORT

(c) for the purposes of immediate exchange of trailers between prime movers or combination road vehicles, provided this is carried out off road and security is maintained; or (d) in an emergency requiring the trailer to be detached in the interests of safety; or (e) in the event of the vehicle becoming disabled on a road or street.

13.1.3.5 Operation of burners

13.1.3.5.1 Except as provided in 13.1.3.5.2. where a road tank vehicle is equipped with a burner to heat the load, the burner must not be operated when the vehicle is moving.

13.1.3.5.2 Burners may be operated on moving bitumen tankers if done in accordance with AS 2809.5, however the burner on a spray vehicle must not be operated when the vehicle is spraying bitumen. 13.1.4 ROUTES

13.1.4.1 Routes for road vehicles transporting dangerous goods must be pre- planned whenever possible to the extent practicable, taking into account the factors in this Section1 .

13.1.4.2 Routes should be selected to minimise the risk of personal injury or harm to the environment or property during the journey.

13.1.4.3 Routes should wherever practicable avoid heavily populated or environmentally sensitive areas, congested crossings, tunnels, narrow streets, alleys, or sites where there may be, a concentration of people.

13.1.4.4 A road vehicle transporting dangerous goods must observe any requirements or restrictions on the selection of routes or times of travel which have been determined by the Competent Authority.

1 While it is not always practicable to pre-plan in detail the route of a courier or local pick-up or delivery vehicle, the driver should nonetheless be made aware of any areas to avoid in localities where travel is anticipated. APPENDICES

APPENDICES

APPENDIX A: GOODS TOO DANGEROUS TO BE TRANSPORTED

A 1 Appendix A lists a number of substances and articles which are considered to be goods too dangerous to be transported.

A 2 If an entry in this Appendix includes the expression ‘N.E.S.’, it refers to goods not elsewhere specified. In those cases, the goods named in this entry are also named in one or more entries in the Dangerous Goods Lists in Chapter 3.2. An entry in the Dangerous Goods Lists describes goods of that name that may be transported. For example, it may be possible to transport a substance in compliance with this Code after mixing it with diluents, stabilisers, inhibitors, desensitisers, phlegmatisers, solvents, wetting agents or adulterants, as specified in the Dangerous Goods List, to overcome the instability inherent in the goods. The entry in this Appendix refers to goods that do not meet the description specified in the Dangerous Goods Lists and any associated Special Provisions in Chapter 3.3.

A 3 The list in this Appendix is not an exhaustive listing of goods too dangerous to be transported (see 3.1.1.3).

A 4 Under Regulation 1.5.1(2)(a), the Competent Authority may determine that other goods are to be classified as goods too dangerous to be transported, or that goods listed in this Appendix are not too dangerous to be transported.

A 5 Some State and Territory legislation, that embodies the principles of the NOHSC National Standard on the Storage and Handling of Dangerous Goods, makes reference to this list and assigns a label or placard to these goods, for use when they are kept or handled on premises. The use of that label/placard is not authorised by this Code for transport purposes.

APPENDICES

Table A1: List of some goods too dangerous to be transported

Acetyl acetone peroxide, N.E.S. Benzene diazonium nitrate, N.E.S. Acetyl benzoyl peroxide, N.E.S. Benzene-1,3-disulfohydrazide, N.E.S. Acetyl cyclohexane sulfonyl peroxide, Benzene triozonide N.E.S. Benzoxidiazoles, N.E.S. Acetylene (liquefied) Benzoyl azide Acetylene silver nitrate Biphenyl triozonide Acetyl hydroperoxide, N.E.S. (Alt: 2,2-Bis-(tert-butylperoxy) butane, N.E.S. Peracetic acid) 1,1-Bis-(tert-butylperoxy) cyclohexane, Acetyl peroxide, N.E.S. N.E.S. Acraldehyde, N.E.S. (Alt: Acrolein) 2,2-Bis-(4,4-di-tert-butylperoxy cyclohexyl) Acroleic acid, N.E.S. (Alt: Acrylic acid) propane, N.E.S. Acrolein dimer, N.E.S. Bis-(2-methylbenzoyl) peroxide, N.E.S. Acrolein, N.E.S. Bis-(3,5,5-trimethyl-1,2-dioxolanyl- Acrylaldehyde, N.E.S. (Alt: Acrolein) 3)peroxide, N.E.S. Acryldehyde, N.E.S. Bromine azide Acrylic acid , N.E.S. 4-Bromo-1,2-dinitrobenzene Acrylic acid isobutyl ester, N.E.S. (Alt: Bromosilane Isobutyl acrylate) Butadienes, N.E.S. Acrylic aldehyde, N.E.S. (Alt: Acrolein) 1,2,4-Butanetriol trinitrate Acrylonitrile, N.E.S. 2-Butenal, N.E.S. (Alt: Crotonaldehyde) Allyl aldehyde, N.E.S. (Alt: Acrolein) Butene oxide, N.E.S. (Alt: 1,2-Butylene Aluminium dross, wet or hot oxide) Ammonium azide tert-Butoxycarbonyl azide Ammonium bromate n-Butoxyethylene, N.E.S. (Alt: Butyl vinyl Ammonium chlorate ether) Ammonium fulminate Butyl acrylate, N.E.S. Ammonium nitrate, N.E.S. 1,2-Butylene oxide, N.E.S. Ammonium nitrite tert-Butyl hydroperoxide, N.E.S. Ammonium permanganate tert-Butyl peracetate, N.E.S. Ammonium picrate, N.E.S. tert-Butyl perdiethylacetate and Ammonium salt and a chlorate, mixtures of tert-Butyl perbenzoate mixtures, N.E.S. Ammonium salt and a nitrite, mixtures of tert-Butyl perisobutyrate, N.E.S. tert-Amyl hydroperoxide, N.E.S. tert-Butyl peroxyacetate, N.E.S. tert-Amyl perdecanoate, N.E.S. tert-Butyl peroxybutyl fumarate, N.E.S. tert-Amyl peroxyacetate, N.E.S. tert-Butyl peroxycrotonate, N.E.S. (Alt: tert-Butyl percrotonate) tert-Amyl peroxybenzoate, N.E.S. n-Butyl peroxydicarbonate, N.E.S. tert-Amyl peroxyneodecanoate, N.E.S. (Alt: n-Butyl perdicarbonate, and tert-Amyl peroxypivalate, N.E.S. Di-n-butylperoxydicarbonate) Antimony sulfide and chlorate, mixtures of tert-Butyl peroxyisobutyrate, N.E.S. Arsenic sulfide and chlorate, mixtures of (Alt: tert-Butyl perisobutyrate) Ascaridole tert-Butyl peroxyisopropylcarbonate, Azaurolic acid (salts of), N.E.S. N.E.S. Azidodithiocarbonic acid 1-(2-tert-Butylperoxy isopropyl)-3- Azidoethyl nitrate isopropenylbenzene, N.E.S. Azido guanidine picrate, N.E.S. tert-Butyl peroxyneoheptanoate, N.E.S. 5-Azido-1-hydroxy tetrazole tert-Butyl peroxypivalate, N.E.S. Azido hydroxy tetrazole (mercury and (Alt: tert-Butyl perpivalate) silver salts) Butyl vinyl ether, N.E.S. 3-Azido-1,2-propylene glycol dinitrate Calcium azide, N.E.S. Aziridine, N.E.S. (Alt: Ethyleneimine) Carbazide Azotetrazole, N.E.S. Charcoal screenings, wet Barium azide, N.E.S. Charcoal, wet Benzene diazonium chloride, N.E.S. Chloral, anhydrous, N.E.S. APPENDICES

Chloric acid, N.E.S. 1,1-Di-(4-tert-butylperoxy)cyclohexane, Chlorine azide N.E.S. Chlorine cyanide, N.E.S. (Alt: Cyanogen (Alt: 1,1-Bis-(4-tert-butylperoxy) chloride) cyclohexane) Chlorine dioxide Di-n-butylperoxydicarbonate, N.E.S. Chloroacetone, N.E.S. Di-(tert-butylperoxy) phthalate, N.E.S. p-Chlorobenzoyl peroxide, N.E.S. 2,2-Di-(tert-butylperoxy)propane, N.E.S. 2-Chlorobutadiene-1,3, N.E.S. (Alt: Dichloroacetylene, N.E.S. Chloroprene) N,N’-Dichloroazodicarbonamidine (salts 3-Chloroperoxybenzoic acid, N.E.S. of), N.E.S. Chloroprene, N.E.S. Di-4-chlorobenzoyl peroxide, N.E.S. Chlorotrifluoroethylene, N.E.S. (Alt: p-Chlorobenzoyl peroxide) (Alt: Trifluorochloroethylene) Dichloroethyl sulfide Cinnamene, N.E.S. (Alt: Styrene 2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl) monomer) propane, N.E.S. Cinnamol, N.E.S. (Alt: Styrene monomer) Di-2,4-dichlorobenzoyl peroxide, N.E.S. Coal briquettes, hot Diethanol nitrosamine dinitrate, N.E.S. Coke, hot Diethylene glycol dinitrate Copper acetylide Diethylgold bromide Copper amine azide Diethyl perdicarbonate, N.E.S. Copper tetramine nitrate Diethyl peroxydicarbonate, N.E.S. Crotonaldehyde, N.E.S. (Alt: Diethyl pericarbonate) Cumyl hydroperoxide, N.E.S. 2,2-Dihydroperoxy propane, N.E.S. Cumyl peroxyneodecanoate, N.E.S. 1,8-Dihydroxy-2,4,5,7- Cumyl peroxyneoheptanoate, N.E.S. tetranitroanthraquinone (Chrysamminic acid) Cumyl peroxypivalate, N.E.S. Di-(1-hydroxytetrazole), N.E.S. Cyanogen chloride, N.E.S. Diiodacetylene Cyanuric triazide Diisobutyryl peroxide, N.E.S. (Alt: Cyclohexanone peroxide, N.E.S. Isobutyryl peroxide) Cyclotetramethylene tetranitramine, N.E.S. Diisopropylbenzene hydroperoxide, N.E.S. (Alt: HMX) Cyclotrimethylene trinitramine, N.E.S. Di-(2-methylbenzoyl) peroxide, N.E.S. (Alt: RDX or Cyclonite) 2,5-Dimethyl-2,5-di-(tert- Diacetone alcohol peroxides, N.E.S. butylperoxy)hexyne-3, N.E.S. Diacetyl peroxide, N.E.S. (Alt: Acetyl 2,5-Dimethyl-2,5-dihydroperoxyhexane, peroxide) N.E.S. 1,1-Di-(tert-amylperoxy)cyclohexane, 3,5-Dimethyl-3,5-dihydroxydioxolane-1,2, N.E.S. N.E.S. p-Diazidobenzene 2,5-Dimethyl-2,5-di-(3,5,5- trimethylhexanoylperoxy)hexane, 1,1-Diazidoethane N.E.S. 1,1’-Diazidoethane Dimethyleneimine, N.E.S. (Alt: 1,2’-Diazidoethane Ethyleneimine) 1,1’-Diazoaminonaphthalene 2,5-Dimethylhexane-2,5-dihydroperoxide, Diazoaminotetrazole, N.E.S. N.E.S. Diazodinitrophenol, N.E.S. (Alt: 2,5-Dimethyl-2,5-dihydroperoxy Diazodiphenylmethane hexane) Diazonium nitrates, N.E.S. 1,1-Dimethyl-3-hydroxybutyl Diazonium perchlorates, N.E.S. peroxyneoheptanoate, N.E.S. 1,3-Diazopropane Di-(1-naphthoyl) peroxide Dibenzyl perdicarbonate, N.E.S. Di-(2-neodecanoylepoxyisopropyl) Dibenzyl peroxydicarbonate, N.E.S. benzene, N.E.S. Dibromoacetylene Dinitro-7,8-dimethylglycoluril, N.E.S. Di-tert-butyl peroxyazelate, N.E.S. 1,3-Dinitro-5,5-dimethyl hydantoin 2,2-Di-(tert-butylperoxy) butane, N.E.S. 1,3-Dinitro-4,5-dinitrosobenzene (Alt: 2,2-Bis-(tert-butylperoxy) butane) 1,1-Dinitroethane, N.E.S. 1,2-Dinitroethane APPENDICES

Dinitroglycoluril Formaldehyde, gaseous Dinitromethane 2-Formyl-3,4-dihydro-2H-pyran, N.E.S. Dinitropropylene glycol (Alt: Acrolein dimer) 2,4-Dinitroresorcinol (heavy metal salts of), Fulminate of mercury, N.E.S. N.E.S. Fulminating gold 4,6-Dinitroresorcinol (heavy metal salts of), Fulminating platinum N.E.S. Fulminating silver Dinitroresorcinols, N.E.S. Fulminic acid 3,5-Dinitrosalicylic acid (lead salt), N.E.S. Galactan trinitrate Dinitrosobenzylamidine and salts of, Galactsan trinitrate N.E.S. Glycerol-1,3-dinitrate N,N-Dinitroso-N,N’- Glycerol monogluconate trinitrate dimethylterephthalimide, N.E.S. Glycerol monolactate trinitrate N,N’-Dinitrosopentamethylenetetramine, Guanyl nitrosaminoguanylidene hydrazine, N.E.S. N.E.S. 2,2-Dinitrostilbene Guanyl nitrosaminoguanyl tetrazine 1,4-Dinitro-1,1,4,4- Hafnium metal powder, N.E.S., having a tetramethylolbutanetetranitrate, N.E.S. particle size less than 3 micrometres if 2,4-Dinitro-1,3,5-trimethylbenzene mechanically produced or 10 Di-( -nitroxyethyl) ammonium nitrate micrometres if chemically produced ,‘-Di-(nitroxy) methylether Hexamethylene triperoxide diamine, 1,9-Dinitroxy pentamethylene-2,4,6,8- N.E.S. tetramine, N.E.S. Hexamethylol benzene hexanitrate Diperoxy azelaic acid, N.E.S. Hexanitroazoxy benzene Diperoxy dodecane diacid, N.E.S. 2,2’,4,4’,6,6’-Hexanitro-3,3’- Dipropionyl peroxide, N.E.S. (Alt: dihydroxyazobenzene, N.E.S. Propionyl peroxide) 2,2’,3’,4,4’,6-Hexanitrodiphenylamine, Distearyl perdicarbonate, N.E.S. N.E.S. Distearyl peroxydicarbonate, N.E.S. 2,3’4,4’,6,6’p-Hexanitrodiphenylether (Alt: Distearyl perdicarbonate) N,N’-(Hexanitrodiphenyl) ethylene Di-(3,5,5-trimethyl-1,2-dioxolanyl-3) dinitramine, N.E.S. peroxide, N.E.S. Hexanitrodiphenyl urea Di-(3,5,5-trimethylhexanoyl) peroxide, Hexanitroethane N.E.S. Hexanitrooxanilide Divinyl, N.E.S. (Alt: Butadienes) HMX, N.E.S. Divinyl ether, N.E.S. Hydrazine azide Divinyl oxide, N.E.S. (Alt: Divinyl ether) Hydrazine chlorate 2,6-Epoxy-5-hexenal, N.E.S. (Alt: Acrolein Hydrazine dicarbonic acid diazide dimer) Hydrazine perchlorate Ethanolamine dinitrate Hydrazine selenate Ethyl acrylate, N.E.S. Hydrocyanic acid, anhydrous, N.E.S. Ethyl 3,3-di-(tert-amylperoxy)butyrate, Hydrogen cyanide, anhydrous, N.E.S. N.E.S. Hydrogen peroxide, concentrations greater Ethylene diamine diperchlorate than 60% hydrogen peroxide, N.E.S. Ethylene glycol dinitrate Hydroxylamine iodide Ethyleneimine, N.E.S. Hyponitrous acid Ethyl hydroperoxide Ignition element for lighter, containing Ethyl methacrylate, N.E.S. pyrophoric liquid Ethyl methyl ketone peroxide(s), N.E.S. Initiating explosives, N.E.S. Ethyl nitrate Inositol hexanitrate, N.E.S. Ethyl nitrite Inulin trinitrate, N.E.S. Ethyl perchlorate Iodine azide, N.E.S. Ethyl propenoate, N.E.S. (Alt: Ethyl Iodoxy compounds, N.E.S. acrylate) Iridium nitratopentamine iridium nitrate Flammable mixture of dangerous goods of Isobutyl acrylate, N.E.S. Division 2.1 or sub-hazard 2.1 with Isobutyl methacrylate, N.E.S. oxygen, nitrous oxide or air APPENDICES

