Cavansite, a Calcium and Vanadium Silicate of Formula Ca(VO)(Si4o1o
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Optical-Spectroscopy.Pdf
Reviews in Mineralogy & Geochemistry Vol. 78 pp. 371-398, 2014 9 Copyright© Mineralogical Society of America Optical Spectroscopy George R. Rossman Division of Geological and Planetary Sciences California Institute of Technology Pasadena, California 91125-2500, U.S.A. grr@ gps.caltech.edu INTRODUCTION Optical spectroscopy is concerned with the measurement of the absorption, reflection and emission of light in the near-ultraviolet (-250 nm) through the mid-infrared ( -3000 nm) portions of the spectrum. The human interface to the geological and mineralogical world is primarily visual. Optical spectroscopy is, in particular, well suited to investigating the origin of color in minerals. The reflection spectroscopy of minerals has been motivated to a large extent by interest in remote sensing. Emission spectra are usually studied in reference to luminescence phenomena. Studies of mineral color, metal ion site occupancy, oxidation states and concentrations have generally been done with absorption spectroscopy. This chapter concentrates on single crystal absorption spectroscopy. Absorption of light by crystals can occur for a number of reasons. For many minerals, the presence of ions of transition elements (e.g., Ti, V, Cr, Mn, Fe, Co, Ni, Cu) in their various oxidation states is the cause of light absorption. In some minerals, the individual ions cause the light absorption while in others it is the interaction between ions such as between Fe2+ and Fe3+ that causes color. In some minerals, rare-earth elements are an important source of color. 2 Some minerals are colored by small molecular units involving metal ions (UOl+, Cr04 -) or anions (S 3- in sodalites). Many sulfide minerals such as cinnabar (HgS) and realgar (As4S4) owe their color to band gaps in the semiconducting sulfides. -
Apophyllite-(Kf)
December 2013 Mineral of the Month APOPHYLLITE-(KF) Apophyllite-(KF) is a complex mineral with the unusual tendency to “leaf apart” when heated. It is a favorite among collectors because of its extraordinary transparency, bright luster, well- developed crystal habits, and occurrence in composite specimens with various zeolite minerals. OVERVIEW PHYSICAL PROPERTIES Chemistry: KCa4Si8O20(F,OH)·8H20 Basic Hydrous Potassium Calcium Fluorosilicate (Basic Potassium Calcium Silicate Fluoride Hydrate), often containing some sodium and trace amounts of iron and nickel. Class: Silicates Subclass: Phyllosilicates (Sheet Silicates) Group: Apophyllite Crystal System: Tetragonal Crystal Habits: Usually well-formed, cube-like or tabular crystals with rectangular, longitudinally striated prisms, square cross sections, and steep, diamond-shaped, pyramidal termination faces; pseudo-cubic prisms usually have flat terminations with beveled, distinctly triangular corners; also granular, lamellar, and compact. Color: Usually colorless or white; sometimes pale shades of green; occasionally pale shades of yellow, red, blue, or violet. Luster: Vitreous to pearly on crystal faces, pearly on cleavage surfaces with occasional iridescence. Transparency: Transparent to translucent Streak: White Cleavage: Perfect in one direction Fracture: Uneven, brittle. Hardness: 4.5-5.0 Specific Gravity: 2.3-2.4 Luminescence: Often fluoresces pale yellow-green. Refractive Index: 1.535-1.537 Distinctive Features and Tests: Pseudo-cubic crystals with pearly luster on cleavage surfaces; longitudinal striations; and occurrence as a secondary mineral in association with various zeolite minerals. Laboratory analysis is necessary to differentiate apophyllite-(KF) from closely-related apophyllite-(KOH). Can be confused with such zeolite minerals as stilbite-Ca [hydrous calcium sodium potassium aluminum silicate, Ca0.5,K,Na)9(Al9Si27O72)·28H2O], which forms tabular, wheat-sheaf-like, monoclinic crystals. -
Swiss Society of Mineralogy and Petrology
