Acetone Safety Data Sheet According to Federal Register / Vol
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Zheng31sympa.Pdf
Proceedings of the Combustion Institute Proceedings of the Combustion Institute 31 (2007) 1215–1222 www.elsevier.com/locate/proci High temperature ignition and combustion enhancement by dimethyl ether addition to methane–air mixtures q Zheng Chen, Xiao Qin, Yiguang Ju *, Zhenwei Zhao, Marcos Chaos, Frederick L. Dryer Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544, USA Abstract The effects of dimethyl ether (DME) addition on the high temperature ignition and burning properties of methane–air mixtures were studied experimentally and numerically. The results showed that for a homo- geneous system, a small amount of DME addition to methane resulted in a significant reduction in the high temperature ignition delay. The ignition enhancement effect by DME addition was found to exceed that possible with equivalent amounts of hydrogen addition, and it was investigated by using radical pool growth and computational singular perturbation analysis. For a non-premixed methane–air system, it was found that two different ignition enhancement regimes exist: a kinetic limited regime and a transport limited regime. In contrast to the dramatic ignition enhancement in the kinetic limited regime, the ignition enhancement in the transport limited regime was significantly less effective. Furthermore, laminar flame speeds as well as Markstein lengths were experimentally measured for methane–air flames with DME addi- tion. The results showed that the flame speed increases almost linearly with DME addition. However, the Markstein length and the Lewis number of the binary fuel change dramatically at small DME concentra- tions. Moreover, comparison between experiments and numerical simulations showed that only the most recent DME mechanism well reproduced the flame speeds of both DME–air and CH4–air flames. -
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Safety Data Sheet
Safety Data Sheet Hazardous Chemical, Dangerous Goods 1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION Product name: Acetone Synonyms Product Code Acetone, 1 Litre 9AC1L Acetone, 20 Litres 9AC20L Acetone, 200 Litres 9AC200L Acetone, 4 Litres 9AC4L Recommended use: Solvents used in the processing of resins, lacquers, waxes, adhesives, inks, paints and plastics Supplier: Glendale Packaging Pty Ltd ABN: 74 114 020 450 Street Address: Unit 1/75 Newton Road Wetherill Park NSW 2164 Australia Telephone: 02 9756-2315 Facsimile: 02 9756-2316 Emergency telephone number: 02 9756-2315 (Mon-Fri; 8am-4:30pm; AEST) 2. HAZARDS IDENTIFICATION This material is hazardous according to health criteria of Safe Work Australia. Signal Word Danger Hazard Classifications Flammable Liquids - Category 2 Serious Eye Damage/Irritation - Category 2A Specific Target Organ Toxicity (Single Exposure) - Category 3 Narcotic Effects Hazard Statements H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Prevention Precautionary Statements P102 Keep out of reach of children. P103 Read label before use. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical, ventilating, lighting and all other equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust, fume, gas, mist, vapours or spray.. P264 Wash hands, face and all exposed skin thoroughly after handling. Product Name: Acetone Reference No: GP00003 Issued: 2016-09-16 Version: 1.1 Page 1 of 8 Safety Data Sheet P271 Use only outdoors or in a well-ventilated area. -
Ethylene Glycol Dimethyl Ether.Pdf
SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.0 Revision Date 03/14/2010 Print Date 09/08/2010 1. PRODUCT AND COMPANY IDENTIFICATION Product name : 1,2-Dimethoxyethane Product Number : 259527 Brand : Sigma-Aldrich Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +18003255832 Fax : +18003255052 Emergency Phone # : (314) 776-6555 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards Flammable liquid, Target Organ Effect, Reproductive hazard Target Organs Liver, Kidney, Blood, Central nervous system, Female reproductive system., Male reproductive system. GHS Label elements, including precautionary statements Pictogram Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. H303 May be harmful if swallowed. H332 Harmful if inhaled. H360 May damage fertility or the unborn child. Precautionary statement(s) P201 Obtain special instructions before use. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P308 + P313 IF exposed or concerned: Get medical advice/attention. HMIS Classification Health hazard: 1 Chronic Health Hazard: * Flammability: 3 Physical hazards: 0 NFPA Rating Health hazard: 0 Fire: 3 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Sigma-Aldrich - 259527 Page 1 of 6 Ingestion May be harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : Monoglyme Dimethylglycol mono-Glyme Ethylene glycol dimethyl ether Formula : C4H10O2 Molecular Weight : 90.12 g/mol CAS-No. EC-No. Index-No. Concentration Ethylene glycol dimethyl ether 110-71-4 203-794-9 603-031-00-3 - 4. -
