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Groundwater and Pesticides

About 50 percent of the U.S. population relies on groundwater for drinking . Rural populations utilizing groundwater for may reach 95 percent. Groundwater feeds drinking-water . Because of the potential risk to human health, of groundwater is a national topic.

What Is Groundwater? Simply put, groundwater is located below the earth’s surface, while is found above the earth’s surface. Because it is underground, groundwater is found in spaces within , sediment, sand, gravel, and rocks. Studies now show that the soil does not act as a barrier to prevent pesticides and other chemicals from reaching groundwater, contrary to the thinking prior to the 1970s.

Groundwater Contamination are found in water-bearing beds of rock, gravel or sand and contain fresh, brackish or salty water. If the is large enough, it can feed a U.S. Geological Survey public water system. Groundwater can discharge from an aquifer into surface water, including rivers, lakes and wetlands. If the groundwater is contaminated, these surface water bodies can Pesticide Properties Related to Groundwater become contaminated, as . Specific properties of pesticides and other chemicals Contamination of groundwater by any chemical that influence its ability to reach groundwater can take years even decades to develop. This delay incorporate: between chemicals entering the environment and • Solubility – How dissolvable is it in water? Is it possibly polluting groundwater depends upon many hydrophobic? factors, including the properties of the chemical, • Soil adsorption – How strongly does it stick to the permeability of the soil or sediment, climate soil? How mobile is it in soil? conditions, management practices, and the depth of drinking-water wells. • Degradation – How quickly does it break down in the root zone? Sources of Groundwater Contamination • Volatilization – Does it evaporate into the Groundwater contamination can come from atmosphere? applications to crops, from contaminated Here are some examples of the relevance of these surface water, accidental spills and leaks, and properties with respect to groundwater: improper storage and disposal. It can also occur through runoff from fields after , melted snow • A pesticide that is not soluble in water and binds or water. Not all pesticides have been strongly to soil is basically immobile and not found to leach into groundwater, so it is important likely to reach groundwater. It typically remains to understand the chemical-physical properties in upper soil layers until degradation occurs. of a pesticide in order to predict its potential for contaminating groundwater. GROUNDWATER AND PESTICIDES

• A pesticide that moves freely through soil will and loading site or a direct discharge into water contaminate groundwater if it is not degraded from an industrial or treatment . first – this consequence is especially true for A non-point source of can come from water-soluble pesticides carried by water down a broad or diffuse area where a specific source through the soil. may not be identifiable. An example of this type • A highly volatile pesticide (exclusive of soil of pollution includes contamination caused by fumigants) is mainly lost to the atmosphere rainfall or melted snow moving over the ground. and not likely to leach into groundwater. As this runoff moves, it picks up contaminants and eventually deposits them into bodies of water Factors Influencing Groundwater Contamination including groundwater. from Pesticides Another nonpoint example would involve broadcast In addition to pesticide properties, other factors applications of pesticides moving into water bodies. affect the potential of pesticides leaching into The U.S. Environmental Protection Agency (USEPA) groundwater. Soil texture, permeability, organic has received reports from some states that non-point- content and structure play a role in groundwater source pollution is the main problem in contamination. Coarse soil allows swifter movement issues. Most of the pesticides that end up in water of water down through the soil, potentially carrying are from runoff from across treated surfaces or from pesticides to groundwater as the opportunity to downward leaching through the soil or sediment from adsorb to the soil is decreased. The same principle the surface – this downward leaching is especially applies to highly permeable soil. Applying or problematic for groundwater. Polluted runoff water plowing under cover crops increases the soil’s organic can travel great distances through drainage ditches, content, holding water and dissolved pesticides in streams, ponds or other surface . the root zone. Soil structure that is loosely packed or contains animal borings enhances downward Maximum Contaminant Limits (MCLs) movement of water and dissolved pesticides for Pesticides potentially contaminating groundwater. The USEPA has instituted MCLs for pesticides Site conditions affect the possibility of groundwater in drinking water. Drinking water wells sampled pollution. The depth of groundwater plays a role, mainly in agricultural areas across the U.S. revealed as some groundwater locations are only a few feet that less than 2 percent of the wells sampled had from the surface. Geologic conditions contribute concentrations that surpassed MCLs. However, not to soil permeability. For example, gravel is more all pesticides and their metabolites have established permeable, while is not. With topography, flat MCLs or other water-quality criteria. Additionally, with permeable allows water possibly MCLs are calculated regarding individual pesticides carrying contaminants to gather and penetrate the and do not consider potential cumulative effects if ground rather than runoff. High rates of rainfall and/ more than one pesticide is present in the same well. or heavy irrigation contribute to pesticides leaching Many pesticides and their metabolites have not been into groundwater especially just after application widely tested for in urban and suburban areas where and with permeable soils. pesticides are also used.

Point-Source or Non-Point-Source Groundwater Cleanup Contamination Once groundwater is contaminated by pesticides, Groundwater pollution can also be categorized as cleanup can be quite difficult and expensive. resulting from either point-source or non-point- The contamination could last for years, as source contamination. A point source comes from cold temperatures and low microbial activity a specific place – a place that can be identified in groundwater to slower degradation of and pointed to. Examples of point source pollution pesticides than at the soil surface. include pesticides spilled into water from a mixing GROUNDWATER AND PESTICIDES

Groundwater contamination effects include • Conservation and Recovery Act (RCRA) poor drinking water quality; loss of water supply; – Regulates treatment, storage and disposal of degraded surface water systems, including loss of hazardous and nonhazardous wastes. habitats; high cleanup costs; high costs for • Comprehensive Environmental Response, alternative water supplies; and/or potential health Compensation, and Liability Act (CERCLA, problems. A further consequence of groundwater or ) – Authorizes the government to contamination by a pesticide is the possibility of clean up contamination or sources of potential losing the use of that pesticide through its being contamination from sites or banned by the EPA. chemical spills including those that threaten drinking water supplies. Federal Regulations to Protect Groundwater Quality • Federal , Fungicide and Rodenticide Act (FIFRA) – Regulates pesticide use. The following federal regulations have been enacted to protect groundwater quality: • Toxic Substances Control Act (TSCA) – Regulates manufactured chemicals. • (CWA) – Regulates groundwater with a connection to surface water. • Safe Drinking Water Act (SDWA) – Includes regulation that public water systems meet minimum health standards.