Amendments to Precautionary Statement P280

UN/SCETDG/42/INF.8/Add.1 UN/SCEGHS/24/INF.5/Add.1 Committee of Experts on the Transport of Dangerous Goods and on the Globally Harmonized System of Classification and Labelling of Chemicals 29 November 2012

Sub-Committee of Experts on the Sub-Committee of Experts on the Globally Harmonized Transport of Dangerous Goods System of Classification and Labelling of Chemicals

Forty-second session Twenty-fourth session Geneva, 3– 11 December 2012 Geneva, 12–14 December 2012 Item 8 (e) of the provisional agenda Item 2 (d) of the provisional agenda Updating of the Globally Harmonized System of Issues relating to the Globally Harmonized System Classification and Labelling of Chemicals (GHS): of Classification and Labelling of Chemicals: Annexes Miscellaneous

Amendments to precautionary statement P280

Transmitted by the expert from the United Kingdom on behalf of the informal correspondence group on Annexes 1-3 of the GHS

Introduction

1. This paper proposes an adjustment to one of the proposals in ST/SG/AC.10/C.4/2012/19 to amend the precautionary statements in Annex 3 of the GHS. The adjustment addresses an issue that arose during completion of information document INF.5 (GHS, 24th session) –INF.8 (TDG, 42nd session). 2. Precautionary statement P280 currently reads “Wear protective gloves/protective clothing/eye protection/face protection.” The conditions for use contain further instructions on the type of equipment to be specified for some hazard classes, e.g. “specify protective gloves/clothing. Manufacturer/supplier or the competent authority to specify type of equipment.”. However it is not clear whether in this case the label should just read “Wear protective gloves/clothing”, or whether an additional specification of the type of gloves or clothing should be made. 3. The proposal below makes it clear that an additional specification of the type of equipment, for example, to specify the material of gloves that are required (e.g. “wear nitrile gloves”) may be appropriate. 4. For some hazard classes, it has been proposed in ST/SG/AC.10/C.4/2012/19 to remove the specific instruction as to the type of equipment, so that the condition for use simply reads “manufacturer/supplier or the competent authority to specify the appropriate type of equipment”. In these cases no change is required since the intention is already clear. 5. Table A3.2.2 and the matrix tables in A3.3.5 of the GHS, as amended to take into account the new condition for use for P280 proposed in this document are reproduced in annexes 1 and 2. UN/SCETDG/42/INF.8/Add.1 UN/SCEGHS/24/INF.5/Add.1 Proposal

6. Replace the amendment to P280 in document ST/SG/AC.10/C.4/2012/19 and in annex 1 to informal document INF.5 (GHS) – INF.8 (TDG), with the following:

“For P280 For Explosives (chapter 2.1): Remove the condition for use “- specify face protection” and amend the remaining wording to read: “manufacturer/supplier or the competent authority to specify the appropriate type of equipment”. For the group of hazard classes “Acute toxicity (dermal)”, “Skin corrosion”, “skin irritation”, “skin sensitisation”, “severe eye damage” and “eye irritation”: in the condition for use, replace “Manufacturer/supplier or the competent authority to specify type of equipment” with “Manufacturer/supplier or the competent authority may further specify type of equipment where appropriate”. For the group of hazard classes “Flammable liquids”, “Flammable solids”, “self- reactive substances and mixtures”, “pyrophoric liquids”, “pyrophoric solids”, “self- heating substances and mixtures”, “Substances and mixtures which, in contact with water, emit flammable gases”, “oxidizing liquids”, “oxidizing solids” and “Organic peroxides”: remove the condition for use: “- specify protective gloves and eye/face protection” and amend the remaining wording to read: “manufacturer/supplier or the competent authority to specify the appropriate type of equipment”. For the group of hazard classes “Germ cell mutagenicity”, “carcinogenicity” and “reproductive toxicity”: amend the condition for use to read “manufacturer/supplier or the competent authority to specify the appropriate type of equipment”.”

2 Annex 1 Changes to precautionary statement P280 in table A3.2.2

Code Prevention Hazard class Hazard Conditions for use Explanation/Justification precautionary category statements

(1) (2) (3) (4) (5) P280 Wear protective Explosives (chapter 2.1) Unstable Manufacturer/supplier or the compet- Slash is appropriate because gloves/protective explosives ent authority to specify the appropri- manufacturer/supplier or the ate type of equipment. clothing/eye and competent authority should protection/face divisions choose which phrase is protection. 1.1, 1.2, appropriate. 1.3, 1.4, 1.5 Proposal to amend the conditions for use: Face protection is not always

appropriate, appropriate U

protection should rather be /

specified. E

Flammable liquids (chapter 2.6) 1, 2, 3, 4 Manufacturer/supplier or the Proposal to amend the D

competent authority to specify the / Flammable solids (chapter 2.7) 1, 2 conditions for use: 4

appropriate type of equipment. / Appropriate protection should I Self-reactive substances and mixtures (chapter 2.8) Types A, B, N be specified. F

C, D, E, F 8

Pyrophoric liquids (chapter 2.9) 1 d

Pyrophoric solids (chapter 2.10) 1

Self-heating substances and mixtures (chapter 2.11) 1, 2 U

Substances and mixtures which, in contact with water, emit 1, 2, 3 C

flammable gases (chapter 2.12) G

Oxidizing liquids (chapter 2.13) 1, 2, 3 S

Oxidizing solids (chapter 2.14) 1, 2, 3 /

Organic peroxides (chapter 2.15) Types A, B, A

C, D, E, F A

Code Prevention Hazard class Hazard Conditions for use Explanation/Justification /

precautionary category

statements T

(1) (2) (3) (4) (5) /

Acute toxicity – dermal (chapter 3.1) 1, 2, 3, 4 - Specify protective gloves/clothing. Proposal to amend the F