Isobutyl methyl ketone peroxide, N.E.S. Methylvinylbenzenes, N.E.S. (Alt: Vinyl Isobutyryl peroxide, N.E.S. toluenes) Isoprene, N.E.S. Monochloroacetone, N.E.S. Isopropyl sec-butyl peroxydicarbonate Naphthalene diozonide + Di-sec-butyl peroxydicarbonate Naphthylamine perchlorate + Di-isopropyl peroxydicarbonate, Nickel picrate N.E.S. Nitrated paper (unstable) Isopropylcumyl hydroperoxide, N.E.S. Nitrates of diazonium compounds (Alt: Diisopropylbenzene N-Nitroaniline hydroperoxide) m-Nitrobenzene diazonium perchlorate Isothiocyanic acid Nitrocellulose, N.E.S. Lead azide, N.E.S. Nitrocotton, N.E.S. Lead mononitroresorcinate, N.E.S. 6-Nitro-4-diazotoluene-3-sulfonic acid, Lead picrate, N.E.S. N.E.S. Lead styphnate, N.E.S. Nitroethyl nitrate Lead 2,4,6-trinitroresorcinate, N.E.S. Nitroethylene polymer Lighters (cigarettes) containing pyrophoric Nitrogen trichloride liquid Nitrogen triiodide Magnesium dross, wet or hot Nitrogen triiodide monoamine Mannitan tetranitrate Nitroglycerin, liquid, N.E.S. Mercurous azide Nitroguanidine, N.E.S. Mercury acetylide Nitroguanidine nitrate Mercury iodide aquabasic ammonobasic 1-Nitro hydantoin (Iodide of Millon’s base) Nitroisobutanetriol trinitrate Mercury nitride Nitromannite, N.E.S. Mercury oxycyanide, N.E.S. N-Nitro-N-methylglycolamide nitrate Methacrylic acid, N.E.S. 2-Nitro-2-methylpropanol nitrate Methazoic acid m-Nitrophenyldinitro methane Methyl acetylene/propadiene, mixtures, Nitrostarch, N.E.S. N.E.S. Nitrosugars, N.E.S. -Methyl acrolein, N.E.S. (Alt: Octogen, N.E.S. Crotonaldehyde) 1,7-Octadiene-3,5-diyne-1,8-dimethoxy-9- Methyl acrylate, N.E.S. octadecynoic acid Methylamine dinitramine and dry salts Organic peroxide type A, liquid thereof Organic peroxide type A, solid Methylamine nitroform Pentaerythrite tetranitrate, N.E.S. Methylamine perchlorate, N.E.S. Pentaerythritol tetranitrate, N.E.S. Methyl-1,3-butadiene, N.E.S. (Alt: Pentanitroaniline, N.E.S. Isoprene) Peracetic acid, N.E.S. Methylcyclohexanone peroxide(s), N.E.S. Perchloric acid, N.E.S. Methyldichloroarsine Peroxyacetic acid, N.E.S. Methylene glycol dinitrate PETN, N.E.S. Methyl ethyl ketone peroxide(s), N.E.S. m-Phenylene diaminediperchlorate, N.E.S. -Methylglucoside tetranitrate Phenylethylene, N.E.S. (Alt: Styrene -Methylglycerol trinitrate monomer) Methyl isobutyl ketone peroxide(s), N.E.S. Phosphorus (white or red) and a chlorate, Methyl methacrylate monomer, N.E.S. mixtures of Methyl nitramine, metal salts of Picric acid, N.E.S. Methyl nitrate Potassium carbonyl Methyl nitrite 2-Propenal, N.E.S. (Alt: Acrolein) Methyl picric acid, heavy metal salts of Propenenitrile, N.E.S. (Alt: Acrylonitrile) Methylpropyl acrylate, N.E.S. (Alt: Isobutyl Propenoic acid, N.E.S. (Alt: Acrylic acid) acrylate) Propionyl peroxide, N.E.S. Methylstyrenes, ortho-, meta-, para-, Propylene aldehyde, N.E.S. (Alt: N.E.S. Crotonaldehyde) Methyl trimethylol methane trinitrate Propyleneimine, N.E.S. APPENDICES

Pyridine perchlorate 2,4,4-Trimethylpentyl-2- Quebrachitol pentanitrate peroxyneodecanoate, N.E.S. Selenium nitride 1,3,5-Trimethyl-2,4,6-trinitrobenzene Self-reactive liquid type A Trinitroacetic acid, N.E.S. Self-reactive solid type A Trinitroacetonitrile Shaped charges (commercial) containing Trinitroamine cobalt more than 220g of explosives Trinitrobenzene, N.E.S. Silver acetylide, N.E.S. Trinitrobenzoic acid, N.E.S. Silver azide, N.E.S. 2,4,6-Trinitro-1,3-diazobenzene Silver chlorate, N.E.S. Trinitroethanol Silver chlorite, N.E.S. Trinitroethylnitrate Silver fulminate, N.E.S. Trinitromethane Silver oxalate, N.E.S. 1,3,5-Trinitronaphthalene Silver perchlorate Trinitrophenol, N.E.S. (Alt: Picric acid) Silver picrate, N.E.S. 2,4,6-Trinitrophenyl guanidine, N.E.S. Sodium dinitro-o-cresolate, N.E.S. 2,4,6-Trinitrophenyl nitramine Sodium picramate, N.E.S. 2,4,6-Trinitrophenyl trimethylol methyl Sodium picryl peroxide nitramine trinitrate, N.E.S. Sodium tetranitride 2,4,6-Trinitroso-3-methyl nitraminoanisole Styrene, monomer, N.E.S. Trinitrotetramine cobalt nitrate Sucrose octanitrate, N.E.S. 2,4,6-Trinitro-1,3,5-triazido benzene, Sulfur and chlorate, loose mixtures of N.E.S. Sulfur trioxide, N.E.S. Tri-( -nitroxyethyl) ammonium nitrate Sulfuric anhydride, N.E.S. (Alt: Sulfur Tris-bis-bifluoroamino diethoxy propane trioxide) (TVOPA) Tetraazido benzene quinone Urea nitrate, N.E.S. Tetrachloromethyl perchlorate Vinyl acetate, N.E.S. Tetraethylammonium perchlorate, N.E.S. Vinyl benzene, N.E.S. (Alt: Styrene, Tetrafluorohydrazine monomer) Tetrahydrofuran, N.E.S. Vinyl bromide, N.E.S. Tetramethylene diperoxide dicarbamide Vinyl-n-butylether, N.E.S. (Alt: Vinyl Tetranitrodiglycerin butylether) 2,3,4,6-Tetranitrophenol Vinyl butyrate, N.E.S. 2,3,4,6-Tetranitrophenyl methyl nitramine Vinyl chloride, N.E.S. 2,3,4,6-Tetranitrophenylnitramine Vinyl cyanide, N.E.S. (Alt: Acrylonitrile) Tetranitroresorcinol, N.E.S. Vinyl ether, N.E.S. (Alt: Divinyl ether) 2,3,5,6-Tetranitroso-1,4-dinitrobenzene Vinyl ethyl ether, N.E.S. 2,3,5,6-Tetranitroso nitrobenzene, N.E.S. Vinyl fluoride, N.E.S. Tetrazine, N.E.S. Vinylidene, N.E.S. Tetrazolylazide, N.E.S. Vinyl isobutylether, N.E.S. Titanium dichloride Vinyl methyl ether, N.E.S. Tolyethylenes, mixed isomers, N.E.S. Vinyl nitrate polymer (Alt: Vinyl toluenes) Vinyl pyridines, N.E.S. Trichloroacetaldehyde, anhydrous, N.E.S. Vinyl toluenes, mixed isomers, N.E.S. (Alt: Chloral) Vinyl trichlorosilane, N.E.S. Trichloroacetic aldehyde, anhydrous, p-Xylyl diazide N.E.S. (Alt: Chloral) Zirconium picramate, N.E.S. Trichloromethyl perchlorate Trifluorochloroethylene, N.E.S. Trifluoromonochloroethylene, N.E.S. Triformoxime trinitrate Trimethylene glycol diperchlorate Trimethylol nitromethane trinitrate 2,2,4-Trimethylpentyl-2-peroxyphenoxy acetate, N.E.S. APPENDICES

APPENDIX B: FORMS

NOTE 1: Appendix B of UN20 is a Glossary of Terms relating to Explosives. That Glossary is repeated in the Australian Explosives Code. Where the symbol ‘†’ is included in Column 2 of the Dangerous Goods List in Section 3.2.5 of this Code, this is an indication that reference should be made to Appendix B of UN20 or to Appendix 5 of the Australian Explosives Code.

NOTE 2: This appendix includes forms that are referenced in the text of this Code that may be useful when consigning or transporting dangerous goods, or in responding to emergencies. The use of these forms is not mandated by this Code or the Regulations. These forms may be printed from this publication by printing only the page number(s) of the required form.

B 1 Multimodal Dangerous Goods Form Figure B1 is a copy of the Multimodal Dangerous Goods Form, reproduced from Chapter 5.4 of UN20. Use of such a form is mandatory under the IMDG Code for sea transport of dangerous goods. For road and rail transport in Australia, the actual format of the dangerous goods transport document is not mandated. Flexibility of transport documentation design is permitted within the constraints of Chapter 11.1, to allow for computer generated documentation and preprinted forms. The Multimodal Dangerous Goods Form is, however, an acceptable form of documentation under this Code and may be useful for small consignments where details are entered by hand. Particular attention is drawn to the need to enter the dangerous goods details at Item 14 as a character string in a particular sequence (see 11.1.1.2.3). If using this form as a transport document solely for transport of dangerous goods by road or rail within Australia, it is not necessary to complete those fields that are required by the international Codes but are not mandated in Part 11 of this Code.

B 2 Sample Generic Concessional Limited Quantities Transport Document loads Figure B2 is a sample generic transport document that may be used, when correctly completed, in lieu of a transport document that complies with Part 11, for the transport of dangerous goods that fully comply with all of the conditions of the Concessional Limited Quantity requirements prescribed in Chapter 3.4.10.

B 3 Revised Hazchem Emergency Action Code Pocket Card Figure B3 is a double sided card that provides interpretation of the revised Hazchem Codes as incorporated in Appendix C. When used in conjunction with Hazchem Codes on emergency information panels prepared in accordance with the previous edition of this Code, any characters in reverse print should be read as the corresponding letter in normal print. The advice provided by following this card will still be valid.

APPENDICES

Figure B1: Multimodal Dangerous Goods Form 1. Shipper / Consignor /Sender 2. Transport document number

3. 4. Shipper’s reference Page 1 of ……… pages 5. Freight Forwarder’s reference

6. Consignee 7. Carrier (to be completed by the carrier)

SHIPPER’S DECLARATION I hereby declare that the contents of this consignment are fully and accurately described below by the proper shipping name, and are classified, packaged, marked and labelled / placarded and are in all respects in proper condition for transport according to the applicable international and national governmental regulations. 8. This shipment is within the limitations prescribed for: 9. Additional handling information (Delete non-applicable) PASSENGER AND CARGO AIRCRAFT ONLY CARGO AIRCRAFT 10. Vessel / flight 11. Port / place of loading

No. and date

) 12. Port / place of 13. Destination discharge

14. Shipping marks * Number and kind of packages; description of goods Gross mass (kg) Net mass Cube 3 (m )

packing(where group assigned

15. Container identification 16. Seal number(s) 17. Container/vehicle size & 18. Tare 19. Total gross No./ type (kg) mass vehicle registration No. (including tare)

(kg)

CONTAINER/VEHICLE PACKING 21. RECEIVING ORGANISATION RECEIPT CERTIFICATE I hereby declare that the goods described Received the above number of packages/containers/trailers in apparent above have been packed/loaded into the good order and condition unless stated hereon: RECEIVING container/vehicle identified above in ORGANISATION REMARKS: accordance with the applicable provisions ** MUST BE COMPLETED AND SIGNED

and any other element other any and information of required applicable under national international and regulations FOR ALL CONTAINER / VEHICLE LOADS BY PERSON RESPONSIBLE FOR PACKING / LOADING 20. Name of company Haulier’s name 22. Name of company (OF SHIPPER

PREPARING THIS NOTE) * FOR DANGEROUS FOR * GOODS specify: must you proper No., UN shipping name, hazardclass, Name / Status of declarant Vehicle reg. no. Name / Status of declarant

Place and date Signature and date Place and date

Signature of declarant DRIVER’S SIGNATURE Signature of declarant

** See 5.4.2.1 of the UN Model Regulations.

APPENDICES

MULTIMODAL DANGEROUS GOODS FORM

1. Shipper / Consignor /Sender 2. Transport document number

3. 4. Shipper’s reference Page ……. of ……… pages

5. Freight Forwarder’s reference

) and any other other any and ) information of element required applicable under national international nd a regulations 14. Shipping marks * Number and kind of packages; description of goods Gross mass (kg) Net mass 3

Cube (m )

FOR DANGEROUS GOODS DANGEROUS FOR you specify: must shipping proper name, class, hazard packing No., UN (where group assigned

APPENDICES

Figure B2: Sample Concessional Limited Quantities Transport Document TRANSPORT DOCUMENT - CONCESSIONAL LIMITED QUANTITY LQ Loads LOADS Consignor:This documentation applies for non-placard and placardConsignee: loads Address: Address:

