Application for Grant of Terms of Reference

APPLICATION FOR GRANT OF TERMS OF REFERENCE FOR Expansion of Chemical and Agro Chemical Intermediates Manufacturing Unit Activity : 5(b) & 5(f) ; Category A Existing production capacity 5825 TPA, Total After Expansion 33,267 TPA Existing Project Cost: Rs. 11 Crores; Proposed Cost of Expansion: 36 Crores; Total cost after Expansion Rs. 47 Crores

Site Address Plot no. 21/2, Dhatav MIDC, Taluka Roha, District- Raigad, State - Maharashtra

Project Proponent M/S ANSHUL INNOVATIVE CHEMISTRY PRIVATE LIMITED Registered Address-Plot no. 21/2, Roha MIDC, Taluka Roha, District- Raigad, State - Maharashtra

Contact Person- Shirish Ramchandra Satpute Designation- Sr. Vice President Phone: 9819490645 Email- [email protected]

Environmental Consultant Perfact Envirosolutions Pvt Ltd (PESPL) (NABET Registered List of Accredited Consultant Organisations NABET/EIA/1922/RA 0184) Registered Address:- 5th Floor, Sector 3, Rohini, New Delhi- 110085 Email- [email protected] Website- www.perfactgroup.com Phone- +91-11-49281360

UID No: PE2021/018/B-02

TABLE OF CONTENT

S. No. Particulars Page No.

1 Section A: Form I A-1 to A-19

2 Section B: Brief Summary B-1 to B-8

3 Section C: PFR Report C-1 to C-94

4 Section D: Annexures

Annexure 1 : Layout Plan D-2

Annexure 2 : Topographical Map D-4

Annexure 3 : Hazardous Waste D-6 Membership

Annexure 4 : Board Resolution D-8

Annexure 5: Authorization Of Consultant D-10

Annexure 6: Consent To Establish D-12

Annexure 7: Deed Of Assignment D-23

Annexure 8 : Earlier Environment D-27 Clearance

Annexure 9 : Screenshot Of Approval Of D-34 Transfer Of Environment Clearance Section-A: Form-I Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

FORM-1

(I) Basic Information

S. No. Item Details 1. Name of the project/s Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant 2. S.No. in the schedule 5 (b) & 5(f) ; Cat A

3. Proposed capacity/area/length/ tonnage to Plant Capacity After Expansion :33267 TPA be handled/command area/lease area/ number of wells to be drilled 4. New/Expansion/Modernization Expansion 5. Existing capacity/area etc., Existing Capacity : Technical product 5,825 TPA 6. Category of Project i.e ‘A’ or ‘B’ A 7. Does it attract the general condition? If yes, No please specify 8. Does it attract the specifc condition? If yes, No please specify 9. Location Plot no. 21/2, Dhatav, MIDC Roha, Taluka-Roha, Dist- Raigad Maharashtra Plot/Survey/Khasra No. Plot no. 21/2 Village Dhatav Tehsil Roha District Raigad State Maharashtra 10. Nearest railway station/airport along with Nearest Railway Station: Roha Railway distance in kms Station-3.50 km NW Nearest Highway: NH 66- 5.82 km ENE Nearest Airport: Chhatrapati Shivaji Maharaj International Airport-79.41 km NNW 11. Nearest Town, city, District Headquarters Dhatav - 0.44 km SE along with distance in Kms 12 Village Panchayats, Zilla Parishad, Municipal Village Dhatav, Taluka Roha, Dist. Raigad Corporation, Local body (complete postal Maharashtra. addresses with telephone nos. to be given) 13 Name of the applicant M/s Anshul Innovative Chemistry Private Limited 14 Registered Address Plot no. 21/2, Dhatav, MIDC Roha, Taluka-Roha, Dist- Raigad Maharashtra 15 Address for correspondence: Name Mr. Shirish Ramchandra Satpute Designation (Owner/Partner/CEO) Sr. Vice President

A-1 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Address Plot no. 21/2, Dhatav MIDC , Roha, Raigad. Pin Code 402116 E-Mail [email protected] Mobile No 9819490645 Telephone No. 02194 263581 Fax No. - 16 Details of Alternative Sites examined, if any Proposal is for expansion of production Location of these sites should be shown on capacity utilising the common infrastructure a topo sheet. available with the existing chemical & agro chemicals intermediated manufacturing unit. Hence, no alternate sites were examined. 17 Interlinked Projects No 18 Whether separate applications of interlinked No projects have been submitted? 19 If yes, date of submission Not Applicable 20. If no, reason Not Applicable 21 Whether the proposal involves No approval/clearance under: If yes, details of the same and their status to be given. (a) The Forest (Conservation) Act, 1980? NA (b) The Wildlife (Protection) Act, 1972? NA (c) The C.R.Z Notifcation, 1991? NA 22 Is there any Government Order/Policy Nil relevant/relating to the site? 23 Forest land involved (hectares) Nil 24 Whether there is any litigation pending No against the project and/or land in which the project is proposed to be set up? (a) Name of the Court NA (b) Case No. NA (c) Orders/directions of the Court, if any NA and its relevance with the proposed project.

(II) Activity 1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.)

S.No. Information/Checklist confrmation Yes/No Details thereof (with approximate quantities /rates, wherever possible) with source of information data

A-2 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1.1 Permanent or temporary change in No As per Land Use Plan, the site falls under Industrial land use, land cover or topography land use. The project is an existing industry within including increase in intensity of land MIDC Industrial Estate and hence conforms to the use (with respect to local land use land use. plan) 1.2 Clearance of existing land, No The project was granted Environmental Clearance vegetation and buildings? in the name of M/s Ambernath Organic Pvt. Ltd. on 1st September 2017, however the industry is not operational. Later on, name change was done to M/s Anshul Innovative Chemistry Private Limited and the proposed project is expansion of existing Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant. A structured, well designed landscaping is existing and a combination of native and appropriate species of trees will be developed within the site. 1.3 Creation of new land uses? No The project is within the notifed Industrial area of MIDC, Roha. 1.4 Pre-construction investigations e.g. Yes Pre-construction soil investigation has been done. bore houses, soil testing? 1.5 Construction works? Yes Existing unit has its Industrial sheds already constructed. Further construction work for the expansion activities will be done as per the layout plan given in Section D Enclosures. 1.6 Demolition works? No No Demolition work is required. 1.7 Temporary sites used for No No major construction activities envisaged during construction works or housing of expansion, only additional plants and machineries construction workers? need to be erected; labourers will be sourced from the neighboring area for erection of equipment and machineries during expansion. 1.8 Above ground buildings, structures Yes It will be done as per the Layout plan attached in or earthworks including linear Section D. The industrial building will have structures, cut and fll or excavations structural sheds and will have only minimum excavations. Since the plot is already developed and levelled by MIDC, there is no requirement for flling / levelling. 1.9 Underground works including No Not Applicable mining or tunneling? 1.10 Reclamation works? No Not applicable 1.11 Dredging? No Not applicable 1.12 Offshore structures? No Not applicable 1.13 Production and manufacturing Yes Industry will manufacture Chemical and Agro processes? Chemical Intermediates. Details are given in the Section-C-PFR Report.

A-3 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1.14 Facilities for storage of goods or Yes Raw materials required for individual products are materials? identifed, quantifed and individual storage has been alloted within the project site itself. Appropriate storage methods and handling processes identifed- Liquid, Solid and Gaseous states. Storage and handling yards will be marked, labelled, barricaded/isolated as required, exhaust system and control measures and Safety equipment will be installed. Storage of all chemicals shall not exceed their threshold limit, wherever threshold is exceeded Clearance shall be obtained as per MSIHC Rules, 1989. Details are given in Section -C. All solid raw materials will be moved to the manufacturing area only in closed containers. All liquid raw materials will be stored in leak proof MS/SS/PP/FRP tanks at a secured and contained location with proper safety measures. All gases will be stored in certifed gas cylinders and moved to the production area through trolleys. 1.15 Facilities for treatment or disposal of Yes Biodegradable- the total 66 kg/day biodegradable. solid waste or liquid effuents? waste will be treated in the proposed OWC. Non Biodegradable waste @99 kg/day will continue to be disposed of through authorised recyclers. Hazardous solid wastes as given below will be sent to TSDF with due authorisation from SPCB: i.MEE Salt - 6059 TPA ii. ETP sludge - 145 TPA Used oil shall be collected, stored and disposed through registered recyclers. Industrial effuent & domestic waste water will be treated in ETP followed by RO & MEE.

Details of Waste generation and Disposal/ Management are given in section C PFR. 1.16 Facilities for long term housing of No The workers will be available from nearby local operational workers? areas thus there will be no need for housing for staff. 1.17 New road, rail or sea traffc during No All raw materials/fnished products need only road construction or operation? transportation. Existing transportation facilities will be adequate. 1.18 New road, rail, air waterborne or No Existing routes will be adequate and will be used other transport infrastructure for transportation. including new or altered routes and stations, ports, airports etc.?

A-4 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1.19 Closure or diversion of existing No No such closure or diversion of existing transport is transport routes or infrastructure required. leading to changes in traffc movements? 1.20 New or diverted transmission lines No No new diversion of transmission lines or pipelines or pipelines? will be done. 1.21 Impoundment, damming, culverting, No Not applicable realignment or other changes to the hydrology of watercourses or aquifers? 1.22 Stream crossings? No Not applicable

1.23 Abstraction or transfers of water No No abstraction of water from ground or surface from ground or surface waters? water sources.

Water will be supplied by MIDC supply. 1.24 Changes in water bodies or the land No Proposed site is well within the MIDC designated surface affecting drainage or Industrial Park and hence not cause /affect drainage run-off? or run-off. 1.25 Transport of personnel or materials Yes During Construction Phase: Local labourers and for construction, operation or materials will be sourced and will be transported decommissioning? using closed containers with PUC vehicles.

During Operation Phase: Transport facilities are available for workers/employees to and from the Industrial area to the nearby town. All raw materials will be transported using road trucks from various parts of India. All the fnished products will be transported using road trucks to various parts of India. 1.26 Long-term dismantling or No Not applicable decommissioning or restoration works? 1.27 Ongoing activity during No Not applicable decommissioning which could have an impact on the environment? 1.28 Infux of people to an area either Yes During construction phase: About 50 no. temporarily or permanent? Labourers will be employed. During operation phase: The present strength of employees and workers @105 will increase to 155. 1.29 Introduction of alien species? No There are no alien species at the proposed site and even after expansion there will be no alien species introduced. 1.30 Loss of native species or genetic No Proposed Green belt development will have native diversity? species with genetic diversity.

A-5 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1.31 Any other actions? No No additional action will be implemented.

2. Use of Natural resources for construction or operation of the Project (such as land, water, materials or energy, especially any resources which are non-renewable or in short supply): S.No. Information/checklist confrmation Yes/No Details thereof (with approximate quantities /rates, wherever possible) with source of information data 2.1 Land especially undeveloped or No Site is within the already developed MIDC agricultural land (ha) Industrial Park. 2.2 Water (expected source & Yes Source of Water: MIDC competing users) unit: KLD After Expansion total water required will be 605 KLD out of which 228 KLD will be treated water and 377 KLD will be fresh water. Activity After expansion Domestic 20 KLD

Industrial process 219 KLD

Cooling tower and Boiler 353 KLD

Gardening 13 KLD

Total 605 KLD

2.3 Minerals (MT) Yes Proposed expansion is for the manufacturing of chemicals which will not use any minerals in its process. 2.4 Construction material – stone, Yes Cement, Stone, Steel etc. will be used for aggregates, sand / soil (expected construction activities as per the requirements source – MT) & shall be bought from the local market. 2.5 Forests and timber (source – MT) No No forest products will be used for expansion work. Timber may be used for offce furniture only. 2.6 Energy including electricity and fuels Yes Electricity- Power requirement will increase (source, competing users) Unit: fuel from existing 577 kVA to 2000 kVA after (MT), energy (MW) expansion. Source: Maharashtra State Electricity Distribution Company Limited (MSEDCL) Standby Power: 2 No. of DG set of 500 KVA which shall be used to support requirements after expansion. Fuel: 160 ltr/hr of High Speed Diesel will be used in DG sets. Boiler: After expansion: 1x5 TPH & 2x3TPH boilers will be in operation with coal as Fuel.

A-6 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Thermic Fluid Heater: 1*200000 kCal/hr. 2.7 Any other natural resources (use No None appropriate standard units)

3. Use, storage, transport, handling or production of substances or materials, which could be harmful to human health or the environment or raise concerns about actual or perceived risks to human health. S.No. Information/Checklist Yes/No Details thereof (with approximate confrmation quantities/rates, wherever possible) with source of information data 3.1 Use of substances or materials, Yes Being a chemical industry, many different which are hazardous (as per MSIHC chemicals are being used as raw materials, and rules) to human health or the fnished products as well. Storage of all environment (fora, fauna, and chemicals shall not exceed their threshold water supplies) limit, wherever threshold is exceeded necessary permission/clearance shall be obtained as per MSIHC Rules, 1989. Details of material to be used and their threshold limit are given in Section C- PFR Report. 3.2 Changes in occurrence of disease or No Suitable drainage and waste management affect disease vectors (e.g. insect or measures shall be adopted. This restricts water borne diseases) stagnation of water or accumulation of water. No occurrence of diseases is anticipated. 3.3 Affect the welfare of people e.g. by No The project affects the nearby people in changing living conditions? positive ways through direct and indirect employment generation. Through proper multi cyclone dust collectors, electrostatic precipitator, stacks and WWTP, the manufacturing plant will ensure neither the environment nor the neighborhood is affected. 3.4 Vulnerable groups of people who No The project is within the MIDC industrial park could be affected by the project e.g. and there is No vulnerable group of people hospital patients, children, the within the Industrial area. elderly etc. 3.5 Any other causes No None

4. Production of solid wastes during construction or operation or decommissioning (MT/month)

S.No. Information/Checklist confrmation Yes/ Details thereof (with approximate No quantities/rates, wherever possible) with source of information data

A-7 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

4.1 Spoil, overburden or mine wastes No Not Applicable 4.2 Municipal waste (domestic and or Yes

commercial wastes) Category After Treatment Method Expansion after expansion (Kg/day)

Biodegradable 66 Treated in Proposed OWC

Non-Biodegra 99 Sold to Authorised dable Recycler

Total 165

4.3 Hazardous wastes (as per Hazardous Yes Waste Management Rules) Hazardous After Disposal waste Expansion Quantity (TPA)

ETP sludge 145 CHWTSDF

MEE salt 6059 CHWTSDF

Empty 20000 CHWTSDF containers No./year

Used Oil 0.5 CHWTSDF

Process Recycled/reused in residue the process /Sale methanol to authorized 673.55 party// CHWTSDF

Distillation CHWTSDF residue 1068

Process Recycled/reused in residue the process /Sale Butanol to authorized 36.6 party// CHWTSDF

4.4 Other industrial process wastes Yes Boiler ash 766.5 TPA will be generated after expansion which will be disposed through nearby brick manufacturing units. Scraps M/S of 500 TPA will be generated after expansion which will be sold to authorized recyclers.

A-8 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

4.5 Surplus product No Nil

4.6 Sewage sludge or other sludge from No ETP sludge & MEE salts shall be disposed of effuent treatment after obtaining necessary HW authorisation to the TSDF site. 4.7 Construction or demolition wastes No There is no generation of C&D Waste anticipated 4.8 Redundant machinery or equipment No Not applicable 4.9 Contaminated soils or other No Not applicable materials 4.10 Agricultural wastes No Not applicable 4.11 Other solid wastes Yes Discarded containers after decontamination will be used for packing of ETP sludge//MEE Salts; excess will be sold to approved recyclers or traders.

