DOCSLIB.ORG

Plasmonic Enhancement for Colloidal Quantum Dot Photovoltaics

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Plasmonic Enhancement for Colloidal Quantum Dot Photovoltaics Plasmonic enhancement for colloidal quantum dot photovoltaics by Daniel Paz-Soldan A thesis submitted in conformity with the requirements for the degree of Master of Applied Science Graduate Department of Electrical and Computer Engineering University of Toronto Toronto, Ontario Canada Copyright © 2013 by Daniel Paz-Soldan Plasmonic enhancement for colloidal quantum dot photovoltaics Abstract Plasmonic enhancement for colloidal quantum dot photovoltaics Daniel Paz-Soldan Master of Applied Science Graduate Department of Engineering University of Toronto 2013 Colloidal quantum dots (CQD) are used in the fabrication of efficient, low-cost solar cells synthesized in and deposited from solution. Breakthroughs in CQD materials have led to a record efficiency of 7.0 %. Looking forward, any path toward increasing efficiency must address the trade-off between short charge extraction lengths and long absorption lengths in the near-infrared spectral region. Here we exploit the localized surface plasmon resonance of metal nanoparticles to enhance absorption in CQD films. Finite-difference time-domain analysis directs our choice of plasmonic nanoparticles with minimal parasitic absorption and broadband response in the infrared. We find that gold nanoshells (NS) enhance absorption by up to 100 % at λ = 820 nm by coupling of the plasmonic near-field to the surrounding CQD film. We engineer this enhancement for PbS CQD solar cells and observe a 13 % improvement in short-circuit current and 11 % enhancement in power conversion efficiency. Daniel Paz-Soldan University of Toronto ii Plasmonic enhancement for colloidal quantum dot photovoltaics Acknowledgments This work was made possible by the collective effort of an exemplary group of individuals. First, I thank my supervisor, Professor Edward H. Sargent, for his constant guidance and support. He sets the bar high and encourages us to think big. I am grateful for having had the opportunity to work in a world-class research group in such an exciting field. I am grateful to Dr. Susanna Thon for her leadership and guidance through thick and thin. I owe many thanks to Dr. Anna Lee, mentor and friend, who taught me the virtues of the scientific process and whose contributions were invaluable. I also thank Dr. Michael Adachi for his objective insight and practical know-how with FDTD simulations. I extend thanks to Dr. Mingjian Yuan, Dr. Pouya Maraghechi, Andre´ Labelle, and Haopeng Dong for their helpful advice and important work on the project. I particularly thank David Zhitomirsky, Dr. Illan Kramer, and Dr. Rui Li for guiding my research focus from the very beginning. I am grateful to Dr. Larissa Levina and Elenita Palmiano for CQD synthesis and tireless preparation of materials for the lab on a daily basis. I also thank Damir Kopilovic and Remigiusz Wolowiec for designing and building anything, on-demand, and in a timely fashion. I feel privileged to have collaborated with a diverse and talented group of individuals outside of the Sargent group while at the Uni- versity of Toronto and I am thankful for their valuable contributions: Dr. Aftab Ahmed, Dr. Kun Liu, Dr. Alexander Melnikov, Dr. Peter M. Brodersen, Anjan Reijnders, and Luke Sandilands. I also thank Dr. Neil Coombs and Dr. Ilya Gourevich for training and assistance with electron microscopy. I thank Dr. Sjoerd Hoogland, Dr. Armin Fischer, and Dr. Oleksandr Voznyy for in- sightful discussions. For scientific and non-scientific discussions alike, I thank: Dr. Yuan Daniel Paz-Soldan University of Toronto iii Plasmonic enhancement for colloidal quantum dot photovoltaics Ren, Dr. Jennifer Flexman, Dr. Shokouh Farvid, Dr. Jin Young Kim, Dr. Ghada Koleilat, Dr. Zhijun Ning, Dr. Silvia Masala, Dr. Philipp Stadler, Alex Ip, Kyle Kemp, Graham Carey, Melissa Furukawa, Lisa