A) Inner packaging must not exceed Limited Quantities amount, found in Column 7 of the Dangerous Goods List in Section 3.2.3 of the ADG Code Edition 7.5 B) UN 0337, UN 1057, UN 2911 and UN 1044 do not have set quantity limits Class or division or specific substance Max LQ Total a Only include the quantity of those substances on the load Package Size Quantity 1.4S UN0337 fireworks (party poppers, sparklers and bon bons only) B N/A 2 UN1950 aerosols 1 L 2.1 Flammable gas 120 ml 2.1 UN1057- lighters or lighter refills B N/A 2.2 UN1044 – fire extinguishers (portable only)B N/A 2.2 Other non-flammable non-toxic gas 120 ml 3 Nitromethane, UN 1261 1 L (PGII) 3 Other flammable liquid 1 L (PGII) 5 L (PGIII) 4.1 Flammable solid 1 KG (PGII) 5 KG (PGIII) 4.2 Substances liable to spontaneous combustion 500 g (PGII) 1 KG (PGIII) 4.3 Substances which in contact with water emit flammable gases 500 g (PGII) 1 KG (PGIII) 5.1 Calcium hypochlorite (UN 1748, 2208, 2880, 3485, 3486, 3487) 1 KG (PGII) 5 KG (PGIII 5.1 Dicholoroisocyanuric acid, trichloroisocyanuric acid 1 KG (PGII) 5 KG (PGIII) UN 2465, 2468 or any -chloroisocyanurate 5.1 Any bromate, chlorate, chlorite (also Class 8), hypochlorite 1 KG (PGII) 5 KG (PGIII 5.1 Other oxidising agent 1 KG (PGII) 5 KG (PGIII) 5.2 Organic peroxide 500 g 6.1 Toxic 500 g (PGII) 5KG (PGIII) 7 UN2911 – domestic smoke detectors B N/A 8 Strong and concentrated acids (concentrated versions of UN 1830, 2796, 1832, 1 KG (PGII) 1789, 1788, 1787, 2031, 1802) 5 KG (PGIII) 8 Strong and concentrated alkalis (concentrated versions of UN 2679, 2680, 1823, 1 KG (PGII) 1824, 1813, 1814, 2677, 2678, 2681, 2682, 1564, 2923, 3262, 1759) 5 KG (PGIII) 8 Other corrosive 1 KG (PGII) 5 KG (PGIII) 9 Miscellaneous 1 KG (PGII) 5 KG (PGIII) Any inorganic nitrate (various classes) 1 KG (PGII) 5 KG (PGIII) Total aggregate quantity Food (do not include in the aggregate quantity) Yes / No Certification: This load complies with all the characteristics of a CLQ Load specified in Chapter 3.4.10 of the ADG Code Name: Title: Signature: Date: APPENDICES

Figure B3: Revised Hazchem Pocket Card

Front Back

HAZCHEM Additional Information DRY AGENT Emergency Water must not be allowed to come Action Code into contact with the substance at risk. FOR FIRE OR SPILLAGE ALCOHOL RESISTANT FOAM •2 or •3 Alcohol resistant foam is the preferred 1 COARSE SPRAY medium. 2 FINE SPRAY If not available: – If •2 – use Fine Spray or Water Fog 3 FOAM – If •3 – use Normal Protein Foam 4 DRY AGENT V • ALCOHOL RESISTANT Substance can be violently or even FOAM explosively reactive, including combustion. P V LTS LTS R Liquid-Tight Chemical Protective Suit DILUTE S V BA & FIRE with BA. T KIT Full FIRE KIT should also be worn for thermal protection if the substance is: W V LTS Liquid Oxygen X CONTAI or Liquefied Toxic Gas (Division 2.3) Y V BA & FIRE N or Toxic Gas with sub-hazard 2.1 or 5.1 Z KIT or Class or sub-hazard 3 or Division 5.1 PGI with sub-hazard 6.1 or 8 E PUBLIC SAFETY HAZARD or carried at temperature > 100°C DILUTE May be washed to drain with large quantities of water. CONTAIN Prevent, by any means available, spillage from entering drains or water course. E People should be warned to stay indoors with all doors and windows closed, –but evacuation may need to be considered. Consult Control, Police and product expert.

APPENDICES

APPENDIX C: HAZCHEM CODES Introductory Notes

C1 Scope and Application

C1.1 This Appendix provides additional information that may be useful in event of an emergency for most dangerous goods listed in the Dangerous Goods List in Chapter 3.2. For the UN Numbers with information, two codes are listed in C3, as follows: (a) the HAZCHEM Code, as listed in the Dangerous Goods Emergency Action Code List 2013, published by HM Fire Service Inspectorate of the United Kingdom. This is the primary code used in Australia; and (b) the Hazard Identification Number (HIN) assigned in the ADR and RID, which is provided for information purposes only.

NOTE The list of Emergency Action Codes (EACs) is current at the time of publishing the ADGC. Later editions of the Dangerous Goods Emergency Action Code List may need to be checked for amendments to the Hazchem Codes.

C1.2 When dangerous goods are transported in portable tanks, demountable tanks, multiple element gas containers, bulk containers or tank vehicles, it is a requirement of Chapter 5.3 of this Code that the Hazchem Code be displayed on the emergency information panel. This Hazchem Code should be determined from the list in C3.

C1.3 The codes allocated and shown in the list in C3 apply to transport of the single substance by road or rail. These codes will not necessarily apply for non-transport incidents although they may be used to provide some indication of the action that may be necessary.

C2 Hazchem Codes

NOTE: The Hazchem Code is fully titled “Hazchem Emergency Action Code”. In European publications, it is now frequently referred to simply as “Emergency Action Code” or “EAC”. In Australia it is still commonly known as the Hazchem Code.

C2.1 General

C2.1.1 A Hazchem Code offers guidance on appropriate initial emergency response in a potentially dangerous situation such as leakage, spillage or fire involving the dangerous goods to which it relates.

C2.1.2 The Hazchem Code is composed of a number, followed by one or more letters as detailed in C2.2–C2.65.

C2.1.3 Hazchem Codes are allocated to most dangerous goods in Column 2 of the table at C3. APPENDICES

C2.1.4 In some cases, there is more than one Hazchem Codeshown in C3 for a single UN number. In each such instance, a notation which is explained at the end of the table indicates how to determine which of the multiple entries applies e.g. for UN 1224 Ketones where two Hazchem Codes are listed – the notation (3) next to the entry 3YE indicates that this Hazchem Code applies only to ketones of packing groups I and II –3Y therefore applies to packing group III.

C2.1.5 Substances in Class 7, i.e. radioactive material, have not been allocated Hazchem Codes.

C2.2 Extinguishing Media

C2.2.1 The firefighting extinguishing media is determined by reference to the first character of the Hazchem Code as follows: 1 denotes coarse water spray 2 denotes fine water spray 3 denotes normal foam i.e. protein based foam that is not alcohol resistant 4 denotes dry agent —water MUST NOT be allowed to come into contact with substance

NOTE: Any higher number than the one shown can be used but a lower number must not be used.

C2.2.2 A bullet ‘•’ sometimes precedes the number 2 or 3 in the list in C3. •2 and •3, have the following meanings: •2 denotes that alcohol resistant foam is the preferred firefighting medium but, if it is not available, fine water spray can be used. •3 denotes that alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used. For example, the Hazchem Code assigned to UN 1193 Ethyl Methyl Ketone in C3 is •2YE. The ‘•’ here indicates to the emergency services that alcohol resistant foam is the preferred firefighting medium. However, if such foam is not available, fine water spray, as the next most effective medium, should be used. Table C1: Meaning of Second Character of Hazchem Code Risk of Violent Recommended Personal Appropriate Letter Reaction or Explosion Protective Equipment Measures P Yes Liquid-tight chemical protective R No clothing and breathing apparatus Dilute S Yes Full fire kit T No and breathing apparatus W Yes Liquid-tight chemical protective X No clothing and breathing apparatus Contain Y Yes Full fire kit Z No and breathing apparatus

NOTE: See C 2.3 to C2.5 for further details.

C2.3 Personal protection APPENDICES

C2.3.1 Where the second character of the Hazchem Code is S, T, Y or Z, normal firefighting clothing is appropriate, i.e. self-contained open circuit positive pressure compressed air breathing apparatus, worn in combination with fire kit, firefighters’ gloves and firefighters’ boots.

NOTE 1: Leather boots may not provide adequate chemical resistance and therefore caution should be exercised in their use.

NOTE 2: Letters S, T, Y and Z, which In previous editions of this Code were shown in reverse printing or square brackets for some dangerous goods, are now always shown in normal print, indicating that breathing apparatus should be used for all significant incidents.

NOTE 3: LP Gas, which in previous Codes was assigned a Hazchem Code of 2WE, is now assigned to 2YE in recognition that the most important personal protection from this substance is thermal protection that is best provided by full fire kit, including breathing apparatus.

C2.3.2 Where the second character of the Hazchem Code is P, R, W or X, liquid-tight chemical protective clothing in combination with breathing apparatus specified in C2.3.1, should be used.

C2.3.3 For some substances for which liquid-tight chemical protective clothing is indicated, full fire kit should also be worn for thermal protection. This applies to incidents involving the following substances when they are assigned to P, R, W, or X: (a) UN 1073 Oxygen, Refrigerated Liquid; (b) All Division 2.3 Toxic Gases when transported in the liquefied state; (c) Any Division 2.3 Gas with a Subsidiary Hazard of 2.1 or 5.1; (d) Class or Subsidiary Hazard 3 liquids; (e) Division 5.1 substances of packing group I, having a Subsidiary Hazard of 6.1 or 8; (f) Substances transported at elevated temperature > 100 °C. However, an incident controller may determine, through a risk based assessment, that full fire kit need not be worn.

C2.4 Violent Reaction

C2.4.1 Where the second character of the Hazchem Code is a P, S, W or Y there is a danger that the substance can be violently or explosively reactive. This danger may be present due to one of the following: - Violent or explosive decomposition of the material involved, including ignition or friction. - The ignition of a flammable gas or vapour cloud (this danger exists for all flammable gases and flammable liquids with a flash point below 60 °C) - The rapid acceleration of combustion due to the involvement of an oxidiser. - A reaction with water which is itself violent, and may also evolve flammable gases. APPENDICES

C2.4.2 The actual dangers present can be determined from the placards on vehicles or containers, or by reference to the classes, divisions and subsidiary hazards shown on the transport document.

C2.5 Contain/dilute Where the second character of an Hazchem Code is W, X, Y or Z spillages and decontamination run-off should be prevented from entering drains and watercourses. Where the second character of the code is P, R, S or T spillages and decontamination run-off may be washed to drains with large quantities of water. Due care must however still be exercised to avoid unnecessary pollution of watercourses.

NOTE 1: Ideally most contamination and decontamination run-off should be contained. However, this will not always be practical for normal emergency services operations, as life-saving operational procedures must take precedence over other considerations at the scene of an incident. Nevertheless, all steps that are reasonably practicable should be taken to contain contaminants and the emergency service should always inform the environmental authority as soon as possible so that appropriate advice can be given.

NOTE 2: Potentially polluting substances, even apparently harmless substances such as food and beverages, can cause serious problems if discharged into a watercourse e.g. 250 litres of a soft drink, milk or beer would constitute a pollutant as it can lead to deoxygenation of the water. Firefighting foams are also a potential source of pollution and their entry into watercourses and drainage systems should be prevented whenever possible.

C2.6 E “Public Safety Hazard” An ‘E’ following the first two characters of a Hazchem Code indicates that there may be a public safety hazard outside the immediate area of the incident, and that the following actions should be considered:

C2.6.1 People should be warned to stay indoors with all doors and windows closed, preferably in rooms upstairs and facing away from the incident. Ignition sources should be eliminated and any ventilation stopped.

C2.6.2 Effects may spread beyond the immediate vicinity. All non-essential personnel should be instructed to move at least 250 metres away from the incident.

C2.6.3 Police and Fire Brigade incident commanders should consult each other and with a product expert, or with a source of product expertise.

C2.6.4 The possible need for subsequent evacuation should be considered, but it should be remembered that in most cases it will be safer to remain in a building than to evacuate. Some situations where evacuation may be necessary are listed in Table C2.

APPENDICES

Table C2.6: Situations where evacuation may be necessary

EXAMPLES ASSESSMENT 1.(i) Smoke from product fire which is Nuisance effects will last several hours. allowed to burn out. (Often the Smoke or gas concentrations in open air safest and least environmentally are unpleasant but short-term exposure is damaging option.) not likely to be dangerous. (ii) Small/low concentration long lasting toxic emission. 2. A larger long lasting toxic gas Area considered for evacuation will not be emission which will be carried exposed to significant danger for at least towards an inhabited area after a an hour, preferably longer. predicted wind change not due for at least two hours. 3. Evacuation of people from an Downwind area is very sparsely isolated house in the country may populated and resources are available to be feasible, possibly using protect people during their evacuation. additional BA sets. 4.(i) Righting a loaded road tanker or Area considered for evacuation could be rail tank wagon, especially one exposed to danger as a result of actions carrying a liquefied gas. necessary to restore normality at a time (ii) Recovering or clearing petrol from determined by the recovery team. drains.

C2.7 Assigning Hazchem Codes to multi-loads The following procedure must be used to assign a Hazchem Code to a vehicle or cargo transport unit transporting more than one type of dangerous goods to which different Hazchem Codes are assigned by C3.

C2.7.1 1st character of the code The number forming the first character of the code for a multi-load is the highest of the numbers occurring in the Hazchem Codes for the individual dangerous goods.

1.- If the 1st character of the calculated multi-load Hazchem Code is 2 or 3 and if one or more of the individual Hazchem Codes has an alcohol resistant bullet include an alcohol resistant bullet in the multi-load Hazchem Code

2.- If the 1st character of the calculated multi-load Hazchem Code is 4 do not include a bullet, even if one or more of the individual Hazchem Codes includes an alcohol resistant bullet (on the basis that 4 indicates that a dry agent must be used).

C2.7.2 2nd Character of the code

C2.7.2.1 The letter forming the second character of the code should be determined from the first letter of the Hazchem Code for each of the dangerous goods from the chart below.

APPENDICES

Table C2.7: Hazchem Code chart for determination of Hazchem codes for multi-loads Hazchem calculation

P R S T W X Y Z P P P P P W W W W R P R P R W X W X S P P S S W W Y Y T P R S T W X Y Z W W W W W W W W W X W X W X W X W X Y W W Y Y W W Y Y Z W X Y Z W X Y Z

Table C2.7.2.1: Code chart for determination of Hazchem codes for multi-loads

C2.7.2.2 If the letter forming the second character of the code for each of the dangerous goods is the same, then that letter will automatically form the second character of the Hazchem Code for the multi-load.

C2.7.2.3 If however the letter forming the second character of the code for each of the dangerous goods is different, then one of those letters should be selected along the top row of the chart and then a second letter should be selected down the far left-hand column i.e. the two bold sections. The letter in the square where the appropriate column and row meet is the ‘resultant letter’ for those two substances. If there are only two dangerous goods to be carried in the multi-load, then that resultant letter is the letter forming the second character of the Hazchem Code for that multi-load.

