Warm Absorber"): Modélisation Multi-Longueurs D'onde Et Diagnostics De Plasmas Dans Le Domaine Des Rayons X

Total Page:16

File Type:pdf, Size:1020Kb

Warm Absorber r"'\f'"' (ô~~) [' lJ POR THESE DE DOCTORAT PR,ESENTEE POUR OBTENIR LE TITRE DE DOCTEUR, DE L'UNIVERSITE DE PARIS 6 présentée par Delphine PORQUET Spécialité: Méthodes instrumentales en Astrophysique et leurs applications spatiales Etude du milieu fortement ionisé dans les Noyaux Actifs de Galaxies ("Warm Absorber"): Modélisation multi-longueurs d'onde et diagnostics de plasmas dans le domaine des rayons X Soutenue le 15 Octobre 1999 Jury co1nposé de: M. Jean Ballet R,apporteur M. Jacques Dubau Mme Anne-Marie Dumont M. Pierre Encrenaz Mme Martine Mouchet Directrice de thèse M. Martin W"ard Rapporteur ...-1 ,~ L/ {35 ~ Ill A rna rnère et rnon père A Nicolas A mes grands-parents IV Table des matières Résumé 1 Summary 3 Remerciements 5 I Introduction 7 1 Les Noyaux Actifs de Galaxies 9 1.1 Introduction ......... 10 1.2 Les différentes classes de NAGs 10 1.2.1 Les galaxies Radio-Quiet 11 1.2.2 Les galaxies et les NAGs Radio-Laud 17 1.3 Le modèle de source centrale . 19 1.4 Le rayonnement X dans les NAGs Radio-Quiet . 20 1.4.1 Le spectre continu et les processus d'émission 20 1.4.2 La variabilité ................. 22 1.4.3 Les principales caractéristiques en émission et en absorption 22 2 Le Warm Absorber 25 2.1 Les signatures spectrales multi-longueurs d'onde .... 26 2.1.1 Les X-mous .................... 26 2.1.2 L'ultraviolet (UV) et l'extrême-ultraviolet (EUV) 30 2.1.3 L'infrarouge et l'optique 31 2.2 La variabilité ....... 31 2.2.1 Les échelles de temps 31 2.2.2 Les observations . 32 2.3 Le cas particulier des NLS1 33 2.4 Conclusion . 34 II Plasmas et codes de calculs 35 3 Processus d'ionisation de plasmas et modélisations 37 3.1 Les modèles de plasmas pour le Warm Absorber 38 3.1.1 Les modèles photoionisés 38 3.1.2 Les plasmas mixtes ........... 39 V VI TABLE DES MATIÈRES 3.2 Les codes de calculs . 4 l 3.2.l PEGAS . 42 3.2.2 IRIS . 43 3.3 Des diagnostics de processus d'ionisation du Warm Absorber 45 III Détermination des paramètres physiques du WA 47 4 Les raies coronales 49 4.1 Le bilan observationnel 50 4.2 La modélisation . 53 4.3 Les résultats ..... 56 4.3.1 Les caractéristiques moyennes des galaxies de Seyfert 1 56 4.3.2 Le cas particulier d'une Seyfert 1: MCG-06-30-15 59 4.4 Conclusion .......... 61 4.5 Les perspectives . 63 4.6 Article I: Parquet et al. 1999 . 65 5 Les ions héliumoïdes 79 5.1 Introduction ........... 80 5.2 Le calcul des données atomiques . 82 5.3 Les diagnostics . 83 5.3.1 L'introduction aux calculs des rapports des raies . 83 5.3.2 Les diagnostics de processus d'ionisation 85 5.3.3 Les diagnostics de densité 87 5.4 Discussion . 89 5.5 Conclusion et perspectives .... 90 5.6 Article II: Parquet & Dubau 2000 9;3 IV Conclusion et perspectives 119 V Annexes 123 A Spectroscopie et processus atomiques 125 A.l Introduction de spectroscopie ..... 125 A.2 Les processus atomiques . 126 A.2.1 Les excitations et les désexcitations 126 A.2.2 L'ionisation et la recombinaison .. 127 A.2.3 Les processus intervenant dans la formation du continu 130 A.3 L'équilibre d'ionisation .... 131 A.4 L'équilibre thermique radiatif ..... 132 B La nouvelle génération des satellites X 133 B.l Introduction .................... 133 B.1.1 Les caractéristiques des futurs satellites X 133 TABLE DES MATIÈRES Vil B.1.2 Les perspectives pour les observatio11s des N AGs . 134 C Articles non soumis à comité de lecteurs 137 C.l Compte rendu de colloque I: Porquet & Dumont 1998 . 139 C.2 Compte rendu de colloque II: Dumont & Porqm~t 1998 . 147 C.3 Compte rendu de colloque III: Porquet, Dumont, l\fouchet 1998 155 CA Compte rendu de colloque IV: Porquet 1998 . 