On the Presence of a Hydrous Component in a Gemstone Variety of Intermediate Olivine-Type Triphylite-Lithiophilite, Li(Fe, Mn)PO4
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NEW MINERALS It Is Proposed Hereafter to Indicate In.A General Way the Classification of All New Minerals Recoided in This Department
JOURNAL MINERALOGICAL SOCIETY OF AMENICA 63 Dr. Kunz then spoke of the various city localities and the minerals found therein. He stated that the East Side, from 37 to 110 St., probably afforded the most specimens. The various tunnels and their minerals were spoken of. Capt. Miller called attention to the fine collection of Brooklyn Drift Minerals and Rocks in the collection of the Long Island Historical Society. Ife abo mentioned the occurrence of monazite and xenotime crystals, on the Speedway,Harlem River. Dr. Kunz emphasizedthe irnportance of complete records being kept of all finds. Tnou,q,s L Mrr,r,nn, SecretaryPro, Tem. NEW MINERALS It is proposed hereafter to indicate in.a general way the classification of all new minerals recoided in this department. Subdivision will be first into "families," of which nine may be recognized,as listed in the January number (Am. Min.6 (1), 12,1921). Eachfamilywillbe separatedinto "subfamilies " based on special features of composition. This arrangement is tentative and open to modification, and criticism of it will be welcome, [Eo.] FAMILY 2. SULFIDES, ETC. SosreMrr,v 3. Doust,u suLFrDEs oF METALSAND sEMr-METAr,s. I'LTRABASITE V. Rosrcxf and J. Srnnse-Btinu. Ultrabasit, ein neues Mineral aus Freiberg in Sachsen. (Ultrabasite, a new mineral from Freiberg, Saxony). Rozpr.Eeslcd Ako,il. Prag,25, No. 45, 1916;Z. Krgst. Min., 55,43H39, 1920, Neun: From its extremely basic chemical composition. Pnrsrcar, Pnopnnrrus Color black, somewhat grayish; luster metallic; streak black; cleavage none; fracture scaly, with somewhat greasy luster on the surface. H. : 5; sp. gr. -
Geology of the Pegmatites and Associated Rocks of Maine
DEPARTMENT OF THE INTERIOR UNITED STATES GEOLOGICAL SURVEY GEORGE OTIS SMITH, DIRECTOR BULLETIN 445 GEOLOGY OF THE PEGMATITES AND ASSOCIATED ROCKS OF MAINE INCLUDING FELDSPAR, QUARTZ, MICA, AND GEM DEPOSITS BY EDSON S. BASTIN WASHINGTON GOVERNMENT PRINTING OFFICE 1911 CONTENTS. Introduction.............................................................. 9 Definition of pegmatite...................................................... 10 Geographic distribution.................................................... 10 Geology.................................................................. 10 Bordering rocks....................................................... 10 Pegmatites in foliated rocks........................................ 11 General statement............................................ 11 Sedimentary foliates........................................... 11 Igneous foliates.....".......................................... 12 Pegmatites in massive granites.................................... 13 'Age.................................................................. 15 General character..................................................... 15 Mineral and chemical composition................................. 15 Mineral constituents.......................................... 15 Relative proportions of minerals............................... 18 Quartzose phases. ..............................^............. 18 Fluidal cavities............................................... 19 Sodium and lithium phases................................... 20 Muscovite -
Triphylite Li(Fe , Mn )PO4 C 2001-2005 Mineral Data Publishing, Version 1