C2.7.2.4 If there are more than two dangerous goods to be carried in the multi- load, then use the ‘resultant letter’ obtained in paragraph C2.7.2.3 along the top row as above and select another letter down the far left-hand column as above. The letter in the square where the appropriate column and row meet is the new ‘resultant letter’. If there are no more dangerous goods to be carried in the multi-load, then that ‘resultant letter’ is the letter forming the second character of the code. If there are any further dangerous goods to be carried then this procedure must be repeated until all the other letters have been used.

C2.7.3 Letter ‘E’ The letter ‘E’ must be included as the third character in the multi-load Hazchem Code if it occurs in the Hazchem Code of any of the dangerous goods to be carried. If the letter ‘E’ does not occur in any of the Hazchem Codes of the dangerous goods to be carried, the Hazchem Code will be just a two character code determined from C2.7.2 above. Example of how to calculate the Hazchem Code for a multi-load: There are three substances to be carried as a multi-load, having Hazchem Codes of 3Y, •2S and 4WE.

APPENDICES

1ST CHARACTER (NUMBER) The first character of the Hazchem Code for each of the three substances is 2, 3 and 4. The highest number must be taken as the first character of the code for the multi-load and therefore the first character will be 4. Alcohol resistant bullet The bullet in •2S is not assigned to the mixed load because the first character is 4 (see 2.7.1). If the example had only included 3Y and •2S the first character would be 3 and the alcohol resistant bullet would be required.

2ND CHARACTER (LETTER) The second character for the Hazchem Code for each of the three substances is Y, S and W. Taking the Y along the top row of the chart and the S along the left hand column, the intersection is at Y and therefore the character for the first two substances would be Y. This resultant character (Y) is then taken along the top row and the character for the third substance (W) is taken along the left hand column. The intersection point is now W. The second character of the code for the three substances is therefore W.

LETTER ‘E’ The third substance has an ‘E’ as a third character and therefore the multi-load must also have an ‘E’. The resultant Hazchem Code for the three substances carried as a multi-load will therefore be 4WE.

APPENDICES

Table C3: List Of Hazchem Codes

NOTE 1: The HIN listing below and its explanation in C4 are provided for information purposes only.

NOTE 2: The use of the bullet ‘•’ sometimes preceding ‘2’ or ‘3’ in the Hazchem Code is explained in C2.2.2.

Table Notes: (1) No HIN issued under RID and ADR (2) No Hazchem Code issued to these articles (3) This Hazchem Code applies to PG I & II (4) This Hazchem Code applies only to PG I (5) This Hazchem Code applies only to liquid material carried under this UN No. (6) This Hazchem applies only when transported at > 100 ºC (7) This Hazchem Code applies only when ethanol is being transported