Manufacturer/supplier or the compet- conditions for use: A ent authority may further specify d The proposal makes it clear d

. type of equipment where appropriate. 1

that an additional specification –

Skin corrosion (chapter 3.2) 1A, 1B, 1C - Specify protective gloves/clothing U

of the type of equipment, for N

/ and eye/face protection. example, to specify the S

Manufacturer/supplier or the compet- material of gloves that are E ent authority may further specify G required (e.g. “wear nitrile H

type of equipment where appropriate. S

gloves”) may be appropriate. 2 Skin irritation (chapter 3.2) 2 - Specify protective gloves. 4

I Manufacturer/supplier or the N Skin sensitization (chapter 3.4) 1, 1A, 1B F

. competent authority may further 5

specify type of equipment where d

appropriate. 1 Severe eye damage (chapter 3.3) 1 - Specify eye/face protection. Eye irritation (chapter 3.3) 2A Manufacturer/supplier or the competent authority may further specify type of equipment where appropriate. Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2 Manufacturer/supplier or the Proposal to amend the Carcinogenicity (chapter 3.6) 1A, 1B, 2 competent authority to specify the conditions for use: appropriate type of equipment. Reproductive toxicity (chapter 3.7) 1A, 1B, 2 Appropriate protection should be specified. Annex 2

Tables in A3.3.5 of the GHS as amended to take into account the new condition for use for P280 proposed in this document EXPLOSIVES (Chapter 2.1) Symbol Exploding bomb

Hazard category Signal word Hazard statement

Unstable explosive Danger H200 Unstable explosive

Precautionary statements

Prevention Response Storage Disposal

P201 P370+P372+P380+P373 P401 P501

Obtain special instructions before use. In case of fire: Explosion risk. Store in accordance with... Dispose of contents/container to ... U

P250 Evacuate area. DO NOT fight / …Manufacturer/supplier or the S Do not subject to grinding/shock/friction/... fire when fire reaches explosives. C competent authority to specify …in accordance with local/regional/ E - if the explosive is mechanically sensitive. T . local/regional/ national/international national/international regulations (to D

…Manufacturer/supplier or the competent G

regulations as applicable. be specified). / authority to specify applicable rough handling. 4

Manufacturer/supplier or the /

I P280 N competent authority to specify F

Wear protective gloves/protective 8

whether disposal requirements apply / clothing/eye protection/face protection. A to contents, container or both. d Manufacturer/supplier or the competent d

authority to specify the appropriate type of

equipment. U

1 4 A U

EXPLOSIVES x C

(Chapter 2.1) T

Symbol /

Exploding bomb /

Hazard category Signal word Hazard statement F

/ Division 1.1 Danger H201 Explosive; mass explosion hazard A

Division 1.2 Danger H202 Explosive; severe projection hazard 1

Division 1.3 Danger H203 Explosive; fire, blast or projection hazard U

Precautionary statements S

Prevention Response Storage Disposal E

P210 P401 H P370 +P372+P380+P373 P501 S

Keep away from heat, hot surfaces, Store in accordance with... 2

In case of fire: Explosion risk. Dispose of contents/container to ... 4

sparks, open flames and other ignition …Manufacturer/supplier or the I

Evacuate area. DO NOT fight fire … in accordance with local/ N

sources. No smoking. competent authority to specify F

when fire reaches explosives. . local/regional/national/international regional/national/international 5

/ regulations (to be specified). A P230 regulations as applicable. d

Keep wetted with... Manufacturer/supplier or the .

1 - for substances and mixtures which are competent authority to specify wetted, diluted, dissolved or suspended with whether disposal requirements apply a phlegmatizer in order to reduce or to contents, container or both. suppress their explosive properties (desensitized explosives). … Manufacturer/supplier or the competent authority to specify appropriate material. - P234 Keep only in original packaging. P240 Groundand bond container and receiving equipment. - if the explosive is electrostatically sensitive. P250 Do not subject to grinding/shock/friction/.... - if the explosive is mechanically sensitive. …Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

1 4 A U

EXPLOSIVES x C

(Chapter 2.1) T

Symbol /

Exploding bomb /

/ Division 1.4 H204 Fire or projection hazard A

Precautionary statements N

Prevention Response Storage Disposal C

E P210 P401 P501 G P370+P372+P380+P373 H Keep away from heat, hot surfaces, sparks, Store in accordance Dispose of contents/container to... S In case of fire: Explosion risk .Evacuate /

area. DO NOT fight fire when fire reaches 4

open flames and other ignition sources. No with... … in accordance with /

I smoking. explosives. …Manufacturer/supplier local/regional/national/international N

- except for explosives of division 1.4 . or the competent authority regulations (to be specified). 5

/ (compatibility group S) in transport A

P234 to specify local/regional/ Manufacturer/supplier or the d packaging. d

. Keep only in original packaging. national/international competent authority to specify 1 P240 P370+P380+P375 regulations as applicable. whether disposal requirements apply Ground and bond container and receiving In case of fire: Evacuate area. Fight fire to contents, container or both. equipment. remotely due to the risk of explosion. - if the explosive is electrostatically sensitive. - for explosives of division 1.4 (compatibility P250 group S) in transport packaging Do not subject to grinding/shock/friction/…. - if the explosive is mechanically sensitive. …Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment. EXPLOSIVES (Chapter 2.1) Symbol No symbol Hazard category Signal word Hazard statement Division 1.5 Danger H205 May mass explode in fire Precautionary statements Prevention Response Storage Disposal P210 P370 + P372 + P380 + P373 P401 P501 Keep away from heat, hot surfaces, sparks, In case of fire: Explosion risk. Evacuate Store in accordance with... Dispose of contents/container to ... open flames and other ignition sources. No area. DO NOT fight fire when fire …Manufacturer/supplier or … in accordance with local/regional/ smoking. reaches explosives. the competent authority to national/international regulations (to specify local/regional/ be specified). P230 national/international Manufacturer/supplier or the Keep wetted with... regulations as applicable. competent authority to specify - for substances and mixtures which are whether disposal requirements apply wetted, diluted, dissolved or suspended with a to contents, container or both.