5. Release of pollutants or any hazardous, toxic or noxious substances to air (kg/hr)

S.No. Information/Checklist confrmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 5.1 Emissions from combustion of fossil Yes The major air pollutants sources by fuels from stationary or mobile combustion of Fossil fuels are given below: sources ● Boiler ● Process Reactors ● DG sets After Expansion, Details of emission and the control systems unit wise are given in Section C, PFR Report. 5.2 Emissions from production Yes Flue gases generated from the production processes processes of different products and intermediates shall contain and Total Particulate Matter (TPM). Flue gases will be channelised through a hood into a centralised ducting system then transferred to a common wet scrubber to scrub the gases. 5.3 Emissions from materials handling No Raw materials / fnished goods will be stored including storage or transport in appropriate containers/drums. Through standard operating procedures and right tools and plants , the same in required quantities will be moved to the process bay wherever it is required to be handled. 5.4 Emissions from construction Yes There will be no hazardous / toxic /noxious activities including plant and emissions from construction activities. equipment

A-9 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

5.5 Dust or odors from handling of Yes Dust is likely to be generated from materials materials including construction handling operations including transportation materials, sewage and waste which will be suppressed by water sprinklers. There will be generation of particulate matters due to construction and machines erection activities. However, care will be taken to minimise by adopting best engineering practices , avoidance of parallel activities and if required to granting work permit system Domestic waste water along with effuent will be treated in effuent treatment plants; adequate ventilation shall be provided to ensure minimum malodour. Plant manufacturing area will be neat and clean. All process reactions will be carried out in closed vessels with proper dust and odor removal systems in place. 5.6 Emissions from incineration of No None waste 5.7 Emissions from burning of waste in No Not applicable open air (e.g. slash materials, construction debris) 5.8 Emissions from any other sources No None

6. Generation of Noise and Vibration, and Emissions of Light and Heat:

S.No. Information/Checklist confrmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data with source of information data 6.1 From operation of equipment e.g. Yes Noise will be generated during operation of the engines, ventilation plant, crushers plant from pumps & motors, machineries, cooling tower, boiler, DG set & Thermic fuid heater, etc. Each equipment will have their noise generation limited to 75 dBA or less at the time of procurement. Through noise barriers, regular and periodic maintenance noise levels of these machineries will be maintained within allowable limits. DG sets will be procured with built-in acoustic enclosures that will ensure a minimum of 25 dbA reduction. All workers will be provided with ear muffers working in such areas where noise levels will be high.

A-10 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Greenbelt will be developed to abate the noise across the boundary. 6.2 From industrial or similar processes Yes Sources of noise pollution from the plant will be Pumps & Motors, Machineries, Cooling Tower, D.G. set etc. 6.3 From construction or demolition yes Noise generated from the construction activities will be mitigated by the use of adequate PPE and noise barriers shall be proposed if required. 6.4 From blasting or piling No No blasting or piling will be done. 6.5 From construction or operational Yes Noise will be generated from vehicular traffc movement in the installation/construction and operational phase & will be within permissible limit. Green belts developed at the periphery of the project site will act as a barrier to noise. 6.6 From lighting or cooling systems No Not applicable 6.7 From any other sources No Not applicable

7. Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea:

S.No. Information/Checklist confrmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 7.1 From handling, storage, use or Yes Industry is providing adequate storage areas spillage of hazardous materials for the safe storage of products, raw materials and hazardous chemicals as per approved Layout drawing. Proper care shall be taken to avoid any spillage. Proper care for handling hazardous material will be taken as per the MSIHC rules, 1989 7.2 From discharge of sewage or other Yes Sewage and effuent generated within the unit effuents to water or the land will be treated in the Effuent Treatment Plant; (expected mode and place of while 228 KLD all the treated effuent will be discharge) reused within the plant itself. 7.3 By deposition of pollutants emitted No Necessary Air Pollution Control Devices will to air into the land or into water be installed and fue gases/ vent gases will pass through wet scrubber before being let out into air through stacks of adequate heights. These measures ensure proper dilution of fue /vent gases at appropriate heights and thus will not allow any deposition of pollutants. 7.4 From any other sources No None

A-11 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

7.5 Is there a risk of long-term buildup No None of pollutants in the environment from these sources?

8. Risk of accidents during construction or operation of the Project, which could affect human health or the environment

S.No Information/Checklist confrmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 8.1 From explosions, spillages, fres etc Yes Being a chemical industry, the risk of from storage, handling, use or accidents is imminent. By undertaking production of hazardous substances QRA/HAZOP/HAZEN studies, the risks and mitigation will be identifed before commencing operation of the manufacturing plant. All recommended SOPs and safety measures will be incorporated in the plant during operation.

However, during construction works no hazardous substances will be used, handled or stored. Therefore, no risk of accidents is anticipated due to hazardous substances. 8.2 From any other causes No Even during any unexpected natural calamity, earthquakes, etc, there will not be may risk involved as the raw materials/fnished materials will always be stored properly 8.3 Could the project be affected by Yes As the proposed project site is falling in natural disasters causing seismic zone-IV, the risk of earthquake is very environmental damage (e.g. less; the area is not food prone and has foods, earthquakes, landslides, never experienced cloudbursts. cloudburst etc)?

9. Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality

S. No. Information/Checklist confrmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data

A-12 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

9.1 Lead to development of support, No impact on the surrounding environment is Yes facilities, ancillary development or envisaged due to the following facts: development stimulated by the project ● Proposed project will be located within which could have an impact on the the already operational MIDC Roha environment e.g.: industrial area. • Supporting infrastructure (roads, ● Existing roads and transportation power supply, waste or waste water facilities will be utilized. treatment, etc.) ● Power demand will be met through Maharashtra State Electricity Distribution • housing development No Company Limited (MSEDCL). Adequate • extractive industries No provision is already made for the • supply industries No Industrial activities within the park. • other No ● Industrial wastewater will be treated in an in-house ETP followed by MEE & RO and it will be a ZLD unit. 9.2 Lead to after-use of the site, which No Though the plant is a chemical manufacturing could have an impact on the unit, there won’t be any environment spillage/contamination over the soil or structures during the operation as the plant will be run through a set of SOPs. Hence, even after-use of the site, for whatever reason, there won’t be any impact on the environment. 9.3 Set a precedent for later developments No The project itself is a part of MIDC’s initiative to develop chemical manufacturing units at Roha, Raigad. 9.4 Have cumulative effects due to No All precautions/ measures like APCS/ZLD will proximity to other existing or planned be taken to control/ avoid pollution loads in projects with similar effects the surrounding. Hence , there will be no addition of any pollutant that could lead to cumulative adverse effects due to proximity with other similar industries within MIDC Park.

(II) Environment Sensitivity

S. No Areas Name/Identity Aerial distance (within 15 km.) from Proposed project location boundary

Distance in km Direction

Areas protected under international ASI Monuments 1 conventions, national or local ASI Monuments :Attached :Attached ASI legislation for their ecological, Separately Separately Monuments

A-13 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

landscape, cultural or other related :Attached value Separately Western Ghats (Draft 2.23 Km SW Notifed) Village Dhatav CT Phansad WildLife Sanctuary With ESZ 11.26 Km WSW Phansad WildLife Sanctuary 14.06 Km WSW Water Bodies Pond near Dhatav 0.79 KM SE Kundalika River 0.98 Km NNE Canal near Nadawali 5.90 Km NE Low water Line near Kopra 7.62 Km NW Kund River 9.11 Km SSW Pond near Kansai 9.15 Km NNE River near Wazaroli 10.26 Km NNE Forest Reserve Forest near Dhatav 1.44 Km ESE Reserve Forest near Washi 2.19 Km SSE Reserve Forest near Nivi 2.34 Km SW Reserve Forest near Areas which are important or sensitive Bhubaneswar 2.70 Km WNW for ecological reasons - Wetlands, Reserve Forest near 2 watercourses or other water bodies, Dhankanhe 4.61 Km NNE coastal zone, biospheres, mountains, Reserve Forest near Sambhe 4.95 Km SE forests Reserve Forest near Vandoli 5.36 Km NNW Reserve Forest near Tambadiwadi 6.05 Km WSW Reserve Forest near Katoriwadi 6.79 Km ESE Reserve Forest near Varasgaon 7.19 Km SE Reserve Forest near Khambere 7.18 Km WSW Reserve Forest near Gathon 7.45 Km ESE Reserve Forest near Varvade 8.67 Km NW Reserve Forest near Mukte 8.86 Km SSW Reserve Forest near Jambwadi 9.06 Km SSE

A-14 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Reserve Forest near Ainvahal 9.26 Km ENE Reserve Forest near Kumbhoshi 9.54 Km NW Reserve Forest near Muchne 10.13 Km SW Reserve Forest near Kondthare 10.22 Km SSW Reserve Forest near Chinchawali Tarf Diwali 10.46 Km ESE Reserve Forest near Chinchawali Tarf Stone 10.46 Km NE Reserve Forest near Borhan 11.98 Km SW Reserve Forest near Arali 12.72 Km SW Reserve Forest near Kanti 13.12 Km SW Western Ghats Boundary 2.23 Km SW Areas used by protected, important or village (Dhatav CT) Draft Notifed 3 sensitive species of fora or fauna for breeding, nesting, foraging, resting, Phansad WildLife Sanctuary overwintering, migration With ESZ 11.26 Km WSW Phansad WildLife Sanctuary 14.06 Km WSW 4 Inland, coastal, marine or Araban Sea 25.54 Km W underground waters 5 State, National boundaries None within 15 km Radius None within 15 None within 15 km Radius km Radius Road Roha-Kolad Road 0.91 Km N Roha-Ghosale Road 4.03 Km WNW NH-66 5.82 Km ENE Routes or facilities used by the public Railway Station 6 for access to recreation or other Roha Railway Station 3.50 Km NW tourist, pilgrim areas Nidi Railway Station 6.91 Km NW Kolad Railway Station 8.29 Km SE Airport Chhatrapati Shivaji Maharaj International Airport 79.41 Km NNw 7 Defence installations None within 15 None within 15 None within 15 km Radius km Radius km Radius

8 Densely populated or built-up area Dhatav 0.44 Km SE

A-15 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Hospital Dr. Dhruv Narsing Home- 2.70 Km NWN Amrita Nursing Home, Varse, Bhuwaneshwar, Maharashtra Jadhav Hospital- Wali, Tala, 3.07 Km NWN Maharashtra Dr.Bhat Nursing Home-Opp 3.28 Km WNW Panchayat Samiti, Bhuwaneshwar,Roha, Maharashtra Post Offce Roha A V Sub Post 0.91 Km NNW Offce-Roha, B K Maharashtra Varse Post Offce- Varse, 2.39 Km NNW Bhuwaneshwar, Maharashtra Post Offce Roha-Wali, 3.69 Km NNW Tala,Maharashtra Place of Worship Areas occupied by sensitive Kale Datta Mandir-Brahmin 3.76 Km NNW man-made land uses (hospitals, 9 Ali, Wali,Roha Maharashtra schools, places of worship, community Shree Datt Mandir Roha- 3.76 Km NNW facilities) Chhatrapati Shivaji Maharaj Marg, Roha Maharashtra Shree Omkareshwar Mandir, 3.86 Km NNW Wali, Roha Maharashtra School Dhatav School Roha,Kolad 0.91 Km NNE Road, Roha, Maharashtra J M Rathi English School, (Pre 1.88 Km NNW Primary),Roha Khurd, Roha, Ashtami Maharashtra J M Rathi School, Roth Khurd, 2.09 Km NNW Roha, Maharashtra Bank Bank of Maharashtra- Roha 0.94 Km S Industrial Estate,CFC Building,MDC Estate, Dhatav, Maharashtra

A-16 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Bank of India, MIDC, 1.23 Km SSE Common Facility Centre At & Post, Dhatav, Roha Maharashtra IDBI Bank Roha, Tala, Wali 2.90 Km NNW Tala, Maharashtra ASI Monuments :Attached ASI Monuments ASI Monuments Separately :Attached :Attached Separately Separately Water Bodies Pond near Dhatav 0.79 KM SE Kundalika River 0.98 Km NNE Canal near Nadawali 5.90 Km NE Low water Line near Kopra 7.62 Km NW Kund River 9.11 Km SSW Pond near Kansai 9.15 Km NNE Forest Reserve Forest near Dhatav 1.44 Km ESE Reserve Forest near Washi 2.19 Km SSE Areas containing important, high Reserve Forest near Nivi 2.34 Km SW quality or scarce resources Reserve Forest near Bhuwaneshwar 2.70 Km WNW 10 (Groundwater resources, surface Reserve Forest near resources, forestry, agriculture, Dhankanhe 4.61 Km NNE fsheries, tourism, minerals) Reserve Forest near Sambhe 4.95 Km SE Reserve Forest near Vandoli 5.36 Km NNW Reserve Forest near Tambadiwadi 6.05 Km WSW Reserve Forest near Katoriwadi 6.79 Km ESE Reserve Forest near Varasgaon 7.19 Km SE Reserve Forest near Khambere 7.18 Km WSW Reserve Forest near Gathon 7.45 Km ESE Reserve Forest near Varvade 8.67 Km NW Reserve Forest near Mukte 8.86 Km SSW

A-17 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Reserve Forest near Jambwadi 9.06 Km SSE Reserve Forest near Ainvahal 9.26 Km ENE Reserve Forest near Kumbhoshi 9.54 Km NW Reserve Forest near Muchne 10.13 Km SW Reserve Forest near Kondthare 10.22 Km SSW Reserve Forest near Chinchawali Tarf Diwali 10.46 Km ESE Reserve Forest near Chinchawali Tarf Atone 10.46 Km NE Reserve Forest near Borhan 11.98 Km SW Reserve Forest near Arali 12.72 Km SW Reserve Forest near Kanti 13.12 Km SW Areas already subjected to pollution None within 15 km Radius None within 15 None within 15 11 or environmental damage. (Those km Radius km Radius where existing legal environmental standards are exceeded) Areas susceptible to natural hazard Area falls in Area falls in which could cause the project to seismic zone IV. seismic zone IV. 12 present environmental problems (Earthquakes, subsidence, landslides, erosion, fooding or extreme or adverse climatic conditions)

A-18 A-19 SECTION B: BRIEF SUMMARY Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

The proposed project is for “Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant” located at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra. developed by M/s Anshul Innovative Chemistry Private Limited. The project was originally granted with an Environmental Clearance for the production of technical product is 5,825 TPA and By-Product is 710 TPA Vide EC F.NO J-11011/353/2016-IA II(I) dated 1st Sept 2017 to M/s Ambernath Organics Pvt. Ltd who has not initiated any work at site and subsequently the project was taken over by M/s. Anshul Innovative Chemistry Pvt. Ltd on 19.06.2020.

The project is Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant with a total Existing production capacity of technical product is 5,825 TPA and By-product is 710 TPA manufacturing Materials in accordance with CTE vide letter no. Format 1.0/AS(T)/UAN No. 0000100363/CE-2102000633 dated 10.02.2021.

After expansion total production capacity will be 33267 TPA.

Proposed project is involved in manufacture of synthetic organic chemicals industry (synthetic organic chemicals and chemical intermediates) along with some specifc pesticide intermediates (agrochemical intermediates) and lies within the notifed industrial area. The proposal will be considered at the central level a category ‘A’ in Schedule 5(b) of the EIA Notifcation 2006 and its subsequent amendment. all products covered under 5(f) & 5(b) of EIA notifcation are categorized under Cat ‘A’ and are required to be appraised by Industry 3- EAC at MoEF&CC.

The estimated project cost after expansion will be Rs. 47 Crores (Existing Cost: Rs. 36 Crores; Proposed Expansion Cost: Rs. 11 Crores). Total capital cost earmarked towards environmental pollution control measures is Rs. 635 Lakhs and the Recurring cost (operation and maintenance) will be about Rs 583 Lakhs per annum. Greenbelt area will also be increased to 5182 m2 i.e 33.0 % out of the total area of the project.

Total Employment after the proposed expansion will be 155 persons (105 existing and 50 proposed). Industry proposes to allocate Rs. 5 Lakhs of Project Cost towards Corporate Environmental Management plan.