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1001 2SE 239 1041 2SE 239 1079 2RE 268 1002 2T 20 1043 2RE (1) 1080 2TE 20 1003 2P 225 1044 (2) (1) 1081 2SE 239 1005 2XRE 268 1045 2PE (1) 1082 2WE 263 1006 2T 20 1046 2T 20 1083 2PE 23 1008 2RE 268 1048 2RE 268 1085 2YE 239 1009 2TE 20 1049 2SE 23 1086 2YE 239 1010 2YE 239 1050 2RE 268 1087 2YE 239 1011 2YE 23 1051 2WE (1) 1088 •3YE 33 1012 2YE 23 1052 2XE 886 1089 •2YE 33 1013 2T 20 1053 2WE 263 1090 •2YE 33 1014 2S 25[DK8] 1055 2YE 23 1091 •2YE 33 1016 2SE 263 1056 2TE 20 1092 •2WE 663 1017 2XE 265 1057 (2) (1) 1093 •3WE 336 1018 2TE 20 1058 2TE 20 1098 •2WE 663 1020 2TE 20 1060 2YE 239 1099 2WE 336 1021 2TE 20 1061 2PE 23 1100 3YE 336 1022 2TE 20 1062 2X 26 1104 •3Y 30 1023 2SE 263 1063 2YE 23 1105 •3YE(3) 33 1026 2PE 263 1064 2WE 263 1105 •3Y 30 1027 2YE 23 1065 2T 20 1106 •2WE(3) 338 1028 2TE 20 1066 2T 20 1106 38 1029 2TE 20 1067 2PE 265 •2W 1030 2YE 23 1069 2RE (1) 1107 3YE 33 1032 2PE 23 1070 2P 25 1108 3YE 33 1033 2YE 23 1071 2SE 263 1109 3Y 30 1035 2YE 23 1072 2S 25 1110 3Y 30 1036 2PE 23 1073 2P 225 1111 3WE 33 1037 2YE 23 1075 2YE 23 1112 3Y 30 1038 2YE 223 1076 2XE 268 1113 3YE 33 1039 2SE 23 1077 2YE 23 1114 3WE 33 1040 2PE 263 1078 2TE 20 1120 •2YE(3) 33 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1120 •2Y 30 1170 •2Y 30 1224 •3YE(3) 33 1123 3YE(3) 33 1171 •2Y 30 1224 •3Y 30 1123 3Y 30 1172 •2Y 30 1228 3WE 336/36 1125 •2WE 338 1173 •3YE 33 1229 •3Y 30 1126 2YE 33 1175 3YE 33 1230 •2WE 336 1127 3YE 33 1176 •3YE 33 1231 •2YE 33 1128 •3YE 33 1177 3Y 30 1233 3Y 30 1129 •3YE 33 1178 3YE 33 1234 •2YE 33 1130 3Y 30 1179 3YE 33 1235 •2WE 338 1131 2WE 336 1180 3Y 30 1237 •3YE 33 1133 •3YE(3) 33 1181 2W 63 1238 2WE 663 1133 •3Y 30 1182 •3WE 663 1239 3WE 663 1134 2Y 30 1183 4WE X338 1242 4WE X338 1184 2YE 336 1243 •2YE 33 1135 •2W 663 1185 •2WE 663 1244 •2WE 663 1136 3WE(3) 33 1188 •2Y 30 1245 •3YE 33 1136 3W 30 1189 •2Y 30 1246 3YE 339 1139 •3YE(3) 33 1190 •2YE 33 1247 3YE 339 1139 •3Y 30 1191 3Y 30 1248 3YE 33 1143 •2WE 663 1192 •2Y 30 1249 •3YE 33 1144 3YE 339 1193 •2YE 33 1250 4WE X338 1145 3YE 33 1194 •2WE 336 1251 •2WE 639 1146 3YE 33 1195 •3YE 33 1259 2WE 663 1147 3Y 30 1196 4WE X338 1261 •2Y (1) 1148 •2YE(3) 33 1197 3YE(3) 33 1262 3YE 33 1148 •2Y 30 1197 3Y 30 1263 •3YE(3) 33 1149 3Y 30 1198 •2W 38 1263 •3Y 30 1150 2YE 33 1199 •3Y 63 1264 •2Y 30 1152 3Y 30 1201 •2YE(3) 33 1265 3YE 33 1153 •3YE(3) 33 1201 •2Y 30 1266 •3YE(3) 33 1153 •3Y 30 1202 3Y 30 1266 •3Y 30 1154 •2WE 338 1203 3YE 33 1267 3WE(3) 33 1155 •3YE 33 1204 •2YE (1) 1267 3W 30 1156 33 •3YE 1206 3YE 33 1268 3YE(3) 33 1157 3Y 30 1207 3Y 30 1268 3Y 30 1158 •3WE 338 1208 3YE 33 1270 3YE 33 1159 3YE 33 1210 •3YE(3) 33 1270 •3YE(7) 33 1160 •2WE 338 1210 •3Y 30 1272 3Y 30 1161 3YE 33 1212 •3Y 30 1274 •2YE(3) 33 1162 4WE X338 1213 3YE 33 1274 •2Y 30 1163 •2WE 663 1214 •2WE 338 1275 •2YE 33 1164 3YE 33 1216 3YE 33 1276 •2YE 33 1165 •2YE 33 1218 3YE 339 1277 •2WE 338 1166 •2YE 33 1219 •2YE 33 1278 3YE 33 1167 3YE 339 1220 •3YE 33 1279 2YE 33 1169 3YE(3) 33 1221 •2WE 338 1280 •3YE 33 1169 3Y 30 1222 3YE (1) 1281 •3YE 33 1170 •2YE(3) 33 1223 3Y 30 1282 •2WE 33 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1286 3YE(3) 33 1332 1Z 40 1393 4W 423 1286 3Y 30 1333 IZ (1) 1394 4W 423 1287 3YE(3) 33 1334 1Z 40 1395 4W 462 1287 3Y 30 1336 1W (1) 1396 4W 423 1288 3WE(3) 33 1337 1W (1) 1397 4WE (1) 1288 3W 30 1338 1Z 40 1398 4Y 423 1289 •2WE(3) 338 1339 4Y 40 1400 4W 423 1289 •2W 38 1340 4W 423 1401 4W 423 1292 3Y 30 1341 4Y 40 1402 4W X423/ 1343 4Y 40 423423 1293 •2YE(3) 33 1344 1W (1) 1403 4W 423 1293 •2Y 30 1345 1Z 40 1404 4W (1) 1294 3YE 33 1346 1Z 40 1405 4W 423 1295 4WE X338 1347 1W (1) 1407 4W X423 1296 •2WE 338 1348 1W (1) 1408 4W 462 1297 •2WE(3) 338 1349 1W (1) 1409 4W 423 1297 •2W 38 1350 1Z 40 1410 4W (1) 1298 4WE X338 1352 1Z 40 1411 4WE (1) 1299 3Y 30 1353 1Z (1) 1413 4W (1) 1300 3YE(3) 33 1354 1W (1) 1414 4W (1) 1300 3Y 30 1355 1W (1) 1415 4W X423 1301 339 •3YE 1356 1W (1) 1417 4W 423 1302 3YE 339 1357 1W (1) 1418 4W 423 1303 2YE 339 1358 1Z 40 1419 4WE (1) 1304 3YE 339 1360 4WE (1) 1420 4W X323 1305 4WE X338 1361 1Y 40 1421 4W X323 1306 •3YE(3) 33 1362 1Y 40 1422 4W X323 1306 •3Y 30 1363 1Y 40 1423 4W X423 1307 3YE(3) 33 1364 1Y 40 1426 4W (1) 1307 3Y 30 1365 1Y 40 1427 4W (1) 1308 3YE(3) 33 1369 1Y 40 1428 4W X423 1308 3Y 30 1372 1Y (1) 1431 1W 48 1309 4Y 40 1373 1Y 40 1432 4WE (1) 1310 1W (1) 1374 1Y 40 1433 4WE (1) 1312 1Z 40 1376 1Y 40 1435 4Y 423 1313 1Z 40 1378 1Y 40 1436 4W 423 1314 1Z 40 1379 1Y 40 1437 4Y 40 1318 1Z 40 1380 4W 333 1438 1Z 50 1320 1W (1) 1381 1WE 46 1439 1Y 50 1321 1W (1) 1382 1W 40 1442 1Y 50 1322 1W (1) 1383 4Y 43 1444 1Z 50 1323 1Z 40 1384 1S 40 1445 1Y 56 1324 1Z (1) 1385 1W 40 1446 1Y 56 1325 1Z 40 1386 1Y 40 1447 1Y 56 1326 1Z 40 1387 1Y (1) 1448 1Y 56 1327 1Z (1) 1389 4W X323 1449 1Y 56 1328 1Z 40 1390 4W 423 1450 1Y 50 1330 1Z 40 1391 4W X323 1451 1Z 50 1331 1Z (1) 1392 4W X323 1452 1Y 50 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1453 1Y 50 1509 1Y 50 1587 2X 60 1454 1Z 50 1510 2W 665 1588 2X 66/60 1455 1Y 50 1511 1X 58 1589 2XE (1) 1456 1Y 50 1512 1Y 50 1590 2X 60 1457 1Y 50 1513 1Y 50 1591 2Z 60 1458 1Y 50 1514 1Y 50 1593 2Z 60 1459 1Y 50 1515 1Y 50 1594 2X 60 1461 1Y 50 1516 1Y 50 1595 •3XE 668 1462 1Y 50 1517 1W (1) 1596 2X 60 1463 1W 568 1541 •2X 669 1597 2X 60 1465 1Z 50 1544 2X 66/60 1598 2X 60 1466 1Z 50 1545 3WE 639 1599 2X 60 1467 1Z 50 1546 2Z 60 1600 2W 60 1469 1Y 56 1547 •3X 60 1601 2X 66/60 1470 1Y 56 1548 2X 60 1602 2X(4) 66 1471 1W 50 1549 2Z 60 1602 2X 60 1472 1Y 50 1550 2Z 60 1603 2W 63 1473 1Y 50 1551 2Z 60 1604 •2W 83 1474 1Z 50 1553 2X 66 1605 2X 66 1475 1Y 50 1554 2Z 60 1606 2X 60 1476 1Y 50 1555 2Z 60 1607 2X 60 1477 1Y 50 1556 2X 66/60 1608 2X 60 1479 1Y 50 1557 2X 66/60 1611 2X 60 1481 1Y 50 1558 2Z 60 1612 2RE 26 1482 1Y 50 1559 2Z 60 1613 •2WE 663 1483 1Y 50 1560 2X 66 1614 2WE (1) 1484 1Y 50 1561 2X 60 1616 2Z 60 1485 1Y 50 1562 2Z 60 1617 2Z 60 1486 1Z 50 1564 2Z 60 1618 2Z 60 1487 1Y 50 1565 2X 66 1620 2Z 60 1488 1Y 50 1566 2Z 60 1621 2X 60 1489 1Y 50 1567 2Z 64 1622 2Z 60 1490 1Y 50 1569 2W 63 1623 2X 60 1491 1W (1) 1570 2X 66 1624 2X 60 1492 1Z 50 1571 1W (1) 1625 2X 60 1493 1Y 50 1572 2Z 60 1626 2X 66 1494 1Y 50 1573 2Z 60 1627 2X 60 1495 1Y 50 1574 2Z 60 1629 2X 60 1496 1Y 50 1575 2X 66 1630 2X 60 1498 1Z 50 1577 2X 60 1631 2X 60 1499 1Z 50 1578 2X 60 1634 2X 60 1500 1Z 56 1579 2X 60 1636 2X 60 1502 1Y 50 1580 2XE 66 1637 2X 60 1503 1Y 50 1581 2XE 26 1638 2X 60 1504 1W (1) 1582 2XE 26 1639 2X 60 1505 1Z 50 1583 2XE(3) 66 1640 2X 60 1506 1Y 50 1583 2X 60 1641 2X 60 1507 1Z 50 1585 2Z 60 1642 2X 60 1508 1Y 50 1586 2Z 60 1643 2X 60 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1644 2X 60 1701 2XE 60 1757 2X 80 1645 2X 60 1702 2X 60 1758 4WE X88 1646 2X 60 1704 2X 60 1759 2X 88/80 1647 2X 66 1707 2Z 60 1760 2X 88/80 1648 •2YE 33 1708 •3X(5) 60 1761 2X 86 1649 2WE 66 1709 2X 60 1762 4W X80 1650 2Z 60 1763 4W X80 1710 2Z 60 1651 2Z 60 1764 2X 80 1711 2X 60 1652 2X 60 1765 4W X80 1712 2Z 60 1653 2X 60 1766 4W X80 1713 2X 66 1654 2X 60 1767 4W X83 1714 4WE (1) 1655 2X 66/60 1768 2X 80 1715 •3W 83 1656 2X 60 1769 4W X80 1716 4W 80 1657 2X 60 1770 2X 80 1717 4WE X338 1658 2X 60 1771 4W X80 1718 2X 80 1659 2X 60 1773 2X 80 1719 2R 80 1660 2PE (1) 1774 (1) 1722 •3WE 668 1661 2X 60 1775 2X 80 1723 2WE 338 1662 2X 60 1776 2X 80 1724 4W X839 1663 2X 60 1777 4WE 88 1725 4W 80 1664 2X 60 1778 2X 80 1726 4W 80 1665 2X 60 1779 •2W 83 1727 2X 80 1669 2Z 60 1780 4W 80 1728 4W X80 1670 2XE 66 1781 4W X80 1729 4W 80 1671 2X 60 1782 2X 80 1730 4WE X80 1672 2XE 66 1783 2X 80 1731 4WE 80 1673 2X 60 1784 4W X80 1732 4W 86 1674 2X 60 1786 2W 886 1733 4W 80 1677 2X 60 1787 2R 80 1736 4W 80 1678 2X 60 1788 2R 80 1737 2X 68 1679 2X 60 1789 2R 80 1738 2X 68 1680 2X 66 1790 2W(4) 886 1739 2X 88 1683 2Z 60 1790 2X 86 1740 2X 80 1684 2X 60 1791 2X 80 1741 2WE 268 1685 2X 60 1792 4WE 80 1742 2X 80 1686 2X 60 1793 2X 80 1743 2X 80 1687 2XE (1) 1794 2X 80 1744 2XE 886 1688 2X 60 1796 2P(4) 885 1745 4WE 568 1689 2X 66 1796 2R 80 1746 4WE 568 1690 2Z 60 1798 2P (1) 1747 4W X83 1691 2Z 60 1799 4W X80 1748 1W 50 1692 2X 66 1800 4W X80 1749 2WE 265 1693 2XE 66/60 1801 4W X80 1750 2X 68 1694 2XE 66 1802 2P 85 1751 2X 68 1803 2X 80 1695 •2WE 663 1752 2XE 668 1804 4W X80 1697 2Z 60 1753 4W X80 1805 2R 80 1698 2XE 66 1754 4WE X88 1806 4W 80 1699 2XE 66 1755 2X 80 1807 2X 80 1700 2X (1) 1756 2X 80 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1808 4WE X80 1865 3YE (1) 1941 2Z 90 1809 4WE 668 1866 •3YE(3) 33 1942 1Y 50 1810 4WE X668 1866 •3Y 30 1944 1Z (1) 1811 2X 86 1868 1X 46 1945 1Z (1) 1812 2X 60 1869 1Z 40 1950 (2) (1) 1813 2W 80 1870 4W (1) 1951 2T 22 1814 2R 80 1871 1Y 40 1952 2T 20 1815 •3WE 338 1872 1X 56 1953 2PE 263 1816 4W X83 1873 2P 558 1954 2SE 23 1817 4WE X80 1884 2Z 60 1955 2RE 26 1818 4WE X80 1885 2Z 60 1956 2TE 20 1819 2R 80 1886 2Z 60 1957 2SE 23 1823 2W 80 1887 2X 60 1958 2TE 20 1824 2R 80 1888 2Z 60 1959 2YE 239 1825 2W 80 1889 2XE 668 1961 2YE 223 1826 2W(4) 885 1891 2W 60 1962 2SE 23 1826 2X 80 1892 2XE 66 1963 2T 22 1827 4WE X80 1894 2X 60 1964 2SE 23 1828 4WE X88 1895 2X 60 1965 2YE 23 1829 4WE X88 1897 2Z 60 1966 2YE 223 1830 2P 80 1898 4W 80 1967 2XE 26 1831 4WE X886 1902 2X 80 1968 2TE 20 1832 2W 80 1903 2X(4) 88/80 1969 2YE 23 1833 2R 80 1905 2X 88 1970 2TE 22 1834 4WE X668 1906 2W 80 1971 2SE 23 1835 2X 80 1907 2X 80 1972 2YE 223 1836 4WE X88 1908 2X 80 1973 2TE 20 1837 4WE X80 1910 2X (1) 1974 2TE 20 1838 4WE X668 1911 2PE (1) 1975 2PE (1) 1839 2X 80 1912 2YE 23 1976 2TE 20 1840 2X 80 1913 2T 22 1977 2T 22 1841 2Z 90 1914 3Y 30 1978 2YE 23 1843 2X 60 1982 2TE 20 1915 •3Y 30 1845 2T (1) 1983 2TE 20 1916 •3W 63 1846 2Z 60 1984 2T 20 1917 •3WE 339 1847 2X 80 1986 •3WE(3) 336 1918 3Y 30 1848 •2W 80 1986 •3W 36 1919 3WE 339 1849 2X 80 1987 33 1920 3Y 30 •3YE(3) 1851 2X 60 1987 30 1921 •2WE 336 •3Y 1854 4Y 43 1922 •2WE 338 1988 •3WE(3) 336 1855 4W (1) 1923 1S 40 1988 •3W 36 1856 1Y (1) 1928 4WE X323 1989 •3YE(3) 33 1857 1Y (1) 1929 1S 40 1989 •3Y 30 1858 2TE 20 1931 2Z 90 1990 3Z 90 1859 2PE 268 1932 1Y 40 1991 •3YE 336 1860 2YE 239 1935 2X(4) 66/60 1992 •3WE(3) 336 1862 3YE 33 1938 2X 80 1992 •3W 36 1863 3YE(3) 33 1939 4W 80 1993 •3YE(3) 33 1863 3Y 30 1940 2X 80 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 1993 •3Y 30 2051 •2W 83 2216 1Z (1) 1994 2WE 663 2052 3Y 30 2217 1Y 40 1999 2WE(3) 33 2053 •3Y 30 2218 •2W 839 1999 2W 30 2054 •2W 883 2219 •2Y 30 2000 1Z (1) 2055 3Y 39 2222 3Y 30 2001 1Z 40 2056 •2YE 33 2224 3Z 60 2002 1Y (1) 2057 3YE(3) 33 2225 2X 80 2004 1Y 40 2057 3Y 30 2226 2X 80 2006 1Y (1) 2058 3YE 33 2227 3W 39 2008 4Y 43/40 2059 •2YE(3) 33 2232 •2XE 66 2009 1Y 40 2059 •2Y 30 2233 2X 60 2010 4WE (1) 2067 1Y 50 2234 2Y 30 2011 4WE (1) 2071 1YZ (1) 2235 2Z 60 2012 4WE (1) 2073 2XRE 20 2236 2X 60 2013 4WE (1) 2074 2X 60 2237 2X 60 2014 2P 58 2075 2X 69 2238 3Y 30 2015 2P 559 2076 •2X(5) 68 2239 2X 60 2016 2X (1) 2077 2Z 60 2240 2W 88 2017 2XE (1) 2078 2Z 60 2241 3YE 33 2018 2X 60 2079 2X 80 2242 3YE 33 2019 2X 60 2186 2RE (1) 2243 3Y 30 2020 2X 60 2187 2T 22 2244 3Y 30 2021 2X 60 2188 2PE (1) 2245 •3Y 30 2022 3X 68 2189 2WE 263 2246 3YE 33 2023 63 •3W 2190 2PE (1) 2247 3Y 30 2024 2X 66/60 2191 2XE 26 2248 •3W 83 2025 2X 66/60 2192 2PE 263 2249 •3WE (1) 2026 2X 66/60 2193 2TE 20 2250 2X 60 2027 2Z 60 2194 2RE (1) 2251 3YE 339 2028 2X (1) 2195 2RE (1) 2252 •2YE 33 2029 •2WE (1) 2196 2WE (1) 2253 3Z 60 2030 •2X 886/86 2197 2RE 268 2254 1Z (1) 2031 2P(4) 885 2198 2RE (1) 2256 3YE 33 2031 2R 850 2199 2PE (1) 2257 4W X423 2032 2PE 856 2200 2YE 239 2258 •2W 83 2033 2W 80 2201 2P 225 2259 2X 80 2034 2SE 23 2202 2WE (1) 2260 3W 38 2035 2YE 23 2203 2SE 23 2261 2X 60 2036 2TE 20 2204 2PE 263 2262 4W 80 2037 (2) (1) 2205 •3X 60 2263 3YE 33 2038 2X 60 2206 2X 60 2264 •3W 83 2044 2YE 23 2208 1X 50 2265 •2Y 30 2045 •2YE 33 2209 •2X 80 2266 •2WE 338 2046 3Y 30 2210 1Y 40 2267 2X 68 2047 2YE(3) 33 2211 2Y 90 2269 •2X 80 2047 2Y 30 2212 2X 90 2270 •2PE 338 2048 3Y 30 2213 1Z 40 2271 3Y 30 2049 3Y 30 2214 2X 80 2272 3Z 60 2050 3YE 33 2215 2X 80 2273 3X 60 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 2274 2X 60 2325 3Y 30 2375 3WE 33 2275 3Y 30 2326 2X 80 2376 •2YE 33 2276 •2W 38 2327 2X 80 2377 •2YE 33 2277 3WE 339 2328 2Z 60 2378 3WE 336 2278 3YE 33 2329 3Y 30 2379 3WE 338 2279 2X 60 2330 3Y 30 2380 •2YE 33 2280 2X 80 2331 2X 80 2381 3WE 336 2281 2Z 60 2332 •2Y 30 2382 •2WE 663 2282 3Y 30 2333 •3YE 336 2383 •2WE 338 2283 3W 39 2334 •2WE 663 2384 3YE 33 2284 •3WE 336 2335 3WE 336 2385 •3YE 33 2285 •3W 63 2336 3WE 336 2386 3WE 338 2286 3Y 30 2337 3WE 663 2387 3YE 33 2287 3YE 33 2338 2YE 33 2388 3YE 33 2288 3YE 33 2339 2YE 33 2389 3YE 33 2289 2X 80 2340 •2YE 33 2390 2YE 33 2290 2Z 60 2341 2Y 30 2391 2YE 33 2291 2Z 60 2342 2YE 33 2392 2Y 30 2293 3Y 30 2343 2YE 33 2393 •3YE 33 2294 3X 60 2344 2YE(3) 33 2394 3Y 30 2295 2W 663 2344 2Y 30 2395 •3WE 338 2296 3YE 33 2345 2YE 33 2396 •2WE 336 2297 30 •3Y 2346 •2YE 33 2397 •3YE 33 2298 3YE 33 2347 •3WE 33 2398 •3YE 33 2299 2X 60 2348 3W 39 2399 •2WE 338 2300 3Z 60 2350 3YE 33 2400 •3YE 33 2301 3YE 33 2351 33 •3YE(3) 2401 •2WE 883 2302 •3Y 30 2351 30 •3Y 2402 •3WE 33 2303 3Y 30 2352 339 •3YE 2403 •3YE 33 2304 1Y 44 2353 •3WE 338 2404 336 2305 2X 80 •2WE 2354 •3WE 336 2306 2X 60 2405 3Y 30 2356 3YE 33 2307 2X 60 2406 3YE 33 2357 •2W 83 2308 2X X80 2407 •3WE (1) 2358 3YE 33 2309 3YE 33 2409 3YE 33 2359 •2WE 338 2310 •2Y 36 2410 •2WE 33 2360 •3WE 336 2311 2X 60 2411 •3WE 336 2361 3WE 38 2312 •3X 60 2412 3WE 33 2362 2YE 33 2313 30 2413 •2Y 30 •2W 2363 3WE 33 2315 2X 90 2414 3WE 33 2364 3Y 30 2316 2X 66 2416 •3YE 33 2366 3Y 30 2317 2X 66 2417 2PE 268 2367 3YE 33 2318 1Y 40 2418 2PE (1) 2368 3Y 30 2419 2YE 23 2319 3Y 30 2370 3YE 33 2320 2X 80 2420 2WE 268 2371 3YE 33 2321 2X 60 2421 2PE (1) 2372 •2YE 33 2322 2Z 60 2422 2TE 20 2373 •2YE 33 2323 3Y 30 2424 2TE 20 2374 •3YE 33 2324 3Y 30 2426 1Y 59 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 2427 2Y 50 2483 •3WE 663 2547 1W (1) 2428 2Y 50 2484 •3WE 663 2548 2WE (1) 2429 2Y 50 2485 •3W 663 2552 2X 60 2430 2X 88/80 2486 •3WE 663 2554 3WE 33 2431 2Z 60 2487 •3W 663 2555 1Z (1) 2432 •3X 60 2488 •3W 663 2556 1Y (1) 2433 2X 60 2490 2Z 60 2557 1Z (1) 2434 4W X80 2491 2X 80 2558 •2W 663 2435 4W X80 2493 •2WE 338 2560 •3Y 30 2436 •2WE 33 2495 4WE 568 2561 3YE 33 2437 4W X80 2496 •3X 80 2564 2X 80 2438 663 2565 2X 80 •3WE 2498 •3Y 30 2567 2X 60 2439 2X 80 2501 2X 60 2570 2X 66/60 2440 2X 80 2502 4W 83 2571 2X 80 2441 4WE (1) 2503 2X 80 2572 60 2442 4W X80 2504 2Z 60 •3X 2443 4WE 80 2505 2X 60 2573 1Y 56 2444 4WE X88 2506 2X 80 2574 2X 60 2446 2X 60 2507 2X 80 2576 1X 80 2447 1WE 446 2508 2X 80 2577 4W 80 2448 1Y 44 2509 2X 80 2578 2X 80 2451 2S 25 2511 2X 80 2579 2X 80 2452 2YE 239 2512 2X 60 2580 2X 80 2453 2YE 23 2513 4W X80 2581 2X 80 2454 2YE 23 2514 2Y 30 2582 2X 80 2455 2PE (1) 2515 2X 60 2583 2X 80 2456 3YE 33 2516 2Z 60 2584 2X 80 2457 3YE 33 2517 2YE 23 2585 2X 80 2458 3YE 33 2518 3Z 60 2586 2X 80 2459 3YE 33 2520 3Y 30 2587 2Z 60 2460 3YE 33 2588 2X 66/60 2521 •3W 663 2461 3YE 33 2589 3W 63 2522 •2W 69 2463 4WE (1) 2590 2X 90 2524 •3Y 30 2464 1Y 56 2591 2TE 22 2525 •3Z 60 2465 1W 50 2599 2TE 20 2526 •2W 38 2466 1W (1) 2601 2YE 23 2527 3W 39 2468 1W 50 2602 2TE 20 2528 3Y 30 2469 1Z 50 2603 3WE 336 2529 38 2470 2X 60 •2W 2604 4WE 883 2471 2X 66 2531 3W 89 2605 3WE 663 2473 2Z 60 2533 2Z 60 2606 3WE 663 2534 2WE 263 2474 2X 66 2607 •2Y 39 2535 •2WE 338 2475 2X 80 2608 •3Y 30 2536 33 2477 •3WE 663 •2YE 2609 2X 60 2538 1Z 40 2478 •3WE(3) 336 2610 3W 38 2541 3Y 30 2478 •3W 36 2611 •2W 63 2542 3X 60 2480 •3WE 663 2612 •3YE 33 2545 1Y 40 2481 •3WE 663 2614 •2Y 30 2546 1Y 40 2482 •3WE 663 2615 •3YE 33 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 2616 •3YE(3) 33 2684 •2W 38 2747 2X 60 2616 •3Y 30 2685 •2W 83 2748 2X 68 2617 •3Y 30 2686 •2W 83 2749 3YE 33 2618 3Y 39 2687 1Z 40 2750 2X 60 2619 3W 83 2688 2X 60 2751 4W 80 2752 3Y 30 2620 •3Y 30 2689 2X 60 2753 2X 60 2621 •2Y 30 2690 2X 60 2754 3X 60 2622 •2WE 336 2691 4W 80 2757 2X 66/60 2623 1Z (1) 2692 4WE X88 2758 •3WE 336 2624 4W 423 2693 2X 80 2759 2X 66/60 2626 2P 50 2698 2X 80 2760 •3WE 336 2627 1Y 50 2699 2X 88 2761 2X 66/60 2628 2X 66 2705 2X 80 2762 336 2629 2X 66 2707 •3YE(3) 33 •3WE 2630 2X 66 2707 •3Y 30 2763 2X 66/60 2709 2642 2X 66 3Y 30 2764 •3WE 336 2643 2X 60 2710 3Y 30 2771 2X 66/60 2644 2X 66 2713 2X 60 2772 •3WE 336 2645 2X 60 2714 1Z 40 2775 2X 66/60 2646 2X 66 2715 1Z 40 2776 •3WE 336 2647 2X 60 2716 2X 60 2777 2X 66/60 2648 2X 60 2717 1Z 40 2778 •3WE 336 2649 2X 60 2719 1W 56 2779 2X 66/60 2650 2X 60 2720 1Z 50 2780 •3WE 336 2651 2Z 60 2721 1Y 50 2781 2X 66/60 2653 2X 60 2722 1Z 50 2782 •3WE 336 2655 2X 60 2723 1Y 50 2783 2X 66/60 2656 2X 60 2724 1Z 50 2784 •3WE 336 2657 2Z 60 2725 1Z 50 2785 2X 60 2659 2Z 60 2726 1Z 50 2786 2X 66/60 2660 2X 60 2727 1Y 65 2787 •3WE 336 2661 2Z 60 2728 1Z 50 2788 2X 66/60 2729 2Z 60 2664 2Z 60 2789 •2P 83 2730 2Z 60 2667 3X 60 2790 2R 80 2732 2X 60 2668 2W 663 2793 1Y 40 2733 338 2669 2Z 60 •2WE(3) 2794 2R 80 2670 2X 80 2733 •2W 38 2795 2R 80 2671 2X 60 2734 •2W 883/83 2796 2R 80 2672 2XR 80 2735 2X 88/80 2797 2R 80 2673 2X 60 2738 2Z 60 2798 2X 80 2674 2X 60 2739 •3X 80 2799 2W 80 2676 2PE (1) 2740 •3WE 668 2800 2R 80 2677 2R 80 2741 1Y 56 2801 2X 88/80 2678 2W 80 2742 •3W 638 2802 2X 80 2679 2R 80 2743 •3W 638 2803 2Z 80 2680 2X 80 2744 •3W 638 2805 4W 423 2681 2R 80 2745 2X 68 2806 4W (1) 2682 2W 80 2746 2X 68 2807 2Z (1) 2683 •2W 86 2809 2X 86 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 2810 2X 66/60 2872 2X 60 2966 2X 60 2811 2X 66/60 2873 2Z 60 2967 2X 80 2812 2X (1) 2874 •2X 60 2968 4Y 423 2813 4W X423/ 2875 2X 60 2969 2Z 90 423 2876 2Z 60 2983 •2WE 336 2814 2XE 606 2878 4Y 40 2984 2R 50 2815 •2X 860 2879 4WE X886 2985 4WE X338 2817 2X 86 2880 1W 50 2986 4W X83 2818 2X 86 2881 4Y 43/40 2987 4W X80 2819 2X 80 2900 2X 606 2988 4WE X338 2820 •2X 80 2901 2WE 265 2989 1Z 40 2821 2X 60 2902 2X(4) 66 2990 2Z (1) 2822 2X 60 2902 2X 60 2991 •3W 663/63 2823 2X 80 2903 •3W 663/63 2992 2X 66/60 2826 2W 83 2904 2X 80 2993 •3W 663/63 2829 2X 80 2905 2X 80 2994 2X 66/60 2830 4W 423 2907 1Z (1) 2995 •3W 663/63 2831 2Z 60 2920 •3W 883/83 2996 2X 66/60 2834 2X 80 2921 2X 884/84 2997 •3W 663/663 2835 4W 423 2922 2X(4) 886 2998 2X 66/60 2837 2R 80 2922 2X 86 3005 •3W 663/63 2838 3YE 339 2923 2X 886/86 3006 2X 66/60 2839 •2X 60 2924 •3WE(3) 338 3009 •3W 663/63 2840 30 •3W 2924 •3W 38 3010 2X 66/60 2841 36 •3W 2925 1W 48 3011 •3W 663/63 2842 •3Y 30 2926 1X 46 3012 2X 66/60 2844 4Y 423 2927 2XE(3) 668 3013 •3W 663/63 2845 •3W 333 2927 2X 68 3014 2X 66/60 2846 4Y (1) 2928 2X 668/68 3015 •3W 663/63 2849 •2X 60 2929 •3W 663/63 3016 2X 66/60 2850 3Y 30 2930 2X 664/64 3017 •3W 663/63 2851 4W 80 2931 2Z 60 3018 2X 66/60 2852 1W (1) 2933 •3Y 30 3019 •3W 663/63 2853 2Z 60 2934 3Y 30 3020 2X 66/60 2854 2Z 60 2935 3Y 30 3021 •3WE 336 2855 2Z 60 2936 •2X 60 3022 •2YE 339 2856 2Z 60 2937 2Z 60 3023 3WE 663 2857 2Z (1) 2940 1Y 40 3024 •3WE 336 2858 1Z 40 2941 2X 60 3025 •3W 663/63 2859 2Z 60 2942 2X 60 3026 2X 66/60 2861 2X 60 2943 •2Y 30 3027 2X 66/60 2862 2X 60 2945 •2WE 338 3028 2X 80 2863 2X 60 2946 2X 60 3048 4W 642 2864 2X 60 2947 3Y 30 3054 3WE 30 2865 2X 80 2948 2X 60 3055 2X 80 2869 4W 80 2949 2X 80 3056 3Y 30 2870 4W X333 2950 4Y 423 3057 2XE 268 2870 4W (1) 2956 1Y (1) 3064 (1) 2871 2X 60 •2YE 2965 4WE 382 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 3065 •2YE(3) 33 3120 1W 539 3166 2YE (1) 3065 •2Y 30 3121 4W (1) 3167 2YE (1) 3066 2X 80 3122 2WE 665/65 3168 2WE (1) 3070 2TE 20 3123 4W 623 3169 2XE (1) 3071 •3WE 63 3124 2W 664/64 3170 4W 423 3072 2Z (1) 3125 4W 642 3171 4W (1) 3073 •3W 638 3126 1W 48 3172 2X 66/60 3077 2Z 90 3127 1W (1) 3174 1Y 40 3078 4W 423 3128 1W 46 3175 1Z 40 3079 •3WE 663 3129 4W X382/3 3176 1Y 44 82 3080 •3W 63 3178 1Z 40 3130 4W X362/3 3179 1X 46 3082 •3Z 90 62 3180 1X 48 3083 2WE 265 3131 4W X482/ 3181 1Z 40 3084 2W 885/85 482 3182 1Z 40 3085 1W 58 3132 4W (1)423 3183 •3W 30 3086 2W 665/65 3133 4W (1) 3184 •3W 36 3087 1W 56 3134 4W 462 3185 38 3088 1Y 40 3135 4W (1)423 •3W 3089 4Y 40 3136 2T 22 3186 •3W 30 3090 4YW (1) 3137 1W (1) 3187 •3W 36 3091 4YW (1) 3138 2YE 223 3188 •3W 38 3092 •2Y 30 3139 2Y (1) 3189 1Y 40 3093 2W 885/85 3140 2X 66/60 3190 1Y 40 3094 4W 823 3141 2Z 60 3191 1W 46 3095 2W 884/84 3142 2X 66/60 3192 1W 48 3096 4W 842 3143 2X 66/60 3194 2W 333 3097 1Y (1) 3144 2X 66/60 3200 4W 43 3098 2W (1) 3145 2X 88/80 3205 1Y 40 3099 2W (1) 3146 2X 66/60 3206 1W 48 3100 1W (1) 3147 2X 88/80 3208 4W 423 3101 2WE (1) 3148 4W X323/3 3209 4W 423 3102 1WE (1) 23 3210 2Y 50 3103 2WE (1) 3149 2P 58 3211 2Y 50 3104 1WE (1) 3150 2YE (1) 3212 1W 50 3105 2WE (1) 3151 2X 90 3213 2Y 50 3106 1WE (1) 3152 2X 90 3214 2Y 50 3107 2W (1) 3153 2YE 23 3215 1Z 50 3108 1W (1) 3154 2YE 23 3216 2Z 50 3109 2W 539 3155 2X 60 3218 2Y 50 3110 1W 539 3156 2S 25 3219 2Y 50 3111 2WE (1) 3157 2PE 25 3220 2TE 20 3112 1WE (1) 3158 2TE 22 3221 2WE (1) 3113 2WE (1) 3159 2TE 20 3222 1WE (1) 3114 1WE (1) 3160 2WE 263 3223 2WE (1) 3115 2WE (1) 3161 2YE 23 3224 1WE (1) 3116 1WE (1) 3162 2XE 26 3225 2WE (1) 3117 2W (1) 3163 2TE 20 3226 1WE (1) 3118 1W (1) 3164 2T (1) 3227 2W (1) 3119 2W 539 3165 •2WE (1) 3228 1W (1) APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 3229 2W (1)40 3275 3W 663/63 3336 3WE 33/30 3230 1W (1)40 3276 2X 66/60 3337 2TE 20 3231 2WE (1) 3277 2X 68 3338 2TE 20 3232 1WE (1) 3278 2X 66/60 3339 2TE 20 3233 2WE (1) 3279 •3W 663/63 3340 2TE 20 3234 1WE (1) 3280 2X 66/60 3341 1Y 40 3235 2WE (1) 3281 2X 66/60 3342 1Y 40 3236 1WE (1) 3282 2X 66/60 3343 •2Y (1) 3237 2W (1) 3283 2X 66/60 3344 1Y (1) 3238 1W (1) 3284 2X 66/60 3345 2X 66/60 3239 2W 40 3285 2X 66/60 3346 •3WE 336 3240 1W 40 3286 •3WE 368 3347 •3W 663/63 3241 1Y (1) 3287 2X 66/60 3348 2X 66/60 3242 1Y 40 3288 2X 66/60 3349 2X 66/60 3243 2X 60 3289 2X 668/68 3350 •3WE 336 3244 2X 80 3290 2X 668/68 3351 •3W 663/63 3245 2Z (1) 3291 2X 606 3352 2X 66/60 3246 2XE 668 3292 4W (1) 3354 2YE 23 3247 1Y 50 3293 •2X 60 3355 2WE 263 3248 •3WE(3) 336 3294 •2WE 663 3356 1Y (1) 3248 •3W 36 3295 3YE(3) 33 3357 •2Y (1) 3249 2X 60 3295 3Y 30 3358 2YE (1) 3250 2W 68 3296 2T 20 3359 2Z (1) 3251 1Y (1) 3297 2TE 20 3360 1Z (1) 3252 2YE 23 3298 2TE 20 3361 4W 68 3253 2X 80 3299 2TE 20 3362 4WE 638 3254 3W 333 3300 2PE 263 3363 1Z (1) 3255 2WE (1) 3301 2W 884/84 3364 1W (1) 3256 2Y 30 3302 2X 60 3365 1W (1) 3257 2Y 99 3303 2PE 265 3366 1W (1) 3258 1Y 99 3304 2RE 268 3367 1W (1) 3259 2X 88/80 3305 2PE 263 3368 1W (1) 3260 2X 88/80 3306 2PE 265 3369 1W (1) 3261 2X 88/80 3307 2WE 265 3370 1W (1) 3262 2X 88/80 3308 2XE 268 3371 3YE 33 3263 2X 88/80 3309 2WE 263 3373 2X 606 3264 2X 88/80 3310 2WE 265 3374 2SE (1) 3265 2X 88/80 3311 2PE 225 3375 1Y 50 3266 2X 88/80 3312 2YE 223 3376 1W (1) 3267 2X 88/80 3313 1Y 40 3377 1Z 50 3268 2Z (1) 3314 2Y 90 3378 1Y 50 3269 •2YE (1) 3315 2X (1) 3379 •3YE (1) 3270 1Z (1) 3316 2Z (1) 3380 1W (1) 3271 3YE(3) 33 3317 1W (1) 3381 2XE 66 3271 3Y 30 3318 2XRE 268 3382 2XE 66 3272 •3YE(3) 33 3319 1Y (1) 3383 •3WE 663 3272 •3Y 30 3320 2X 80 3384 •3WE 663 3273 3WE 336 3334 2Z (1) 3385 4WE 623 3274 •3WE 338 3335 2Z (1) 3386 4WE 623 APPENDICES

