BIOLOGICAL STUDIES WI'i'h POLONIUM, Radiubi, AND
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Distribution Coefficients of Polonium Between 0.75 M HDEHP in Cyclo- Hexane and Aqueous Hydrochloric and Nitric Acids Guogang Jia* and Giancarlo Torri
18 The Open Inorganic Chemistry Journal, 2008, 2, 18-21 Distribution Coefficients of Polonium Between 0.75 M HDEHP in Cyclo- hexane and Aqueous Hydrochloric and Nitric Acids Guogang Jia* and Giancarlo Torri Agency for Environmental Protection and for Technical Services, Via V. Brancati 48, 00144 Roma, Italy Abstract: The distribution coefficients (D) of polonium between 0.75 M di(2-ethyhexyl)phosphoric acid (HDEHP) in cy- clohexane and aqueous hydrochloric and nitric acids have been studied. Results indicate that: (1) D values are ranged from 32.7 to 0.00048 when the HCl acidities vary from 0.10 to 10.0 M, showing that polonium can well be extracted by 0.75 M HDEHP in cyclohexane if the aqueous HCl acidities are 0.050 M and it will not be extracted if 0.10 M HCl; (2) D values are ranged from 47.1 to 0.0117 when the HNO3 acidities vary from 0.10 to 10.0 M, showing that polonium can be extractable by 0.75 M HDEHP in cyclohexane and in a wide range acidity of 4 M HNO3. The different extraction behaviours of polonium in 0.75 M HDEHP in cyclohexane and different acidities of HCl and HNO3 were found. The find- ings will be very helpful to improve the methods involving polonium decontamination for determination and separation of americium, curium as well as other radioelements in environmental soil, water and biological samples. Keywords: Polonium, HDEHP, distribution coefficients. 1. INTRODUCTION on its oxidation state. Therefore, question is raised: which oxidation state is responsible for major polonium volatility, The element polonium (210Po) was discovered by Marie valences of +2, +4, and probably +6? Curie as the first element separated from pitchblende, and named after her home country, Poland [1, 2]. -
Radionuclides (Including Radon, Radium and Uranium)
Radionuclides (including Radon, Radium and Uranium) Hazard Summary Uranium, radium, and radon are naturally occurring radionuclides found in the environment. No information is available on the acute (short-term) noncancer effects of the radionuclides in humans. Animal studies have reported inflammatory reactions in the nasal passages and kidney damage from acute inhalation exposure to uranium. Chronic (long-term) inhalation exposure to uranium and radon in humans has been linked to respiratory effects, such as chronic lung disease, while radium exposure has resulted in acute leukopenia, anemia, necrosis of the jaw, and other effects. Cancer is the major effect of concern from the radionuclides. Radium, via oral exposure, is known to cause bone, head, and nasal passage tumors in humans, and radon, via inhalation exposure, causes lung cancer in humans. Uranium may cause lung cancer and tumors of the lymphatic and hematopoietic tissues. EPA has not classified uranium, radon or radium for carcinogenicity. Please Note: The main sources of information for this fact sheet are EPA's Integrated Risk Information System (IRIS) (5), which contains information on oral chronic toxicity and the RfD for uranium, and the Agency for Toxic Substances and Disease Registry's (ATSDR's) Toxicological Profiles for Uranium, Radium, and Radon. (1) Uses Uranium is used in nuclear power plants and nuclear weapons. Very small amounts are used in photography for toning, in the leather and wood industries for stains and dyes, and in the silk and wood industries. (2) Radium is used as a radiation source for treating neoplastic diseases, as a radon source, in radiography of metals, and as a neutron source for research. -
Factsheets & Faqs Polonium-210
