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Available online at www.sciencedirect.com ScienceDirect Geochimica et Cosmochimica Acta 285 (2020) 129–149 www.elsevier.com/locate/gca Heterogeneous nickel isotopic compositions in the terrestrial mantle – Part 1: Ultramafic lithologies Naomi J. Saunders a,b,⇑, Jane Barling a, Jason Harvey c, Alex N. Halliday a,b a Dept of Earth Sciences, University of Oxford, South Parks Road, Oxford OX1 3AN, UK b Lamont-Doherty Earth Observatory, Columbia University, 61 Route 9W, Palisades 10964, USA c School of Earth and Environment, University of Leeds, Leeds LS2 9JT, UK Received 15 October 2019; accepted in revised form 18 June 2020; available online 3 July 2020 Abstract High precision nickel stable isotopic compositions (d60/58Ni) are reported for 22 peridotite xenoliths from the USA (Kil- bourne Hole, New Mexico), Tanzania, and Cameroon. For a subset of these, d60/58Ni is also reported for their constituent mineral separates (olivine, orthopyroxene, clinopyroxene, and spinel). Bulk peridotites show significant heterogeneity in Ni isotopic composition, ranging from +0.02‰ to +0.26‰. Unmetasomatised fertile peridotites from three localities, define an average d60/58Ni of +0.19±0.09‰ (n = 18). This value is comparable to previous estimates for the d60/58Ni of the bulk sil- icate earth (BSE), but is unlikely to be representative, given observed heterogeneity, presented here and elsewhere. Samples with reaction rims and interstitial glass (interpreted as petrographic indications of minor metasomatism) were excluded from this average; their Ni isotopic compositions extend to lighter values, spanning nearly the entire range observed in peridotite worldwide. Dunites (n = 2) are lighter in d60/58Ni than lherzolites and harzburgites from the same location, and pyroxenites (n = 5) range from +0.16‰ to as light as À0.38‰.
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