Sample Chapter Template for AFFA
The Training Material on “Dangerous Goods Handling (All modes)” has been produced under Project Sustainable Human Resource Development in Logistic Services for ASEAN Member States with the support from Japan-ASEAN Integration Fund (JAIF). Copyright Association of Southeast Asian Nations (ASEAN) 2014. All rights reserved. Dangerous Goods Handling Chapter 2: International Classification of Dangerous Goods Objectives This chapter will explain UN Transport regulations, its history and basis as model regulations for international classification system for other modes of transport. The linkage into the ASEAN Protocol 9 framework on the international carriage of dangerous goods in ASEAN will also be explained. 9 classes of dangerous goods classification shall be key content in this chapter. Other relevant basic terms such as Class, Division, Packaging Group (PG), UN Number (UNNO) and Proper Shipping Names (PSN) will also be covered. As supplement knowledge in classification of substances or mixtures that have more than one hazard, the explanation on precedence of hazard characteristics will be given. Basic hazard communication such as Labelling requirements, Dangerous Goods Declaration (DGD) or Multi-modal Dangerous Goods Form shall be explained. 1. Introduction 1.1 United Nations Recommendations on the Transport of Dangerous Goods (UNTDG/UNRTDG) These Recommendations have been developed by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods in the light of technical progress, the advent of new substances and materials, the exigencies of modern transport systems and, above all, the requirement to ensure the safety of people, property and the environment. They are addressed to governments and international organizations concerned with the regulation of the transport of dangerous goods. -
Selective Carbonylation of Dimethyl Ether to Methyl Acetate on Ferrierite
Catalysis Communications 75 (2016) 28–31 Contents lists available at ScienceDirect Catalysis Communications journal homepage: www.elsevier.com/locate/catcom Short communication Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite So Young Park a, Chae-Ho Shin b,JongWookBaea,⁎ a School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon, Gyeonggi-do 440-746, Republic of Korea b Department of Chemical Engineering, Chungbuk National University (CNU), Cheongju, Chungbuk 361-763, Republic of Korea article info abstract Article history: Synthesis of methyl acetate (MA) by carbonylation of dimethyl ether (DME) was investigated using laboratory- Received 19 August 2015 made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER with a Si/Al ratio of Received in revised form 6 November 2015 12 (FER(12)) revealed a higher DME conversion as well as MA selectivity. The observed higher catalytic perfor- Accepted 9 December 2015 mance on the FER(12) was mainly attributed to a higher ratio of Bronsted to Lewis acid sites as well as the higher Available online 10 December 2015 crystallinity with the less coke formation. The superior properties of the FER(12) having a higher ratio of Bronsted fi Keywords: to Lewis acid sites and crystallinity ef ciently suppressed the formation of inactive coke precursors. Carbonylation © 2015 Elsevier B.V. All rights reserved. Dimethyl ether Methyl acetate Ferrierite Coke formation 1. Introduction can be finally regenerated by forming an adsorbed methyl group [12, 13]. Interestingly, the micropores of the H-form Ferrierite (H-FER), Carbonylation reaction of dimethyl ether (DME) with CO has been which has one-dimensional channels of 8-MR with perpendicularly largely investigated to selectively synthesize an important petrochemi- intersected channels of 10-MR structures, seem to be effective for cal intermediate or alternative clean fuels [1,2]. -
Hazardous Materials Regulations (HMR) and Should Not Be Used to Determine Compliance with the HMR
