DOCSLIB.ORG

(12) United States Patent (10) Patent No.: US 8,198.367 B2 You Et Al

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
(12) United States Patent (10) Patent No.: US 8,198.367 B2 You Et Al US008198367B2 (12) United States Patent (10) Patent No.: US 8,198.367 B2 You et al. (45) Date of Patent: Jun. 12, 2012 (54) THERMOPLASTIC FOREIGN PATENT DOCUMENTS ACRYLONTRILE-BUTADIENE-STYRENE DE 1983.9369 A1 4f1999 RESIN COMPOSITION WITH EXCELLENT DE 1995.1648 A1 5, 2001 RELEASABILITY AND COLORABILITY DE 112004000633 B4 10, 2007 KR 100493.459 B1 6, 2005 KR 100632208 B1 9, 2006 (75) Inventors: Han Jong You, Daejeon (KR); Seong KR 1007OO683 B1 3, 2007 Lyong Kim, Daejeon (KR) KR 100774.820 B1 11, 2007 KR 10O836572 B1 6, 2008 (73) Assignee: LG Chem, Ltd., Seoul (KR) KR 1020090038508 A 4/2009 (*) Notice: Subject to any disclaimer, the term of this OTHER PUBLICATIONS patent is extended or adjusted under 35 European Search Report issued on Dec. 4, 2009 in connection with U.S.C. 154(b) by 290 days. corresponding European Applin. No. 09010557.8-2109. (21) Appl. No.: 12/543,618 * cited by examiner (22) Filed: Aug. 19, 2009 Primary Examiner – David W. Wu (65) Prior Publication Data Assistant Examiner — Deve E Valdez US 201O/OO48798 A1 Feb. 25, 2010 (74) Attorney, Agent, or Firm — Lerner, David, Littenberg, Krumholz & Mentlik, LLP (30) Foreign Application Priority Data Aug. 19, 2008 (KR) ........................ 10-2008-0080697 (57) ABSTRACT A thermoplastic acrylonitrile-butadiene-styrene (ABS) resin (51) Int. Cl. composition of the present invention comprises (a) a bimodal C08G 63/9. (2006.01) graft copolymer of a conjugated diene rubbery polymer COSL 5L/04 (2006.01) whose average particle diameter of 800 to 1,500 A and a CD8L 53/00 (2006.01) conjugated diene rubbery polymer whose average particle COSL 55/02 (2006.01) diameter of 2,500 to 3,500 A, the conjugated diene rubbery COSL 53/02 (2006.01) polymers being grafted with an aromatic vinyl compound and (52) U.S. Cl. .............. 525/71; 524/504; 525/66; 525/55; a vinyl cyanide compound, (b) an acrylic resin of a meth 525/70; 526/340; 526/335; 526/341 acrylic or acrylic acid alkyl ester compound, an aromatic (58) Field of Classification Search .................. 524/504; vinyl compound and a vinyl cyanide compound, (c) a copoly 525/71, 66, 55, 70; 526/340,335, 341 mer of an aromatic vinyl compound and a vinyl cyanide See application file for complete search history. compound, and (d) polysiloxane masterbatches. The ABS resin composition has excellent colorability and releasability (56) References Cited while maintaining the inherent physical properties (e.g., impact strength and tensile strength) of the base resin. U.S. PATENT DOCUMENTS 5, 112,895 A 5, 1992 Chen et al. 2008.0167426 A1* 7/2008 Kim et al. ....................... 52.5/71 9 Claims, No Drawings US 8, 198,367 B2 1. 2 THERMOPLASTC Further, Korean Patent No. 10-0493.459 discloses that the ACRYLONTRILE-BUTADIENE-STYRENE addition of a resin, such as ABS, LLDPE or HDPE, to a RESIN COMPOSITION WITH EXCELLENT polycarbonate (PC) resin improves the releasability, process RELEASABILITY AND COLORABILITY ability, economic efficiency, chemical resistance, etc. of the PC resin while maintaining the inherent advantages of the PC CROSS REFERENCE TO RELATED resin in terms of impact resistance, self-extinguishing prop APPLICATION erties, dimensional stability and heat resistance. This patentis Somewhat distinguished from the present invention in that the The present application claims the benefit of Korean Appli releasability of the base resin is improved by the addition of a cation No. 10-2008-0080697, filed Aug. 19, 2008, the disclo 10 resin different from the base resin rather than by the addition sure of which is hereby incorporated by reference herein. of an additive. Thus, there is an urgent need for a thermoplastic ABS resin BACKGROUND OF THE INVENTION composition that is prepared by previously adding an additive to a resin to improve the releasability of the resin and