Can Wavefunction Collapse Conserve Energy?
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Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Quantum Theory of the Hydrogen Atom
Quantum Theory of the Hydrogen Atom Chemistry 35 Fall 2000 Balmer and the Hydrogen Spectrum n 1885: Johann Balmer, a Swiss schoolteacher, empirically deduced a formula which predicted the wavelengths of emission for Hydrogen: l (in Å) = 3645.6 x n2 for n = 3, 4, 5, 6 n2 -4 •Predicts the wavelengths of the 4 visible emission lines from Hydrogen (which are called the Balmer Series) •Implies that there is some underlying order in the atom that results in this deceptively simple equation. 2 1 The Bohr Atom n 1913: Niels Bohr uses quantum theory to explain the origin of the line spectrum of hydrogen 1. The electron in a hydrogen atom can exist only in discrete orbits 2. The orbits are circular paths about the nucleus at varying radii 3. Each orbit corresponds to a particular energy 4. Orbit energies increase with increasing radii 5. The lowest energy orbit is called the ground state 6. After absorbing energy, the e- jumps to a higher energy orbit (an excited state) 7. When the e- drops down to a lower energy orbit, the energy lost can be given off as a quantum of light 8. The energy of the photon emitted is equal to the difference in energies of the two orbits involved 3 Mohr Bohr n Mathematically, Bohr equated the two forces acting on the orbiting electron: coulombic attraction = centrifugal accelleration 2 2 2 -(Z/4peo)(e /r ) = m(v /r) n Rearranging and making the wild assumption: mvr = n(h/2p) n e- angular momentum can only have certain quantified values in whole multiples of h/2p 4 2 Hydrogen Energy Levels n Based on this model, Bohr arrived at a simple equation to calculate the electron energy levels in hydrogen: 2 En = -RH(1/n ) for n = 1, 2, 3, 4, . -
The Concept of Quantum State : New Views on Old Phenomena Michel Paty
The concept of quantum state : new views on old phenomena Michel Paty To cite this version: Michel Paty. The concept of quantum state : new views on old phenomena. Ashtekar, Abhay, Cohen, Robert S., Howard, Don, Renn, Jürgen, Sarkar, Sahotra & Shimony, Abner. Revisiting the Founda- tions of Relativistic Physics : Festschrift in Honor of John Stachel, Boston Studies in the Philosophy and History of Science, Dordrecht: Kluwer Academic Publishers, p. 451-478, 2003. halshs-00189410 HAL Id: halshs-00189410 https://halshs.archives-ouvertes.fr/halshs-00189410 Submitted on 20 Nov 2007 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. « The concept of quantum state: new views on old phenomena », in Ashtekar, Abhay, Cohen, Robert S., Howard, Don, Renn, Jürgen, Sarkar, Sahotra & Shimony, Abner (eds.), Revisiting the Foundations of Relativistic Physics : Festschrift in Honor of John Stachel, Boston Studies in the Philosophy and History of Science, Dordrecht: Kluwer Academic Publishers, 451-478. , 2003 The concept of quantum state : new views on old phenomena par Michel PATY* ABSTRACT. Recent developments in the area of the knowledge of quantum systems have led to consider as physical facts statements that appeared formerly to be more related to interpretation, with free options. -
Vibrational Quantum Number
Fundamentals in Biophotonics Quantum nature of atoms, molecules – matter Aleksandra Radenovic [email protected] EPFL – Ecole Polytechnique Federale de Lausanne Bioengineering Institute IBI 26. 03. 2018. Quantum numbers •The four quantum numbers-are discrete sets of integers or half- integers. –n: Principal quantum number-The first describes the electron shell, or energy level, of an atom –ℓ : Orbital angular momentum quantum number-as the angular quantum number or orbital quantum number) describes the subshell, and gives the magnitude of the orbital angular momentum through the relation Ll2 ( 1) –mℓ:Magnetic (azimuthal) quantum number (refers, to the direction of the angular momentum vector. The magnetic quantum number m does not affect the electron's energy, but it does affect the probability cloud)- magnetic quantum number determines the energy shift of an atomic orbital due to an external magnetic field-Zeeman effect -s spin- intrinsic angular momentum Spin "up" and "down" allows two electrons for each set of spatial quantum numbers. The restrictions for the quantum numbers: – n = 1, 2, 3, 4, . – ℓ = 0, 1, 2, 3, . , n − 1 – mℓ = − ℓ, − ℓ + 1, . , 0, 1, . , ℓ − 1, ℓ – –Equivalently: n > 0 The energy levels are: ℓ < n |m | ≤ ℓ ℓ E E 0 n n2 Stern-Gerlach experiment If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be random and continuous. Each particle would be deflected by a different amount, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount. -
