Fabricating Photopolymer Objects by Mold 3D Printing and UV Curing

Total Page:16

File Type:pdf, Size:1020Kb

Fabricating Photopolymer Objects by Mold 3D Printing and UV Curing Computational Design and Fabrication FabSquare: Fabricating Photopolymer Objects by Mold 3D Printing and UV Curing Vahid Babaei, Javier Ramos, Yongquan Lu, Guillermo Webster, and Wojciech Matusik ■ Massachusetts Institute of Technology apid prototyping tools provide practical of the mold content is carried out by ultraviolet methods for personal fabrication, al- (UV) energy. We replace the expensive and time- lowing designers and engineers to refine consuming mold-making stage in injection molding Rand iterate their ideas quickly. Because of their with 3D printing and substitute the high-pressure, low cost and versatility, 3D printers in particu- high-temperature process involving large and costly lar are becoming increasingly popular. Although hardware with simple injection and UV curing. 3D printers are incredibly powerful devices for Recently, 3D printing has been used as a tool to creating complex geometries, they are inherently fabricate molds for traditional thermoplastic injec- slow and only print materials tion molding. The molds are temporary and used that are within a small range to test mold geometries and for short production The FabSquare system of properties. This puts them in runs. Typically, the molds only last for several dozen fabricates objects by casting clear contrast with classic fabri- injections because the mold polymer degrades un- photopolymers inside a 3D cation processes such as injection der high pressure and heat. Moreover, such molds printed mold. The molds are molding, where speed and high still require the heavy machinery used for injection printed with UV-transparent throughput come at the expense molding. UV injection molding has also been used materials to allow for UV of cost and flexibility. at the µm and mm scales. In biology, UV microin- photopolymerization. Because Injection molding is the pro- jection molding allows for fabricating biocompat- it uses simple and inexpensive cess of injecting molten ther- ible hydrogel structures1 and biosensors.2 Micro UV hardware, FabSquare is moplastic materials into a mold molding has been used to fabricate micro-optical 3 suitable for ordinary users in cavity, inside which they harden devices. While, to the best of our knowledge, there nonspecialized labs. as they cool. The conventional is no literature on the fabrication of large-scale ob- mold-making stage is painstak- jects via 3D printing combined with UV injection ing, expensive, and slow. Apart from the mold molding, we believe that the main contribution development, the required machinery is also pro- of our work is to introduce a flexible fabrication hibitively expensive and best suited for producing method that is suitable for researchers without ac- thousands to millions of parts. cess to complicated hardware, such as computer To address these challenges, we developed Fab- graphics researchers. (See the “Related Work in Square, a system that brings injection molding into Casting and Personal Fabrication” sidebar for more the realm of personal fabrication by leveraging 3D details about previous work.) printing and interactive design. The FabSquare sys- Compared with injection molding, FabSquare is tem is similar to injection molding, except that it significantly less expensive and less complicated, works with photopolymers and the solidification with much simpler hardware requirements, and 34 May/June 2017 Published by the IEEE Computer Society 0272-1716/17/$33.00 © 2017 IEEE g3bab.indd 34 4/3/17 5:25 PM Related Work in Casting and Personal Fabrication njection molding is one of the most popular methods Hopper Ifor manufacturing plastic parts1 because it is capable of fabricating relatively complex parts with high accuracy. In Parting line this method, raw materials melted under high tempera- Mold ture and high pressure are fed into a mold and then hard- ened via cooling. Figure A shows a simplified diagram that illustrates the injection molding process. Injection molding Screw plunger Part requires high startup costs and long lead times before the Barrel Heater Ejection pins first part is produced.2 The metal mold is expensive—on the order of tens of thousands of dollars—and takes weeks Figure A. Simple demonstration of the injection-molding process. to draft, design, and manufacture. This approach is best The material is fed from the hopper into the barrel and forced by the suited for the mass production of end-use products. rotating screw plunger into the mold cavity. The heaters melt the Personal fabrication devices, such as 3D printers and material and keep them molten. After cooling and hardening inside laser cutters, are versatile tools for producing single-item the mold cavity, the part is released with the help of ejection pins. parts.3 Numerous recent works have been focused on speeding up various personal fabrication processes. For example, parallelizing