163 D Abréviations, symboles et constantes 171 D.l Abréviations . 171 D.2 Symboles 173 Références bibliographiques 173 Liste des tables 185 Liste des figures 187 Vlll TABLE DES MATIÈRES Résumé Le milieu chaud appelé "vVarm Absorber" est obsern~ dans les régions centra.les des Noyaux Actifs de Galaxies et plus particulièrement dans les galaxies de Seyfert 1. Il est caractérisé principalement par la présence, dans le spectre X, des seuils en absorption dus aux ions O VII et O VIII. C'est un milieu dont l'étude (modélisation et observation) est une clé importante dans la compréhension des Noyaux Actifs de Galaxies. Le travail présenté ici consiste principalement à modéliser le Warm Absorber et à déve­ lopper des diagnostics de spectroscopie X afin de contraindre les paramètres physiques de différents milieux chauds, tel que le vVarm Absorber. Les paramètres physiques du vVarm Absorber ( densité, température, processus d'ioni­ sation ... ) peuvent difficilement être déterminés sur la seule base de! 'étude des données X actuellement disponibles. En particulier, la valeur de la densité ne peut pas être ob­ tenue avec la seule modélisation des raies de résonance et des seuils en absorption dans les X-mous puisqu'ils sont quasiment insensibles à la densité sur le domaine de den­ sité prédit du Warm Absorber. C'est pourquoi, nous avons développé plusieurs types de diagnostics basés sur une approche multi-longueurs d'onde. La modélisation se fait grâce à l'utilisation de deux codes de calculs complémentaires: PEGAS, et IRIS qui inclut les données atomiques les plus précises (Dumont & Parquet, en préparation). Ces deux codes ont permis de modéliser plusieurs types de processus d'ionisation ( plasmas photoionisés et/ ou collisionnels). Les résultats pour le Warm Absorber ont été confrontés à des observations multi­ longueurs d'onde (principalement aux raies coron ales optiques du fer [Fe x] 6375À, [Fe XI] 7892À, et [Fex1v] 5303À). La méthode proposée a permis de mettre en évidence que le Warm Absorber peut être au moins en partie responsable des émissions des raies coronales. Tous les modèles de \Varm Absorber prod11isant des largeurs équivalentes de raies coronales supérieures à celles observées, ont été éliminés, nous permettant de fortement contraindre les paramètres physiques du vVarm Absorber, et plus particuliè­ rement la densité (nH 2:10 10 cm<', Parquet et al. [1999]). La nouvelle génération de satellites X (Chandra/ AXAF, XMM ... ) va permettre d'ob­ tenir des spectres à résolution spectrale et rapport signal sur bruit très élevés. Pour la première fois les diagnostics de plasmas à partir des principales raies des ions hé­ liumoïdes pourront être utilisés pour des plasmas photoionisés. Les données atomiques pour les recombinaisons radiatives et diélectroniques ainsi que pour les excitations col­ lisionnelles dues aux électrons ont été calculées afin d'obtenir les rapports de ces raies qui permettront des diagnostics de densité, de processus d'ionisation et de température du Warm Absorber (Porquet & Dubau [2000]). l 2 TABLE DES MATIÈRES • Summary The so-called "\Varm Absorber" medium is observed in the central region of Active Ga.la.ctic Nuclei and particularly in Seyfert l galaxies. lt is mainly cha.racterized by 0 VII and O VIII absorption edges detected in the soft X-rays. lts study (modelisa.tion a.nd observation) is an important key tool to understand Active Ga.lactic Nuclei. The work presented here consists in modelling the Warm Absorber, and in developing X-ray spectroscopy diagnostics to constrain the physical parameters of any hot medium such a.s the \Varm Absorber. The physical parameters of the Warm Absorber ( density, temperature, ioniza.tion pro­ cesses ... ) a.re