(a) Water Requirement and Source Total water Requirement After Expansion:- 605 KLD Fresh Water Requirement: 377 KLD Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B2 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Source of water: MIDC Roha Supply Power requirement for the project is to be met from Maharashtra State Electricity Distribution Company Limited (MSEDCL). At Present power requirement is 577 kVA. After expansion power requirement will be 2000 kVA and DG sets of 2x500 kVA will be used as standby during power failure with maximum stack height of 4 m as per CPCB norms.

Details of Emission wise Air Pollution Control Measures and Management Emission from utility EMISSIONS FROM UTILITIES

Source Type of Fuel APCS Stack Height (m)

DG SET-2* 500 kVA HSD Acoustic enclosure 10

Boiler -5 TPH Coal multi cyclone dust collector 30

Boiler : 2x3 TPH Coal multi cyclone dust collector 30

Thermic fuid heater THF cap Coal ESP, Stack 20 2 Lac Kcal/hr

Emissions from Process Sr. Name of Stack Location Pollution Height Stack dia Cross Sec Paramet No Control in Mtr area er Measure

3 1 S-01 IA Plant Packed 18 300 NB 5000 m /hr CO2 IA Plant Sigma Sigma column, Venturi scrubber with blower Scrubbing media- Caustic water

2 S -02 OC Caustic Falling flm 5 100 NB 16 m2/hr HCl, Cl OC Plant Scrubber Scrubber Scrubbing media- caustic water

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B3 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

3 S-03 CMIC Caustic Falling flm 3 80 NB 16 m2/hr HCl, Cl CMIC Plant Scrubber Scrubber Scrubbing media- Caustic water

4 S-04 OC/ CMIC Venturi 25 600 mm 12750 m3/hr HCl, Cl Emergency Plant scrubber with Scrubber Emergency blower Scrubber

5 S-05 Chlorine Venturi 20 600 mm 6000 m3/hr Cl Chlorine Eme Vaporizer scrubber with System Emergency blower Scrubber

Details of Solid waste/ Hazardous waste generation and its management as shown below:

Solid Waste Management

After Expansion Category Type of Waste (kg/day) Treatment Method

Biodegradable Organic Waste 66 Sent to MSW disposal site

Non-Biodegradable Recyclable 99 Sold to Authorised Recycler Waste (Plastic, paper, wood, glass, etc) Total 165

Non- Hazardous waste Management

NON-HAZARDOUS WASTE MANAGEMENT (PROCESS)

Process Waste Unit Total after expansion Treatment/Disposal

Boiler Ash TPA 766.5 Brick manufacturing

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B4 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Plastic Waste TPA 1.2 Sale to authorised party for recycle

Wooden pallets Nos / Annum 50 Sale to authorised party for recycle

SCRAP M/S TPA 500 Sale to authorised party for recycle

Hazardous Waste Management HAZARDOUS WASTE MANAGEMENT (PROCESS)

S.No Waste Category Unit Total after Disposal expansion

1 Chemical sludge from 35.3 Landfll at CHWTSDF wastewater treatment TPA 145 (ETP Sludge)

2 Concentration or 37.3 Sale to authorized party// evaporated residue TPA 6059 CHWTSDF (MEE Salt )

3 Empty barrels/ 33.1 Sale to authorized Containers/liners reconditioner / CHWTSDF contaminated with Nos./Y 20000 hazardous chemicals/ waste

4 Used or spent Oil 5.1 Sale to authorized party// Ltr/Annum 500 CHWTSDF

5 Process Residue and 28.1 Recycled/reused in the waste (Recovered TPA 673.55 process /Sale to authorized Methanol) party// CHWTSDF

6 Distillation residue 20.3 Sale to authorized party// TPA 1068 CHWTSDF

7 Process Residue and 28.1 Recycled/reused in the waste (Recovered TPA 36.6 process /Sale to authorized Butanol) party// CHWTSDF

The project is exempted from Public Hearing as the site is within the notifed industrial area (MIDC). There is no litigation pending against the project.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B5 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

The details of products and capacity as under:

Products/ By-Product Existing Proposed After Expansion Sr. No. Name Cas No. (TPA) (TPA) (TPA)

A Pharma & Chemical Intermediates

1 Isatoic Anhydride 118-48-9 3,005.0 - 3,005.0

2 Anthranilic acid 118-92-3 400.0 - 400.0

3 Methyl Anthranilate 134-20-3 2,000.0 - 2,000.0

4 Dimethyl anthranilate 85-91-6 200.0 - 200.0

5 Butyl Anthranilate 7756-96-9 100.0 - 100.0

6 Anthranilamide 88-68-6 80.0 160.0 240.0

7 Dibromoester 105-36-2 40.0 - 40.0

8 Oxalyl chloride 79-37-8 - 2,400.0 2,400.0

Chloromethyl isopropyl 35180-01-0 9 carbonate 9 - 1,200.0 1,200.0

Methyl Oxalyl Chloride 10 (MOC) 5781-53-3 - 300.0 300.0

11 2-Chloroacetamide (2CAA) 79-07-2 - 300.0 300.0

2-[N-(2-Aminobenzoyl)]-a 2 mino benzoic acid(AAS) 1147-43-9 - 72.0 72.0

13 Trichloroacetamide (TCA) 594-65-0 - 72.0 72.0

14 Hexabromobenzene (HBB) 87-82-1 - 120.0 120.0

2[2-(Hydroxy benzoyl) amino] benzoic acid 58574-03-0 15 (HBAB) 1 - 60.0 60.0

Naphthalene 2-Sulfonyl 16 chloride (NSCl) 93-11-8 - 72.0 72.0

17 3,5-Xylenol 108-68-9 - 1,200.0 1,200.0

p-Chloro Meta Xylenol 18 (PCMX) 88-04-0 -- 600.0 600.0

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B6 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Tetramethyl bisphenol-F 19 (TMBP-F) 5384-21-4 - 600.0 600.0

Sub Total (A) 5,825.0 7,156.0 12,981.0

B Agrochemicals

20 2-Cyanoaniline 1885-29-6 - 60.00 60.00

Sub Total (B) - 60.00 60.00

C Industrial Chemicals

21 HCL (min 30 %) 7647-01-0 - 20,181.0 20,181.0

22 Dimethyl Oxalate 553-90-2 - 45.0 45.0

Sub Total (C) - 20,226.0 20,226.0

Total production Capacity (A+B+C) 5,825.0 27,442.0 33,267.0

Cost on Environment Management Plan Capital Cost: Sr. No. Particulars Proposed Unit (Lacs)

1 Air Pollution Control 80 2 Water Pollution Control 500 3 Noise Pollution Control 5 4 Landscaping/Green Belt 5 5 Rain Water Harvesting 10 6 Solid Waste Management 30 7 Social Activities 5 Total 635

Recurring cost Sr. No. Particulars (Rs. in Lacs)

1 Air Pollution Control 50 2 Water Pollution Control 200 3 Noise Pollution Control 1 4 Landscaping/Green Belt 2 5 Rain Water Harvesting 1 6 Solid Waste Management 300 7 Environment monitoring 3 8 Work Zone monitoring 1

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B7 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

9 Occupational Health & safety 25 Total 583

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. B8 SECTION-C

PRE- FEASIBILITY REPORT Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1. EXECUTIVE SUMMARY 7

2. INTRODUCTION TO THE PROJECT 8 2.1. Introduction of Project and Project Proponent 8 2.2. Brief description and nature of the project 9 2.3. Need for the project and its importance to the country and or region 9 2.4. Demand – Supply Gap 11 2.5. Import vs. Indigenous Production 12 2.6. Employment Generation (Direct and Indirect) due to the project 12

3. PROJECT DESCRIPTION 13 3.1. Type of Project including interlinked and independent projects, if any. 13 3.2. Location of the site is given below 13 3.2.1. Details of alternative sites considered and basis of selecting the proposed site 17 3.2.2. Existing Site photographs 18 3.3. Size or magnitude of operation 18 3.4. Project description with process details 19 3.4.1. 2-Chloroacetamide (2-CAA) 20 3.4.2. 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) 22 3.4.3. Trichloroacetamide (TCA) 24 3.4.4. Hexabromo benzene (HBB) 26 3.4.5. 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) 30 3.4.6. Naphthalene 2-Sulfonyl chloride (NSCl) 35 3.4.7. 3,5-Xylenol 38 3.4.8. p-Chloro Meta Xylenol (PCMX) 40 3.4.9. Tetramethyl bisphenol-F (TMBP-F) 41 3.4.10. 2-Cyanoaniline 44 3.4.11. Anthranilic acid (AA) 45 3.4.12. 3, 5-Dibromo methyl anthranilate(Dibromo MA) 47 3.5. Raw material required along with estimated quantity, likely source, mode of transport of raw materials and fnished product 50 3.6. Plant & Machineries 58 3.7. Resources optimization/ recycling and reuse envisaged in the project 70 3.8. Availability of water it’s source, Energy /power requirement and source 70 3.9. Power Requirement and Source 73

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 2 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

3.10. Air Emissions and Control 73 3.10.1. Odour Control 75 3.11. Waste Management 75 3.11.1. Domestic Solid Waste 75 3.11.2. Process Waste (Non-Hazardous) 76 3.11.3. Hazardous Waste Management 76

4. SITE ANALYSIS 77 4.1. Connectivity 77 4.2. Social Infrastructure around the Project Site 77 4.3. Topography 79 4.4. Existing land use pattern 79 4.5. Existing Infrastructure 80 4.6. Soil classifcation 80 4.7. Climatic data from secondary sources 81 4.7.1. Climatic Conditions (As per the Indian Meteorological Data-Station Mumbai Airport) 81 4.7.2. Temperature 81 4.7.3. Relative Humidity 82 4.7.4. Rainfall 84 4.8. Social Infrastructure available 84

5. PLANNING BRIEF 84

6. PROPOSED INFRASTRUCTURE 85

7. REHABILITATION AND RESETTLEMENT (R & R) PLAN 88

8. PROJECT SCHEDULE AND COST ESTIMATES 88

9. ANALYSIS OF PROPOSAL (Final Recommendations) 90

List Of Images ■ Figure 1. Satellite image of the site ■ Figure 2. Plant Layout plan ■ Figure 3. Topographical map ■ Figure 4. Process fow diagram-1 for Chloroacetamide (2-CAA)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 3 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

■ Figure 5. Process fow diagram-2 for Chloroacetamide (2-CAA) ■ Figure 6. Process fow diagram-3 for Chloroacetamide (2-CAA) ■ Figure 7. Chemical reaction for 2-Chloroacetamide ■ Figure 8. Process fow diagram-1 of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) ■ Figure 10. Process fow diagram-2 of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) ■ Figure 10. Process fow diagram-2 of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) ■ Figure 11. Chemical reaction of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) ■ Figure 12. Process fow diagram of Trichloroacetamide (TCA) ■ Figure 13. Chemical reaction of Trichloroacetamide (TCA) ■ Figure 16. Process fow diagram of Hexabromo benzene (HBB) ■ Figure 16. Process fow diagram of Hexabromo benzene (HBB) ■ Figure 16. Process fow diagram of Hexabromo benzene (HBB) ■ Figure 17. Chemical reaction of Hexabromobenzene ■ Figure 20. Process fow diagram of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) ■ Figure 20. Process fow diagram of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) ■ Figure 20. Process fow diagram of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) ■ Figure 21. Chemical reaction of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) ■ Figure 22. Process fow diagram-1 of Naphthalene 2-Sulfonyl chloride (NSCl) ■ Figure 24. Process fow diagram-1 of Naphthalene 2-Sulfonyl chloride (NSCl) ■ Figure 24. Process fow diagram-1 of Naphthalene 2-Sulfonyl chloride (NSCl) ■ Figure 25. Chemical reaction of Naphthalene 2-Sulfonyl chloride (NSCl) ■ Figure 26. Process fow diagram of 3,5-Xylenol ■ Figure 27. Chemical reaction of 3,5-Xylenol

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 4 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

■ Figure 28. Process fow diagram of p-Chloro Meta Xylenol (PCMX) ■ Figure 29. Chemical reaction of p-Chloro Meta Xylenol (PCMX) ■ Figure 30. Process fow diagram of Tetramethyl bisphenol-F (TMBP-F) ■ Figure 31. Chemical reaction of Tetramethyl bisphenol-F (TMBP-F) ■ Figure 32. Process fow diagram of 2-Cyanoaniline ■ Figure 33. Chemical reaction of 2-Cyanoaniline ■ Figure 34. Process fow diagram of Anthranilic acid (AA) ■ Figure 35. Chemical reaction of Anthranilic acid (AA) ■ Figure 36. Process fow diagram of 3, 5-Dibromo methyl anthranilate(Dibromo MA) ■ Figure 37. Chemical reaction of 3, 5-Dibromo methyl anthranilate(Dibromo MA) ■ Figure 38. Water Balance ■ Figure 39. Land use Map ■ Figure 40. Maximum Humidity in % ■ Figure 41. Google Image using existing road near the project site

List Of Tables ■ Table 1. Project details ■ Table 2. Use of Product and by product ■ Table 3. Details of manpower ■ Table 4. Location of the site ■ Table 5. Latitude and longitude of the site ■ Table 6. Production details ■ Table 7. Material balance for Chloroacetamide ■ Table 8. Material balance of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) ■ Table 9. Material balance of Trichloroacetamide (TCA) ■ Table 10. Material balance of Hexabromo benzene (HBB) ■ Table 11. Material balance of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) ■ Table 12. Material balance of Naphthalene 2-Sulfonyl chloride (NSCl) ■ Table 13. Material balance of 3,5-Xylenol ■ Table 14. Material balance of p-Chloro Meta Xylenol (PCMX)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 5 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

■ Table 15. Material balance of Tetramethyl bisphenol-F (TMBP-F) ■ Table 16. Material balance of 2-Cyanoaniline ■ Table 17. Material balance of Anthranilic acid (AA) ■ Table 18. Material balance of 3, 5-Dibromo methyl anthranilate(Dibromo MA) ■ Table 19. Details of raw material ■ Table 20. Equipment list ■ Table 21. Details of plant & Machinery ■ Table 22. water requirement ■ Table 23. Wastewater generation ■ Table 24. Characteristics of wastewater and treated water ■ Table 25. Emission from utility ■ Table 26. Emission from process ■ Table 27. Solid waste management ■ Table 28. Non- Hazardous waste management ■ Table 29. Hazardous waste management ■ Table 30. Social infrastructure around the site ■ Table 31. List of Industries ■ Table 32. Area breakup details ■ Table 33. Temperature ■ Table 34. Relative humidity ■ Table 35. Rainfall data ■ Table 36. List of industries in 2 km ■ Table 37. Capital Expenditure ■ Table 38. Recurring Expenditure

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 6 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 1. EXECUTIVE SUMMARY

The proposed project is for Expansion of Chemical and Agro Chemical Intermediates Manufacturing Unit located at Plot no. 21/2, Dhatav MIDC, Taluka Roha, District Raigad, State Maharashtra developed by M/s Anshul Innovative Chemistry Private Limited.

The project was originally granted with an Environmental Clearance for the production of technical product is 5,825 TPA and By-Product is 710 TPA Vide EC F.NO J-11011/353/2016-IA II(I) Dated 1st Sept 2017 to M/s Ambernath Organics Pvt. Ltd who has not initiated any work at site and subsequently the project was taken over by M/s. Anshul Innovative Chemistry Pvt. Ltd on 19.06.2020.

M/s. Anshul Innovative Chemistry Pvt.Ltd , has secured Consent To Establish (CTE) vide letter no. Format 1.0/AS(T) UAN No 0000100363/CE -2102000633 dated 10.02.2021 granted by Maharashtra Pollution Control Board with validity for a period till commissioning or upto 5 years whichever is earlier, and have just initiated the site works as per the Consent to Establish secured. The construction works are going on at site and procurement of required equipment and machinery has been initiated.