multiple heads can significantly in- 3. N. Gershenfeld, Fab: The Coming Revolution on Your Desktop– crease the printing speed.4 WirePrint fabricates low-fidelity From Personal Computers to Personal Fabrication, Basic Books, previews of a prototype by printing a wireframe mesh.5 2008. faBrickation limits 3D printing to the parts of the object 4. C.J. Hansen et al., “High-Throughput Printing via Microvascular where a higher resolution is needed, and the user puts Multinozzle Arrays,” Advanced Materials, vol. 25, no. 1, 2013, Lego-like bricks everywhere else.6 CofiFab is a computa- pp. 96–102. tional method that fabricates highly detailed, large-scale 5. S. Mueller et al., “WirePrint: 3D Printed Previews for Fast objects rapidly.7 It fabricates the interior shell with a laser Prototyping,” Proc. 27th Ann. ACM Symp. User Interface Software cutter and 3D prints the outer surface. and Technology, 2014, pp. 273–280. There have also been recent efforts to create custom 6. S. Mueller et al., “faBrickation: Fast 3D Printing of Functional thermoforming setups for generating one-off, textured ob- Objects by Integrating Construction Kit Building Blocks,” jects.8,9 Like FabSquare, one of these approaches uses molds Proc. 32nd Ann. ACM Conf. Human Factors in Computing Systems, to cast the object made of gypsum.8 However, in that ap- 2014, pp. 3827–3834. proach, the mold is destroyed when the object is removed. 7. P. Song et al., “CofiFab: Coarse-to-Fine Fabrication of Large 3D Objects,” ACM Trans. Graphics, vol. 35, no. 4, 2016, article no. 45. References 8. C. Schüller et al., “Computational Thermoforming,” ACM 1. D.V. Rosato and M.G. Rosato, Injection Molding Handbook, Trans. Graphics, vol. 35, no. 4, 2016, article no. 43. Springer, 2012. 9. Y. Zhang, Y. Tong, and K. Zhou, “Coloring 3D Printed Surfaces 2. G. Menges et al., How to Make Injection Molds, Carl Hanser by Thermoforming,” IEEE Trans. Visualization and Computer Verlag, 2001. Graphics, preprint, 2016; doi:10.1109/TVCG.2016.2598570. is therefore within the reach of ordinary users. FabSquare Workflow and Compared with 3D printing, the printed mold Technical Details in FabSquare can be reused to rapidly create ad- To fabricate a CAD model, the FabSquare workflow ditional copies of the intended object. Hence, it is follows these steps: well suited to situations where more than a hand- ful of parts are needed. Moreover, many differ- 1. Design a mold geometry. ent additive components can be mixed with the 2. Fabricate the mold with a 3D printer. photopolymer to improve its physical properties. 3. Fill the mold with a specified polymer material. This is an important advantage over 3D printing, 4. Solidify the fluid inside the mold with UV- which only works with a limited range of mate- triggered polymerization. rial properties. FabSquare does have some limita- tions: Similar to injection molding, the maximum Figure 1 and an online web extra video (see achievable thickness with UV curing is limited. https://youtu.be/a-s13U5uLAE) illustrate each of Moreover, the FabSquare editor does not support these four steps. First, the user specifies the geom- molds with more than two parts. etry in the form of a digital model. The mold can IEEE Computer Graphics and Applications 35 g3bab.indd 35 4/3/17 5:25 PM Computational Design and Fabrication then be designed from the model in a 3D CAD software. The output is two STL files that can be directly printed with UV-transparent materials. Next, the photopolymer fluid is injected into the tightly clamped mold. Then, the mold contain- ing the material is exposed to UV light, and the polymerization takes place. After the liquid inside the mold solidifies, the object can be removed from the mold. (a) (b) Figure 2 shows a set of example objects created with FabSquare. Mold Design The mold’s digital design can take place in a CAD environment, such as SolidWorks. We have also developed a stand-alone application that performs the same design steps with a high degree of auto- (c) (d) mation. (We describe our mold-design application in detail later in this article.) The intended 3D geometry for fabrication is used to generate two halves of a mold: A side and B side. The design includes a material inlet and an air outlet in order to let materials flow through (e) the mold. We should be able to tightly clamp the Figure 1. The FabSquare workflow. To fabricate a CAD model, the two halves of the mold together in order to prevent FabSquare workflow follows these steps: (a) design a mold geometry, the material from leaking out of the model region. (b) fabricate the mold with a 3D printer, (c) fill the mold with a specified For this, we distribute screw holes along the mold’s polymer material, (d) solidify the fluid inside the mold with UV- periphery evenly and densely. Figure 3a shows the triggered polymerization, and (e) remove the object from the mold. outline of a designed mold after printing. The maximum mold outline surface area is lim- ited by the area of the 3D printer’s tray and the size of the UV-curing module.
