DOCSLIB.ORG

Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts catalysts Article Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts Vignesh Kumaravel 1,2,* , Muhammad Danyal Imam 3, Ahmed Badreldin 3, Rama Krishna Chava 4 , Jeong Yeon Do 4, Misook Kang 4,* and Ahmed Abdel-Wahab 3,* 1 Department of Environmental Science, School of Science, Institute of Technology Sligo, Ash Lane, F91 YW50 Sligo, Ireland 2 Centre for Precision Engineering, Materials and Manufacturing Research (PEM), Institute of Technology Sligo, Ash Lane, F91 YW50 Sligo, Ireland 3 Chemical Engineering Program, Texas A&M University at Qatar, Doha 23874, Qatar; [email protected] (M.D.I.); [email protected] (A.B.) 4 Department of Chemistry, College of Natural Sciences, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea; [email protected] (R.K.C.); [email protected] (J.Y.D.) * Correspondence: [email protected] (V.K.); [email protected] (M.K.); [email protected] (A.A.-W.) Received: 15 February 2019; Accepted: 11 March 2019; Published: 18 March 2019 Abstract: Photocatalytic water splitting is a sustainable technology for the production of clean fuel in terms of hydrogen (H2). In the present study, hydrogen (H2) production efficiency of three promising photocatalysts (titania (TiO2-P25), graphitic carbon nitride (g-C3N4), and cadmium sulfide (CdS)) was evaluated in detail using various sacrificial agents. The effect of most commonly used sacrificial agents in the recent years, such as methanol, ethanol, isopropanol, ethylene glycol, glycerol, lactic acid, glucose, sodium sulfide, sodium sulfite, sodium sulfide/sodium sulfite mixture, and triethanolamine, were evaluated on TiO2-P25, g-C3N4, and CdS. H2 production experiments were carried out under simulated solar light irradiation in an immersion type photo-reactor. All the experiments were performed without any noble metal co-catalyst. Moreover, photolysis experiments were executed to study the H2 generation in the absence of a catalyst. The results were discussed specifically in terms of chemical reactions, pH of the reaction medium, hydroxyl groups, alpha hydrogen, and carbon chain length of sacrificial agents. The results revealed that glucose and glycerol are the most suitable sacrificial agents for an oxide photocatalyst. Triethanolamine is the ideal sacrificial agent for carbon and sulfide photocatalyst. A remarkable amount of H2 was produced from the photolysis of sodium sulfide and sodium sulfide/sodium sulfite mixture without any photocatalyst. The findings of this study would be highly beneficial for the selection of sacrificial agents for a particular photocatalyst. Keywords: photocatalysis; TiO2; g-C3N4; CdS; energy 1. Introduction Photocatalytic hydrogen (H2) production via water splitting is a sustainable and renewable energy production technology with negligible impact on the environment [1] (Figure1). H 2 is one of the most promising and clean energy sources for the future, with water as the only combustion product. After the invention of photo-electrochemical water splitting in 1972 [2] by Fujishima and Honda, nearly 9000 research articles have been published, outlining the use of various photocatalysts. In particular, most of the research works have been carried out using powder photocatalysts (except photo-electrochemical studies). The reported materials in the recent years are categorized as oxide Catalysts 2019, 9, 276; doi:10.3390/catal9030276 www.mdpi.com/journal/catalysts Catalysts 2018, 8, x FOR PEER REVIEW 2 of 35 InCatalysts particular,2019, 9 ,most 276 of the research works have been carried out using powder photocatalysts (except2 of 35 photo-electrochemical studies). The reported materials in the recent years are categorized as oxide [3–149], carbon [3,81,150–237], and sulfide [3,14,17,35,58,59,113,114,119,128,133,154,164,169,[3–149], carbon [3,81,150–237], and sulfide [3,14177,181,195,203,208,210,215,220,227,230,235,238–,17,35,58,59,113,114,119,128,133,154,164,169,177,181, 345]195, 203photocatalysts.,208,210,215 ,Titanium220,227,230 oxide–P25,235,238– 345(TiO] photocatalysts.2-P25), graphitic Titanium carbon nitride oxide–P25 (g-C (TiO3N4),2 -P25),and cadmium graphitic sulfidecarbon (CdS) nitride are (g -Cthe3 Nmost4), and extensively cadmium studied sulfide photoc (CdS) areatalysts the most for water extensively splitting. studied Many photocatalysts review articles for havewater also splitting. been published Many review [1,116,163,167,225,237,238,245,346–419] articles have also been published [1,116 discussing,163,167, 225the, 237various,238,245 features,346–419 of ] thediscussing photocatalytic the various water features splitting, ofthe such photocatalytic as fundamental water concepts, splitting, suchtheoretical as fundamental principles, concepts, nature (morphology,theoretical principles, surface characteristics, nature (morphology, and optical surface properties) characteristics, of the and photocatalyst, optical properties) role of of co- the catalyst/sacrificialphotocatalyst, role reagents, of co-catalyst/sacrificial mechanism, kineti reagents,cs, etc. mechanism, Nevertheless, kinetics, there etc. Nevertheless,is still not theremany is comprehensivestill not many comprehensivestudies to identify studies an appropriate to identify an sa appropriatecrificial reagent sacrificial with reagentrespect to with the respect nature to of the a photocatalyst.nature of a photocatalyst. FigureFigure 1. 1. SchematicSchematic representation ofof thethe water-splitting water-splitting process process on on a photocatalyst a photocatalyst surface surface under under light lightirradiation irradiation [1]. Reproduced[1]. Reproduced with with permission permission from from Ref. [Ref.1]. Copyright [1]. Copyright 2019, 2019, Elsevier. Elsevier. Sacrificial agents or electron donors/hole scavengers play a prominent role in photocatalytic H Sacrificial agents or electron donors/hole scavengers play a prominent role in photocatalytic H22 production because the water splitting is energetically an uphill reaction (DH = 286 kJ mol−1). It is production because the water splitting is energetically an uphill reaction (ΔH0 = 286 kJ mol−1). It is realizedrealized that that methanol, methanol, triethanolamine, triethanolamine, and and sodium sodium sulfide/sodium sulfide/sodium sulfite sulfite are are the the most most commonly commonly usedused sacrificial sacrificial reagents reagents for for oxide, oxide, carbon, carbon, and and su sulfidelfide photocatalysts, photocatalysts, respectively. respectively. In In most most of of the the cases, fresh water (e.g., deionized water or double distilled water) has been used to evaluate the H cases, fresh water (e.g., deionized water or double distilled water) has been used to evaluate the H22 productionproduction efficiency efficiency in in a a micro micro photo-reactor photo-reactor (vol (volumeume in in the the range range of of 30 30 to to 70 70 mL) mL) with with a a strong strong ≤ lightlight irradiation irradiation source source (nearly (nearly ≤ 300300 W). W).However, However, the vitality the vitality and utilization and utilization of this of technology this technology have nothave been not comprehensively been comprehensively studied studied in a real in aenvironment. real environment. Moreover, Moreover, the commercialization the commercialization of this of technologythis technology is still is restrained still restrained by its by poor its poorefficiency efficiency and the and use the of use expensive of expensive noble noble metals metals (like Pt, (like Au, Pt, Pd,Au, Rh) Pd, as Rh) co-catalysts. as co-catalysts. Most Most of the of thepublished published results results do donot not have have much much consistency consistency in in terms terms of of efficiency. For example, different efficiency values have been reported for pure TiO using methanol as efficiency. For example, different efficiency values have been reported for pure TiO2 2 using methanol asa scavengera scavenger (Table (Table1). 