School of GeoS ciences
Dissertation For the degree of
MSc in Ecological Economics
Lina Isabel Brand Correa*
August 2014
* Beneficiaria COLFUTURO 2013.
EXERGY AND USEFUL WORK ANALYSIS AS A TOOL FOR IMPROVED ENERGY POLICY MAKING: THE CASE OF THE
COLOMBIAN ENERGY SECTOR
Lina Isabel Brand Correa
A dissertation presented for the degree of Master of Science University of Edinburgh, 2014.
I assert my right to be identified as the author of this work in accordance with section 78 Copyright Designs and Patents Act 1988.
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THE UNIVERSITY OF EDINBURGH
(Regulation ABSTRACT OF THESIS 3.5.13)
Name of Candidate Lina Isabel Brand Correa
Address 39/5 Marchmont Crescent, EH9 1HF, Edinburgh
th Degree MSc. in Ecological Economics Date 15 of August, 2014
Title of Thesis Exergy and Useful Work Analysis as a Tool for Improved
Energy Policy Making: The Case of the Colombian Energy Sector
No. of words in the main text of Thesis 20653
Energy systems entail a dualism: they are absolutely vital for the normal functioning of societies, but the activities related to them are threatening the stability of the natural environment where societies develop (by being the main source of greenhouse gas emissions). Therefore, energy systems need to be maintained and further expanded, whilst simultaneously reducing their negative environmental impacts. In this sense, a deeper understanding of the thermodynamic concepts behind energy use and conversion processes is needed. Exergy and useful work provide such an understanding and hence their analysis can be used as a tool for improved energy policy making, particularly when dealing with efficiency improvements.
In consideration of the above, this dissertation first looks into the energy dualism, followed by the description of the conceptual framework which orientates the work. Subsequently this is applied to the analysis of Colombia as an illustrative case study, taking into account data availability and specific features of that country’s energy system, which in themselves provide special analytical interest. Finally, this dissertation discusses methodological issues and results, as well as the energy policy implications derived from the analysis, both in general/conceptual terms and in the specific case of Colombia.
As a result, it was found that exergy and useful work analysis is a tool that can complement traditional energy analysis when assessing national energy systems. Exergy and useful work provide significant conceptual improvements, as well as strengthening the comprehension of the whole flow of energy through society. Furthermore, exergy and useful work analysis leads to different energy policy recommendations when compared to the traditional energy based analysis, particularly regarding energy sources for electricity generation, efficiency dilution effects and leapfrogging opportunities.
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ACKNOWLEDGEMENTS
First and foremost I would like to extend warm thanks to Paul Brockway for his generous sharing of time, knowledge and experience, and for introducing me into the academic circle of exergy. This dissertation would not have achieved what it has without his kindness and support. I would also like to thank sincerely my supervisor, Claudio
Cattaneo, especially for his critical and opportune advice when in danger of getting carried away by my enthusiasm for the topic. Additionally, a big thank you to Oscar
Gonzalo Manrique for sharing the data for Colombia, but ever more so for awakening my interest in this topic some years ago. And to Héctor Iván Velásquez and Sergio A. Giraldo for being so patient with me while I struggled to grasp, at least partially, the thermodynamics behind it all.
On the personal side, I would like to thank especially my library buddies R and T for providing such nice study breaks, while creating our own gastronomic/cultural routine!
Also to my family and friends back in Colombia, whose support even across the distance felt so close, and the thought of seeing them again gave me strength and inspiration.
Finally, heartfelt acknowledgements both to my dad, who is a constant source of objective and loving advice, and my mom, who virtually walked home with me every late night, patiently listening to all the ups and downs of this rollercoaster experience.
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TABLE OF CONTENTS
Acknowledgements ...... i Table of Contents ...... iii Table of Tables ...... v Table of Figures ...... vii List of Abbreviations, Symbols and Units ...... ix Chapter 1. Introduction...... 1 Chapter 2. Dualism of Energy for Modern Societies ...... 5 2.1. Energy as key for economic growth ...... 5 2.2. Energy as one of main causes of climate change and resource exhaustion ...... 9 2.3. Energy transition and the role of efficiency ...... 12 Chapter 3. Exergy and Useful Work ...... 15 3.1. Definition of relevant concepts ...... 15 3.2. Literature review of exergy applications ...... 27 3.3. Rationale and research question ...... 33 Chapter 4. The Colombian Case ...... 37 4.1. Colombia and its energy sector ...... 37 4.1.1. General context ...... 37 4.1.2. Energy reserves and potential ...... 39 4.1.3. Current energy use ...... 41 4.1.4. Evolution of energy use ...... 44 4.2. Methodology ...... 44 4.3. Past exergy and useful work ...... 47 4.4. Data analysis ...... 52 4.5. Future energy projections (PENs) ...... 61 Chapter 5. Discussion ...... 65 5.1. Methodology ...... 65 5.2. Results ...... 69 5.3. Policy implications ...... 72 5.3.1. General / conceptual ...... 72 5.3.2. Colombia ...... 75 Chapter 6. Conclusions ...... 81 References ...... 85 Appendix A ...... 101
