DOCSLIB.ORG

Synthesis and Crystal Structure of a New Calcium-Containing Trimesate Coordination Polymer: [Ca3(Btc)2(H2O)12]∞

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Synthesis and Crystal Structure of a New Calcium-Containing Trimesate Coordination Polymer: [Ca3(Btc)2(H2O)12]∞ Synthesis and crystal structure of a new calcium-containing trimesate coordination polymer: [Ca3(btc)2(H2O)12]1. Magatte Camara, Carole Daiguebonne, Olivier Guillou, Albert Manga Badiane, Insa Badiane, Saïbatou Yague, Florence Le Dret To cite this version: Magatte Camara, Carole Daiguebonne, Olivier Guillou, Albert Manga Badiane, Insa Badiane, et al.. Synthesis and crystal structure of a new calcium-containing trimesate coordination polymer: [Ca3(btc)2(H2O)12]1.. Journal de la Société Ouest-Africaine de Chimie, Société Ouest-Africaine de Chimie, 2013, 035, pp.57-63. hal-01074624 HAL Id: hal-01074624 https://hal.archives-ouvertes.fr/hal-01074624 Submitted on 15 Oct 2014 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Journal de la Société Ouest-Africaine de Chimie J. Soc. Ouest-Afr. Chim. Code Chemical Abstracts : JSOCF2 Cote INIST (CNRS France) : <27680> ISSN 0796-6687 18èmeAnnée, Juin 2013, N° 035 Site Web: http://www.soachim.org J. Soc. Ouest-Afr. Chim. (2013) 035 ; 57 - 63 Synthesis and crystal structure of a new calcium-containing trimesate coordination polymer: [Ca3(btc)2(H2O)12]∞. Magatte Camaraa*, Carole Daiguebonneb,c, Olivier Guilloub,c, Albert Manga Badianea, Insa Badianea, Saïbatou Yaguea, Florence Le Dretb,c. aUniversité Assane Seck de Ziguinchor, LCPM – Groupe "Matériaux Inorganiques : Chimie Douce et Cristallographie", BP. 523 Ziguinchor – Sénégal bUniversité européenne de Bretagne, France. c INSA, UMR 6226 "Institut des Sciences Chimiques de Rennes", F-35708 Rennes. (Reçu le 10/04/2013 – Accepté après corrections le 30 /06/2013) Abstract : Reaction in gel between the sodium salt of 1,3,5-benzenetricarboxylic acid or trimesic (Na3[C6H3(COO)3] hereafter referenced as Na3btc) and calcium chloride has afforded single crystals of a bidimensional coordination polymer with chemical formula [Ca3(btc)2(H2O)12]∞. This compound crystallizes in the monoclinic system, space group C2/c (n° 15) with a = 19.3028 (16) Å, b = 11.4850 (9) Å, c = 13.0435 (12) Å, β = 106.394 (10)° and Z = 4. The crystal structure consists of a superposition of molecular planes that spread parallel to the, plane. Keywords : Ca(II); Crystal structure; Trimesate coordination polymers. Synthèse et caractérisation structurale d’un nouveau polymère de coordination à base de calcium et du ligand trimésate: [Ca3(btc)2(H2O)12]∞. Résumé : La réaction en milieu gel entre le sel de sodium de l'acide 1,3,5-benzènetricarboxylique ou trimésique (Na3 [C6H3 (COO)3] noté par la suite Na3btc) et le chlorure de calcium a donné des monocristaux d'un polymère de coordination bidimensionnel de formule chimique [Ca3(btc)2(H2O)12]∞. Ce composé cristallise dans le système monoclinique, groupe d'espace C2/c (n°15) avec a = 19,3028 (16) Å, b = 11,4850 (9) Å, c = 13,0435 (12) Å, β = 106,394 (10) ° et Z = 4. La structure cristalline consiste en une superposition de plans moléculaires se propageant parallèlement au plan, . Mots-clés : Ca(II); Structure cristalline; Polymères de coordination à base de l’acide trimésique. * Corresponding author: [email protected] , tel. (+221) 33938 85 86. fax: (+221) 33991 68 09 M. Camara et al 57 J. Soc. Ouest-Afr. Chim. (2013) 035 ; 57 - 63 1. Introduction. possible to obtain diffeifferent crystal structure by replacing an alkaline eartarth metal ion by another. Over the past few decaecades, a number of In order to initnitiate this study, we have coordination polymers have beenen published for their chosen