2+ 2+ Triphylite Li(Fe , Mn )PO4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. Crystals rare, typically prismatic, with large {011}, {100}, {010}, {021}, {120}, several other forms. Commonly subhedral, to 6.5 m, cleavable, compact, massive. Physical Properties: Cleavage: {100}, perfect; {010}, imperfect; {011}, interrupted. Fracture: Uneven to subconchoidal. Hardness = 4–5 D(meas.) = 3.50–3.58 D(calc.) = 3.562 Optical Properties: Transparent to translucent. Color: Bluish gray to greenish gray; brownish to black where altered. Streak: White to grayish white. Luster: Vitreous to subresinous. Optical Class: Biaxial (+). Orientation: X = a or c; Y = c or b; Z = b or a. Dispersion: r<v, strong. α = 1.675–1.694 β = 1.684–1.695 γ = 1.685–1.700 2V(meas.) = 0◦–55◦ Cell Data: Space Group: P mnb. a = 6.0285(6) b = 10.3586(9) c = 4.7031(3) Z = 4 X-ray Powder Pattern: Palermo #1 mine, New Hampshire, USA. 3.008 (100), 2.525 (81), 4.277 (76), 3.487 (70), 5.175 (34), 2.781 (34), 3.923 (26) Chemistry: (1) (2) P2O5 44.76 45.11 Fe2O3 1.07 FeO 30.05 22.84 MnO 12.40 22.55 MgO 0.72 CaO 0.34 Li2O 8.33 9.50 H2O 0.25 insol. 1.55 Total 99.47 100.00 (1) “Central Asia”, Russia. (2) Li(Fe, Mn)PO4 with Mn:Fe = 1:1. Mineral Group: Forms a series with lithiophilite. Occurrence: The most abundant primary phosphate in complex zoned granite pegmatites. -
Roscherite-Group Minerals from Brazil
■ ■ Roscherite-Group Minerals yÜÉÅ UÜté|Ä Daniel Atencio* and José M.V. Coutinho Instituto de Geociências, Universidade de São Paulo, Rua do Lago, 562, 05508-080 – São Paulo, SP, Brazil. *e-mail: [email protected] Luiz A.D. Menezes Filho Rua Esmeralda, 534 – Prado, 30410-080 - Belo Horizonte, MG, Brazil. INTRODUCTION The three currently recognized members of the roscherite group are roscherite (Mn2+ analog), zanazziite (Mg analog), and greifensteinite (Fe2+ analog). These three species are monoclinic but triclinic variations have also been described (Fanfani et al. 1977, Leavens et al. 1990). Previously reported Brazilian occurrences of roscherite-group minerals include the Sapucaia mine, Lavra do Ênio, Alto Serra Branca, the Córrego Frio pegmatite, the Lavra da Ilha pegmatite, and the Pirineus mine. We report here the following three additional occurrences: the Pomarolli farm, Lavra do Telírio, and São Geraldo do Baixio. We also note the existence of a fourth member of the group, an as-yet undescribed monoclinic Fe3+-dominant species with higher refractive indices. The formulas are as follows, including a possible formula for the new species: Roscherite Ca2Mn5Be4(PO4)6(OH)4 • 6H2O Zanazziite Ca2Mg5Be4(PO4)6(OH)4 • 6H2O 2+ Greifensteinite Ca2Fe 5Be4(PO4)6(OH)4 • 6H2O 3+ 3+ Fe -dominant Ca2Fe 3.33Be4(PO4)6(OH)4 • 6H2O ■ 1 ■ Axis, Volume 1, Number 6 (2005) www.MineralogicalRecord.com ■ ■ THE OCCURRENCES Alto Serra Branca, Pedra Lavrada, Paraíba Unanalyzed “roscherite” was reported by Farias and Silva (1986) from the Alto Serra Branca granite pegmatite, 11 km southwest of Pedra Lavrada, Paraíba state, associated with several other phosphates including triphylite, lithiophilite, amblygonite, tavorite, zwieselite, rockbridgeite, huréaulite, phosphosiderite, variscite, cyrilovite and mitridatite. -
Wyllieitej Na2fe~~1 [P04 ]31 a New Species by Paul B
WyllieiteJ Na2Fe~~1 [P04 ]31 A New Species by Paul B. Moore, Department of the Geophysical Sciences, The University of Chicago, Chicago, Illinois 60637 and Jun Ito Department of Geological Sciences, Harvard University, Cambridge, Massachusetts 02138 INTRODUCTION mention that optical studies indicated a 7(n:, triphylite the After two field and collecting excursions to 102 Black composition. We have good evidence that this phase was Hills pegmatites in the summers of 1971 and 1972, it be indeed the wyllieite. A 70% triphylite would have a ml'an he came clear that the Victory mine pegmatite was chemi index of refraction around 1.695, the value found hy Pe cally unique, so peculiar in fact that a major mineralogical cora and Fahey (1949) for their "triphylitc" fWIll the Vic m. investigation is now in progress. Not only is the pegmatite tory mine, the sample of which we found to hc in fact not ile of interest to the mineralogist for an unusual abundance triphylite but wyllieite. This index of refraction i~ practi >cr· ., of Na-rich primary phosphates rarely encountered else cally identical to our observations on wyllicite. Finally. where, but the textures of the cocrystallizing phases are we remark that our wyllieite specimcns show abundant in themselves a source of interest to petrologists as well. coarse quartz and perlhile as well as the pl;lgioda~e, ~ug Our account concerns a new species which evidently oc gesting that the mineral crystallized toward the end of thl! curred in considerable abundance during operation of the wall zone formation and during early core cot1\olidation. -