achieve 1. Field of the Invention 15 good colorability and well-balanced physical properties. The present invention relates to a thermoplastic acryloni trile-butadiene-styrene (ABS) resin composition with excel SUMMARY OF THE INVENTION lent release and colorability. More specifically, the present In view of the foregoing problems of the prior art, an object invention relates to a thermoplastic ABS resin composition of the present invention is to provide a thermoplastic acry comprising a base resin and polysiloxane masterbatches as lonitrile-butadiene-styrene (ABS) resin composition with release agents wherein the base resin contains two kinds of excellent colorability and releasability. grafted conjugated diene rubbery polymers having different According to an aspect of the present invention, there is rubber sizes and distributions. provided a thermoplastic acrylonitrile-butadiene-styrene 2. Description of the Related Art 25 (ABS) resin composition comprising (a) 25 to 40 parts by Acrylonitrile-butadiene-styrene (ABS) resins are typical weight of a bimodal graft copolymer of a conjugated diene resins that are highly functional and can be used for general rubbery polymer whose average particle diameter of 800 to purposes. ABS resins are used in various applications, includ 1,500 A and a conjugated diene rubbery polymer whose ing automotive parts, electric/electronic components and average particle diameter of 2,500 to 3,500 A, the conjugated general merchandise, due to their advantages in terms of 30 diene rubbery polymers being grafted with an aromatic vinyl impact strength, tensile strength, modulus of elasticity, etc. compound and a vinyl cyanide compound, (b) 10 to 45 parts For use in such applications, ABS resins are generally molded by weight of an acrylic resin of a methacrylic or acrylic acid by Suitable techniques, such as injection and extrusion mold alkyl ester compound, an aromatic vinyl compound and a ing. In the case where a resin is used as a material for a product vinyl cyanide compound, (c) 50 to 65 parts by weight of a requiring high precision dimensions or a product having a 35 copolymer of an aromatic vinyl compound and a vinyl cya complex shape by molding or automatic injection molding of nide compound, and (d) 0.5 to 5 parts by weight of master a resin is performed at high speed, the releasability of the resin batches containing a polysiloxane whose viscosity is from may greatly affect the productivity and quality of the molded 1,000,000 to 3,000,000 cSt, based on 100 parts by weight of product. a base resin composed of (a), (b) and (c). Suitable modification of molding processing conditions 40 can partially solve the problems associated with releasability, DETAILED DESCRIPTION OF THE INVENTION and in most cases, it does not provide a satisfactory Solution to the releasability problems. Further, even if the problem of The present invention will now be described in detail. poor releasability is satisfactorily solved, the molding cycle The present invention provides a thermoplastic acryloni time is increased, which leads to low productivity. 45 trile-butadiene-styrene (ABS) resin composition comprising In another attempt to solve the problem of poor releasabil (a) 25 to 40 parts by weight of a bimodal graft copolymer of ity, the application of a release agent to a mold is suggested. a conjugated diene rubbery polymer whose average particle However, in the case of a molded toy product for children, diameter of 800 to 1,500 A and a conjugated diene rubbery ingredients of the release agent may remain on the molded polymer whose average particle diameter of 2,500 to 3,500 A. product and have a bad influence on the safety of children. 50 the conjugated diene rubbery polymers being grafted with an In an alternative attempt, a release agent is previously aromatic vinyl compound and a vinyl cyanide compound, (b) blended with a resin to improve the releasability of the resin. 