Factsheets & FAQs Polonium-210 Basic Facts Polonium-210 (Po-210) is a radioactive element that occurs naturally and is present in the environment at extremely low concentrations. Polonium was discovered by Marie Sklodowska-Curie and Pierre Curie in 1898 and was named after Marie's native land of Poland (Latin: Polonia). This element was the first one discovered by them while they were investigating the cause of pitchblende radioactivity. It is a fairly volatile (50% is vaporized in air in 45 hours at 55°C) silvery-grey soft metal. Po-210 has a half-life of 138 days. This is the time it takes for the activity to decrease by half due to a process of radioactive decay. Po-210 decays to stable lead-206 by emitting alpha particles, accompanied by very low intensity gamma rays. The majority of the time Po-210 decays by emission of alpha particles only, not by emission of an alpha particle and a gamma ray. Only about one in a 100,000 decays results in the emission of a gamma ray. Alpha spectroscopy is the best method of measuring this isotope. Origin Being produced during the decay of naturally occurring uranium-238, polonium-210 is widely distributed in small amounts in the earth's crust. Although it can be produced by the chemical processing of uranium ores or minerals, uranium ores contain less than 0.1 mg Po-210 per ton. Because Po-210 is produced from the decay of radon-222 gas, it can be found in the atmosphere from which it is deposited on the earth's surface. -
Periodic Table of the Elements Notes
Periodic Table of the Elements Notes Arrangement of the known elements based on atomic number and chemical and physical properties. Divided into three basic categories: Metals (left side of the table) Nonmetals (right side of the table) Metalloids (touching the zig zag line) Basic Organization by: Atomic structure Atomic number Chemical and Physical Properties Uses of the Periodic Table Useful in predicting: chemical behavior of the elements trends properties of the elements Atomic Structure Review: Atoms are made of protons, electrons, and neutrons. Elements are atoms of only one type. Elements are identified by the atomic number (# of protons in nucleus). Energy Levels Review: Electrons are arranged in a region around the nucleus called an electron cloud. Energy levels are located within the cloud. At least 1 energy level and as many as 7 energy levels exist in atoms Energy Levels & Valence Electrons Energy levels hold a specific amount of electrons: 1st level = up to 2 2nd level = up to 8 3rd level = up to 8 (first 18 elements only) The electrons in the outermost level are called valence electrons. Determine reactivity - how elements will react with others to form compounds Outermost level does not usually fill completely with electrons Using the Table to Identify Valence Electrons Elements are grouped into vertical columns because they have similar properties. These are called groups or families. Groups are numbered 1-18. Group numbers can help you determine the number of valence electrons: Group 1 has 1 valence electron. Group 2 has 2 valence electrons. Groups 3–12 are transition metals and have 1 or 2 valence electrons. -
Polonium Human-Injection Experiments Injection and Lived Another 8 Years Be- Fore Dying, in 1953, of Heart Failure
The Human Plutonium Injection Experiments any effect on the normal course of his life.” HP-12 was 53 at the time of the Polonium Human-Injection Experiments injection and lived another 8 years be- fore dying, in 1953, of heart failure. In 1944, in response to concerns for the risk associated with occupational Late radiation effects, such as cancer, exposures to polonium, the Army Medical Corps authorized Rochester to un- were not expected to develop for ten to dertake a study of the biological behavior of that element. The program was fifteen years, if at all. For example, the started in August 1944 with animals, and by November, studies with humans induction period in humans for radium- had begun. Eventually, tracer amounts of radioactive polonium-210 were in- induced cancer, especially malignancy jected into four hospitalized humans and ingested by a fifth. of the bones, was about 10 to 30 years after exposure. Despite Langham’s Polonium, the first element isolated by Marie and Pierre Curie from pitch- statement, we cannot, of course, dis- blende in 1898, is an alpha emitter. When alpha particles from polonium- count the fact that HP-12 might have 210 collide with beryllium atoms, neutrons are ejected, and polonium-berylli- lived 20 or more years; although in um combinations had already served physicists as a convenient source of 1945, fifty years of age was considered neutrons. During the Manhattan Project, it was decided to use that neutron to be fairly advanced. On the other source as an initiator of the chain reaction in the atomic bombs, thus making hand, the GIs at Los Alamos who were polonium (and beryllium) an occupational health hazard for the people who heavily exposed to plutonium in 1945 needed to develop and build the initiators. -
