Nomenclature of Pyroxenes
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Bedrock Geology Glossary from the Roadside Geology of Minnesota, Richard W
Minnesota Bedrock Geology Glossary From the Roadside Geology of Minnesota, Richard W. Ojakangas Sedimentary Rock Types in Minnesota Rocks that formed from the consolidation of loose sediment Conglomerate: A coarse-grained sedimentary rock composed of pebbles, cobbles, or boul- ders set in a fine-grained matrix of silt and sand. Dolostone: A sedimentary rock composed of the mineral dolomite, a calcium magnesium car- bonate. Graywacke: A sedimentary rock made primarily of mud and sand, often deposited by turbidi- ty currents. Iron-formation: A thinly bedded sedimentary rock containing more than 15 percent iron. Limestone: A sedimentary rock composed of calcium carbonate. Mudstone: A sedimentary rock composed of mud. Sandstone: A sedimentary rock made primarily of sand. Shale: A deposit of clay, silt, or mud solidified into more or less a solid rock. Siltstone: A sedimentary rock made primarily of sand. Igneous and Volcanic Rock Types in Minnesota Rocks that solidified from cooling of molten magma Basalt: A black or dark grey volcanic rock that consists mainly of microscopic crystals of pla- gioclase feldspar, pyroxene, and perhaps olivine. Diorite: A plutonic igneous rock intermediate in composition between granite and gabbro. Gabbro: A dark igneous rock consisting mainly of plagioclase and pyroxene in crystals large enough to see with a simple magnifier. Gabbro has the same composition as basalt but contains much larger mineral grains because it cooled at depth over a longer period of time. Granite: An igneous rock composed mostly of orthoclase feldspar and quartz in grains large enough to see without using a magnifier. Most granites also contain mica and amphibole Rhyolite: A felsic (light-colored) volcanic rock, the extrusive equivalent of granite. -
Crystallization History of Gabbroic Shergottite Nwa 6963 As Revealed by Pyroxene Zoning
Lunar and Planetary Science XLVIII (2017) 1504.pdf CRYSTALLIZATION HISTORY OF GABBROIC SHERGOTTITE NWA 6963 AS REVEALED BY PYROXENE ZONING. A. L. Meado1, S. P. Schwenzer2, S. J. Hammond2, and J. Filiberto1,2, 1Southern Illinois University, Department of Geology, Carbondale IL 62901, USA. [email protected], 2School of Enviroment, Earth, and Ecosystem Sciences, The Open University, Walton Hall, Milton Keynes, MK7 6AA, UK. Introduction: NorthWest Africa (NWA) 6963 is an comprised of 40 to 120 measured points depending on intriguing new coarse grained Martian meteorite that grain size. This method produced precise zoing profiles further extends our sample collection both composition- used to interpret NWA 6963 petrogenetic history. Meas- ally and texturally [1]. It was originally documented as urements too close to the edge of grains, melt inclusions, a basaltic shergottite because the pyroxene composi- sulfides, fractures, or alteration were removed from zon- tions [2, 3] and modal abundances are similar to Sher- ing profiles. Outliers were identified by obvious gotty. However, recent work reclassified NWA 6963 as changes in bulk chemisty, poor oxide weight totals, and an intrusive, gabbroic Martian meteorite because of the visual inspection of back scatter electron (BSE) images. large oriented pyroxene crystals [1]. This investigation Element maps of three pyroxene grains were produced will focus on NWA 6963 pyroxene zoning profiles and to better interpret zoning profiles. interpreting igneous processes related to its crystalliza- Trace elements have recently been analyzed by laser tion history. ablation-ICPMS at the Open University, UK. The data Compositional zoning of pyroxene crystals in basal- is currently being reduced to further interpret pyroxene tic shergottites have previously been interpreted for pe- zoning profiles in NWA 6963. -
Orthopyroxene–Omphacite
Lithos 216–217 (2015) 1–16 Contents lists available at ScienceDirect Lithos journal homepage: www.elsevier.com/locate/lithos Orthopyroxene–omphacite- and garnet–omphacite-bearing magmatic assemblages, Breaksea Orthogneiss, New Zealand: Oxidation state controlled by high-P oxide fractionation☆ Timothy Chapman a,⁎, Geoffrey L. Clarke a, Nathan R. Daczko b,c, Sandra Piazolo b,c, Adrianna Rajkumar a a School of Geosciences, F09, University of Sydney, Sydney, NSW 2006, Australia b ARC Centre of Excellence for Core to Crust Fluid Systems, Department of Earth and Planetary Sciences, Macquarie University, NSW 2109, Australia c GEMOC, Department of Earth and Planetary Sciences, Macquarie University, NSW 