to use Ca2+ as memetal ions because it is non- fascinating topologies coupled wwith their potential toxic and abundant in eearth crust and because its application in gas storageage[1-3], catalysis[4], ionic radius (1.00 Å) is similar to the one of the separation[5], luminescent devices[6,7] or lightest lanthanide ionions. Trimesate or 1,3,5- magnetism[8].For more than a dececade some of us are benzenetricarboxylate ligligand (hereafter symbolized engaged in that research field wiwith the objective of by btc2-) has been chosensen because it is a non-toxic designing new lanthanide-babased coordination and commercially availabilable ligand (See Scheme 1). polymers exhibiting interestesting luminescent Moreover, this ligand ppresents a great ability to properties[9,10] and/or porosity[11-13]. As far as this form infinite connectiontions with lanthanide metal second objective is targeted lalanthanide ions are ions[18-21] and a remarkakable versatility in adopting mainly used because of their abilibility to adopt various several different coordindination modes ranging from coordination modes. Actually,ly, it is generally unidentate to chelating aand bridging. At last, to the admitted that, due to the innennerness of their 4f best of our knowledge,, tthere are only few reported valence orbitals, lanthanide ions,s, in contrast with 3d trimesate coordination ppolymers that involve this metal ions, present only littlee ppreference in bond metallic cation[22,23]. direction[14]. However, shortagee oof these metals is a In lanthanide coordinatioion polymers three bonding global concern [15,16] and rationalalization of their use modes have been obsobserved according to the is mandatory. Therefore, we hhave undertaken a coordination environmenent of the COO− group [18,24] study in which alkaline earthh metal ions would as shown in Schemee 2: Mode I, acting as a replace lanthanide ions in coordordination polymers. unidentate ligand to bindind one metal ion; Mode II, Indeed, alkaline earth metall ions as well as acting as a bidentate ligangand to chelate one metal ion; lanthanide ions present little ppreference in bond Mode III, acting as a brbridging group between two direction and their coordination mmode is essentially metal ions. governed by steric hindrancee aand intermolecular In this paper wee wwish to report the synthesis interaction between ligands. MMoreover, alkaline and the crystal structurture of a new coordination earth ionic radii vary from 0.722 Å (Mg2+) to 1.35 Å polymer, [Ca (btc) (H OO) ] , that constitutes our (Ba2+) while lanthanide ionic radiadii vary from 0.86 Å 3 2 2 12 ∞ (Lu3+) to 1.03 Å (La3+)[17]. Therefrefore, it must be first result in this project. Scheme 1. 11,3,5-benzenetricarboxylate (or trimesate) ligandd ((btc3-). Modee I Mode II Modee IIIII Scheme 2. Bondingg mmodes in lanthanide-containing trimesate coordinaination polymers. M. Camara et al 58 J. Soc. Ouest-Afr. Chim. (2013) 035 ; 57 - 63 2. Experimental section hydrogen atoms. All non-hydrogen atoms were refined anisotropically using the SHELXL program 2.1 Synthesis [30]. Hydrogen atoms bound to the organic ligands Trimesic acid was purchased from Acros were localized at ideal positions. Hydrogen atoms Organics and used without further purification. of water molecules have not been localized. Calcium chloride was purchased from STREM Absorption corrections were performed using the Chemicals and used without further purification. Its facilities [29,31,32] included in the WINGX program sodium salt was prepared by addition of three suite [31].Crystal and final structure refinement data equivalents of sodium hydroxide to a suspension of are listed in Table I. Positional parameters, selected trimesic acid in de-ionized water until complete bond lengths and angles are listed in Tables II to dissolution. Then, the solution was evaporated to IV. dryness. The solid phase was then put in suspension in ethanol, stirred and refluxed during 1 h. After Table I. Crystal and final structure refinement data filtration and drying in a desiccator, a white powder for[Ca3(btc)2(H2O)12]∞. of tri-sodium trimesate was obtained. The yield of Molecular formula Ca3C18 O24H30 this synthesis is 90%. Anal. Calc.