1). This This discrepancy discrepancy is ascribed is ascribed to the to followingthe following reasons: reasons: photo-reactor photo-reactor design, design, inert gas (Ar or N ) purging flow rate, light irradiation source, gas sampling method, gas chromatography inert gas (Ar2 or N2) purging flow rate, light irradiation source, gas sampling method, gas chromatography(GC) analysis conditions, (GC) analysis calculations, conditions, etc. calculations, etc. Catalysts 2019, 9, 276 3 of 35 Table 1. Photocatalytic H2 production efficiency of TiO2 using methanol sacrificial agent. Catalyst Concentration of H Production Light Source 2 Reference Amount (g/L) Methanol (%) Efficiency (µmol/g/h) 300 W of Xe (without 1 10 42.00 [420] UV cutoff filter) 300 W of Xe (with UV 0.6 16.66 18.47 [217] cutoff filter) 300 W of Xe (with UV 0.5 20 ~20.00 [194] cutoff filter) 300 W of Xe (with UV 1.29 25.8 ~2.00 [421] cutoff filter) The photochemical reactions of sacrificial agents (methanol, ethanol, isopropanol, ethylene glycol, glycerol, glucose, lactic acid, triethanolamine, sodium sulfide, sodium sulfite, and sodium sulfide/sodium sulfite mixture) and their degradation products during H2 production are summarized as follows: Methanol [422] (MeOH): + • + H2O(l) + h ! OH + H (1) • • CH3OH (l) + OH ! CH2OH + H2O (l) (2) • + − CH2OH ! HCHO (l) + H + e (3) + − 2H + 2e ! H2 (g) (4) HCHO + H O ! HCOOH + H (5) (l) 2 (l) (l) 2 (g) HCOOH ! CO + H (6) (l) 2 (g) 2 (g) Overall reaction: CH OH + H O ! CO + 3H (7) 3 (l) 2 (l) 2 (g) 2 (g) Ethanol [423] (EtOH): CH CH
Load more

Recommended publications
  • Anaerobic Degradation of Methanethiol in a Process for Liquefied Petroleum Gas (LPG) Biodesulfurization
    Anaerobic degradation of methanethiol in a process for Liquefied Petroleum Gas (LPG) biodesulfurization Promotoren Prof. dr. ir. A.J.H. Janssen Hoogleraar in de Biologische Gas- en waterreiniging Prof. dr. ir. A.J.M. Stams Persoonlijk hoogleraar bij het laboratorium voor Microbiologie Copromotor Prof. dr. ir. P.N.L. Lens Hoogleraar in de Milieubiotechnologie UNESCO-IHE, Delft Samenstelling promotiecommissie Prof. dr. ir. R.H. Wijffels Wageningen Universiteit, Nederland Dr. ir. G. Muyzer TU Delft, Nederland Dr. H.J.M. op den Camp Radboud Universiteit, Nijmegen, Nederland Prof. dr. ir. H. van Langenhove Universiteit Gent, België Dit onderzoek is uitgevoerd binnen de onderzoeksschool SENSE (Socio-Economic and Natural Sciences of the Environment) Anaerobic degradation of methanethiol in a process for Liquefied Petroleum Gas (LPG) biodesulfurization R.C. van Leerdam Proefschrift ter verkrijging van de graad van doctor op gezag van de rector magnificus van Wageningen Universiteit Prof. dr. M.J. Kropff in het openbaar te verdedigen op maandag 19 november 2007 des namiddags te vier uur in de Aula Van Leerdam, R.C., 2007. Anaerobic degradation of methanethiol in a process for Liquefied Petroleum Gas (LPG) biodesulfurization. PhD-thesis Wageningen University, Wageningen, The Netherlands – with references – with summaries in English and Dutch ISBN: 978-90-8504-787-2 Abstract Due to increasingly stringent environmental legislation car fuels have to be desulfurized to levels below 10 ppm in order to minimize negative effects on the environment as sulfur-containing emissions contribute to acid deposition (‘acid rain’) and to reduce the amount of particulates formed during the burning of the fuel. Moreover, low sulfur specifications are also needed to lengthen the lifetime of car exhaust catalysts.