Public hearing is exempted under the provision as per para 7 (i) III. Stage (3) (b) as per EIA notifcation 2006.

The project details are given below: Table 1. Project details S. No. Particulars Unit Details as per EC Proposed After Expansion dated 01.09.2017 Expansion Details Details

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 7 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1 Project Cost INR Crores 11 36 47

2 Total Plot Area m2 15,703 0 15,703 3 Green Area m2 6218 (39.6%) 5182 (33.0%) 4 Built-up area m2 2,355.17 7098.86 9454.03 5 Manpower No. 105 50 155 6 Source of power - Maharashtra State Electricity Distribution Company Limited (MSEDCL) 7 Total power kVA 577 1423 2000 requirement 8 Boiler TPH 3 nos.*0.8 1 no.*5 1 no.*5

Boiler TPH 2 nos.*1 2 no.*3 2 no.*3

Note: 0.8x3 TPH and 1x2 TPH will not be installed and changed to 5TPH and 2x3TPH 9 DG set kVA - 2 no.* 500 2 no.* 500

10 Source of water - Maharashtra Industrial Development Corporation (MIDC) 11 Total water KLD 391.26 213.8 605 demand 12 Fresh water KLD 178.67 198.33 377 demand 13 Treated water KLD - 228 228 reuse 14 Waste water KLD - 264 264 generation 15 ETP KLD 240 10 250

16 RO KLD - 250 250 17 MEE KLD 120 80 200 18 Municipal solid kg/day - 165 165 waste generation 19 ETP Sludge TPA - 145 145 20 MEE Salt TPA - 6059 6059 21 Boiler Ash TPA - 766.5 766.5

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 8 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 2. INTRODUCTION TO THE PROJECT 2.1. Introduction of Project and Project Proponent

The proposed project “Expansion of Chemical and Agro Chemical Intermediates Manufacturing Unit” located at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra will be developed by M/s Anshul Innovative Chemistry Private Limited It is located at Latitude: 18°25'28.87"N and Longitude: 73° 9'4.39"E. The elevation of the site is about m with respect to mean sea level.

Total Capacity: 33,267 TPA

Name of the: Applicant: Mr. Shirish Ramchandra Satpute

Address: Plot no. 21/2, Dhatav MIDC , Roha, Raigad.

Contact No: 02194 263581

E-Mail: [email protected] 2.2. Brief description and nature of the project

The proposal for expansion of an already secured EC project on account of the proposed enhanced production capacity of already secured clearance. The project envisages huge market demand and hence proposes change in planning with an increase in manufacturing of Chemical and Agro Chemical Intermediates Unit increasing production capacity from 5,825 TPA to 33,267 TPA.

The project is involved in the of Manufacturing of Chemical and Agro Chemical Intermediates Unit which is covered under Category ‘A’ of 5 (b) the proposal will be considered at the central level, category ‘A’ in Schedule 5(b) & 5 (f) of the EIA Notifcation 2006 and its subsequent amendment.and will be appraised by Industry 3- EAC at MoEF&CC. 2.3. Need for the project and its importance to the country and or region

Chemical synthesis is the process of creating a desired substance by means of one or more controlled chemical reactions. The products of the synthetic organic chemicals (SOC) sector represent the penultimate goal of much of the chemical

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 9 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. industry— the manufacture of chemicals tailored such that they are directly useful to the fnal customer (in contrast to the inorganic chemicals and petrochemicals sectors, which mostly produce intermediate materials). The industrial sequence involved and the connections between this sector and those of the inorganic minerals and chemicals sector and the petrochemical sector are obvious. The diversity of the synthetic organic chemical sector may be appreciated by listing some of its sub sectors, though even this list is far from exhaustive: Pharmaceuticals Flavors and perfumes Soaps and detergents Biocides (Pesticides, herbicides, fungicides) Adhesives Dyes Paints and coatings Biotechnology products. Isatoic Anhydrides (IA) as a starting material for heterocyclic compounds. Other felds of application are not included: for example, reactions leading to open-chain anthranilic acid derivatives, use in the manufacture of agricultural chemicals, dyes, pigments, cross-linking agents and chain stoppers in resins and other uses in polymer and rubber chemistry, use as a modifer in protein and carbohydrate substrates (wool, paper, textiles), use as a petroleum additive (fuel and lubricants), use as a blowing agent for polymer foams, a fameproofng agent, and a corrosion inhibitor, use in metal fnishing, for foods and beverages, soaps and detergents, perfumes, cosmetics, and use in pharmaceuticals and medicines.

Table 2. Use of Product and by product Products/By-Product Name End Use of the Product

Isatoic Anhydride Flavors, Fragrance, Pharmaceutical Intermediates, Chemical intermediates , Bird Repellent

Anthranilic acid Mainly in Fragrance

Methyl Anthranilate Flavour & Fragrances

Dimethyl anthranilate Flavour & Fragrances

Butyl Anthranilate Paints and dyes

Anthranilamide Dyes, Chemical intermediates

Dibromoester Fragrances

Oxalyl chloride Pharma Intermediates

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 10 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Chloromethyl isopropyl carbonate Pharma Intermediates

Methyl Oxalyl Chloride MOC Pharma Intermediates

2-Chloroacetamide 2CAA Pharma Intermediates

2-[N-(2-Aminobenzoyl)]-amino Pharma Intermediates benzoic acid(AAS)

Trichloroacetamide (TCA) Pharma Intermediates

Hexabromobenzene (HBB) Pharma Intermediates

2[2-(Hydroxy benzoyl) amino] Pharma Intermediates benzoic acid (HBAB)

Naphthalene 2-Sulfonyl chloride Pharma Intermediates (NSCl)

3,5-Xylenol Pharma Intermediates p-Chlorometaxylenol (PCMX) Pharma Intermediates

Tetramethyl bisphenol-F (TMBP-F) Pharma Intermediates

2-Cyanoaniline Agrochemical

HCL (min 30 %) Industrial chemicals

Dimethyl Oxalate Industrial chemicals

2.4. Demand – Supply Gap

About 75% of the total requirement of the Indian market is being imported from 10-12 countries.

2.5. Import vs. Indigenous Production

Proposed products manufacturing in the country will be very much economical compared to Imports of the same and also the export of the same will earn extra revenue generation for our county.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 11 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 2.6. Employment Generation (Direct and Indirect) due to the project

Direct and Indirect employment will be generated after the expansion of the project. During construction phase approximately 50 labourers will be required and during operation phase, total employment in the project after expansion will be around 155 nos. At present, the unit has a manpower of 105 people. The local villagers will be given employment. The details of manpower is given below:

Table 3. Details of manpower MANPOWER Existing Proposed After Expansion

Skilled employees 75 35 35

Unskilled employees 30 15 15

Total 105 50 155

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 12 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3. PROJECT DESCRIPTION 3.1. Type of Project including interlinked and independent projects, if any. Interlinked Projects: There is no interlinked project. Interdependent Projects: There is no interdependent project. 3.2. Location of the site is given below

Table 4. Location of the site Plot No Plot no. 21/2, Dhatav MIDC, Taluka Roha District Raigad State Maharashtra Toposheet No. E43H2 Elevation 9 m Latitude 18°25'28.87"N Longitude 73° 9'4.39"E

Locational advantages: The site can be assessed by an approach road named as Roha-Kolad Road located at a distance of 0.91 km North and NH-66 is at a distance of 5.82 km ENE to the project site.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 13 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 1. Satellite image of the site

Table 5. Latitude and longitude of the site Points Latitude Longitude Elevation A 18°25'30.23"N 73° 9'0.72"E 9 meter B 18°25'31.54"N 73° 9'1.27"E 9 meter C 18°25'29.67"N 73° 9'6.03"E 10 meter D 18°25'30.33"N 73° 9'6.35"E 10 meter E 18°25'29.97"N 73° 9'7.29"E 10 meter F 18°25'25.65"N 73° 9'5.28"E 9 meter G 18°25'27.28"N 73° 9'4.92"E 10 meter H 18°25'27.21"N 73° 9'2.62"E 10 meter I 18°25'29.19"N 73° 9'3.34"E 10 meter

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 14 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Plant Layout Plan

Figure 2. Plant Layout plan

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 15 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Topographical Map with 10 km buffer radius

Figure 3. Topographical map

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 16 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.2.1. Details of alternative sites considered and basis of selecting the proposed site ● No Alternative site is examined for expansion as no additional land is required for the proposed expansion. ● The unit is located in a notifed Industrial area MIDC Roha. The proposed expansion will be increasing the production capacity by installing additional equipment/machinery in the existing site only. ● The existing plant has water supply pipelines, access to road, electricity supply, drainage system. All the mentioned facilities are able to cater the proposed expansion. ● The site is well connected with roads and railway networks. The availability of transportation is as follows: Nearest Railway Station : Roha Railway Station-3.50 km NW Nearest Highway : NH 66- 5.82 km ENE Nearest Airport : Chhatrapati Shivaji Maharaj International Airport-79.41 km NNW

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 17 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.2.2. Existing Site photographs

3.3. Size or magnitude of operation

The production capacity has been proposed to increase from from 5825 TPA to 33,267 TPA

Table 6. Production details Products/ By-Product Proposed After Expansion S. No. Name Cas No. Existing (TPA) (TPA) (TPA)

A Pharma & Chemical Intermediates

1 Isatoic Anhydride 118-48-9 3,005.0 - 3,005.0

2 Anthranilic acid 118-92-3 400.0 - 400.0

3 Methyl Anthranilate 134-20-3 2,000.0 - 2,000.0

4 Dimethyl anthranilate 85-91-6 200.0 - 200.0

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 18 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

5 Butyl Anthranilate 7756-96-9 100.0 - 100.0

6 Anthranilamide 88-68-6 80.0 160.0 240.0

7 Dibromoester 105-36-2 40.0 - 40.0

8 Oxalyl chloride 79-37-8 - 2,400.0 2,400.0

Chloromethyl isopropyl 9 carbonate 35180-01-09 - 1,200.0 1,200.0

Methyl Oxalyl Chloride 10 (MOC) 5781-53-3 - 300.0 300.0

2-Chloroacetamide 11 (2CAA) 79-07-2 - 300.0 300.0

2-[N-(2-Aminobenzoyl)] -amino benzoic 2 acid(AAS) 1147-43-9 - 72.0 72.0

Trichloroacetamide 13 (TCA) 594-65-0 - 72.0 72.0

Hexabromobenzene 14 (HBB) 87-82-1 - 120.0 120.0

2[2-(Hydroxy benzoyl) amino] benzoic acid 15 (HBAB) 58574-03-01 - 60.0 60.0

Naphthalene 2-Sulfonyl 16 chloride (NSCl) 93-11-8 - 72.0 72.0

17 3,5-Xylenol 108-68-9 - 1,200.0 1,200.0

p-Chloro Meta Xylenol 18 (PCMX) 88-04-0 -- 600.0 600.0

Tetramethyl bisphenol-F 19 (TMBP-F) 5384-21-4 - 600.0 600.0

Sub Total (A) 5,825.0 7,156.0 12,981.0

B Agrochemicals

20 2-Cyanoaniline 1885-29-6 - 60.00 60.00

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 19 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Sub Total (B) - 60.00 60.00

C Industrial Chemicals

21 HCL (min 30 %) 7647-01-0 - 20,181.0 20,181.0

22 Dimethyl Oxalate 553-90-2 - 45.0 45.0

Sub Total (C) - 20,226.0 20,226.0

Total production Capacity (A+B+C) 5,825.0 27,442.0 33,267.0

3.4. Project description with process details The Company proposes to manufacture synthetic organic chemical and Agro chemical intermediate by using modern machines and equipment with emphasis on waste minimization techniques. Detailed manufacturing process along with chemical reactions & process fow diagram and material balance of each product is given below:

3.4.1. 2-Chloroacetamide (2-CAA)

Process Flow diagram

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 20 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 4. Process fow diagram-1 for Chloroacetamide (2-CAA)

Figure 5. Process fow diagram-2 for Chloroacetamide (2-CAA)

Figure 6. Process fow diagram-3 for Chloroacetamide (2-CAA) Material balance:

Table 7. Material balance for Chloroacetamide

MATERIAL BALANCE FOR 2-CHLOROACETAMIDE In put Kg Output Kg Monochloro acetic acid 1182 2-Chloroacetamide 1000

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 21 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. n-Hexane 3842 Effuent 2326 Sulfuric acid 61.25 NH3 Solution 121 Ammonia gas 223.12 Recovered methanol 418 water for NH3 gas scrubber 100 Recovered n-Hexane 3745.25 Methanol 440 Evaporation loss 119 water 2000 Distillation residue 119.12 Total 7848.37 Total 7848.37 Chemical reaction

Chemical Reaction:

Figure 7. Chemical reaction for 2-Chloroacetamide

Process Description:

Acid catalyzed esterifcation of monochloroacetic acid gives methyl chloromethyl acetate. Monochloro methyl acetate on treatment with ammonia gives 2-Chloroacetamide.

3.4.2. 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS)

Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 22 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 8. Process fow diagram-1 of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 23 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 10. Process fow diagram-2 of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) Material balance:

Table 8. Material balance of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) MATERIAL BALANCE FOR 2-[N-(2-AMINOBENZOYLl)]-AMINO BENZOIC ACID (AAS) In put Kg Output Kg Methyl anthranilate 621 AAS 1000 Water 40000 CO2 180.5 Sodium hydroxide 164 Unreacted IA 14 Isatoic anhydride 668.8 Effuent 40686.8 35% HCl solution 427.5 Total 41881.3 Total 41881.3

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 24 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Chemical reaction

Chemical Reaction:

Figure 11. Chemical reaction of 2-[N-(2-Aminobenzoyl)]-amino benzoic acid(AAS) Process Description: Base catalyzed reaction of methyl anthranilate and isatoic anhydride gives sodium salt of AAS. On acidifcation gives AAS.

3.4.3. Trichloroacetamide (TCA)

Process Flow Diagram:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 25 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 12. Process fow diagram of Trichloroacetamide (TCA) Material balance:

Table 9. Material balance of Trichloroacetamide (TCA) MATERIAL BALANCE FOR TRICHLOROACETAMIDE Input Kg Output Kg Hexachloroacetone 1650 Trichloroacetamide 1000 Chloroform 7375 Recovered chloroform 8069.07

NH3 gas 130 NH3 Solution 124.2

Water for NH3 scrubber 100 Evaporation loss 61.73 Total 9255 Total 9255

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 26 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Chemical Reaction:

Figure 13. Chemical reaction of Trichloroacetamide (TCA)

Process Description: Amidation of hexachloroacetone using ammonia gas in n-hexane as solvent gives trichloroacetamide and chloroform. Filtrate Can be used for the next batch without any purifcation. 3.4.4. Hexabromo benzene (HBB)

Process Flow Sheet

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 27 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 28 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 29 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 16. Process fow diagram of Hexabromo benzene (HBB) Material balance:

Table 10. Material balance of Hexabromo benzene (HBB)

MATERIAL BALANCE FOR HEXABROMOBENZENE In put Kg Output Kg Benzene 169.57 Hexachloro-p-xylene 1000 Tetrachloroethane 2696.2 Recovered Solvent 2561.39 Fe powder 50.87 Nitrogen gas 100

Iodine 8.4786 Recovered Br2 34.784 Bromine 2121.83 40% HBr Solution 440.23 Cl2 gas 1217.44 Acidic effuent 7250.51 Nitrogen gas 100 Basic effuent 6245.2 10% HCl solution 5739.2 Distillation residue 240 5% Sodium bicarbonate 5739.2 Loss of solvent 134.81 Water for HBr scrubber 264.135 10% hypochlorite solution 290 10% NaOH solution 240 Effuent 5789.2 Total 24086.12 Total 24086.12

Chemical Reaction:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 30 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 17. Chemical reaction of Hexabromobenzene

Process Description: Catalytic bromination of benzene using molecular bromine and Fe-powder/Iodine as catalyst gives Hexabromobenzene (HBB) and HBr as byproducts.

