RH Schwendeman and Erik Bjarnov Department Of
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MICROWAVE SPECTROSCOPY INFORMATION LETTER NO. XXIII April 1, 1980 Compiled by: R. H. Schwendeman and Erik Bjarnov Department of Chemistry Michigan State University East Lansing, MI 48824 USA MICROWAVE SPECTROSCOPY NEWSLETTER XXIII List of Contributors No. Contributor Institute Page I-:- Alonso, J, L, University of Valladolid -1- 2. Bak, B, University of Copenhagen 2 3. Baker, J. G. University of Manchester 3 4. Bauder, A. Swiss Federal Institute of Technology 4 5. Beaudet, R, A .. University of Southern California 5 6, Beeson, E. L, University of New Orleans 5 7. Bevan, J. W. Texas A&M University 6 8. Boggia, L. M, U.N.L,P. (Argentina) 6 9. Bohn, R. K. University of Connecticut 7 10. Brown, R. D. Monash University 8 11. Cederbalk, P, University of Stockholm 8 40. Cohen, E, A. Jet Propulsion Laboratory 31 12, Cook, R. L~ Mississippi State University 9 13. Cox, A, P. University of Bristol 10 14. Curl, R. F. Rice University 11 54. Dijkerman, H, A, Rijksuniversiteit Utrecht 41 15. Doraiswamy, S. Tata Institute of Fundamental Research 11 16. Dreizler, H. Universitat Kiel 12 17. Durig, J., R. University of South Carolina 14 18. Favero, P. Institute Chimico "G. Ciamician'-' 15 19. Ford, R. G. Memphis State University 16 20. Gerry, M~ C. L, University of British Columbia 17 21. Ghosh, D. K. Saha Institute of Nuclear Physics 17 22. Gillies, C, W. Rensselaer Polytechnic Institute 18 23. Graybeal, J .. D. Virginia Polytechnic Institute 18 i No. Contributor Institute Page 16. Guarnieri, A, Universitat Kiel 12 4. Gtinthard, Hs. H. Swiss Federal Institute of Technology 4 24. Harmony, M. D. University of Kansas 19 25. Hayashi, M. Hiroshima University 19 26. Hirota, E. Institute for Molecular Science, Japan 20 27. Hoeft, J, Freie Universitat Berlin 21 33. Johnson, D. R. National Bureau of Standards 26 28. Kewley, R, Queen's University 23 29. Kojima, T. Toyama University 23 30. Kroto, H, W. University of Sussex 24 31. Kuczkowski, R. L, University of Michigan 25 32. Kukolich, S. G. University of Arizona 26 37. Legan, A. C. University College London 29 46. Lees, R, M. University of New Brunswick 35 33. Lovas, F. J. National Bureau of Standards 26 48. Macdonald, J, University College of North Wales 37 34. Marstokk, K. M. University of Oslo 27 35. Matsumura, C. National Chemical Laboratory for Industry 28 36. Meerts, W. L. Katholieke Universiteit 28 37. Millen, D. J. University College London 29 38. Mills, I, M. University of Reading 30 18. Mirri, A. Tnstituto Chimico ''G. Ciamician''' 15 34. M¢llendal, H, University of Oslo 27 39. Morino, Y .. Sagami Chemical Research Center 31 40. Pickett, H. M. Jet Propulsion Laboratory 31 40. Poynter, R. L. Jet Propulsion Laboratory 31 41. Pozdeev, N, Bashkirian Filial, Academy of Sciences, USSR 32 ii No. Contributor Institute Page 42. Quade, c. R. Texas Tech University 33 43. Roussy, G. Dniversit~ de Nancy 33 44. Rudolph, H. D, University of Ulm 34 26. Saito, S. Institute for Molecular Science, Japan 20 45. Sasada, Y. Kanto Gakuin University 35 46. Sastry, K,V,L.N, University of New Brunswick 35 47. Schwendeman, R. H. Michigan State University 36 15. Sharma, S. D. Tata Institute of Fundamental Research 11 48. Sheridan, J. University College of North Wales 