MADE in the USA Powering America’S Clean Energy Transition

Total Page:16

File Type:pdf, Size:1020Kb

MADE in the USA Powering America’S Clean Energy Transition LITHIUM – MADE IN THE USA Powering America’s Clean Energy Transition :PLL :PLL ABN 50 002 664 495 September 2020 OUR PURPOSE CORPORATE SNAPSHOT To provide the domestic lithium required for PIEDMONT LITHIUM LIMITED America’s transition to a clean energy future Shares / ADRs (1 ADR = 100 Shares) 11.5 M 1,155.3 M Price (@ 8/28/20) $6.05 A$0.09 Average Daily Trading Volume (30-day) $620,000 A$103,000 Market Cap (@ 8/28/20) 1 $69 M A$99 M Founded in 2016 – Headquartered in Belmont, NC, USA Cash (@ 6/30/20) 1 $26 M A$36 M 1 – Pro forma for the placement which closed 8/4/20 Listed on NASDAQ and ASX – Symbol PLL KEY SHAREHOLDERS Australian Super 13% Fidelity 9% Plan to Produce Lithium Hydroxide from Spodumene Officers and Directors 8% United States ADR Program 24% Ideally Located to Address China’s Market Dominance BOARD OF DIRECTORS Ian Middlemas Australia Chairman Keith D. Phillips USA President & CEO World-Class Business in Scale and Economics Anastasios Arima USA Director Jeff Armstrong USA Director Jorge Beristain USA Director Strong Cash Position Levi Mochkin Australia Director RESEARCH COVERAGE Trading at Steep Discount to NPV and Peer Group 2 : PLL : PLL THE PIEDMONT VALUE PROPOSITION . Electric vehicle (EV) penetration projected to grow from ~3% to ~30% by 2030 Electric Vehicle Demand Accelerating . EV equities are at all-time highs as investors price in the electrification mega-trend . Volkswagen describes lithium as the ‘irreplaceable element of the electric era’ EVs Require Lithium . Other materials can vary but a relatively stable lithium content is required in all Li-ion batteries . Lithium hydroxide (LiOH) is required for high-nickel batteries in longer-range vehicles Lithium Hydroxide is Taking Share . LiOH demand expected to grow 21% per year through 2040 . Piedmont will produce LiOH from spodumene, the feedstock preferred by western OEMs Spodumene the Preferred Feedstock . Piedmont has a large, high-grade spodumene resource on the Carolina Tin-Spodumene Belt . China produces ~83% of the world’s lithium hydroxide OEMs Seeking Ex-China Supply . Piedmont is developing the only conventional lithium project in the United States . Project is world-class in terms of scale and economics with NPV of $1.1B for integrated project World-Class Project . Business model is uniquely scalable given US location and global availability of spodumene . PLL trades at <10% of net present value and at a significant discount to key comparables Piedmont is Attractively Valued . $26M cash position to drive project forward to construction LITHIUM HYDROXIDE…FROM SPODUMENE…IN THE UNITED STATES 3 : PLL : PLL ELECTRIFICATION IS A GLOBAL MEGA-TREND ELECTRIC VEHICLE PENETRATION 80.0% . EVs are superior vehicles 70.0% ‐ Smoother, quieter, faster 60.0% . EVs reduce emissions 50.0% ‐ 2/3 lower greenhouse gas emissions vs. ICEs 40.0% 30.0% . EVs are lower cost ‐ Far cheaper to fuel and 20.0% maintain 10.0% 0.0% Tesla Model 3 4 Source: Benchmark Minerals Intelligence : PLL : PLL EV DEMAND IS DRIVEN BY ECONOMICS LI-ION BATTERY COSTS DOWN 87% SINCE 2010 EV SELLING PRICES PROJECTED TO FALL DUE TO LOWER BATTERY COSTS (PACK PRICE - REAL 2019 $/KWH) $1,200 $45,000 250 Mile Range EV Price Toyota Camry MSRP $40,000 $1,000 -22% $35,000 $800 $30,000 -21% -8% $25,000 $600 -11% $20,000 $400 -35% $15,000 -23% -26% $10,000 -18% $200 -13% $5,000 $0 $0 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2018 2020 2022 2024 : PLL : PLL 5 Source: Bloomberg New Energy Finance https://about.bnef.com/blog/behind-scenes-take-lithium-ion-battery-prices Source: ARK Innovation – Big Ideas 2020 SUPPORTIVE POLICY DRIVING EUROPEAN EV SALES EU CO2 EMISSIONS PENALTIES 2021 4 YEAR CONSUMER OWNERSHIP COSTS EV SALES GROWTH IN EUROPE $45.0 40,000 € 3,000 € 5,000 € 4,000 € bonus by JUNE YTD YTD YTD $39.1 $39.1 bonus by bonus by government 2020 2020 2019 CHANGE $40.0 government + 35,000 € government + 2,000 € + Sweden 26% 26% 11% 136% 6,000 € 1,000 € bonus by car 7,000 € 1,000 € bonus by bonus by car manufacturers $35.0 bonus by bonus by car government manufacturers government manufacturers Netherlands 16% 13% 9% 78% 30,000 € + $28.8 3,000 € $30.0 bonus by car Other 11% 11% 6% 83% manufacturers Australia Spain 25,000 € France Italy $25.0 $22.8 United Kingdom 10% 8% 2% 400% Germany BILLIONS $18.8 20,000 € $20.0 France 9% 9% 2% 350% $15.2 Germany 9% 8% 3% 200% $15.0 15,000 € $11.8 AVERAGE 8% 8% 3% 167% $10.0 $8.6 10,000 € $5.6 Belgium 7% 7% 3% 133% $5.0 $2.8 $1.5 Austria 6% 6% 3% 100% $0.6 5,000 € $0.0 Italy 3% 3% 1% 200% 0 € Spain 3% 3% 1% 200% VW e-Golf VW e-Golf VW e-Golf VW e-Golf VW e-Golf VW e-Golf VW e-Golf (Recovery (Recovery (Recovery (Recovery (Recovery Gasoline Poland 1% 1% 0% 100% Package) Package) Package) Package) Package) 6 Source: HSBC, Macquarie, JATO Source: International Council on Clean Transportation Source: International Council on Clean Transportation SUPPORTIVE POLICIES IN THE USA 7 : PLL : PLL TESLA MODEL 3 THE #1 SELLER IN THE UNITED STATES SMALL + MIDSIZE LUXURY CAR SALES - H1 2020 38,314 Tesla Model 3 38,195 BMW 2 + 3 + 4 + 5 Series 33,509 Mercedes C/CLA/CLS/E-Class 27,382 Audi A3 + A4 + A5 + A6 24,941 Lexus ES + GS + IS + RC 18,861 Tesla Model Y 11,043 Infiniti Q50 + Q60 + Q70 9,815 Acura RLX + TLX 9,043 Lincoln Continental MKZ 8,383 Chrysler 300 7,624 Volvo 60 + 90 6,615 Cadillac CT5 + CT6 + CTS + XTS 6,393 Genesis G70 + G80 3,451 Alfa Romeo Guilia 0 5,000 10,000 15,000 20,000 25,000 30,000 35,000 40,000 Tesla Model 3 sales are a highly informed estimate : PLL : PLL 8 Chart: Clean Technica | Source: Automakers, Clean Technica VW ID.3 (2020) IT’S NOT JUST TESLA # OF EVS LAUNCHED BY 2025 . Major auto companies VW 80 are all-in on electric BMW 47 vehicles Geely 41 Mustang MachE ‐ 400+ new EV models coming (2021) to market by 2025 Changan 34 FCA 32 Rivian Trucks (2022) . Mass market vehicles SAIC 30 coming for the first time Ford 28 ‐ Ford to produce electric F-150 HMC-KIA 23 “before 2022” GM 20 ‐ VW ID.3 launching in 2020 RNM Alliance 12 ‐ Renault producing $9,000 EV Peugeot 11 Porsche Taycan for Indian market (2020) Toyota 10 Daimler 10 020406080 9 Source: Bloomberg