10 to 45 parts by weight of an acrylic resin of a methacrylic or Higher fatty acids and metal salts thereof, polyoxypropylene acrylic acid alkyl ester compound, an aromatic vinyl com glycols and silicone oils are known to be suitable for this pound and a vinyl cyanide compound, (c) 50 to 65 parts by purpose. However, when the release agent is added in an 55 weight of a copolymer of an aromatic vinyl compound and a amount of 0.5 parts by weight or more, a balance in the basic vinyl cyanide compound (hereinafter referred to simply as a physical properties of the resin may collapse and a portion of styrene-acrylonitrile (SAN) resin), and (d) 0.5 to 5 parts by the release agent may migrate to the resin Surface to contami weight of masterbatches containing a polysiloxane whose nate the Surfaces of a mold and a molded product or worsen viscosity is from 1,000,000 to 3,000,000 cSt, based on 100 the thermal stability of the resin. 60 parts by weight of a base resin composed of (a), (b) and (c). Korean Patent No. 10-0632208 discloses that a silicone The thermoplastic resin composition of the present inven release solution containing an epoxy compound and a silane tion exhibits excellent colorability and releasability when compound is coated on the Surface of a polyester film to compared to acrylonitrile-butadiene-styrene (ABS) resins. improve the releasability of the polyester film. This patent is Based on these advantages, the thermoplastic resin composi distinguished from the present invention by its application 65 tion can be applied to the manufacture of a product having a and in that the releasability of the polyester film is improved complex shape by molding or to high-speed injection mold by the coating of the particular compounds. ing. In addition, the thermoplastic resin composition of the US 8, 198,367 B2 3 4 present invention can be used as a material for automotive As the peroxide initiators, there may be used, for example, parts, electric/electronic components, toy elements, and the Sodium persulfate, calcium persulfate, cumene hydroperoX like.
Load more

Recommended publications
  • The Use of PEEK in Digital Prosthodontics: a Narrative Review Ioannis Papathanasiou1, Phophi Kamposiora1*, George Papavasiliou1 and Marco Ferrari2
    Papathanasiou et al. BMC Oral Health (2020) 20:217 https://doi.org/10.1186/s12903-020-01202-7 REVIEW Open Access The use of PEEK in digital prosthodontics: A narrative review Ioannis Papathanasiou1, Phophi Kamposiora1*, George Papavasiliou1 and Marco Ferrari2 Abstract Background: Advanced computer-aided design and computer-aided manufacturing (CAD-CAM) technology led to the introduction of an increasing number of machinable materials suitable for dental prostheses. One of these materials is polyetheretherketone (PEEK), a high performance polymer recently used in dentistry with favorable physical, mechanical and chemical properties. The purpose of this study was to review the current published literature on the use of PEEK for the fabrication of dental prostheses with CAD-CAM techniques. Methods: Electronic database searches were performed using the terms “PEEK”, “CAD-CAM”, “dental”, “dentistry” to identify studies related to the use of PEEK for the fabrication of CAD-CAM prostheses. The search period spanned from January 1990 through February 2020. Both in vivo and in vitro studies in English were eligible. Review articles and the references of the included publications were searched to identify relevant articles. Results: A great number of in vitro studies are available in the current literature pointing out the noticeable properties of PEEK. The use of PEEK has been recommended for a wide range of CAD-CAM fabricated fixed and removable dental prostheses. PEEK was additionally recommended for occlusal splints, intra-radicular posts, implant abutments, customized healing abutments and provisional restorations. However, only a few clinical studies were identified. Conclusions: PEEK could be considered as a viable alternative for CAD-CAM fixed and removable dental prostheses to well-established dental materials.