(found) for Formula weight 750.66 -1 System monoclinic C9H3O6Na3(MW = 276 g mol ) : C : 39.1%(39.0%) Space-group C2/c (n° 15) ; H : 1.1%(1.1%) ; O : 34.8%(34.5%) ; Na : a/Å 19.3028(16) 25.0%(25.4%). b/Å 11.4850(9) c/Å 13.0435(12) Single crystals of the coordination polymer α/° 90 were obtained by slow diffusions of dilute aqueous β/° 106.394(10) solutions of Ca(II) chloride (0.25 mmol in 20mL) γ/° 90 V/Å3 2774.1(4) and of sodium salt of trimesate (0.25 mmol in Z 4 -3 20mL) through an agar-agar gel bridge in a U- Dcalcd/g·cm 1.797 shaped tube. The gel was purchased from Acros F(000) 1560 µ/mm-1 0,703 Organics and jellified according to established Radiation Monochromated Mo Kα (λ = 0.71073 Å [25-27] procedure . After several weeks, colorless hkl Range -23 ≤ h ≤ 22; 0 ≤ k ≤ 14; 0 ≤ k ≤ 15 single crystals were obtained. θ Range (°) 2.09 ≤ θ ≤ 25.92 Data Collected 2547 Anal. Calc.(found) for [Ca3(btc)2(H2O)12]∞(MW = -1 Observed data (Fobs ≥ 1895 2 750.66 g mol ) : Ca : 16,0% (16,2%); C : 2σ (Fobs )) 28.8%(28.79%) ; H :4.0%(4.0%) ; O : Parameters refined 205 51.2%(51.0%). R (%) 4.14 Rw (%) 8.53 IR spectrum clearly shows vibration bands Goodness-of-fit 0.901 characteristic of the – (O– C – O) – groups around Final shift/error 0 -1 -1 a b 2 2 1/2 R1 = Σ[|Fo|-|Fc|]/Σ|Fo| ; Rw = [Σw(|Fo|-|Fc|) /Σw|Fo| ] 1560 cm and 1490 cm confirming the presence of 2 2 2 2 2 w = 1/[σ (Fo )+(0.0650×P) +42.0485×P] where P = (Fo +2×Fc )/3.
Load more

Recommended publications
  • Synthesis, X-Ray Structure and Properties of a Calcium(II) Coordination Polymer Showing Μ2-Η :Η and Μ3-Η :Η Coordination M
    Ms. Ref. No.: POLY-D-08-00248 (REVISED PAPER) Published in Polyhedron: 27(15); 2008; 3299-3305 Synthesis, X-ray structure and properties of a 1 1 calcium(II) coordination polymer showing µ2-η :η 2 1 and µ3-η :η coordination modes of 4-nitrobenzoate ∗ BIKSHANDARKOIL R SRINIVASAN , SANTOSH Y SHETGAONKAR, JYOTI V SAWANT, PALLEPOGU RAGHAVAIAH a Department of Chemistry, Goa University, Goa 403206 India email: [email protected] aPresent address: School of Chemistry, University of Hyderabad, Hyderabad, India 500 046 Abstract 1 2 The reaction of the monomeric compound [Ca(H 2O) 4(η -4-nba)( η -4-nba)] 1 (4-nba = 4-nitrobenzoate) with N-methylimidazole (N-MeIm) or imidazole (Im) at 100 oC results in the formation of the anhydrous mixed ligand complexes of composition [Ca(L)(4- nba) 2] (L=N-MeIm 2; L=Im 3). The compounds were characterized by elemental analysis, IR, UV-Vis and 1H NMR spectra, TG-DSC thermograms, weight loss studies and the structure of 2 was determined by single crystal X-ray crystallography. Compounds 2 and 3 can be transformed into 1 by heating with water. At elevated temperatures all compounds ( 1-3) are thermally decomposed to CaO. Compound 2 crystallizes in the centrosymmetric triclinic space group P ī with all atoms located in general positions. The structure reveals that 2 is a polymer and can be formulated as 1 1 2 1 catena -poly[[(N-methylimidazole)calcium(II)]( µ2-η :η -4-nitrobenzoato)( µ2-η :η -4- 1 1 2 1 nitrobenzoato)] . The structure of [[Ca(N-MeIm)]( µ2-η :η -4-nba)( µ3-η :η -4-nba)] n 2 2 consists of a central Ca(II) ion, a terminal N-MeIm ligand and two crystallographically independent 4-nba ligands.