difficult to determine only on the basis of present X-ra.y data. ln pa.rticu­ la.r, the value of the density cannot be derived only from the modelling of the resona.nce lines and of the soft X-ray absorption edges since there are a.lmost insensitive to the density in the range of values expected for the Warm Absorber. lt is why we have developed diagnostic methods based on a. multi-wavelength approach. The modelling is made with two complementary computational codes: PEGAS, and IRIS which takes into account the most accurate a.tomic data. (Dumont & Porquet, in preparation). With these two codes, we have modelled several types of plasma ionisa­ tion processes (photoionized plasmas and/or collisional). Results for the \Varm Absorber were compared to multi-wavelength observations (mainly the optical iron corona.l lines [Fe x] 6375Â, [Fe XI] 7892À, and [Fe XIV] 5303Â). The pro­ posed method has allowed to show that the Warm Absorber could be responsible of the emission of these lines tota.lly or partially. All models of the \rVarm Absorber produ­ cing coronal line equivalent widths larger than observed were ruled out. This strongly constrains the physical parameters of the Warm Absorber, and particularly its density 10 3 (nH ~10 cm- , Porquet et al. [1999]). The new generation of X-ray satellites (Chandra/ AXAF, XlVIM ... ) will produce spec­ tra a.t high spectral resolution and high sensitivity. For the first time, the plasmas diagnostics based on the most intense He-like ion lines will be used for photoionized plasmas, such as the \Varm Absorber. Atomic data for radiative and dielectronic re­ combination and for electronic collisional excitation have been calculated in order to predict line ratios, from which density, ionization processes and temperature diagnos­ tics of the Warm Absorber will be inferred (Porquet & Dubau [2000]). 3 4 TABLE DES A1ATIÈRES Remerciements Ct;s t mis année ont hé pour moi p/eirws de richesses sr·iuzlijiques et humaines grâce notamment a 1Warfim ;\101Lchet qui a {té pour moi ru1c dindrice de thèse absolument parfaite.
Recommended publications
  • United States Patent (19) (11) 4,183,795 Bloom Et Al
    United States Patent (19) (11) 4,183,795 Bloom et al. (45) Jan. 15, 1980 (54) CREATION OF F2+ COLOR CENTERS Attorney, Agent, or Firm-Daniel D. Dubosky 75) Inventors: David M. Bloom, Holmdel; Linn F. 57 ABSTRACT Molenauer, Colts Neck, both of N.J. Production of F2+ color centers in alkalihalide crystals 73 Assignee: Bell Telephone Laboratories, with densities high enough for efficient use in lasers is Incorporated, Murray Hill, N.J. achieved by a two-step, highly selective photoioniza 21 Appl. No.: 908,774 tion mechanism. This mechanism is coupled with the use of suitable divalent metal ions as efficient and stable 22 Filed: May 23, 1978 electron traps to allow nearly 100 percent conversion of 51) Int. C.’................................................ B01J 1/10 F2 color centers to F2 color centers. The two-step 52 U.S. C. .................... 204/157.1 R; 204/DIG. 11; photoionization mechanism comprises photo-exciting 331/94.5F the F2 color center to the first bound state, which re 58 Field of Search ................................. 204/157.1 R quires lower energy than the corresponding transition for F color centers, then photoionizing the F2 color (56) References Cited center from the first bound state, and finally, capturing U.S. PATENT DOCUMENTS the electron thus liberated on the divalent metal ions. 3,970,960 7/1976 Mollenauer ..................... 331/94.5F Primary Examiner-Howard S. Williams 8 Claims, 7 Drawing Figures PUMP BEAM FOR LASER OPERATION CRYSTAL WITH W. F; CENTERS \\ \ N-PROCESSING BEAM U.S. Patent Jan. 15, 1980 Sheet 1 of 3 4,183,795 A/G.