Rollny, Xinzheng Lan, Brandon Sutherland, Jixian Xu, Chris Wong, Valerio Adinolfi, and Jeannie Ing. I thank my parents, Carlos and Patricia, and my brothers, Carlos Jr. and Mario. I am privileged to have been born into a family that stands behind me in everything I do. Finally I thank Jessica Nguyen, whose constant encouragement and support through everything made this work possible. Daniel Paz-Soldan University of Toronto iv CONTENTS Plasmonic enhancement for colloidal quantum dot photovoltaics Contents Abstract ii Acknowledgments iii Acronyms vii List of Tables viii List of Figures ix 1 Introduction 1 1.1 Colloidal quantum dots . 3 1.1.1 Recent advances in colloidal quantum dot solar cells . 4 1.1.2 Limitations . 5 1.2 Thesis objectives . 7 2 Background 9 2.1 Solar cell fundamentals . 9 2.1.1 Figures of merit . 10 2.1.2 Quantum efficiency . 12 2.2 Surface plasmons . 12 2.2.1 Localized surface plasmons . 14 2.2.2 Effect of ligand . 14 2.3 State of the art . 15 3 Infrared plasmonic nanoparticles 17 3.1 Optical design considerations . 17 3.2 Finite-difference time-domain simulations . 19 3.3 Engineering of optical resonances . 20 3.3.1 Hemisphere-capped nanorods . 20 3.3.2 Arrowhead nanorods . 21 3.3.3 Nanoshells . 23 3.4 Plasmonic particle spacing in CQD films . 25 3.5 Conclusions . 27 4 Integrating MNPs into CQD solar cells 28 4.1 PbS CQD and NS film deposition . 28 4.2 Physical and electrical considerations . 29 4.2.1 Surface modification and purification . 30 4.2.2 Agglomeration . 31 Daniel Paz-Soldan University of Toronto v CONTENTS Plasmonic enhancement for colloidal quantum dot photovoltaics 4.3 Nanoshell film deposition . 31 4.3.1 Solvent controls . 32 4.3.2 MNP film fabrication by spin casting . 32 4.3.3 MNP film fabrication by reservoir drop casting . 33 4.4 Conclusions . 33 5 Characterization of devices 34 5.1 Design of plasmonic CQD solar cells . 34 5.2 Performance of CQD solar cells with NR and ARNR . 35 5.3 Optical properties of plasmonic CQD films . 35 5.4 Device performance . 37 5.5 Quantum efficiency . 38 5.6 Conclusions . 39 6 Conclusion 40 6.1 Contributions to the field . 40 6.2 Future work . 41 References 43 A Materials and experimental procedures 48 A.1 PbS CQD synthesis and solvent exchange . 48 A.2 Photovoltaic device fabrication . 48 A.3 Nanorod synthesis . 49 A.4 Arrowhead nanorod synthesis . 50 A.5 Nanoshell solution preparation . 51 B Measurements and simulations 53 B.1 AM 1.5 photovoltaic performance characterization . 53 B.2 EQE measurements . 53 B.3 Solution absorption . 54 B.4 Film absorption . 54 B.5 Double pass film absorption . 54 B.6 FDTD simulations . 54 Daniel Paz-Soldan University of Toronto vi CONTENTS Plasmonic enhancement for colloidal quantum dot photovoltaics Acronyms AM 1.5 Air Mass 1.5 G solar spectrum MNP Metal Nanoparticle ARNR Arrowhead Nanorod MPA 1-mercaptopropanoic Acid CQD Colloidal quantum dot MW Molecular weight EM Electromagnetic MPP Maximum power point EQE External Quantum Efficiency NR Nanorod NS Nanoshell FF Fill Factor OPV Organic Photovoltaics FTO Fluorine doped Tin Oxide PbS Lead sulfide ITO Indium doped Tin Oxide PCE Power Conversion Efficiency IQE Internal Quantum Efficiency PV Photovoltaics J − V Current-Voltage Characteristic PVP Polyvinylpyrrolidone JSC Short-Circuit Current RS Series Resistance LSPR Localized Surface Plasmon Reso- nance RSH Shunt Resistance MeOH Methanol VOC Open-Circuit Voltage Daniel Paz-Soldan University of Toronto vii LIST OF TABLES Plasmonic enhancement for colloidal quantum dot photovoltaics List of Tables 1 Solar cell performance results with embedded NS with and without pre- sonication . 31 2 Solar cell performance results with embedded NS for spin casting and drop casting . 32 3 Solar cell performance of devices with embedded NRs . 35 4 Solar cell performance of devices with embedded ARNRs . 36 5 Device results using nanoshells . 37 Daniel Paz-Soldan University of Toronto viii LIST OF FIGURES Plasmonic enhancement for colloidal quantum dot photovoltaics List of Figures 1.1 Electricity generation by source in the United States, 2009 . 