    [Show full text]
  • Sonochemical Synthesis of Cadmium(II) Coordination Polymer Nanospheres As Precursor for Cadmium Oxide Nanoparticles
    crystals Article Sonochemical Synthesis of Cadmium(II) Coordination Polymer Nanospheres as Precursor for Cadmium Oxide Nanoparticles Farhad Akbari Afkhami 1 , Ali Akbar Khandar 1, Ghodrat Mahmoudi 2,* , Reza Abdollahi 3, Atash V. Gurbanov 4,5 and Alexander M. Kirillov 5,6,* 1 Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran; [email protected] (F.A.A.); [email protected] (A.A.K.) 2 Department of Chemistry, Faculty of Science, University of Maragheh, 55181-83111 Maragheh, Iran 3 Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran; [email protected] 4 Department of Organic Chemistry, Baku State University, Z. Khalilov str. 23, AZ 1148 Baku, Azerbaijan; [email protected] 5 Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal 6 Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya st., Moscow 117198, Russia * Correspondence: [email protected] (G.M.); [email protected] (A.M.K.) Received: 15 March 2019; Accepted: 2 April 2019; Published: 9 April 2019 Abstract: Nanospheres of a new coordination polymer {[Cd2(µ-HL)(µ-L)(NO3)3(H2O)]·H2O}n (1) were easily prepared by a sonochemical method from cadmium(II) nitrate and HL (HL, pyridine-2-carboxaldehyde isonicotinoyl hydrazone) in ethanol. Single crystals of 1 were also obtained using a branched tube method. The crystal structure of 1 indicates that the µ-HL/µ-L− blocks act as linkers between the Cd(II) centers, assembling them into 1D tooth-shaped interdigitated chains, which are further interlinked into a complex 3D H-bonded network with a rare hms (3,5-conn) topology.
    [Show full text]
  • Porous Coordination Polymers with Ubiquitous and Biocompatible Metals and a Neutral Bridging Ligand
    ARTICLE Received 30 Apr 2014 | Accepted 14 Nov 2014 | Published 16 Jan 2015 DOI: 10.1038/ncomms6851 OPEN Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand Shin-ichiro Noro1,2,3,4, Junya Mizutani2, Yuh Hijikata5, Ryotaro Matsuda3,6, Hiroshi Sato6, Susumu Kitagawa6, Kunihisa Sugimoto7, Yasutaka Inubushi8,w, Kazuya Kubo1,2 & Takayoshi Nakamura1,2 The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper materials and lead to enhanced biocompatibility, examples of magnesium(II) and calcium(II) PCPs are extremely limited compared with commonly used transition metal ones, because neutral bridging ligands have not been available for magnesium(II) and calcium(II) ions. Here we report a rationally designed neutral and charge-polarized bridging ligand as a new partner for magnesium(II) and calcium(II) ions. The three-dimensional magnesium(II) and calcium(II) PCPs synthesized using such a neutral ligand are stable and show selective adsorption and separation of carbon dioxide over methane at ambient temperature. This synthetic approach allows the structural diversification of Group II magnesium(II) and calcium(II) PCPs. 1 Research Institute for Electronic Science, Hokkaido University, Sapporo 001-0020, Japan. 2 Graduate School of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan. 3 PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi 332-0012, Japan. 4 Creative Research Institute (CRIS), Hokkaido University, Sapporo 001-0021, Japan.