    [Show full text]
  • Powder Coatings
    Emmanouil Spyrou Powder Coatings Chemistry and Technology 3rd Revised Edition Emmanouil Spyrou: Powder Coatings: Chemistry and Technology © Copyright 2012 by Vincentz Network, Hanover, Germany ISBN: 978-3-86630-884-8 Spyrou_Powder Coatings.indb 1 14.09.2012 10:17:21 Cover: Evonik Industries AG, Marl/Germany Bibliographische Information der Deutschen Bibliothek Die Deutsche Bibliothek verzeichnet diese Publikation in der Deutschen Nationalbibliographie; detaillierte bibliographische Daten sind im Internet über http://dnb.ddb.de abrufbar. Emmanouil Spyrou, 3rd Revised Edition Based on Pieter G. de Lange’s, 2nd Edition, Vincentz Network, 2004, and Tosko A. Misev’s, 1st Edition, John Wiley and Sons, 1991 Powder Coatings: Chemistry and Technology Hanover: Vincentz Network, 2012 EUROPEAN COATINGS TecH FILES ISBN 3-86630-884-1 ISBN 978-3-86630-884-8 © 2012 Vincentz Network GmbH & Co. KG, Hanover Vincentz Network, P.O. Box 6247, 30062 Hanover, Germany This work is copyrighted, including the individual contributions and figures. Any usage outside the strict limits of copyright law without the consent of the publisher is prohibited and punishable by law. This especially pertains to reproduction, translation, microfilming and the storage and processing in electronic systems. The information on formulations is based on testing performed to the best of our knowledge. The appearance of commercial names, product designations and trade names in this book should not be taken as an indication that these can be used at will by anybody. They are often registered names which can only be used under certain conditions. Please ask for our book catalogue Vincentz Network, Plathnerstr. 4c, 30175 Hanover, Germany T +49 511 9910-033, F +49 511 9910-029 [email protected], www.european-coatings.com Layout: Vincentz Network, Hanover, Germany Printed by: Quensen Druck + Verlag GmbH & Co.
    [Show full text]
  • The Transversal Strength Comparison Between Polyethylene and Glass Fiber As an Acrylic Resin Denture Plate Repair Material
    Majalah Kedokteran Gigi Indonesia Vol 5 No 1 – April 2019 ISSN 2460-0164 (print), ISSN 2442-2576 (online) Aditama,Available et al: The online transversal at https://jurnal.ugm.ac.id/mkgi strength comparison … DOI: http://doi.org/10.22146/majkedgiind.17497 RESEARCH ARTICLE The transversal strength comparison between polyethylene and glass fiber as an acrylic resin denture plate repair material Pramudya Aditama*, Sabdayana**, Erwan Sugiatno* *Department of Prosthodontics, Faculty of Dentistry, Universitas Gadjah Mada, Yogyakarta, Indonesia **Dentistry Study Program, Faculty of Dentistry, Universitas Gadjah Mada, Yogyakarta, Indonesia *Jl Denta No 1, Sekip Utara, Yogyakarta, Indonesia; e-mail: [email protected] Submitted: 29th December 2016; Revised: 10th February 2017; Accepted: 25th March 2018 ABSTRACT Acrylic resin is the most commonly used denture base material. However, it has a shortage of being easily broken. One way to resolve this problem is by adding polyethylene (PE) or glass fibers. The purpose of this research is to compare the transversal strength of PE and glass fibers from denture plate acrylic resin repair material. The experiment involved 32 plates of heat cure acrylic with the dimensions of 65 mm x 10 mm x 2.5 mm. The speciments were prepared to create a 3 mm gap and 45° bevel. Subjects were divided into 2 groups, each group containing 16 plates. Group I was reinforced with PE fiber and Group II was reinforced with glass fiber. All plates were soaked in distillation water for one day at 37 °C. Plates were tested for transverse strength with universal testing machine and all data were analyzed with independent t-tes at 95% confidence level.