1 1.2 Spectral tuning of quantum dots across the broad solar spectrum . 4 1.3 The depleted heterojunction architecture for CQD PV . 5 1.4 Measured absorption coefficient spectrum of a PbS CQD film . 6 2.1 Basic operation of a solar cell . 9 2.2 Equivalent circuit of a solar cell . 11 2.3 Dispersion curves (!) for gold and silver . 13 2.4 Simple illustration of a surface plasmon on a metal nanoparticle . 14 2.5 The effect of a ligand shell on the surface plasmon of a silver nanoparticle . 15 3.1 Extinction and schematic of hemisphere-capped gold nanorods . 20 3.2 FDTD simulation of hemisphere-capped gold nanorods . 22 3.3 Extinction and schematic of arrowhead-capped gold nanorods . 23 3.4 FDTD simulation of arrowhead-capped gold nanorods . 24 3.5 Summary of peak scattering and absorption cross sections for NR and ARNR 25 3.6 Experimental and calculated extinction of gold nanoshells . 26 4.1 TEM images of nanoshells before and after purification . 30 5.1 Schematic representation and cross sectional TEM image of plasmonic nanoshell CQD solar cell . 34 5.2 (a) Single pass absorption spectrum of PbS CQD films with and without embedded NS . 36 5.3 External quantum efficiency spectra and J-V characterization of represen- tative samples with and without NS embedded . 38 5.4 Internal quantum efficiency spectra of representative samples with and with- out NS embedded . 39 A-1 TEM image of typical NR . 50 A-2 TEM image of typical ARNR . 51 A-1 Double pass absorption spectrum of PbS CQD films with and without em- bedded NS . 55 Daniel Paz-Soldan University of Toronto ix 1 Introduction Plasmonic enhancement for colloidal quantum dot photovoltaics 1 Introduction Electricity, however produced, is now considered a basic right in the developed world. We demand it and we fight to keep costs low despite the grave implications for the environment.
Load more

Recommended publications
  • Graphene Plasmonics: Physics and Potential Applications
    Graphene plasmonics: Physics and potential applications Shenyang Huang1,2, Chaoyu Song1,2, Guowei Zhang1,2, and Hugen Yan1,2* 1Department of Physics, State Key Laboratory of Surface Physics and Key Laboratory of Micro and Nano Photonic Structures (Ministry of Education), Fudan University, Shanghai 200433, China 2Collaborative Innovation Center of Advanced Microstructures, Nanjing 210093, China *Email: [email protected] Abstract Plasmon in graphene possesses many unique properties. It originates from the collective motion of massless Dirac fermions and the carrier density dependence is distinctively different from conventional plasmons. In addition, graphene plasmon is highly tunable and shows strong energy confinement capability. Most intriguing, as an atom-thin layer, graphene and its plasmon are very sensitive to the immediate environment. Graphene plasmons strongly couple to polar phonons of the substrate, molecular vibrations of the adsorbates, and lattice vibrations of other atomically thin layers. In this review paper, we'll present the most important advances in grapene plasmonics field. The topics include terahertz plasmons, mid-infrared plasmons, plasmon-phonon interactions and potential applications. Graphene plasmonics opens an avenue for reconfigurable metamaterials and metasurfaces. It's an exciting and promising new subject in the nanophotonics and plasmonics research field. 1 Introduction Graphene is a fascinating electronic and optical material and the study for graphene started with its magneto-transport measurements and an anomalous Berry phase[1, 2]. Optical properties of graphene attracted more and more attention later on. Many exciting developments have been achieved, such as universal optical conductivity[3], tunable optical absorption[4, 5] and strong terahertz response[6]. Most importantly, as an interdisciplinary topic, plasmon in graphene has been the major focus of graphene photonics in recent years.