UN HAZCHEM HIN UN HAZCHEM HIN UN HAZCHEM HIN 3387 2WE 665 3432 2X 90 3483 •3WE 663 3388 2WE 665 3434 2X 60 3484 •2X 886 3389 2XE 668 3436 2X 60 3485 1W 58 3390 2XE 668 3437 2Z 60 3486 1W 58 3391 4Y 43 3438 2Z 60 3487 1W 58 3392 4Y 333 3439 2X 66/60 3488 2WE 663 3393 4W X432 3440 2X 66/60 3489 2WE 663 3394 4W X333 3441 2X 60 3490 4WE 623 3395 4W X423/4 3442 2X 60 3491 4WE 623 23 3443 2X 60 3492 2WE 668 3396 4W X423/4 3444 2X 60 3493 2WE 668 23 3445 2X 60 3494 •3WE(3) 336 3397 4W X423/4 3446 2X 60 23 3494 •3W 36 3447 2X 60 3398 4W X323/3 3495 2WE 86 23 3448 2X 66/60 3496 2Y (1) 3399 4W X323/3 3449 2X 66 3497 1Y 40 23 3450 2X 66 3498 2X 80 3400 2Y 40 3451 2X 60 3499 1Z (1) 3401 4W X423 3452 2X 60 3500 2ZE 20 3402 4W X423 3453 2X 80 3501 2YE 23 3403 4W X423 3454 2X 60 3502 2XE 26 3404 4W X423 3455 2X 68 3503 2XE 28 3405 2Y 56 3456 2X X80 3504 2WE 263 3406 2Y 56 3457 2X 60 3505 2WE 238 3407 2Y 50 3458 2Z 60 3506 2X (1) 3408 2Y 56 3459 2X 60 3507 (2) (1) 3409 2X 60 3460 2X 60 3508 1Z (1) 3410 2X 60 3462 2X 66/60X 3509 2Z 90 3411 2Z 60 3463 •2W 66/6083 3510 2SE (1) 3412 •2X 80 3464 2X 66/60 3511 2TE (1) 3413 2X 66/60 3465 2X 66/60 3512 2RE (1) 3414 2X 66/66 3466 2X 66/60 3513 2S (1) 3415 2Z 60 3467 2X 66/60 3514 2PE (1) 3416 2Z 60 3468 2SE (1) 3515 2PE (1) 3417 2X 60 3469 •3WE(3) 338(1) 3516 2RE (1) 3418 2X 60 3469 •3W 38 3517 2PE (1) 3419 2X 80 3470 •3W 83 3518 2PE (1) 3420 2X 80 3471 2X 86 3519 2RE (1) 3421 2X 86 3472 •2X 80 3520 2XE (1) 3422 2X 60 3473 •2WE (1) 3521 2PE (1) 3423 2X 80 3474 1W (1) 3522 2PE (1) 3424 2X 60 3475 •3YE 33 3523 2PE (1) 3425 2X 80 3476 4W (1) 3524 2RE (1) 3426 2X 60 3477 2X (1) 3525 2PE (1) 3427 2X 60 3478 2Y (1) 3526 2WE (1) 3428 2X 60 3527 not 3479 2W 23(1) (1) listed1W 3429 2X 60 3480 4W2Y (1) 3528 not 3430 2X 60 3481 4W2Y (1) (1) listed2YE 3431 2X 60 3482 4WE X323 APPENDICES