iii
TABLE OF TABLES
Table 1. Energy forms and types classification ...... 16 Table 2. Units of energy, exergy, work, heat and power in the different systems of units 17 Table 3. Sectors and Consumption Categories ...... 50 Table 4. Details of TFC-UW and TPES-UW exergy efficiencies (1975-2009) ...... 53 Table 5. Exergy coefficients for Colombia's energy sources ...... 101
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TABLE OF FIGURES
Figure 1. Energy production and GDP for the world from 1830 to 2000 ...... 6 Figure 2. Global GHG emissions and fossil fuels ...... 10 Figure 3. UK's production and consumption emissions ...... 11 Figure 4. Resource classification ...... 12 Figure 5. Energy and exergy content of different systems ...... 21 Figure 6. Energy and exergy efficiency for 4 conversion systems ...... 24 Figure 7. Energy and exergy flow diagrams of a condensing power plant ...... 25 Figure 8. Energy system levels of analysis ...... 26 Figure 9. The flow-path of exergy to energy services ...... 27 Figure 10. Map of Colombia ...... 38 Figure 11. Colombia's non-renewable energy resources in 2013 ...... 40 Figure 12. Colombia's 2012 TPES and TFC ...... 42 Figure 13. TPES/TFC ratio and share of electricity generated by hydropower ...... 43 Figure 14. Colombia’s TFC by sector as a percentage of the total (2012) ...... 43 Figure 15. Energy sources used by sector (2012) ...... 44 Figure 16. TPES by energy sources as a percentage of the total (1975-2012) ...... 44 Figure 17. Colombia's primary exergy inputs ...... 47 Figure 18. Colombia's primary exergy inputs as a share of the total primary exergy input ...... 48 Figure 19. Colombia's secondary exergy inputs ...... 49 Figure 20. Colombia's secondary exergy inputs as a share of the total secondary exergy input ...... 49 Figure 21. Total exergy inputs in Colombia (1975-2009) ...... 49 Figure 22. Colombia's total exergy inputs by sector ...... 51 Figure 23. Colombia's total exergy inputs by sector as a percentage of total exergy inputs ...... 51 Figure 24. Total useful work in Colombia (1975-2009) ...... 52 Figure 25. Colombia's aggregate exergy efficiency (1975-2009)...... 53 Figure 26. Exergy efficiency by sectors and total exergy efficiency ...... 54 Figure 27. Exergy efficiency by agriculture processes and total agriculture exergy efficiency ...... 55 Figure 28. Exergy efficiency by industry processes and total industry exergy efficiency .. 55 Figure 29. Level of activity of the sectors ...... 56 Figure 30. Industry sector share of processes ...... 57 Figure 31. Residential sector share of processes ...... 57 Figure 32. Transport sector share of processes ...... 58 Figure 33. Exergy, useful work and exergy efficiency in Colombia (1975-2009) normalized 1975=1 ...... 59 Figure 34. Comparison of several country's overall exergy efficiency ...... 60 Figure 35. Projected TFC in the BAU and alternative scenario...... 63 Figure 36. Projected GHG emissions (PEN 2010) ...... 64 Figure 37. Comparison between UPME and IEA data ...... 66
vii
Figure 38. 2010 PEN projections and hypothetical stagnated TFC-UW efficiency ...... 70 Figure 39. Exergy and useful work in relation to GDP (1975-2009) ...... 72 Figure 40. Diagram of the potential exergy efficiency improvements ...... 74
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LIST OF ABBREVIATIONS , SYMBOLS AND UNITS
ANDI National Businessmen Association of Colombia BEN National Energy Balance COMMEND Community for Energy, Environment and Development E Exergy inputs Exergy efficiency GDP Gross Domestic Product IEA International Energy Agency LEAP Long -range Energy Alternatives Planning system Mtoe Million tonnes of oil equivalent OLADE Latin American Energy Organization PEN National Energy Plan SEI Stockholm Environment Institute TCal Tera calories TFC Total Final Consumption TPES Total Primary Energy Supply UPME Energy and Mining Planning Unit URE Rational Use of Energy UW Useful Work
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Energy is important enough to become a determinant, or at least conditionant, of all human activity IDEE (1994, p. 52)
Chapter 1. INTRODUCTION
Energy is the backbone of modern societies; their normal functioning is unconceivable without a sufficient, constant and secure supply of energy. That is the reason why governments all around the world maintain and further develop energy systems that satisfy their country’s needs. Energy is also important to achieve what are now considered minimum living conditions, therefore it must be affordable by everybody.
The current context of climate change (IPCC, 2013) poses additional challenges to the energy sector, especially since the majority of global greenhouse gas (GHG) emissions are a consequence of activities related to energy systems (IEA, 2012a). Thus, besides being secure and affordable, energy supply must be low carbon emitting. Together these three objectives of energy policy (security of supply, affordability and low carbon emissions) are grouped into what has been called by the World Energy Council the “energy trilemma” (Harvey, 2014).
By taking a step back and looking at the bigger picture, the trilemma can be transformed into a dualism: energy systems are vital for societies, but at the same time they are negatively affecting the natural environment that supports human life. In this sense, it is clear that in order to solve the energy dualism, energy systems need to be maintained and expanded, but they also need to transition towards being low carbon and sustainable.