phlegmatizer in order to reduce or suppress U

their explosive properties (desensitized /

explosives). E

… Manufacturer/supplier or the competent D

authority to specify appropriate material. /

I P234 N

. Keep only in original packaging. 8

P240 d

Ground and bond container and receiving 1

equipment U

- if the explosive is electrostatically sensitive. /

P250 E Do not subject to grinding/shock/friction/…. G

- if the explosive is mechanically sensitive. /

…Manufacturer/supplier or the competent F

authority to specify applicable rough handling. A

4 P280

1 4 A U

Wear protective gloves/protective /

clothing/eye protection/face protection.

Manufacturer/supplier or the competent T

authority to specify the appropriate type of G

equipment. 2

1 FLAMMABLE LIQUIDS (Chapter 2.6) Symbol Flame Hazard category Signal word Hazard statement 1 Danger H224 Extremely flammable liquid and vapour 2 Danger H225 Highly flammable liquid and vapour 3 Warning H226 Flammable liquid and vapour

1 4 A U

Precautionary statements n

E Prevention Response Storage Disposal 2

P210 P303 + P361 + P353 P403 + P235 P501 D Keep away from heat, hot surfaces, sparks, open IF ON SKIN (or hair): Take off G

Store in a well- Dispose of contents/container to... 4

flames and other ignition sources. No smoking. immediately all contaminated clothing. 2

ventilated place. Keep I Rinse skin with water [or shower]. N

cool. … in accordance with F

P233 . - text in square brackets to be included 8

/ Keep container tightly closed. where the manufacturer/supplier or the - for flammable liquids local/regional/national/international A

- if the liquid is volatile and may generate an explosive competent authority consider it Category 1 and other regulations (to be specified). d

atmosphere. appropriate for the specific chemical.

flammable liquids that Manufacturer/supplier or the –

P240 P370 + P378 are volatile and may competent authority to specify U

Ground and bond container and receiving In case of fire: Use ... to extinguish. / generate an explosive whether disposal requirements S equipment - if water increases risk. C atmosphere. apply to contents, container or E - if the liquid is volatile and may generate an ... Manufacturer/supplier or the G

both. H competent authority to specify explosive atmosphere. S

/ appropriate media. 2 P241 4

I Use explosion-proof [electrical/ventilating/ N

lighting/...]equipment. 5

- if the liquid is volatile and may generate and d

explosive atmosphere. 1 - may be omitted where local or national legislation introduces more specific provisions. - text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.

P242 Use non-sparking tools. - if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the minimum ignition energy is <0.1mJ, e.g. carbon disulfide). P243 Take action to prevent static discharges. - if the liquid is volatile and may generate an explosive atmosphere. - may be omitted where local or national legislation introduces more specific provisions. P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

1 4 A U

FLAMMABLE LIQUIDS x C

(Chapter 2.6) T

Symbol G

No symbol 2

4 Warning H227 Combustible liquid A

Precautionary statements .

Prevention Response Storage Disposal U

P210 P370 + P378 P403 P501 S Keep away from heat, hot surfaces, sparks, In case of fire: Use ... to extinguish. C Store in a well-ventilated place. Dispose of contents/container to... E open flames and other ignition sources. No - if water increases risk. G - for flammable liquids in accordance with local/regional/ H

smoking. ... Manufacturer/supplier or the S Category 1 and other flammable national/international regulations (to /

P280 competent authority to specify 4 liquids that are volatile and may be specified). /

I Wear protective gloves/protective clothing/eye appropriate media. N generate an explosive Manufacturer/supplier or the F

protection/face protection. 5

atmosphere. / competent authority to specify A Manufacturer/supplier or the competent authority

whether disposal requirements apply d

to specify the appropriate type of equipment. . to contents, container or both. 1 FLAMMABLE SOLIDS (Chapter 2.7) Symbol Flame Hazard category Signal word Hazard statement 1 Danger H228 Flammable solid 2 Warning H228 Flammable solid

Precautionary statements Prevention Response Storage Disposal P210 P370 + P378 Keep away from heat, hot surfaces, sparks, In case of fire: Use ... to extinguish open flames and other ignition sources. No - if water increases risk. smoking. ... Manufacturer/supplier or the competent authority to specify appropriate media. P240 Ground and bond container and receiving equipment.

- if the solid is electrostatically sensitive. N

/ P241 S

Use explosion-proof [electrical/ventilating/ E

lighting/...]equipment. D

- if dust clouds can occur. N

- may be omitted where local or national 8

/ legislation introduces more specific A

provisions. .