The Quantum Mechanical Model of the Atom
The Quantum Mechanical Model of the Atom Quantum Numbers In order to describe the probable location of electrons, they are assigned four numbers called quantum numbers. The quantum numbers of an electron are kind of like the electron’s “address”. No two electrons can be described by the exact same four quantum numbers. This is called The Pauli Exclusion Principle. • Principle quantum number: The principle quantum number describes which orbit the electron is in and therefore how much energy the electron has. - it is symbolized by the letter n. - positive whole numbers are assigned (not including 0): n=1, n=2, n=3 , etc - the higher the number, the further the orbit from the nucleus - the higher the number, the more energy the electron has (this is sort of like Bohr’s energy levels) - the orbits (energy levels) are also called shells • Angular momentum (azimuthal) quantum number: The azimuthal quantum number describes the sublevels (subshells) that occur in each of the levels (shells) described above. - it is symbolized by the letter l - positive whole number values including 0 are assigned: l = 0, l = 1, l = 2, etc. - each number represents the shape of a subshell: l = 0, represents an s subshell l = 1, represents a p subshell l = 2, represents a d subshell l = 3, represents an f subshell - the higher the number, the more complex the shape of the subshell. The picture below shows the shape of the s and p subshells: (notice the electron clouds) • Magnetic quantum number: All of the subshells described above (except s) have more than one orientation. -
4 Nuclear Magnetic Resonance
Chapter 4, page 1 4 Nuclear Magnetic Resonance Pieter Zeeman observed in 1896 the splitting of optical spectral lines in the field of an electromagnet. Since then, the splitting of energy levels proportional to an external magnetic field has been called the "Zeeman effect". The "Zeeman resonance effect" causes magnetic resonances which are classified under radio frequency spectroscopy (rf spectroscopy). In these resonances, the transitions between two branches of a single energy level split in an external magnetic field are measured in the megahertz and gigahertz range. In 1944, Jevgeni Konstantinovitch Savoiski discovered electron paramagnetic resonance. Shortly thereafter in 1945, nuclear magnetic resonance was demonstrated almost simultaneously in Boston by Edward Mills Purcell and in Stanford by Felix Bloch. Nuclear magnetic resonance was sometimes called nuclear induction or paramagnetic nuclear resonance. It is generally abbreviated to NMR. So as not to scare prospective patients in medicine, reference to the "nuclear" character of NMR is dropped and the magnetic resonance based imaging systems (scanner) found in hospitals are simply referred to as "magnetic resonance imaging" (MRI). 4.1 The Nuclear Resonance Effect Many atomic nuclei have spin, characterized by the nuclear spin quantum number I. The absolute value of the spin angular momentum is L =+h II(1). (4.01) The component in the direction of an applied field is Lz = Iz h ≡ m h. (4.02) The external field is usually defined along the z-direction. The magnetic quantum number is symbolized by Iz or m and can have 2I +1 values: Iz ≡ m = −I, −I+1, ..., I−1, I. -
Entanglement of the Uncertainty Principle
Open Journal of Mathematics and Physics | Volume 2, Article 127, 2020 | ISSN: 2674-5747 https://doi.org/10.31219/osf.io/9jhwx | published: 26 Jul 2020 | https://ojmp.org EX [original insight] Diamond Open Access Entanglement of the Uncertainty Principle Open Quantum Collaboration∗† August 15, 2020 Abstract We propose that position and momentum in the uncertainty principle are quantum entangled states. keywords: entanglement, uncertainty principle, quantum gravity The most updated version of this paper is available at https://osf.io/9jhwx/download Introduction 1. [1] 2. Logic leads us to conclude that quantum gravity–the theory of quan- tum spacetime–is the description of entanglement of the quantum states of spacetime and of the extra dimensions (if they really ex- ist) [2–7]. ∗All authors with their affiliations appear at the end of this paper. †Corresponding author: [email protected] | Join the Open Quantum Collaboration 1 Quantum Gravity 3. quantum gravity quantum spacetime entanglement of spacetime 4. Quantum spaceti=me might be in a sup=erposition of the extra dimen- sions [8]. Notation 5. UP Uncertainty Principle 6. UP= the quantum state of the uncertainty principle ∣ ⟩ = Discussion on the notation 7. The universe is mathematical. 8. The uncertainty principle is part of our universe, thus, it is described by mathematics. 9. A physical theory must itself be described within its own notation. 10. Thereupon, we introduce UP . ∣ ⟩ Entanglement 11. UP α1 x1p1 α2 x2p2 α3 x3p3 ... 12. ∣xi ⟩u=ncer∣tainty⟩ +in po∣ sitio⟩n+ ∣ ⟩ + 13. pi = uncertainty in momentum 14. xi=pi xi pi xi pi ∣ ⟩ = ∣ ⟩ ∣ ⟩ = ∣ ⟩ ⊗ ∣ ⟩ 2 Final Remarks 15. -
