CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION
4.1 Flash Point: 7.1 Grades of Purity: Commercial Common Synonyms Solid White Odorless Not flammable 7.2 Storage Temperature: Ambient Ammonium pentachlorozincate 4.2 Flammable Limits in Air: Not flammable Ammonium zinc chloride 7.3 Inert Atmosphere: No requirement 4.3 Fire Extinguishing Agents: Not pertinent Sinks and mixes with water. 7.4 Venting: Open 4.4 Fire Extinguishing Agents Not to Be 7.5 IMO Pollution Category: Currently not available Keep people away. Avoid contact with solid and dust. Used: Not pertinent Notify local health and pollution control agencies. 4.5 Special Hazards of Combustion 7.6 Ship Type: Currently not available Protect water intakes. Products: Not pertinent 7.7 Barge Hull Type: Currently not available 4.6 Behavior in Fire: Currently not available Not flammable. Fire 4.7 Auto Ignition Temperature: Not pertinent 8. HAZARD CLASSIFICATIONS 4.8 Electrical Hazards: Not pertinent 8.1 49 CFR Category: ORM-E 4.9 Burning Rate: Not pertinent CALL FOR MEDICAL AID. 8.2 49 CFR Class: Not pertinent Exposure 4.10 Adiabatic Flame Temperature: Currently DUST 8.3 49 CFR Package Group: Not listed. Irritating to eyes, nose and throat. not available 8.4 Marine Pollutant: No If inhaled will cause coughing or difficult breathing. 4.11 Stoichometric Air to Fuel Ratio: Not If in eyes, hold eyelids open and flush with plenty of water. pertinent. 8.5 NFPA Hazard Classification: Not listed If breathing has stopped, give artificial respiration. 4.12 Flame Temperature: Currently not 8.6 EPA Reportable Quantity: 1000 pounds If breathing is difficult, give oxygen. available 8.7 EPA Pollution Category: C 4.13 Combustion Molar Ratio (Reactant to 8.8 RCRA Waste Number: Not listed SOLID Product): Not pertinent. Irritating to skin and eyes. 8.9 EPA FWPCA List: Yes If swallowed will cause nausea and vomiting. 4.14 Minimum Oxygen Concentration for Remove contaminated clothing and shoes. Combustion (MOCC): Not listed Flush affected areas with plenty of water. 9. PHYSICAL & CHEMICAL PROPERTIES IF IN EYES, hold eyelids open and flush with plenty of water. 5. CHEMICAL REACTIVITY 9.1 Physical State at 15° C and 1 atm: Solid IF SWALLOWED and victim is CONSCIOUS, have victim drink water or milk and have victim induce vomiting. 5.1 Reactivity with Water: No reaction 9.2 Molecular Weight: 296.8 IF SWALLOWED and victim is UNCONSCIOUS OR HAVING CONVULSIONS, 5.2 Reactivity with Common Materials: 9.3 Boiling Point at 1 atm: (sublimes) 644°F = do nothing except keep victim warm. Currently not available 340°C = 613°K 5.3 Stability During Transport: Stable 9.4 Freezing Point: Not pertinent Effect of low concentrations on aquatic life is unknown. 9.5 Critical Temperature: Not pertinent Water May be dangerous if it enters water intakes. 5.4 Neutralizing Agents for Acids and Pollution Notify local health and wildlife officials. Caustics: Not pertinent 9.6 Critical Pressure: Not pertinent Notify operators of nearby water intakes. 5.5 Polymerization: Not pertinent 9.7 Specific Gravity: 1.81 at 20°C (solid) 5.6 Inhibitor of Polymerization: Not pertinent 9.8 Liquid Surface Tension: Not pertinent 9.9 Liquid Water Interfacial Tension: Not 6. WATER POLLUTION pertinent 1. CORRECTIVE RESPONSE ACTIONS 2. CHEMICAL DESIGNATIONS 9.10 Vapor (Gas) Specific Gravity: Not pertinent Dilute and disperse 6.1 Aquatic Toxicity: 2.1 CG Compatibility Group: Not listed. 9.11 Ratio of Specific Heats of Vapor (Gas): Stop discharge . Currently not available 2.2 Formula: ZnCl2 3NH4Cl 6.2 Waterfowl Toxicity: Currently not Not pertinent 2.3 IMO/UN Designation: Not listed available 2.4 DOT ID No.: 9154 9.12 Latent Heat of Vaporization: Not pertinent 2.5 CAS Registry No.: 52628-25-8 6.3 Biological Oxygen Demand (BOD): 9.13 Heat of Combustion: Not pertinent Currently not available 2.6 NAERG Guide No.: 171 9.14 Heat of Decomposition: Not pertinent 2.7 Standard Industrial Trade Classification: 6.4 Food Chain Concentration Potential: 9.15 Heat of Solution: Not pertinent 52329 Zinc accumulates in some organisms but is not considered to be bioconcentrative. 9.16 Heat of Polymerization: Not pertinent 3. HEALTH HAZARDS 6.5 GESAMP Hazard Profile: Not listed 9.17 Heat of Fusion: Currently not available 3.1 Personal Protective Equipment: Dust mask; goggles or face shield; protective gloves 9.18 Limiting Value: Currently not available 3.2 Symptoms Following Exposure: Inhalation of dust irritates nose and throat. Ingestion can cause 9.19 Reid Vapor Pressure: Currently not irritation or corrosion of the alimentary tract. Contact with eyes or skin causes irritation. available 3.3 Treatment of Exposure: INHALATION: remove from exposure; begin artificial respiration if breathing has ceased. INGESTION: induce vomiting, followed by prompt and complete gastric lavage, catharsis, and demulcents. EYES: flush with water for at least 15 min. SKIN: flush with water. NOTES 3.4 TLV-TWA: Not listed. 3.5 TLV-STEL: Not listed. 3.6 TLV-Ceiling: Not listed. 3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5-5 g/kg 3.8 Toxicity by Inhalation: Currently not available. 3.9 Chronic Toxicity: Currently not available 3.10 Vapor (Gas) Irritant Characteristics: Currently not available 3.11 Liquid or Solid Characteristics: Currently not available 3.12 Odor Threshold: Currently not available 3.13 IDLH Value: Not listed. 3.14 OSHA PEL-TWA: Not listed. 3.15 OSHA PEL-STEL: Not listed. 3.16 OSHA PEL-Ceiling: Not listed. 3.17 EPA AEGL: Not listed
JUNE 1999 ZINC AMMONIUM CHLORIDE ZAC
9.20 9.21 9.22 9.23 SATURATED LIQUID DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOSITY
Temperature Pounds per cubic foot Temperature British thermal unit per Temperature British thermal unit inch Temperature Centipoise (degrees F) (degrees F) pound-F (degrees F) per hour-square foot-F (degrees F)
N N N N O O O O T T T T
P P P P E E E E R R R R T T T T I I I I N N N N E E E E N N N N T T T T
9.24 9.25 9.26 9.27 SOLUBILITY IN WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY
Temperature Pounds per 100 pounds Temperature Pounds per square inch Temperature Pounds per cubic foot Temperature British thermal unit per (degrees F) of water (degrees F) (degrees F) (degrees F) pound-F
V N N N E O O O R T T T Y P P P S E E E O R R R L T T T U I I I B N N N L E E E E N N N T T T
JUNE 1999