However, resolving the energy dualism is more easily said than done. Energy systems are complex and energy is not like any other commodity. It requires large infrastructure and capital investments that lead to lock-in into certain technological and fuel alternatives
(Unruh, 2000), limiting substitution possibilities. Furthermore, it needs to be delivered to
Introduction 1
final users whenever it is needed, which becomes a vital consideration when the option of storage is not yet fully developed.
In addition, history teaches us that energy transitions do not happen overnight. The past full transition from traditional energy sources to fossil fuels took around 400 years, i.e. the full diffusion of the new energy sources and associated technologies (Fouquet, 2010). The ongoing transition towards low carbon sustainable energy systems is no exception; current evidence shows that renewables are not being implemented at the pace required to avoid catastrophic climate change consequences (IEA, 2014b).
Therefore, careful planning and efficiency improvements are important while a very much needed transition towards renewable and sustainable energy sources takes place.
Moreover, efficiency improvements represent the largest and least costly alternative to reduce the emissions caused by energy systems (IEA, 2008, p. 40), hence they are being promoted by most energy related organizations both national (see for example DECC,
2012; EIA, 2014; Univerisdad Nacional de Colombia & Fundación Bariloche, 2010) and international (see for example IEA, 2008; WEC, 2010).
In order to promote the efficiency alternative, a thorough understanding of the thermodynamic concepts behind it is needed. Nonetheless, when projecting future efficiency changes and their impact on energy demand –in order to formulate policies that meet such projections- , national and international organizations tend to rely on a first law of thermodynamics approach (i.e. energy analysis). This can be complemented by a second law of thermodynamics approach (exergy and useful work analysis) which, by analysing the maximum work obtainable from a system, reveals the maximum theoretical efficiency possibilities (Rosen, 2006a) and in turn suggests different policy recommendations.
Efficiency analysis can go a step further, moving into the sphere of energy services. Here the use of energy is considered in relation to the service it provides, for instance lighting,
Introduction 2
transportation or comfortable ambient temperature. In this context, efficiency can be assessed taking into account additional technical and social elements, which also lead to alternative policy recommendations. Although the importance of this level of analysis is fully recognised, as will be acknowledged throughout the dissertation, data availability limitations make it outside the scope of the present work.
Bearing in mind the above, the main goal of this dissertation is to analyse conceptually how exergy and useful work analysis can be used as a tool for improved energy policy making, based on the acknowledgement that there is an energy dualism upon which it is important to act in the short term. The analysis will be developed through an illustrative case study: Colombia, where, as in most countries, energy and energy efficiency are the concepts used to guide projections and policy making.
The selection of Colombia as a case study was made in part on the grounds of data availability on exergy efficiencies for that country, basic data deriving from previous research but further elaborated and analysed in the context of this dissertation. There are, however, other factors that make Colombia an interesting case study. Firstly, little previous work exists on the analysis of exergy and useful work in the context of energy policy for a developing country. Secondly, energy dualism is particularly relevant for developing countries in general. Finally, Colombia has considerable potential for developing alternative energy sources and the transition to a fossil fuel based energy system is still incomplete, thereby presenting interesting opportunities for leapfrogging.
Additionally, this dissertation will discuss the energy policy implications of exergy and useful work analysis, specifically for the Colombian case, but also for energy policy in general from a conceptual point of view. Furthermore, the value of exergy and useful work analysis will be related to specific demand, supply and efficiency concerns, which are the major areas of energy policy focus.
Introduction 3
The dissertation is organised into six main chapters. Following this introduction, the second chapter addresses the aforementioned dualism, explaining the importance of energy for societies (particularly for economic growth) but also the environmental impacts of current energy systems. This leads to the justification of the urgent need to undergo an energy transition towards low carbon and sustainable energy systems, but also the need to implement efficiency measures as an intermediate step.
The third chapter provides the conceptual framework needed to understand why exergy and useful work are relevant concepts to energy policy making. In this sense, a detailed explanation of exergy and useful work is given, followed by a literature review that reveals the paucity of their application in the energy policy field, and finally the rationale and research question underlying this dissertation are laid out.
The fourth chapter addresses the case study of Colombia’s energy system. It describes the country’s energy resources and potential in order to provide context. Subsequently it describes the methodology employed to analyse it. Existing exergy and useful work data are then presented, upon which a detailed analysis is undertaken, particularly with regard to the factors behind exergy efficiency changes. The chapter concludes with the evaluation of energy scenarios constructed by the Colombian government´s Unit of Mining and
Energy Planning (UPME in Spanish).
The fifth chapter develops a discussion of the three main issues that arise from the dissertation: methodological concerns, detailed results, and policy implications. Finally, the sixth chapter presents the main conceptual and case study related conclusions, especially in relation to policy implications, which are the main goal of this work.
Introduction 4
Energy sources of various kinds heat and power human development, but also put at risk the quality and long-term viability of the biosphere Hammond (2000, p. 304)
Chapter 2. DUALISM OF ENERGY FOR MODERN SOCIETIES
Energy is vital for the normal functioning of modern societies; it is central to economic and development related issues, but it is also central to pressing environmental issues.
Both these aspects are particularly relevant for developing nations, where large shares of the population cannot yet meet their basic needs and where the most adverse consequences of climate change will be felt (IPCC, 2014).