    [Show full text]
  • Large Quasineutral Electron Velocity Oscillations in Radial Expansion of an Ionizing Plasma
    Large quasineutral electron velocity oscillations in radial expansion of an ionizing plasma A R Karimov, M Y Yu and Lennart Stenflo Linköping University Post Print N.B.: When citing this work, cite the original article. Original Publication: A R Karimov, M Y Yu and Lennart Stenflo, Large quasineutral electron velocity oscillations in radial expansion of an ionizing plasma, 2012, Physics of Plasmas, (19), 9, 092118. http://dx.doi.org/10.1063/1.4754865 Copyright: American Institute of Physics (AIP) http://www.aip.org/ Postprint available at: Linköping University Electronic Press http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-85093 PHYSICS OF PLASMAS 19, 092118 (2012) Large quasineutral electron velocity oscillations in radial expansion of an ionizing plasma A. R. Karimov,1,a) M. Y. Yu,2,3,b) and L. Stenflo4 1Institute for High Temperatures, Russian Academy of Sciences, Izhorskaya 13/19, Moscow 127412, Russia 2Department of Physics, Institute for Fusion Theory and Simulation, Zhejiang University, 310027 Hangzhou, China 3Institut fur€ Theoretische Physik I, Ruhr-Universitat€ Bochum, D-44780 Bochum, Germany 4Department of Physics, Linkoping€ University, SE-58183 Linkoping,€ Sweden (Received 13 July 2012; accepted 12 September 2012; published online 28 September 2012) Radial expansion of an ionizing gas or plasma cylinder into vacuum is investigated. An exact model for the evolution of the density and velocity fields of the electrons, ions, and neutrals, including the effect of photo and electron-impact ionization on the flow characteristics is developed and solutions obtained. A quasineutral nonlinear electrostatic mode involving rapid oscillations in the electron velocity but not in the density can occur in the expanding plasma.
    [Show full text]
  • Gas Chromatography–Mass Spectrometry of Organochlorine Pesticides in Environmental Waters Claire A
    August 2019 | Volume 32 Number 8 www.chromatographyonline.com LC TROUBLESHOOTING Ion-exchange separations and MS PERSPECTIVES IN MODERN HPLC HPLC pumps ANALYSIS FOCUS SEC in polymer analysis Does your carrier gas come with hidden dangers? A Clear Vision A novel automated GC method to detect organochlorine pesticides in environmental waters magentablackcyanyellow ES107242_LCE0819_CVTP1_FP.pgs 08.02.2019 16:57 UBM BIP® Technology Changing the way you think about high purity gas The BIP® range of gases are available with a minimum purity grade of BIP®BIP® gases gases - Performance - Performance with with GC-FID GC-FID 6.0, however is purity everything? Even with a purity level of 99.9999% 12001200 what exactly is in the other 0.0001%? Despite being an extremely tiny 11801180 percentage, what if some “active” impurities were still affecting your 11601160 results and processes? Air Products’ ultra-high purity gases delivered 11401140 with BIP® technology guarantee the market’s lowest possible levels of 11201120 potentially harmful impurities: oxygen (≤ 10 ppb), moisture (≤ 20 ppb) 11001100 and total hydrocarbons (< 100 ppb). 10601060 10601060 BIP® Technology 2 2 4 4 6 6 8 8 1010 12 12 14 14 16 16 18 18min. min. FID baselineFID baseline with with BIP® BIP® N2 as N markup2 as markup gas gas The BIP® technology hidden in every cylinder uniquely filters out FID baselineFID baseline with with non-BIP® non-BIP® N2 as N markup2 as markup gas gas potentially damaging impurities before the gas leaves the cylinder. BIP® technology is available with the most commonly used ultra-high purity gases: Helium, Nitrogen, Hydrogen and Argon.