UN HAZCHEM HIN 3529 2YEnot (1) listed 3530 2Ynot listed (1) 3531 1Wnot 40 listed 3532 2Wnot 40 listed 3533 1Wnot 40 listed 3534 2Wnot 40 listed 3535 2X(4)not 664 listed 3535 2Xnot listed 64 3536 4Y (1) 3537 2SE (1) 3538 2T (1) 3539 2RE (1) 3540 3YE (1) 3541 1Z (1) 3542 1W (1) 3543 4W (1) 3544 2Y (1) 3545 2WE (1) 3546 2X (1) 3547 2X (1) 3548 1Z (1)[DK9]

APPENDICES

C4 Hazard Identification Number (HIN)

NOTE: This Section C4 and the HIN listing in C3 are provided for information purposes only. There is no requirement of this Code to apply a Hazard Identification Number (HIN) to any load of dangerous goods being transported in Australia.

The HIN is usually displayed on portable tanks, bulk containers and some freight containers loaded with dangerous goods sourced from Europe and some other countries. It is displayed in the upper half of the RID/ADR Plate that is placarded on the cargo transport unit, together with the Sample RID/ADR Plate Class label. The UN Number is for UN 1088 Acetal displayed in the lower half.

The HIN is not strictly an emergency action code. Rather it is a numerical system of identifying the hazard of the dangerous goods in more detail than is provided by the dangerous goods classification alone.

C4.1 The HIN consists of two or three figures. In general, the figures indicate the following hazards:

2 Emissions of gas due to pressure or to chemical reaction

3 Flammability of liquids (vapours) and gases or self- heating liquids

4 Flammability of solids or self-heating solids

5 Oxidising (fire-intensifying) effect

6 Toxicity (or risk of infection)

7 Radioactivity

8 Corrosivity

9 Risk of spontaneous, violent reaction

NOTE 1: The hazards assigned above to numbers ‘4’ to ‘8’ inclusive are similar to the hazards indicated by the same numbers in the United Nations dangerous goods classification system used in this Code

NOTE 2: Spontaneous violent reaction within the meaning of hazard ‘9’ above includes the possibility of the risk of explosion, disintegration and polymerisation reaction with the release of considerable heat or flammable and/or toxic gases.

C4.2 Doubling of a figure indicates an intensification of that particular hazard. APPENDICES

C4.3 Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by zero.

C4.4 The following combinations of figures have a special meaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539, 606, 623, 642, 823, 842 and 90, (see C4.6).

C4.5 If the letter ‘X’ prefixes a hazard identification number, this indicates that the substance will react dangerously with water. For these substances, water may only be used with the approval of experts.

C4.6 The hazard identification numbers have the following meanings: 20 Asphyxiant gas or gas with no subsidiary hazard 22 Refrigerated liquefied gas, Asphyxiant 223 Refrigerated liquefied gas, flammable 225 Refrigerated liquefied gas, oxidising (fire intensifying) 23 Flammable gas 239 Flammable gas, which can spontaneously lead to violent reaction 25 Oxidising (fire-intensifying) gas 26 Toxic gas 263 Toxic gas, flammable 265 Toxic gas, oxidising (fire-intensifying) 268 Toxic gas, corrosive 30 Flammable liquid (flash-point between 23°C and 61°C inclusive) or flammable liquid or solid in the molten state with a flash point above 61°C, heated to a temperature equal to or above its flash point, or self-heating liquid 323 Flammable liquid which reacts with water, emitting flammable gases X323 Flammable liquid which reacts dangerously with water, emitting flammable gases* 33 Highly flammable liquid (flash-point below 23°C) 333 Pyrophoric liquid X333 Pyrophoric liquid, which reacts dangerously with water* 336 Highly flammable liquid, toxic 338 Highly flammable liquid, corrosive X338 Highly flammable liquid, corrosive, which reacts dangerously with water* 339 Highly flammable liquid which can spontaneously lead to violent reaction. 36 Flammable liquid (flash-point between 23°C and 61°C inclusive), slightly toxic or self-heating liquid toxic. 362 Flammable liquid, toxic, which reacts with water, emitting flammable gases X362 Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gases* 368 Flammable liquid, toxic, corrosive APPENDICES

38 Flammable liquid (flash-point between 23°C and 61°C inclusive), slightly corrosive or self-heating liquid, corrosive 382 Flammable liquid, corrosive, which reacts with water, emitting flammable gases X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gases* 39 Flammable liquid, which can spontaneously lead to violent reaction 40 Flammable solid, or self-reactive substance, or self heating substance 423 Solid which reacts with water, emitting flammable gases X423 Flammable solid which reacts dangerously with water, emitting flammable gases* 43 Spontaneously flammable (Pyrophoric) solid 44 Flammable solid, in the molten state at an elevated temperature 446 Flammable solid, toxic, in the molten state, at an elevated temperature 46 Flammable or self-heating solid, toxic 462 Toxic solid which reacts with water, emitting flammable gases* X462 Solid which reacts dangerously with water, emitting toxic gases 48 Flammable or self-heating solid, corrosive 482 Corrosive solid which reacts with water, emitting corrosive gases X482 Solid which reacts dangerously with water, emitting corrosive gases* 50 Oxidising (fire-intensifying) substance 539 Flammable organic peroxide 55 Strongly oxidising (fire-intensifying) substance 556 Strongly oxidising (fire-intensifying) substance, toxic 558 Strongly oxidising (fire-intensifying) substance, corrosive 559 Strongly oxidising (fire-intensifying) substance, which can spontaneously lead to violent reaction 56 Oxidising substance (fire-intensifying), toxic 568 Oxidising substance (fire-intensifying), toxic, corrosive 58 Oxidising substance (fire-intensifying), corrosive 59 Oxidising substance (fire-intensifying) which can spontaneously lead to violent reaction 60 Toxic or slightly toxic substance 606 Infectious substance 623 Toxic liquid, which reacts with water, emitting flammable gases 63 Toxic substance, flammable (flash-point between 23°C and 61°C inclusive) 638 Toxic substance, flammable (flash-point between 23°C and 61°C inclusive), corrosive 639 Toxic substance, flammable (flash-point not above 61°C inclusive), which can spontaneously lead to violent reaction 64 Toxic solid, flammable or self-heating APPENDICES

642 Toxic solid, which reacts with water, emitting flammable gases 65 Toxic substance, oxidising (fire-intensifying) 66 Highly toxic substance 663 Highly toxic substance, flammable (flash-point not above 61°C inclusive) 664 Highly Toxic substance, flammable or self-heating 665 Highly toxic substance, oxidising (fire-intensifying) 668 Highly toxic substance, corrosive 669 Highly toxic substance which can spontaneously lead to a violent reaction 68 Toxic substance, corrosive 69 Toxic or slightly toxic substance, which can spontaneously lead to violent reaction 70 Radioactive material 72 Radioactive gas 723 Radioactive gas, flammable 73 Radioactive liquid, flammable (flash-point not above 61°C inclusive) 74 Radioactive solid, flammable 75 Radioactive material oxidising (fire-intensifying) 76 Radioactive material, toxic 78 Radioactive material, corrosive 80 Corrosive or slightly corrosive substance X80 Corrosive or slightly corrosive substance, which reacts dangerously with water* 823 Corrosive liquid which reacts with water, emitting flammable gases 83 Corrosive or slightly corrosive substance, flammable (flash-point between 23°C and 61°C inclusive) X83 Corrosive or slightly corrosive substance, flammable (flash-point between 23°C and 61°C inclusive), which reacts dangerously with water* 839 Corrosive or slightly corrosive substance, flammable (flash-point between 23°C and 61°C inclusive), which can spontaneously lead to violent reaction X839 Corrosive or slightly corrosive substance, flammable (flash-point between 23°C and 61°C inclusive), which can spontaneously lead to violent reaction and which reacts dangerously with water* 84 Corrosive solid, flammable or self-heating 842 Corrosive solid which reacts with water, emitting flammable gases 85 Corrosive or slightly corrosive substance, oxidising (fire- intensifying) 856 Corrosive or slightly corrosive substance, oxidising (fire- intensifying) and toxic 86 Corrosive or slightly corrosive substance, toxic 88 Highly corrosive substance APPENDICES

X88 Highly corrosive substance, which reacts dangerously with water* 883 Highly corrosive substance, flammable (flash point between 23°C and 61°C inclusive) 884 Highly corrosive solid, flammable or self-heating 885 Highly corrosive substance, oxidising (fire-intensifying) 886 Highly corrosive substance, toxic X886 Highly corrosive substance, toxic which reacts dangerously with water* 89 Corrosive or slightly corrosive substance, which can spontaneously lead to violent reaction 90 Environmentally hazardous substance; miscellaneous dangerous substances 99 Miscellaneous dangerous substance carried at an elevated temperature *Water must not to be used except by approval of experts

APPENDICES

APPENDIX D: CODE OF PRACTICE FOR REPROCESSING STEEL DRUMS

NOTE 1: This Appendix has the full title ‘Code of Practice for the Reprocessing of Closed Head Steel Drums in the Nominal Capacity Range of 200-220 Litres’. Previous editions were published separately as Supplement 1 to earlier editions of this Code.

NOTE 2: Adherence to this Code of Practice is necessary in order to prevent those reprocessed drums which show unsatisfactory performance characteristics from being used in the transport of dangerous goods.

D1 SCOPE This mandatory Code of Practice has been prepared by the Advisory Committee on the Transport of Dangerous Goods. It is to be adhered to by those persons reprocessing non-removable head steel drums in the nominal capacity range of between 200 and 220 litres, for second and subsequent use of these drums in the transport of dangerous goods of packing groups II and III. It recognises the long standing practice of the use of reprocessed drums for the transport of dangerous goods in Australia. The purpose of this Code of Practice is to afford a mechanism to control the quality of drums prior to subsequent use and to that end it sets out: (a) selection criteria for drums intended for second or subsequent use in transporting dangerous goods; and (b) reprocessing procedures to which such drums must be subjected. Reprocessed drums must not be used for dangerous goods of packing group I. Notwithstanding drums being reprocessed to the requirements of this Code of Practice, the responsibility for the selection and suitability of the drums for a particular purpose remains with the packer. This Code of Practice is to be read in conjunction with this ADG Code.

D2 DEFINITIONS AND PROHIBITED PRACTICES Drum for the purposes of this Code of Practice is a flat ended cylindrical receptacle made of metal with filling apertures in the body and/or in the top head, with or without rolling hoops or corrugations and with ends permanently fixed to the body by means such as seaming or welding and has a nominal capacity of 200 to 220 litres and commonly known as a closed or non-removable head steel drum. In House describes the circumstances where a packer of dangerous goods reuses or launders drums on the packer's premises for the packer's own use but does not make such drums available to others as packagings for dangerous goods. Launder means the action of washing the exterior and interior of drums and where necessary, repainting the exterior of the drums to obliterate all previous package markings (other than packaging approval markings), with or without chaining or de-scaling the interior prior to filling. Packer means a person who fills, or causes to be filled, the drum. APPENDICES

Recondition means the actions of both mechanical repair and laundering of drums involving processes which require reformation to original shape of any component by mechanical means, and repairs of holes by welding, but excludes the process of remaking. Remake means the action of replacing one or both ends of a drum. Reuse means the action of in-house refilling of drums with goods of a type chemically similar to the goods initially packed. Reuse does not include laundering, but rinsing and painting, if needed, are permitted. Reprocess means the actions of either laundering or reconditioning drums. Rinsing means the action of washing a drum with fluids whose residues need not be removed, other than by drying, before the drum is refilled. Weld means the action of repairing a hole by welding. Welding does not include the placing of a patch. Welding is not permitted on the bottom of a drum or within 50mm of a body seam, chime of flange. Welding of holes longer than 15mm or those caused by corrosion or fatigue is not permitted.

D3 SELECTION OF DRUMS A drum may be re-used or reprocessed for use with dangerous goods provided that: (a) the drum is selected for re-use, laundering or reconditioning, or rejection, in accordance with the criteria specified in the selection table in Section D9; and (b) the drum selected for reprocessing does not exhibit damage to a degree equivalent to those illustrations designated as `NOT ACCEPTABLE’ in the Pictorial Guide in Section D10 of this Code of Practice.

D4 EQUIPMENT Reprocessors must possess both leak testing equipment and a set of scales. Both of these must be calibrated against Australian StandardsStandards or equivalent and only used within their calibration period. The following equipment is optional: - washing machine - spray painting equipment - chaining or de-scaling equipment - de-denter - chime straightener. Reprocessors who possess either a de-denter or a chime straightener (or both) will be deemed to be reconditioners. All equipment must be adequately protected to minimise the risk of injury to equipment operators.