New Energy Finance Electric Vehicle Outlook 2019 : PLL : PLL EQUITY MARKETS ARE PAYING UP FOR EV EQUITIES YTD SHARE PRICE PERFORMANCE . EV equities outperforming ‐ TSLA and others up >200% ytd 434% WKHS . EVs dominating the SPAC market 415% TSLA 397% NIO 302% NKLA . Private capital investing aggressively ‐ Rivian has raised $5.35B in past 18 months 299% FUV . Battery raw materials stocks lagging 287% BLNK ‐ LIT ETF up only 40% ytd, largely driven by TSLA 43% LIT 0% 100% 200% 300% 400% 500% 10 : PLL : PLL YOU CAN’T HAVE EVS WITHOUT LITHIUM “LITHIUM: THE IRREPLACEABLE ELEMENT OF THE ELECTRIC ERA” (VW) LITHIUM CHEMICAL DEMAND 2020-2040 6,000,000 LITHIUM Lithium Carbonate Demand (t/y) is the lightest and most energy-dense Lithium Hydroxide Demand (t/y) metal, making it ideal for energy 5,000,000 storage applications 4,000,000 LITHIUM HYDROXIDE is required in the high-nickel cathode materials used in longer-range EVs 3,000,000 2,000,000 LiOH SHORTAGES are expected by 2023 TONNES OF LITHIUM CARBONATE EQUIVALENT (LCE) OF TONNES 1,000,000 CHINA Produces the vast majority of the - world’s lithium hydroxide 2020 2025 2030 2035 2040 Source: Benchmark Mineral Intelligence 11 SPODUMENE THE PREFERRED FEEDSTOCK SPODUMENE IS THE LOW- MAJOR AUTO COMPANIES COST SOURCE FOR PREFER SPODUMENE- LITHIUM HYDROXIDE SOURCED HYDROXIDE Raw Material Carbonate Conversion Hydroxide Conversion 7,000 “Lithium extracted from mining … is commercially more attractive … more stable to 6,000 extract, easier to scale and generally more 5,000 2,000 sustainable.” VW –April 2019 4,000 2,100 3,000 “BMW signs contract with Ganfeng for 3,500 2,000 sustainable lithium from mines in Australia.” 3,000 BMW – November 2019 1,000 665 - Brine Spodumene Source: McKinsey & Co., costs represent indicative 2025 costs for typical South American brine operations and typical Western Australian spodumene operations. 12 WILMINGTON BALTIMORE PIEDMONT IDEALLY LOCATED IN THE WILMINGTON USA’S AUTO ALLEY… CHARLESTON SAVANNAH JACKSONVILLE HOUSTON NEW ORLEANS TAMPA BAY EVERGLADES 13 : PLL : PLL …AND CLOSE TO EUROPE’S GROWING BATTERY SUPPLY CHAIN 14 NORTH CAROLINA - THE CRADLE OF THE LITHIUM INDUSTRY USA #1 US State for PROJECT Business (Forbes ) 0% State Mining Royalties 23% Corporate Tax Rate ~100% of World Lithium Production from 1950s to the 1980s 15 : PLL : PLL TWO COMPLEMENTARY DEVELOPMENT SCENARIOS USA CHEMICAL PLANT PROJECT MERCHANT INTEGRATED Spodumene Supply Spodumene from Piedmont from the Market Mine / Concentrator Capacity of 22,700 t/y LiOH Capacity of 22,700 t/y LiOH 25 Year Chemical Plant Life 25 Year Mine & Chemical Plant Life World’s Lowest Cost Merchant Producer2 World’s Lowest Cost Producer2 $714M NPV – 26% IRR1 $1.1B NPV – 26% IRR1 $149M run rate EBITDA1 $218M run rate EBITDA1 Initial Capex – $377M1 Initial Capex - $545M1 1. Source: Estimated values previously announced in Company announcement “Chemical Plant PFS Demonstrates Exceptional Economics and Optionality of USA Location” dated May 26, 2020 2. Based on Roskill’s forecasted 2028 all-in sustaining cost curve for lithium hydroxide production : PLL : PLL 16 NC Advantage NORTH CAROLINA vs.