- text in square brackets may be used to

specify specific electrical, ventilating, lighting N

or other equipment if necessary and as C

appropriate.P280 G Wear protective gloves/protective H

/ clothing/eye protection/face protection. 2

Manufacturer/supplier or the competent N

authority to specify the appropriate type of A

equipment. n

1 4 A U

SELF-REACTIVE SUBSTANCES AND MIXTURES x C

(Chapter 2.8) T

Symbol G

/ Exploding bomb 4

I Hazard category Signal word Hazard statement N

. Type A 8 Danger H240 Heating may cause an explosion /

1 Precautionary statements Prevention Response Storage Disposal P210 P403 P501 Keep away from heat, hot surfaces, P370 + P372 + P380 + P373 Store in a well-ventilated place. Dispose of contents/container to... sparks, open flames and other ignition In case of fire: Explosion risk. - except for temperature controlled … in accordance with sources. No smoking. Evacuate area. Do NOT fight fire self-reactive substances and local/regional/national/international when fire reaches explosives. mixtures or organic peroxides regulations (to be specified). P234 because condensation and Keep only in original packaging. consequent freezing may take Manufacturer/supplier or the place. competent authority to specify P235 P411 Keep cool. whether disposal requirements apply Store at temperatures not to contents, container or both. - may be omitted if P411 is given on the exceeding …°C/…°F. label. - if temperature control is required P240 (according to section 2.8.2.3 or 2.15.2.3 of the GHS) or if otherwise Ground and bond container and receiving deemed necessary. equipment. ... Manufacturer/supplier or the - if electrostatically sensitive and able to competent authority to specify generate an explosive atmosphere. temperature using applicable P280 temperature scale.

Wear protective gloves/protective U

P420 N

clothing/eye protection/face protection.. / Store separately. S Manufacturer/supplier or the competent C

authority to specify the appropriate type of T

equipment. G

1 4 A U

(Chapter 2.8) T

Symbol G

/ Exploding bomb and flame 4

Type B Danger H241 Heating may cause a fire or explosion /

1 Precautionary statements Prevention Response Storage Disposal P210 P370 + P380 + P375 [+ P378] P403 P501 Keep away from heat, hot surfaces, In case of fire: Evacuate area. Fight Store in a well-ventilated place. Dispose of contents/container to... sparks, open flames and other ignition fire remotely due to the risk of - except for temperature …in accordance with sources. No smoking. explosion. [Use ... to extinguish.] controlled self-reactive substances local/regional/national/international - text in square brackets to be used if and mixtures or organic peroxides regulations (to be specified). P234 water increases risk. because condensation and Keep only in original packaging. …Manufacturer/supplier or the consequent freezing may take Manufacturer/supplier or the competent place. authority to specify whether disposal P235 competent authority to specify appropriate media. Keep cool. P411 requirements apply to contents, - may be omitted if P411 is given on the Store at temperatures not container or both. label exceeding …°C/…°F. P240 - if temperature control is Ground and bond container and required (according to section receiving equipment. 2.8.2.3 or 2.15.2.3 of the GHS) or - if electrostatically sensitive and able to if otherwise deemed necessary. generate an explosive atmosphere. ... Manufacturer/supplier or the competent authority to specify P280 temperature using applicable Wear protective gloves/protective temperature scale. U clothing/eye protection/face protection. N

/ P420 S Manufacturer/supplier or the competent C Store separately. E authority to specify the appropriate type of T

equipment. G

1 4 A U

(Chapter 2.8) T

Symbol G

/ Flame 4

Type C Danger H242 Heating may cause a fire /

Type D Danger H242 Heating may cause a fire d

Type E Warning H242 Heating may cause a fire –

Type F Warning H242 Heating may cause a fire N

1 Precautionary statements Prevention Response Storage Disposal P210 P370 + P378 P403 P501 Keep away from heat, hot surfaces, In case of fire: Use ... to extinguish Store in a well-ventilated place. Dispose of contents/container to... sparks, open flames and other ignition - if water increases risk. - except for temperature …in accordance with sources. No smoking. controlled self-reactive substances ... Manufacturer/supplier or the local/regional/national/international competent authority to specify and mixtures or organic peroxides regulations (to be specified). P234 appropriate media. because condensation and consequent freezing may take Manufacturer/supplier or the competent Keep only in original packaging. place. authority to specify whether disposal P235 P411 requirements apply to contents, Keep cool. Store at temperatures not container or both. - may be omitted if P411 is given on the label exceeding …°C/…°F. - if temperature control is P240 required (according to section Ground and bond container and 2.8.2.3 or 2.15.2.3 of the GHS) or receiving equipment. if otherwise deemed necessary. - if electrostatically sensitive and able to ...Manufacturer/supplier or the generate an explosive atmosphere. competent authority to specify P280 temperature using applicable

Wear protective gloves/protective U temperature scale.

clothing/eye protection/face protection. / P420 S Manufacturer/supplier or the competent C Store separately. E authority to specify the appropriate type of T

equipment. G

1 4 A U

PYROPHORIC LIQUIDS x C

(Chapter 2.9) T

Symbol G

/ Flame 4

1 Danger H250 Catches fire spontaneously if exposed to air /

1 Precautionary statements Prevention Response Storage Disposal P210 P302 + P334 Keep away from heat, hot surfaces, sparks, IF ON SKIN: Immerse in cool water open flames and other ignition sources. No or wrap with wet bandages smoking. P370 + P378 P222 In case of fire: Use ... to extinguish Do not allow contact with air. - if water increases risk. - if emphasis of the hazard statement is deemed ... Manufacturer/supplier or the necessary. competent authority to specify P231+P232 appropriate media. Handle and store contents under inert gas/…. Protect from moisture. …Manufacturer/supplier or the competent authority to specify appropriate liquid or gas if “inert gas” is not appropriate. P233 Keep container tightly closed. P280 Wear protective gloves/protective clothing/eye