WOLFEITE, XANTHOXENITE, and WHITLOCKITE from the PALERMO MINE, NEW HAMPSHIRE* Crunono Fronorr-,E Araard
WOLFEITE, XANTHOXENITE, AND WHITLOCKITE FROM THE PALERMO MINE, NEW HAMPSHIRE* Crunono FRoNoRr-,E araard. LI nia er sity, Cambri d, ge, M assachus ett s. Assrnncr Xanthoxenite, hitherto known only from Rabenstein, Bavaria,on the basis of a partial description, occurs abundantly at the palermo mine. Composition: Ca2Fe///(pOtr(OH) 'l}HrO from the analysis: CaO 24.99,MgO 0.91, MnO 4.55, Fe2O327.6g,AlrO3 0.01, pros 37.62,H2o+9.13, Hro-0.86, insol.0.78; total 100.53.As crusts or massesof indistinct Wor,rBrrB This mineral was first noticed by professor C. W. Wolfe of Boston Uni- versity and was tentatively identified by him as triploidite. The mineral is a hydrothermal replacement of the triphylite and is associatedwith * Contribution from the Department of Mineralogy and petrography, Harvard Uni- versity, No. 306. 692 NEW HAMPSHIRE WOLFEITE, XANTHOXENITE, WHITLOCKITR 693 indistinct veinlets containing chlorite, sphalerite, pyrite and arsenopy- rite. Several months later further operations in the quarry exposed another large triphylite crystal that had been partly reworked hydro- thermally into a granular aggregate composed of residual triphylite, siderite, qu.attz,apatite, plagioclase,ludlamite and abundant columnar- fibrous massesof a dark clove-brown mineral. The latter mineral was f ound by the writer to afiord an n-ray powder pattern identical with that of triploidite, but with smaller cell dimensions, and the indices of refrac- tion proved to be considerably higher than those of the Branchville triploidite. These facts, together with the occurrence of the mineral as an alteration product of triphylite, rather than of lithiophilite as at Branchville, suggestedthat the material was the iron analogue of trip- loidite. -
JAN 2 2 200! This Document Consists of 71 Pages, Plus 1 Figures, Series A
T7' IN REPLY REFER TO: UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY WASHINGTON 25, D. C. AEC - 430/5 February 14, 1955 Mr, Robert D 0 Niiiinger, Acting Assistant Director Division of Raw Materials U, S* Atomic Energy Commission Washington 25, D. C. Dear Bobs Transmitted herewith are three copies of TEI-478, "Pegmatites and associated rocks in the Newry Hill area, Oxford County, Maine, 11 by the late Vincent £, Shainin and Louis F. Dellwig, November 1954- We are asking Mr. Hosted to approve our plan to submit this report for publication as a bulletin of the Maine Geological Survey. In the published version, tonnage estimates will be deleted from the section entitled "Mineral deposits." Sincerely yours, f ^"^—-H - o-u^ -H>-TW.P H. Bradley Chief Geologist JAN 2 2 200! This document consists of 71 pages, plus 1 figures, Series A UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Vinaettt E. Snainin and Louis F. Dell wig November 1954 Trace Elements Investigations Report 478 This preliminary report is distributed without editorial and technical review for conformity with official standards and nomenclature,, It is not for public inspection or quotation. *This report concerns work done partly on behalf of the Division of Raw Materials of the U. S, Atomic Energy Commission and in cooperation with the Maine Geological Survey. USGS - TEI-478 GEOLOGY AND MINERALOGY Distribution (Series A) No,... of copies Argonne National Laboratory ............. *...„. .....to... ...,,. «, 1 Atomic Energy Commission, Washington ......... ...............a.... 2 Division of Raw Materials,, Albuquerque ............................. 1 Division of Raw Materials, Bufte ......•••....eo....o.»«...o..«.« « 1 Division of Raw Materials, Casper .............................. -
