Actinide Separation Inspired by Self-Assembled Metal-Polyphenolic Nanocages
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A Protein Engineered to Bind Uranyl Selectively and with Femtomolar Affinity
ARTICLES PUBLISHED ONLINE: 26 JANUARY 2014 | DOI: 10.1038/NCHEM.1856 A protein engineered to bind uranyl selectively and with femtomolar affinity Lu Zhou1†, Mike Bosscher1†, Changsheng Zhang2,3†,SalihO¨ zc¸ubukc¸u1, Liang Zhang1, Wen Zhang1, Charles J. Li1, Jianzhao Liu1, Mark P. Jensen4, Luhua Lai2,3* and Chuan He1* 21 ∼ Uranyl (UO2 ), the predominant aerobic form of uranium, is present in the ocean at a concentration of 3.2 parts per 109 (13.7 nM); however, the successful enrichment of uranyl from this vast resource has been limited by the high concentrations of metal ions of similar size and charge, which makes it difficult to design a binding motif that is selective for uranyl. Here we report the design and rational development of a uranyl-binding protein using a computational screening process in the initial search for potential uranyl-binding sites. The engineered protein is thermally stable and offers very high affinity and selectivity for uranyl with a Kd of 7.4 femtomolar (fM) and >10,000-fold selectivity over other metal ions. We also demonstrated that the uranyl-binding protein can repeatedly sequester 30–60% of the uranyl in synthetic sea water. The chemical strategy employed here may be applied to engineer other selective metal-binding proteins for biotechnology and remediation applications. ranium is the key element for nuclear-energy production and Through billions of years of evolution nature has produced is important in many other applications. The most stable and strategies to recognize beneficial or toxic metal ions with high Urelevant uranium ion in aerobic environments is the uranyl sensitivity and selectivity. -
Hierarchically-Structured Metalloprotein Composite
ARTICLE There are amendments to this paper https://doi.org/10.1038/s41467-020-14709-y OPEN Hierarchically-structured metalloprotein composite coatings biofabricated from co-existing condensed liquid phases ✉ Franziska Jehle 1, Elena Macías-Sánchez1, Sanja Sviben1, Peter Fratzl1, Luca Bertinetti 1 & ✉ Matthew J. Harrington 1,2 1234567890():,; Complex hierarchical structure governs emergent properties in biopolymeric materials; yet, the material processing involved remains poorly understood. Here, we investigated the multi- scale structure and composition of the mussel byssus cuticle before, during and after for- mation to gain insight into the processing of this hard, yet extensible metal cross-linked protein composite. Our findings reveal that the granular substructure crucial to the cuticle’s function as a wear-resistant coating of an extensible polymer fiber is pre-organized in con- densed liquid phase secretory vesicles. These are phase-separated into DOPA-rich proto- granules enveloped in a sulfur-rich proto-matrix which fuses during secretion, forming the sub-structure of the cuticle. Metal ions are added subsequently in a site-specific way, with iron contained in the sulfur-rich matrix and vanadium coordinated by DOPA-catechol in the granule. We posit that this hierarchical structure self-organizes via phase separation of specific amphiphilic proteins within secretory vesicles, resulting in a meso-scale structuring that governs cuticle function. 1 Department of Biomaterials, Max Planck Institute of Colloids and Interfaces, 14424 Potsdam, -
Depleted Uranium Technical Brief
Disclaimer - For assistance accessing this document or additional information,please contact [email protected]. Depleted Uranium Technical Brief United States Office of Air and Radiation EPA-402-R-06-011 Environmental Protection Agency Washington, DC 20460 December 2006 Depleted Uranium Technical Brief EPA 402-R-06-011 December 2006 Project Officer Brian Littleton U.S. Environmental Protection Agency Office of Radiation and Indoor Air Radiation Protection Division ii iii FOREWARD The Depleted Uranium Technical Brief is designed to convey available information and knowledge about depleted uranium to EPA Remedial Project Managers, On-Scene Coordinators, contractors, and other Agency managers involved with the remediation of sites contaminated with this material. It addresses relative questions regarding the chemical and radiological health concerns involved with depleted uranium in