    [Show full text]
  • A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties
    crystals Article A Cd(II) Coordination Polymer Based on Mixed Ligands: Synthesis, Crystal Structure, and Properties Shuai-Shuai Han, Zi-Wei He, Lei Li and Shui-Sheng Chen * College of Chemistry and Chemical Engineering, Fuyang Normal University, Fuyang 236041, China; [email protected] (S.-S.H.); [email protected] (Z.-W.H.); [email protected] (L.L.) * Correspondence: [email protected] Received: 11 November 2019; Accepted: 25 November 2019; Published: 27 November 2019 Abstract: A new coordination polymer, namely, [Cd(L)(frda)(H O)] 0.5L H O(1) was synthesized 2 · · 2 by hydrothermal reaction based on mixed multi-N donor 1-(4-(1H-imidazol-5-yl) phenyl)-1H- 1,2,4-triazole (L) and O-donor 2,5-furandicarboxylic acid ligands (H frda) with CdCl 2.5H O. 2 2· 2 Compound 1 was characterized by single-crystal x-ray diffraction, elemental analysis, and IR 2 spectroscopy. In 1, both the multi-N donor and O-donor frda − ligands act as linear two-connectors to bridge Cd(II) atoms, forming a two-dimensional (2D) layer. Interestingly, the parallel 2D layers stack in an AAA mode, and the infinite one-dimensional (1D) channels formed along the a-axis ··· direction, where the uncoordinated L molecules were embedded in the void. Furthermore, the weak interactions including the rich hydrogen bonding and π π stacking interactions progress the 2D − structure into a three-dimensional (3D) supramolecular polymer. Diffuse reflectance spectra and the luminescent property were also investigated. Keywords: coordination polymer; characterization; optical property 1. Introduction Coordination polymers (CPs) consisting of organic ligands and metal ions have attracted an upsurge in research during the past decades, due to their charming structures and their possibly applied domain of luminescence [1–4], gas adsorption/separation [5,6], proton conductivity [7], chemical separations [8], catalysis [9], and so on.
    [Show full text]
  • Crown Ethers and Their Alkali Metal Ion Complexes As Assembler Groups in Uranyl–Organic Coordination Polymers With
    Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis -1,3-, cis -1,2-, and trans -1,2-Cyclohexanedicarboxylates Pierre Thuéry, Youssef Atoini, Jack Harrowfield To cite this version: Pierre Thuéry, Youssef Atoini, Jack Harrowfield. Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis -1,3-, cis -1,2-, and trans - 1,2-Cyclohexanedicarboxylates. Crystal Growth & Design, American Chemical Society, In press, 18 (5), pp.3167-3177. 10.1021/acs.cgd.8b00266. cea-01759418 HAL Id: cea-01759418 https://hal-cea.archives-ouvertes.fr/cea-01759418 Submitted on 6 Apr 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Crown Ethers and their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis -1,3-, cis -1,2- and trans -1,2-Cyclohexanedicarboxylates Pierre Thuéry* ,† Youssef Atoini ‡ and Jack Harrowfield*,‡ †NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette, France ‡ISIS, Université de Strasbourg, 8 allée Gaspard Monge, 67083 Strasbourg, France ABSTRACT: Alkali metal cations (Na +, K +) and crown ether molecules (12C4, 15C5, 18C6) were used as additional reactants during the hydrothermal synthesis of uranyl ion complexes with cis /trans -1,3-, cis -1,2- and trans -1,2- cyclohexanedicarboxylic acids ( c/t-1,3-chdcH2, c-1,2-chdcH2 and t-1,2-chdcH2, respectively, the latter as racemic or pure (1 R,2 R) enantiomer).
    [Show full text]
  • Coordination Polymers, Metal-Organic Frameworks and the Need for Terminology Guidelines
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE Accepted manuscript: CrystEngComm, 2012,14, 3001-3004 provided by Chalmers Publication Library DOI: 10.1039/C2CE06488J, http://pubs.rsc.org/en/content/articlelanding/2012/ce/c2ce06488j Coordination Polymers, Metal-Organic Frameworks and the Need for Terminology Guidelines Stuart R. Battena, Neil R. Champnessb, Xiao-Ming Chenc, Javier Garcia-Martinezd, Susumu Kitagawae, Lars Öhrströmf*, Michael O’Keeffeg, Myunghyun Paik Suhh and Jan Reedijki,j Coordination Polymers (CP) and Metal-Organic Frameworks (MOF) are among the most prolific research areas of inorganic chemistry and crystal engineering in the last 15 years, and yet it still 5 seems that consensus is lacking about what they really are, or are not. Background Nomenclature and terminology should always create added value. They are tools to incorporate new results into the greater weave of science and enable us to go from the specific to the general. New terminology should also help us to constructively discuss new compounds, 10 materials and phenomena without having to proceed through endless preambles of definitions. When two or more sub-disciplines of science find themselves preparing and analysing similar kinds of new materials, an ad hoc terminology often develops from different viewpoints and may not naturally converge into a self-consistent and logical result. This dual situation occurs for Coordination Polymers (CP)1 and Metal-Organic Frameworks 2 15 (MOF) , compounds generated in interdisciplinary research fields with their origins in solid state, inorganic and coordination chemistry that have expanded rapidly during the last 15 years. The diversity in both focus and scientific basis of the researchers involved has lead to numerous terminology suggestions and practices for this class of compounds and of several subgroups within them;3 additionally, a disquieting number of acronyms are also in use for these materials.