Recommended publications
  • Direct Preparation of Some Organolithium Compounds from Lithium and RX Compounds Katashi Oita Iowa State College
    Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1955 Direct preparation of some organolithium compounds from lithium and RX compounds Katashi Oita Iowa State College Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Organic Chemistry Commons Recommended Citation Oita, Katashi, "Direct preparation of some organolithium compounds from lithium and RX compounds " (1955). Retrospective Theses and Dissertations. 14262. https://lib.dr.iastate.edu/rtd/14262 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. INFORMATION TO USERS This manuscript has been reproduced from the microfilm master. UMI films the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter face, while others may be from any type of computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand comer and continuing from left to right in equal sections with small overiaps.
    [Show full text]
  • Manufacturing Scalability Implications of Materials Choice in Inorganic Solid-State Batteries Abstract Context & Scale Intro
    1 Manufacturing Scalability Implications of Materials Choice in Inorganic 2 Solid-State Batteries 3 Kevin J. Huang1, Gerbrand Ceder2, Elsa A. Olivetti1* 4 5 1Department of Materials Science & Engineering, MIT, Cambridge, MA 02139; 2Department of Materials 6 Science & Engineering, University of California Berkeley, Berkeley, CA 94720, USA 7 Abstract 8 The pursuit of scalable and manufacturable all-solid-state batteries continues to intensify, motivated by the 9 rapidly increasing demand for safe, dense electrical energy storage. In this Perspective, we describe the 10 numerous, often conflicting, implications of materials choices that have been made in the search for 11 effective mitigations to the interfacial instabilities plaguing solid-state batteries. Specifically, we show that 12 the manufacturing scalability of solid-state batteries can be governed by at least three principal 13 consequences of materials selection: (1) the availability, scaling capacity, and price volatility of the chosen 14 materials’ constituents, (2) the manufacturing processes needed to integrate the chosen materials into full 15 cells, and (3) the cell performance that may be practically achieved with the chosen materials and processes. 16 While each of these factors is, in isolation, a pivotal determinant of manufacturing scalability, we show that 17 consideration and optimization of their collective effects and tradeoffs is necessary to more completely 18 chart a scalable pathway to manufacturing. 19 Context & Scale 20 With examples pulled from recent developments in solid-state batteries, we illustrate the consequences of 21 materials choice on materials availability, processing requirements and challenges, and resultant device 22 performance. We demonstrate that while each of these factors is, by itself, essential to understanding 23 manufacturing scalability, joint consideration of all three provides for a more comprehensive understanding 24 of the specific factors that could impede the scale up to production.
    [Show full text]
  • Alteration of Spodumene, Montebrasite and Lithiophilite In
    American Mineralogist, Volume 67, pages 97-113, 1982 Alteration of spodumene,montebrasite and lithiophilite in pegmatites of the White PicachoDistrict, Arizona Davrp Lor.rooxrnNo DoNer-uM. Bunr Department of Geology Arizona State University Tempe, Arizona 85281 Abstract The crystallization sequence and metasomatic alteration of spodumene (LiAlSizOe), montebrasite(LiAIPO4(OH,F)), and lithiophilite (Li(Mn,Fe)PO+)are describedfor nine zoned lithium pegmatitesin the White Picacho district, Arizona. The observedcrystalliza- tion trends suggesta progressiveincrease in the activities of lithium species(spodumene follows microcline as the principal alkali aluminosilicate), as well as an increase in the activities of the acidic volatiles phosphorus and fluorine (montebrasite succeedsspodu- mene as the stableprimary lithium phase).Much of the lithiophilite occurs with columbite, apatite, beryl, zircon, and