the environment. This technical brief was developed to address the common misconception that depleted uranium represents only a radiological health hazard. It provides accepted data and references to additional sources for both the radiological and chemical characteristics, health risk as well as references for both the monitoring and measurement and applicable treatment techniques for depleted uranium. Please Note: This document has been changed from the original publication dated December 2006. This version corrects references in Appendix 1 that improperly identified the content of Appendix 3 and Appendix 4. The document also clarifies the content of Appendix 4. iv Acknowledgments This technical bulletin is based, in part, on an engineering bulletin that was prepared by the U.S. Environmental Protection Agency, Office of Radiation and Indoor Air (ORIA), with the assistance of Trinity Engineering Associates, Inc. -
A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4n]3[UO2(Ncse)5]
inorganics Article A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4N]3[UO2(NCSe)5] Stefano Nuzzo, Michelle P. Browne, Brendan Twamley, Michael E. G. Lyons and Robert J. Baker * School of Chemistry, Trinity College, University of Dublin, 2 Dublin, Ireland; [email protected] (S.N.); [email protected] (M.P.B.); [email protected] (B.T.); [email protected] (M.E.G.L.) * Correspondence: [email protected]; Tel.: +353-1-896-3501; Fax: +353-1-671-2826 Academic Editors: Stephen Mansell and Steve Liddle Received: 30 October 2015; Accepted: 4 February 2016; Published: 16 February 2016 Abstract: The first example of a uranyl selenocyanate compound is reported. The compound [Et4N]3[UO2(NCSe)5] has been synthesized and fully characterized by vibrational and multinuclear (1H, 13C{1H} and 77Se{1H}) NMR spectroscopy. The photophysical properties have also been recorded and trends in a series of uranyl pseudohalides discussed. Spectroscopic evidence shows that the U–NCSe bonding is principally ionic. An electrochemical study revealed that the reduced uranyl(V) species is unstable to disproportionation and a ligand based oxidation is also observed. The structure of [Et4N]4[UO2(NCSe)5][NCSe] is also presented and Se¨ ¨ ¨ H–C hydrogen bonding and Se¨ ¨ ¨ Se chalcogen–chalcogen interactions are seen. Keywords: uranyl; structural determination; photophysics 1. Introduction The chemistry of uranium in its highest oxidation state has held scientists fascination for a long 2+ period of time. The uranyl moiety, [UO2] , is well studied in aqueous phases due, in part, to relevance in the nuclear waste treatment. Moreover, the photophysical properties of uranyl were first used in ancient roman times in colored glass [1], whilst comprehensive understanding of the bonding, and therefore photophysical properties, has come from both experiment and theory. -
Largest Mixed Transition Metal/Actinide Cluster: a Bimetallic Mn/Th Complex with A
Inorg. Chem. 2006, 45, 2364−2366 Largest Mixed Transition Metal/Actinide Cluster: A Bimetallic Mn/Th 18+ Complex with a [Mn10Th6O22(OH)2] Core Abhudaya Mishra, Khalil A. Abboud, and George Christou* Department of Chemistry, UniVersity of Florida, GainesVille, Florida 32611-7200 Received December 6, 2005 A high-nuclearity mixed transition metal/actinide complex has been well-characterized transition metal/actinide complexes, among III - - prepared from the reaction of a Mn 4 complex with Th(NO3)4 in which are the dinuclear metal metal bonded M An orga- ) ) 6a MeCN/MeOH. The complex [Th6Mn10O22(OH)2(O2CPh)16(NO3)2- nometallic complexes (M Fe, Ru and An Th, U) and the family of linear trimetallic M IIUIV (M ) Co, Ni, Cu, (H2O)8] is the largest such complex to date and the first Th/Mn 2 6b species. It is rich in oxide groups, which stabilize all of the metals Zn) complexes containing a hexadentate Schiff base. in the high ThIV and MnIV oxidation levels. Magnetic characterization However, only one of these contains Mn, trinuclear [MnU O L (py) ](L- ) 1,7-diphenyl-1,3,5,7-heptanetetro- establishes that the complex has an S ) 3 ground-state spin value. 2 2 2 4 nato).7 Although Th is used in a wide array of products and processes, the cluster chemistry of Th is poorly developed compared to transition metals: Currently, there - 8a We have had a longstanding interest in the development are metal organic frameworks and organically templated 8b of manganese carboxylate cluster chemistry, mainly because Th complexes known, and the largest molecular Th 9 of its relevance to a variety of areas, including bioinorganic complex is Th6. -