    [Show full text]
  • One Dimensional Coordination Polymers Based on Bridging N,N Donor Ligands
    One Dimensional Coordination Polymers Based on Bridging N,N Donor Ligands Der Naturwissenschaftlichen Fakultät der Friedrich-Alexander-Universität Erlangen-Nürnberg zur Erlangung des Doktorgrades Dr. rer. nat. vorgelegt von Nico Fritsch aus Forchheim Als Dissertation genehmigt von der Naturwissen- schaftlichen Fakultät der Friedrich-Alexander-Universität Erlangen-Nürnberg Tag der mündlichen Prüfung: 13. Juni 2014 Vorsitzender des Promotionsorgans: Prof. Dr. Johannes Barth Gutachter: Prof. Dr. Nicolai Burzlaff Prof. Dr. Julien Bachmann Die vorliegende Arbeit entstand in der Zeit von Juni 2011 bis März 2014 im Department für Chemie und Pharmazie (Lehrstuhl für Anorganische und Metallorganische Chemie) der Friedrich-Alexander-Universität Erlangen-Nürnberg unter der Anleitung von Prof. Dr. Nicolai Burzlaff. Teile dieser Dissertation wurden bereits veröffentlicht: “trans-1,2-Bis(N-methylimidazol-2-yl)ethylene: Towards Building Blocks of 2D Fabrics and MML-Type 2D Molecular Strands”, N.V. Fischer, M. S. Alam, I. Jum´h, M. Stocker, N. Fritsch, V. Dremov, F.W. Heinemann, N. Burzlaff, P. Müller, Chem. – Eur. J., 2011, 17, 9293-9297. “Battlement-shaped 1D coordination polymer based on bis(N-methylimidazole-2yl)butadiyne ligand”, T. Waidmann, N. Fritsch, J. Tucher, M. Rudolf, F. Glaser, D.M. Guldi, N. Burzlaff, CrystEngComm, 2013, 10157-10160. – Reproduced by permission of The Royal Society of Chemistry. You can´t always get what you want. But if you try sometimes you might find, You get what you need. (Sir Mick Jagger) Table of contents 1! GENERAL INTRODUCTION ............................................................................................ 1! 1.1! From metal organic frameworks to 1D coordination polymers ........................................... 2! 1.2! Different concepts of molecular wires .................................................................................... 5! 1.2.1! Organic based molecular wires ..........................................................................................
    [Show full text]
  • A Supramolecular Coordination Polymer Derived Electrocatalyst for Oxygen Evolution Reaction
    A Supramolecular Coordination Polymer Derived Electrocatalyst for Oxygen Evolution Reaction Chi Zhang,a Chen Zhang,b Yunchao Xie,a Xiaoqing He,c Tommi White,c d Derek Demaree,e Mark H. Griep,e Jerry L Atwood*b and Jian Lin*a a. Department of Mechanical & Aerospace Engineering, University of Missouri, Columbia, Missouri 65211, United States. E- mail: [email protected] b. Department of Chemistry, University of Missouri, Columbia, Missouri 65211, United States. E-mail: [email protected] c. Electron Microscopy Core Facility, University of Missouri, Columbia, MO 65211, United States d. Department of Biochemistry, University of Missouri, Columbia, MO 65211, United States e. U.S. Army Research Laboratory, 4600 Deer Creek Loop, Aberdeen Proving Groun, Maryland 21005, United States An iron oxide decorated nickel iron alloy nanoparticle/porous graphene hybrid exhibits high electrocatalytic activity and excellent durability toward oxygen evolution reaction (OER). It displays a LOW overpotential of 274 mV at 10 mA/cm2, and low Tafel slope of 37 mV/dec, showing a superior performance to the state-of-the-art RuO2 OER electrcatalyts. Scanning electron microscopy (SEM) was performed to characterize the morphology and structure. Fig. 1b shows that the nanoparticles are well dispersed on the surface of the LIG sheets. The corresponding elemental mapping confirms the existence of the C, O, Fe, and Ni elements and their uniform dispersion. High-resolution TEM (HRTEM) was further performed to investigate the nanostructures in more details. The HRTEM image (Fig. 1d) reveals well-resolved lattice fringes with interplanar distances of 0.205 nm, 0.290 nm and 0.364 nm, of Fe3O4 and (002) plane of graphene, respectively.