2109, Australia article info abstract Article history: The Breaksea Orthogneiss comprises a monzodioritic host partially recrystallised to omphacite–garnet–plagioclase– Received 19 December 2013 rutile granulite at 850 °C and 1.8 GPa, with metre to decametre-scale, cognate inclusions ranging from ultramafic Accepted 21 November 2014 through gabbroic to monzodioritic composition. Coarsely layered garnetite and diopsidic clinopyroxenite cumulate Available online 3 December 2014 preserves igneous textures, whereas garnet–omphacite cumulate shows a partial metamorphic overprint to eclogite. Garnet and omphacite in undeformed to weakly deformed rocks have similar major and rare earth element Keywords: characteristics reflecting their common igneous origin, pointing to a lack of metamorphic recrystallisation. Inclusions Omphacite–garnet granulite – – – Orthopyroxene eclogite of omphacite orthopyroxene plagioclase ulvöspinel orthogneiss have whole-rock compositions almost identical Omphacite–orthopyroxene granulite to the host monzodiorite. Reaction zones developed along contacts between the orthopyroxene-bearing inclusions REE and host contain metamorphic garnet that is microstructurally and chemically distinct from igneous garnet. -
High-Pressure Single-Crystal Elasticity and Thermal Equation Of
Journal of Geophysical Research: Solid Earth 10.1029/2018JB016964 2001). For example, D. Zhang et al. (2016) performed single‐crystal X‐ray diffraction (XRD) experiments on omphacite up to 47 GPa at 300 K. Pandolfo et al. (2012b) measured the thermal expansion coefficients of omphacite up to 1073 K at 1 atm. The only available in situ high P‐T EOS study for omphacite is performed on polycrystalline samples using multianvil press up to 10 GPa and thus is unable to cover the entire P stability field of omphacite in the Earth's interior (Nishihara et al., 2003). On the other hand, although the sound velocities of the Mg,Ca end member diopside have been studied at various P‐T conditions (Isaak et al., 2006; Isaak & Ohno, 2003; Levien et al., 1979; Li & Neuville, 2010; Matsui & Busing, 1984; Sang et al., 2011; Sang & Bass, 2014; Walker, 2012), the single‐crystal elastic properties of omphacite have only been measured at ambient condition (Bhagat et al., 1992) or investigated computationally at high‐P 0‐K conditions (Skelton & Walker, 2015). The lack of experimentally determined thermoelastic properties of omphacite, which is the most abundant mineral phase in eclogite, restricts our understanding of the subduction process as well as the possible seismic identification of eclogitic materials in the Earth's interior. To fill in this knowledge gap, we performed high P‐T single‐crystal XRD measurements on natural P2/n omphacite crystals up to 18 GPa 700 K at GeoSoilEnviroCARS (GSECARS), Advanced Photon Source, Argonne National Laboratory, as well as single‐crystal Brillouin spectroscopy measurements of the same crystals up to 18 GPa at 300 K at the high‐P laser spectroscopy laboratory at University of New Mexico (UNM). -
Ultra-High Pressure Aluminous Titanites in Carbonate-Bearing Eclogites at Shuanghe in Dabieshan, Central China
Ultra-high pressure aluminous titanites in carbonate-bearing eclogites at Shuanghe in Dabieshan, central China D. A. CARSWELL Department of Earth Sciences, University of Sheffield, Sheffield $3 7HF, UK R. N. WILSON Department of Geology, University of Leicester, Leicester LE1 7RH, UK AND M. ZtIAI Institute of Geology, Academia Sinica, P.O. Box 634, Beijing 100029, China Abstract Petrographic features and compositions of titanites in eclogites within the ultra-high pressure metamorphic terrane in central Dabieshan are documented and phase equilibria and thermobarometric implications discussed. Carbonate-bearing eclogite pods in marble at Shuanghe contain primary metamorphic aluminous titanites, with up to 39 mol.% Ca(AI,Fe3+)FSiO4 component. These titanites formed as part of a coesite- bearing eclogite assemblage and thus provide the first direct petrographic evidence that AIFTi_IO_j substitution extends the stability of titanite, relative to futile plus carbonate, to pressures within the coesite stability field. However, it is emphasised that A1 and F contents of such titanites do not provide a simple thermobarometric index of P-T conditions but are constrained by the activity of fluorine, relative to CO2, in metamorphic fluids - as signalled by observations of zoning features in these titanites. These ultra-high pressure titanites show unusual breakdown features developed under more H20-rich amphibolite-facies conditions during exhumation of these rocks. In some samples aluminous titanites have been replaced by ilmenite plus amphibole symplectites, in others by symplectitic intergrowths of secondary, lower AI and F, titanite plus plagioclase. Most other coesite-bearing eclogite samples in the central Dabieshan terrane contain peak assemblage rutile often partly replaced by grain clusters of secondary titanites with customary low AI and F contents. -