    [Show full text]
  • Pulsed Discharge Detector Manual
    Valco Instruments Co. Inc. Pulsed Discharge Detector Models D-3-I-HP and D-3-I-7890 Instruction Manual Rev 1/15 North America, South America, and Australia/Oceania contact: Europe, Asia, and Africa contact:: Valco Instruments Co. Inc. VICI AG International 800 · 367· 8424 sales Schenkon, Switzerland 713 · 688· 9345 tech Int + 41 · 41 · 925· 6200 phone 713 · 688· 8106 fax Int + 41 · 41 · 925· 6201 fax [email protected] [email protected] This page intentionally left blank for printing purposes Table of Contents Introduction Description and Operating Principles ............................................................ 1 Safety Notes and Information ........................................................................ 2 Symbols Installation Category Safety Components of the Detector System ............................................................. 3 System Requirements Components not Included with the Detector System ..................................... 4 System Purity ................................................................................................ 4 Gas Specifications ......................................................................................... 5 Installation General Precautions ...................................................................................... 6 Checking the Firmware Version Agilent 6890 GC ..................................................................................... 6 Agilent 7890 GC ..................................................................................... 6 Mounting
    [Show full text]
  • STIS Echelle Observations of the Seyfert Galaxy NGC 4151: Physical Conditions in the Ultraviolet Absorbers1
    to appear in The Astrophysical Journal STIS Echelle Observations of the Seyfert Galaxy NGC 4151: Physical Conditions in the Ultraviolet Absorbers1 S. B. Kraemer2,D.M.Crenshaw2,J.B.Hutchings3,I.M.George4;5, A.C. Danks6,T.R. Gull7, M.E. Kaiser8, C.H. Nelson9, & D. Weistrop9 ABSTRACT 1Based on observations made with the NASA/ESA Hubble Space Telescope. STScI is operated by the Association of Universities for Research in Astronomy, Inc. under the NASA contract NAS5-26555. 2Catholic University of America, NASA’s Goddard Space Flight Center, Code 681, Greenbelt, MD 20771; [email protected], [email protected]. 3Dominion Astrophysical Observatory, National Research Council of Canada, Victoria, BC V8X 4M6, Canada; [email protected]. 4Laboratory for High Energy Astrophysics, NASA’s Goddard Space Flight Center, Code 662, Greenbelt, MD 20771; [email protected] 5Joint Center for Astrophysics, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, MD 21250 6Raytheon Polar Services, NASA’s Goddard Space Flight Center, Code 681, Greenbelt, MD 20771; [email protected]. 7NASA’s Goddard Space Flight Center, Code 681, Greenbelt, MD 20771; [email protected]. 8Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218; [email protected]. 9Department of Physics, University of Nevada, Las Vegas, 4505 Maryland Parkway, Las Vegas, NV 89154-4002; [email protected], [email protected]. –2– We have examined the physical conditions in intrinsic UV-absorbing gas in the Seyfert galaxy NGC 4151, using echelle spectra obtained with the Space Telescope Imaging Spectrograph (STIS) on the Hubble Space Telescope (HST) on 1999 July 19.
    [Show full text]
  • Quantification of Brominated Polycyclic Aromatic Hydrocarbons in Environmental Samples by Liquid Chromatography Tandem Mass Spec
    Analytical Sciences Advance Publication by J-STAGE Received January 28, 2020; Accepted April 22, 2020; Published online on May 1, 2020 DOI: 10.2116/analsci.20P025 1 Original Papers 2 3 Quantification of Brominated Polycyclic Aromatic Hydrocarbons in 4 Environmental Samples by Liquid Chromatography Tandem Mass 5 Spectrometry with Atmospheric Pressure Photoionization and 6 Post-Column Infusion of Dopant (LC-DA-APPI-MS/MS) 7 8 Misato Masuda, Qi Wang, Masahiro Tokumura, Yuichi Miyake†, and Takashi Amagai† 9 10 Graduate Division of Nutritional and Environmental Sciences, University of Shizuoka, 52-1 11 Yada, Suruga, Shizuoka 422-8526, Japan 12 † To whom correspondence should be addressed. 13 E-mail: [email protected] (Miyake), [email protected] (Amagai) 14 1 Analytical Sciences Advance Publication by J-STAGE Received January 28, 2020; Accepted April 22, 2020; Published online on May 1, 2020 DOI: 10.2116/analsci.20P025 15 Abstract 16 A sensitive method for the quantification of brominated polycyclic aromatic hydrocarbons 17 (BrPAHs) in environmental samples is yet to be developed. Here, we optimized the analytical 18 conditions for liquid chromatography tandem mass spectrometry with atmospheric pressure 19 photoionization and post-column infusion of dopant (LC-DA-APPI-MS/MS). We then 20 compared the sensitivity of our developed method with that of conventional gas 21 chromatography high-resolution MS (GC-HRMS) by comparing the limits of quantification 22 (LOQs) for a range of BrPAHs. Finally, to evaluate our developed method, 12 BrPAHs in 23 sediments and fish collected from Tokyo Bay, Japan, were analyzed; 9 common PAHs were also 24 targeted.