Path Integral for the Hydrogen Atom
Path Integral for the Hydrogen Atom Solutions in two and three dimensions Vägintegral för Väteatomen Lösningar i två och tre dimensioner Anders Svensson Faculty of Health, Science and Technology Physics, Bachelor Degree Project 15 ECTS Credits Supervisor: Jürgen Fuchs Examiner: Marcus Berg June 2016 Abstract The path integral formulation of quantum mechanics generalizes the action principle of classical mechanics. The Feynman path integral is, roughly speaking, a sum over all possible paths that a particle can take between fixed endpoints, where each path contributes to the sum by a phase factor involving the action for the path. The resulting sum gives the probability amplitude of propagation between the two endpoints, a quantity called the propagator. Solutions of the Feynman path integral formula exist, however, only for a small number of simple systems, and modifications need to be made when dealing with more complicated systems involving singular potentials, including the Coulomb potential. We derive a generalized path integral formula, that can be used in these cases, for a quantity called the pseudo-propagator from which we obtain the fixed-energy amplitude, related to the propagator by a Fourier transform. The new path integral formula is then successfully solved for the Hydrogen atom in two and three dimensions, and we obtain integral representations for the fixed-energy amplitude. Sammanfattning V¨agintegral-formuleringen av kvantmekanik generaliserar minsta-verkanprincipen fr˚anklassisk meka- nik. Feynmans v¨agintegral kan ses som en summa ¨over alla m¨ojligav¨agaren partikel kan ta mellan tv˚a givna ¨andpunkterA och B, d¨arvarje v¨agbidrar till summan med en fasfaktor inneh˚allandeden klas- siska verkan f¨orv¨agen.Den resulterande summan ger propagatorn, sannolikhetsamplituden att partikeln g˚arfr˚anA till B. -
Two-State Systems
1 TWO-STATE SYSTEMS Introduction. Relative to some/any discretely indexed orthonormal basis |n) | ∂ | the abstract Schr¨odinger equation H ψ)=i ∂t ψ) can be represented | | | ∂ | (m H n)(n ψ)=i ∂t(m ψ) n ∂ which can be notated Hmnψn = i ∂tψm n H | ∂ | or again ψ = i ∂t ψ We found it to be the fundamental commutation relation [x, p]=i I which forced the matrices/vectors thus encountered to be ∞-dimensional. If we are willing • to live without continuous spectra (therefore without x) • to live without analogs/implications of the fundamental commutator then it becomes possible to contemplate “toy quantum theories” in which all matrices/vectors are finite-dimensional. One loses some physics, it need hardly be said, but surprisingly much of genuine physical interest does survive. And one gains the advantage of sharpened analytical power: “finite-dimensional quantum mechanics” provides a methodological laboratory in which, not infrequently, the essentials of complicated computational procedures can be exposed with closed-form transparency. Finally, the toy theory serves to identify some unanticipated formal links—permitting ideas to flow back and forth— between quantum mechanics and other branches of physics. Here we will carry the technique to the limit: we will look to “2-dimensional quantum mechanics.” The theory preserves the linearity that dominates the full-blown theory, and is of the least-possible size in which it is possible for the effects of non-commutivity to become manifest. 2 Quantum theory of 2-state systems We have seen that quantum mechanics can be portrayed as a theory in which • states are represented by self-adjoint linear operators ρ ; • motion is generated by self-adjoint linear operators H; • measurement devices are represented by self-adjoint linear operators A. -
Structure of a Spin ½ B