Genius of the Periodic Table
GENIUS OF THE PERIODIC TABLE "Isn't it the work of a genius'. " exclaimed Academician V.I. Spitsyn, USSR, a member of the Scientific Advisory Committee when talking to an Agency audience in January. His listeners shared his enthusiasm. Academician Spitsyn was referring to the to the first formulation a hundred years ago by Professor Dmitry I. Mendeleyev of the Periodic Law of Elements. In conditions of enormous difficulty, considering the lack of data on atomic weights of elements, Mendeleyev created in less than two years work at St. Petersburg University, a system of chemical elements that is, in general, still being used. His law became a powerful instrument for further development of chemistry and physics. He was able immediately to correct the atomic weight numbers of some elements, including uranium, whose atomic weight he found to be double that given at the time. Two years later Mendeleyev went so far as to give a detailed description of physical or chemical properties of some elements which were as yet undiscovered. Time gave striking proof of his predictions and his periodic law. Mendeleyev published his conclusions in the first place by sending, early in March 186 9, a leaflet to many Russian and foreign scientists. It gave his system of elements based on their atomic weights and chemical resemblance. On the 18th March that year his paper on the subject was read at the meeting of the Russian Chemical Society, and two months later the Society's Journal published his article entitled "The correlation between properties of elements and their atomic weight". -
Radioactive Equipment DISPOSAL
Radioactive Equipment DISPOSAL EQUIPMENT WITH RADIOACTIVE MATERIAL REQUIRES EVALUATION BEFORE DISPOSAL Contact the Division of Research Safety if you see the following equipment. Aircraft Gauges, Timepieces, Ceramic Plates Alnor Dew Pointer Switches, and Breakers Inside Electrical Switches Devices from the 1910s Quickly determines dew These 600-pound though the ‘60s used points of gases. Some switches have ceramic radioactive paint for glow- contain a label indicating plates containing in-the-dark applications. radioactive material. radioactive material. Compound: Radium Compound: Radium-226 Compound: Thorium Densitometers or Soil Corning Uranium-Glass Emergency Signs Optical Filter Density Gauges An optical filter to A tool that measures Glow-in-the-dark devices, transmit or absorb light the density and inner like exit signs, may con- in the ultraviolet, visible, structure of the test tain radioactive material. and infrared spectrum. material. Compound: Tritium (H-3) Compound: Uranium Compounds: Americium/ beryllium and cesium-137 [email protected] | 217-333-2755 Gas Chromatographs Geiger Counters Ionization Smoke Detectors Chromatographs that Civil defense Cold War Some smoke detectors, use an electron capture Geiger counters often especially older mod- device contain a sealed included chips of uranium. els, contain radioactive radioactive source. sources. Compound: Uranium Compounds: Iron-55 Compounds: Am-241 or nickel-63 or nickel-63 Liquid Scintillation Photographic Lenses Radioactive Power Counters Resistors These devices contain -
Radium & Uranium in Public Drinking Water Systems Brochure