Recommended publications
  • Ink Jet Barrier Film for Resolving Narrow Ink Channels
    Ink Jet Barrier Film For Resolving Narrow Ink Channels Karuppiah Chandrasekaran Dupont Ink Jet Enterprise, Towanda, Pennsylvania Abstract Non-Aqueous Development Ink Jet Barrier Film is a photoresist sandwiched between One of the stringent properties the Ink Jet Barrier film a polyester and a polyolefin. The unexposed photopoly- has to satisfy is ink resistance. Inks are aqueous solu- mer film instantly adheres to different types of substrates. tions containing colorant(s), biocide(s), organic solvents The film can be exposed with a photographic artwork, and optionally dispersion agents. Alcohols and Pyrro- and the unexposed area can be developed in lidones are the commonly used co-solvents2-4. pH of the non-halogenated solvents. The cured film on a substrate ink ranges from 5 to 9. Aqueous developable photopoly- can be laminated on to a top plate at elevated tempera- mer films contain acidic or basic functional groups. Dur- tures. The film is highly flexible and resists partially ing aqueous development, unexposed photopolymer non-aqueous high pH inks. Several factors affect the swells in the developer solvent and the swollen film is resolution of the Ink Jet Barrier Film. Chemical compo- dispersed using mechanical force. Developed film is ther- sition and process conditions that affect resolution have mally and/or photochemically cured to increase cross link been identified. It was possible to resolve 10 micron density. Even the cured photopolymer film contains a channels with 30 micron thick films. A modern high tech- significant number of acidic (basic) functional groups. nology clean room coater is used to manufacture the Ink The acidic (basic) functional groups tend to hydrate in Jet Barrier Films.
    [Show full text]
  • Novacryl 10440 Interior Sign Specification Nova Polymers
    Nova Polymers Novacryl 10440 Interior Sign Specification Nova Polymers Thank you for your interest in Nova Polymers. At Nova Polymers, we are committed to customer service, product development/ support and the continual development of progressive product solutions. Our goal is to provide the most creative and diverse range of photopolymer materials to the architectural design and sign fabrication industries. It is through these commitments, as well as our relationship with the architectural sign community that ensures we are fully capable of exceeding all of your design expectations. Nova continues to be at the forefront of ADA legislation by representing the ISA and SEGD on the International Code Council and is proud to be the industry leader as the focus continues to increase on green building initiatives and sustainable design materials in environmental graphic design. Whether it is innovative materials and equipment, workflow management software or consulting services that can make your process more efficient and profitable; we are there to help. Thank you for your time. If there are any questions, please feel free to contact us directly. Novacryl® Series Photopolymer 10440 Novacryl® Series Photopolymer Section 10440 Interior Signage Novacryl Series Photopolymer Display hidden notes to specifier. (Don't know how? Click Here) NOTE TO SPECIFIER ** This section is based on the products manufactured Nova Polymers, Inc., which is located at: 8 Evans St. Suite 201 Fairfield, NJ 07004 USA Tel: (888) 484-6682 Tel: (973) 882-7890 Fax: (973) 882-5614 Email: [email protected] Website: www.NovaPolymers.com Nova Polymers, Inc. (NPI) is the manufacturer and distributor of all Novacryl Series Photopolymer substrates.