    [Show full text]
  • Adverse Reactions to Denture Resin Materials
    European Review for Medical and Pharmacological Sciences 2017; 21: 5298-5305 Adverse reactions to denture resin materials M. KOSTIC1, A. PEJCIC2, M. IGIC1, N. GLIGORIJEVIC1 1Clinic of Stomatology, Department of Prosthodontics, Faculty of Medicine, University of Nis, Nis, Serbia 2Clinic of Stomatology, Department of Oral Medicine and Periodontology, Faculty of Medicine, University of Nis, Nis, Serbia Abstract. – Irrespective of the new generation holders, artificial teeth, veneers and temporary of dental materials, acrylates still have a wide crowns and bridges3,4. Soft acrylic materials are indication field. Although they are classified used in the preparation, conditioning, and treat- as biomaterials, acrylates can have both local ment of damaged and inflamed tissue. Special and systemic side effects. The individual com- types of acrylates are used as a part of the structu- ponents of the acrylic materials may leave the dental restorations and diffuse into saliva. The re of materials for the permanent binding of fixed aim of this study was to point out the potential- dentures (resin cement, glass ionomer resin mo- ly toxic components of acrylic dental materials, dified cement). As supporting materials acrylates as well as their possible adverse effects on oral have found the application in making individual tissues and the organism in general. The paper trays, certain dental restorations models, bite pla- was based on the assumption that the appropri- nes and occlusal templates1,2. ate selection of the type of acrylic material and the proper method of their preparation reduce Acrylics, depending on their indication field, their adverse effects to a minimum, which was may differ by type and method of preparation.
    [Show full text]
  • Coating Containing Urethane and Acrylic Resin Mixture for Improved
    Europaisches Patentamt (19) European Patent Office Office europeenpeen des brevets £P 0 661 317 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) intci.6: C08G 18/40, C09D 175/06 of the grant of the patent: 11.11.1998 Bulletin 1998/46 (21) Application number: 94119907.7 (22) Date of filing: 16.12.1994 (54) Coating containing urethane and acrylic resin mixture for improved resistance to chipping Urethan- und Acrylharzgemisch enthaltende Beschichtung zur Verbesserung des Steinschlagschutzes Revetement a partir d'un melange de resine d'urethane et d'acrylique pour une resistance amelioree aux pierres (84) Designated Contracting States: • Foukes, Richard J. DE ES FR GB IT SE Utica, Michigan 48317 (US) (30) Priority: 23.12.1993 US 173296 (74) Representative: Munch, Volker, Dr. et al Dres. Fitzner, Munch & Jungblut (43) Date of publication of application: Kaiserswerther Strasse 74 05.07.1995 Bulletin 1995/27 40878 Ratingen (DE) (73) Proprietor: BASF CORPORATION (56) References cited: Southfield, Michigan 48086-5009 (US) EP-A- 0 542 105 EP-A- 0 555 705 (72) Inventors: • Harris, Paul J. West Bloomfield, Michigan 48324 (US) DO Is- CO CO CD Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice the Patent Office of the Notice of shall be filed in o to European opposition to European patent granted. opposition a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. a. 99(1) European Patent Convention). LU Printed by Jouve, 75001 PARIS (FR) EP0 661 317 B1 Description Field of the Invention 5 The present invention is directed to coating compositions.
    [Show full text]
  • The Dynisco Extrusion Processors Handbook 2Nd Edition
    The Dynisco Extrusion Processors Handbook 2nd edition Written by: John Goff and Tony Whelan Edited by: Don DeLaney Acknowledgements We would like to thank the following people for their contributions to this latest edition of the DYNISCO Extrusion Processors Handbook. First of all, we would like to thank John Goff and Tony Whelan who have contributed new material that has been included in this new addition of their original book. In addition, we would like to thank John Herrmann, Jim Reilly, and Joan DeCoste of the DYNISCO Companies and Christine Ronaghan and Gabor Nagy of Davis-Standard for their assistance in editing and publication. For the fig- ures included in this edition, we would like to acknowledge the contributions of Davis- Standard, Inc., Krupp Werner and Pfleiderer, Inc., The DYNISCO Companies, Dr. Harold Giles and Eileen Reilly. CONTENTS SECTION 1: INTRODUCTION TO EXTRUSION Single-Screw Extrusion . .1 Twin-Screw Extrusion . .3 Extrusion Processes . .6 Safety . .11 SECTION 2: MATERIALS AND THEIR FLOW PROPERTIES Polymers and Plastics . .15 Thermoplastic Materials . .19 Viscosity and Viscosity Terms . .25 Flow Properties Measurement . .28 Elastic Effects in Polymer Melts . .30 Die Swell . .30 Melt Fracture . .32 Sharkskin . .34 Frozen-In Orientation . .35 Draw Down . .36 SECTION 3: TESTING Testing and Standards . .37 Material Inspection . .40 Density and Dimensions . .42 Tensile Strength . .44 Flexural Properties . .46 Impact Strength . .47 Hardness and Softness . .48 Thermal Properties . .49 Flammability Testing . .57 Melt Flow Rate . .59 Melt Viscosity . .62 Measurement of Elastic Effects . .64 Chemical Resistance . .66 Electrical Properties . .66 Optical Properties . .68 Material Identification . .70 SECTION 4: THE SCREW AND BARREL SYSTEM Materials Handling .