37 49. Shimizu, T. University of Tokyo 38 33. Suenram, R. National Bureau of Standards 26 16. Sutter, D. Universitat Kiel 12 50. Takami, M, Institute of Physical Chemical Research, Japan 39 51. Takano, M. National Defense Academy, Japan 39 52. Tanaka, T. Kyushu University 40 53. Tiemann, E. Universitat Hannover 41 27. Tischer, R. Freie Universitat Berlin 21 27. Tarring, T. Freie Universit~t Berlin 21 54. van Eijck, B. P. Rijksuniversiteit Utrecht 41 55 . Wertheimer, R. Universit~ de Lille 42 56. Whiffen, D. H. University of Newcastle upon Tyne 43 57. Wilson, E. B. Harvard University 44 58. Winnewisser, B, P. Justus Liebig UniversitHt Giessen 45 58, Winnewisser, G. Justus Liebig Universitat Giessen 45 58. Winnewisser, M, Justus Liebig Universit~t Giessen 45 59. Woods, R. c. University of Wisconsin 46 60. Yamaguchi, I. Sophia University 46 61. Zeil, W. Universit~t Tubingen 47 iii 1 Uni '·/crs it':' of ~/.::d 1 ado 1 id 1. Name to whom queries should be addressed ~Jose L. f\lons __o _____________ _ Mailing address ______D_e~pa_r_t_a_m_e_nt_o __ d_e_Q~u_i_n_1i_c_a_-F_i_s_i_c_a _______________ Facultad de Ciencias, Universidao de Valladolid Valladolid, Spain Telephone n~bc~.~~~(-9_8_3_)_2_5_18_8_4__ ~~~~~~~~~--~~~ FO~fiJLA NAME OF NAME OF PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS . cis-Propionyl Chloride F. r~ata J. ~ol. Structure Jose L. Alonso 56, (1979) 199-?05 Sulfolane ·Jose L•. Alonso Ground state (with Harvard) assigned Ethylene Carbonate Jose L. Alonso Rotation-Vibration (with Harvard) Interactions Ethylene trithiocarbonate Jose L . .l\lonso Just beginning (vii th Harvard) Cyclohexanone \.lose L . .l\·lonso Excited states .(with Harvard) assigned 2 Chloro cyclohexanone Jose L. Alonso Just beginning ( vii t h Ha r v a r'd ) l,3Dithianc Jose L. Alonso Just beginnin(] (with Harvard) Thionyl Chloride F. Mata vJork ; n pro~] res s N. Carballo Butyryl Chloride F. Mata High resolution J. Perez spectrum observed 4-Nitropyridine F. Mata Spectrum observed R. Mulas 2 2. ~arne to whom queries should be addressed: Staff member indicated by +) below . Mailing address: Chemical Laboratory V UNIVERSITY OF COPENHAGEN H.C. 0rsted Institutet 5, Universitetsparken DK-2100 Copenhagen, DENf1ARK Telephone number: 01 35 31 33 F,ORMULA NAME OF NAME OF PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS C2H4N2 N-cyanomethyl +)B.Bak Acta Chem.Scand. amine, H.Svanholt in press. (CH NHCN) CH - and CD - 3 . 3 3 c H N o x X=S,Se 1, 6-dioxa- +)T.Pedersen Spectra 3 2 2 2 4 2,5-diaza-6aA. - obtained. thia(selena)pentalene 0-X-0 I I \ N C N " c/\. c / H H C H S methylthioketene +)B.Bak Spectrum 3 4 (cH CH=C=S) H.Svanholt assigned. 3 H F 2,4,6-trifluoro T.Correll J.Mol . Structure c6 2 3No 2 nitrobenzene +) N. V.J. Lars en in press. +)T.Pedersen 2,4-difluoro + ) N . ~"1 • Lars en l-1 a -spectrum. nitrobenzene O.V.Nielsen assigned. 2-,3- and 4-fluoro T.Correll J.Hol.Structure nitrobenzene +)N.W.Larsen in press. +)T.Pedersen phenylphosphine, +)N.W.Larsen Paper in -PH ,-PHD,-PD T.Steinarsson preparation. 2 2 2-,3- and 4-fluoro B.Filt S¢rensen LID1W recorded, benzoylfluoride +)N.W.Larsen a-type spectra +)T.Pedersen assigned. 