HOW TO USE The Hazardous Materials Re ulations CFR 49 Parts 100 To 185 g U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration How to Use the HMR TABLE OF CONTENTS Preface............................................................................................................................. i Information/Recommendations ................................................................................... 1 Structure of the Code of Federal Regulations ............................................................ 2 Basic Outline ........................................................................................................... 2 Pyramid Diagram .................................................................................................... 3 Rules of Construction ............................................................................................. 3 Exercises......................................................................................................................... 4 Exercise 1: Parts ..................................................................................................... 4 Exercise 2: Locating Reference Numbers ............................................................... 5 Exercise 3: Suggested Tabbing ............................................................................... 6 Exercise 4: Finding a Specific Section .................................................................... 8 Exercise 5: Communicating the Hazard ................................................................. -
Dangerous Goods Classifications
Dangerous Goods Classifications Dangerous Goods Classifications Click on a class to read more details: 1. Explosives 2. Gases 3. Flammable Liquids 4. Flammable Solids 5. Oxidizing Substances 6. Toxic & Infectious Substances 7. Radioactive Material 8. Corrosives 9. Miscellaneous Dangerous Goods CLASS 1: EXPLOSIVES Explosives are materials or items which have the ability to rapidly conflagrate or detonate as a consequence of chemical reaction. Subclass Subclass 1.1: Explosives with a mass explosion hazard Consists of explosives that have a mass explosion hazard. A mass explosion is one which affects almost the entire load instantaneously. Subclass 1.2: Explosives with a severe projection hazard Consists of explosives that have a projection hazard but not a mass explosion hazard. Subclass 1.3: Explosives with a fire Consists of explosives that have a fire hazard and either a minor blast hazard or a minor projection hazard or both but not a mass explosion hazard. Subclass 1.4: Minor fire or projection hazard Consists of explosives that present a minor explosion hazard. The explosive effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Subclass 1.5: An insensitive substance with a mass explosion hazard Consists of very insensitive explosives with a mass explosion hazard (explosion similar to 1.1). This division is comprised of substances which have a mass explosion hazard but are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport. -
Emergency Response Guidebook.Pdf
UNEP-ICCA Project “Promo2ng Chemical Safety Management in the African Region” Training Workshop on Emergency Preparedness anD Dangerous GooDs Handling Tema, Ghana, 16-19 June 2014 Timothy R Gablehouse Colorado Emergency Planning Commission ERG2012 The Emergency Response GuiDebook 2012 (ERG2012) is primarily a guiDe to aiD first responDers in quickly iDen2fying the specific or generic hazards of the material(s) involved in the incident, and protec2ng themselves and the general public during the inial response phase of the inciDent. Before an emergency – become familiar with this guiDebook! 2 Overview of the ERG2012 The main sec@ons are: § Table of placards (pages 6-7) § Railcar & Trailer Iden@ficaon charts (pages 8-9) § YELLOW sec@on (ID numbers) § BLUE sec@on (names of material) § ORANGE secon (guide pages) § GREEN sec@on (ini@al isolaon and protec@ve ac@on distances for highlighted substances) 3 Overview of the ERG2012 The new secons are § TABLE 3 - Ini2al Isola2on anD Protec2ve Ac2on Distances for Different Quan22es of Six Common TIH Gases (pages 352-355) § BLEVE - Boiling Liquid Expanding Vapour Explosion (pages 364- 367) § Improvised Explosive Device - IED (page 372) TIH: Toxic Inhalation Hazard 4 Additional Sections Other ERG2012 sections, not covered in the presentation, but suggested for reading: § Shipping Documents (inside front page cover) § Safety Precautions (page 2) § Hazard Classification System (page 4) § Hazard Identification Numbers Displayed on Some Intermodal Containers (pages 10-13) § Pipeline Transportation (pages 14-19) § Protective Actions (pages 287-288) § Protective Clothing (pages 361-362) § Fire and Spill Control (pages 363-364) § Criminal / Terrorist Use of Chemical / Biological / Radiological Agents (pages 368-371) § Glossary (pages 374-382) 5 Table of Placards § The different placards used in the transport of dangerous goods are found on pages 6 and 7 of the ERG2012. -
Sds – Safety Data Sheet