Swiss Society of Mineralogy and Petrology http://ssmp.scnatweb.ch A MAJOR BREAKTHROUGH IN SWITZERLAND – THE GOTTHARD BASE TUNNEL On 15 October 2010, the last meter of rock separating the northern and southern parts of the eastern tube of the new Gotthard base tunnel disaggregated into dust. With a length of 57 km, it is currently the longest railroad tunnel in the world. It was built with a total deviation of only 1 cm vertically and 8 cm horizontally from the planned axis, and it traverses the Alps at an altitude of only 550 m above sea level. The tunnel was excavated using tunnel-boring machines and classical blasting in more schistose zones. Construction started in 1996, and to reduce the total construction time, excavation was carried out simul- taneously in several sections. The tunnel will be fully operational in 2017. Most rock types present at the surface are also found at tunnel level, almost 2.5 km below the surface, because the rock strata and foliations have a steep dip in this section of the Alps. The Gotthard region is famous for well-formed minerals occurring in Alpine-type fi ssures, and thus it was anticipated that mineralized cavities would be located in Quartz crystals 28 to 35 cm in length. PHOTO: PETER VOLLENWEIDER the new tunnel. For this reason, “mineral guards” were employed, whose duties were to collect, document and preserve mineralized clefts On May 13, 2011, the Natural History Museum in Bern opened a new encountered during tunnel excavation. The best sample material is permanent exhibit featuring one of the largest quartz crystal fi nds in currently exhibited in museums in Seedorf (Mineralienmuseum Schloss the Swiss Alps. -
Mineral Collecting Sites in North Carolina by W
.'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami nation, survey, and mapping of the geology, mineralogy, and topo graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa tional Series, Geologic Maps, and Special Publications. -
Cavansite Ca(V O)Si4o10 ² 4H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Orthorhombic
4+ Cavansite Ca(V O)Si4O10 ² 4H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Orthorhombic. Point Group: 2=m 2=m 2=m: As prismatic crystals, to 1 mm, elongated [001]; dominant forms 110 and 101 ; as spherulitic rosettes, to 5 mm. k f g f g Physical Properties: Cleavage: Good on 010 . Tenacity: Brittle. Hardness = 3{4 D(meas.) = 2.21{2.31 D(calc.) = 2.33 f g Optical Properties: Transparent. Color: Brilliant sky-blue to greenish blue. Luster: Vitreous. Optical Class: Biaxial (+). Pleochroism: Pronounced; X = Z = colorless; Y = blue. Orientation: X = b; Y = a; Z = c. Dispersion: r < v; extreme. ® = 1.542(2) ¯ = 1.544(2) ° = 1.551(2) 2V(meas.) = 52(2)± Cell Data: Space Group: P cmn: a = 9.792(2) b = 13.644(3) c = 9.629(2) Z = 4 X-ray Powder Pattern: Owyhee Dam, Oregon, USA. 7.964 (100), 6.854 (50), 6.132 (25), 3.930 (25), 3.420 (25), 2.779 (25), 4.531 (13) Chemistry: (1) (2) SiO2 49.4 53.24 VO2 17.1 18.38 CaO 11.5 12.42 H2O [21.0] 15.96 rem: 0.8 Total [99.8] 100.00 (1) Oregon; by XRF, H2O by estimation; actual H2O content established by structure analysis. (2) Ca(VO)Si4O10 ² 4H2O: Polymorphism & Series: Dimorphous with pentagonite. Occurrence: In a brown tu® partly ¯lling a fault ¯ssure (Lake Owyhee State Park, Oregon, USA); in a vesicular basalt and red tu® breccia, as cavity ¯llings and in calcite veinlets (Chapman quarry, Oregon, USA); in pores of altered basalt breccia and tu®aceous andesite (Poona district, India). -
Thermal Stability of the Stilbite-Type Framework: Crystal Structure of the Dehydrated Sodium/Ammonium Exchange Form
American Mineralogist, Volume 6E, pages 414419, 1983 Thermal stability of the stilbite-type framework: crystal structure of the dehydratedsodium/ammonium exchange form Wrlrnreo J. Monrren Katholieke Universiteit Le uven Centrum voor Oppervlaktescheikundeen Colloildale Scheikunde de Croylaan 42 8-3030Leuven (Heverlee),Belgium Abstract O-T bridges between them occurs. The cations are located at the six-ring site and the flat eight-ring site, and residual water moleculesat the boat-shapedeight-ring. The framework Oistortionsare cation-induced and readily affect the cuboid polyhedron of the framework which is formed by joining adjacent structural units' Introduction protons, but also cations such as K+ and Rb* with a sufficiently low ionic potential (Passaglia, 1980) may Stilbite-type minerals are zeolites with a two-dimen- "stabilize" the stilbite-type framework. The K and Rb sional interconnected channel system. Ten-membered forms do not undergo appreciable contraction and their ringsof (Si, Al) Oatetrahedra (free diametet4.1 x 6.24, destruction occurs only at fusion, i.e., at about 10fi)"C. Meier and Olson, 1978)Iimit the pore size of the largest As the dehydrated Ca-form exhibits a smaller fraction channels. These intersect with smaller ch-annelswith of broken T-O-T bonds (Alberti et al', 1978)than the eight-ring apertures(free diameter 2.7 x 5.7A, Meier and dehydratedNa-form (Alberti et al.,1978), the number of Olson, 1978). The inner surface should therefore be cations might be an important parameter. A further readily accessibleto small molecules and these minerals reduction of the number of cations is attempted here in could have a potential use as molecular sieves or cata- the study of a dehydrated Na-H-stilbite form. -