Economic growth and societal development depend on the availability of energy and material resources, but also life on earth depends on the conservation of the fragile conditions of ecosystems. In this section, this dual role of energy, as something absolutely essential for societies but at the same time as something that currently entails serious environmental impacts, will be analysed, in order to justify the need for a transition towards renewable and sustainable energy sources and hence the role of efficiency while the transition takes place.
2.1. ENERGY AS KEY FOR ECONOMIC GROWTH
Modern societies are absolutely dependant on a constant flow of energy. This dependence becomes evident when the flow is interrupted (Verbong & Loorbach, 2012), for example during electricity blackouts or during supply cut offs of other energy carriers (such as oil and gas). The disturbances in the normal functioning of societies prove that when the flow of energy is altered societies suffer: from simple events such as people getting stuck in elevators, to more serious issues such as production processes stopping, transport systems collapsing, the flow of information being disturbed and political tensions arising.
Energy systems are the lifeblood not only of modern societies, but also of any society throughout history. Cipolla (1978) describes the history of world population based on the
Dualism of Energy for Modern Societies 5
increased control over energy sources, moving from animated energy converters in agricultural societies (human and animal muscles) towards inanimate energy converters in industrial societies (steam engine, gas turbine and electric devices, amongst others). In other words, the increased control over and use of natural resources, particularly energy carriers, has led to a steep increase in population and productive activity.
In the same line of thought, White (1943) explains the history of cultural evolution in terms of energy and the efficiency of energy conversion processes. For White (1943) culture has the purpose of satisfying human needs, therefore humanity has to continue harnessing and exploiting natural resources in order for cultural progress not to cease.
Fouquet and Pearson (1998) provide empirical evidence of the above when analysing one thousand years (1000-2000) of energy statistics for the UK, showing that energy use has increased together with population and production, more markedly in the last two centuries when energy use has increased significantly (see Figure 1).
Figure 1. Energy production and GDP for the world from 1830 to 2000 Source: Murphy and Hall (2011, p. 68).
Dualism of Energy for Modern Societies 6
Energy use is linked primarily to productive activity and therefore to economic growth when measured by Gross Domestic Product (GDP, which measures the amounts of goods and services produced in a country in a year). This link is empirically illustrated by Figure
1, and section 3.1 will conceptually support the historical evidence by demonstrating, using physics and thermodynamics, that not a single productive process can be understood without the use of energy. Therefore, although these historical accounts are very valuable, they become more explicit when there is an understanding of important physic and thermodynamic concepts.
However, energy has not formally entered mainstream economic growth theory. This theory is based on the classic economics conception of labour and capital being the main factors of production. After World War II, when empirical corroboration of economic growth theory was possible (given the availability of national accounts), almost simultaneously Solow (1956) and Swan (1956) developed a model that used the Cobb-
Douglas function to perform statistical tests. The main finding was that a third factor of production, an exogenous one, was needed to explain economic growth, namely technological change, although it was used “as a shorthand expression for any kind of shift in the production function” (Solow, 1957, p. 312).
This third factor of production has mutated over the years, both in name and conception.
It has been called technical change, technological progress, the Solow residual and Total
Factor Productivity (TFP). It has also been endogenized in some economic growth models since the 1980s, using variables such as knowledge or human capital (Romer, 1994).
However, its true meaning continues to be quite ambiguous, hence it is not surprising that it has been referred to by some authors as the “measure of our ignorance” (Abramovitz,
1956, p. 11) or even as a “black box” (Rosenberg, 1982, p. 11).
The fact that mainstream economic theory has not incorporated energy in its conceptualization of economic growth is of considerable concern in the face of a much needed energy transition. There have been efforts, however, from disciplines such as
Dualism of Energy for Modern Societies 7
ecological economics to explain the role of natural resources in general and energy in particular in economic activity. In this line of thought, the theoretical contributions since the late 19 th century of some authors must be recognized: Serhii Podolinsky in the last decades of the 19 th century, Frederick Soddy and Alfred Lotka in the first half of the 20 th century (Cleveland, 1987; Martínez-Alier, 1987).
Since the second half of the 20 th century theoretical contributions continued with Nicholas
Georgescu-Roegen (1975), Herman E. Daly (1974, 1987), Reiner Kümmel (1982, 2011),
Cutler J. Cleveland and others (Cleveland, Kaufmann, & Stern, 2000; Cleveland & Ruth,
1997), Charles E. Hall and others (Hall & Kiltgaard, 2012), Bernard Beaudreau (1999),
Vladimir Pokrovsky (2003), Benjamin Warr and Robert Ayres (Ayres, Ayres, &
Pokrovsky, 2005; Ayres, Ayres, & Warr, 2003; Ayres, Turton, & Casten, 2007; Ayres &
Voudouris, 2014; Warr, Ayres, Eisenmenger, Krausmann, & Schandl, 2010), just to mention the main ones.
The two latter authors in particular (Ayres & Warr, 2009), find that by analysing the efficiency with which energy and materials flow in the economic system, an objective measure of technological progress can be found: useful work (see section 3.1 for a detailed definition). Furthermore, they use this new measure, together with a Linear Exponential function -LINEX first derived by Kümmel (1982)- completely different from the traditional Cobb-Douglas one, to test empirically its explanatory power.