protection/face protection. N

/ Manufacturer/supplier or the competent authority S

to specify the appropriate type of equipment. E

1 4 A U

PYROPHORIC SOLIDS x C

(Chapter 2.10) T

Symbol G

/ Flame 4

. Catches fire spontaneously if exposed to air 8 1 Danger /

1 Precautionary statements Prevention Response Storage Disposal P210 P302 + P335 + P334 Keep away from heat, hot surfaces, IF ON SKIN: Brush off loose particles from skin. sparks, open flames and other ignition Immerse in cool water or wrap in wet bandages. sources. No smoking. P370 + P378 P222 In case of fire: Use ... to extinguish Do not allow contact with air. - if water increases risk. - if emphasis of the hazard statement is ... Manufacturer/supplier or the competent authority deemed necessary. to specify appropriate media. P231 + P232 Handle and store contents under inert gas/…. Protect from moisture. …Manufacturer/supplier or the competent authority to specify appropriate liquid or gas if “inert gas” is not appropriate. P233 Keep container tightly closed. P280 Wear protective gloves/protective

clothing/eye protection/face protection. N

/ Manufacturer/supplier or the competent S

authority to specify the appropriate type of E

equipment. D

1 4 A U

SELF-HEATING SUBSTANCES AND MIXTURES x C

(Chapter 2.11) T

Symbol G

/ Flame 4

1 Danger H251 Self-heating; may catch fire /

2 Warning H252 Self-heating in large quantities; may catch fire d

1 Precautionary statements Prevention Response Storage Disposal P235 Keep cool. P407 - may be omitted if P413 is given on the label Maintain air gap between stacks or pallets. P280 P410 Wear protective gloves/protective Protect from sunlight. clothing/eye protection/face protection. P413 Manufacturer/supplier or the competent Store bulk masses greater than … authority to specify the appropriate type of kg/…lbs at temperatures not equipment. exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify mass and temperature using applicable scale. P420 Store separately.

1 4 A U

SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES x C

(Chapter 2.12) T

Symbol G

/ Flame 4

1 Danger H260 In contact with water releases flammable gases, which may ignite /

spontaneously d

Danger H261 In contact with water releases flammable gas –

1 Precautionary statements Prevention Response Storage Disposal P223 P302 + P335 + P334 P402 + P404 P501 IF ON SKIN: Brush off loose particles Do not allow contact with water. Store in a dry place. Store in a Dispose of contents/container to... from skin. Immerse in cool water. - if emphasis of the hazard statement is closed container. …in accordance with P370 + P378 deemed necessary. local/regional/national/ international In case of fire: Use ... to extinguish P231 + P232 regulations (to be specified). Handle and store contents under inert - if water increases risk. Manufacturer/supplier or the gas/.... Protect from moisture. ... Manufacturer/supplier or the competent authority to specify - if the substance or mixture reacts readily competent authority to specify with moisture in air. appropriate media. whether disposal requirements apply to contents, container or both. ... Manufacturer/supplier or the competent authority to specify appropriate liquid or gas if “inert gas” is not appropriate.P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

1 4 A U

SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES x C

(Chapter 2.12) T

Symbol G

/ Flame 4

3 Warning H261 In contact with water releases flammable gas /

1 Precautionary statements Prevention Response Storage Disposal P231 + P232 P370 + P378 P402 + P404 P501 Handle and store contents under inert In case of fire: Use ... to extinguish. Store in a dry place. Store in a Dispose of contents/container to... - if water increases risk. gas/.... Protect from moisture. closed container. ... in accordance with ... Manufacturer/supplier or the local/regional/national/international - if the substance or mixture reacts readily competent authority to specify regulations (to be specified). with moisture in air. appropriate media. ... Manufacturer/supplier or the competent Manufacturer/supplier or the competent authority to specify appropriate liquid or gas authority to specify whether disposal if “inert gas” is not appropriate. requirements apply to contents, container or both. P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

1 4 A U

OXIDIZING LIQUIDS x C

(Chapter 2.13) T

Symbol 4

Flame over circle I

Hazard category Signal word Hazard statement .

1 Danger H271 May cause fire or explosion; strong oxidizer d

1 Precautionary statements Prevention Response Storage Disposal P210 P306 + P360 P420 P501 Keep away from heat, hot surfaces, IF ON CLOTHING: Rinse immediately Store separately. Dispose of contents/container to... sparks, open flames and other ignition contaminated clothing and skin with …in accordance with local/regional/ sources. No smoking. plenty of water before removing national/international regulations (to P220 clothes. be specified). Keep away from clothing and other P371 + P380 + P375 combustible materials. In case of major fire and large Manufacturer/supplier or the P280 Wear protective gloves/protective quantities: Evacuate area. Fight fire competent authority to specify clothing/eye protection/face protection. remotely due to the risk of explosion. whether disposal requirements apply Manufacturer/supplier or the competent P370 + P378 to contents, container or both. authority to specify the appropriate type of In case of fire: Use ... to extinguish. equipment. - if water increases risk. ... Manufacturer/supplier or the competent P283 authority to specify appropriate media. Wear fire resistant or flame retardant clothing.

1 4 A U

OXIDIZING LIQUIDS x C

(Chapter 2.13) T

Symbol G

Flame over circle 2

2 Danger H272 May intensify fire; oxidizer A

3 Warning H272 May intensify fire; oxidizer 1

1 Precautionary statements Prevention Response Storage Disposal P210 P370 + P378 P501 Keep away from heat, hot surfaces, sparks, In case of fire: Use ... to extinguish. Dispose of contents/container to... open flames and other ignition sources. No - if water increases risk. smoking. …in accordance with local/regional/ ... Manufacturer/supplier or the competent national/international regulations (to P220 authority to specify appropriate media. be specified). Keep away from clothing and other combustible materials. Manufacturer/supplier or the competent authority to specify whether disposal requirements apply P280 Wear protective gloves/protective to contents, container or both. clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