    [Show full text]
  • 7 Plasmonics
    7 Plasmonics Highlights of this chapter: In this chapter we introduce the concept of surface plasmon polaritons (SPP). We discuss various types of SPP and explain excitation methods. Finally, di®erent recent research topics and applications related to SPP are introduced. 7.1 Introduction Long before scientists have started to investigate the optical properties of metal nanostructures, they have been used by artists to generate brilliant colors in glass artefacts and artwork, where the inclusion of gold nanoparticles of di®erent size into the glass creates a multitude of colors. Famous examples are the Lycurgus cup (Roman empire, 4th century AD), which has a green color when observing in reflecting light, while it shines in red in transmitting light conditions, and church window glasses. Figure 172: Left: Lycurgus cup, right: color windows made by Marc Chagall, St. Stephans Church in Mainz Today, the electromagnetic properties of metal{dielectric interfaces undergo a steadily increasing interest in science, dating back in the works of Gustav Mie (1908) and Rufus Ritchie (1957) on small metal particles and flat surfaces. This is further moti- vated by the development of improved nano-fabrication techniques, such as electron beam lithographie or ion beam milling, and by modern characterization techniques, such as near ¯eld microscopy. Todays applications of surface plasmonics include the utilization of metal nanostructures used as nano-antennas for optical probes in biology and chemistry, the implementation of sub-wavelength waveguides, or the development of e±cient solar cells. 208 7.2 Electro-magnetics in metals and on metal surfaces 7.2.1 Basics The interaction of metals with electro-magnetic ¯elds can be completely described within the frame of classical Maxwell equations: r ¢ D = ½ (316) r ¢ B = 0 (317) r £ E = ¡@B=@t (318) r £ H = J + @D=@t; (319) which connects the macroscopic ¯elds (dielectric displacement D, electric ¯eld E, magnetic ¯eld H and magnetic induction B) with an external charge density ½ and current density J.
    [Show full text]
  • Towards Deep Integration of Electronics and Photonics
    applied sciences Review Towards Deep Integration of Electronics and Photonics Ivan A. Pshenichnyuk 1,* , Sergey S. Kosolobov 1 and Vladimir P. Drachev 1,2,* 1 Skolkovo Institute of Science and Technology, Center for Photonics and Quantum Materials, Nobelya 3, 121205 Moscow, Russia; [email protected] 2 Department of Physics, University of North Texas,1155 Union Circle, Denton, TX 76203, USA * Correspondence: [email protected] (I.A.P.); [email protected] (V.P.D.) Received: 15 September 2019; Accepted: 5 November 2019; Published: 12 November 2019 Abstract: A combination of computational power provided by modern MOSFET-based devices with light assisted wideband communication at the nanoscale can bring electronic technologies to the next level. Obvious obstacles include a size mismatch between electronic and photonic components as well as a weak light–matter interaction typical for existing devices. Polariton modes can be used to overcome these difficulties at the fundamental level. Here, we review applications of such modes, related to the design and fabrication of electro–optical circuits. The emphasis is made on surface plasmon-polaritons which have already demonstrated their value in many fields of technology. Other possible quasiparticles as well as their hybridization with plasmons are discussed. A quasiparticle-based paradigm in electronics, developed at the microscopic level, can be used in future molecular electronics and quantum computing. Keywords: plasmon; light-matter interaction; photonics; nano-electronics; quasiparticle 1. Introduction Further achievements in electronics and photonics imply their better integration. Usage of photons at the level of circuits and single chips has a huge potential to improve modern intelligent systems [1].