    [Show full text]
  • Properties of Ptfe
    Bio-Polymer LECTURE 5 MSc: Amir N.Saud Al-Mustaqbal university college POLYMER AS BIOMATERIAL Polymer : is a large molecule, or macromolecule, composed of many repeated subunits. Due to their broad range of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life.[ Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers . Polymers have assumed an important role in medical applications. In most of these applications, polymers have little or no competition from other types of materials. Their unique properties are: 1- Flexibility; 2- Resistance to biochemical attack; 3- Good biocompatibility; 4- Light weight; 5- Available in a wide variety of compositions with adequate physical and mechanical properties; 6- Can be easily manufactured into products with the desired shape APPLICATIONS IN BIOMEDICAL FIELD AS: 1- Tissue engineering; 2- Implantation of medical devices and artificial organs due to its inert nature; 3- Prostheses; 4- Dentistry; 5- Bone repair; 6- Drug delivery and targeting into sites of inflammation or tumors; 7- Plastic tubing for intra-venous infusion; 8- Bags for the transport of blood plasma; 9- Catheter. A FEW OF THE MAJOR CLASSES OF POLYMER ARE LISTED BELOW: (1) (PTFE) Polytetrafluoroethylene is a fluorocarbon– based polymer. Commercially, the material is best known as Teflon. It is made by free-radical polymerization of tetrafluoroethylene and has a carbon backbone chain, where each carbon has two fluorine atoms attached to it.
    [Show full text]
  • Surface Microhardness, Flexural Strength, and Clasp Retention And
    ORIGINAL RESEARCH Surface Microhardness, Flexural Strength, and Clasp Retention and Deformation of Acetal vs Poly-ether-ether Ketone after Combined Thermal Cycling and pH Aging Salma Mahmoudd Fathy1, Radwa Mohsen Kamal Emera2, Reham Mohamed Abdallah3 ABSTRACT Aim: To evaluate the effect of combined thermocycling and artificial saliva pH on flexural strength, surface microhardness, as well as clasp retention and deformation of two different thermoplastic polymers. Materials and methods: Three groups were created, heat-cured polymethyl methacrylate, acetal, and poly-ether-ether ketone (PEEK) resins. Specimens were wrapped in plastic bags containing artificial saliva with three pH values (acidic 5.8, neutral 7.2, and alkaline 8.3). Two Aker clasps materials (acetal and PEEK), for premolar and molar, were stored in neutral salivary pH. Specimens were subjected to 2,000 thermocycles (5–55°C). Surface microhardness, flexural strength, and clasp retention and deformation were evaluated before and after aging. Data were analyzed by ANOVA, Tukey’s test, Student’s t-test, and paired t-tests (p < 0.05). Results: Thermal cycling at acidic and alkaline pH significantly decreased flexural strength and surface microhardness of acetal. It had no significant effect on PEEK properties. Poly-ether-ether ketone showed statistically significant higher mechanical properties in all groups. Acetal clasps exhibited a statistically significant deformation and a corresponding decrease in retention after thermocycling at neutral pH. Conclusion: Mechanical properties of acetal, as well as its clasp retention and deformation, significantly decreased after combining thermal and pH aging and thermal cycling in neutral pH, respectively. Meanwhile, PEEK clasps were not significantly affected. Clinical significance: Different intraoral variables may significantly affect mechanical performance, retention, and deformation of TMs used for denture base and clasp construction.