Triploidite (Mn2+,Fe2+)2(PO4)(OH)
2+ 2+ Triploidite (Mn , Fe )2(PO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. As prismatic crystals, elongated and striated k [001], to 1 mm, columnar to parallel fibrous, may be spherulitic to divergent fibrous; rarely granular. Physical Properties: Cleavage: {100}, good; {120}, fair; {010}, poor. Fracture: Uneven to subconchoidal. Hardness = 4.5–5 D(meas.) = 3.70 D(calc.) = [3.80] Optical Properties: Transparent to translucent. Color: Pinkish brown, wine-yellow, yellowish brown, red-orange; pale pink in transmitted light. Streak: White, nearly. Luster: Vitreous, adamantine, greasy. Optical Class: Biaxial (+); abnormal interference colors due to strong dispersed extinction. Pleochroism: Faint in thick grains. Orientation: X = b; Z ∧ c =4◦–14◦. Dispersion: r> v, very strong. Absorption: Z > X = Y. α = 1.709–1.735 β = [1.710]–1.736 γ = 1.714–1.740 2V(meas.) = ∼50◦ ◦ Cell Data: Space Group: P 21/a. a = 12.366 b = 13.276 c = 9.943 β = 108.23 Z=16 X-ray Powder Pattern: Branchville, Connecticut, USA; close to wolfeite. 2.94 (10), 3.10 (9), 3.19 (8), 1.80 (6), 3.41 (5), 2.58 (5), 2.31 (5) Chemistry: (1) (2) (3) P2O5 32.11 28.54 31.86 As2O5 3.64 SiO2 0.68 FeO 14.88 0.03 32.25 MnO 48.45 59.16 31.85 CaO 0.33 0.34 H2O 4.08 [7.61] 4.04 Total 99.85 [100.00] 100.00 (1) Branchville, Connecticut, USA. (2) Wheal Owles, England; H2O by difference, corresponds • to (Mn1.95Ca0.01Si0.03)Σ=1.99[(P0.94As0.07)Σ=1.01O4](OH)1.00 0.49H2O. -
Huréaulite Mn
2+ • Hur´eaulite Mn5 (PO4)2(PO3OH)2 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals long to short prismatic, elongated along [001], with {100}, {110}, or tabular {100}, to 3 cm, may be equant; in bundled fascicles, less commonly fibrous, scaly, compact, massive. Physical Properties: Cleavage: On {100}, good. Hardness = 3.5 D(meas.) = 3.15–3.19 D(calc.) = 3.19 Optical Properties: Transparent to translucent. Color: Light pink, rose-violet, pale rose, amber, orange, red-orange, red, brownish orange, reddish to yellowish brown. Streak: Nearly white. Luster: Vitreous, inclined towards greasy. Optical Class: Biaxial (–). Pleochroism: X = colorless; Y = yellow to pale rose; Z = reddish yellow to reddish brown. Orientation: X = b; Z ∧ c =75◦. Dispersion: r< v,very strong, crossed. α = 1.647–1.654 β = 1.654–1.662 γ = 1.660–1.667 2V(meas.) = 75◦–82◦ Cell Data: Space Group: C2/c (synthetic). a = 17.587(4) b = 9.127(3) c = 9.497(5) β =96.68(3)◦ Z=4 X-ray Powder Pattern: Stewart mine, Pala, California, USA. (ICDD 34-146). 3.152 (100), 8.09 (70), 2.992 (65), 8.75 (40), 2.630 (40), 4.545 (35), 3.198 (30) Chemistry: (1) (2) (3) (1) (2) (3) P2O5 38.00 38.09 38.96 MgO 0.30 FeO 11.10 20.65 CaO 0.38 MnO 32.85 28.72 48.68 H2O 18.00 [11.86] 12.36 Total 99.95 [100.00] 100.00 (1) Hur´eaux, France. (2) S˜aoJose de Safira, Brazil; by electron microprobe, average of three • analyses, total Fe as FeO, H2O by difference. -
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American Mineralogist, Volume 59, pages 896-899, 1974 Metavivianite,Fe.(POu),.8HrO, a New Mineral' Cnlnrps Rrrz Department of Chemistry, Entc J. EssnNn,,c,Nu DoNlr,D R. PEAcoR Department of Geology and Mineralogy, The Uniaersity of Michigan, Ann Arbor, Michigan 48104 Abstract Metavivianite, Fe*(POn),'8H,O, is a new mineral occurring with kryzhanovskitein solution cavities in triphylite at the Big Chief pegmatite near Glendale, South Dakota. It is triclinic, - - - with a 7.814, b 9.084., c 4.65A, a - 94.77",F - 97.15",r - 107.37",and is isostructural with symplesite, Fe"(AsO.),.EH,O. Electron probe analysis indicates that it is a polymorph of vivianite. Vivianite and parasymplesite are therefore isostructural, monoclinic dimorphs cif the isoetructural and triclinic minerals metavivianite and symplesite. fntroduction the two phosphatesand the two arsenates.Type The pegmatitesof the Black Hills, South Dakota, material of metavivianite is present in the collec- are well known as sourcesof a variety of primary tions of the U. S. National Museum (Smithsonian and secondaryphosphates. In 1969, Dr. David Institution) and the Department of Geology and Garske of the South Dakota School of Mines kindly Mineralogy, The University of Michigan. The min- donated to us specimens of phosphate minerals eral and the name have been approved by the which are products of the alteration of triphylite. I.M.A. Commissionon New Minerals and Mineral Crystals from one of these specimenswere used Names. in a single-crystal study, with preliminary results Occurrence indicating that they were triclinic, and similar to symplesite,Fes(AsOa)2.8II2O. However, chemical The mineral occurs on one specimen collected analysisindicated the presenceof P but no As. -
Vibrational Spectroscopy of the Phosphate Mineral Lazulite €“ (Mg
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 107 (2013) 241–247 Contents lists available at SciVerse ScienceDirect Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy journal homepage: www.elsevier.com/locate/saa Vibrational spectroscopy of the phosphate mineral lazulite – (Mg, Fe)Al2(PO4)2Á(OH)2 found in the Minas Gerais, Brazil ⇑ Ray L. Frost a, , Yunfei Xi a, Martina Beganovic b, Fernanda Maria Belotti c, Ricardo Scholz b a School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia b Geology Department, School of Mines, Federal University of Ouro Preto, Campus Morro do Cruzeiro, Ouro Preto, MG 35400-00, Brazil c Federal University of Itajubá, Campus Itabira, Itabira, MG 35903-087, Brazil highlights graphical abstract " In this work, we have studied the structure of lazulite. " Lazulite is pegmatite phosphate with calculated formula (Fe0.11)Al1.86(PO4)2.08(OH)2.04. " The structure of lazulite was assessed using a combination of Raman and infrared spectroscopy. article info abstract Article history: This research was done on lazulite samples from the Gentil mine, a lithium bearing pegmatite located in the Received 20 September 2012 municipality of Mendes Pimentel, Minas Gerais, Brazil. Chemical analysis was carried out by electron Received in revised form 6 November 2012 microprobe analysis and indicated a magnesium rich phase with partial substitution of iron. Traces of Ca Accepted 23 January 2013 and Mn, (which partially replaced Mg) were found. The calculated chemical formula of the studied sample Available online 1 February 2013 is: (Mg0.88,Fe0.11)Al1.87(PO4)2.08(OH)2.02. -
Revision 1 Single-Crystal Neutron Diffraction and Mössbauer Spectroscopic Study of Hureaulite, (Mn,Fe)5(PO4)2(HPO4)2(H2O)4
Revision_1 Single-crystal neutron diffraction and Mössbauer spectroscopic study of hureaulite, (Mn,Fe)5(PO4)2(HPO4)2(H2O)4 Running title: Crystal chemistry of hureaulite Abstract Introduction Sample description and mineralogy Experimental methods: 1) Chemical analysis 2) Single-crystal X-ray and neutron diffraction experiment 3) Mössbauer spectroscopy Results: Neutron structure refinement of hureaulite Results: Mössbauer spectrum of hureaulite Discussion Concluding remarks Acknowledgements References Table and Figure captions Corresponding author: G. Diego GATTA Dipartimento di Scienze della Terra, Università degli Studi di Milano, Via Botticelli 23, I-20133 Milano, Italy Email: [email protected] Tel. : +39 02 503 15607 Fax: +39 02 503 15597 Submitted to European Journal of Mineralogy Single-crystal neutron diffraction and Mössbauer spectroscopic study of hureaulite, (Mn,Fe)5(PO4)2(HPO4)2(H2O)4 G. Diego Gatta1,2, Günther J. Redhammer3, Pietro Vignola1,4 Martin Meven5, Garry J. McIntyre6 1 Dipartimento di Scienze della Terra, Università degli Studi di Milano, Via Botticelli 23, I-20133 Milano, Italy 2CNR - Istituto di Cristallografia, Via G. Amendola 122/o, Bari, Italy 4Abteilung für Mineralogie, FB Materialforschung & Physik, Universität Salzburg, Hellbrunnerstr. 34/III, 5020 Salzburg, Austria 3 CNR-Istituto per la Dinamica dei Processi Ambientali, Milano, Italy 5Institut für Kristallographie, RWTH Aachen, and Jülich Centre for Neutron Science (JCNS), Forschungszentrum Jülich GmbH, at Heinz Maier-Leibnitz Zentrum (MLZ), Lichtenbergstasse