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8840-B Flame Retardant Urethane (Part B)

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8840-B Flame Retardant Urethane (Part B) 8840-B Flame Retardant Urethane (Part B) MG Chemicals UK Limited Version No: A-1.00 Issue Date: 17/09/2020 Safety Data Sheet (Conforms to Regulation (EU) No 2015/830) Revision Date: 17/09/2020 L.REACH.GBR.EN SECTION 1 Identification of the substance / mixture and of the company / undertaking 1.1. Product Identifier Product name 8840-B Synonyms SDS Code: 8840-Part B; 8840-B, 8840-500ML, 8840-2L, 8840-4.5L Other means of identification Flame Retardant Urethane (Part B) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Urethane hardener for use with resins Uses advised against FOR INDUSTRIAL USE ONLY 1.3. Details of the supplier of the safety data sheet Registered company name MG Chemicals UK Limited MG Chemicals (Head office) Heame House, 23 Bilston Street, Sedgely Dudley DY3 1JA United Address 9347 - 193 Street Surrey V4N 4E7 British Columbia Canada Kingdom Telephone +(44) 1663 362888 +(1) 800-201-8822 Fax Not Available +(1) 800-708-9888 Website Not Available www.mgchemicals.com Email [email protected] [email protected] 1.4. Emergency telephone number Association / Organisation Verisk 3E (Access code: 335388) Emergency telephone +(44) 20 35147487 numbers Other emergency telephone +(0) 800 680 0425 numbers SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to H334 - Respiratory Sensitizer Category 1, H373 - Specific target organ toxicity - repeated exposure Category 2, H332 - Acute Toxicity (Inhalation) regulation (EC) No 1272/2008 Category 4, H335 - Specific target organ toxicity - single exposure Category 3 (respiratory tract irritation), H315 - Skin Corrosion/Irritation [CLP] [1] Category 2, H319 - Eye Irritation Category 2, H317 - Skin Sensitizer Category 1, H351 - Carcinogenicity Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI 2.2. Label elements Hazard pictogram(s) UFI: QAQ0-G03C-V00R-DVY6 Signal word Danger Hazard statement(s) H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. (Respiratory system) (Inhalation) H332 Harmful if inhaled. H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. Page 1 continued... Page 2 of 17 8840-B Flame Retardant Urethane (Part B) H351 Suspected of causing cancer. Supplementary statement(s) EUH204 Contains isocyanates. May produce an allergic reaction. Precautionary statement(s) Prevention P201 Obtain special instructions before use. P260 Do not breathe mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment (see advice on this label). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. 2.3. Other hazards REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 Composition / information on ingredients 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1.CAS No 2.EC No %[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP] 3.Index No 4.REACH No Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye Irritation Category 1.9016-87-9 2, Skin Sensitizer Category 1, Carcinogenicity Category 2, Specific target organ toxicity - single 2.Not Available polymeric diphenylmethane 30-60 exposure Category 3 (respiratory tract irritation), Specific target organ toxicity - repeated exposure 3.Not Available diisocyanate Category 2, Respiratory Sensitizer Category 1; H332, H315, H319, H317, H351, H335, H373, 4.01-2119457024-46-XXXX H334, EUH204 [1] Carcinogenicity Category 2, Acute Toxicity (Inhalation) Category 4, Specific target organ toxicity - 1.26447-40-5 diphenylmethane repeated exposure Category 2, Skin Sensitizer Category 1, Specific target organ toxicity - single 2.247-714-0 30-60 diisocyanate (MDI) mixed exposure Category 3 (respiratory tract irritation), Skin Corrosion/Irritation Category 2, Respiratory 3.615-005-00-9 isomers Sensitizer Category 1, Eye Irritation Category 2; H351, H332, H373**, H317, H335, H315, H334, 4.01-2120770510-62-XXXX H319 [2] 1.101-68-8 Carcinogenicity Category 2, Acute Toxicity (Inhalation) Category 4, Specific target organ toxicity - 2.202-966-0 repeated exposure Category 2, Skin Sensitizer Category 1, Specific target organ toxicity - single 3.615-005-00-9 4,4'-diphenylmethane 10-30 exposure Category 3 (respiratory tract irritation), Skin Corrosion/Irritation Category 2, Respiratory 4.01-2119457014-47- diisocyanate (MDI) Sensitizer Category 1, Eye Irritation Category 2; H351, H332, H373**, H317, H335, H315, H334, XXXX|01-2120766410-60- H319 [2] XXXX|01-2120770510-62-XXXX Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available SECTION 4 First aid measures 4.1. Description of first aid measures Continued... Page 3 of 17 8840-B Flame Retardant Urethane (Part B) If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Immediately flush body and clothes with large amounts of water, using safety shower if available. Skin Contact Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Inhalation Perform CPR if necessary. Transport to hospital, or doctor, without delay. Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respiration should be administered as needed. Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Treatment is essentially symptomatic. A physician should be consulted. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed For sub-chronic and chronic exposures to isocyanates: This material may be a potent pulmonary sensitiser which causes bronchospasm even in patients without prior airway hyperreactivity. Clinical symptoms of exposure involve mucosal irritation of respiratory and gastrointestinal tracts. Conjunctival irritation, skin inflammation (erythema, pain vesiculation) and gastrointestinal disturbances occur soon after exposure. Pulmonary symptoms include cough, burning, substernal pain and dyspnoea. Some cross-sensitivity occurs between different isocyanates. Noncardiogenic pulmonary oedema and bronchospasm are the most serious consequences of exposure. Markedly symptomatic patients should receive oxygen, ventilatory support and an intravenous line. Treatment for asthma includes inhaled sympathomimetics (epinephrine [adrenalin], terbutaline) and steroids. Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) may be useful for ingestion. Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be used for corneal abrasions. There is no effective therapy for sensitised workers. [Ellenhorn and Barceloux; Medical Toxicology] NOTE: Isocyanates cause airway restriction in naive individuals with the degree of response dependant on the concentration and
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