    [Show full text]
  • Removal of Hydrogen Sulfide from Landfill Gas Using a Solar Regenerable Adsorbent
    Removal of Hydrogen Sulfide from Landfill Gas Using a Solar Regenerable Adsorbent by Sreevani Kalapala Submitted in Partial Fulfillment of the Requirements for the Degree of Master of Science in the Chemistry Program YOUNGSTOWN STATE UNIVERSITY May, 2014 Removal of Hydrogen Sulfide from Landfill Gas Using A Solar Regenerable Adsorbent Sreevani Kalapala I hereby release this thesis to the public. I understand that this thesis will be made available from the OhioLINK ETD Center and the Maag Library Circulation Desk for public access. I also authorize the University or other individuals to make copies of this thesis as needed for scholarly research. Signature: Sreevani Kalapala, Student Date Approvals: Dr. Clovis A. Linkous, Thesis Advisor Date Dr. Daryl Mincey, Committee Member Date Dr. Sherri Lovelace-Cameron, Committee Member Date Dr. Salvatore A. Sanders, Associate Dean of Graduate Studies Date ABSTRACT: Landfill gas is a complex mix of gases, containing methane, carbon dioxide, nitrogen and hydrogen sulfide (H2S), created by the action of microorganisms within the landfill. The gas can be collected and flared off or used to produce electricity. However, the H2S content, which may vary from 10’s to 1000’s of ppm, can cause irreversible damage to equipment, and when combusted creates SO2, a precursor of acid rain. It is also a toxic eye and lung irritant, so that prolonged exposure must be kept below a few ppm. Therefore, H2S must be removed before landfill gas can be utilized. Our approach is to scrub H2S into aqueous media and then use an adsorbent to sequester it. The adsorbent is then regenerated in a photocatalytic reaction potentially using sunlight.
    [Show full text]
  • Method 9215: Potentiometric Determination of Sulfide in Aqueous Samples and Distillates with Ion-Selective Electrode, Part of Te
    METHOD 9215 POTENTIOMETRIC DETERMINATION OF SULFIDE IN AQUEOUS SAMPLES AND DISTILLATES WITH ION-SELECTIVE ELECTRODE 1.0 SCOPE AND APPLICATION 1.1 This method can be used for measuring total sulfide in a distilled sample. The method is meant to be used as an alternate determinative step following the distillation in either SW- 846 Methods 9030 or 9031. 1.2 This method must not be used for undistilled samples because of possible mercury and silver ion interferences. Also, the ISE only responds to free sulfide dianion and will not detect sulfide in complexes. Therefore, this method would provide low recoveries for undistilled samples. 1.3 The method detection limit is 1.0 mg/L. Sulfide concentrations from 0.1 to 12,000 mg/L may be measured. However, when a linear calibration is used, results less than 1 mg/L may be biased up to approximately 90 percent low. 2.0 SUMMARY OF METHOD 2.1 The distillations in Methods 9030 and/or 9031 are performed, except that the scrubber solution is sulfide anti-oxidant buffer (SAOB), with ascorbic and salicylic acids added as oxygen scavengers. The distillates are then analyzed potentiometrically using a sulfide ion-selective electrode (ISE) in conjunction with a double-junction reference electrode and a pH meter with an expanded millivolt scale or an ISE meter capable of being calibrated directly in terms of sulfide concentration. 2.2 This method is an alternative to the iodometric titration procedure, where a solution of thiosulfate is standardized against the thiosulfate solution, and the sulfide standard is standardized against the iodine solution/thiosulfate solution (which requires daily calibration itself).
