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The Creation and Annihilation Operators Are 5X5 Matrices

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The Creation and Annihilation Operators Are 5X5 Matrices Raising & Lowering; Creating & Annihilating Frank Rioux The purpose of this tutorial is to illustrate uses of the creation (raising) and annihilation (lowering) operators in the complementary coordinate and matrix representations. These operators have routine utility in quantum mechanics in general, and are especially useful in the areas of quantum optics and quantum information. The harmonic oscillator eigenstates are regularly used to represent (in a rudimentary way) the vibrational states of diatomic molecules and also (more rigorously) the quantized states of the electromagnetic field. The creation operator adds a quantum of energy to the molecule or the electromagnetic field and the annihilation operator does the opposite. The harmonic oscillator eigenfunctions in coordinate space are given below, where v is the quantum number and can have the values 0, 1, 2, ... 2 1 x Ψ()vx Her() v x exp v 2 2 v π First we demonstrate that the harmonic oscillator eigenfunctions are normalized. ∞ ∞ ∞ 2 2 2 Ψ()0x d1x Ψ()1x d1x Ψ()2x d1x ∞ ∞ ∞ Next we demonstrate that they are orthogonal: ∞ ∞ ∞ Ψ()0x Ψ()1x d0x Ψ()0x Ψ()2x d0x Ψ()1x Ψ()2x d0x ∞ ∞ ∞ The harmonic oscillator eigenfunctions form an orthonormal basis set. They are displayed below. Ψ()0x Ψ()1x Ψ()2x x x x d The raising or creation operator in the coordinate representation in reduced units x is the position operator minus i times the coordinate space momentum operator: dx Operating on the v = 0 eigenfunction d xΨ()0x Ψ()0x yields the v = 1 eigenfunction: dx x d The lowering or annihilation operator in the coordinate representation in reduced x units is the position operator plus i times the coordinate space momentum operator: dx d Operating on the v = 2 eigenfunction xΨ()2x Ψ()2x yields the v = 1 eigenfunction: dx x The energy operator in coordinate space and the energy expectation value for the v = 2 state are given below. Ev = v + 1/2 in atomic units. ∞ 2 2 1 d 1 2 1 d 1 2 H = x Ψ()2x Ψ()2x x Ψ()2x dx 2.5 2 2 2 dx 2 2 dx 2 ∞ In the matrix formulation of quantum mechanics the harmonic oscillator eigenfunctions are vectors. The matrix representations for the first five eigenstates are given below. They are actually infinite vectors which for practical purposes are truncated at order 5. 1 0 0 0 0 1 0 0 v0 0 v1 0 v2 1 v3 0 0 0 0 1 0 0 0 0 They form an orthonormal basis set: T T T T T T v0 v0 1 v1 v1 1 v2 v2 1 v0 v1 0 v0 v2 0 v1 v2 0 In this context the creation and annihilation operators are 5x5 matrices. 0 0 0 0 0 0 1 0 0 0 1 0 0 0 0 0 0 2 0 0 Create 0 2 0 0 0 Annihilate 0 0 0 3 0 0 0 3 0 0 0 0 0 0 4 0 0 0 4 0 0 0 0 0 0 0 0 0 1.414 The annihilation operator on the v = 2 state: anˆ nn1 Annihilate1 0 0 0 0 0 1 0 0 0 The annihilation operator on the v = 0 state: Annihilate0 0 0 0 0 0 0 0 0 0 † The creation operator on the v = 2 state: anˆ n11 n Create1 0 0 1.732 0 0 The number operator on the v = 2 state: 0 0 0 0 0 0 0 0 1 0 0 0 0 0 aanˆˆ† nn Create Annihilate 0 0 2 0 0 Create Annihilate1 2 0 0 0 3 0 0 0 0 0 0 0 4 0 0 T T Or do it this way: v0 CreateAnnihilatev0 0 v1 CreateAnnihilatev1 1 T T v2 CreateAnnihilatev2 2 v3 CreateAnnihilatev3 3 † 11 The energy operator operating on the v = 2 and 4 states: aaˆˆ n n n 22 0 0 0 0 0 0 0 0 0 0 0 0 1 1 Create Annihilate1 1 2.5 Create Annihilate0 0 0 2 2 0 0 0 0 0 0 0 0 0 1 1 4.5 1 0 0 0 1 1 2 na ()0ˆ† n Create 0 1 Creating the v = 2 eigenstate from the vacuum: 2 n! 0 0 0 0 0 0 1 2 Create v0 1 2 0 0 This operation is illustrated graphically in the coordinate representation as follows: d d d xx Ψ()0x Ψ()0x xΨ()0x Ψ()0x dx dx dx x Construct the matrix forms of the position and momentum operators using the annihilation and creation operators. See E. E. Anderson, Modern Physics and Quantum Mechanics, page 201. Annihilate Create i Position Momentum ()Create Annihilate 2 2 Calculate the position and momentum expectation values for several states: T T T T v0 Positionv0 0 v0 Momentumv0 0 v1 Positionv1 0 v1 Momentumv1 0 Calculate the position‐momentum uncertainty product (xp) for several states: 2 2 T 2 T T 2 T v0 Position v0 v0 Positionv0 v0 Momentum v0 v0 Momentumv0 0.5 2 2 T 2 T T 2 T v1 Position v1 v1 Positionv1 v1 Momentum v1 v1 Momentumv1 1.5 Calculate the energy expectation value for the following superposition state. 1 1 1 T 1 7 Ψ v0 v1 v2 Ψ Create AnnihilateΨ Ψ 2 3 6 2 6 7 1 1 1 3 1 5 7 P E P E P E = 0 0 1 1 2 2 6 2 2 3 2 6 2 6 Below it is demonstrated that there are two equivalent forms of the harmonic oscillator energy operator in the matrix formulation of quantum mechanics. † 11 † 11 aaˆˆ n n n aaˆˆ n n n 22 22 0 0 0 0 0 0 0 0 0 0 0 0 1 1 Create Annihilate0 0 0 Annihilate Create0 0 0 2 2 1 1 3.5 1 1 3.5 0 0 0 0 0 0 Or, do it this way: 0 0 0 0 Create Annihilate Annihilate Create 0 0 2 1 3.5 0 0 Or this way: 0 0 0 0 2 2 Momentum Position 0 0 2 2 1 3.5 0 0 Demonstrate that the position and momentum operators donʹt commute using the matrix form of the operators. i 0 0 0 0 0 i 0 0 0 Position Momentum Momentum Position 0 0 i 0 0 0 0 0 i 0 0 0 0 0 4i This calculation yields the i times the identity matrix as expected, except for the value of the last diagonal element. The latter is a mathematical artifact of using truncated matrices for operators which are infinite. The creation, annihilation and number operators are related to the X and Y Pauli operators. 0 1 0 i Pauli X and Y operators: X Y 1 0 i 0 1 0 0 Creation operator: ()XiY 2 1 0 1 0 1 Annihilation operator: ()XiY 2 0 0 1 1 0 0 Number operator: ()XiY ()XiY 2 2 0 1 .
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