Effective Date: 02/05/16 Replaces Revision: 01/01/13, 02/26/09 NON-EMERGENCY TELEPHONE 24-HOUR CHEMTREC EMERGENCY TELEPHONE 610-866-4225 800-424-9300 SDS – SAFETY DATA SHEET 1. Identification Product Identifier: ACETONE / ISOPROPYL ALCOHOL BLEND Synonyms: None Chemical Formula: Not Applicable to mixtures Recommended Use of the Chemical and Restrictions On Use: Laboratory Reagent Manufacturer / Supplier: Puritan Products; 2290 Avenue A, Bethlehem, PA 18017 Phone: 610-866-4225 Emergency Phone Number: 24-Hour Chemtrec Emergency Telephone 800-424-9300 2. Hazard(s) Identification Classification of the Substance or Mixture: Flammable liquids (Category 2) Skin irritation (Category 3) Eye irritation (Category 2A) Specific target organ toxicity - single exposure (Category 3) Risk Phrases: R11: Highly flammable. R36: Irritating to eyes. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapors may cause drowsiness and dizziness. Label Elements: Trade Name: ACETONE / ISOPROPYL ALCOHOL BLEND Signal Word: Danger Hazard Statements: H225: Highly flammable liquid and vapor. H316: Causes mild skin irritation. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. ACETONE / ISOPROPYL ALCOHOL BLEND Page 1 of 6 Precautionary Statements: P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261: Avoid breathing dust / fume / gas / mist / vapors / spray. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 3. Composition / Information on Ingredients CAS Number: Not Applicable to mixtures Molecular Weight: Not Applicable to mixtures Ingredient CAS Number EC Number Percent Hazardous Chemical Characterization Acetone 67 - 64 - 1 200-662-2 70 - 90% Yes Substance Isopropyl Alcohol 67 - 63 - 0 200-661-7 10 - 30% Yes Substance 4. -
SAFETY DATA SHEET Acetone
SAFETY DATA SHEET Acetone Revision date: 12.05.15 SDS/004/8 Page 1 of 6 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Acetone EC No. 200-662-2 1.2. Relevant identified uses of the substance or mixture and uses advised against Household Solvent 1.3. Details of the supplier of the safety data sheet Thornton & Ross Ltd, Linthwaite, Huddersfield, HD7 5QH Tel: 01484 842217 Fax: 01484 847301 Email: [email protected] 1.4 Emergency telephone number: Out of normal working hours: +44 870 8510207 2. Hazards identification 2.1. Classification of the substance or mixture According to Regulation EC 1272/2008 classified as Flammable Liquid Category 2, Eye Irritant Category 2, Specific Target Organ Toxicity Single Exposure Category 3. 2.2. Label element GHS Pictogram Signal Word Hazard Class Danger Flammable Liquids, Category 2 Eye Irritation, Category 2 Specific Target Organ Toxicity-Single Exposure, Category 3 Hazard Statements Precautionary statements H225: Highly flammable liquid and vapour. P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking. H319: Causes serious eye irritation P305+351+338: IF IN EYES: Rinse cautiously with H336: May cause drowsiness or dizziness water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. P337+313: Get medical advice/attention. P403: Store in a well ventilated place. Supplemental Hazard Information (EU) EUH066: Repeated exposure may cause skin dryness or cracking 2.3. Other hazards N/A SAFETY DATA SHEET Acetone Revision date: 12.05.15 SDS/004/8 Page 2 of 6 3. -
Combustion and Emissions Characteristics of a Compression-Ignition Engine Using Ammonia-DME Mixtures Christopher Wolfgang Gross Iowa State University
Iowa State University Capstones, Theses and Graduate Theses and Dissertations Dissertations 2012 Combustion and emissions characteristics of a compression-ignition engine using ammonia-DME mixtures Christopher Wolfgang Gross Iowa State University Follow this and additional works at: https://lib.dr.iastate.edu/etd Part of the Mechanical Engineering Commons Recommended Citation Gross, Christopher Wolfgang, "Combustion and emissions characteristics of a compression-ignition engine using ammonia-DME mixtures" (2012). Graduate Theses and Dissertations. 12589. https://lib.dr.iastate.edu/etd/12589 This Thesis is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Graduate Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. Combustion and emissions characteristics of a compression- ignition engine using ammonia-DME mixtures by Christopher W. Gross A thesis submitted to the graduate faculty in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Major: Mechanical Engineering Program of Study Committee: Song-Charng Kong, Major Professor Terrence Meyer Stuart Birrell Iowa State University Ames, Iowa 2012 Copyright © Christopher W. Gross, 2012. All rights reserved. ii Table of Contents List of Figures ........................................................................................................................