Structure of a spin ½ B. C. Sanctuary Department of Chemistry, McGill University Montreal Quebec H3H 1N3 Canada Abstract. The non-hermitian states that lead to separation of the four Bell states are examined. In the absence of interactions, a new quantum state of spin magnitude 1/√2 is predicted. Properties of these states show that an isolated spin is a resonance state with zero net angular momentum, consistent with a point particle, and each resonance corresponds to a degenerate but well defined structure. By averaging and de-coherence these structures are shown to form ensembles which are consistent with the usual quantum description of a spin. Keywords: Bell states, Bell’s Inequalities, spin theory, quantum theory, statistical interpretation, entanglement, non-hermitian states. PACS: Quantum statistical mechanics, 05.30. Quantum Mechanics, 03.65. Entanglement and quantum non-locality, 03.65.Ud 1. INTRODUCTION In spite of its tremendous success in describing the properties of microscopic systems, the debate over whether quantum mechanics is the most fundamental theory has been going on since its inception1. The basic property of quantum mechanics that belies it as the most fundamental theory is its statistical nature2. The history is well known: EPR3 showed that two non-commuting operators are simultaneously elements of physical reality, thereby concluding that quantum mechanics is incomplete, albeit they assumed locality. Bohr4 replied with complementarity, arguing for completeness; thirty years later Bell5, questioned the locality assumption6, and the conclusion drawn that any deeper theory than quantum mechanics must be non-local. In subsequent years the idea that entangled states can persist to space-like separations became well accepted7. -
A Relativistic Electron in a Coulomb Potential
A Relativistic Electron in a Coulomb Potential Alfred Whitehead Physics 518, Fall 2009 The Problem Solve the Dirac Equation for an electron in a Coulomb potential. Identify the conserved quantum numbers. Specify the degeneracies. Compare with solutions of the Schrödinger equation including relativistic and spin corrections. Approach My approach follows that taken by Dirac in [1] closely. A few modifications taken from [2] and [3] are included, particularly in regards to the final quantum numbers chosen. The general strategy is to first find a set of transformations which turn the Hamiltonian for the system into a form that depends only on the radial variables r and pr. Once this form is found, I solve it to find the energy eigenvalues and then discuss the energy spectrum. The Radial Dirac Equation We begin with the electromagnetic Hamiltonian q H = p − cρ ~σ · ~p − A~ + ρ mc2 (1) 0 1 c 3 with 2 0 0 1 0 3 6 0 0 0 1 7 ρ1 = 6 7 (2) 4 1 0 0 0 5 0 1 0 0 2 1 0 0 0 3 6 0 1 0 0 7 ρ3 = 6 7 (3) 4 0 0 −1 0 5 0 0 0 −1 1 2 0 1 0 0 3 2 0 −i 0 0 3 2 1 0 0 0 3 6 1 0 0 0 7 6 i 0 0 0 7 6 0 −1 0 0 7 ~σ = 6 7 ; 6 7 ; 6 7 (4) 4 0 0 0 1 5 4 0 0 0 −i 5 4 0 0 1 0 5 0 0 1 0 0 0 i 0 0 0 0 −1 We note that, for the Coulomb potential, we can set (using cgs units): Ze2 p = −eΦ = − o r A~ = 0 This leads us to this form for the Hamiltonian: −Ze2 H = − − cρ ~σ · ~p + ρ mc2 (5) r 1 3 We need to get equation 5 into a form which depends not on ~p, but only on the radial variables r and pr. -
Hamilton Equations, Commutator, and Energy Conservation †
quantum reports Article Hamilton Equations, Commutator, and Energy Conservation † Weng Cho Chew 1,* , Aiyin Y. Liu 2 , Carlos Salazar-Lazaro 3 , Dong-Yeop Na 1 and Wei E. I. Sha 4 1 College of Engineering, Purdue University, West Lafayette, IN 47907, USA; [email protected] 2 College of Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 3 Physics Department, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 4 College of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310058, China; [email protected] * Correspondence: [email protected] † Based on the talk presented at the 40th Progress In Electromagnetics Research Symposium (PIERS, Toyama, Japan, 1–4 August 2018). Received: 12 September 2019; Accepted: 3 December 2019; Published: 9 December 2019 Abstract: We show that the classical Hamilton equations of motion can be derived from the energy conservation condition. A similar argument is shown to carry to the quantum formulation of Hamiltonian dynamics. Hence, showing a striking similarity between the quantum formulation and the classical formulation. Furthermore, it is shown that the fundamental commutator can be derived from the Heisenberg equations of motion and the quantum Hamilton equations of motion. Also, that the Heisenberg equations of motion can be derived from the Schrödinger equation for the quantum state, which is the fundamental postulate. These results are shown to have important bearing for deriving the quantum Maxwell’s equations. Keywords: quantum mechanics; commutator relations; Heisenberg picture 1. Introduction In quantum theory, a classical observable, which is modeled by a real scalar variable, is replaced by a quantum operator, which is analogous to an infinite-dimensional matrix operator.