    [Show full text]
  • Liquid Resins & Additives
    LIQUID RESINS & ADDITIVES Europe, Middle East & Africa Corporate Center Frankfurt The Squaire 13 Am Flughafen D 60549 Frankfurt am Main Germany www.allnex.com www.allnex.com LRA006-EMEA-0219 LRA Lillestrm (NO) Wageningen (NL) Hamburg (DE) Bergen op Zoom (NL) Riga (LV) Frankfurt (DE) Silvertown (UK) Shebekino (RU) Ulsan (KR) Kalamazoo (MI) Schoonaarde (BE) Bitterfeld (DE) Wallingford (CT) Shimonoseki (P) East St Louis (IL) Drogenbos (BE) Graz (AT) Changshu (CN) Werndorf (AT) Otake (P) Willow Island (WV) Louisville (KY) Wiesbaden (DE) Suzhou (CN) Romano d’Ezzelino (IT) Shanghai (CN) Alpharetta (GA) Langley (SC) Foshan (CN) North Augusta (SC) Fengxian (CN) Bangkok (TH) Mumbai (IN) Zhuhai (CN) Rayong (TH) Bien Hoa (VN) Seremban (MY) Malakka (MY) Surabaya (ID) akarta (ID) Ponta Grossa (BR) Wacol (AU) Botany (AU) Penrose (NZ) Facts & Figures • Global company with over €2.1 billion in sales • 33 manufacturing facilities • Broad technology portfolio: liquid coating resins, • 23 research and technology centers energy curable resins, powder coating resins, • 5 ventures crosslinkers and additives, composites and • Extensive range of solutions for key coating segments: construction materials automotive, industrial, packaging coating and inks, • Approximately 4000 employees protective, industrial plastics and specialty With manufacturing, R&D and technical facilities located throughout Europe, North America, Asia Pacific and Latin America, • Customers in more than 100 countries architectural allnex offers global and reliable supply of resins and additives combined with local, responsive customer support. allnex 3 We are allnex allnex is a leading producer of liquid coating resins and to be used in multiple end-user segments including additives (LRA). The LRA business provides Automotive OEM, Vehicle Refinish, Marine & a comprehensive range of products with its core Protective, High End Metal Finishes, Decorative and technologies including: Alkyds, Acrylics, Epoxies, Construction.
    [Show full text]
  • Comparison of Denture Base Material Processed by the Traditional and a Two-Cycle Method
    Comparison of Denture Base Material Processed by the Traditional and a Two-cycle Method Undergraduate Research Thesis Presented in partial fulfillment of the requirements for graduation with honors research distinction in Biochemistry in the undergraduate colleges of The Ohio State University. By Gefei Wang The Ohio State University Project Advisor: Professor Fengyuan Zheng, College of Dentistry Professor Scott Schricker, College of Dentistry Defense Committee: Dr. Scott Schricker, Dr. John Shimko, Dr. Fengyuan Zheng and Dr. Richard Swenson ACKNOWLEDGEMENTS First, I want to acknowledge and thank Dr. Fengyuan Zheng, for introducing me to this project and for his guidance and encouragement. To my honors advisor, Dr. Scott Schricker, thank you for your helpfulness and willingness to answer all of my questions throughout the past two years. I would like to thank Dr. Mostafa Ibrahim for all of his help making the specimen for the study. I want to thank the lab technician, Mr. Carl Kipp, for teaching me the proper methods of using the lab equipment. I would like to thank Dr. Callam Christopher for allowing me to use equipment from organic chemistry lab. I would also like to thank Dr. William Johnston for helping me measure the color and transparence of the specimen. I would like to thank Dr. John Shimko and Dr. Richard Swenson for serving as my defense committee members. I am grateful to the financial support from ASC Undergraduate Research Scholarship and Rudy Melfi Fellowship. Finally, I would like to thank my family for always loving and supporting me in everything that I do. 1 ABSTRACT Poly(methyl methacrylate) PMMA is the preferred polymer to fabricate denture base materials.