They find that the Solow residual is almost entirely explained by useful work for the period 1900-2000 in the US and Japan, i.e. they endogenize technological progress using an objective and physics based measure. But more importantly, their work provides an explanation and a quantification of the shared intuition of many ecological economists:
“[P]roduction in the real world cannot be understood without taking into account the role of materials and energy” (Ayres & Warr, 2005, p. 182).
Dualism of Energy for Modern Societies 8
Finally, energy use has also been linked with development and quality of life. Lambert et al. (2014) find that energy indices (EROI and energy use per capita, amongst others) are correlated with higher standards of living (measured by the Human Development Index, percent of children under weight, health expenditures, Gender Inequality Index, literacy rate and access to improved water). The United Nations Advisory Group on Energy and
Climate Change (2010) also considers energy a key for poverty alleviation, health improvements, education access and food security, given that all of the above need energy supply to be achieved.
Even though the relationship between energy and quality of life is more indirect and cannot be proven by physics or thermodynamic concepts, it makes the energy question even more relevant for developing countries, which already need to consider the energy issue seriously in relation to economic growth 1. If economic growth is to continue into the future and if developing countries are to catch-up with developed countries in terms of living standards, there needs to be a greater use of energy sources, and thus a greater understanding of their physical and thermodynamic properties.
The empirical and historical understanding of the vital role energy has to play in economic growth and in the normal functioning of our societies addressed in this section, must be accompanied by an assessment of the environmental consequences of its use.
Hence, this issue will be analysed in the next section.
2.2. ENERGY AS ONE OF MAIN CAUSES OF CLIMATE CHANGE AND RESOURCE
EXHAUSTION
1 This dissertation will not address the issue of whether economic growth is a positive thing for societies and for the environment, but it is acknowledged that it is a much contested issue and that from a biophysical perspective evidence points towards the contrary.
Dualism of Energy for Modern Societies 9
Globally, the energy sector is the major emitter of GHG 2: around 65% of global GHG emissions originate from activities related to the energy system, i.e. extraction, transformation, delivery and use, and this figure rises to 83% in Annex I countries 3 (IEA,
2012a). The combustion of fossil fuels entails the emission of CO 2 resulting from the oxidation of carbon, which accounts for 92% of the emissions related to the energy sector; the remaining 8% is constituted by CH 4 and N 2O originated in other processes such as mining and transmission (IEA, 2012a). In 2011 81.6% of the world’s total energy supply came from fossil fuels, namely coal, oil and natural gas (IEA, 2012b), which has implications for both climate change and resource exhaustion. Figure 2 shows the relationship between global GHG emissions and fossil fuels.
Figure 2. Global GHG emissions and fossil fuels Source: Own elaboration based on data from IEA (2012a, 2012b).
Regarding climate change, there is now a scientific consensus that increased anthropogenic GHG emissions are linked with climate change (IPCC, 2013). Given that energy accounts for most GHG emissions worldwide, that fossil fuels are the world’s main energy source and that energy use has increased dramatically since the industrial
2 The GHG are: water vapour, CO 2 (carbon dioxide), CH 4 (methane), N 2O (nitrous oxide), O 3 (ozone) and CFC (chlorofluorocarbon). 3 Annex I countries correspond to industrialized countries and economies in transition as defined by the United Nations Convention on Climate Change (UNCCC) (IEA, 2012a).
Dualism of Energy for Modern Societies 10
revolution, the implications for climate change of the world’s energy mix being dominated by fossil fuels are clear. This is illustrated by Figure 2, especially if seen from right to left.
Considering the importance of energy for economic activity discussed in section 2.1, it might then seem contradictory the recent decreasing trend of emissions in certain countries (IEA, 2012a); however, it is important to note that this trend can be deceiving.
Emissions can be reduced in a single country even as economic growth keeps rising, but when taking into account global trade this decarbonisation of certain economies is not as clear as it might seem.
In a globalized world, trade has a major role to play. This is revealed when a country’s emissions analysis is done through the lens of consumption (Barrett et al., 2013; Davis &
Caldeira, 2010), where the embedded emissions in imported goods are taken into account.
The difference between the UK’s GHG emissions from production and consumption can be seen in Figure 3.
Figure 3. UK's production and consumption emissions Source: Barrett et al. (2013, p. 454).
It is not only in terms of climate change emissions that emissions and energy system related activities affect the environment. Energy has negative impacts in other areas of
Dualism of Energy for Modern Societies 11
environmental concern which include: stratospheric ozone depletion, acid precipitation and deposition, air pollution, smog and air quality and visibility degradation, water pollution (including groundwater and surface water degradation), solid waste disposal, hazardous waste disposal, soil degradation, oil spills and other major environmental accidents, and radiation and radioactivity releases (Rosen, 2002a).
On the other hand, regarding resource exhaustion, fossil fuels are deposits that are emptied as they are used. This corresponds to a resource classification following Wall
(1977), in which there are flows and stocks (see Figure 4). The former are unlimited in time (for example sun light), whilst the latter are limited in time and subdivided into live stocks or funds (such as a forest) and dead socks or deposits (such as oil, coal and gas).