    [Show full text]
  • Photoelectrochemistry and Nanoparticle Research
    Photoelectrochemistry and Nanoparticle Research Research Activity January 2003 - December 2003 Prashant V. Kamat Radiation Laboratory and Chemical and Biomolecular Engineering University of Notre Dame Notre Dame, Indiana 46556-0579 Tel. (574 631-5411 Fax (574) 631-8068 E-mail: [email protected] Website: http://www.nd.edu/~pkamat Research Funding Office of Basic Energy Sciences, U.S. Department of Energy 2 Research Program Graduate Students Roxana Nicolaescu (Chemistry, U. of Notre Dame) Photoelectrochemical Processes for Light Energy Julie Peller (Chemistry, U. of Notre Dame) Conversion Ravi Vaidyanathan (Chem. Eng. U. of Notre Dame) • Charge transfer processes in semiconductor and Said Barazzouk (Chemistry, U. of Quebec) metal nanostructures Taku Hasobe (Chemistry, Osaka U) • Semiconductor-metal nanocomposites Hisashi Kikuchi (Osaka Prefecture Univ.) • Photochemical and radiation chemical processes on surfaces • Excited state & redox processes of novel molecular Undergraduate Students assemblies • Environmental remediation M. Haria (Co-Op student, McMaster U,) Jan-Aug 2003 External Collaborators Ph. D. Dissertations Julie Peller (Chemistry, UND, May 2003), “Hydroxyl K. George Thomas (RRL, Trivandrum) radical mediated transformations of Herbicide, 2,4- S. Hotchandani (U. of Quebec) Dichlorophenoxyacetic acid and related compounds”. K. Vinodgopal (Indiana U., N. W.) S. Padmaja (Unilever Research) S. Fukuzumi (Osaka University) Professional Activities H. Imahori (Kyoto University) M. Anpo (Osaka Prefecture University) • Senior Editor/Editorial Board Member, Journal of Physical Chemistry Collaborators at Notre Dame • Editor/ Editorial Board Member, Research on Chemical Intermediates Joan Brennecke, Bruce Bunker, Olaf Wiest, and • Editorial Board Member, Langmuir Eduardo Wolf • Editorial Board Member, Fullerene Science & Technology • Editorial Board Member, International Journal of Visiting Scientists Photoenergy • Editorial Board Member, Interface K.