WHAT SHOULD I DO? RADIUM AND We cannot eliminate radiation from our environment. We can, however, reduce possible URANIUM IN health risks by minimizing our exposures to it. The risks to health from radium in water do not represent a health emergency and radium can FOR MORE INFORMATION PUBLIC DRINKING be controlled by your water provider by using treatment or finding a supply with lower levels. WATER SYSTEMS The risk estimates* from exposure to radium and Georgia Division of Public Health uranium in drinking water assume that an Chemical Hazards Program individual drinks two liters of water each day for (404) 657-6534 70 years. If you drink less tap water or consume more bottled water instead, your health risk will www.health.state.ga.us/programs/hazards be reduced. Sensitive Populations Infants and young children are the population Georgia Environmental Protection most at risk for adverse health effects from Division repeated exposure to radium and uranium in Drinking Water Compliance Program drinking water. Because of their body weight and (404) 656-4807 developing systems, infants and children are exposed to higher doses. Their growing bodies www.gaepd.org absorb more contamination and can sustain permanent damage if exposures occur during critical growth stages. U.S. Environmental Protection Agency Therefore, pregnant and nursing women, Radiation Protection Programs women who may become pregnant, infants and small children are sensitive populations that (404) 562-9459 should avoid consuming large quantities for an www.epa.gov/radiation/basic extended period of time. The estimated health risks from exposure to low levels of radium and uranium are small, and short term exposures pose only extremely small risks. -
J. Newell Stannard and the University of Rochester
J. Newell Stannard and the University of Rochester A collection of papers presented at a special session at the Forty-Eighth annual meeting of the Health Physics Society in San Diego, California on July 22, 2003 in honor of Dr. J. Newell Stannard. J. Newell Stannard and the University of Rochester Contents Prologue and Acknowledgment……………………………………………....................1 Photograph of Participants ……………………………………………………………...3 Introduction ……………………………………………………………………………..5 William Bair Sketch of the University of Rochester Atomic Energy Project ………………………...7 J. Newell Stannard University of Rochester and the Health Physics Opportunity …………………………11 Paul Rohwer Firm Foundations for Understanding Radionuclide Dosimetry and Health Effects ……………………………………………………………………..17 Bruce Boecker Advances in Aerosol Science for Radiation Protection ……………………………….27 Otto Raabe Field Studies of Plutonium and Fission Products in Animals …………………………37 Robert Thomas Radon, Smoking, and Lung Cancer: We’ve Come a Long Way Baby! .........................51 Jan Johnson The Chernobyl Accident: Predictions vs. Reality ……………………………………..59 Marvin Goldman Selected Publications of Dr. J. Newell Stannard ………………………………………63 Prologue and Acknowledgement My first graduate student, Bill Bair was invited by the chairman of the Health Physics Society’s History Committee, Sydney Porter, to organize a session at the San Diego Meeting of the Health Physics Society, July 2003, to acknowledge and honor me and the University of Rochester for their many contributions to radiation protection through education and research. In consultation with Bob Thomas, Bill selected speakers to represent the contributions of the educational program at the University of Rochester made to the profession of radiation protection through all of its graduates. The early sections of Bill Bair’s introduction to the session and of my short sketch of the Rochester Project, also describe, respectively, how the special session came about and my delight and gratitude at the honor bestowed on me. -
The Environmental Behaviour of Polonium