    [Show full text]
  • Sodium Sulfide, Flake
    CHEMICAL PRODUCTS CORPORATION SDS No. 49A SAFETY DATA SHEET February 8, 2019 Page 1 of 9 Pages __________________________________ _________________________ 1. PRODUCT IDENTIFIER Product Name: Sodium Sulfide Flake Trade Name: Sodium Sulfide Flakes - 60-62% Sodium Sulfide, Hydrated with not less than 30% water SYNONYMS: Sodium Sulfide Hydrated; Disodium Sulfide hydrate. RECOMMENDED USES: - For industrial use to precipitate metals from solution - Waste and wastewater treatment - De-hairing agent in leather processing - Pulp and paper manufacture - Chemical and textile industrial processes Industrial uses advised against: None. 1.3 SUPPLIER OF THIS SDS: Chemical Products Corporation 102 Old Mill Road P.O. Box 2470 Cartersville, Georgia 30120-1688 Telephone: 1-770-382-2144 1.4 EMERGENCY PHONE NUMBER: CHEMTREC, 800-424-9300 (24 hours every day) 2. HAZARD IDENTIFICATION 2.1 Classification in accordance with paragraph (d) of §1910.1200 Corrosive to Metals, Category 1 H290: May be corrosive to metals. Acute toxicity, Category 3 H301: Toxic if swallowed. Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. 2.2 Signal word, hazard statement(s), symbol(s) and precautionary statement(s) Signal Word DANGER CAUSES SEVERE SKIN BURNS AND EYE DAMAGE Hazard Statements - H290: May be corrosive to metals. - H301: Toxic if swallowed. - H314: Causes severe skin burns and eye damage - H318: Causes serious eye damage Precautionary Statements Prevention - P234 Keep only in original container. - P260 Do not breathe dusts or mists. - P264 Wash skin thoroughly after handling. - P270 Do not eat, drink or smoke when using this product. - P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
    [Show full text]
  • Safety Data Sheet According to 29CFR1910/1200 and GHS Rev
    Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 10.24.2014 Page 1 of 8 Sodium Sulfide,Nonahydrate SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Sodium Sulfide,Nonahydrate Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25570 Recommended uses of the product and uses restrictions on use: Manufacturer Details: AquaPhoenix Scientific 9 Barnhart Drive, Hanover, PA 17331 Supplier Details: Fisher Science Education 15 Jet View Drive, Rochester, NY 14624 Emergency telephone number: Fisher Science Education Emergency Telephone No.: 800-535-5053 SECTION 2 : Hazards identification Classification of the substance or mixture: Irritant Acute toxicity (oral, dermal, inhalation), category 4 Toxic Acute toxicity (oral, dermal, inhalation), category 3 Corrosive Skin corrosion, category 1B Serious eye damage, category 1 Environmentally Damaging Acute hazards to the aquatic environment, category 1 Chronic hazards to the aquatic environment, category 1 Hazards Not Otherwise Classified - Combustible Dust Acute Oral Tox. 4 Acute Dermal Tox. 3 Skin Corr. 1B Eye corr. 1 Aquatic Acute 1 Aquatic Chronic 1 Signal word :Danger Hazard statements: Causes severe skin burns and eye damage Toxic in contact with skin Harmful if swallowed Very toxic to aquatic life with long lasting effects Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 10.24.2014 Page 2 of 8 Sodium Sulfide,Nonahydrate
    [Show full text]
  • Technical Guide for Solutions of Sodium Hydrosulfide Technical Guide for Solutions of Sodium Hydrosulfide