    [Show full text]
  • Plasmonics in Nanomedicine: a Review
    Global Journal of Nanomedicine ISSN: 2573-2374 Mini Review Glob J Nanomed Volume 4 Issue 5 - December 2018 Copyright © All rights are reserved by SS Verma DOI: 10.19080/GJN.2018.04.555646 Plasmonics in Nanomedicine: A Review SS Verma* Department of Physics, SLIET, India Submission: October 29, 2018; Published: December 06, 2018 *Corresponding author: SS Verma, Department of Physics, SLIET, Longowal, Sangrur, Punjab, India Abstract the presentPlasmonics article, involves the latest the confinementdevelopments and in manipulationthe area of plasmonics of light at in the nanomedicine nanoscale using are surfacebeing presented. plasmons and is making a tremendous impact in the field of life sciences, with applications in bioimaging, biosensing, and targeted delivery and externally-triggered locoregional therapy. In Keywords: Optics; Photonics; Plasmonics; Nanoparticles; Nanomedicine; Surface plasmons Abbreviations: Dynamic Therapy; PTT: Thermal PhotoTherapy; SERS: Surface-Enhanced Raman Scattering; LSPRs: Localized Surface Plasmon Resonances; MRI: Magnetic ResonanceIR: Infrared; Imaging UV: Ultraviolet; RF: Radiofrequency; DDA: Discrete Dipole Approximation; NIR: Near-Infrared Region; PDT: Photo Plasmonics and its Applications The optical excitation of surface plasmons in metal nanopar- of plasmonics properties of these nanoparticles depending on metals like gold and silver can offer. Recent research on the use their size, wavelength and surrounding medium has revealed the ticles leads to nanoscale spatial confinement of electromagnetic with surface electrons can generate intense, localized thermal en- fields. The controlled electromagnetic fields while interacting possibility towards many beneficial and potential applications like biomedical, cancer treatment and plasmonic solar cells. ergy and large near-field optical forces and this interaction have Biomedical Plasmonics led toPlasmonics the emerging is tremendously field known as growing plasmonics.
    [Show full text]
  • Extraordinary Optical Transmission Enhanced by Antireflection
    Optical Curtain Effect: Extraordinary Optical Transmission Enhanced by Antireflection Yanxia Cui1,2,*, Jun Xu3, Yinyue Lin1, Guohui Li1,Yuying Hao1, Sailing He2, and Nicholas X. Fang3 1Department of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, China 2Centre for Optical and Electromagnetic Research, State Key Laboratory of Modern Optical Instrumentation; JORCEP (KTH-ZJU Joint Center of Photonics), Zhejiang University, Hangzhou 310058, China 3Department of Mechanical, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA Corresponding author: [email protected] Abstract In this paper, we employ an antireflective coating which comprises of inverted π shaped metallic grooves to manipulate the behaviour of a TM-polarized plane wave transmitted through a periodic nanoslit array. At normal incidence, such scheme can not only retain the optical curtain effect in the output region, but also generate the extraordinary transmission of light through the nanoslits with the total transmission efficiency as high as 90%. Besides, we show that the spatially invariant field distribution in the output region as well as the field distribution of resonant modes around the inverted π shaped grooves can be reproduced immaculately when the system is excited by an array of point sources beneath the inverted π shaped grooves. In further, we investigate the influence of center-groove and side-corners of the inverted π shaped grooves on suppressing the reflection of light, respectively. Based on our work, it shows promising potential in applications of enhancing the extraction efficiency as well as controlling the beaming pattern of light emitting diodes. ACS numbers: 42.25.Bs, 42.25.Fx, 42.79.Ag, 73.20.Mf 1 Since the discovery of extraordinary optical transmission (EOT) in 1998 [1], metallic nano-structures have attracted significant attention because of their novel ability to excite propagating surface plasmon polariton (SPP) or localized surface plasmon modes (LSP) [2-4].