1 4 A U

OXIDIZING SOLIDS x C

(Chapter 2.14) T

Symbol G

/ Flame over circle 4

1 Danger H271 May cause fire or explosion; strong oxidizer A

1 Precautionary statements Prevention Response Storage Disposal P210 P306 + P360 P420 P501 Keep away from heat, hot surfaces, sparks, IF ON CLOTHING: Rinse Store separately. Dispose of contents/container to... open flames and other ignition sources. No immediately contaminated clothing and …in accordance with local/regional/ smoking. skin with plenty of water before national/international regulations (to P220 removing clothes. be specified). Keep away from clothing and other P371 + P380 + P375 combustible materials. In case of major fire and large Manufacturer/supplier or the quantities: Evacuate area. Fight fire competent authority to specify remotely due to the risk of explosion. whether disposal requirements apply P280 Wear protective gloves/protective P370 + P378 to contents, container or both. clothing/eye protection/face protection. In case of fire: Use ... to extinguish. Manufacturer/supplier or the competent - if water increases risk. authority to specify the appropriate type of ... Manufacturer/supplier or the competent equipment. authority to specify appropriate media. P283 Wear fire resistant or flame retardant clothing.

1 4 A U

OXIDIZING SOLIDS x C

(Chapter 2.14) T

Symbol G

Flame over circle 2

/ May intensify fire; oxidizer A 2 Danger H272 d

3 Warning H272 May intensify fire; oxidizer –

1 Precautionary statements

Prevention Response Storage Disposal P210 P370 + P378 P501 Keep away from heat, hot surfaces, In case of fire: Use ... to extinguish. Dispose of contents/container to... sparks, open flames and other ignition - if water increases risk. ... in accordance with sources. No smoking. ... Manufacturer/supplier or the local/regional/national/international P220 competent authority to specify regulations (to be specified). Keep away from clothing and other appropriate media. combustible materials. Manufacturer/supplier or the competent authority to specify whether disposal requirements apply to contents, container P280 Wear protective gloves/protective or both. clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify the appropriate type of equipment.

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ORGANIC PEROXIDES x C

(Chapter 2.15) T

Symbol G

Exploding bomb 2

/ Type A Danger H240 Heating may cause an explosion A

Prevention Response Storage Disposal P370 + P372 + P380 + P373 P210 P403 P501 Keep away from heat, hot surfaces, sparks, open In case of fire: Explosion risk. Store in a well-ventilated place. Evacuate area. Do NOT fight Dispose of contents/container to... flames and other ignition sources. No smoking. - except for temperature controlled fire when fire reaches self-reactive substances and explosives mixtures or organic peroxides ... in accordance with because condensation and local/regional/national/international P234 consequent freezing may take regulations (to be specified). Keep only in original packaging. place. Manufacturer/supplier or the P235 competent authority to specify Keep cool. P411 whether disposal requirements - may be omitted if P411 is given on the label Store at temperatures not apply to contents, container or exceeding …°C/…°F. both. P240 Ground and bond container and receiving - if temperature control is required equipment. (according to section 2.8.2.3 or - if electrostatically sensitive and able to generate an 2.15.2.3 of the GHS) or if explosive atmosphere. otherwise deemed necessary. P280 ... Manufacturer/supplier or the

Wear protective gloves/protective clothing/eye competent authority to specify U

temperature using applicable / protection/face protection. S temperature scale. C Manufacturer/supplier or the competent authority to E

specify the appropriate type of equipment. P410 D

Protect from sunlight. 4

I P420 N

. Store separately. 8

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(Chapter 2.15) T

Symbol G

Exploding bomb and flame 2

/ Type B Danger H241 Heating may cause a fire or explosion A

P210 P370 + P378 P403 P501 Keep away from heat, hot surfaces, In case of fire: Use ... to extinguish Store in a well-ventilated place. Dispose of contents/container to...... Manufacturer/supplier or the sparks, open flames and other ignition - except for temperature controlled ... in accordance with competent authority to specify sources. No smoking. self-reactive substances and local/regional/national/international appropriate media. mixtures or organic peroxides - if water increases risk. regulations (to be specified). because condensation and Manufacturer/supplier or the competent consequent freezing may take authority to specify whether disposal P234 P370+P380+P375 place. Keep only in original packaging. In case of fire: Evacuate area. Fight requirements apply to contents, fire remotely due to the risk of P411 Store at temperatures not container or both. P235 explosion. exceeding …°C/…°F. - if Keep cool. temperature control is required (according to section 2.8.2.3 or - may be omitted if P411 is given on the P370 + P380 + P375 [+ P378] 2.15.2.3 of the GHS) or if label In case of fire: Evacuate area. Fight otherwise deemed necessary. fire remotely due to the risk of P240 explosion. [Use ... to extinguish.] Ground and bond container and …Manufacturer/supplier or the - text in square brackets to be used if competent authority to specify receiving equipment. water increases risk. - if electrostatically sensitive and able to temperature using applicable …Manufacturer/supplier or the

generate an explosive atmosphere. temperature scale.P410 U

competent authority to specify N

Protect from sunlight. / P280 Wear protective gloves/protective appropriate media. S