    [Show full text]
  • Model Calculations of Photoemission from a Surface-Deposited Fullerene Monolayer
    IOP PUBLISHING JOURNAL OF PHYSICS B: ATOMIC, MOLECULAR AND OPTICAL PHYSICS J. Phys. B: At. Mol. Opt. Phys. 40 (2007) 4617–4624 doi:10.1088/0953-4075/40/24/006 Model calculations of photoemission from a surface-deposited fullerene monolayer O Kidun1, D Bauer1, N Fominykh2 and J Berakdar3 1 Max-Planck-Institut fur¨ Kernphysik, Postfach 10 39 80, 69029 Heidelberg, Germany 2 Max-Planck Institut fur¨ Mikrostrukturphysik, Weinberg 2, 06120 Halle, Germany 3 Insitut fur¨ Physik, Martin-Luther-Universitat¨ Halle-Wittenberg, Heinrich-Damerow-Str. 4, 06120 Halle, Germany Received 3 September 2007, in final form 18 October 2007 Published 19 November 2007 Online at stacks.iop.org/JPhysB/40/4617 Abstract We theoretically investigate the energy and the angular-resolved cross section for the photoelectron emission from a hexagonal monolayer of a C60 fullerene physisorbed on an inert substrate. On the basis of a tight-binding scheme with an on-site shell model for the single molecules we evaluate the energy and angular spectra of the photoelectrons upon the absorption of VUV linearly polarized photons. A symmetry analysis provides a clear interpretation of the observed structures in the numerically calculated cross sections. When the photoelectron is temporarily captured within the molecular cage, the symmetry of the angular emission pattern is mainly determined by the symmetry of the single fullerene molecule. In contrast, for the photoelectron state mainly located outside the C60 the angular dependence of the photoemission reproduces the symmetry of the lattice. These changes of the angular patterns repeat concurrently with the oscillations of the angle-integrated cross section.
    [Show full text]
  • The Use of Dopants in Atmospheric Pressure Ionization Sources of Mass Spectrometers
    THE USE OF DOPANTS IN ATMOSPHERIC PRESSURE IONIZATION SOURCES OF MASS SPECTROMETERS by Faezeh Dousty M.Sc, The University of Tehran, 2009 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF Doctor of Philosophy in THE COLLEGE OF GRADUATE STUDIES (Chemistry) THE UNIVERSITY OF BRITISH COLUMBIA (Okanagan) May 2015 © Faezeh Dousty, 2015 Abstract Dopants, as ―ionization assisting‖ chemicals, have been used in different ionization techniques. However, they have been used most frequently in the field of Atmospheric Pressure Photoionization (APPI). These chemicals that have high photoabsorption and photoionization cross sections easily get photoionized and ―preserve‖ to a certain extent the energy of the photon flux, which otherwise is significantly lost due to the absorption by matrix components. Subsequently, these photo-dopant ions ionize analyte molecules through ion-molecule chemical reactions. Obtaining a profound understanding of ion formation mechanisms is a crucial step in successful applications of mass spectrometry. The first part of this thesis focuses on comprehensively describing ionization mechanisms and specifically the role of dopants. With the understanding obtained from in depth research on ion formation mechanisms, two novel dopants for APPI are proposed, i.e., carbon disulfide and isoprene. The potential of these chemicals as dopants, alongside their underlying ionization mechanisms, were investigated with a commercial APPI source coupled to a liquid chromatograph and a custom-built APPI source coupled to a gas chromatograph. Carbon disulfide was proven to be an effective charge transfer reagent for the positive ion APPI (PI-APPI) and promoted the ionization of non-polar compounds, for which the proton transfer route was not possible.
    [Show full text]
  • Characterization of Iron Oxide Thin Films for Photoelectrochemical Hydrogen Production