Fossil fuels are non-renewable in our time frame and therefore finite, which means that they could be exhausted if they continue to be harnessed. Out of the three main fossil fuels, oil is the one that could be exhausted first, although there is no consensus about a time where ‘peak oil’ will be reached (Bradshaw, 2010).
Figure 4. Resource classification Source: Adapted from Wall (1977, p. 28).
2.3. ENERGY TRANSITION AND THE ROLE OF EFFICIENCY
Dualism of Energy for Modern Societies 12
Taking into account the environmental and resource exhaustion consequences of current energy sources, together with the vitality of energy for societies, it becomes clear that an energy transition must take place. However, history teaches us that energy transitions are slow and led by the opportunity to develop better or cleaner energy sources (Fouquet,
2010). Although in previous transitions the role of prices and scarcity was determinant, in this transition the role of regulation and directed action towards the reduction of GHG emissions will be a key component, given the pressing concerns about climate change and the adoption of legally binding commitments to reduce GHG emissions (Fouquet, 2012;
Pearson & Foxon, 2012). Therefore, energy policy must be directed towards sustainable and least environmentally harmful energy sources, i.e. renewable energy sources.
Nonetheless, the current rate of development of sustainable renewable energy is not sufficient to meet the 2⁰C stabilisation target established by the IPCC. As the IEA (2014b, p. 14) states: “[T]oday’s policies and market signals are not strong enough to switch investment to low-carbon sources […] at the necessary scale and speed”. In parallel, there is a debate around the decoupling of economic activity from energy and material use.
Decoupling can be absolute or relative: absolute decoupling is a myth, because as was mentioned before, economic activity cannot be understood without the use of energy; relative decoupling is possible through efficiency improvements, but it has an upper limit
(Jackson, 2009).
Thus, energy efficiency improvements should only be considered as a way to ease the transition towards a low-carbon economy, not as a final solution to the dualism described above. Nonetheless, “energy efficiency improvements […] represent the largest and least costly” alternative to reduce GHG emissions caused by the energy system (IEA, 2008), besides reducing the depletion of non-renewable energy sources and decreasing energy costs (Cullen & Allwood, 2010b, p. 2059).
It is at this point where exergy and useful work analysis has an important role to play as a tool for improved energy policy making: it can be used to better understand and address
Dualism of Energy for Modern Societies 13
energy efficiency. As will be explained in the following section, exergy and useful work analysis is particularly useful in revealing where the biggest losses in energy conversion processes occur and thus where the largest potential for efficiency improvements lay
(Rosen, 2006a, 2006b). This is relevant because efficiency improvements are a feasible and cost effective way forward while a complete transition towards low carbon sustainable energy takes place. In other words, exergy and useful work analysis can be used to increase relative decoupling of energy from economic activity while an absolute decoupling of non-renewable energy resources from economic activity takes place.
Dualism of Energy for Modern Societies 14
The second law of thermodynamics is, without a doubt, one of the most perfect laws in physics. Any reproducible violation of it, however small, would bring the discoverer great riches as well as a trip to Stockholm. The world’s energy problems would be solved at one stroke Bazarov (1964)
Chapter 3. EXERGY AND USEFUL WORK
Having established the need for a transition towards renewable and sustainable energy sources, but also the importance of efficiency improvements to ease such a transition, the thermodynamics behind efficiency in energy systems will now be addressed. First an in depth definition of relevant concepts will be made. Secondly a literature review of how these concepts have been applied in different fields will be made. And finally, the rationale and research question will be established.
3.1. DEFINITION OF RELEVANT CONCEPTS
Before going into the definition of unfamiliar concepts, such as exergy and useful work, more familiar concepts such as energy, work and power, will be defined. The latter, although used more often, are not necessarily better understood by non-experts. For instance, expressions such as “I’m going for a run to get energized” are fundamentally incorrect (Smil, 2006, p. 2), as well as talking about energy production or consumption is a common mistake, and even the expressions energy crises (Rosen, 2002b) and energy conservation (Rosen, 2002c) are confusing and misleading.
Energy in particular is a concept that is abstract and difficult to understand. “We cannot understand what energy actually is, since everything we can observe is energy in different forms” (Dincer, 2002, p. 141). But at the same time, energy is something absolutely essential for life. “Energy is the cause and measure of all that there has been, is, and will be […], it is a fundamental property of existence” (Kostic, 2007, p. 1). Although energy itself cannot be easily defined, its manifestations have been clearly identified and measured. Energy can take the forms summarized in Table 1.
Exergy and Useful Work 15
Table 1. Energy forms and types classification Energy Form Energy Type 4 Example Kinetic Kinetic A bowling ball thrown down a bowling lane Mechanical Gravitational Potential A painter on a stair A distorted elastic band (stretched, Elastic Potential compressed or folded) Sensible Kinetic Warm iron piece (no change in state) Thermal Latent Potential Frozen ice cube (change in state) Chemical Potential Ignition of a fuel, food oxidation Nuclear Potential Fission of uranium atoms Electro-kinetic Kinetic Electric current travelling through a cable Electric Electro-static Potential Nylon jumper out of the tumble dryer Electromagnetic Potential Electromagnetic magnet Source: Classification taken from Kostic (2004) and examples taken from Hecht (1987).