    TECHNICAL GUIDE FOR SOLUTIONS OF SODIUM HYDROSULFIDE TECHNICAL GUIDE FOR SOLUTIONS OF SODIUM HYDROSULFIDE TABLE OF CONTENTS TOPIC PAGE Overview 1 Health Hazards and First Aid 2 Flammability and Fire Response / Storage 3 Handling (PPE) 4 Equipment Recommendations / Transfers 5 Shipping 13 Releases 14 APPENDIX Material Safety Data Sheet 16 H2S Monitors 23 Hydrogen Sulfide Toxicity Chart 26 Density, Boiling and Freezing Points of 28 Sodium Hydrosulfide Viscosity of Typical 45% Sodium 30 Hydrosulfide Solution Sodium Hydrosulfide Site Assessment 32 Checklist TECHNICAL GUIDE FOR SOLUTIONS OF SODIUM HYDROSULFIDE Overview Sodium Hydrosulfide, chemical formula NaHS, is a highly alkaline salt solution with a pH of 11.5 to 12.5. The solution is typically yellow to dark green and has a rotten-egg odor due to the Hydrogen Sulfide (H2S) content. The product strength ranges from 20% to 45% by weight and weighs 9 to 11 pounds per gallon (specific gravity from 1.13 to 1.30 g/cm3). Solutions of NaHS are considered stable in normal transportation. The vapor space over NaHS solutions contains highly toxic Hydrogen Sulfide gas. The Hydrogen Sulfide gas is colorless and it is heavier than air. It will remain close to the ground and collect in low lying areas. The amount of Hydrogen Sulfide gas evolved from NaHS solutions is noticeably increased when the pH of the solution is below the pH of 10.2. This hap pens when the solution comes into contact with acidic materials or other materials that have a pH lower than 10.2. Dilution of the material will also create a minimal amount of Hydrogen Sulfide gas due to the lower pH of water coming in contact with the solution.
    [Show full text]
  • Fate of Sodium Sulfide.Pdf
    ---· fate of SodiuM Sulfide and SodiuM ·sisul'ticte . ' 3 in SteaM Muffler Effluent ·,·:,· ~Jr l'f·;'.lfR & -..... _, __ . --.-- _,_,-; .'~;ENT The cheMical species generated by the treatMent of geotherMal steaM with sodiuM hydroxide <HaOH> include sodiuM carbonate <Haf0 3>, sodiuM bicarbonate <HaHCO?, sodiuM sulfide <HazS>, and sodiuM bisulfide <HaHS>. The forMer t~o cheMicals are environMentally benign and their disposal will have no significant effect on groundwater quality. SodiuM sulfide and bisulfide can 7 however~ have substantial iMpacts on water quality due to their toxicity at Moderate concentrations and their potential for odor generation at extreMely low concentrations. Hence 7 the fate of these cheMicals under norMal environMental conditions is of concern in considering their production and disposal as a result of treatMent of geotherMal steaM. Hydrogen sulfide abateMent froM geotherMal steaM has been accoMplished in Hawaii by the injection of a lOX solution of sodiuM hydroxide into the steaM phase at a Mole ratio of three Moles of sodiuM hydroxide to one Mole of hydrogen sulfide. The pH of the resultant solution will be in the range of 12 to 13 and hence the predoMinant sulfide species in solution will be sodiuM sulfide- Because a quantitative reaction of hydrogen sulfide to sodiuM sulfide ~auld require only two Moles of caustic to one MOle of sulfide~ an excess of caustic will be present that will Maintain the pH at a high level for a substantial period after the scrubber effluent is exposed to atMospheric air. Upon exposure of the sodiuM sulfide solution to air 7 the Most iMportant reaction that will occur is the oxidation of the sodiuM sulfide.