    [Show full text]
  • Compounding of Ethylene-Propylene Polymers for Electrical Applications
    Compounding of Ethylene-Propylene Polymers for Electrical Applications Morton Brown, A. Schulman Inc., Akron, Ohio Background Frequently, the considerations given to the arlier articles in this magazine have reviewed selection of compound ingredients may crosslinked polyethylene (XLPE) insulation and require compromises in one characteristic in Eethylene-propylene rubber (EPR). This article is intended as a sequel to the latter order to improve another. Because of its combination of superior electrical properties, its flexibility over a wide temperature range and its resistance to moisture and weather, EPR is used Proper selection of the ingredientk) in each category in a diverse range of electrical applications: requires that consideration be given to the desired 0 Power cables physical, electrical and environmental properties, as 0 Flexible cords well as cost, ease of mixing, chemical stability and ease 0 Control and instrument wire of processing. Frequently these considerations may re- Automotive ignition wire quire compromises in one characteristic in order to 0 Appliance wire improve another. In the following discussion, factors to 0 Motor lead wire be considered in the proper choice of each ingredient 0 Mining cable will be explored. Molded electrical accessories Compounding is the technology of converting the raw rubber resin into useful materials through the ad- Curatives and Curing Coagents dition of fillers, reinforcers, stabilizers, process aids, curatives, flame retardants, pigments, etc. The resulting composition is called a compound. In Although these components comprise only a small this paper, additive levels will be expressed in parts per percentage of the total compound, the development of hundred of resin (or rubber), commonly called by com- a practical compound and the selection of the ingredi- pounders "phr." This is a more convenient form than ents cannot be carried out on a rational basis without weight percentages, some of which are optional, de- considering the crosslinking chemistry to be employed.
    [Show full text]
  • Differential Scanning Calorimetry of Epoxy Curing Using DSC 6000
    APPLICATION NOTE Thermal Analysis Author Justin Lang Ph.D. PerkinElmer, Inc. 710 Bridgeport Avenue Shelton, CT 06484 Differential Scanning Introduction When testing materials using DSC, scientists often utilize Calorimetry of Epoxy multiple techniques to study their samples. When presented Curing Using DSC 6000 with a sample which exhibits multiple and/or overlapping thermal events, separation and identification of the transitions become important. One of the more obvious questions is whether the events are thermo-dynamic or kinetically controlled. A couple of examples of thermodynamic events would be the melting point and the glass transition of materials. An example of a kinetic transition would be a thermal event, which involves a change in the material such as cross-linking, and decomposition. It is not uncommon to find kinetic events close to (if not overlapping) thermodynamic transitions, such as enthalpic relaxation and the glass transition or melting and decomposition. The two most common techniques used to assist when studying these types of materials is HyperDSC® or MT-DSC. HyperDSC can be utilized to suppress kinetic events, and MT-DSC to separate kinetic from thermodynamic events. A commonly studied sample by DSC is thermoset epoxy materials where the sample is heated to an elevated temperature, at which point it starts to cross-link.When studying these types of materials, multiple transitions are typically sought after: • Initial glass transition Tgi • Peak cure temperature • Cure onset temperature • Cure heat • Final glass transition Tgf • Specific heat of the final material • Percent cure PerkinElmer’s DSC 6000 is an excellent tool for measuring • Standard DSC experiment these thermal events, not only in the typical testing methods, – Heat from 25-200 ˚C at 10 ˚C/min.