    [Show full text]
  • Mossbauer Spectroscopic Studies of Complexes of Fe(III) with Nitrogen Containing Polymers
    Polymer Journal, Vol. 23, No. 4, pp 339~342 (1991) NOTES Mossbauer Spectroscopic Studies of Complexes of Fe(III) with Nitrogen Containing Polymers E. A. BEKTUROV, S. E. KUDAIBERGENOV, G. S. KANAPYANOVA, S. S. SALTYBAEVA, A. I. SKUSHNIKOVA, A. L. PAVLOVA, and E. S. DoMNINA * Institute of Chemical Science, Kazakh SSR Academy of Sciences, Alma-Ata 480100, Krasin Str. 106, USSR * Institute of Organic Chemistry Siberian Branch of Academy of Sciences of the USSR, Irkutsk, USSR (Received July 30, I 990) KEY WORDS Nitrogen Containing Polymers / Complex Formation / Mossbauer Spectroscopy / Coordination polymer compounds have EXPERIMENT AL been successfully used in various catalytic processes such as hydrogenation, oxidation, P2VPy, P2M5VPy, and P4VPy were synthe­ hydroformylation, polymerization, isomeriza­ sized by the radical polymerization of mono­ tion, etc. 1 Nitrogen containing polymers are mers in methanol at 333 K in presence of interesting polymer ligands that function as azobisisobutyronitrile (AIBN) as initiator. 8 supports in catalysis. Copolymers based on VI and VP were Complex formation ability of nitrogen synthesized by radical copolymerization in containing polymers in relation to the transi­ ethanol at 333 Kin the presence of AIBN. All tion metal ions is due to the presence of polymers and copolymers were purified by primary, secondary and tertiary aminogroups fractional precipitation. The compositions of which are able to form donor-acceptor copolymers were determined by IR spectros­ bonds. 2 - 7 The structures of coordination copy9 and by elemental analysis. PVI with compounds influence on the catalytic activity molecular weight 16 x l 03 and commercial of polymer-metal complexes. sample of PVP with molecular weight 5.6 x 10 5 In the present paper the results of an were used.
    [Show full text]
  • A New Calcium(II) Coordination Polymer Based on a Μ2-Bridging Tridentate 4-Nitrobenzoate
    Indian Journal of Chemistry Vol. 51A, March 2012, pp. 435-443 A new calcium(II) coordination polymer based on a µ2-bridging tridentate 4-nitrobenzoate Bikshandarkoil R Srinivasana, *, Santosh Y Shetgaonkara, Manav Saxenab & Christian Nätherc aDepartment of Chemistry, Goa University, Goa 403 206, India Email: [email protected] bDepartment of Chemistry, Indian Institute of Technology, Kanpur, 208 016 India cInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany Received 17 September 2011; revised and accepted 16 January 2012 Reaction of a heptacoordinated Ca(II) compound [Ca(H2O)4(4-nba)2] (4-nba = 4-nitrobenzoate) with 3,5-dimethyl- pyrazole (dmp) leads to the formation of an eight coordinated Ca(II) compound, [[Ca(H2O)2(4-nba)2]·2dmp]n, containing two coordinated water molecules, two unique 4-nba ligands and two free dmp molecules in the lattice. The µ2-bridging tridentate binding mode of the unique 4-nba ligands results in the formation of a one-dimensional (1-D) coordination polymer. The title compound exhibits enhanced fluorescence emission. An analysis of the six different bridging binding modes of the 4-nba ligand in twenty two different structurally characterized 4-nitrobenzoate compounds is described. Keywords: Coordination chemistry, Calcium, 4-Nitrobenzoates, 3,5-Dimethylpyrazole, Coordination polymers, Metal organic frameworks Coordination polymers (CPs) also known as metal differing dimensionalities can be constructed. For the organic frameworks (MOFs) have attracted much oxophilic s-block metals, carboxylic acids are useful attention because of their topology and applications in linkers for the construction of coordination polymers catalysis, adsorption (gas storage), separation and as the metals can be linked into an extended chain luminescence1-3.