tourmaline in cleavelanditecomplexes that formed in part at the expenseof quartz-spodumenepegmatite. Fracture-controlledpseudomorphic alteration of the primary lithium minerals is widespread and apparently is the result of subsolidus reactionswith residualpegmatitic fluids. Spodumenehas been replacedby eucryptite, albite, and micas. Alteration products of montebrasite include low-fluorine secondary montebrasite,crandallite (tentative), hydroxylapatite, muscovite, brazilianite, augelite (tentative),scorzalite, kulanite, wyllieite, and carbonate-apatite.Secondary phases identi- fied in altered lithiophilite include hureaulite, triploidite, eosphorite,
    [Show full text]
  • Lithium in Lithium-Ion Batteries for Electric Vehicles
    Office of Industries Working Paper ID-069 July 2020 Global Value Chains: Lithium in Lithium-ion Batteries for Electric Vehicles Gregory M. LaRocca Abstract Lithium is an essential material in the production of lithium-ion batteries (LIBs), which power electric vehicles. This paper examines the global value chain (GVC) for lithium as part of a series of working papers that map out the global sources of mining, refining, and value-added for the key LIB materials. Results show that few countries have economically viable resources of the upstream raw materials that supply the lithium GVC. Most lithium-rich ores are exported from Australia to China for processing, while most lithium brine concentrates are exported from Chile to South Korea, Japan, and China for processing. The large inflows of lithium to China support its dominant position in the downstream refining process, which is where the largest share of value-added occurs. Consequently, China is capturing the largest shares of value-added along the lithium GVC, despite lacking in resource endowment. Disclaimer: Office of Industries working papers are the result of the ongoing professional research of USITC staff and solely represent the opinions and professional research of individual authors. These papers do not necessarily represent the views of the U.S. International Trade Commission or any of its individual Commissioners. U.S. International Trade Commission Global Value Chains: Lithium in Lithium-ion Batteries for Electric Vehicles Gregory M. LaRocca Office of Industries U.S. International Trade Commission (USITC) July 2020 The author is staff with the Office of Industries of the U.S.
    [Show full text]
  • Dilithium Sequestrene As Ananticoagulant
    J Clin Pathol: first published as 10.1136/jcp.12.3.254 on 1 May 1959. Downloaded from J. clin. Path. (1959), 12, 254. DILITHIUM SEQUESTRENE AS AN ANTICOAGULANT BY L. S. SACKER,* K. E. SAUNDERS,t BERYL PAGE, AND MARGARET GOODFELLOW From the Departments of Pathology, Dulwich and Lewisham Hospitals, London (RECEIVED FOR PUBLICATION SEPTEMBER 20, 1958) The variety of different anticoagulants used for Ethylene diamine tetra-acetic acid (E.D.T.A.), 29.2 blood samples has increased, but there is still need g., and 7.4 g. of lithium carbonate were intimately for a suitable anticoagulant for the routine mixed. Then 200 ml. of water was added and solution estimation of sodium and potassium by flame took place with vigorous evolution of carbon dioxide. photometry. So far the only satisfactory substance for this purpose has been the expensive calcium Method 2 heparin (King and Wootton, 1956). Disodium sequestrene (Proescher, 1951 ; Hadley E.D.T.A., 29.2 g., was dissolved in 200 ml. of normal and Larson, 1953) and dipotassium sequestrene lithium hydroxide solution (41.96 g. LiOH.H20 per are the most valuable of litre). (Hadley and Weiss, 1955) In both cases the resulting solution contained the the recently introduced anticoagulants for routine dilithium salt. haematological procedures because they preserve Dilithium sequestrene was obtained from these morphology of leucocytes for short periods the solutions after filtration to remove a small quantity copyright. better than the ammonium and potassium oxalate of amorphous debris, by precipitation on the addition mixture or heparin, and they prevent platelets of an equal volume of absolute methyl alcohol and clumping and preserve them.