This classification is related to the energy of a system, in its different forms, at a given moment. A system is as big as its boundaries; it can be a single cell, an industrial process or a whole economy. Therefore, the definition of the energy of a system by Kostic (2012, p.
810) is appropriate: “Energy is fundamental property of a physical system and refers to its potential to maintain a system identity or structure and to influence changes with other systems (via forced interaction) by imparting work (forced directional displacement) or heat (forced chaotic displacement/motion of a system’s molecular or related structures)”.
However, it is generally more interesting to analyse the second part of Kostic’s definition that refers to system interaction, which can be more generally stated as “energy is the capacity to cause changes in the world” (Kümmel, 2011, p. 29). That is, to analyse how the energy in a system can influence other systems. In other words, energy transformations and their related manifestations of work performed and heat transferred when two systems interact.
Heat appears when energy is transferred in a disorganized (dissipative) way (as heat transfer); work, on the other hand, appears when energy is transferred in an organized
4 Kinetic: movement; Potential: state or position with respect to a force.
Exergy and Useful Work 16
way (movement in the direction of a force 5); and finally power is the rate of energy transfer per unit of time 6 (Kostic, 2004). The units in which energy, work, heat and power are measured can be seen in Table 2.
Table 2. Units of energy, exergy, work, heat and power in the different systems of units System of Units SI Metric English Energy and Exergy Joule (J) kcal Btu Work N×m= J kg f×m lb f×ft Heat a cal kcal (1000 cal) Btu Power J/s = W (Watt) KWh hp a Heat needed to warm by one degree of temperature a unit of mass of water (cal: 1 gram, 1°C; kcal: 1kg, 1°C; Btu: 1lb, 1°F). Source: Based on Kostic (2004, p. 529) and Levenspiel (1997, p. 6).
The above is even more relevant in the context of this dissertation, because work and heat are, in general, the energy manifestations that societies need to maintain themselves and their economic systems, whichever they are. Energy transformation processes are the ones that allow everything to happen: from “simple” phenomena such as our muscles moving because chemical energy is transformed into mechanical energy; through to more complex phenomenon like our cars, buses, trains and airplanes transporting us and tonnes of goods around the world because chemical energy (mostly fossil fuels) is transformed into mechanical energy; and our lights shining and our computers turned on because some sort of energy form (kinetic, chemical, nuclear, thermal, etc.) has been transformed into electricity.
In other words, the manifestations of energy transformation processes constitute the backbone of our societies. In the specific case of economies, and by allowing change to occur, no productive activity can be undertaken without energy use (this was historically and empirically demonstrated in section 2.1). Heat is important for certain industries and
5 Work = force * distance (W=f*d) 6 Power = energy transfer / time (P=E/t). It is usually related to the rate of work (P=W/t) but the rate of heat transfer can also be obtained (Kostic, 2004, p. 528).
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chemical processes, but also to warm up our houses and offices. Work on the other hand, given that it has higher quality 7, is even more important than heat.
Work has been and is particularly important for societies at every point in time; in early societies work was done by human and animal muscles, which was replaced during the
Industrial Revolution with inanimate energy sources (Cipolla, 1978). Early energy units are still used today (e.g. horse power), and even the increased use of inanimate energy sources has been compared to the amount of people that would be needed to perform the same work if humans did not have the capacity to harvest additional energy sources: energy ‘slaves’ (Armaroli & Balzani, 2011).
Electricity is a form of energy that is very versatile and can be completely transformed into work, therefore it is usually considered as a special case. To continue with the analogy mentioned above, electricity is the most skilful slave ever, given the fact that it can be converted into all other energy forms without major losses. It can also be considered the most efficient ‘slave’ ever, given that it travels at great speed, it does not need holidays or get injured and is always available for its users at the flick of a switch
(Manrique Díaz, 2013). Even historically it has been considered as a key driver of industrial development (Beaudreau, 1995; Rosenberg, 1998) and even change in social relations (Nye, 1990). However, its storage has not been developed yet, which has serious implications for several renewable energy sources such as wind and solar.
But how does all this relate to exergy? Exergy measures the quality of energy, and can be defined as “the maximum possible work that may be obtained from a system by bringing it to the equilibrium in a process with reference surroundings” (Kostic, 2012, p. 816). As
Gaggioli & Wepfer (1980, p. 823) state, exergy “is synonymous with what the layman calls
‘energy’. It is exergy, not energy, that is the resource of value, and it this commodity, that
‘fuels’ processes, which the layman is willing to pay for”.
7 “Work is a more valuable form of energy than heat inasmuch as 100% of work can be converted to heat, but only a fraction of heat can be converted to work” (Kanoglu et al., 2012, p. 15).
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Therefore, all the energy forms listed above (Table 1) have an exergy content which describes their quality. However, the exergy content depends on the surroundings, so usually a reference or average environment needs to be defined in order to be able to carry out exergy calculations 8. The exergy content of each energy form depends on its chemical and physical properties, and how they relate to the reference environment.
Appendix A shows the exergy coefficient for each energy form used in Colombia.