clothing/eye protection/face protection. P420 E

Manufacturer/supplier or the competent Store separately. D

authority to specify the appropriate type of 4

equipment. I

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(Chapter 2.15) T

Symbol G

Flame 2

Type C Danger H242 Heating may cause a fire d

Type D Danger H242 Heating may cause a fire –

Type E Warning H242 Heating may cause a fire N

Type F Warning H242 Heating may cause a fire E

Prevention Response Storage Disposal P370 + P378 P210 P403 P501 Keep away from heat, hot surfaces, In case of fire: Use ... to Store in a well-ventilated place. extinguish Dispose of contents/container to... sparks, open flames and other ignition - except for temperature controlled self- - if water increases risk. ... in accordance with sources. No smoking. reactive substances and mixtures or ... Manufacturer/supplier or the organic peroxides because local/regional/national/international competent authority to specify condensation and consequent freezing regulations (to be specified). appropriate media. may take place. Manufacturer/supplier or the competent P234 P411 authority to specify whether disposal Keep only in original packaging. Store at temperatures not exceeding requirements apply to contents, container P235 …°C/…°F. - if temperature control is or both. Keep cool. required (according to section 2.8.2.3 - may be omitted if P411 is given on the or 2.15.2.3 of the GHS) or if otherwise label. deemed necessary. P240 ... Manufacturer/supplier or the Ground and bond container and competent authority to specify receiving equipment. temperature using applicable - if electrostatically sensitive and able to generate an explosive atmosphere. temperature scale. P410 U

Protect from sunlight. S

P280 Wear protective gloves/protective E P420 T clothing/eye protection/face protection. D Store separately. G

Manufacturer/supplier or the competent 4

authority to specify the appropriate type of I

equipment. F

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ACUTE TOXICITY - DERMAL x C

(Chapter 3.1) T

Symbol G

Skull and crossbones 2

/ 1 Danger H310 Fatal in contact with skin A

. 2 Danger 1 H310 Fatal in contact with skin

P262 P302 + P352 P405 P501 Do not get in eyes, on skin, or on clothing. IF ON SKIN: Wash with plenty of Store locked up. Dispose of contents/container to... water/...... in accordance with P264 …Manufacturer/supplier or the competent Wash … thoroughly after handling. authority may specify a cleansing agent if local/regional/national/international … Manufacturer/supplier or the competent appropriate, or may recommend an regulations (to be specified). authority to specify parts of the body to be alternative agent in exceptional cases if Manufacturer/supplier or the competent washed after handling. water is clearly inappropriate. authority to specify whether disposal P270 P310 requirements apply to contents, Do not eat, drink or smoke when using Immediately call a POISON container or both. this product. CENTER/doctor/... P280 …Manufacturer/supplier or the competent authority to specify the appropriate source of Wear protective gloves/protective clothing. emergency medical advice. Manufacturer/supplier or the competent authority may further specify type of P321 equipment where appropriate. Specific treatment (see ... on this label) - if immediate measures such as specific cleansing agent is advised. ... Reference to supplemental first aid U

instruction. S P361+ P364 C

Take off immediately all contaminated T

clothing and wash it before reuse. G

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(Chapter 3.1) T

Symbol G

Skull and crossbones 2

/ 3 Danger H311 Toxic in contact with skin A

Prevention Response Storage Disposal P405 P302 + P352 P280 Store locked up. P501 Wear protective gloves/protective IF ON SKIN: Wash with plenty of water/... Dispose of contents/container to... …Manufacturer/supplier or the competent clothing. ... in accordance with authority may specify a cleansing agent if Manufacturer/supplier or the competent appropriate, or may recommend an alternative local/regional/national/international authority may further specify type of agent in exceptional cases if water is clearly regulations (to be specified). equipment where appropriate. inappropriate. Manufacturer/supplier or the competent authority to specify whether disposal P312 Call a POISON CENTER/doctor/…/if you requirements apply to contents, feel unwell. container or both. …Manufacturer/supplier or the competent authority to specify the appropriate source of emergency medical advice. P321 Specific treatment (see ... on this label) - if immediate measures such as specific cleansing agent is advised. ... Reference to supplemental first aid instruction. U

P361 + P364 C Take off immediately all contaminated E

clothing and wash it before reuse. D

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(Chapter 3.1) T

Symbol G

Exclamation mark 2

/ 4 Warning H312 Harmful in contact with skin A

P280 P302 + P352 P501 Wear protective gloves/protective clothing IF ON SKIN: Wash with plenty of Dispose of contents/container to... water/... Manufacturer/supplier or the competent ... in accordance with …Manufacturer/supplier or the competent authority may further specify type of authority may specify a cleansing agent if local/regional/national/international equipment where appropriate. appropriate, or may recommend an regulations (to be specified). alternative agent in exceptional cases if water Manufacturer/supplier or the competent is clearly inappropriate. authority to specify whether disposal P312 requirements apply to contents, Call a POISON CENTER/doctor/…/if you container or both. feel unwell. …Manufacturer/supplier or the competent authority to specify the appropriate source of emergency medical advice. P321 Specific treatment (see ... on this label) - if immediate measures such as specific cleansing agent is advised. ... Reference to supplemental first aid U

instruction. S

P362 + P364 E

Take off contaminated clothing and wash D

it before reuse. /

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SKIN CORROSION/IRRITATION x C

(Chapter 3.2) T

Symbol G

/ Corrosion 4

. 1A to 1C 8 Danger H314 Causes severe skin burns and eye damage /

Prevention Response Storage Disposal P260 P301 + P330 + P331 P405 P501 Do not breathe dusts or mists. IF SWALLOWED: Rinse mouth. Do NOT induce Store locked Dispose of contents/container to... - if inhalable particles of dusts or mists vomiting. up. ... in accordance with may occur during use. P303 + P361 + P353 local/regional/national/international P264 IF ON SKIN (or hair): Take off immediately all regulations (to be specified). Wash …thoroughly after handling. contaminated clothing. Rinse skin with water [or Manufacturer/supplier or the …Manufacturer/supplier or the competent shower]. competent authority to specify whether authority to specify parts of the body to be - text in square brackets to be included where the disposal requirements apply to washed after handling. manufacturer/supplier or the competent authority consider contents, container or both. P280 it appropriate for the specific chemical. Wear protective gloves/protective P363 clothing/eye protection/face protection. Wash contaminated clothing before reuse. Manufacturer/supplier or the competent P304 + P340 authority may further specify type of IF INHALED: Remove person to fresh air and keep equipment where appropriate. comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/... …Manufacturer/supplier or the competent authority to specify the appropriate source of emergency medical U

advice. S

P321 E

Specific treatment (see ... on this label) D

Manufacturer/supplier or the competent authority may G

specify a cleansing agent if appropriate. 2

... Reference to supplemental first aid instruction. N

P305 + P351 + P338 F

IF IN EYES: Rinse cautiously with water for several A

minutes. Remove contact lenses, if present and easy to d

do. Continue rinsing. 1

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SKIN CORROSION/IRRITATION x C