    [Show full text]
  • Electrolyte Stability and Discharge Products of an Ionic-Liquid-Based Li-O2 Battery Revealed by Soft X-Ray Emission Spectroscopy
    Lawrence Berkeley National Laboratory Recent Work Title Electrolyte Stability and Discharge Products of an Ionic-Liquid-Based Li-O2 Battery Revealed by Soft X-Ray Emission Spectroscopy Permalink https://escholarship.org/uc/item/6gd3f1x1 Journal Journal of Physical Chemistry C, 123(51) ISSN 1932-7447 Authors León, A Fiedler, A Blum, M et al. Publication Date 2019-12-26 DOI 10.1021/acs.jpcc.9b08777 Peer reviewed eScholarship.org Powered by the California Digital Library University of California Electrolyte Stability and Discharge Products of an Ionic- Liquid-based Li-O2 Battery Revealed by Soft X-Ray Emission Spectroscopy Aline Léon*1, Andy Fiedler2, Monika Blum3,4, Wanli Yang4, Marcus Bär5,6,7, Frieder Scheiba2, Helmut Ehrenberg2, Clemens Heske1,3,8, and Lothar Weinhardt1,3,8 1) Institute for Photon Science and Synchrotron Radiation (IPS), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany 2) Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany 3) Department of Chemistry and Biochemistry, University of Nevada, Las Vegas (UNLV), NV 89154-4003, USA 4) Advanced Light Source (ALS), Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States 5) Department of Interface Design, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (HZB), Albert-Einstein-Str. 15, 12489 Berlin, Germany 6) Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy (HI ERN), Albert-Einstein-Str. 15, 12489 Berlin, Germany 1 7) Department of Chemistry and Pharmacy, Friedrich-Alexander- Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Erlangen, Germany 8) Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Engesserstr.
    [Show full text]
  • Lithium 2017
    2017 Minerals Yearbook LITHIUM [ADVANCE RELEASE] U.S. Department of the Interior September 2020 U.S. Geological Survey Lithium By Brian W. Jaskula Domestic survey data and tables were prepared by Annie Hwang, statistical assistant. In the United States, one lithium brine operation with an cobalt oxide and 2,160 kg of lithium-nickel-cobalt-aluminum associated lithium carbonate plant operated in Silver Peak, oxide (Defense Logistics Agency Strategic Materials, 2017). At NV. Domestic and imported lithium carbonate, lithium yearend 2017, the NDS held 540 kg of lithium-cobalt oxide and chloride, and lithium hydroxide were consumed directly 1,620 kg of lithium-nickel-cobalt-aluminum oxide. in industrial applications and used as raw materials for downstream lithium compounds. In 2017, lithium consumption Production in the United States was estimated to be equivalent to The U.S. Geological Survey (USGS) collected domestic 3,000 metric tons (t) of elemental lithium (table 1) [16,000 t production data for lithium from a voluntary canvass of the of lithium carbonate equivalent (LCE)], primarily owing to only U.S. lithium carbonate producer, Rockwood Lithium Inc. demand for lithium-based battery, ceramic and glass, grease, (a subsidiary of Albemarle Corp. of Charlotte, NC). Production pharmaceutical, and polymer products. In 2017, the gross weight and stock data collected from Rockwood Lithium were withheld of lithium compounds imported into the United States increased from publication to avoid disclosing company proprietary data. by 7% and the gross weight of exports increased by 29% from The company’s 6,000-metric-ton-per-year (t/yr) Silver Peak those in 2016.
    [Show full text]
  • Common Name: LITHIUM ALUMINUM HYDRIDE HAZARD
    Common Name: LITHIUM ALUMINUM HYDRIDE CAS Number: 16853-85-3 RTK Substance number: 1121 DOT Number: UN 1410 Date: April 1986 Revision: November 1999 ----------------------------------------------------------------------- ----------------------------------------------------------------------- HAZARD SUMMARY * Lithium Aluminum Hydride can affect you when * Exposure to hazardous substances should be routinely breathed in. evaluated. This may include collecting personal and area * Contact can cause severe skin and eye irritation and burns. air samples. You can obtain copies of sampling results * Breathing Lithium Aluminum Hydride can irritate the from your employer. You have a legal right to this nose and throat. information under OSHA 1910.1020. * Breathing Lithium Aluminum Hydride can irritate the * If you think you are experiencing any work-related health lungs causing coughing and/or shortness of breath. Higher problems, see a doctor trained to recognize occupational exposures can cause a build-up of fluid in the lungs diseases. Take this Fact Sheet with you. (pulmonary edema), a medical emergency, with severe shortness of breath. WORKPLACE EXPOSURE LIMITS * Exposure can cause loss of appetite, nausea, vomiting, The following exposure limits are for Aluminum pyro powders diarrhea and abdominal pain. (measured as Aluminum): * Lithium Aluminum Hydride can cause headache, muscle weakness, loss of coordination, confusion, seizures and NIOSH: The recommended airborne exposure limit is coma. 5 mg/m3 averaged over a 10-hour workshift. * High exposure can affect the thyroid gland function resulting in an enlarged thyroid (goiter). ACGIH: The recommended airborne exposure limit is * Lithium Aluminum Hydride may damage the kidneys. 5 mg/m3 averaged over an 8-hour workshift. * Lithium Aluminum Hydride is a REACTIVE CHEMICAL and an EXPLOSION HAZARD.