3.4.5. 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 31 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 32 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 33 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 20. Process fow diagram of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) Material balance:

Table 11. Material balance of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB) MATERIAL BALANCE For 2-[N-(2-HYDROXYBENZOYL)]-AMINOBENZOIC ACID (HBAB) Input Kg Output Kg Salicylic acid 920 HBAB 1000 Methyl anthranilate 1056.65 30% HCl for sale 779.6 Phosphorus trichloride 293.33 Recovered toluene 8146.64 Toluene 3468 Effuent 25600 Water for scrubber 545.73 Recovered methanol 5285 Water 23666.13 Toluene evaporation loss 106.36 Caustic lye 906.66 Methanol evaporation loss 62 Conc. HCl 853.33 Distillation residue 300.23 Toluene for purifcation 4785 Methanol for purifcation 4785 Total 41279.83 Total 41279.83

Chemical Reaction

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 34 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 21. Chemical reaction of 2[2-(Hydroxy benzoyl) amino] benzoic acid (HBAB)

Process Description:

Salicylic acid and methyl anthranilate undergo coupling reaction in presence of phosphorus trichloride to form methyl ester of HBAB. Hydrolysis of methyl ester of HBAB using caustic lye gives crude 2-[N-(2-Hydroxy Aminobenzoyl)]-aminobenzoic acid. Purifcation of crude product by toluene followed by methanol gives pure product.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 35 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.4.6. Naphthalene 2-Sulfonyl chloride (NSCl) Process Flow Sheet:

Figure 22. Process fow diagram-1 of Naphthalene 2-Sulfonyl chloride (NSCl)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 36 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 37 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 24. Process fow diagram-1 of Naphthalene 2-Sulfonyl chloride (NSCl) Material balance:

Table 12. Material balance of Naphthalene 2-Sulfonyl chloride (NSCl)

MATERIAL BALANCE For NAPHTHALENE SULFONYL CHLORIDE (NSCl)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 38 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

In put Kg Output Kg Na-2-Naphthalene sulfonate 1710 NSCl 1000

Water 17483.8 Recovered toluene + POCl3 5224 Sodium carbonate 142.5 Charcoal+ Hyfosuercel 95 Sodium chloride 925 Recovered toluene 7440 Toluene for reaction 4820 Toluene evaporation loss 150 Dimethyl formamide 24 Recovered pet ether 2600 Phosphorus oxychloride 1571.3 Pet ether evaporation loss 100 Toluene for isolation 7590 Distillation residue 300.23 Sodium bicarbonate 120 Effuent 19985 Activated charcoal 35 Distillation residue 277.37 Hyfo Supercel 50 Per ether 2700 Total 37171.6 Total 37171.6

Chemical Reaction:

Figure 25. Chemical reaction of Naphthalene 2-Sulfonyl chloride (NSCl)

Process Description:

Crude Sodium- 2-Naphthalene sulfonate purifed by base purifcation. Purifed product reacts with phosphorus oxychloride gives crude 2-Naphthalene sulfonate which is recrystallized in toluene and pet ether as solvent media gives pure product.

3.4.7. 3,5-Xylenol

Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 39 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 26. Process fow diagram of 3,5-Xylenol Material balance:

Table 13. Material balance of 3,5-Xylenol MATERIAL BALANCE FOR 3,5-XYLENOL In put Kg Output Kg Isophorone 1191 3,5-Xylenol 1000 Dimethyl carbonate 8 Distillation residue 70 Dimethyl sulphate 8 Methane gas to scrubber 137 Water for methane wet scrubber 250 Reusable water for scrubber 250 Total 1457 Total 1457

Chemical Reaction:

Figure 27. Chemical reaction of 3,5-Xylenol

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 40 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Process Description:

Demethylation of isophorone using catalytic dimethyl sulphate and dimethyl carbonate at higher temperature gives aromatized products. Crude product is purifed by distillation and gives 3,5-Xylenol. .

3.4.8. p-Chloro Meta Xylenol (PCMX) Process fow diagram

Figure 28. Process fow diagram of p-Chloro Meta Xylenol (PCMX) Material balance:

Table 14. Material balance of p-Chloro Meta Xylenol (PCMX)

MATERIAL BALANCE FOR PARACHLOROMETAXYLENOL In put Kg Output Kg 3,5-Xylenol 1090 Parachlorometaxylenol 1000

Copper chloride II 1319 Recovered HCl and CuCl2 for reuse 7120 Conc. HCl 5450 Hypochlorite solution 239 Chlorine gas 375 Distillation residue 116

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 41 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Caustic solution for free Cl2 241 Total 8475 Total 8475

Chemical Reaction:

Figure 29. Chemical reaction of p-Chloro Meta Xylenol (PCMX)

Process Description:

Chlorination of 3,5-xylenol was done using CuCl2 and Conc. HCl at refux temperature, crude product was isolated at room temperature. Crude products purifed by distillation and CuCl2 can be recovered by chlorination of CuCl solution. Recovered CuCl2 can be reused for the next cycle.

3.4.9. Tetramethyl bisphenol-F (TMBP-F) Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 42 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 30. Process fow diagram of Tetramethyl bisphenol-F (TMBP-F)

Material balance:

Table 15. Material balance of Tetramethyl bisphenol-F (TMBP-F)

MATERIAL BALANCE OF TETRAMETHYL BIPHENOL (TMBP-F) Input Kg Output Kg 2,6-Xylenol 1003.5 TMBP-F 1000 Water 3500 Effuent 3759.5 p-Formaldehyde 271 Methanol recovery 1620 Oxalic acid 50 Methanol evaporation loss 30 TBAB 15 Distillation Residue 80 Methanol 1650 Total 6489.5 Total 6489.5

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 43 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Chemical Reaction:

Figure 31. Chemical reaction of Tetramethyl bisphenol-F (TMBP-F)

Process Description:

2,5-Xylenol reacts with p-formaldehyde in presence of oxalic acid and catalytic tetra butyl ammonium bromide gives tetra methyl bis-phenol (TMBP-F) crude. Crude product is purifed by recrystallization using methanol as solvent.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 44 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.4.10. 2-Cyanoaniline Process Flow Sheet:

Figure 32. Process fow diagram of 2-Cyanoaniline Material balance:

Table 16. Material balance of 2-Cyanoaniline

MATERIAL BALANCE OF 2-CYANOANILINE In put Kg Output Kg

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 45 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Anthranilamide 1213 2-Cyanoaniline 1000

Phosphorus pentachloride 1855 Distilled POCl3 1365 Toluene 5260 Recovered toluene 5103 Water for HCl scrubber 1517.58 Toluene evaporation loss 157 30% HCl Solution 2168 Distillation residue 52.58 Total 9845.58 Total 9845.58

Chemical Reaction:

Figure 33. Chemical reaction of 2-Cyanoaniline Process Description:

Anthranilamide reacts with PCl5 converts into 2-Cyanoaniline with phosphoryloxy chloride and hydrogen chloride as side products. Purifcation of crude material in water gives 2-Cyanoaniline pure.

3.4.11. Anthranilic acid (AA)

Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 46 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 34. Process fow diagram of Anthranilic acid (AA) Material balance:

Table 17. Material balance of Anthranilic acid (AA)

MATERIAL BALANCE FOR ANTHRANILIC ACID

In put Kg Output Kg Methyl anthranilate 1160 Anthranilic acid 1000 Water 4664 Effuent 7765 Caustic lye 640

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 47 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Conc. HCl 801 Water for washing 1500 Total 8765 Total 8765

Chemical Reaction:

Figure 35. Chemical reaction of Anthranilic acid (AA)

Process Description:

Ester hydrolysis of methyl anthranilate using sodium hydroxide gives sodium salt of anthranilic acid which on acidifcation gives Anthranilic acid.

3.4.12. 3, 5-Dibromo methyl anthranilate(Dibromo MA)

Process Flow Sheet:

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 48 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Figure 36. Process fow diagram of 3, 5-Dibromo methyl anthranilate(Dibromo MA) Material balance:

Table 18. Material balance of 3, 5-Dibromo methyl anthranilate(Dibromo MA)

MATERIAL BALANCE FOR DIBROMO MA

In put Kg Out put Kg Methyl anthranilate 514.5 Dibromo MA 1000 Dichloromethane 1162 Dichloromethane recovery 1130 Hydrogen peroxide 100 Evaporation loss 32 Bromine 626.2 25% Aq. Ammonia 25

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 49 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Ammonia gas 10 Effuent 175.7 Water for NH3 scrubber 20 Distillation residue 70 Total 2432.7 Total 2432.7

Chemical Reaction:

Figure 37. Chemical reaction of 3, 5-Dibromo methyl anthranilate(Dibromo MA)

Process Description:

Free radical reaction of methyl anthranilate with molecular bromine in presence if hydrogen peroxide gives intermediate salt which is on base with ammonia gas gives dibromo methyl anthranilate.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 50 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

3.5. Summary of Material Balance

Production Proposed Qty Residue Water EXISTING CONSENTED Product Effuent Effuent Residue 300 Days S.No. of Product ton/Tonn of Input HCL MT/A PRODUCT Qty MT/A KL /Tonn KL/Day ton /Day Working MT/M prod Kg/day MT/Day

1 Isatoic Anhydride 250 3005 12.08 121.001 118.80 10.02

2 Anthranilic acid 33 400 9.998 13.331 15.75 1.33

3 Methyl Anthranilate 200 2000 6.67

4 Dimethyl anthranilate 17 200 36.840 24.560 23.68 0.67

5 Butyl Anthranilate 8 100 0.33

6 Anthranilamide 20 240 0.25 0.200 0.07 0.80

7 Dibromoester 3 40 0.233 0.031 0.13

8 Oxalyl chloride 100 1200 0.200 0.800 8,304.0 4.00 Chloromethyl isopropyl 9 30 360 0.040 0.048 1.10 carbonate 421.6 1.20

10 Methyl Oxalyl Chloride 25 300 0.065 0.065 0.28 1.00

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 51 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

MOC 2-Chloroacetamide 11 25 300 2.326 0.119 2.326 0.119 1.75 2CAA 1.00 2-[N-(2-Aminobenzoyl)]- 12 6 72 40.687 9.765 6.67 amino benzoic acid(AAS) 0.24

13 Trichloroacetamide (TCA) 6 72 124.2 29.808 0.02 0.24 Hexabromobenzene 14 10 120 19.285 0.240 7.714 0.096 2.00 (HBB) 0.40 2[2-(Hydroxy benzoyl) 15 amino] benzoic acid 5 60 25.600 0.300 5.120 0.060 4.04 (HBAB) 0.20 Naphthalene 2-Sulfonyl 16 6 72 19.985 0.578 4.796 0.139 3.50 chloride (NSCl) 0.24

17 3,5-Xylenol 100 1200 0.250 0.070 1.000 0.280 0.83 4.00 p-Chlorometaxylenol 18 50 600 0.116 0.232 (PCMX) 2.00 Tetra methyl bisphenol-F 19 50 600 3.760 0.080 7.519 0.160 5.83 (TMBP-F) 2.00

20 2-Cyanoaniline 5 60 0.053 0.000 0.25 2,168

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 52 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

21 HCL 908 10894

Total 1858 21895 295 2 227.2 2.00 184.58 10893.56

Raw material required along with estimated quantity, likely source, mode of transport of raw materials and fnished product

Raw material estimated quantity,state of raw material, source mode of transport, means of storage and maximum threshold limit as per MSIHC Rule 1989 all the details are given below in the form of table.

Table 19. Details of raw material RAW MATERIAL DETAILS, STORAGE & TRANSPORTATION DETAILS

Name of the Chemicals/ Existing Proposed After Hazardous/No State Means of No. of No. of Total product Items Consumpti Consumption Expansion n Hazardous Storage Tanks/Bags/ Days of Storage on (TPM) (TPM) Consumpti & CAS No. vessels storage capacity on (TPM) Tanks/Ba gs in kgs Phthalic 0 74 85-44-9 Solid Bag 360 30 days 9,000 anhydride 74.4 ISATOIC Urea 16.0 0 16 57-13- 6 Solid Bag 248 30 days 12,400 ANHYDRIDE

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 53 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

0 7 7782 -50-5 Gas Tonner/ 27 02 days 24,300 Chlorine 7.0 Cylinder 47% Caustic sol 50.3 0 50 1310-73-2 Liquid Tank 10 days 2,600 Water 274.8 0 275 7732-18-5 Liquid Tank on going 10% 0 124 7647-01-0 Liquid Tank 30 days 20,000 Hydrochloric acid 123.5 Chlorine Gas 19.5 0 20 7782 -50-5 Gas Tonner 27 02 days 24,300 Caustic Soda : 36.7 0 37 1310-73-2 Solid Bag 10 days 26,000 Phthalimide 35.8 0 36 85-41-6 Solid Bags 30 days 5 Caustic Soda 19.5 0 19 1310-73-2 Liquid Bags 50 50 0 18 7647-01-0 Liquid Tank 56 10 days 2,240 Anthranilic HCl 17.8 Carboy acid WATER 333.3 0 333 7732-18-5 Liquid Tank on going Isatoic 0 54 118-48-9 Solid Bags 400 30 days 10,000 anhydride 53.5 Methanol 67.5 0 68 67-56-1 Liquid Tank 30 days 10,000 METHYL ANTHRANILA Soda ash 1.0 0 1 497-19-8 Solid Bags 117 30 days 5,850 TE Water 100.0 0 100 7732-18-5 Liquid Tank on going

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 54 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Isatoic 0 15 118-48-9 Solid Bag 400 30 days 10,000 anhydride 15.3 N,N-Dimethyl 0 23 68-12-2 Liquid Drum 23 30 days 4,600 formaldehyde 22.6 Dimethyl sulfate 15.3 0 15 77-78-1 Liquid Drum 15 30 days 3,375 Soda ash 15.4 0 15 497-19-8 Solid Bags 117 30 days 5,850 DIMETHYL ANTHRANILA Water 57.0 0 57 7732-18-5 Liquid Tank on going TE Methanol 18.9 0 19 67-56-1 Liquid Tank 30 days 10,000 Isatoic 0 1 118-48-9 Solid Bags 400 30 days 10,000 Anhydride : BUTYL 0.845 1.1 ANTHRANILA Fresh Butanol : 0 3 71-36-3 Liquid Drum 28 30 days 4,620 TE 0.383 CO2 : 0.2 3.2 Isatoic 0 22 118-48-9 Solid Bags 400 30 days 10,000 anhydride 21.8 Aq. Ammonia 0 11 7664-41-7 Liquid Carboy 31 30 days 5,265 (25%) 10.5 Water 29.1 0 29 7732-18-5 Liquid Tank on going Water for 0 15 7732-18-5 Liquid Tank on going ANTHRANILA washing 15.2 MIDE Ethyl Acetate 14.8 0 15 141-78-6 Liquid Drum 11 30 days 2,310

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 55 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Methyl 0 2 134-20-3 Liquid Drum 25 30 days 5,000 Anthranilate 1.6 HBr 0.2 0 0 10035-10-6 Liquid Drum 1 30 days 200 Hydrogen 1 7722-84-1 Liquid Carboy 6 30 days 300 Dibromoester Peroxide 0.7 0 MEG 0 58.2 58 107-21-1 Liquid Tank\ 30 days 10,000 Trichloro acetyl 0 287 76-02-8 Liquid Drum 108 30 days 27,000 chloride 286.6 0 269 7782-50-5 Gas Tonner / 27 02 days 24,300 OXALYL Chlorine 268.9 Cylinder CHLORIDE Water 0 449.9 450 7732-18-5 Liquid Tank on going Methyl 0 23 79-22-1 Liquid Drum/ 112 30 days 22,462 chloroformate 22.8 Tank Chlorine gas 0 15.8 16 7782-50-5 Liquid Cylinder 27 30 days 24,300 Water 0 33.0 33 7732-18-5 Liquid Tank on going Catalyst 0 2.5 2.5 -- Solid Bags 30 days Isopropyl 0 14 67-63-0 Liquid Drum/Tan 65 30 days 10,400 alcohol 14.1 k\ 30% 0 30 7647-01-0 Liquid Tank 30 days 10,000 Chloromethyl Hydrochloric isopropyl acid 30.0 carbonate

