Safety Data Sheet (SDS) Report SDS number: P202003130 5 Applicant: Yangzhou Russell Biotechnology Co., Ltd. Issue Date: 2020 -03-24 Dinggou Industrial Concentration Zone, Jiangdu District, Yangzhou City, Jiangsu China. Jiangsu Hanhe Daily Commodity Co. , Ltd. No.9, Weichai Avenue, Hanjiang district, Yangzhou city, Jiangsu China.
Sample Description: The sample information was submitted and identified on client’s behalf to be: Product Name : Alcohol based hand sanitizer, hand sanitizer Physical State : Liquid Data Received : Mar 13, 2020 Last information Date: Mar 24, 2020 Data Reviewed : Mar 24, 2020
Service Requested: Based on the information provided by the applicant, the Safety Data Sheet (SDS) was generated in accordance with requirements of GB/T16483- 2008 and GB/T17519-2013, for details please refer to attached pages.
Authorized By: On Behalf Of Regulatory Affairs in Intertek Testing Services Ltd., Shanghai
Anna Wang This report shall not be reproduced except in full, without the written Regulatory Consultant approval of the laboratory.
Intertek Health, Environmental &Regulatory Services (HERS) 5th Floor,Building No.86,1198 QinZhou Road(North),Cao Hejing Development Zone,ShangHai,China.
Tel: +86 021 53397917 ZIP: 200233 E-mail:[email protected]
SAFETY DATA SHEET
Alcohol based hand sanitizer, hand sanitizer Jiangsu Hanhe Daily Commodity Co. , Ltd. SDS Number:P2020031305 Version No:1.0 Issue Date:24/03/2020 Authored according to GB/T16483(2008) and GB/T17519(2013) GHS.CHN.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Alcohol based hand sanitizer, hand sanitizer Proper shipping name ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Other means of identification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Antibacterial and handwashing
Details of the supplier of the safety data sheet
Manufacturer name Yangzhou Russell Biotechnology Co., Ltd. Address Dinggou Industrial Concentration Zone, Jiangdu District, Yangzhou City, Jiangsu China. Supplier name Jiangsu Hanhe Daily Commodity Co. , Ltd. Address No.9, Weichai Avenue, Hanjiang district, Yangzhou city, Jiangsu China. Telephone +86-13365118979 Email [email protected] Importer name Address Telephone Email
Emergency telephone number
Association / Organisation Emergency telephone
numbers
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
SUMMARY OF HAZARD IN AN EMERGENCY SITUATION Gel.Flammable.
Classification Flammable Liquid Category 3
Label elements
Hazard pictogram(s)
SIGNAL WORD WARNING
Hazard statement(s)
H226 Flammable liquid and vapour.
Supplementary statement(s) Not Applicable
Precautionary statement(s) General
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use.
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Precautionary statement(s) Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P235 Keep cool. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Precautionary statement(s) Storage
P403+P235 Store in a well-ventilated place. Keep cool.
Precautionary statement(s) Disposal
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
Physical and Chemical Hazard Gel.Flammable. HIGHLY FLAMMABLE.
Health Hazards
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal Inhaled models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
The material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'. This is because of the lack of Ingestion corroborating animal or human evidence.
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Skin Contact Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Direct contact of the eye with ethanol (alcohol) may cause an immediate stinging and burning sensation, with reflex closure of the lid, and a Eye temporary, tearing injury to the cornea together with redness of the conjunctiva. Discomfort may last 2 days but usually the injury heals without treatment.
This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which can Chronic produce severe defects.
Environmental Hazards See Section 12 Other hazards Not Available
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 80 ethanol 7732-18-5 17.855 water 56-81-5 1.45 glycerin 9003-01-4 0.5 Carbomer 102-71-6 0.07 triethanolamine 7722-84-1 0.125 hydrogen peroxide
SECTION 4 FIRST AID MEASURES
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Description of first aid measures
If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary.
Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Advise for rescue team (PPE requirement for rescue personnel)
Indication of any immediate medical attention and special treatment needed Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media Alcohol stable foam. Dry chemical powder.
Special hazards arising from the substrate or mixture
Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Advice for firefighters
Alert Fire Brigade and tell them location and nature of hazard. Fire Fighting May be violently or explosively reactive.
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Combustion products include: Fire/Explosion Hazard carbon monoxide (CO) carbon dioxide (CO2) other pyrolysis products typical of burning organic material.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures See section 8
Measures for Preventing Secondary Contamination Refer to section above
Environmental precautions See section 12
Methods and material for containment and cleaning up
Remove all ignition sources. Minor Spills Clean up all spills immediately.
Clear area of personnel and move upwind. Major Spills Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Limit all unnecessary personal contact. Safe handling Wear protective clothing when risk of exposure occurs.
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Store in original containers in approved flame-proof area. Other information No smoking, naked lights, heat or ignition sources.
Conditions for safe storage, including any incompatibilities
Suitable container PET container.
Avoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates. Storage incompatibility Avoid strong bases.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Not Available
Exposure controls
Appropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can controls be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
Personal protection
Safety glasses with side shields. Eye and face protection Chemical goggles.
Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC. Hands/feet protection Wear safety footwear or safety gumboots, e.g. Rubber
Body protection See Other protection below
Overalls. Other protection PVC Apron.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Transparent colorless gel
Physical state Gel Relative density (Water = 1) Not Available Partition coefficient n-octanol Odour Ethanol smell Not Available / water Odour threshold Not Available Auto-ignition temperature (°C) Not Available pH (as supplied) 7.39 Decomposition temperature Not Available Melting point / freezing point Not Available Viscosity (cSt) Not Available (°C) Initial boiling point and boiling Not Available Molecular weight (g/mol) Not Available range (°C)
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available Flammability Flammable Oxidising properties Not Available Surface Tension (dyn/cm or Upper Explosive Limit (%) Not Available Not Available mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water Not Available pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
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Unstable in the presence of incompatible materials. Chemical stability Product is considered stable.
Possibility of hazardous See section 7 reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition See section 5 products
SECTION 11 TOXICOLOGICAL INFORMATION
ethanol
Inhalation (rat) LC50: 124.7 mg/l/4H[2]
glycerol
Oral (rat) LD50: >10000 mg/kg[2]
Carbomer
Dermal (rabbit) LD50: >2000 mg/kg[1]
Dermal (rabbit) LD50: >3000 mg/kg[2]
[2] Acute Toxicity Oral (rat) LD50: >2500 mg/kg Oral (rat) LD50: 4100 mg/kg[2]
triethanolamine
dermal (rat) LD50: >2000 mg/kg[2]
Oral (rat) LD50: 4190 mg/kg[2]
castor oil, hydrogenated, ethoxylated
[1] dermal (rat) LD50: >2000 mg/kg Oral (rat) LD50: >20000 mg/kg[2]
Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin Based on available data, the classification criteria are not met. sensitisation Germ cell mutagenicity Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Carcinogenicity CAS NO IARC Group 102-71-6 3
Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met.
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
Alcohol based hand sanitizer, hand sanitizer Based on available data, the classification criteria are not met.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days) glycerol LOW LOW Carbomer LOW LOW triethanolamine LOW LOW
Bioaccumulative potential
Ingredient Bioaccumulation
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ethanol LOW (LogKOW = -0.31) glycerol LOW (LogKOW = -1.76) Carbomer LOW (LogKOW = 0.4415) triethanolamine LOW (BCF = 3.9)
Mobility in soil
Ingredient Mobility ethanol HIGH (KOC = 1) glycerol HIGH (KOC = 1) Carbomer HIGH (KOC = 1.201) triethanolamine LOW (KOC = 10)
Other adverse effects No data available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible. Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. Waste chemicals: DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
Contaminated packing Refer to section above materials: Precautions for Transport: Refer to section above
SECTION 14 TRANSPORT INFORMATION
Marine Pollutant NO
Land transport (UN)
UN number 1170 UN proper shipping name ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Class 3 Transport hazard class(es) Subrisk Not Applicable
Packing group III Environmental hazard Not Applicable
Special provisions 144; 223 Special precautions for user Limited quantity 5 L
Air transport (ICAO-IATA / DGR)
UN number 1170 UN proper shipping name Ethanol or Ethanol. solution
ICAO/IATA Class 3 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 3L
Packing group III Environmental hazard Not Applicable
Special provisions A3 A58 A180 Cargo Only Packing Instructions 366 Cargo Only Maximum Qty / Pack 220 L Special precautions for user Passenger and Cargo Packing Instructions 355 Passenger and Cargo Maximum Qty / Pack 60 L Passenger and Cargo Limited Quantity Packing Instructions Y344
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Passenger and Cargo Limited Maximum Qty / Pack 10 L
Sea transport (IMDG-Code / GGVSee)
UN number 1170 UN proper shipping name ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
IMDG Class 3 Transport hazard class(es) IMDG Subrisk Not Applicable
Packing group III Environmental hazard Not Applicable
EMS Number F-E , S-D Special precautions for user Special provisions 144 223 Limited Quantities 5 L
Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable Precautions for Transport Transportation precautions: • Documentation covering all dangerous goods carried on the vehicle • The transport unit must be placarded and marked in accordance with relevant transporting requirements. • Personal protective equipment must be in sufficient quantities and suitable for use by the driver of the vehicle and where required for escape purposes, any other persons travelling in the vehicle.
Suitable Containers See section 7
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances China Inventory of Hazardous Chemicals (Chinese)
WATER IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances
GLYCEROL IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances
CARBOMER IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances
TRIETHANOLAMINE IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs
CASTOR OIL, HYDROGENATED, ETHOXYLATED IS FOUND ON THE FOLLOWING REGULATORY LISTS China Inventory of Existing Chemical Substances
PARFUM IS FOUND ON THE FOLLOWING REGULATORY LISTS Not Applicable
SECTION 16 OTHER INFORMATION
Other information The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
Definitions and abbreviations PC－TWA: Permissible Concentration-Time Weighted Average PC－STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit。 IDLH: Immediately Dangerous to Life or Health Concentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value
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LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index
Disclaimer The information in the SDS applies only for the specified product and does not include mixtures of this product with other substances and mixtures. The SDS provides product safety information for personnel trainned to use this product only.
end of SDS