APPENDICES

D5 TESTING OF DRUMS Except for drums which are only being re-used, every drum must be subjected to the following tests before being utilised for the transport of dangerous goods:

D5.1 Leakproofness Test Description of test: A pressure of 20kPa must be applied using a test method approved by the Competent Authority. Criteria for passing the test successfully: There must be no leakage.

NOTE: Leakproofness testing equipment must be adequately protected to minimise the risk of injury to equipment operators.

D5.2 Tare Weight Test Description of test: The clean empty reprocessed drum must be weighted to an accuracy of +/- 0.1 kg. Criteria for passing the test successfully: The mass of the drum must be not less than 15.5kg.

D6 MARKING OF DRUMS Drums reprocessed in accordance with this Code of Practice must be marked in accordance with Section 6.1.3.

D7 APPROVAL OF REPROCESSORS Each reprocessing facility must be approved as a laundering or reconditioning facility by the Competent Authority in whose jurisdiction the facility is located. NOTE: Details of approved drum reprocessors can be obtained from the Competent Authority. The following steps must be undertaken to obtain approval: (a) The reprocessor must make an application for approval to the Competent Authority. The application must be in writing and will: (i) nominate responsible persons in charge of the reprocessing operation; (ii) list the reprocessing equipment in the facility; (Essential and optional equipment for reprocessors is listed at D4 of this Code of Practice) (iii) verify that all reprocessed drums, prior to being placed into dangerous goods service will have: - had their tare mass determined; - passed through all necessary processes in this Code of Practice; and - been leak tested; (iv) nominate an identifying mark for use under D6. (b) Following receipt of an application completed in accordance with (a), the Competent Authority will inspect the reprocessor's APPENDICES

premises and witness all the equipment listed under (a)(ii) in operation. (The level of equipment will depend on whether a reconditioner or launderer is being inspected). For this inspection, leak testing equipment must be set up and equipped with an accurate gauge. (c) If satisfied with the site inspection under (b) the Competent Authority will grant written approval to the reprocessor. The approval will include a confirmation of the identifying mark nominated in (a)(iv) and advice of approval as a `reconditioner' or a `launderer'. (d) The Competent Authority will fully re-inspect the reprocessor's premises at least biennially.

D8 TRAINING It is a requirement of this Code of Practice that reprocessor's staff involved in the reprocessing of drums for use in the transport of dangerous goods are trained in the drum selection procedures and the procedures for reprocessing and testing contained in this Code of Practice.

D9 DRUM AND PROCESS SELECTION To be suitable for reuse, laundering or reconditioning for packaging dangerous goods, a drum must: (a) be an approved drum, complying with Chapter 6.1 of this Code, as verified by markings in accordance with 6.1.3; (b) have a minimum tare mass of 15.5 kg; and (c) not be damaged to such an extent that, after reprocessing, it may not be capable of meeting the performance tests of this Code applicable to drums for their intended service. Detailed criteria to be applied to the selection of drum suitable for reprocessing are provided in Table D overleaf. This table also indicates what processing is required for different types of damage. This table should be used for segregating drums into those to be reused and those which are candidates for reprocessing or rejection. The pictorial guide provided at D10, must be used to assist in interpreting damage levels referred to in Table D.

APPENDICES

Table D: Reprocessing Criteria and Options

PROCESS OPTION CRITERIA FOR SELECTION Reuse Launder Recondition Reject Criteria based on Original (as new) Status Approved drums 1 2 2 2 2 Unapproved drums - - - 3 Weight Criterion Minimum Tare Mass:– Nominally > 15.5kg 2 2 2 2 – Nominally < 15.5kg - - - 3 Damage Criteria Damage Categories Type, extent or degree Ullage Reduction: Minor 2 2 2 2 Major - - - 3 Apparent Leaks: Minor - - 2 2 Major - - - 3 Flanges: Rust Pitted - - - 3 Loose in Head - - - 3 Out of Round - - - 3 Thread - - 2 2 Damage Bungs: Rust Pitted - - - 3 Thread or - - - 3 Mechanical Damage Blown Ends: Minor - - 2 2 Major - - - 3 General End Damage: Minor 2 2 2 2 Major - - - 3 Out of Rounds - - 2 2 Dents: Body – Within Bands: Shallow and rounded 2 2 2 2 Deep - - - 3 Creased - - - 3 Body – Adjacent to Chime - - 2 2 Swedge: Shallow and 2 2 2 2 rounded - - - 3 Creased Seam: Shallow and 2 2 2 2 rounded - - - 3 Creased Chime – Folded: Minor 2 2 2 2 Major - - - 3 Chime – Flattened - - 2 2 Corrosion: External: Minor 2 2 2 2 Major - - - 3 Internal: Minor - 2 2 2 Major - - - 3 Modifications to Body or Ends - - - 3

APPENDICES

Key to Table D: 1. `Approved' means the drum has been originally approved in accordance with this Code and is marked accordingly. 2. Denotes an acceptable option. 3. Denotes mandatory action.

NOTE: Any drum, irrespective of the extent of damage, may be rejected.

D10 PICTORIAL GUIDE This section provides illustrations of drums which have been used for the transport of dangerous goods and have suffered varying degrees of damage. The reprocessor must examine each drum received to determine the extent of its damage and the type of reprocessing to be undertaken in order to render it suitable to be used in the transport of dangerous goods. The illustrations are designed to provide guidance to reprocessors in the selection of drums based on the condition of the drum. Drums suffering damage to a degree equivalent to those illustrations designated as `NOT ACCEPTABLE' must not be reprocessed for use with dangerous goods. The illustrations have been reproduced, with permission, from the Shell publication `Guidelines for the Selection of Used Drums'. This pictorial guide should be used in conjunction with the Selection Guide in Table D.

APPENDICES

Figure D1: Reprocessing steel drums – dents

A large dent. NOT ACCEPTABLE Major body denting. NOT ACCEPTABLE

The dent is too deep to be blown out The dents cannot be blown out. satisfactorily. Note the damage to the swedged rolling hoops. Note the damage to the swedged The sharp indentations will be the site of leaks. rolling hoops. These sharp indents are potential leak areas.

Deep dents. NOT ACCEPTABLE Shallow dents. ACCEPTABLE.

The 5 dents shown in the photo are Can be blown out sufficiently to make the drum too deep to be blown out successfully. usable. Note the sharp dents in both swedged rolling hoops, which are potential leak areas.

APPENDICES

Figure D2: Reprocessing steel drums – chime and head damage

Two photos of the same damage. NOT ACCEPTABLE.

Dent in chime is too deep to be rolled out. Any attempt will result in splitting of chime and cracking of the drum body.

NOT ACCEPTABLE.

The chime dent can be hammered out to enable the drum to fit the rollers. The dent can then be rolled out further but in doing so the buckles in the head could be cut by the rollers resulting in leaks.

NOT ACCEPTABLE.

The chime cannot be re-rolled nor can the dent in the body be blown out.

APPENDICES

INDEX

Adopted National Exposure Standards Class 2 - gases, 66 for Atmospheric Contaminants in the special packing provisions, 808 Occupational Environment, 31 Class 3 – flammable liquids, 70 ADR (defined), 31 Class 4 - flammable solids - alphabetical index of substances and substances liable to spontaneous articles (Table 3.2.4.2), 518 combustion - substances which, in American Society for Testing and contact with water, emit flammable Materials [W], 7 gases article (defined), 6 special packing provisions for self- assigned organic peroxides in reactive substances of Division packagings (Table 2.5.3.2.4), 101 4.1, 810 assigned self-reactive substances in Class 5 - oxidising substances and packagings (Table 2.4.2.3.2.3), 80 organic peroxides, 95 Australian Explosives Code, 43 special packing provsions for Australian Explosives Code (defined) organic peroxides, 810 [W], 32 Class 6 - toxic and infectious Australian Radiation Protection and substances, 124 Nuclear Safety Authority special packing provisions for part (ARPANSA), 41 of, 812 Australian Radiation Protection and Class 7 - radioactive material, 139 Nuclear Safety Authority Class 8 - corrosive substances, 142 (ARPANSA) [W], 139 Class 9 - miscellaneous dangerous Australian Standard, 945, 1218 substances and articles, including Australian Standard (defined) [W], 32 environmentally hazardous Australian Standard, and ISO, 34, 945 substances, 145 biological products, 137 classes, divisions, packing groups, 43 bulk container (defined), 7, 22 classification of pesticides, 131 Canadian Transport Emergency Code of Practice for the Safe Centre [W], 7 Transport of Radioactive Substances, 43 class (defined), 7 Code of Practice for the Safe Class 1 - explosives, 51 Transport of Radioactive acceptance procedure, 58 Substances (defined) [W], 32 assignment of fireworks to hazard Code, the divisions, 59 assignment to hazard divisions, 59 Amendment Package No. 3, 4 classification codes, 54 amendments commence January classification procedure, 55 2016, 4 compatibility groups, 53, 55 assignment of duties, 4 default fireworks classification table Codes, standards and rules referred (Table 2.1.3.5.5), 61 to, 31 definitions and general provisions, defined, 6, 20 51 exceptions, 3 divisions, 52 interpreting terms, vs Regulations, exclusions, 65 6, 18 scheme of procedure for classifying jurisdictional legislation required, 2 a substance or article (Fig. 2.1.1), offence not committed until 2017, 4 58 units of measurement, 29 special packing provisions, 806 combination road vehicle (defined), 8 APPENDICES combustible liquid (defined), 8 forms competent authority (defined), 8 Multimodal Dangerous Goods Form, composite packagings (defined), 8 1185 Compressed Gas Association (US) revised hazchem emergency action [W], 7 code pocket card, 1185 consignor (defined), 23 free from dangerous goods (defined), 10 corrosive substances, 142 freight container (defined), 10 dangerous goods GHS, marking in accordance with, 40 goods too dangerous to be transported, 1179 goods too dangerous to be transported, 1179 dangerous goods (defined), 23 Hazard Identification Number (HIN), Dangerous Goods Code units of 1212 measurement, 29 Hazchem code (defined), 11 conversion into SI units, 29 Hazchem Code, meaning of second Dangerous Goods List, 45, 46, 165, character, 1191 169, 170 Hazchem Codes, 1190 dangerous goods list (Table 3.2.3), 174 hose assembly (defined), 11 Dangerous Goods List, abreviations / IATA Regulations (defined) [W], 32 symbols and their meanings, 172 ICAO Rules (defined) [W], 32 Dangerous Goods List, design IMDG Code (defined) [W], 32 approval, 1042 Initial Emergency Response Guide Dangerous Goods List, special (defined), 32 provisions, 633 Intermediate Bulk Container (IBC) Dangerous Goods List, structure of, (defined), 11, 24 170 International Atomic Energy Agency Dangerous Goods List, the four types [W], 11 of entry, 46 International Civil Aviation dangerous goods, transport Organisation [W], 11 consignment by post, 4 International Convention for Safe coolant / conditioner, 4 Containers (defined), 32 forbidden goods, 5 International Maritime Organisation lamps, 5 [W], 11 radioactive materials, 5 Interpretation of references to GHS, 40 dangerous situation (defined), 9 ISO (standard) (defined) [W], 32, 34 definitions, 6, 27, 52, 75, 76, 91, 92, key terms, definitions (aerosols, bag, 95, 124, 132, 142, 145, 148, 149, box, consigneee etc.), listings, 6, 22 1024, 1049, 1068, 1085, 1096, Labelling, 852, 855, 859 1147, 1165, 1217 Limited Quantity, 13 Documentation, 901, 905, 1158 liquids (defined), 13 Emergency Responders Guide, Load Restraint Guide (defined), 33 Canada [W], 9 Manual of Tests and Criteria (defined), emergency service (defined), 9 14 EN standard (defined) [W], 32 manufactured product (defined), 14 European Committee for Marking, 852, 855, 873, 883, 911, 973, Standardisation [W], 32 985, 1013, 1219 exemption, 3 material Safety Data Sheet (defined), explosives, 51 19 definitions, 52 methods for determining oral and flammable liquids, 70 dermal toxicity of mixtures, 130 APPENDICES miscellaneous dangerous substances recycled plastics material (defined), 17 and articles, including Regulations environmentally hazardous interpreting terms, vs Code, 6 substances, 145 Regulations, the (defined), 18 Model Subordinate Law, xxxix, 3 reused packagings (definition), 18 defined, 6, 14 revised hazchem emergency action terms defined in the text of, 22 code pocket card, 1185 National Code of Practice for the RID (defined), 33 Preparation of Material Safety Data Sheets (defined) [W], 33 Safety Data Sheet (defined), 19 National Code of Practice for the scope and application, 2 Storage and Handling of Dangerous semi-trailer (defined), 19 Goods (defined) [W], 33 source of ignition (defined), 20 National Standard for the Storage and standard numbers - SA, AS, SNZ, Handling of Dangerous Goods NZS etc., 34 (defined) [W], 33 standards and rules referred to in this numbered Regulation (defined), 18 Code, 31, 34, See also Australian OECD Guidelines for the testing of Standard; ISO; Table 1.2 Chemicals (defined), 33 substances under the Code, class and OECD Test Guidelines [W], 149 division definitions, 43 Office of Inspector of Transport tank (defined), 26 Security [W], 40 telephone advisory service (defined), outer packaging (defined), 15 27 oxidising substances and organic terms defined in the text of the Model peroxides, 95 Subordinate Law, 22 percentage sign (%) defined, 31 The WHO Recommended personal protection, 1192 Classification of Pesticides by Placard, 893 Hazard and Guidelines to Classification (defined) [W], 33 Placarding, 852, 873, 885, 887, 888, 891, 893 The WHO Recommended Classification of Pesticides by portable tank (defined), 16 Hazard and Guidelines to portable tank instructions, 824 Classification [W], 131 portable tank special provisions, 839 this Code (defined), 20 precedence of hazard characteristics, toxic and infectious substances, 124 47 transfer operation (defined), 21 Preparation of Safety Data Sheets for Transport and Infrastructure Council Hazardous Chemicals Code of Practice [W], 19 Amendment Package No. 2, 139 Amendment Package No. 3, 4 prime contractor (defined), 25 transport of dangerous goods. See radioactive material, 139 dangerous goods, transport radioactive material ARPANSA codes transport of samples, 50 [W], 5, 41, 139, 813, 847 ullage (defined), 21 rail operator (defined), 25 Recommendations on the Transport of UN Number (defined), 21 Dangerous Goods, Manual of Tests UN numbers and proper shipping and Criteria, 2 names, 45 Recommendations on the Transport of UN packaging symbol, 962 Dangerous Goods, Manual of Tests UN Recommendations and Criteria (US), 14 Manual of Tests and Criteria reconditioned packagings (defined), 17 (defined), 33 APPENDICES

UN Special Provisions, dangerous United Nations Economic Commission goods list, 633 for Europe (UNECE) [W], 21 UN20 (defined), 33 vehicle owner (defined), 27 United Nations, 2 violent reaction, 1192 'weight' vs 'mass', 31