technical reportS series no. 484 Technical Reports SeriEs No. 484 The Environmental Behaviour of Polonium F. Carvalho, S. Fernandes, S. Fesenko, E. Holm, B. Howard, The Environmental Behaviour of Polonium P. Martin, M. Phaneuf, D. Porcelli, G. Pröhl, J. Twining @ THE ENVIRONMENTAL BEHAVIOUR OF POLONIUM The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GEORGIA OMAN ALBANIA GERMANY PAKISTAN ALGERIA GHANA PALAU ANGOLA GREECE PANAMA ANTIGUA AND BARBUDA GUATEMALA PAPUA NEW GUINEA ARGENTINA GUYANA PARAGUAY ARMENIA HAITI PERU AUSTRALIA HOLY SEE PHILIPPINES AUSTRIA HONDURAS POLAND AZERBAIJAN HUNGARY PORTUGAL BAHAMAS ICELAND QATAR BAHRAIN INDIA REPUBLIC OF MOLDOVA BANGLADESH INDONESIA ROMANIA BARBADOS IRAN, ISLAMIC REPUBLIC OF RUSSIAN FEDERATION BELARUS IRAQ RWANDA BELGIUM IRELAND SAN MARINO BELIZE ISRAEL SAUDI ARABIA BENIN ITALY SENEGAL BOLIVIA, PLURINATIONAL JAMAICA SERBIA STATE OF JAPAN SEYCHELLES BOSNIA AND HERZEGOVINA JORDAN SIERRA LEONE BOTSWANA KAZAKHSTAN SINGAPORE BRAZIL KENYA SLOVAKIA BRUNEI DARUSSALAM KOREA, REPUBLIC OF SLOVENIA BULGARIA KUWAIT SOUTH AFRICA BURKINA FASO KYRGYZSTAN SPAIN BURUNDI LAO PEOPLE’S DEMOCRATIC SRI LANKA CAMBODIA REPUBLIC SUDAN CAMEROON LATVIA SWAZILAND CANADA LEBANON SWEDEN CENTRAL AFRICAN LESOTHO SWITZERLAND REPUBLIC LIBERIA SYRIAN ARAB REPUBLIC CHAD LIBYA TAJIKISTAN CHILE LIECHTENSTEIN THAILAND CHINA LITHUANIA THE FORMER YUGOSLAV COLOMBIA LUXEMBOURG REPUBLIC OF MACEDONIA CONGO MADAGASCAR TOGO COSTA RICA MALAWI TRINIDAD AND TOBAGO CÔTE D’IVOIRE MALAYSIA TUNISIA CROATIA MALI -
Periodic Table Facts
Periodic Table Facts Compact Periodic Table Table Layout The periodic table is normally presented in a compressed form with Transition Metals the Lanthanides (elements 57-71) and Actinides (elements 89-103) in separate rows below the rest of the table. This is A. Earth Metals Metals Earth A. done to make the table more Lanthanides compact. In the extended table, Actinides shown below, these elements are inserted in their proper position between the Alkaline Earth Metals and the Transition Metals. Extended Periodic Table Transition Metals Lanthanides A. Earth Metals Metals Earth A. Actinides increasing mass How Small Are Atoms? Atoms are very, very small. To similar understand how small atoms are, start properties by looking at a meter stick. A meter can be divided into 1000 smaller lengths called millimeters. Now think of that millimeter and divide it into 1000 smaller lengths called micrometers. Now think of that micrometer and Periodic Trends divide it into 1000 even smaller lengths Dmitri Mendeleëv organized elements called nanometers. One nanometer is in the Periodic Table according to large enough for about 5 carbon their mass and reactive properties. He atoms. recognized that some elements had It would take 7,000,000 (7 million) similar properties, so he placed them carbon atoms stacked on top of each in the same column. He placed the other to be the thickness of a dime. elements from left to right in order of increasing mass. Mendeleëv left It would take 120,000,000 (120 million) spaces in his original table for carbon atoms to cross the face of elements that hadn’t yet been a dime. -
Reactive Metals Hazards Packaging
Document No: RXM20172301 Publication Date: January 23, 2017 Revised Date: October 25, 2017 Hazard Awareness & Packaging Guidelines for Reactive Metals General Due to recent events resulting from reactive metals handling, CEI personnel and clients are being updated regarding special packaging guidelines designed to protect the safety of our personnel, physical assets, and customer environments. CEI’s Materials Management staff, in conjunction with guidelines from third party disposal outlets, has approved these alternative packaging guidelines to provide for safe storage and transportation of affected materials. This protocol primarily impacts water reactive or potentially water reactive metals in elemental form, although there are many compounds that are also affected. The alkali metals are a group in the periodic table consisting of the chemical elements lithium, sodium , potassium, rubidium, cesium and francium. This group lies in the s-block of the periodic table as all alkali metals have their outermost electron in an s-orbital. The alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well- characterized homologous behavior. The alkali metals have very similar properties: they are all shiny, soft, highly reactive metals at standard temperature and pressure, and readily lose their outermost electron to form cations with charge +1. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation. Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free element.