Mineralogical Notes on Mesolite and Scolecite from Japan
MINERALOGICAL JOURNAL, VOL . 5, No. 5, PP. 309-320, SEPT., 1968 MINERALOGICAL NOTES ON MESOLITE AND SCOLECITE FROM JAPAN KAZuo HARADA Section of Geology, Chichibu Museum of Natural History , Nagatoro 1417, Chichibu-gun, Saitama MAMORU HARA Geological and Mineralogical Institute, Faculty of Science, Tokyo University of Education, Otsuka, Tokyo and KAZUSO NAKAO Chemical Institute, Faculty of Science, Tokyo University of Education, Otsuka, Tokyo ABSTRACT Occurrence of mesolites and scolecite was confirmed in veinlets or amyg dales in andesitic or basaltic rocks in Japan. The results of chemical, physical and X-ray studies of these minerals are described, with their mineral associ ations and modes of occurrences. Introduction Mesolite and scolecite are usually classified as common fibrous zeolites, but there has been no report on the occurrence of these zeolites in Japan though the thermal and chemical data of mesolite from Tezuka, Nagano, Japan, was given by Koizumi (1953). However, our routine examinations of fibrous zeolites in the National Science Museum, Tokyo, recently confirmed that mesolite and scolecite are not so rare in Japan as hitherto believed. This paper deals with the 310 Mineralogical Notes on Mesolite and Scolecite from Japan descriptions of scolecite and mesolites from Japan. a) Mesolite from Tezuka, Nishisioda-mura, Chiisagata-gun, Naga no, Japan (coll. by Takaharu Imayoshi). This mineral occurs as fibrous aggregates, sometimes associated with heulandite, in the vein lets (2-3cm wide) in andesitic tuff breccia. The DTA, TGA and chemical analysis of this specimen were provided by Koizumi (1953). b) Mesolite from Oshima, Otsuki City, Yamanashi, Japan (coll. by the writers). This mineral occurs as fibrous aggregates closely associated with stilbite in amygdales (1-2cm) of thoroughly altered olivine basalt. -
Stilbite, Stellerite, and Laumontite at Honningsvåg, Magerø, Northern Norway
Stilbite, stellerite, and laumontite at Honningsvåg, Magerø, northern Norway. By Per Chr. Sæbø1, Paul H. Reitan2, and J. J. C. Geul3 Samples from two localities near Honningsvåg on the island of Magerø, northern Norway, were found to contain zeolites. Stilbite (desmine) and stellerite occur on joint surfaces in the steeply dipping Eocambrian schists at Juldagsneset, SE of Honningsvåg, and laumon tite was found on joint surfaces N of Honningsvåg, in the contact metamorphosed rock (hornfels) adjacent to the gabbroic rocks near Honningsvåg. A sample from Juldagsneset, which includes part of a nearly vertical joint, shows that the joint is filled by calcite and in some parts rather much of a pink zeolite, the calcite being innermost and the zeo lite occurring on both sides. In small cavities there occur small, radial aggregates of a colorless zeolite. The x-ray powder diagrams of the two zeolites are identical, but on the basis of optical data wc have identified them as stilbite and stellerite, respectively. Along with the stilbite there can occasionally be seen a little bright green epidote. Stilbite occurs as a coating on the surfaces of the vein calcite. Individual grains are difficult to delimit but are up to about 2 mm in size. Crystal forms are not well developed. a = 1 .487 ± 0.004 and aAc~3°. The color is light, yellowish pink. Stellerite occurs in small, semi-spherical, radial aggregates mostly about 0.5 mm in diameter but some are up to about 1 mm. The crystals are apparently complexly twinned. a = 1 .485 ± 0.003 and y ~ or < 1.500. -
What We Know About Subduction Zones from the Metamorphic Rock Record