    [Show full text]
  • Lithium Aluminum Hydride
    Lithium aluminum hydride sc-215254 Material Safety Data Sheet Hazard Alert Code EXTREME HIGH MODERATE LOW Key: Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Lithium aluminum hydride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. NFPA FLAMMABILITY4 HEALTH3 HAZARD INSTABILITY2 W SUPPLIER Santa Cruz Biotechnology, Inc. 2145 Delaware Avenue Santa Cruz, California 95060 800.457.3801 or 831.457.3800 EMERGENCY ChemWatch Within the US & Canada: 877-715-9305 Outside the US & Canada: +800 2436 2255 (1-800-CHEMCALL) or call +613 9573 3112 SYNONYMS Li-Al-H4, Al-H4-Li, "lithium aluminum hydride", "lithium aluminum tetrahydride", "lithium aluminium tetrahydride", "lithium tetrahydroaluminate", "aluminate, tetrahydro-, lithium", "lithium aluminohydride", "aluminum lithium hydride", "lithium alanate", LAH Section 2 - HAZARDS IDENTIFICATION CHEMWATCH HAZARD RATINGS Min Max Flammability 4 Toxicity 2 Body Contact 4 Min/Nil=0 Low=1 Reactivity 2 Moderate=2 High=3 Chronic 2 Extreme=4 CANADIAN WHMIS SYMBOLS 1 of 10 CANADIAN WHMIS CLASSIFICATION CAS 16853-85-3Lithium tetrahydroaluminate E-Corrosive Material EMERGENCY OVERVIEW RISK Causes severe burns. Risk of serious damage to eyes. Reacts violently with water liberating extremely flammable gases. Extremely flammable. POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED ■ The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion. ■ Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of the mucous membranes, profuse saliva production, with an inability to speak or swallow. Both the oesophagus and stomach may experience burning pain; vomiting and diarrhoea may follow. ■ Accidental ingestion of the material may be damaging to the health of the individual.
    [Show full text]
  • Chemical List
    1 EXHIBIT 1 2 CHEMICAL CLASSIFICATION LIST 3 4 1. Pyrophoric Chemicals 5 1.1. Aluminum alkyls: R3Al, R2AlCl, RAlCl2 6 Examples: Et3Al, Et2AlCl, EtAlCl2, Me3Al, Diethylethoxyaluminium 7 1.2. Grignard Reagents: RMgX (R=alkyl, aryl, vinyl X=halogen) 8 1.3. Lithium Reagents: RLi (R = alkyls, aryls, vinyls) 9 Examples: Butyllithium, Isobutyllithium, sec-Butyllithium, tert-Butyllithium, 10 Ethyllithium, Isopropyllithium, Methyllithium, (Trimethylsilyl)methyllithium, 11 Phenyllithium, 2-Thienyllithium, Vinyllithium, Lithium acetylide ethylenediamine 12 complex, Lithium (trimethylsilyl)acetylide, Lithium phenylacetylide 13 1.4. Zinc Alkyl Reagents: RZnX, R2Zn 14 Examples: Et2Zn 15 1.5. Metal carbonyls: Lithium carbonyl, Nickel tetracarbonyl, Dicobalt octacarbonyl 16 1.6. Metal powders (finely divided): Bismuth, Calcium, Cobalt, Hafnium, Iron, 17 Magnesium, Titanium, Uranium, Zinc, Zirconium 18 1.7. Low Valent Metals: Titanium dichloride 19 1.8. Metal hydrides: Potassium Hydride, Sodium hydride, Lithium Aluminum Hydride, 20 Diethylaluminium hydride, Diisobutylaluminum hydride 21 1.9. Nonmetal hydrides: Arsine, Boranes, Diethylarsine, diethylphosphine, Germane, 22 Phosphine, phenylphosphine, Silane, Methanetellurol (CH3TeH) 23 1.10. Non-metal alkyls: R3B, R3P, R3As; Tributylphosphine, Dichloro(methyl)silane 24 1.11. Used hydrogenation catalysts: Raney nickel, Palladium, Platinum 25 1.12. Activated Copper fuel cell catalysts, e.g. Cu/ZnO/Al2O3 26 1.13. Finely Divided Sulfides: Iron Sulfides (FeS, FeS2, Fe3S4), and Potassium Sulfide 27 (K2S) 28 REFERRAL
    [Show full text]
  • Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: a Review