    [Show full text]
  • Synthesis and Characterization of a New Strontium(II) Coordination Polymer Based on a Μ2-Tridentate Bridging Zwitterionic Glyci
    Published in: Journal of Coordination Chemistry: 64(13); 2011; 2274-2283. Synthesis and characterization of a new strontium(II) coordination polymer based on a µ2-tridentate bridging zwitterionic glycine aS. Natarajan *, aJ. Kalyana Sundar, bS. Athimoolam, cBikshandarkoil R. Srinivasan a *School of Physics, Madurai Kamaraj University, Madurai 625 021, India b Department of Physics, University College of Engineering Nagercoil, Anna University of Technology Tirunelveli, Nagercoil 629 004, India c Department of Chemistry, Goa University, Goa 403206, India Abstract The synthesis and characterization of a new Sr(II) coordination polymer [Sr(H 2O)(H- gly)2Cl2]n 1 (H-gly = glycine) is described. Compound 1 crystallizes in the centrosymmetric orthorhombic space group Pcnb and its structure consists of a central Sr(II) ion, a terminal water, a unique zwitterionic glycine and a chloride ion. The central metal is nine coordinated and is bonded to six oxygen atoms from four different bridging H-gly ligands, two symmetry related chloride ions and a terminal water. The µ2-tridentate bridging nature of the zwitterionic glycine results in the formation of a one dimensional coordination polymer with a Sr···Sr separation of 4.560 Å across the chain. The chloride, H-gly and the coordinated water are involved in five varieties of H-bonding interactions. A comparative study of the structural chemistry of several alkaline-earth glycine compounds is described. Keywords: Coordination polymer; strontium; glycine; zwitterion. 1 REVISED MANUSCRIPT GCOO-2011-0182 1. Introduction Coordination polymers (CPs) also known as metal organic frameworks (MOFs) have attracted much attention because of their topology and applications in catalysis, adsorption (gas storage), separation, luminescence [1-3].
    [Show full text]
  • New Antibacterial Silver(I) Coordination Polymers Based on a Flexible Ditopic Pyrazolyl-Type Ligand
    polymers Article New Antibacterial Silver(I) Coordination Polymers Based on a Flexible Ditopic Pyrazolyl-Type Ligand 1, 2 3 1, Aurel Tăbăcaru * , Claudio Pettinari , Mariana Bus, ilă and Rodica Mihaela Dinică * 1 Faculty of Sciences and Environment, Department of Chemistry, Physics and Environment, “Dunarea de Jos” University of Galati, 111 Domneasca Street, 800201 Galat, i, Romania 2 School of Pharmacy, University of Camerino, Via Madonna delle Carceri 9, 62032 Camerino MC, Italy; [email protected] 3 Department of Materials Science and Engineering, Faculty of Engineering, ”Dunarea de Jos” University of Galati, 111 Domneasca Street, 800201 Galat, i, Romania; [email protected] * Correspondence: [email protected] (A.T.); [email protected] (R.M.D.) Received: 1 October 2019; Accepted: 10 October 2019; Published: 15 October 2019 Abstract: In the last two decades, a tremendous amount of attention has been directed towards the design of antibacterial silver(I)-based materials, including coordination polymers (CPs) built up with a great variety of oxygen and nitrogen-containing ligands. Herein, a family of six new silver(I)-based CPs, having the general stoechiometric formula [Ag(H2DMPMB)(X)] (X = NO3, 1; CF3CO2, 2; CF3SO3, 3; BF4, 4; ClO4, 5; and PF6, 6) and incorporating the flexible ditopic pyrazolyl-type ligand 4,40-bis((3,5-dimethyl-1H-pyrazol-4-yl)methyl)biphenyl (H2DMPMB), has been prepared by the chemical precipitation method involving the reaction of silver(I) salts with H2DMPMB in the 1:1 molar ratio, in alcohols, or acetonitrile at room temperature for two-hours. The new silver(I)-based polymeric materials were characterized by means of Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA), and thermogravimetric analysis (TGA), allowing for the proposition that their structures comprise one-dimensional chains, with the silver(I) ions mostly assuming a T-shapped stereochemistry completed by the exo-bidentate ligands and counter-anions.
    [Show full text]