    [Show full text]
  • New Trends for the Processing of Poly(Methyl Methacrylate) Biomaterial for Dental Prosthodontics Methacrylate) Biomaterial for Dental Prosthodontics
    DOI: 10.5772/intechopen.69066 Chapter 3 Provisional chapter New Trends for the Processing of Poly(Methyl New Trends for the Processing of Poly(Methyl Methacrylate) Biomaterial for Dental Prosthodontics Methacrylate) Biomaterial for Dental Prosthodontics Ma. Concepción Arenas-Arrocena, LilianaMa. Concepción Argueta-Figueroa, Arenas-Arrocena, René García-Contreras, Liliana Argueta-Figueroa, René García-Contreras, Omar Martínez-Arenas, Berenice Camacho-Flores, Omar Martínez-Arenas, Berenice Camacho-Flores, María del Pilar Rodriguez-Torres, Javier de la Fuente-Hernández and Laura S. Acosta-Torres Laura S. Acosta-Torres Additional information is available at the end of the chapter Additional information is available at the end of the chapter http://dx.doi.org/10.5772/intechopen.69066 Abstract Rehabilitation of masticatory function in patients with absent teeth with removable dentures is an established form of treating partial or complete dentition in edentulous patients. The developments in recent decades with dental implants dominate current den- tal research. However, medical contraindications, a negative attitude toward implants, or financial limitations on the part of the patients limit their universal applicability, so the rehabilitation with dental prostheses still makes up a significant portion of everyday clinical practice. Conversely, removable dentures are used in the critical conditions of the oral cavity. There are about 500 strains of microorganisms in the mouth, which form the biofilm in an acidic environment causing several issues, such as denture stomatitis, deterioration of the periodontal status of the remaining teeth, or carious lesions in the supporting teeth. Therefore, it is very important to choose a suitable material for the prosthesis. Poly(methyl methacrylate) (PMMA) is an acrylic resin usually used with a long tradition for prosthetic purposes.
    [Show full text]
  • Waterborne Acrylic Resin Modified with Glycidyl Methacrylate (GMA)
    Polymer 143 (2018) 155e163 Contents lists available at ScienceDirect Polymer journal homepage: www.elsevier.com/locate/polymer Waterborne acrylic resin modified with glycidyl methacrylate (GMA): Formula optimization and property analysis * Xingkui Guo a, Shengsong Ge a, , Junxiang Wang a, Xincheng Zhang a, Tao Zhang a, ** *** **** Jing Lin b, , Cindy Xinxin Zhao c, Bin Wang d, , Guangfei Zhu a, Zhanhu Guo c, a College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, China b School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, China c Integrated Composites Laboratory (ILC), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37996, USA d Engineered Multifunctional Composites (EMC) Nanotechnology LLC, Knoxville, TN 37934, USA article info abstract Article history: Novel waterborne acrylic resin modified with glycidyl methacrylate (GMA) was successfully synthesized Received 21 January 2018 via homogeneous solution polymerization in isopropyl alcohol followed by solvent exchange with water. Received in revised form Aminopropyltriethoxysilane (KH-550), a silane coupling agent that can crosslink with resin and iron base 25 March 2018 material, was used as curing agent for solidifying this GMA modified resin. The cured mechanism of the Accepted 3 April 2018 coating was also investigated by 29Si nuclear magnetic resonance (29Si NMR) spectra and attenuated total Available online 5 April 2018 reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). The waterborne acrylic resin was sprayed on the iron base material and cured by KH-550 for 30 min at 100 C to form the desired coating. Keywords: fi Glycidyl methacrylate The GMA and KH-550 were found to signi cantly decrease the curing temperature of this two- Silane coupling agent component waterborne resin.
    [Show full text]