    [Show full text]
  • Sodium Hydrogen Sulfide
    Product Safety Summary Sodium Hydrogen Sulfide, Solid (70-72% with Crystallization Waters < 25%) CAS No. 16721-80-5 This Product Safety Summary is intended to provide a general overview of the chemical substance. The information on the summary is basic information and is not intended to provide emergency response information, medical information or treatment information. The summary should not be used to provide in-depth safety and health information. In-depth safety and health information can be found on the Safety Data Sheet (SDS) for the chemical substance. Names Sodium hydrogen sulfide (sulphide) Sodium hydrosulfide (hydrosulphide) Sodium mercaptan Sodium sulfhydrate Sodium bisulfide Sodium mercaptide Product Overview Solvay Fluorides, LLC does not sell sodium hydrogen sulfide directly to consumers. Consumers are unlikely to be exposed to sodium hydrogen sulfide in any of the consumer product applications listed below and only where the sodium hydrogen sulfide is not transformed or reacted. Sodium hydrogen sulfide is a yellow, solid flake with a sulfurous (rotten egg) smell. It is used in water treatment, the pulp and paper industry, and in leather processing as a tanning agent or hair remover (from hides). Sodium hydrogen sulfide may be used in the making of colors and dyes. It can also be used in the manufacture of other chemicals, metals or in ore processing (mining) and in waste water, soil and process sludge treatment. Exposure to sodium hydrogen sulfide can cause severe irritation to the skin, eyes, and respiratory tract. Sodium hydrogen sulfide may cause sensitization (develop an allergic reaction). Breathing sodium hydrogen sulfide dusts may aggravate asthma or other pulmonary (breathing) diseases and may cause headaches, dizziness, nausea and vomiting.
    [Show full text]
  • Sodium Sulfide.Pdf
    FLINN SCIENTIFIC INC. "Your Safer Source for Science Supplies" MSDS #: 762.00 Material Safety Data Sheet (MSDS) Revision Date: March 15, 2001 Section 1 — Chemical Product and Company Identification Sodium Sulfide Flinn Scientific, Inc. P.O. Box 219 Batavia, IL 60510 (800) 452-1261 CHEMTREC Emergency Phone Number: (800) 424-9300 Section 2 — Composition, Information on Ingredients Sodium Sulfide, nonahydrate CAS#: 1313-84-4 Section 3 — Hazards Identification Colorless to slightly yellow crystals or lumps. Odor of rotten eggs (hydrogen sulfide). FLINN AT-A-GLANCE Moderately toxic by ingestion or inhalation. Corrosive to body tissue. Health-2 Flammable solid. Liberates toxic hydrogen sulfide on contact with acids. Flammability-2 If ingested, contact with stomach acids can liberate toxic hydrogen sulfide gas. Reactivity-2 Exposure-2 Storage-2 0 is low hazard, 3 is high hazard Section 4 — First Aid Measures Call a physician, seek medical attention for further treatment, observation and support after first aid. Inhalation: Remove to fresh air at once. If breathing has stopped give artificial respiration immediately. Eye: Immediately flush with fresh water for 15 minutes. External: Wash continuously with fresh water for 15 minutes. Internal: Rinse out mouth, give 1 to 2 cups of water or milk, induce vomiting. Call a physician or poison control at once. Section 5 — Fire Fighting Measures Flammable solid. NFPA CODE When heated to decomposition, emits toxic SOx and sulfur fumes. None established Fire Fighting Instructions: Use triclass, dry chemical fire extinguisher. Firefighters should wear PPE and SCBA with full facepiece operated in positive pressure mode. Section 6 — Accidental Release Measures Restrict unprotected personnel from area.
    [Show full text]
  • Production of Sodium Sulfide Depending on the Local Conditions
    Archive of SID 17th Iranian Chemistry Congress Vali-e-Asr University of Rafsanjan 1-3 september 2014 Production of Sodium Sulfide Depending on the Local Conditions Amir Seraji,* Fatemeh Teimouri Department of Chemistry, Islamic Azad University- Saveh Branch, P. O. box 39187-366, Saveh, Iran. [email protected] Background: Sodium sulfide (Na2S) is the most important and applicable compound among alkali and alkaline earth sulfides. Na2S is used in a process for producing poly (phenylene sulfide) and polysulfide polymers. It also is used in reduction of polynitroaromatics and in engine oils [1]. In the laboratory, anhydrous Na2S can be prepared by reaction of sulfur with sodium in anhydrous ammonia or in dry THF with a catalytic amount of naphthalene [2]: 2 Na + S → Na2S ◦ Industrially Na2S is produced by reduction of sodium sulfate with carbon, in the form of coal at 700- 900 C [3]: Na2SO4 +2C→Na2S+2CO2 Methods: In this research we wish to report optimized process for the synthesis of Na2S using Na2SO4 and coal. Raw materials of the reaction are grinded very well in mortar which pass trough sieve with mesh 100. The mix of Na2SO4 and coal is heated in electrical furnace. After evolution of CO2 and CO begins the reaction mass becomes very fluid on further heating, it becomes pasty and finally solid. The produced sodium sulfide that contains excess carbon, ash components and other solid impurities is leached with water, and the undissolvable components are removed by filtration. The filtrate is concentrated by evaporation and solidifies by cooling. ◦ Results: Optimized weight ratio of Na2SO4 to coal was 3.94:1.
