The Plasmon Density of States of a Layered Electron Gas H
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Z. Phys. B 90, 277-281 (1993) Condensed Zeitsehrift far Physik B Matter Springer-Verlag 1993 The plasmon density of states of a layered electron gas H. Morawitz ~, I. Bozovic 2, V.Z. Kresin 3, G. Rietveld 4, D. van der Marel 4 IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099, USA 2 Varian Research Center, 611 Hansen Way, Palo Alto, CA 94303, USA 3 Materials and Chemical Physics Division, Lawrence Berkeley Laboratory, Berkeley, CA 94720, USA 4 Delft University of Technology, Faculty of Applied Physics, Lorentzweg 1, 2628 CJ Delft, The Netherlands Received: 24 September 1992 Abstract. The plasmon density of states (DOS)p(co) of a mon side-band measured with such a local probe. The layered electron gas (LEG) is studied theoretically. It is plasmon-pole approximation replaces the response func- shown that p (co) is a linear function of frequency ~o as co tion with the density of states of the layer plasmons, goes to 0, and then increases more rapidly as co tends to which is defined by the screened, three dimensional plasma frequency cop. We also study the partial densities of state for constant K and p(~o)=(2n) -3 ~ O(~-Op(tc, qz)). (1) q~, where K and qz are the magnitude of the transverse K~ qz and perpendicular momentum transfers. A possible ex- The nature of the collective excitations in layered systems perimental probe for the plasmon DOS is discussed. has been studied extensively [5, 6] theoretically, because of continuing interest in superlattices and naturally layered materials such as graphite and the transition metal I. Introduction chalcogenides (TaS2, TeS2, etc.). The outline of this paper is 'as follows: In Sect. 2 we The new superconducting cuprates [1-4] with high su- rederive the layer plasmon dispersion relations [6] using perconducting transition temperatures T~ are all charac- the random phase approximation (RPA). In Sect. 3 we terized by a layered structure of conducting (CuO2) calculate the partial density of states, keeping either of planes. We propose to use the layered electron gas (LEG) the variables K (the absolute value of the LEG plasmon model [5] to describe their collective charge excitation wavevector parallel to the conducting planes) or qz (the (layer plasmons) and to calculate their density of states LEG plasmon wavevector perpendicular to the planes) (DOS) as a function of frequency in this paper. The struc- constant. In Sect. 4 we derive a simple form of the total ture of the plasmon spectrum in layered, conducting sys- plasmon DOS, based on an approximate form of the LEG tems differs in a striking way from those of the isotropic dispersion relations. In Sect. 5 we calculate both ana- (3 D) conductors. In the latter case, the plasmon branch lytically and numerically the exact layer plasmon density is described by a dispersion relation co (q)=oJ 0 +aq 2, of states and discuss the various frequency regimes whereas a layered conductor is characterized by a highly ~o/cop< l, = 1 and > 1. Finally - in Sect. 6 - discuss the anisotropic plasmon band D 0c, qz) without a gap at tc = 0 implications of these results for the shake-up spectra of except for the single branch for which qz = 0 (to is a two- core levels in a layered compound. dimensional wave-vector in the plane of the sheets and qz has been chosen perpendicular to the layers). That 2. Plasmon dispersion relations produces noticeable changes in the spectrum of collective We assume that the carriers are localized in N(N~) modes of these materials. In experimental probes, such independent layers, spaced a distance D apart. The dis- as absorption of light, the dielectric response is subject persion relation for two-dimensional carriers is assumed to strong momentum selection rules. As a result only the to be given by the effective mass approximation: ek = long-wavelength dielectric response is probed in such ex- k 2/2 m*. Electrons on different sheets are coupled by the periments. In local experimental probes, such as the sud- Coulomb interaction. We can write an electronic Ham- den creation of a core hole by X-ray photo-electron spec- iltonian H el. troscopy, one can, in principle, couple to the full spectrum of plasmons. This shows up as a side-band of the core- H ~1-= ~, eKIA~,+ A,~l hole excitation spectrum due to plasmon shake-up. It is Ir conceivable that the plasmon-pole approximation can be + Z Z V~~ + + ,,"z A,,+ " - ,," z" A,,I" A,~,z used for the calculation of the spectral shape of the plas- K,,,,,,~" l,t" (2) 278 where t~, te' and K" are two-dimensional momentum var- the background dielectric constant of the medium due to iables, and l, l' label different layers, At,. l, A k,z+ are carrier all other high frequency excitations. (A typical value is annihilation and creation operators and the interaction v~ 0.05). With these definitions, and solving for the roots matrix element V~ (l, l') is the two-dimensional Fourier of e (te, qz; co) = 0, we obtain with (8) transform of the Coulomb interaction between electrons on layers l and l'. For an infinite system V(I,l')= F(y,z) [ cop ] Vq-P). 0=1 v~y [COZp_(VFy)2]I/2 1 . (10) 2 7re 2 V~~ ') =-- e -~Dll-r I (3) From this equation we solve the layer plasmon dispersion ~Mte relation F2(Y'Z) (11) If we make a Fourier transformation of the variable c~ v~ Y2-~ v~+ 2F(y,z)/y" r = l- l' we obtain Alternatively we can express this as a dispersion relation q~0(te;q~)= ~. V(O)(r)exp(iq~Dr) for O as a function of te and q~. When written in this r = --ao form the dispersion relation reads 2 7~e2 --- F(teD, q~D), (4) Op (n, qz) CM te 1/2 where we use the dimensionless function F (the 'layer 2 1 .~-VFte 1+ [ 2F(xD'q~D)] form factor'), introduced by Fetter [5b] in the hydro- 4F(xD, q~D) dynamic treatment of the layer plasmon dispersion rB x A r B K sinh teD F (te D, q~D ) - cosh teD - cos q~D " (5) For later use it is convenient to express F as a function of COp and y using (10), and also to express z in terms of The study of the screening properties and collective modes F and y, by inverting (5). The resulting expressions are requires the knowledge of the fully screened interaction found to be V(1, l'). Within the random phase approximation, the v~yV~2p-(vFy) 2 latter obeys the equation F(mp,y) - co, - Vco - (v y)2 " V(I,I')= V~ ") (12) sinh ( y ) ~'~. +H~176 Z V~ V(l",l'), (6) z(Ogp, y)=arccos (cosh (y) ~/ l" where the single layer polarizability H ~ is given by It should be noted here that (11) goes beyond the earlier RPA results as it used the exact form of the single sheet 2 f(8~+q)--f(ek) (7) polarizability )~0 (9) and not its expansion valid for H~ =A - ~ gk+q--ek -ico co ~ VFX only. On the other hand, we have not included the effects of the non-local exchange and correlation part Here A is the area of one layer and f (e,~) is the Fermi of the electron-electron interactions. Some exploration of function. The layer plasmons are defined as the zeroes of the inclusion of such effects by a local field correction the layer dielectric function for the in-plane electron-electron interaction has been recently made in [8]. We note that the general conse- e (te, q~; co) = 1 - ~0 (te, q~)Re {H(~ (8) quence of such treatments as the GRPA (generalized ran- dom phase approximation) is to reduce the strength of In the frequency regime co > vete, the real part of the the electron-electron interactions. polarizability Z0 of a single sheet is [5, 7] Re{H~ (te; co)} =)-~o,[ [CO~_(Vvte)2],/2--1.] (9) 3. Plasmon partial density of states Let us first address the question of the LEG plasmon In order to keep the expressions simple we introduce frequency dependence for co ~ 1. In this region (see Fig. 1) dimensionless variables for the in-plane and out-of-plane y~ 1 holds also, and the hyperbolic functions may be wave-vector components te and qz and the LEG plas- expanded in a Taylor series for small y. The LEG plasmon mon frequency co_, by defining y-=teD, z=-qzD, dispersion relations then reduce to the much simpler form cop (y, z) ~ Op (y, z)f0 o with ~o2 = 2 vZ/(DrB) and VF = (y, z) = 2 OF/(D(20) (rB/2D) 1/2. Here h2e~ is the effec- y2 rB = ~177"e (13) tive Bohr radius, m* the effective carrier mass and c g is [ + 1 -- cos z] [2 + VFI.gy2 .'1 2 + 1 -cosz)] 279 1.5 i r i // / / 1.0 t.O i ',/,t ~- I //Z p(qD,w) 0.5 0 i I i I r I i 0 1 2 3 KD 0.30 I i o 0.5 1 .o y=KD -- 0.2 0.25 --.-- 0.4 --- 0.6 ...... 0.8 0.20 .... 1,0 1.2 8 0.15 l o.10 - I rl i ! dlnp 0.05 i, !!, l\iAjl dlnw 4 i .4.~_//~ ! ~ 0 0 0.5 1.0 c a,,/w 0 Fig. la-d. a Layer plasmon dispersion for v 2= 0.05 and (from top to bottom) z/~ =0, 0.2, 0.4, 0.6, 0.8, 1.