Procedure for Determining Uranium, Plutonium and Americium by Extraction-Chromatographic Procedures
Procedure for determining uranium, plutonium and americium by extraction-chromatographic procedures H-U/Pu/Am-AWASS-01 Authors: M. Beyermann D. Obrikat Federal coordinating office for drinking water, groundwater, wastewater, sludge, waste and wastewater of nuclear power plants (Leitstelle für die Überwachung der Radioaktivität in Trinkwasser, Grundwasser, Abwasser, Klärschlamm, Reststoffen und Abfällen) ISSN 1865-8725 Version October 2000 Procedures manual for monitoring of radioactive substances in the environment and of external radiation (Messanleitungen für die „Überwachung radioaktiver Stoffe in der Umwelt und externer Strahlung“) H-U/Pu/Am-AWASS-01-01 Procedure for determining uranium, plutonium and americium by means of extraction- chromatographic procedures 1 Scope This procedure serves to simultaneously determine the uranium isotopes U-234, U-235 and U-238, the plutonium isotopes Pu-238, Pu-239 and Pu-240, as well as the americium isotope Am-241 in samples of wastewater from nuclear facilities. It furthermore offers an option of determining the curium isotopes Cm-242 and Cm-244 without further effort. For determining Pu-241, reference is made to pro- cedure H-Pu-241-AWASS-01 of these measuring instructions. 2 Sampling As far as sampling is concerned, reference is made to procedure H-SPEKT- AWASS-01 of these measuring instructions. The sample of the wastewater to be analysed is acidified with ca. 10 ml of concentrated nitric acid (14 mol·l-1) per litre to a pH of about 1. The stability of the acidic reaction needs to be monitored, in particular if the sample is stored for an extended period of time. This procedure ensures that a detection limit of 0,05 Bq·l-1 for alpha-emitters is reached in a sample volume of 0,1 litres to 0,25 litres and thus complies with the nuclear safety standard 1504 of the Nuclear Safety Standards Commission (1). -
Adverse Health Effects of Heavy Metals in Children
TRAINING FOR HEALTH CARE PROVIDERS [Date …Place …Event …Sponsor …Organizer] ADVERSE HEALTH EFFECTS OF HEAVY METALS IN CHILDREN Children's Health and the Environment WHO Training Package for the Health Sector World Health Organization www.who.int/ceh October 2011 1 <<NOTE TO USER: Please add details of the date, time, place and sponsorship of the meeting for which you are using this presentation in the space indicated.>> <<NOTE TO USER: This is a large set of slides from which the presenter should select the most relevant ones to use in a specific presentation. These slides cover many facets of the problem. Present only those slides that apply most directly to the local situation in the region. Please replace the examples, data, pictures and case studies with ones that are relevant to your situation.>> <<NOTE TO USER: This slide set discusses routes of exposure, adverse health effects and case studies from environmental exposure to heavy metals, other than lead and mercury, please go to the modules on lead and mercury for more information on those. Please refer to other modules (e.g. water, neurodevelopment, biomonitoring, environmental and developmental origins of disease) for complementary information>> Children and heavy metals LEARNING OBJECTIVES To define the spectrum of heavy metals (others than lead and mercury) with adverse effects on human health To describe the epidemiology of adverse effects of heavy metals (Arsenic, Cadmium, Copper and Thallium) in children To describe sources and routes of exposure of children to those heavy metals To understand the mechanism and illustrate the clinical effects of heavy metals’ toxicity To discuss the strategy of prevention of heavy metals’ adverse effects 2 The scope of this module is to provide an overview of the public health impact, adverse health effects, epidemiology, mechanism of action and prevention of heavy metals (other than lead and mercury) toxicity in children. -
Anion Photoelectron Spectroscopic and Relativistic Coupled-Cluster Studies of − Uranyl Dichloride Anion, Uo2cl2 Mary Marshall, Zhaoguo Zhu, Junzi Liu, Kit H