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 56 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Water 0 18.0 18 7732-18-5 Liquid Tank on going 0 48 79-37-8 Liquid Drum / 20 30 days 5,000 Oxalyl chloride 47.9 Tank

Methyl oxalyl Methanol 0 4.0 4 67-56-1 Liquid Tank 30 days 10,000 chloride. Water 0 8.5 9 7732-18-5 Liquid Tank on going Monochloro 0 1,182 79-11-8 Liquid Drum 3 30 days 600 acetic aced 1,182.0 n-Hexane 0 3,842.0 3,842 110-54-3 Liquid Drum 5 30 days 1,000 Sulfuric acid 0 61.3 61 7664-96-9 Liquid Tank 30 days 3,870 Ammonia gas 0 223.1 223 7664-41-7 Gas Cylinder 2 30 days 50 water for NH3 0 100 7732-18-5 Liquid Tnk on going gas scrubber 100.0

2-Chloroaceta Methanol 0 440.0 440 67-56-1 Liquid Tank 30 days 10,000 mide 2CAA water 0 2,000.0 2,000 7732-18-5 Liquid Tank on going Methyl 0 3 134-20-3 Liquid Drum 20 30 days 5,000 anthranilate 3.1 Water 0 200.0 200 7732-18-5 Liquid Tank on going 2-[N-(2-Amino benzoyl)]-ami Sodium 0 1 Liquid Tank 30 days 10,000 no benzoic hydroxide 0.8 1310-73-2 acid(AAS)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 57 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Isatoic 0 3 118-48-9 Solid Bags 400 30 days 10,000 anhydride 3.3 35% HCl 0 2 7647-01-0 Liquid Tank 56 30 days 2240 solution 2.0 Hexachloroacet 0 1,650 116-16-5 Liquid Drum 25 30 days 5000 one 1,650.0 Chloroform 0 7,375.0 7,375 67-66-3 Liquid Drum 1 30 days 200 NH3 gas 0 130.0 130 7664-41-7 Gas Cylinder 1 30 days 25 Trichloroaceta Water for NH3 0 100 7732-18-5 Liquid Tank on going mide (TCA) scrubber 100.0 Benzene 0 169.6 170 71-43-2 Liquid Drum 2 30 days 600 Tetrachloroetha 0 2,696 79-34-5 Liquid Drum 2 30 days 400 ne 2,696.2 Fe powder 0 50.9 51 7439-89-6 Solid Bags 1 30 days 25 Iodine 0 8.5 8 7553-56-2 Solid Bottel 2 30 days 100 0 2,122 7726-95-6 Liquid Glass 5 30 days 500 Bromine 2,121.8 Bottle Cl2 gas 0 1,217.4 1,217 7782-50-5 Gas Cylinder 02 days Nitrogen gas 0 100.0 100 7727-37-9 Gas Cylinder 7 30 days 49 10% HCl 0 5,739 7647-01-0 Liquid Tank 30 days 2000 Hexabromobe solution 5,739.2 nzene (HBB)

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 58 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Sodium 0 5,739 497-19-8 Liquid Bags 50 30 days 250 bicarbonate 5,739.2 Water for HBr 0 264 7732-18-5 Liquid Tank on going srubber 264.1 10% NaOH 0 240 Liquid Tank 30 days 2000 solution 240.0 1310-73-2 Water for 0 5,739 7732-18-5 Liquid Tank on going washing 5,739.2 2[2-(Hydroxy Salicylic acid 0 920.0 920 69-72-7 Liquid Drum 20 30 days 5000 benzoyl) Methyl 0 1,057 134-20-3 Liquid Drum 20 30 days 5000 amino] benzoic anthranilate 1,056.7 acid (HBAB) Phosphorus 0 293 12-2-7719 Liquid Drum 150 30 days 3000 trichloride 293.3 Toluene 0 3,468.0 3,468 108-88-3 Liquid Drum 5 30 days 1000 Water for 0 546 7732-18-5 Liquid Tank\ on going scrubber 545.7 Water 0 23,666.1 23,666 7732-18-5 Liquid Tank on going Caustic lye 0 906.7 907 1310-73-2 Liquid Tank 30 days 10000 Conc. HCl 0 853.3 853 7647-01-0 Liquid Tank 30 days 5000 Methanol for 0 4,785 67-56-1 Liquid Tank 30 days 10000 purifcation 4,785.0

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 59 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Na-2-Naphthale 0 1,710 91-20-3 Solid Bags 30 days 600 ne sulfonate 1,710.0 Water 0 17,483.8 17,484 7732-18-5 Liquid Tank on going Sodium 0 143 Liquid Bags 5 30 days 250 carbonate 142.5 497-19-8 Sodium chloride 0 925.0 925 7647-14-5 Liquid Bags 6 30 days 300 Toluene for 0 4,820 108-88-3 Liquid Drum 3 30 days 600 reaction 4,820.0 Dimethyl 0 24 68-12-2 Liquid Drum 23 30 days 4600 formamide 24.0 Phosphorus 0 1,571 10025-87-3 Liquid Drum 3 30 days 600 oxychloride 1,571.3 Activated 0 35 7440-44-0 Solid Drum 10 30 days 250 Naphthalene charcoal 35.0 2-Sulfonyl chloride Hyfosupercel 0 50.0 50 61790-53-2 Solid Drum 3 30 days 60 (NSCl) Per ether 0 2,700.0 2,700 8032-32-4 Liquid Drum 3 30 days 600 Isophorone 0 1,191.0 1,191 78-59-1 Liquid Drum\ 3 30 days 600 Dimethyl 0 8 616-38-6 Liquid Drum 4 30 days 800 carbonate 8.0 Dimethyl 0 8 77-78-1 Liquid Drum 9 30 days 2000 3,5-Xylenol sulphate 8.0

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 60 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

3,5-Xylenol 0 1,090.0 1,090 108-68-9 Liquid Drum 3 30 days 600 Copper chloride 0 1,319 7758-89-6 Liquid Drum 5 30 days 100 II 1,319.0 p-Chloro Meta Xylenol Conc. HCl 0 5,450.0 5,450 7647-01-0 Liquid Drum 20 30 days 1000 (PCMX) Chlorine gas 0 375.0 375 7782-50-5 Gas Cylinder 27 02 days 24300 2,6-Xylenol 0 1,003.5 1,004 108-68-9 Liquid Drum 3 30 days 600 Water 0 3,500.0 3,500 7732-18-5 Liquid Tank\ on going p-Formaldehyd 0 271 30525-89-4 Liquid Drum 3 30 days 600 e 271.0 Oxalic acid 0 50.0 50 6153-56-6 Liquid Tank 2 30 days 500 Tetramethyl bisphenol-F TBAB 0 15.0 15 1643-19-2 Solid Bags 5 30 days 1000 (TMBP-F) Methanol 0 1,650.0 1,650 67-56-1 Liquid Tank 30 days 10000 Anthranilamide 0 1,213.0 1,213 88-68-6 Solid Drum 40 30 days 1000 Phosphorus 0 1,855 10026-13-8 Liquid Drum 25 30 days 5000 pentachloride 1,855.0 Toluene 0 5,260.0 5,260 108-88-2 Liquid Drum 5 30 days 1000 2-CYANOANIL Water for HCl 0 1,517.6 1,518 7732-18-5 Liquid Tank ON GOING INE scrubber

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 61 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.6. Plant & Machineries

Table 20. Equipment list

Equipment List Ground Floor OC Plant

S. No. Equipment Description MAKE / MOC TAG NO HP/RPM CAPACITY MOC LOCATION

1 O.C. Distillation Vessel Swiss /MSGLR V-4006 12.5 / 1440 5 KL Star Delta Ist Floor

2 Mixing Vessel for V-407 SIGL / MSGLR V-4007 1 / 1415 100 Lit DOL Ist Floor Fluorolined PVDF 3 TCAC Transfer Pump P-4001 5 / 2 900 3 m3/hr PVDF Ground Floor 40 Fluorolined PVDF 4 O.C. Mixing Pump P-4003 3 m3/hr PVDF Ground Floor 25 Fluorolined PVDF 5 O.C. Transfer Pump P-4004 5 / 2 900 3 m3/hr PVDF Ground Floor 25 6 MEG Transfer Pump Rajedia 32/160 P-4005 7.5 / 2 900 5 m3/hr PVDF Ground Floor

7 MEG Storage Tank Fabricraft ST-4001 23 Kl PVDF Ground Floor

8 TCAC Storage Tank Nile Ind. ST-4002 8 Kl MSGL Ground Floor

9 O.C. Storage Tank Swiss Glascoat ST-4009 10 KL MS GL Ground Floor OC P Tank Vent Gas Bubbler 10 Goel Process B-4010 Double Stage Glass Ground Floor 100 DN

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 62 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

11 Chilling Water Storage Tank ST-4030 10KL MS Ground Floor

12 Chilling Pump P-4028 2 /1400 3 m3/hr CI Ground Floor

13 Chilling Pump P-4029 2 /1400 3 m3/hr CI Ground Floor

14 Chilling Pump P-4030 1.5 / 1500 2 m3/hr CI Ground Floor

15 Chilling Pump P-4031 1.5 / 1501 2 m3/hr CI Ground Floor 16 Chilling Condenser HE-4037 5 m2 Glass Ground Floor 17 Vent Gas Bubbler B-4009 Double Stage Glass Ground Floor 18 Material Lift HE-2001 1 Ton MS Ground Floor

Equipment List First Floor OC Plant Sr.No. Equipment Description MAKE / MOC TAG NO - HP/RPM CAPACITY MOC LOCATION

19 O.C. Distillation Vessel Swiss /MSGLR R-4002 12.5 / 1440 5 KL MSGL Ist Floor

20 TCAC Distillation Vessel Nile Ind./ MSGLR R-4003 5 / 1440 5 KL MSGL Ist Floor P.G . Distillation Vessel of 21 Nile Ind / MSGLR R-4004 3 / 1440 1 KL MSGL Ist Floor Purifcation 22 TCAC Distillation Vessel Nile Ind./ MSGLR R-7001 5 / 1440 3KL MSGL Ist Floor

23 TCAC Distillation Vessel Nile Ind./ MSGLR R-7002 5 / 1440 3 KL MSGL Ist Floor

Equipment List Second Floor OC Plant

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 63 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Sr.No. Equipment Description MAKE / MOC TAG NO - HP/RPM CAPACITY MOC LOCATION Oil Hot Well Tank Pump Chilling 24 KSB / C.I. P-4028 10 / 1450 144 m3/hr Star Delta IInd Floor Water Oil Cold Well Tank Pump 25 KSB / C.I. P-4029 10 / 1450 144 m3/hr Star Delta IInd Floor Chilling Water 26 PHE Cooling Tower Water Basin Merline/MS ST-4025 9 Kl II Floor

27 OIL Storage Tank Shree Fab ST-4030 6 kl MS II Floor Chlorination Column No.01 300 28 Goel Process C-4001 400 Lit Glass I To II Floor DN Chlorination Column No.02 300 29 Goel Process C-4002 400 Lit Glass Ist To IInd Floor DN Chlorination Column No.03 300 30 Goel Process C-4003 400 Lit Glass Ist To IInd Floor DN Chlorination Column No.04 400 31 Goel Process C-4004 400 Lit Glass Ist To IInd Floor DN Chlorination Column No.05 400 32 Goel Process C-4005 400 Lit Glass Ist To IInd Floor DN Chlorination Column No.06 300 33 Goel Process C-4006 400 Lit Glass Ist To IInd Floor DN

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 64 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

V-402 Vessel Distillation 34 Goel Process C-4007 400 Lit Glass Ist To IIIrd Floor Column 400 DN x 7 Mtr V-403 Vessel Distillation 35 Goel Process C-4008 400 Lit Glass Ist To IIIrd Floor Column 300 DN x 7 Mtr V-407 Vessel Distillation 36 Goel Process C-4011 Glass Ist To IIIrd Floor Column 400 DN X 7 Mtr V-4002 Vessel Distillation 37 Goel Process GH-4001 100 Lit Glass IInd Floor Column Handi No.01 V-4002 Vessel Distillation 38 Goel Process GH-4002 100 Lit Glass IInd Floor Column Handi No.02 V-4003 Vessel Distillation 39 Goel Process GH-4003 50 Lit Glass IInd Floor Column Handi No.01 V-4003 Vessel Distillation 40 Goel Process GH-4004 50 Lit Glass IInd Floor Column Handi No.02 41 V-4001 “U” Seal Drain Handi Goel Process GH-4006 50 Lit Glass IIIrd Floor V-407 Vessel Distillation 42 Goel Process GH-4007 100 Lit Glass IInd Floor Column Handi No.01 V-407 Vessel Distillation 43 Goel Process GH-4008 100 Lit Glass IInd Floor Column Handi No.02 C-4001 Chlorination Column 43 Goel Process HE-4008 2.5 m2 Glass IInd Floor Condenser No.1 225 DN

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 65 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

C-4001 Chlorination Column 44 Goel Process HE-4009 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4002 Chlorination Column 45 Goel Process HE-4010 2.5 m2 Glass IInd Floor Condenser No.1 225 DN C-4002 Chlorination Column 46 Goel Process HE-4011 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4003 Chlorination Column 47 Goel Process HE-4012 2.5 m2 Glass IInd Floor Condenser No.1 225 DN C-4003 Chlorination Column 48 Goel Process HE-4013 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4004 Chlorination Column 49 Goel Process HE-4014 2.5 m2 Glass IInd Floor Condenser No.1 225 DN C-4004 Chlorination Column 50 Goel Process HE-4015 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4005 Chlorination Column 51 Goel Process HE-4016 2.5 m2 Glass IInd Floor Condenser No.1 225 DN C-4005 Chlorination Column 52 Goel Process HE-4017 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4006 Chlorination Column 53 Goel Process HE-4018 2.5 m2 Glass IInd Floor Condenser No.1 225 DN

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 66 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

C-4006 Chlorination Column 54 Goel Process HE-4019 2.5 m2 Glass IInd Floor Condenser No.2 225 DN C-4001 Column Chlorine Gas 55 Goel Process B-4018 Single Stage Glass IInd Floor Bubbler 100 DN C-4002 Column Chlorine Gas 56 Goel Process B-4019 Single Stage Glass IInd Floor Bubbler 100 DN C-4003 Column Chlorine Gas 57 Goel Process B-4020 Single Stage Glass IInd Floor Bubbler 100 DN C-4004 Column Chlorine Gas 58 Goel Process B-4021 Single Stage Glass IInd Floor Bubbler 100 DN C-4005 Column Chlorine Gas 59 Goel Process B-4022 Single Stage Glass IInd Floor Bubbler 100 DN C-4006 Column Chlorine Gas 60 Goel Process B-4023 Single Stage Glass IInd Floor Bubbler 100 DN Chlorination Column No.01 400 61 C-7001 400 Lit Glass IInd Floor DN Chlorination Column No.01 400 62 C-7002 400 Lit Glass IInd Floor DN 63 Distillation Column Handi No.01 GH-7001 100 Lit Glass IInd Floor

64 Distillation Column Handi No.02 GH-7002 100 Lit Glass IInd Floor

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 67 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