Considering the above, the highest quality energy forms are those that can be transformed completely into work. In this sense, mechanical and electric energy are the highest quality energy forms; they have 100% of exergy content related to their energy content, or a quality factor of 1; chemical energy follows with a quality factor of almost 1 (or even more than 1 depending on the system definition and surroundings); nuclear energy has between 95% of exergy content related to their energy content; sunlight has a quality factor of 0.9; and finally thermal energy is the one with least quality, because it has an exergy content that varies between 60 and 0% as the temperature difference decreases and approximates to that of the environment (Dincer, 2002; Wall, 1986).
In this sense, exergy accounting, using the same units (see Table 2) of energy accounting, has an advantage over the latter. The different energy forms can be indexed based on their quality, and the issue of having a good criterion of equivalence for national energy statistics posed by (Giampietro & Sorman, 2012) is avoided9. National exergy inputs can
8 Usually, a conventional stable reference environment (SRE) is defined as temperature T0 = 298.15K (25°C), pressure p0=1atm (1.013bar) and average chemical composition of the Earth’s three subsystems (atmosphere, hydrosphere and lithosphere) (Querol, Gonzalez-Regueral, & Perez- Benedito, 2013, pp. 9–10). 9 On the other hand, it is true what Cleveland, Kaufmann, & Stern (2000) point out: that even though exergy is a good common property of all energy and materials, it is one-dimensional, and it does not capture other important attributes such as energy density, cleanliness, conductivity, resistance, etc. Nonetheless, exergy is a tool for improved energy accounting that is based on stable thermodynamic concepts, in which sense it is better than prices or other subjective criterions of equivalence.
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be calculated by multiplying the energy balances by the exergy coefficients of each energy source.
The analogy proposed by Alfvén (cited by Wall, 1986) is particularly appropriate to illustrate this. According to Alfvén, to account for energy without taking quality into consideration is to be like an accountant who adds coins irrespective of their value. It is like adding together a £2 coin (e.g. electricity) with a 5p coin (e.g. low temperature heat) as two coins that can be interchangeable, instead of adding them as £2.05 where the £2 coin can pay for more things than the 5p coin.
Furthermore, similarly with respect to energy, it is more interesting to analyse the exergy in a system and how it is manifested during transformation processes in heat and work.
Exergy is destroyed in real life processes as a system reaches thermodynamic equilibrium with its reference environment; this is due to the irreversibilities present in real processes
(as opposed to ideal processes) (Dincer, 2002), which are accounted for by the second law of thermodynamics 10 . It is exergy the one that is consumed in transformation processes, while energy is conserved 11 . The quality of energy is degraded in transformation processes
(Wall, 1977), i.e. work is performed and heat is dissipated.
When a system reaches thermodynamic equilibrium with its surroundings, it is said to be in a dead-state, i.e. the “system is at the temperature and pressure of its environment (in thermal and mechanical equilibrium), it has no kinetic or potential energy relative to the environment (zero velocity and zero elevation above a reference level), and it does not react with the environment (chemically inert). Also, there are no unbalanced magnetic,
10 The second law of thermodynamics, also referred to as the entropy law and considered the “arrow of time” (Levenspiel, 1997, p. 181), states that the entropy of an isolated system always increases (Kümmel, 2011, p. 131). Exergy is derived from a combination of both the first and second thermodynamic law and measures quantity and quality, making it a more complete concept (Dincer, 2002). 11 Energy is derived from the first law and measures quantity. The first law of thermodynamics is one of the most famous laws of physics, and it is also referred to as the energy conservation law: “energy can be neither created nor destroyed during a process; it can only change forms” (Kanoglu et al., 2012, p. 12).
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electrical, and surface tension effects between the system and its surroundings, if these are relevant to the situation at hand” (Kanoglu, Cengel, & Dincer, 2012, pp. 20–21).
A system that is in a dead-sate may have energy in it, but it will not be possible to obtain work from it. For example, an ice cube has negative energy, but if it’s located in winter time in a country from the northern hemisphere, no work can be obtained from it because it is in equilibrium with its surroundings (Gong & Wall, 2001). However, if there is a temperature difference between a system and its surroundings, a heat engine can be run in order to obtain work from it (Kanoglu et al., 2012) (see Figure 5b). Similarly, if there is a height or speed difference between the system and its surroundings, a turbine can be run and work can be extracted from that system (Kanoglu et al., 2012) (see Figure 5a).
Likewise, work can be extracted when there are differences in pressure, chemical composition, and so on.
Figure 5. Energy and exergy content of different systems In panel a) there is no energy or exergy content when there is no height difference, but when there is a height difference the energy and exergy content is the same (i.e. potential and mechanical energy, which is why hydropower is so
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efficient). In panel b) the energy content of the steam engine and the heat reservoir is the same, but the exergy content of the steam engine is higher due to the higher temperature difference in relation to the environment. Source: Domingos (2013).
Moving on to efficiency, exergy analysis, by calculating the maximum possible work obtainable from a system, can determinate the locations, types and true magnitudes of losses, and thus where the major opportunities for the improvement of energy systems, lay (Kanoglu et al., 2012). This is usually done measuring the exergy efficiency of the different parts of a system. Efficiency in general can be defined as the ratio of desired output over required input; which in the case of energy efficiency is represented by equation (1) (Kanoglu et al., 2012):