    [Show full text]
  • Anhydride Curatives for Epoxy Systems
    distributed by: Request Quote or Samples TECHNICAL BULLETIN DIXIE CHEMICAL 10601 Bay Area Blvd. Pasadena, TX 77507 Tel: (281) 474-3271 Fax: (281) 291-3384 E-Mail: [email protected] FORMULATING ANHYDRIDE-CURED EPOXY SYSTEMS Introduction Dixie Chemical Company makes a range of alicyclic anhydrides which are highly suitable for curing epoxy resins. These anhydrides include: • Tetrahydrophthalic anhydride (THPA) • Hexahydrophthalic anhydride (HHPA) • Methyltetrahydrophthalic anhydride (MTHPA) • Methylhexahydrophthalic anhydride (MHHPA) • Nadic® methyl anhydride (NMA) • Formulated blends of these materials Details about each of these are found in specific Product Technical Bulletins which are available from Dixie Chemical Company. These anhydrides are commonly used to cure epoxy resins in many challenging applications, including fiber reinforced composites used in high performance aerospace and military applications, as well as mechanically demanding applications like filament wound bearings. They also provide excellent electrical properties for use in high voltage applications, as well as in encapsulating electronic components and circuits. Properties of a cured epoxy resin depend on the starting epoxy resin, the curing agent, the accelerator, the ratio of curing agent to resin, the curing time and curing temperature, and the post-cure times and temperatures. No one formulation or one set of process conditions will yield a cured resin having optimum values for all properties. Therefore, it is necessary to determine the desired properties for the intended end use before choosing a formulation. In general, greater cross linking of the resin raises the heat distortion temperature (HDT), hardness, and chemical resistance, but lowers the impact resistance and flexural strength of the cured product. The following sections discuss the factors which influence performance.
    [Show full text]
  • The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber A
    The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science By ROBERT J. WEHRLE B.S., Northern Kentucky University, 2012 Wright State University 2014 WRIGHT STATE UNIVERSITY GRADUATE SCHOOL August 29, 2014 I HEREBY RECOMMEND THAT THE THESIS PREPARED UNDER MY SUPERVISION BY Robert Joseph Wehrle ENTITLED The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber BE ACCEPTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE. Eric Fossum Ph.D. Thesis Director David A. Grossie, Ph.D. Chair, Department of Chemistry Committee on Final Examination Eric Fossum, Ph.D. William A. Feld, Ph.D. Steven B. Glancy, Ph.D. Kenneth Turnbull, Ph.D. Robert E. W. Fyffe, Ph.D. Vice President for Research and Dean of the Graduate School Abstract Wehrle, Robert J. M.S, Department of Chemistry, Wright State University, 2014. The Curing and Degradation Kinetics of Sulfur Cured EPDM Rubber. Ethylene‐propylene‐diene (EPDM) rubbers containing varying amounts of diene were cured with sulfur using either a moving die rheometer (MDR) or a rubber process analyzer (RPA). The effect of removing curatives and how the curing reaction changed was explored. Kinetic data was extracted from the rheology plots and reaction rate constants were determined by two separate ways: manually choosing points of interest or by a computer model. iii TABLE OF CONTENTS Page 1. Introduction 1 1.1 EPDM Overview 1 1.2 Preparation of EPDM 2 1.2.1 Ziegler‐Natta Catalysts 2 1.2.2 Metallocene Catalysts 4 1.3 Cross‐link Chemistry 5 1.3.1 Peroxide Cure 5 1.3.2 Sulfur Cure 6 1.3.3 Cross‐link Sites 8 1.3.3.1 Polymer Branching 9 1.3.4 Rubber Ingredients 10 1.3.4.1 Non‐curative Ingredients 10 1.3.4.2 Curative Ingredients 11 1.4 Kinetics 12 1.5 Instrumentation 13 2.
    [Show full text]
  • Study of UV Curing in the Wood Industry
    Study of UV Curing in the Wood Industry HAIDER OSAMA AL-MAHDI MY0001415 Dept. of Wood, Paper and Coating Technology School of Industrial Technology University Science Malaysia Abstract: Although mass production is the primary demand, the wood finishing must nevertheless conform to certain minimal standards. The surface should be protected and sealed against heat, dirt and abrasion, and insulated from the ingress and evaporation of moisture which would cause dimensional changes in the timber. The finish should be clear (unclouded) and smooth to enhance the natural beauty of the figure and the grain. The finish should also maintain its appearance, and adhesion, as well as protection given to the wood. The film should not seriously be degrading during the lifetime of the article. All the standards mentioned above are available in the 100% solid acrylic UV finishing system. A thorough study of the timber wood anatomy and of the physical and chemical properties of polymerized film is essential in order to match these properties with the wood substrate. Introduction: This paper is not meant to uncover any secrets that have not been known before nor establish new facts that have not been recognized, but to affirm these facts in an elaborate and analytical approach required by those who have interest in the subject, and Its scientific data are based on approved experiments and observations as a guideline for further study and further research. The UV curable wood coating technique offers obvious advantages over conventional wood finishing systems, and increasingly adopted for a wide range of applications. These advantages in short, as determined by the end- users are: 1- High curing speed Increased production: example flooring panels coated by UV with an average line running at 12 M/min can produce about 72,000 square meter per month per shift 2- Lower energy cost (compared to the heat generated by gas fir or electric ovens in some conventional coatings).