    [Show full text]
  • ACTIVE PLASMONICS and METAMATERIALS by MOHAMED
    ACTIVE PLASMONICS AND METAMATERIALS By MOHAMED ELKABBASH Submitted in partial fulfillment of the requirements of the degree of Doctor of Philosophy Department of Physics CASE WESTERN RESERVE UNIVERSITY January, 2018 CASE WESTERN RESERVE UNIVERSITY SCHOOL OF GRADUATE STUDIES We hereby approve the thesis/dissertation of Mohamed ElKabbash Candidate for the degree of Doctor of Philosophy*. Committee Chair Giuseppe Strangi Committee Member Michael Hinczewski Committee Member Jesse Berezovsky Committee Member Mohan Sankaran Date of Defense 11/07/2017 *We also certify that written approval has been obtained for any proprietary material contained therein ii To everyone who nurtured me with love and knowledge. To my late Grandmother, Galilah, and my mom Enas. iii Acknowledgments This work was only possible through the support of many people. I would like to thank my supervisor, prof.Strangi, for mentoring, supporting and believing in me throughout my PhD program. I would also like to thank my committee members, Prof. Hinczewski, Prof. Berezovsky, and Prof. Sankaran. In particular, I would like to thank Prof. Hinczewski whom I just wrote his name without copying from the email address book for the first time and who provided me with mentorship and support beyond what I would expect or ask for. I would also like to thank my collaborators. First, I would like to thank professor Nader Engheta for his support and being a wonderful scientist and person. I would also like to thank professor Humeyra Caglayan for her support. Secondly, I would like to thank my colleagues and lab mates, Alireza, Sreekanth and Melissa who were postdocs when I joined the lab and whom I enjoyed their company in the beginning of my PhD.
    [Show full text]
  • Integrated Spoof Plasmonic Circuits ⇑ Jingjing Zhang, Hao-Chi Zhang, Xin-Xin Gao, Le-Peng Zhang, Ling-Yun Niu, Pei-Hang He, Tie-Jun Cui
    Science Bulletin 64 (2019) 843–855 Contents lists available at ScienceDirect Science Bulletin journal homepage: www.elsevier.com/locate/scib Review Integrated spoof plasmonic circuits ⇑ Jingjing Zhang, Hao-Chi Zhang, Xin-Xin Gao, Le-Peng Zhang, Ling-Yun Niu, Pei-Hang He, Tie-Jun Cui State Key Laboratory of Millimeter Waves, Southeast University, Nanjing 210096, China article info abstract Article history: Using a metamaterial consisting of metals with subwavelength surface patterning, one can mimic surface Received 30 November 2018 plasmon polaritons (SPPs) and achieve surface waves with subwavelength confinement at microwave Received in revised form 21 January 2019 and terahertz frequencies, thus bringing most of the advantages associated with the optical SPPs to lower Accepted 23 January 2019 frequencies. Due to the properties of strong field confinement and high local field intensity, spoof SPPs Available online 2 February 2019 have demonstrated the improved performance for data transmission and device miniaturization in an intensively integrated environment. The distinctive abilities, such as suppression of transmission loss Keywords: and bending loss, and increase of signal integrity, make spoof SPPs a promising candidate for future gen- Spoof surface plasmons eration of electronic circuits and electromagnetic systems. This article reviews the progress in spoof SPPs Metamaterial Electromagnetic system with a special focus on their applications in circuits from transmission lines to passive and active devices Integrated circuits in microwave and terahertz regimes. The integration of versatile spoof SPP devices on a single platform, which is compatible with established electronic circuits, is also discussed. Ó 2019 Science China Press. Published by Elsevier B.V. and Science China Press.