    [Show full text]
  • Sodium Sulfide
    MSDS Number: S5042 * * * * * Effective Date: 08/17/06 * * * * * Supercedes: 11/12/03 SODIUM SULFIDE 1. Product Identification Synonyms: Sodium sulfide nonahydrate; Sodium monosulfide CAS No.: 1313-82-2 (Anhydrous) 1313-84-4 (Nonahydrate) Molecular Weight: 240.18 Chemical Formula: Na2S.9H2O Product Codes: J.T. Baker: 3910 Mallinckrodt: 8044 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------------ --------- Sodium Sulfide 1313-82-2 98 - 100% Yes 3. Hazards Identification Emergency Overview -------------------------- DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating: 3 - Severe Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 4 - Extreme (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: White Stripe (Store Separately) ----------------------------------------------------------------------------------------------------------- Potential Health Effects ---------------------------------- Inhalation: Hazard is highly toxic (50-100 ppm in air) hydrogen sulfide which may accumulate in confined spaces due to the decomposition of sodium sulfide or from its reaction with acids. Symptoms include painful conjunctivitis, headache, nausea, dizziness, coughing
    [Show full text]
  • Sodium Sulfide, Flake (Hydrated) Or Sodium Sulphide, Flake (Hydrated) ID: C1-151
    Safety Data Sheet Material Name: Sodium Sulfide, Flake (Hydrated) or Sodium Sulphide, Flake (Hydrated) ID: C1-151 * * * Section 1 - Identification * * * Chemical Name: Sodium Sulfide Hydrate or Sodium Sulphide Hydrate Product Use: For Commercial Use; RESTRICTIONS on USE NOT TO BE USED AS A PESTICIDE. THIS PRODUCT IS NOT TO BE USED IN VIOLATION OF ANY PATENTS. CHEM ONE LTD. DISCLAIMS ANY AND ALL WARRANTIES, EITHER EXPRESSED OR IMPLIED, INCLUDING THE WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR APPLICATION. IN NO EVENT SHALL CHEM ONE LTD. OR ITS SUPPLIERS BE LIABLE FOR ANY DAMAGES WHATSOEVER INCLUDING DIRECT, INDIRECT, INCIDENTAL, CONSEQUENTIAL, LOSS OF BUSINESS PROFITS OR SPECIAL DAMAGES, EVEN IF CHEM ONE LTD. OR ITS SUPPLIERS HAVE BEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGES. SOME STATES DO NOT ALLOW THE EXCLUSION OF LIMITATION OF LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES SO THE FOREGOING LIMITATION MAY NOT APPLY. Supplier Information Chem One Ltd. Phone: (713) 896-9966 14140 Westfair East Drive Fax: (713) 896-7540 Houston, Texas 77041-1104 Emergency # 800- 424-9300 International +1-703- 527-3887 NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service. * * * Section 2 – Hazard(s) Identification * * * GHS HAZARDS Hazard Classes Hazard Categories Corrosive to metals Category 1 Acute toxicity, Oral Category 3 Skin corrosion Category 1B Serious
    [Show full text]