65 Distillation Column Handi No.03 GH-7003 100 Lit Glass IInd Floor

66 Distillation Column Handi No.04 GH-7004 100 Lit Glass IInd Floor

Equipment List Third Floor OC Plant Sr.No. Equipment Description MAKE / MOC TAG NO - HP/RPM CAPACITY MOC LOCATION Oil Hot Well Tank Pump Cooling 67 Johnson / CI P-4030 10 / 1450 108 m3/hr Star Delta IIIrd Floor Water Oil Cold Well Tank Pump 68 Johnson / CI P-4031 10 / 1450 108 m3/hr Star Delta IIIrd Floor Cooling Water V-4002 Vessel Column 69 Goel Process HE-4020 4 m2 Glass IIIrd Floor Condenser No.01 300 DN V-4002 Vessel Column 70 Goel Process HE-4027 4 m2 Glass IIIrd Floor Condenser No.06 300 DN V-4003 Vessel Column 71 Goel Process HE-4028 2.5 m2 Glass IIIrd Floor Condenser No.01 225 DN V-4003 Vessel Column 72 Goel Process HE-4030 2.5 m2 Glass IIIrd Floor Condenser No.03 225 DN V-4003 Vessel Column Product 73 Goel Process HE-4033 1 m2 Glass IInd Floor Cooler No.02 150 DN Therminol Oil PHE Of Cooling 74 Kelrion India Pvt HE-4038 SS-3604 IIIrd Floor Water

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 68 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

V-407 Vessel Column 75 Goel Process HE-4040 4 m2 Glass IIIrd Floor Condenser No.01 300 DN V-407 Vessel Column 76 Goel Process HE-4041 4 m2 Glass IIIrd Floor Condenser No.02 300 DN V-407 Vessel Column 77 Goel Process HE-4042 4 m2 Glass IIIrd Floor Condenser No.03 300 DN V-407 Vessel Column 78 Goel Process HE-4043 4 m2 Glass IIIrd Floor Condenser No.04 300 DN V-407 Vessel Column 79 Goel Process HE-4044 4 m2 Glass IIIrd Floor Condenser No.05 300 DN V-407 Vessel Column 80 Goel Process HE-4045 4 m2 Glass IIIrd Floor Condenser No.06 300 DN V-407 Vessel Column Product 81 Goel Process HE-4046 1 m2 Glass IInd Floor Cooler No.01 150 DN V-407 Vessel Column Product 82 Goel Process HE-4047 1 m2 Glass IInd Floor Cooler No.02 150 DN V-4001 Vessel Vent Gas 83 Goel Process B-4001 Double Stage Glass IIIrd Floor Bubbler 150 DN C-4001 & C-4002 Column Vent 84 Goel Process B-4002 Double Stage Glass IIIrd Floor Gas Bubbler 150 DN

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 69 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

C-4003 & C-4004 Column Vent 85 Goel Process B-4003 Double Stage Glass IIIrd Floor Gas Bubbler 150 DN C-4005 & C-4006 Column Vent 86 Goel Process B-4004 Double Stage Glass IIIrd Floor Gas Bubbler 150 DN V-4002 Vessel Vent Gas 87 Goel Process B-4005 Double Stage Glass IIIrd Floor Bubbler 150 DN V-4003 Vessel Vent Gas 88 Goel Process B-4006 Double Stage Glass IIIrd Floor Bubbler 100 DN V-4004 Vessel Vent Gas 89 Goel Process B-4007 Double Stage Glass IIIrd Floor Bubbler 150 DN Batch Tank(OC,IF, Catalyst, 90 Goel Process B-4008 Double Stage Glass IIIrd Floor OCR) Gas Bubbler 100 DN TCAC Storage Tank Vent Gas 91 Goel Process B-4009 Double Stage Glass IIIrd Floor Bubbler 100 DN

Equipment List Third Floor Mezzanine OC Plant Sr.No. Equipment Description MAKE / MOC TAG NO - HP/RPM CAPACITY MOC LOCATION

92 DistillationVessel R-4001 12.5 / 1440 5 KL MSGL Mezz. Floor

93 Distillation Column Handi No.06 GH-4006 100 Lit Glass Mezz. Floor

94 Vent Gas Bubbler 150DN B-4009 Double Stage Glass Mezz. Floor

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 70 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

95 MEG Batch Tank Ornat ST-4010 1 Kl HDPE Mezz. Floor

96 TCAC Batch Tank Sachin Industry ST-4011 4 Kl MSGL Mezz. Floor

Table 21. Details of plant & Machinery Ground Floor IA plant

Sr. No. Equipment Name MOC Tag . No CAP. In kl Diameter in MM Height in MM Location

1 Sigma Mixer SS316 R- 1001 1 1150*1150*1150 Ground Floor

2 Scrubber Tank CS T-1001 2 2000 800 Ground Floor

3 Mist eliminator Housing CS T-1002 0.75 800 1500 Ground Floor

4 Scrubber Column CS T-1003 2.8 1200 3000 Ground Floor

5 Hypo Reaction Batch Vessel HDPE V -1004 3 1400 2000 Ground Floor

6 Hypo Reaction Batch Vessel 2 HDPE V- 1005 3 1400 2000 Ground Floor

7 Sodium Hypochlorite Vessel 3 HDPE V - 1006 3 1400 2000 Ground Floor

8 Sewage underground Tank RCC T - 1004 10 3000 3000 Underground

9 Centrifuge -1 SS304 CF - 1001 0.2 1219.19 Ground Floor

10 Centrifuge -2 SS304 CF - 1002 0.2 1219.19 Ground Floor

11 Centrifuge -3 SS304 CF - 1003 0.2 1219.19 Ground Floor

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 71 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

12 Centrifuge -4 SS304 CF - 1004 0.2 1219.19 Ground Floor

13 Tray Drier SS304 D - 1001 0.4 2950 1880 Ground Floor

14 Rotary Vacuum Paddle Dryer SS316 D - 1002 3 1150 ID 4193 Ground Floor

15 Tray Drier SS304 D - 1003 0.4 2950 1880 Ground Floor Sodium Hypochlorite Column 16 Glass C - 1001 150 6000 Ground Floor No.1 Sodium Hypochlorite Column 17 Glass C - 1002 150 6000 Ground Floor No.2 18 HCL Tank Vent Column Glass C - 1003 150 1000 Ground Floor

19 Sigma Scrubber Pump SS316 P-1001 30 1100 200 Ground Floor

20 Hypo Reaction Pump PVDF25 P1002A 3 1100 200 Ground Floor

21 Hypo Reaction Pump PVDF25 P-1002B 3 1100 200 Ground Floor

22 Hypo Reaction Pump PVDF25 P-1003 3 1100 200 Ground Floor Sodium phthalimide Transfer 23 SS316 P-1004 10 1100 200 Ground Floor pump 24 Dilution Mass Transfer Pump SS316 P-1005A 3 1100 200 Ground Floor

25 Dilution Mass Transfer Pump PVDF26 P-1005B 3 1100 200 Ground Floor

26 Neutralization Phthalimide Pump SS316 P-1006A 3 1100 200 Ground Floor

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 72 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

A Neutralization Phthalimide Pump 27 SS316 P-1006B 3 1100 200 Ground Floor A 28 Washing Vessel transfer Pump PVDF25 P-1007 3 1100 200 Ground Floor

29 ETP Submerge Pump Kirloskar CI P-1008A 3 1100 200 Ground Floor 30 ETP Centrifugal Pump CI P-1008B 10 1100 200 Ground Floor 31 Vacuum Pump (RVPD) P - 1009 3 1100 200 Ground Floor

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 73 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 3.7. Resources optimization/ recycling and reuse envisaged in the project

● Water used for cooling is being partially subjected to evaporation and bleed-off and partially recirculated. ● Boiler ash is given to the cement and brick manufacturing Unit. ● Non-Biodegradable waste and E-waste will be given to approved authorised recyclers. ● The discarded raw material containers & bags will be given to approved authorised recyclers. ● Use of mechanical seals and better control for storage of chemicals. ● Solvent Recovery Unit 3.8. Availability of water it’s source, Energy /power requirement and source

(a) Water Requirement and Source Total water Requirement After Expansion:- 605 KLD Fresh water requirement: 377 KLD Source of water: MIDC water supply.

Table 22. water requirement Particulars Water Requirement (KLD) Domestic 20 Industrial Process 219 Cooling Tower & Boiler 353 Gardening 13 Total 605

Waste water generation:-

Table 23. Wastewater generation Particulars Wastewater Generation (KLD) Domestic 16 Industrial Process 219

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 74 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Cooling Tower & Boiler 29 Gardening Nil Total 264

Water Balance after Expansion:

Figure 38. Water Balance

(b) Scheme Of Water Treatment

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 75 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Table 24. Characteristics of wastewater and treated water CHARACTERISTICS OF WASTEWATER & TREATED WATER

Parameter Unit Waste primary primar Biologi Biolog After Inlet RO RO MEE MEE Out s Water Input y cal ical Tertiary to Perm Rejec In stream i.e. Output Second Secon Treatm RO eate t

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 76 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

ETP Inlet ary dary ent in Input Outpu ETP t

Flow m3/ day 265 173 173 189 189 189 189 114 75 150 132 pH ---- 6-7 6-7 6-7 6-7 6-7 6-7 6-7 6-7 6-7 6-7 6-7

COD mg/L 1200 10000- 7000- 4000- 4000- 700- 400-50 400- -150 1200- 11000 8000 5000 5000 800 0 500 <50 0 1500 30-35

BOD mg/L 2200-250 1300- 1300-1 200-2 150-16 150- 400- 400-5 3500-4000 0 1500 500 50 0 160 <20 500 00 <10

TDS mg/L 30000 30000 3000 4500 45000 30000- 30000- -3500 30000- -3500 30000- 0-35 0-50 -5000 35000 35000 0 35000 0 35000 000 1000 000 0 <50

TSS mg/L 1500-200 1000- 600-80 150-2 1500-2000 0 1200 0 00 <100 <100 <10 <100 <100 <20

Pesticides mg/L Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil

3.9. Power Requirement and Source

Source of Power: Maharashtra State Electricity Distribution Company Limited (MSEDCL). During Construction Phase: DG Sets from the existing power plant will be used for the construction works. Total after Expansion:- The Power requirement of the project will be increased from 577 kVA to 2000 kVA to be met from MSEDCL. In case of power failure, power backup will be provided through DG sets of capacities of 2x500 KVA will be enclosed at the surface. 3.10. Air Emissions and Control

The main sources of air emission from the facility area the following- ● Combustion of fossil fuels from sources like Wood based Boiler (2 TPH & 2*3 TPH), HSD based 2 no. of generators (500 kVA) ● Production process from sources like processes in plants like HCl and Bromine. APCS like wet scrubber with caustic Solution with adequate stack height of 15 m will be there.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 77 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Table 25. Emission from utility EMISSIONS FROM UTILITIES

Source Type of Fuel APCS Stack Height (m)

DG SET-2* 500 kVA HSD Acoustic enclosure 10

Boiler -5 TPH Coal multi cyclone dust collector 30

Boiler : 2*3 TPH Coal multi cyclone dust collector 30 Thermic fuid heater coal Stack, ESP 20 THF cap 2 Lac Kcal/hr

Emission from Process Table 26. Emission from process Sr. No Name of Stack Location Pollution Height in Stack dia Cross Sec Parameter Control Mtr area Measure

3 1 S-01 IA Plant Packed column, 18 300 NB 5000 m /hr CO2 IA Plant Sigma Sigma Venturi scrubber with blower Scrubbing media- Caustic water

2 S --02 OC Falling flm 5 100 NB 16 m2/hr HCl, Cl OC Plant Caustic Scrubber Scrubber Scrubbing media- caustic water

3 S-03 CMIC Falling flm 3 80 NB 16 m2/hr HCl, Cl CMIC Plant Caustic Scrubber Scrubber Scrubbing media- Caustic water

4 S-04 OC/ CMIC Venturi 25 600 mm 12750 HCl, Cl Emergency Plant scrubber with m3/hr

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 78 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Scrubber Emergenc blower y Scrubber

5 S-05 Chlorine Venturi 20 600 mm 6000 m3/hr Cl Chlorine Eme Vaporizer scrubber with System Emergenc blower y Scrubber

3.10.1. Odour Control

● All reactors vents are equipped with condensers to trap emissions ● All reactors / storage tanks are connected with scrubbers. Reactor agitator and scrubber blower are interlocked to ensure scrubber running during manufacturing activity. Scrubber liquid is sent to ETP for treatment and scrubbed air let out through a tall stack for effective dispersion. ● Chemicals are transferred in a closed system from bulk tanks to avoid fugitive emissions. ● Chemicals from drums are transferred inside the toxic cabin which is connected with the scrubber. Respirator is used by the operator during transfer to avoid odour nuisance. 3.11. Waste Management

3.11.1. Domestic Solid Waste

Table 27. Solid waste management SOLID WASTE MANAGEMENT

Category Type of Waste After Expansion Treatment Method (Kg/day)

Biodegradable Organic Waste 66 Treated in proposed OWC

Non-Biodegradable Recyclable Waste (Plastic, 99 Sold to Authorised

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 79 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

paper, wood, glass, etc) Recycler

Total 165

3.11.2. Process Waste (Non-Hazardous)

Table 28. Non- Hazardous waste management NON-HAZARDOUS WASTE MANAGEMENT (PROCESS)

Process Waste Unit Total after Treatment expansion /Disposal

Boiler Ash TPA 766.5 Brick manufacturing

Plastic waste TPA 1.2 Sale to authorised party for recycle

wooden pallets Nos / Annum 50.0 Sale to authorised party for recycle

SCRAP M/S TPA 500 Sale to authorised party for recycle

3.11.3. Hazardous Waste Management

Table 29. Hazardous waste management HAZARDOUS WASTE MANAGEMENT (PROCESS)

S.No. Waste Category Unit Total after Disposal expansion 1 Chemical sludge from wastewater treatment (ETP Sludge 35.3 TPA 145 Landfll at CHWTSDF 2 Concentration or evaporated residue Sale to authorized party// (MEE Salt ) 37.3 TPA 6059 CHWTSDF 3 Empty barrels / Containers /liners Sale to authorized contaminated with reconditioner / hazardous 33.1 Nos./Y 20000 CHWTSDF

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 80 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

chemicals / waste

4 Sale to authorized party// Used or spent Oil 5.1 Ltr/Annum 500 CHWTSDF

5 Process Residue Recycled/reused in the and waste process /Sale to authorized (Recovered party// CHWTSDF Methanol) 28.1 TPA 673.55

6 Sale to authorized party// Distillation residue 20.3 TPA 1068 CHWTSDF

7 Process Residue Recycled/reused in the and waste process /Sale to authorized (Recovered party// CHWTSDF Butanol) 28.1 TPA 36.6 *Any byproduct/process waste if consumed internally in the unit Rule- 9 of Hazardous and other wastes (Management & Transboundary Movement) Rules, 2016 shall be followed and necessary permission will be taken. record will be maintained for all the hazardous waste including the quantity of its generation and disposal to designated sites. E-Waste whenever generated will be managed as per E-Waste Management Rules, 2016. 4. SITE ANALYSIS 4.1. Connectivity

The site can be accessed from an adjacent road named as Roha Kolad road (0.9Km) in the north direction . The nearest Railway Station is Roha railway station (3.50 Km NW) and nearest Airport is Chhatrapati Shivaji Maharaj International Airport Mumbai (7.41 Km NNW) 4.2. Social Infrastructure around the Project Site

Table 30. Social infrastructure around the site

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 81 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Particulars Distance Direction Hospital Dr. Dhruv Nursing Home- Amrita Nursing Home, 2.70 Km NWN Varse, Bhuwaneshwar, Maharashtra Jadhav Hospital- Wali, Tala, Maharashtra 3.07 Km NWN Dr.Bhat Nursing Home-Opp Panchayat Samiti, 3.28 Km WNW Bhuwaneshwar,Roha, Maharashtra Post Offce 0.91 Km NNW Roha A V Sub Post Offce-Roha, B K Maharashtra Varse Post Offce- Varse, Bhuwaneshwar, 2.39 Km NNW Maharashtra Post Offce Roha-Wali, Tala,Maharashtra 3.69 Km NNW Place of Worship Kale Datta Mandir-Brahmin Ali, Wali,Roha 3.76 Km NNW Maharashtra Shree Datt Mandir Roha- Chhatrapati Shivaji Maharaj 3.76 Km NNW Marg, Roha Maharashtra 3.86 Km NNW Shree Omkareshwar Mandir, Wali, Roha Maharashtra School 0.91 Km NNE Dhatav School Roha,Kolad Road, Roha, Maharashtra J M Rathi English School, (Pre Primary),Roha Khurd, 1.88 Km NNW Roha, Ashtami Maharashtra

J M Rathi School, Roth Khurd, Roha, Maharashtra 2.09 Km NNW

Bank Bank of Maharashtra- Roha Industrial Estate,CFC 0.94 Km S Building,MDC Estate, Dhatav, Maharashtra

Bank of India, MIDC, Common Facility Centre At & 1.23 Km SSE Post, Dhatav, Roha Maharashtra IDBI Bank Roha, Tala, Wali Tala, Maharashtra 2.90 Km NNW

List of Industries within 5 Km of the project site Table 31. List of Industries

S. No Name of industry Distance from the project site

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 82 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

1 Anshul Speciality Molecules Private Limited 0.5 km

2 Excel Industries Limited 0.3 km

3 Calchem Industries Limited 0.2 km

4 Deepak Nitrite Limited 0.4 km

5 Sudarshan Chemicals 1 km

II. Landform, Land use and Land ownership The land of total area 15,703 m2 has been allotted by MIDC to the M/s Anshul Innovative Chemistry Private Limited. The plant site is located at Plot No. 21/2, Roha MIDC, Taluka Roha, District- Raigad Maharashtra.. The plant site is a fat land and land use surrounding the project site mainly comprises industrial use as it is located within the notifed industrial area of MIDC Roha. 4.3. Topography

The topography of the area is fat. The drainage follows a typical dendritic and mixed pattern in this area. The Topographical Map is already attached in the Report and annexure. 4.4. Existing land use pattern

The existing Land use is Industrial use, located in Notifed Industrial area Plot No. 21/2, Roha MIDC, Taluka Roha, District- Raigad Maharashtra.