The Effect of Cation Order on the Elasticity of Omphacite from Atomistic Calculations
This is a repository copy of The effect of cation order on the elasticity of omphacite from atomistic calculations. White Rose Research Online URL for this paper: http://eprints.whiterose.ac.uk/85963/ Version: Accepted Version Article: Skelton, R and Walker, AM (2015) The effect of cation order on the elasticity of omphacite from atomistic calculations. Physics and Chemistry of Minerals, 42 (8). pp. 677-691. ISSN 0342-1791 https://doi.org/10.1007/s00269-015-0754-9 Reuse Unless indicated otherwise, fulltext items are protected by copyright with all rights reserved. The copyright exception in section 29 of the Copyright, Designs and Patents Act 1988 allows the making of a single copy solely for the purpose of non-commercial research or private study within the limits of fair dealing. The publisher or other rights-holder may allow further reproduction and re-use of this version - refer to the White Rose Research Online record for this item. Where records identify the publisher as the copyright holder, users can verify any specific terms of use on the publisher’s website. Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing [email protected] including the URL of the record and the reason for the withdrawal request. [email protected] https://eprints.whiterose.ac.uk/ 1 The effect of cation order on the elasticity of omphacite from atomistic calculations 2 Richard Skeltona,* and Andrew M. Walkerb,c 3 a Research School of Earth Sciences, Australian National University, -
Sr–Pb Isotopes Signature of Lascar Volcano (Chile): Insight Into Contamination of Arc Magmas Ascending Through a Thick Continental Crust N
Sr–Pb isotopes signature of Lascar volcano (Chile): Insight into contamination of arc magmas ascending through a thick continental crust N. Sainlot, I. Vlastélic, F. Nauret, S. Moune, F. Aguilera To cite this version: N. Sainlot, I. Vlastélic, F. Nauret, S. Moune, F. Aguilera. Sr–Pb isotopes signature of Lascar volcano (Chile): Insight into contamination of arc magmas ascending through a thick continental crust. Journal of South American Earth Sciences, Elsevier, 2020, 101, pp.102599. 10.1016/j.jsames.2020.102599. hal-03004128 HAL Id: hal-03004128 https://hal.uca.fr/hal-03004128 Submitted on 13 Nov 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Copyright Manuscript File Sr-Pb isotopes signature of Lascar volcano (Chile): Insight into contamination of arc magmas ascending through a thick continental crust 1N. Sainlot, 1I. Vlastélic, 1F. Nauret, 1,2 S. Moune, 3,4,5 F. Aguilera 1 Université Clermont Auvergne, CNRS, IRD, OPGC, Laboratoire Magmas et Volcans, F-63000 Clermont-Ferrand, France 2 Observatoire volcanologique et sismologique de la Guadeloupe, Institut de Physique du Globe, Sorbonne Paris-Cité, CNRS UMR 7154, Université Paris Diderot, Paris, France 3 Núcleo de Investigación en Riesgo Volcánico - Ckelar Volcanes, Universidad Católica del Norte, Avenida Angamos 0610, Antofagasta, Chile 4 Departamento de Ciencias Geológicas, Universidad Católica del Norte, Avenida Angamos 0610, Antofagasta, Chile 5 Centro de Investigación para la Gestión Integrada del Riesgo de Desastres (CIGIDEN), Av. -
Wang Et Al., 2001
American Mineralogist, Volume 86, pages 790–806, 2001 Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy ALIAN WANG,* BRAD L. JOLLIFF, LARRY A. HASKIN, KARLA E. KUEBLER, AND KAREN M. VISKUPIC Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, St. Louis, Missouri 63130, U.S.A. ABSTRACT This study reports the use of Raman spectral features to characterize the structural and composi- tional characteristics of different types of pyroxene from rocks as might be carried out using a por- table field spectrometer or by planetary on-surface exploration. Samples studied include lunar rocks, martian meteorites, and terrestrial rocks. The major structural types of quadrilateral pyroxene can be identified using their Raman spectral pattern and peak positions. Values of Mg/(Mg + Fe + Ca) of pyroxene in the (Mg, Fe, Ca) quadrilateral can be determined within an accuracy of ±0.1. The preci- sion for Ca/(Mg + Fe + Ca) values derived from Raman data is