    [Show full text]
  • Plasmonic Luneburg and Eaton Lenses
    Plasmonic Luneburg and Eaton Lenses Thomas Zentgraf 1*, Yongmin Liu 1*, Maiken H. Mikkelsen 1*, Jason Valentine 1,3, Xiang Zhang 1,2,† 1NSF Nanoscale Science and Engineering Center (NSEC), 3112 Etcheverry Hall, University of California, Berkeley, CA 94720, USA 2Materials Science Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA 3Department of Mechanical Engineering, Vanderbilt University, Nashville, TN 37235, USA *These authors contributed equally to this work. †To whom correspondence should be addressed. E-mail: [email protected] Plasmonics is an interdisciplinary field focusing on the unique properties of both localized and propagating surface plasmon polaritons (SPPs) - quasiparticles in which photons are coupled to the quasi-free electrons of metals. In particular, it allows for confining light in dimensions smaller than the wavelength of photons in free space, and makes it possible to match the different length scales associated with photonics and electronics in a single nanoscale device [1]. Broad applications of plasmonics have been realized including biological sensing [2], sub-diffraction- limit imaging, focusing and lithography [3-5], and nano optical circuitry [6-10]. Plasmonics-based optical elements such as waveguides, lenses, beam splitters and reflectors have been implemented by structuring metal surfaces [7, 8, 11, 12] or placing dielectric structures on metals [6, 13-15], aiming to manipulate the two-dimensional surface plasmon waves. However, the abrupt discontinuities in the material properties or geometries of these elements lead to increased scattering of SPPs, which significantly reduces the efficiency of these components. Transformation 1 optics provides an unprecedented approach to route light at will by spatially varying the optical properties of a material [16,17].
    [Show full text]
  • Mathematical Analysis of Plasmonics Resonances for Nanoparticles and Applications Matias Ruiz
    Mathematical analysis of plasmonics resonances for nanoparticles and applications Matias Ruiz To cite this version: Matias Ruiz. Mathematical analysis of plasmonics resonances for nanoparticles and applications. Plasmas. Université Paris sciences et lettres, 2017. English. NNT : 2017PSLEE054. tel-01827839 HAL Id: tel-01827839 https://tel.archives-ouvertes.fr/tel-01827839 Submitted on 2 Jul 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. THÈSE DE DOCTORAT de l’Université de recherche Paris Sciences Lettres – PSL Research University préparée à l’École Normale Supérieure Analyse Mathématique de École doctorale n°386 Résonances Plasmoniques Spécialité: Mathématiques pour des Nanoparticules Appliquées et Applications Soutenue le 27.06.2017 Mathematical Analysis of Plasmonic Resonances for Nanoparticles and Applications Composition du Jury : par Matias Ruiz M. Habib Ammari ETH Zurich Directeur de thèse M. Oscar Bruno California Institute of Technology Rapporteur M. Gilles Lebeau Université de Nice - Sophia Antipolis Rapporteur Mme. Liliana Borcea University of Michigan Examinatrice M. Josselin Garnier École Polytechnique Examinateur M. Bertrand Maury Université Paris Sud Examinateur M. Gabriel Peyré École Normale Supérieure Président du jury iii Acknowledgements I would like to start by thanking the most important person in the achieve- ment of this Ph.D.
    [Show full text]
  • Optical Response of Plasmonic Nanohole Arrays: Comparison of Square and Hexagonal Lattices
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by DSpace@MIT Plasmonics (2016) 11:851–856 DOI 10.1007/s11468-015-0118-9 Optical Response of Plasmonic Nanohole Arrays: Comparison of Square and Hexagonal Lattices Yasa Ekşioğlu1,2 & Arif E. Cetin3 & JiříPetráček1,4 Received: 1 May 2015 /Accepted: 7 October 2015 /Published online: 19 October 2015 # Springer Science+Business Media New York 2015 Abstract Nanohole arrays in metal films allow extraordinary Keywords Plasmonics . Extraordinary optical transmission . optical transmission (EOT); the phenomenon is highly advan- Nanoholes . Refractive index sensitivity . Grating coupling tageous for biosensing applications. In this article, we theoret- ically investigate the performance of refractive index sensors, utilizing square and hexagonal arrays of nanoholes, that can Introduction monitor the spectral position of EOT signals. We present near- and far-field characteristics of the aperture arrays and investi- The ability of light confinement below the diffraction limit gate the influence of geometrical device parameters in detail. with large near-field intensity enhancements through excita- We numerically compare the refractive index sensitivities of tion of surface plasmons [1–3] has enabled various applica- the two lattice geometries and show that the hexagonal array tions in biodetection field, i.e., surface-enhanced vibrational supports larger figure-of-merit values due to its sharper EOT spectroscopy [4–10] and label-free biosensing [11–15]. Sur- response. Furthermore, the presence of a thin dielectric film face plasmons, propagating at metal surfaces, can be utilized, that covers the gold surface and mimics a biomolecular layer e.g., in ultra-compact electro-optic modulators [16].