(Chapter 3.2) T

Symbol G

Exclamation mark 2

/ 2 A Warning H315 Causes skin irritation d

P264 P302 + P352 Wash … thoroughly after handling. IF ON SKIN: Wash with plenty water/ … Manufacturer/supplier or the competent … authority to specify parts of the body to be …Manufacturer/supplier or the washed after handling. competent authority may specify a cleansing agent if appropriate, or may P280 recommend an alternative agent in Wear protective gloves. exceptional cases if water is clearly Manufacturer/supplier or the competent inappropriate. authority may further specify type of equipment where appropriate. P321 Specific treatment (see ... on this label) Manufacturer/supplier or the competent authority may specify a cleansing agent if appropriate. ... Reference to supplemental first aid instruction. P332 + P313 If skin irritation occurs: Get medical advice. U

– may be omitted when P333+P313 is S given on the label C

P362 + P364 D

Take off contaminated clothing and /

wash it before reuse. 2

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EYE DAMAGE/IRRITATION x C

(Chapter 3.3) T

Symbol G

Corrosion 2

/ 1 Danger H318 Causes serious eye damage A

P280 P305 + P351 + P338 Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove Manufacturer/supplier or the competent contact lenses, if present and easy to do. authority may further specify type of Continue rinsing. equipment where appropriate. P310 Immediately call a POISON CENTER/doctor/... …Manufacturer/supplier or the competent authority to specify the appropriate source of emergency medical advice.

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EYE DAMAGE/IRRITATION x C

(Chapter 3.3) T

Symbol G

Exclamation mark 2

/ 2A Warning H319 Causes serious eye irritation A

P264 P305 + P351 + P338 Wash … thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove … Manufacturer/supplier or the competent contact lenses, if present and easy to do. authority to specify parts of the body to be Continue rinsing. washed after handling. P337 + P313 P280 If eye irritation persists: Get medical Wear eye protection/face protection. advice. Manufacturer/supplier or the competent authority may further specify type of equipment where appropriate.

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SENSITIZATION - SKIN x C

(Chapter 3.4) T

Symbol G

Exclamation mark 2

/ 1, 1A, 1B Warning H317 May cause an allergic skin reaction A

P261 P302 + P352 P501 Avoid breathing dust/fume/gas/mist/ IF ON SKIN: Wash with plenty of water/ Dispose of contents/container to... vapours/spray. … ... in accordance with – may be omitted if P260 is given on the …Manufacturer/supplier or the competent label authority may specify a cleansing agent if local/regional/national/international Manufacturer/supplier or the competent appropriate, or may recommend an regulations (to be specified). authority to specify applicable conditions. alternative agent in exceptional cases if water Manufacturer/supplier or the competent is clearly inappropriate. authority to specify whether disposal P272 Contaminated work clothing should not P333 + P313 requirements apply to contents, be allowed out of the workplace. If skin irritation or rash occurs: Get container or both. medical advice. P280 Wear protective gloves. P321 Specific treatment (see ... on this label) Manufacturer/supplier or the competent Manufacturer/supplier or the competent authority may further specify type of authority may specify a cleansing agent if equipment where appropriate. appropriate. ... Reference to supplemental first aid instruction. P362 + P364 U

Take off contaminated clothing and wash S it before reuse. C

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GERM CELL MUTAGENICITY x C

(Chapter 3.5) T

Symbol G

Health hazard 2

Hazard category Signal word 1. Hazard statement F

/ 1 Danger H340 May cause genetic defects <...> A

2 Warning H341 Suspected of causing genetic defects <...>

<...> (state route of exposure if it is conclusively proven that no other N

/ routes of exposure cause the hazard) S

P201 P308 + P313 P405 P501 Obtain special instructions before use. IF exposed or concerned: Get Store locked up. Dispose of contents/container to... medical advice. P202 ... in accordance with Do not handle until all safety precautions local/regional/national/international have been read and understood. regulations (to be specified). P280 Manufacturer/supplier or the competent Wear protective gloves/protective authority to specify whether disposal clothing/eye protection/face protection. requirements apply to contents, Manufacturer/supplier or the competent container or both. authority to specify the appropriate type of equipment.

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CARCINOGENICITY x C

(Chapter 3.6) T

Symbol G

Health hazard 2

/ 1 Danger H350 May cause cancer <...> A

2 Warning H351 Suspected of causing cancer <...>

<...> (state route of exposure if it is conclusively proven that no other N

/ routes of exposure cause the hazard). S

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TOXIC TO REPRODUCTION x C

(Chapter 3.7) T

Symbol G

/ Health hazard 4

1 Danger H360 May damage fertility or the unborn child <...> <<...>> /

2 Warning H361 Suspected of damaging fertility or the unborn child <...> <<...>> d

<...> (state specific effect if known) –

<<...>> (state route of exposure if it is conclusively proven that no N

other routes of exposure cause the hazard) C

1 Precautionary statements Prevention Response Storage Disposal