3 3. Name to whom queries should be addressed Dr J G Baker ------~~~~~------------------------------ Mailing address Schuster Laboratory, The University, Manchester Ml3 9PL, UK Telephone n~~ber------------------------------------------------- 061 273 4832 FOFJvnJLA NAME OF NAME OF .PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS cos carbonyl sulphide D Andrews DR lineshape and R Blore transient measurements. H CO formaldehyde ·Jane Ellis Line and Stark 2 profiles - paper in preparation. iodine pentafluoride B Balicki Excited .states; P N Brier paper in preparation. methyl bromide E Arimondo Laser - rf DR; P Glorieux paper submitted T Oka to J. Mol. Spectr. S Saito methyl fluoroform R Creswell Hm spectrum of excited states; paper in preparation. 4 4. Name t:o whom queries should be addressed Prof. A. Bauder ------------~~--------------~------------ Mailing address Laboratorium flir Physikalische Chemie ETH ETH-Zentrum CH-8092 ZUrich, Switzerland Telephone number 01 1 256 43 41 FORMULA NAME OF NAME OF .PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS excited torsion Methylnitrite P. Ghosh · al states of cis conformer H. Ruprecht measurements complete E. Walder in press (Chern. Phys.) (CH COCOOH) Pyravic acid R. Meyer torsional C3H403 3 interactions in excited states M. Tyblewski exo and endo C7Hl20 (N) Norbornanol s. Vaccani forms assigned c H S ) Thietene M. Rodler spectrum 3 4 (0 measured CH o (HCOOOH) Peroxiformic acid F. Oldani work started 2 3 HN0 Nitric acid P. Ghosh excited states 3 CF N o (CF (N0 ) ) Difluorodinitromethane D. Suter spectrum 2 2 4 2 2 2 measured CFN o (CF(N0 ) ) Fluorotrinitromethane A. Bauder partly assigned 3 6 2 3 5 5. Name to whom queries should be addressed Dr. R. A. Beaudet ~----------~---------------------------- Mailing address Department of Chemistry University of Southern California - Seaver Science 622 Los Angeles, California 90007 Telephone number__ 2_1_3.;_/ _74_1_-_2_99_7_____ ,___ __________ FORMULA NAME OF NAME OF PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS Simmons Completed B4Hl0 Tetra.borane Chiu Unassigned B5Hll Pentaborane(ll) Methyl Dicarborane Chiu Deuterated B2H5CH 3 Isotopes 1,2-Dimethyl Dicarborane Chiu Prepared Sample 6~ Name to whom queries should be addressed E. t. Bees on ~ · ------------------------------------~----- Mailing address Department of Physics University of New Orleans New Orleans, LA 70122 Telephone number (504) 283-0341 --~~~-------------------------------------- FORMULA NAME OF NAME OF PRESENT STAGE COMPOUND INVESTIGATOR OF PROGRESS 1,2,3,4-tetrafluorobenzene William Washington Double resonance started 7. Name to whom queries should be addres~ed--------------------------------------- John W. Bevan 6 Mailing address Chemistry Department Texas A&M University College Station, TX 77843 Telephone number 713-845-6673 --~~~~-------------------------------- FORMULA NAME OF NAME OF PRESENT STAGE COMPOUND · INVESTIGATOR OF PROGRESS BC H N t-butylisocyanide J.F. Stevens Published J. Mol. 5 12 -borane R.F. Curl Spect., 78, 514 (CH 3)3CNCBH 3 J.W. Bevan (1979).- ammonium cyanide J.W. Bevan Work continuing R.F. Curl trimethyl ammonium J.W. Bevan Nearing completion cyanide R.F. Curl endo and exo- J.W. Bevan Nearing completion 6-methyl 3bicyclo T. Richter (3.1.0)hexanone) Bicyclo(3.1.0) 2-4 S. Bomar Spectrum assigned dioxo-3-hexanone Prof. LUIS ~RIO BOGGIA 8. Name to whom queries should be addressed ~~~~------------------------------- Mailing address D:lp.