about the same, except that correc- tions must be made for very low-Ca and very high-Ca samples. Pyroxenes from basalts can be distinguished from those in plutonic equivalents from the distribution of their Mg′ [Mg/(Mg + Fe)] and Wo values, and this can be readily done using point-counting Raman measurements on unpre- pared rock samples. The correlation of Raman peak positions and spectral pattern provides criteria to distinguish pyroxenes with high proportions of non-quadrilateral components from (Mg, Fe, Ca) quadrilateral pyroxenes. INTRODUCTION pyroxene group of minerals is amenable to such identification Laser Raman spectroscopy is well suited for characteriza- and characterization. -
Cold Subduction and the Formation of Lawsonite Eclogite – Constraints from Prograde Evolution of Eclogitized Pillow Lava from Corsica
J. metamorphic Geol., 2010, 28, 381–395 doi:10.1111/j.1525-1314.2010.00870.x Cold subduction and the formation of lawsonite eclogite – constraints from prograde evolution of eclogitized pillow lava from Corsica E. J. K. RAVNA,1 T. B. ANDERSEN,2 L. JOLIVET3 AND C. DE CAPITANI4 1Department of Geology, University of Tromsø, N-9037 Tromsø, Norway ([email protected]) 2Department of Geosciences and PGP, University of Oslo, PO Box 1047, Blindern, 0316 Oslo, Norway 3ISTO, UMR 6113, Universite´ dÕOrle´ans, 1A Rue de la Fe´rollerie, 45071 Orle´ans, Cedex 2, France 4Mineralogisch-Petrographisches Institut, Universita¨t Basel, Bernoullistrasse 30, 4056 Basel, Switzerland ABSTRACT A new discovery of lawsonite eclogite is presented from the Lancoˆne glaucophanites within the Schistes Lustre´ s nappe at De´ file´ du Lancoˆne in Alpine Corsica. The fine-grained eclogitized pillow lava and inter- pillow matrix are extremely fresh, showing very little evidence of retrograde alteration. Peak assemblages in both the massive pillows and weakly foliated inter-pillow matrix consist of zoned idiomorphic Mg-poor (<0.8 wt% MgO) garnet + omphacite + lawsonite + chlorite + titanite. A local overprint by the lower grade assemblage glaucophane + albite with partial resorption of omphacite and garnet is locally observed. Garnet porphyroblasts in the massive pillows are Mn rich, and show a regular prograde growth-type zoning with a Mn-rich core. In the inter-pillow matrix garnet is less manganiferous, and shows a mutual variation in Ca and Fe with Fe enrichment toward the rim. Some garnet from this rock type shows complex zoning patterns indicating a coalescence of several smaller crystallites. -
A Comparative Study of Jadeite, Omphacite and Kosmochlor Jades from Myanmar, and Suggestions for a Practical Nomenclature
Feature Article A Comparative Study of Jadeite, Omphacite and Kosmochlor Jades from Myanmar, and Suggestions for a Practical Nomenclature Leander Franz, Tay Thye Sun, Henry A. Hänni, Christian de Capitani, Theerapongs Thanasuthipitak and Wilawan Atichat Jadeitite boulders from north-central Myanmar show a wide variability in texture and mineral content. This study gives an overview of the petrography of these rocks, and classiies them into ive different types: (1) jadeitites with kosmochlor and clinoamphibole, (2) jadeitites with clinoamphibole, (3) albite-bearing jadeitites, (4) almost pure jadeitites and (5) omphacitites. Their textures indicate that some of the assemblages formed syn-tectonically while those samples with decussate textures show no indication of a tectonic overprint. Backscattered electron images and electron microprobe analyses highlight the variable mineral chemistry of the samples. Their extensive chemical and textural inhomogeneity renders a classiication by common gemmological methods rather dificult. Although a deinitive classiication of such rocks is only possible using thin-section analysis, we demonstrate that a fast and non-destructive identiication as jadeite jade, kosmochlor jade or omphacite jade is possible using Raman and infrared spectroscopy, which gave results that were in accord with the microprobe analyses. Furthermore, current classiication schemes for jadeitites are reviewed. The Journal of Gemmology, 34(3), 2014, pp. 210–229, http://dx.doi.org/10.15506/JoG.2014.34.3.210 © 2014 The Gemmological Association of Great Britain Introduction simple. Jadeite jade is usually a green massive The word jade is derived from the Spanish phrase rock consisting of jadeite (NaAlSi2O6; see Ou Yang, for piedra de ijada (Foshag, 1957) or ‘loin stone’ 1999; Ou Yang and Li, 1999; Ou Yang and Qi, from its reputed use in curing ailments of the loins 2001). -
Pyroxenes, Amphibole, and Mica from the Tiree Marble. 1 (With Plate XIV.)