    [Show full text]
  • Photopolymers in 3D Printing Applications
    Photopolymers in 3D printing applications Ramji Pandey Degree Thesis Plastics Technology 2014 DEGREE THESIS Arcada Degree Programme: Plastics Technology Identification number: 12873 Author: Ramji Pandey Title: Photopolymers in 3D printing applications Supervisor (Arcada): Mirja Andersson Commissioned by: Abstract: 3D printing is an emerging technology with applications in several areas. The flexibility of the 3D printing system to use variety of materials and create any object makes it an attractive technology. Photopolymers are one of the materials used in 3D printing with potential to make products with better properties. Due to numerous applications of photo- polymers and 3D printing technologies, this thesis is written to provide information about the various 3D printing technologies with particular focus on photopolymer based sys- tems. The thesis includes extensive literature research on 3D printing and photopolymer systems, which was supported by visit to technology fair and demo experiments. Further, useful information about recent technological advancements in 3D printing and materials was acquired by discussions with companies’ representatives at the fair. This analysis method was helpful to see the industrial based 3D printers and how companies are creat- ing digital materials on its own. Finally, the demo experiment was carried out with fusion deposition modeling (FDM) 3D printer at the Arcada lab. Few objects were printed out using polylactic acid (PLA) material. Keywords: Photopolymers, 3D printing, Polyjet technology, FDM
    [Show full text]
  • Curing with Sulfur and Sulfur Donor Systems
    26651 Sulpher Solution17.qxp_Layout 1 7/8/21 3:36 PM Page 1 FUNDAMENTALS OF CROSSLINKING: continued 2 FUNDAMENTALS OF CROSSLINKING: continued 3 EFFICIENCY OF SULFUR CROSSLINKING: continued 4 5 Fig. 1: Schematic of a Cure Curve The cure rate is the speed at which a rubber compound increases in modulus (crosslink density) As one can see the carbon-carbon bond has a higher bond energy (350kJ) than the sulfur-carbon type of crosslink systems and the at a specified crosslinking temperature or heat history. Cure time refers to the amount of time torque bond (285kJ) formed by the EV (Efficient Vulcanization) sulfur cure system and a much curing with sulfur and required to reach specified states of cure at specified cure temperature or heat history. An example (dNm) stronger bond strength than the sulfur-sulfur bond (< 270 kJ) formed by a CV (Conventional t effect on physical properties of cure time is the time required for a given compound to reach 50% or 90% of the ultimate state 90 reversion Vulcanization) sulfur cure system. sulfur donor systems of cure at a given temperature often referred to as t50 and t90 respectively. (See Fig.1) When we refer to bond energy or bond strength we are referring to the amount of energy Based on the sulfur/accelerator combinations, three popular crosslinking (cure) systems Probably the most complex issues in rubber compounding are the cure systems. The Determining what is the optimum cure time for a small curemeter specimen is not the same as required to break a bond. The higher bond strength means greater heat is needed to break the method used to crosslink the elastomers is crucial to finished properties(i.e.