Journal of Molecular Spectroscopy 379 (2021) 111496 Contents lists available at ScienceDirect Journal of Molecular Spectroscopy journal homepage: www.elsevier.com/locate/yjmsp Article Anion photoelectron spectroscopic and relativistic coupled-cluster studies of * uranyl dichloride anion, UO2Cl2 Mary Marshall, Zhaoguo Zhu, Junzi Liu, Kit H. Bowen, Lan Cheng < Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA ARTICLEINFO ABSTRACT Keywords: A joint relativistic coupled-cluster and experimental photoelectron (PE) spectroscopic study of the uranyl Coupled-cluster * dichloride anion, UO2Cl2 , is reported. Sophisticated electronic-structure calculations predict the photodetach- Anion photoelectron * ment of UO2Cl to involve a U 5f electron and to be followed by significant geometry relaxation. Therefore, the Uranyl 2 adiabatic electron affinity (EAa) of the uranyl dichloride neutral molecule, UO2Cl2, and the vertical detachment * energy (VDE) of its anion, UO2Cl2 , provide valuable information about its uranium 5f orbital energies. The EAa value was computed to be 3.15 eV. The VDE value was calculated to be 3.55 eV by augmenting the computed EAa with a shift derived from a Franck–Condon simulation using coupled-cluster potential energy surfaces. The VDE, which corresponds to the highest intensity peak in the PE spectrum, was measured to be 3.69 , 0.20 eV, in good agreement with the computed value. The origin transition in the PE spectrum, whose electron binding energy corresponds to the EAa, was assigned to the feature at 3.2 , 0.20 eV, consistent with the computed EAa. 1. Introduction at 20323 cm*1 with nearly harmonic vibrational progressions at a frequency of 840 cm*1 [15]. -
Periodic Table of the Elements Notes
Periodic Table of the Elements Notes Arrangement of the known elements based on atomic number and chemical and physical properties. Divided into three basic categories: Metals (left side of the table) Nonmetals (right side of the table) Metalloids (touching the zig zag line) Basic Organization by: Atomic structure Atomic number Chemical and Physical Properties Uses of the Periodic Table Useful in predicting: chemical behavior of the elements trends properties of the elements Atomic Structure Review: Atoms are made of protons, electrons, and neutrons. Elements are atoms of only one type. Elements are identified by the atomic number (# of protons in nucleus). Energy Levels Review: Electrons are arranged in a region around the nucleus called an electron cloud. Energy levels are located within the cloud. At least 1 energy level and as many as 7 energy levels exist in atoms Energy Levels & Valence Electrons Energy levels hold a specific amount of electrons: 1st level = up to 2 2nd level = up to 8 3rd level = up to 8 (first 18 elements only) The electrons in the outermost level are called valence electrons. Determine reactivity - how elements will react with others to form compounds Outermost level does not usually fill completely with electrons Using the Table to Identify Valence Electrons Elements are grouped into vertical columns because they have similar properties. These are called groups or families. Groups are numbered 1-18. Group numbers can help you determine the number of valence electrons: Group 1 has 1 valence electron. Group 2 has 2 valence electrons. Groups 3–12 are transition metals and have 1 or 2 valence electrons. -
Novel Heterometallic Uranyl-Transition Metal Materials: Structure, Topology, and Solid State Photoluminescence Properties † ‡ ‡ § Germań E
Article Cite This: Inorg. Chem. 2019, 58, 7243−7254 pubs.acs.org/IC Novel Heterometallic Uranyl-Transition Metal Materials: Structure, Topology, and Solid State Photoluminescence Properties † ‡ ‡ § Germań E. Gomez, J. August Ridenour, Nicole M. Byrne, Alexander P. Shevchenko, ‡ and Christopher L. Cahill*, † Instituto de Investigaciones en Tecnología Química (INTEQUI), Area de Química General e Inorganicá “Dr. G. F. Puelles,” Facultad de Química, Bioquímica y Farmacia, Chacabuco y Pedernera, Universidad Nacional de San Luis, Almirante Brown, 1455, 5700 San Luis, Argentina ‡ Department of Chemistry, The George Washington University, Science and Engineering Hall, 800 22nd Street, NW, Washington, DC 20052, United States § Samara Center for Theoretical Materials Science, Samara University, 34, Moskovskoye shosse, Samara, 443086, Russia *S Supporting Information ABSTRACT: Six new uranyl hybrid materials have been synthesized solvothermally ′ ′ ′ ′ ′′ utilizing the