Theories of Intramolecular Vibrational Energy Transfer
THEORIES OF INTRAMOLECULAR VIBRATIONAL ENERGY TRANSFER T. UZER School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332-0430, USA and Bilkent University. Ankara, Turkey with an appendix by W.H. MILLER Department of Chemistry, and Materials and Molecular Research Division of the Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720, USA NORTH-HOLLANDI PHYSICS REPORTS (Review Section of Physics Letters) 199, No. 2 (1991) 73—146. North-Holland THEORIES OF INTRAMOLECULAR VIBRATIONAL ENERGY TRANSFER T. UZER School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332-0430, USA and Bilkent University, Ankara, Turkey with an appendix by W.H. MILLER Department of Chemistry, and Materials and Molecular Research Division of the Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720, USA Editor: E.W. McDaniel Received January 1990 Contents: 1. Brief history and overview 75 4.3. The Onset of stochasticity 101 2. Definition and nature of intramolecular relaxation 78 5. Classical microscopic theory of energy sharing; energy 2.1. General molecular model for intramolecular vibra- transfer through nonlinear resonances 104 tional energy redistribution (IVR) 80 5.1. Nonlinear resonances and classical mechanics of the 2.2. Criteria for IVR regimes 82 pendulum 105 2.3. Dephasing versus relaxation in isolated molecules 84 5.2. Vibrational energy transfer and overlapping reso- 3. “Phenomenological” theories of energy sharing; approach nances 108 of radiationless transitions 86 5.3. Generalizing the pendulum 112 3.1. Molecular model for fluorescence 87 5.4. Nonstatistical effects and phase space structures 113 3.2. “Exact” molecular eigenstates 88 6. ‘Mesoscopic” description of intramolecular vibrational 3.3.
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