    UNLV Theses, Dissertations, Professional Papers, and Capstones 2009 Characterization of iron oxide thin films for photoelectrochemical hydrogen production Kyle Eustace Nelson George University of Nevada Las Vegas Follow this and additional works at: https://digitalscholarship.unlv.edu/thesesdissertations Part of the Oil, Gas, and Energy Commons, and the Physical Chemistry Commons Repository Citation George, Kyle Eustace Nelson, "Characterization of iron oxide thin films for photoelectrochemical hydrogen production" (2009). UNLV Theses, Dissertations, Professional Papers, and Capstones. 147. http://dx.doi.org/10.34917/1391032 This Thesis is protected by copyright and/or related rights. It has been brought to you by Digital Scholarship@UNLV with permission from the rights-holder(s). You are free to use this Thesis in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/ or on the work itself. This Thesis has been accepted for inclusion in UNLV Theses, Dissertations, Professional Papers, and Capstones by an authorized administrator of Digital Scholarship@UNLV. For more information, please contact [email protected]. CHARACTERIZATION OF Fe2O3 THIN FILMS FOR PHOTOELECTROCHEMICAL HYDROGEN PRODUCTION by Kyle Eustace Nelson George Bachelor of Arts Unive rsity of Nevada, Las Vegas 2008 A thesis submitted in partial fulfillment
    [Show full text]
  • Electrochemical Aspects of Electrospray and Laser Desorption/Ionization for Mass Spectrometry
    AC03CH11-Girault ARI 11 May 2010 13:26 Electrochemical Aspects of Electrospray and Laser Desorption/Ionization for Mass Spectrometry Melanie´ Abonnenc,1 Liang Qiao,1,2 BaoHong Liu,2 and Hubert H. Girault1 1Laboratoire d’Electrochimie Physique et Analytique, Station 6, Ecole Polytechnique Fed´ erale´ de Lausanne, CH-1015 Lausanne, Switzerland; email: Melanie.Abonnenc@epfl.ch, Liang.Qiao@epfl.ch, Hubert.Girault@epfl.ch 2Department of Chemistry, Institute of Biomedical Science, Fudan University, Shanghai 200433, China; email: [email protected] Annu. Rev. Anal. Chem. 2010. 3:231–54 Key Words First published online as a Review in Advance on electrochemistry, electron-transfer reaction, emitters, ion source, peptide March 1, 2010 by Ecole Polytechnique Federal Lusanne on 12/19/11. For personal use only. analysis, proteomics The Annual Review of Analytical Chemistry is online at anchem.annualreviews.org Abstract This article’s doi: Soft-ionization methods, namely electrospray ionization and laser Annual Review of Analytical Chemistry 2010.3:231-254. Downloaded from www.annualreviews.org 10.1146/annurev.anchem.111808.073740 desorption/ionization, are widely used to transfer large molecules as in- Copyright c 2010 by Annual Reviews. tact gas-phase ions either from a solution or from a solid substrate. During All rights reserved both processes, in-source electrochemical and photoelectrochemical reac- 1936-1327/10/0719-0231$20.00 tions occur. These electrode reactions, which take place at interfaces, play important roles in influencing the ionization products, but they have re- ceived little attention. We show that having good control over both types of electrochemical reactions can lead to new analytical applications.
    [Show full text]
  • Photoionization Mass Spectrometric Studies of Selected Compounds in a Molecular Beam
    \' LA-7727-T Thesis ITER Photoionization Mass Spectrometric Studies of Selected Compounds in a Molecular Beam • MM c o o05 a> ? 'S'Hi:? D-iH;uiiSfJT its uwtKSiiTe LOS ALAMOS SCIENTIFIC LABORATORY Post Office Box 1663 Los Alamos. New Mexico 87545 LA-7727-T Thesis Special Distribution Issued: March 1979 Photoionization Mass Spectrometric Studies of Selected Compounds in a Molecular Beam Wayne Merle Trott4 Sandia Laboratories, Org. 4212, Albuquerque, NM 87115. -NOTICE- This report wai prepared as an account of wor. sponsoied by the United Slates Government. Neither thi United States nor the United States Department o Enerf^, no1 any of their employees, nor any of thei contractor, subcontractors, oi (heir employees, make: any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness oi usefulness of any information, apparatus, product or process disclosed, or represents tint its use would not infringe privately owned rights. TABLE OP CONTENTS Page List of Figures viii List of Tables ' xi I. Introduction: General Methods in the Study of Ionization and Dissociation Processes .... 1 II. Photoionization Mass Spectrometry 12 A. Historical Overview 12 B. General Considerations 17 1. Phctoionization Processes 18 a. Direct Ionization and the Pranck-Condon Principle 18 b. Selection Rules 22 c. Autoionization 29 2. Photoionization Efficiency Curves . 36 a. Physical Conditions Leading to Coarse and Pine Structure 37 b. Molecular and Ionic State Energetic Information . 51 c. Instrumental and Thermal Effects. Jc 3. Appearance Potential Measurements of Fragmentation Processes 62 C. Supersonic Molecular Beam Sampling. .... 7^ D. Experimental Design 95 III. Apparatus ill A. Nozzle Beam Source and Ionizer Ill B.
    [Show full text]