    [Show full text]
  • Future Electronics: Photonics and Plasmonics at the Nanoscale
    Future electronics: Photonics and plasmonics at the nanoscale Robert Magnusson Texas Instruments Distinguished University Chair in Nanoelectronics Professor of Electrical Engineering Department of Electrical Engineering University of Texas-Arlington Arlington, Texas 76019 [email protected] http://leakymoderesonance.com/ Applied Power Electronics Conference Fort Worth, Texas March 16 – 20, 2014 1 Scope Plasmonics: Surface plasmons are coherent electron oscillations at the interface between two materials where the real part of the dielectric function changes sign across the interface. Nanoplasmonics: Plasmonics in nanoscale systems. Photonics: Technology concerned with the properties and transmission of photons, for example in fiber optics, waveguides, and lasers. Nanophotonics the study of the behavior of light on a nanometer scale. Engineering the interaction of light with particles or substances at deeply subwavelength scales. Silicon photonics: CMOS! Focus: Nanophotonic and nanoplasmonic periodic devices. 2 Nanoplasmonics Surface plasmons on dielectric-metal boundaries 3 Metal coupler example Jesse Lu, Csaba Petre, Eli Yablonovitch, and Josh Conway, “Numerical optimization of a grating coupler for the efficient excitation of surface plasmons at an Ag–SiO2 interface,” J. Opt. Soc. Am. B/Vol. 24, No. 9/September 2007 4 Undergrad plasmonics: SPR sensor experiment 5 SP-highlights Surface plasmon: EM field charge-density oscillation at the interface between a conductor and a dielectric SP: AC current at optical frequency Metallic
    [Show full text]
  • Opportunities and Challenges of Using Plasmonic Components in Nanophotonic Architectures Hassan M
    1 Opportunities and Challenges of using Plasmonic Components in Nanophotonic Architectures Hassan M. G. Wassel, Student Member, IEEE, Daoxin Dai, Member, IEEE, Mohit Tiwari, Jonathan K. Valamehr, Student Member, IEEE, Luke Theogarajan, Member, IEEE, Jennifer Dionne, Frederic T. Chong, Member, IEEE, Timothy Sherwood, Member, IEEE Abstract—Nanophotonic architectures have recently been pro- offer high frequency operation, limited attenuation over long posed as a path to providing low latency, high bandwidth distances, the ability to perform wavelength division multi- network-on-chips. These proposals have primarily been based plexing, and low power modulation and detection. Recent ad- on micro-ring resonator modulators which, while capable of operating at tremendous speed, are known to have both a vances in nanophotonics have been able to bring the structures high manufacturing induced variability and a high degree of required for non-trivial topologies down to a scale that they temperature dependence. The most common solution to these two could feasibly be coupled with a microprocessor die. problems is to introduce small heaters to control the temperature Most of these architectural proposals have been based on of the ring directly, which can significantly reduce overall power efficiency. In this paper, we introduce plasmonics as a the micro-ring resonator-based modulators and filters which complementary technology. While plasmonic devices have several have many attractive properties such as compactness, energy- important advantages, they come with their own new set of efficiency, and the ability to tune the wavelength of resonance. restrictions, including propagation loss and lack of Wave Division However, the resonant wavelength of these rings is highly Multiplexing (WDM) support.
    [Show full text]