ligands 2,2 -bipyridine-3,3 -dicarboxylic acid (H2L) and 2,2 :6 ,2 -terpyridine (TPY). The six compounds are classified as either molecular complexes (I0O0 connectivity), · · [(UO2)(L)(TPY)] H2O(1), [Ni(TPY)2][(UO2)(L)2] 3H2O(2), and [Cu(TPY)2]- · − 0 3 [(UO2)(L)2] 3H2O(3), or 3D metal organic frameworks (MOFs, I O connectivity), · [Cu2(UO2)2(OH)(C2H3O2)(L)3(TPY)2] 6H2O(4), [Zn2(UO2)2(OH)(NO3)(C2H3O2)- · · (L)3(TPY)2] 4H2O(5), and Na[Ni(UO2)3(OH)(O)(L)3] 9H2O(6). A discussion of the influence of transition metal incorporation, chelating effects of the ligand, and synthesis conditions on the formation of uranyl materials is presented. The structure of compound 6 is of particular note due to large channel-like voids with a diameter of approximately 19.6 Å. -
Periodic Table 1 Periodic Table
Periodic table 1 Periodic table This article is about the table used in chemistry. For other uses, see Periodic table (disambiguation). The periodic table is a tabular arrangement of the chemical elements, organized on the basis of their atomic numbers (numbers of protons in the nucleus), electron configurations , and recurring chemical properties. Elements are presented in order of increasing atomic number, which is typically listed with the chemical symbol in each box. The standard form of the table consists of a grid of elements laid out in 18 columns and 7 Standard 18-column form of the periodic table. For the color legend, see section Layout, rows, with a double row of elements under the larger table. below that. The table can also be deconstructed into four rectangular blocks: the s-block to the left, the p-block to the right, the d-block in the middle, and the f-block below that. The rows of the table are called periods; the columns are called groups, with some of these having names such as halogens or noble gases. Since, by definition, a periodic table incorporates recurring trends, any such table can be used to derive relationships between the properties of the elements and predict the properties of new, yet to be discovered or synthesized, elements. As a result, a periodic table—whether in the standard form or some other variant—provides a useful framework for analyzing chemical behavior, and such tables are widely used in chemistry and other sciences. Although precursors exist, Dmitri Mendeleev is generally credited with the publication, in 1869, of the first widely recognized periodic table. -
Icp-Oes and Xas Investigation of the Phytoextraction of Lanthanides and Actinides from Aqueous Environmental Solutions 1J.G
ICP-OES AND XAS INVESTIGATION OF THE PHYTOEXTRACTION OF LANTHANIDES AND ACTINIDES FROM AQUEOUS ENVIRONMENTAL SOLUTIONS 1J.G. Parsons, 2J.L. Gardea-Torresdey, 1K.J. Tiemann, 1J.R. Peratta-Videa, 1E. Gomez, and 1J.H. Gonzalez 1Department of Environmental Science and Engineering, 500 W. University Ave., University of Texas at El Paso, El Paso TX. 79968; Phone: (915)747-5359; Fax: (915)747- 5748. 2Department of Chemistry, 500 W. University Ave, University of Texas at El Paso, El Paso, TX 79968; Phone: (915)747-5359; Fax: (915)747-5748. Abstract Use of nuclear power raises questions about nuclear waste, especially how it can be minimized and stored safely. One alternative is extraction and reprocessing of the uranium from the spent fuel. But the reprocessing of spent fuel is very expensive and requires use of ion exchange resins that cannot be reused. Some biomaterials have been studied for their ability to extract lanthanides and actinides, such as uranyl cation from solution. In this study, the extraction of uranyl nitrate, uranyl acetate, and europium nitrate from aqueous solution using an alfalfa biomaterial was investigated. Major factors affecting the sorption of cations from solution are pH, time, and interfering cations. Studies were performed to investigate each of the above parameters. In addition, capacity studies were performed for comparison purposes with common methods to extract these cations from solutions. To investigate the chemical environment where uranyl and europium cations were bound to the alfalfa biomass, X-ray absorption spectroscopy studies were performed. The X-Ray absorption near-edge structure showed that europium(III) and uranyl cations remained in the same oxidation state when bound to the biomass, with characteristic LIII-edge energies for uranyl and europium(III) of 17.172 keV and 6.981 keV, respectively.