230 Pyroxenes, amphibole, and mica from the Tiree marble. 1 (With Plate XIV.) By A. F. HALLIMOND,M.A., Sc.D. With chemical analyses by C. O. HARVEY, B.Sc., A.R.C.S. [Read March 27, 1947.] I. INTRODUCTION. HE Tiree pink marble, a fine-grained, severely crushed limestone T with evidence of earlier coarse crystallization, is exposed in several small areas up to 100 feet across on the farm of Balephetrish near the north coast of the island of Tiree in the Hebrides. It contains a r~mark- able quantity of dark silicate minerals and has discordant contacts with the adjacent Lewisian gneiss. The precise nature of its relation to the gneiss, and mode of emplacement, have been much discussed. ~ The writer has been permitted to consult accounts of the literature, by Mr. V. A. Eyles, and of the petrography, by Sir Edward B. Bailey, and is also indebted to those authors for discussion of the problems. At the suggestion of Sir Edward Bailey the present work was undertaken as a contribution to the study of this problem from the mineralogical point of view. Most of the determinations were made in 1938, but it was not possible to complete publication at that time. Scattered somewhat evenly throughout the carbonate groundmass of the marble are numerous dark green crystalline patches which usually do not exceed half an inch across and are often much smaller; locally, however, there are pieces of dark gneiss-like rock of much larger size. The majority consist of pyroxene, sometimes accompanied by amphi- bole, &c., and the latter were regarded by Coom~rasw~my and others as modified gneiss inclusions. -
Eclogite Resembling Metamorphic Disequilibrium Assemblage Formed Through Fuid‑Induced Metasomatic Reactions Sanghoon Kwon1, Vinod O
www.nature.com/scientificreports OPEN Eclogite resembling metamorphic disequilibrium assemblage formed through fuid‑induced metasomatic reactions Sanghoon Kwon1, Vinod O. Samuel1*, Yungoo Song1, Sung Won Kim2, Seung‑Ik Park3, Yirang Jang4 & M. Santosh5,6 Equilibrium omphacite‑garnet‑bearing mafc rocks have been classifed as eclogites, either pristine or retrogressed, that were formed at great depths in the lithosphere. Here we report a unique natural example of eclogite resembling assemblage in disequilibrium formed through fuid‑induced metasomatic reactions under the amphibolite to granulite facies. Primarily, the amphibolized protolith experienced a garnet‑amphibolite facies metamorphism at ~ 500–700 °C and ~ 0.8–1 GPa. Subsequently, CO2 fuid induced fracturing and dissolution‑reprecipitation reactions occurred at peak metamorphic conditions of ~ 700 °C and ~ 1 GPa. Occasional omphacite‑albite assemblage, which gradually replace diopside‑oligoclase symplectite adjacent to albite veins along fractures, indicates fuid‑induced coupled dissolution‑reprecipitation disequilibrium reactions. Here the albite‑omphacite assemblage is in local equilibrium at least on 1 mm length scale, during cooling, below ~ 600 ºC and ~ 1 GPa, within the amphibolite facies conditions. The results from this study clearly suggest that disequilibrium garnet‑omphacite assemblage in mafc rocks could be formed by crustal reworking processes below granulite facies conditions, and their textural equilibrium is an important criterion while defning eclogite facies. Eclogite facies metamorphic rocks formed through subduction and collision processes are common in global orogenic belts1–12 (e.g., Usagaran belt 1, Belomorian Belt2, Trans-Hudson orogen3, Grenvillian-Caledonian belt 4,5 Qinling–Dabie–Sulu belt6, Appalachian Orogenic Belt 7, Central Asian Orogenic Belt 8, Sambagawa belt 9, Alpine- Himalayan belt10,11, Franciscan complex12 etc.) created throughout Earth’s history.