    [Show full text]
  • Movement Between Bonded Optics
    MOVEMENT BETWEEN BONDED OPTICS Andrew Bachmann, Dr. John Arnold and Nicole Langer DYMAX Corporation, September 13, 2001 INTRODUCTION Controlling the movement of bonded optical parts depends, in large measure, on the properties of the adhesives used. Common issues include both shrinkage during cure and expansion during thermal excursions. Designers have historically had to limit their designs to optics whose thermal range fell below the then-available “high” glass transition temperature (Tg) epoxies; i.e., operating below the adhesive’s Tg. However, many of today’s optical devices employ even higher operating temperatures and require greater resistance to environmental conditions. The common minus 50ºC to plus 200ºC microelectronic test operating range challenges even classical “High Tg” optical epoxies. The NO SHRINK™ family of Optical Positioning adhesives features low total movement between bonded parts either on cure or when the optical device is thermally cycled. NO SHRINK™ products are based on novel, patent- applied-for technology. This technology was incorporated into light curing urethane-acrylics to create products with thermal characteristics that are different from those of older technology adhesives. Table 1. Dimensional changes (measured at 25ºC) Adhesive OP-60-LS Adhesive OP-64-LS < 0.1% (during UV Cure) < 0.1% (during UV Cure) < 0.1% (after 24 hr, 120°C) < 0.1% (after 24 hr, 120°C) Tg ~ 50ºC Tg ~ 125ºC “Rules of thumb” for comparing epoxy resins are not accurate for comparing other resins or other resins with epoxies. Novel NO SHRINK™ UV and visible light curing adhesives exhibit less total movement over a temperature range regardless of the Tg.
    [Show full text]
  • Post-Polymerization Paper Technical
    Post-Polymerization Paper Technical By Igor V. Khudyakov, V-curing technology is often Formal kinetics leads to the Ph.D., D.Sc. selected because of the high- following simple equation for post- speed nature of the process. polymerization: Although curing is initiated by UV U [M] [M] = o (3) irradiation, polymerization continues in t . (l + k [R ] t)kt /kp the dark following irradiation. For the t n o purpose of this paper, chemistry that Here a subscript “o” stands occurs after irradiation is defined as for the initial moment when post- post-polymerization. polymerization is initiated. [Rn ]o is The kinetics of free-radical UV the initial concentration of macro- curing of vinyl monomers in solution radicals at the moment when is well-known. The cessation of irradiation is terminated. For vinyl irradiation of the photoinitiator monomers in solution kt /kp>> 1, (PI) in the presence of a monomer and post-polymerization leads to a (M) quickly leads to termination of negligible additional consumption polymerization due to lack of new of M (formation of polymer). The radicals from the PI.1 Reactive macro- rate constants kp and kt (each has radicals, which exist in the solution dimension of M-1∙s-1) characterizes at the moment irradiation is stopped, the free-radical polymerization chain undergo primarily bimolecular reaction in solution. The rate constant termination: of an elementary bimolecular reaction kt in a diluted solution does not depend . → Rn + Rm macromolecule (1) upon time or concentration of reagents While “dying,” macro-radicals react but depends only upon temperature with the monomer: and pressure.
    [Show full text]
  • Recent Advances in Cationic Photopolymerization
    Journal of Photopolymer Science and Technology Volume 32, Number 2 (2019) 233 - 236 Ⓒ 2019SPST Recent Advances in Cationic Photopolymerization Marco Sangermano Politecnico di Torino, Dipartimento di Scienza Applicata e Tecnologia, C.so Duca degli Abruzzi 24, 10129, Torino, Italy [email protected] The paper reports important strategies to overcome limitation of cationic photopolymerization. First, it was possible to run emulsion cationic photopolymerization in water, taking the advantages of hydrophobic droplets of suitable dimension to avoid termination reaction, achieving capsules of about 200 nm. Subsequently a frontal polymerization reaction is used to promote the UV-induced crosslinking process of an epoxy composites via a radical induced cationic frontal polymerization. Keywords: Cationic photopolymerization, Emulsion polymerization, Frontal polymerization 1. Introduction the main limitation of UV-induced crosslinking Cationic photopolymerization is an interesting reactions is related to the hindering of UV-light UV-induced process since the mechanism is penetration towards thickness of the formulations, characterized by important advantages such as which limits this polymerization technique in the absence of oxygen inhibition, low shrinkage upon preparation of thick composite materials. This curing, and good versatility of the crosslinked limitation has been overcome by the introduction of materials [1]. While the main applications are in the a Radical Induced Cationic Frontal Polymerization field of coating and the electronic industry, we have (RICFP) process. The suggested mechanism put recently investigated the use of cationic UV-induced together the so-called Radical Induced Cationic polymerization for the synthesis of polymeric Polymerization (RICP) with Frontal Polymerization particles and for the fabrication of polymeric (FP). UV-cured bulk epoxy composites were composites.
    [Show full text]