What we know about subduction zones from the metamorphic rock record Sarah Penniston-Dorland University of Maryland Subduction zones are complex We can learn a lot about processes occurring within active subduction zones by analysis of metamorphic rocks exhumed from ancient subduction zones Accreonary prism • Rocks are exhumed from a wide range of different parts of subduction zones. • Exhumed rocks from fossil subduction zones tell us about materials, conditions and processes within subduction zones • They provide complementary information to observations from active subduction systems Tatsumi, 2005 The subduction interface is more complex than we usually draw Mélange (Bebout, and Penniston-Dorland, 2015) Information from exhumed metamorphic rocks 1. Thermal structure The minerals in exhumed rocks of the subducted slab provide information about the thermal structure of subduction zones. 2. Fluids Metamorphism generates fluids. Fossil subduction zones preserve records of fluid-related processes. 3. Rheology and deformation Rocks from fossil subduction zones record deformation histories and provide information about the nature of the interface and the physical properties of rocks at the interface. 4. Geochemical cycling Metamorphism of the subducting slab plays a key role in the cycling of various elements through subduction zones. Thermal structure Equilibrium Thermodynamics provides the basis for estimating P-T conditions using mineral assemblages and compositions Systems act to minimize Gibbs Free Energy (chemical potential energy) Metamorphic facies and tectonic environment SubduconSubducon zone metamorphism zone metamorphism Regional metamorphism during collision Mid-ocean ridge metamorphism Contact metamorphism around plutons Determining P-T conditions from metamorphic rocks Assumption of chemical equilibrium Classic thermobarometry Based on equilibrium reactions for minerals in rocks, uses the compositions of those minerals and their thermodynamic properties e.g. -
The Story of Cavansite
Northwest Micro Mineral Study Group MICRO PROBE FALL, 2008 VOLUME X, Number 8 FALL MEETING . .VANCOUVER, WASHINGTON November 8, 2008 9:00 am to 5:00 pm Clark County P. U. D. Building 1200 Fort Vancouver Way Vancouver, Washington Come find out what everyone has been up to this summer. Bring your microscopes and something for the free table to share with others. There will be plenty of room and ample time to check out all the new things that people have to brag about. We will have our usual brief business meeting in the afternoon, a discussion of future articles, and our update session on the status of localities. No guest speaker has been planned, but we will N be showing pictures of the new twins from Lemolo Lake, as well as of other choice pieces from the Northern California meeting in July. If you have digitals or slides of mineral specimens or collecting localities, this would be a perfect time to share them with the group. We will have projectors and a screen waiting. I5 The kitchen area is again available and we will plan on sharing lunch together. We will provide meat, cheese, bread, lettuce, tomatoes, mayo and mustard for sand-wiches as well as coffee, PUD Mill Plain Blvd. tea, cider, and cocoa. Members need to bring some sides, ie, salads, chips, desserts and anything else that they would like to have to Park Ft. Vancouver Way munch on. Washington In the evening, many of us plan to go to a local Interstate buffet restaurant, so please plan to join us if you Bridge Columbia River can. -
STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials. -
Joint Meeting
Joint Meeting 19. Jahrestagung der Deutschen Gesellschaft für Kristallographie 89. Jahrestagung der Deutschen Mineralogischen Gesellschaft Jahrestagung der Österreichischen Mineralogischen Gesellschaft (MinPet 2011) 20.-24. September 2011 Salzburg Referate Oldenbourg Verlag – München Inhaltsverzeichnis Plenarvorträge ............................................................................................................................................................ 1 Goldschmidt Lecture .................................................................................................................................................. 3 Vorträge MS 1: Crystallography at High Pressure/Temperature ................................................................................................. 4 MS 2: Functional Materials I ........................................................................................................................................ 7 MS 3: Metamorphic and Magmatic Processes I ......................................................................................................... 11 MS 4: Computational Crystallography ....................................................................................................................... 14 MS 5: Synchrotron- and Neutron Diffraction ............................................................................................................. 17 MS 6: Functional Materials II and Ionic Conductors ................................................................................................