Land Use Distribution of project after expansion

Table 32. Area breakup details AREA DISTRIBUTION DETAILS

Particulars Total area after % Area expansion in sqm

Ground Coverage 4218 26.9

Green Belt & Plantation Area 5182 33

Parking Area 1885 12

Road & Open area 4419 28.1

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 83 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

Total Plot area 15,703 100.0

Land Use Map Distribution of project after expansion

Figure 39. Land use Map

4.5. Existing Infrastructure

Total plant area is 15,703 m2 with an existing built up area of 2355.17 m2 . The site is well connected by Roha kolad road (0.9km) in the north direction from the project site. Hospitals, post offces, and banks are available within 3 km from the project site. 4.6. Soil classifcation

Laterite soil is found in the Ratnagiri, Sindhudurg and Raigad regions of South Konkan, Kolhapur area in the Western Maharashtra and at the top of Sahyadri mountain locale. The soil in the districts are formed from the deccan trap which is predominating rock formation with small out-crops of laterite at a few places in the poladpur taluka and matheran hill.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 84 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 4.7. Climatic data from secondary sources

4.7.1. Climatic Conditions (As per the Indian Meteorological Data-Station Mumbai Airport)

The Important parameters considered are temperature, Humidity, Wind Speed, Wind Direction and Rainfall. The extract of Maximum, Minimum values (month wise) of above said parameters from Indian Meteorological data station, Mumbai Airport (2003 - 2015) are given Below in the tables: 4.7.2. Temperature

The Maximum temperature of the area in twelve Years, was recorded as 39.5 in March 2007 and November 2015, whereas the minimum temperature of the area was recorded as 11.8 in February 2008. Data of the maximum and minimum temperature are given below.

Table 33. Temperature Month Year Hmax Year Lmin Year Mmax Year Mmin

Jan 2009 36.3 2012 12.5 2009 32 2008 18.1

February 2015 37.2 2008 11.8 2006 32.5 2008 17.5

March 2007 39.5 2012 18.0 2004 32.9 2012 21.9

April 2009 37.3 2008 21.8 2009 34.2 2008 24.6

May 2004 38.7 2006 24.1 2015 35.0 2005, 2009 26.7

June 2009 36.1 2004 21.8 2009 33.8 2008 25.5

July 2014 34.0 2006 22.0 2012 30.7 2008 24.7

August 2013 32.7 2008 22.4 2009 31.2 2008 24.0

September 2014 35.0 2013 21.8 2009 31.1 2008 24.1

October 2009 37.3 2014 21.0 2008 34.1 2008 24.0

November 2015 39.5 2012 19.2 2006 ,2014 34.1 2005 22.0

December 2008 36.7 2005 15.7 2008 33.0 2005 19.8

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 85 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

H max-Highest maximum, L min-Lowest minimum, M max- Mean max, L min-Lowest min, (Source: IMD, Station –Mumbai from 2004 -2015)

(Source: IMD, Station –Mumbai 2004 -2015) H max- Highest max, L min- Lowest min, Mmax- Mean max., M min- Mean min.

4.7.3. Relative Humidity

From the data, the Maximum relative humidity was recorded as 96 % in July, August, September 2014. Minimum relative humidity was recorded as 53 % in December 2004 and January 2005. The humidity fgures show that the area is humid.

Table 34. Relative humidity Month Year Max Year Min January 2013 84 2005 53 February 2009 85 2008 54 March 2005 85 2004 60 April 2014 88 2008 60 May 2014 87 2008 64 June 2013 91 2009 74 July 2014 96 2015 85

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 86 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

August 2014 96 2009 80 September 2014 96 2015 71 October 2013 90 2004 63 November 2009 85 2004 60 December 2009 84 2004 53

(SOURCE: IMD, STATION –Mumbai 2004 -2015)

Figure 40. Maximum Humidity in %

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 87 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 4.7.4. Rainfall

The maximum rainfall was recorded in July (upto 1356.9 mm) in 2014. From data, it is clear that the maximum time of year remains moist, the wet months exceed dry months. July, August & September are the wettest months and are considered as the monsoon season. Average Annual rainfall is 2182.9 mm.

Table 35. Rainfall data Month Year Rf Year Rf Average Max (mm) Min Rainfall (mm) (mm) Jan 2014 0.9 2005 0.6 0.2 Feb 2014 7.8 2007 4.0 1.2 March 2015 12.2 2006 7.3 2 April 2015 1.4 2004-2014 0.0 0.1 May 2006 128.0 2007 0.7 16.4 June 2013 1282.5 2014 55.0 542.1 July 2014 1356.9 2015 278.2 742.2 Aug 2004 786.9 2015 156.2 432.3 Sep 2005 593.3 2006 184.0 346.4 Oct 2006 246.0 2008 1.0 80.6 Nov 2009 120.2 2015 1.7 15.6 Dec 2014 30.0 2008 0.3 3.8 (Source: IMD, Station –Mumbai 2004 -2015)

4.8. Social Infrastructure available

All necessary infrastructure such as transport facilities, electricity, water supply exists near to the project site as it is located within the MIDC Roha, industrial area. 5. PLANNING BRIEF

I. Planning Concept (type of industries, facilities, transportation etc.) Town and country Planning/ Development authority Classifcation. Proposed expansion envisages augmenting plant machinery and minimum expansion of buildings to accommodate the augmented machineries (@500 m2), thus total built-up area will increase to 9454.03 m² Transportation of raw

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 88 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. material and fnal product is being carried out utilising existing road and rail networks which will be adequate to meet the increased raw material demand and increased product delivery after expansion as well.

II. Population Projection Currently 105 people are working in the industry and after expansion 50 people will be employed as skilled and unskilled workers. However, a temporary infux of 50 No. of labourers will occur during the construction phase.

III. Land use planning (breakup along with green belt etc) Out of the total plot area is 15703 m²; Ground coverage will be 4218 m² , Green belt area will be 5182 m2 (33.% ), Parking area will be 1885 m² ( 12%) , Road area will be 4419 m² (28.1%).

IV. Assessment of Infrastructure Demand (Physical & Social) M/s Anshul Innovative Chemistry Private Limited, has assessed the capacity of infrastructure (Physical & Social) in the nearby area of the plant site. M/S Anshul Innovative Chemistry Private Limited is undertaking development activities in nearby areas under a corporate Environmental Responsibilities program.

V. Amenities/Facilities Being located within a notifed MIDC Roha Industrial Estate , all developments towards amenities / facilities are being maintained within and in the nearby area. M/s Anshul Innovative Chemistry Private Limited being a member unit continues to contribute to MIDC in these development and maintenance activities . After expansion , 6. PROPOSED INFRASTRUCTURE

I. Industrial Area (Processing Area) Plant area will be about 15,703 m2

II. Storage 62.06 m2 area is being provided for the storage of raw materials.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 89 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

III. Parking 1885 m2 (12%) area is being provided for parking of vehicles within the plant itself.

IV. Residential Area (Non-processing area) No residential unit will be housed within the plant .

V. Green Belt Greenbelt area will be 33% (5182 m2) of the total plot area with a combination of native species specifc to reduce dust and noise pollution levels and to increase aesthetic beauty of the area.

VI. Social Infrastructure Proposed expansion project will result in growth of the surrounding areas by increased indirect employment opportunities in the region.

Table 36. List of industries in 2 km

Serial Name of industry Distance from the project site no

1 Anshul speciality Molecules Private Limited 0.5 km

2 Excel Industries Limited 0.3 km

3 Calchem Industries Limited 0.2 km

4 Deepak Nitrite Limited 0.4 km

5 Sudarshan Chemicals 1 km

Project site is located within the Maharashtra Industrial Development Corporation of Roha. From the project site the nearest village is Dhatav at a distance of 0.44 km SE, it belongs to the Konkan region. It is located 47 km towards East from District headquarters Alibag. 5 km from Roha 86km from the State capital. Dhatav is surrounded by Tala Taluka towards South , Sudhagad Taluka towards North , Murud Taluka towards west , Mangaon Taluka towards South . Demographics of Dhatav Colleges near Dhatav ● Kes's Dr. C.d.deshmukh College, Roha.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 90 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

School in Dhatav ● Audigic Vidyalaya Dhatav

Govt Health Centers near Dhatav 1) Roha , Sub District Hospital Roha , Tilak Road , Nagar Palika Road 2) Mahagaon, SubCenter Mahagaon, Mahagaon tal mangaon Raigad - Mangaon Raigad, 3) Mangaon , SubCenter Mahagaon.

VII. Connectivity (Traffc and Transportation Road/Rail/Metro/Waterways etc) The site can be accessed from an adjacent road named as Roha Kolad road (0.9 km) in the north direction. The nearest Railway Station is Roha railway station (3.50 km NW) and nearest Airport is Chhatrapati Shivaji Maharaj International Airport Mumbai (79.41 km NNW).

Figure 41. Google Image using existing road near the project site

VIII. Drinking Water Management (Source & Supply of water)

After expansion total water requirement will be 605 KLD out of this fresh water requirement will be 377 KLD which will be met by MIDC Supply Water.

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 91 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

IX.Sewerage System

Sewage generated will be treated along with effuent of High COD stream in proposed ETP; after treatment in ETP will be subjected to MEE and treated water will be re-used in cooling tower & boiler. CETP membership has been applied by the industry & it is in an advanced stage of processing.

X. Industrial Waste management

Industry has applied for Membership in CHWTSDF for hazardous waste disposal.

XI.Solid Waste Management

After expansion: Total solid waste will be generated from the plant 165 kg/day out of which 66 kg/day will be biodegradable waste and 99 kg/day will be non biodegradable waste (given to Approved vendor). Boiler ash of 766.5 TPA will be generated (sent to brick Manufacturing unit) and Plastic waste 1.2 TPA sold to authorized parties to recycle.

XII. Power Requirement & Supply/source Existing power requirement is 577 KVA after expansion will be 2000 KVA. Power is sourced from Maharashtra State Electricity Distribution Company Limited (MSEDCL). 7. REHABILITATION AND RESETTLEMENT (R & R) PLAN

The proposed project is located within the Dhatav MIDC, Roha. Hence R&R specifc to this project is not applicable. 8. PROJECT SCHEDULE AND COST ESTIMATES

Likely date of start of construction and likely date of completion. The expansion of the project will be done after obtaining Environmental Clearance and other clearances from statutory state authority. Project will be

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 92 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd.

completed in 6 to 12 months period after obtaining all the regulatory approvals. Estimated project cost along with analysis in terms of economic viability of the project. Total cost of the Project after expansion will be Rs. 47 Crore (Existing- Rs 11 crores, Proposed for expansion- Rs 36 crores)

Table 37. Capital Expenditure EMP Cost (Environment Management Cost) 1. Capital Expenditure in Lakhs Sr. No. Particulars Proposed Unit (Lacs)

1 Air Pollution Control 80 2 Water Pollution Control 500 3 Noise Pollution Control 5 4 Landscaping/Green Belt 5 5 Rain Water Harvesting 10 6 Solid Waste Management 30 7 Social Activities 5 Total 635

Table 38. Recurring Expenditure 2. Recurring Expenditure in lakhs per annum Sr. No. Particulars (Rs. in Lacs)

1 Air Pollution Control 50 2 Water Pollution Control 200 3 Noise Pollution Control 0.5 4 Landscaping/Green Belt 1.0 5 Rain Water Harvesting 1.0 6 Solid Waste Management 300 7 Environment monitoring 3.0 8 Work Zone monitoring 1 9 Occupational Health & safety 25 Total 583

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 93 Expansion of Chemical and Agro Chemical Intermediates Manufacturing Plant at Plot no. 21/2, Dhatav MIDC , Roha, Raigad, Maharashtra By M/s Anshul Innovative Chemistry Pvt Ltd. 9. ANALYSIS OF PROPOSAL (Final Recommendations)

Financial and social benefts with special emphasis on the beneft to the local people including tribal population, if any, in the area. ● Increasing direct employment upto 155 opportunities & indirect employment in proportion. ● It will support increased business opportunities for both industrial & consumer products. ● The project commits to improve social infrastructure like upgradation of facilities in nearby schools, drinking water supply, etc. in a phased manner. ● The project will increase revenue to Maharashtra state by way of taxes & will also help in increasing employment opportunities for the locals. ● A systematic environmental program, the project will ensure that no increase to the air pollution, maximizing water reuse, harvesting solar energy for common area lighting & more importantly will generate social harmony. ● The plot will have well-balanced native species within an area of 5182 m2 (approx. 1000 trees).

Environmental consultant M/s Perfact Envirosolutions Pvt. Ltd. C 94 SECTION D: Annexures ANNEXURE 1 : LAYOUT PLAN

D-1 D-2 Annexure 2 : TOPOGRAPHICAL MAP

D-3 D-4 Annexure 3 : HAZARDOUS WASTE MEMBERSHIP

D-5 D-6 Annexure 4 : BOARD RESOLUTION

D-7 D-8 Annexure 5: AUTHORIZATION OF CONSULTANT

D-9 D-10 Annexure 6: CONSENT TO ESTABLISH

D-11 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-12 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-13 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-14 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-15 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-16 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-17 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-18 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-19 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-20 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Maharashtra Pollution Control Board 6023a2781365dd57617a8ab0

D-21 Kindly verify Maharashtra Pollution Control Board's document on Blockchain by scanning the QR code. https://blockchain.ecmpcb.in/docs/a5cb192d6c37a73581b3c22a9037cbaf690ee0fce2dcd608458cc7de55aac154 Annexure 7: DEED OF ASSIGNMENT

D-22 D-23 D-24 D-25 Annexure 8 : EARLIER ENVIRONMENT CLEARANCE

D-26 D-27 D-28 D-29 D-30 D-31 D-32 Annexure 9 : SCREENSHOT OF APPROVAL OF TRANSFER OF ENVIRONMENT CLEARANCE

D-33 D-34