    resources Review Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: A Review Laurence Kavanagh * , Jerome Keohane, Guiomar Garcia Cabellos, Andrew Lloyd and John Cleary EnviroCORE, Department of Science and Health, Institute of Technology Carlow, Kilkenny, Road, Co., R93-V960 Carlow, Ireland; [email protected] (J.K.); [email protected] (G.G.C.); [email protected] (A.L.); [email protected] (J.C.) * Correspondence: [email protected] Received: 28 July 2018; Accepted: 11 September 2018; Published: 17 September 2018 Abstract: Lithium is a key component in green energy storage technologies and is rapidly becoming a metal of crucial importance to the European Union. The different industrial uses of lithium are discussed in this review along with a compilation of the locations of the main geological sources of lithium. An emphasis is placed on lithium’s use in lithium ion batteries and their use in the electric vehicle industry. The electric vehicle market is driving new demand for lithium resources. The expected scale-up in this sector will put pressure on current lithium supplies. The European Union has a burgeoning demand for lithium and is the second largest consumer of lithium resources. Currently, only 1–2% of worldwide lithium is produced in the European Union (Portugal). There are several lithium mineralisations scattered across Europe, the majority of which are currently undergoing mining feasibility studies. The increasing cost of lithium is driving a new global mining boom and should see many of Europe’s mineralisation’s becoming economic. The information given in this paper is a source of contextual information that can be used to support the European Union’s drive towards a low carbon economy and to develop the field of research.
    [Show full text]
  • Synthesis of Lithium Peroxide from Hydrogen Peroxide and Lithium Hydroxide in Aqueous-Organic Medium: Wasteless Technology
    MATEC Web of Conferences 96, 00004 (2017) DOI: 10.1051/ matecconf/20179600004 REE-2016 Synthesis of Lithium Peroxide from Hydrogen Peroxide and Lithium Hydroxide in Aqueous-Organic Medium: Wasteless Technology Roman Nefedov* and Yury Ferapontov Tambov State Technical University, Tambov, Russia Abstract. Lithium is a rare element, and widely used in manufacturing, electronics, medicine, and etc. One of the important lithium compounds is lithium peroxide. It is a component of regenerating products to protect the human respiratory system from damaging factors of chemical and biological nature. This paper describes the methods of obtaining the lithium peroxide. All industrial techniques for the synthesis of lithium peroxide are presented. A critical assessment of these techniques is given. A new wasteless synthesis technology of lithium peroxide from Hydrogen Peroxide and Lithium Hydroxide in Aqueous-Organic Medium is presented. This technology allows obtaining the pure product containing Li2O2 up to 94 %. The possibility of the solvent regeneration by the anhydrous lithium hydroxide has been shown. The yield of the lithium – 98 % and a significant reduction in solvent consumption per unit of finished product has been obtained. 1 Introduction The use of ethanol is not a prerequisite for obtaining lithium peroxide, although it is beneficial in terms of that The inorganic peroxide compounds based on rare, lithium peroxide contained in it unlike other organic radioactive, and especially alkali metals have a wide substances practically insoluble (dissolved in methanol range of industrial applications (e.g., energy storage and about 3.5 g/L Li2O2. Ethanol can be replaced by other oxygen source, etc.) [1, 2]. organic solvents (methanol, pyridine, propanol, kenotic An identifying characteristic of inorganic peroxide and others [12, 14]).
    [Show full text]