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APPENDIX

Initial and final molalities and H** (J kg-1) values for ternary aqueous solutions of enantiomeric -amino acids at 298 K.

L-PHENYLALANINE / L-GLUTAMINE i i f f mL (PHE) mL (GLN) mL (PHE) mL (GLN) H** 0.05778 0.01985 0.02805 0.009636 0.331 0.03128 0.01075 0.01542 0.005298 0.0908 0.04433 0.01523 0.02169 0.007451 0.205 0.05778 0.01985 0002805 0.009636 0.331 0.05069 0.01741 0.02470 0.008488 0.284 0.03745 0.01287 0.01839 0.006319 0.125 0.03128 0.01075 0.01542 0.005298 0.103 0.04433 0.01523 0.02169 0.007451 0.205 0.05778 0.01985 0.02805 0.009636 0.331 0.05069 0.01741 0.02471 0.008488 0.236 0.03745 0.01287 0.01839 0.006319 0.125 0.03128 0.01075 0.01542 0.005298 0.0554 0.04433 0.01523 0.02169 0.007451 0.170 0.05778 0.01985 0.02805 0.009636 0.295 0.05069 0.01741 0.02471 0.008488 0.200 0.03745 0.01287 0.01839 0.006319 0.137

L-PHENYLALANINE / D-GLUTAMINE i i f f mL (PHE) mL (GLN) mL (PHE) mL (GLN) H** 0.03518 0.009922 0.01725 0.004866 0.135 0.05013 0.01414 0.02433 0.006862 0.249 0.06570 0.01853 0.03155 0.008897 0.421 0.05746 0.01620 0.02775 0.007826 0.300 0.04222 0.01191 0.02061 0.005811 0.162 0.03518 0.009922 0.01725 0.004866 0.111 0.05013 0.01414 0.02433 0.006862 0.228 0.06570 0.01853 0.03155 0.008897 0.396 0.05746 0.01620 0.02775 0.007826 0.288 0.04222 0.01191 0.02061 0.005811 0.154 0.03518 0.009922 0.01725 0.004866 0.115 0.05013 0.01414 0.02433 0.006862 0.236 0.06570 0.01853 0.03155 0.008897 0.404 0.05746 0.01620 0.02775 0.007826 0.300 This journal is © The Owner Societies 1999

0.04222 0.01191 0.02061 0.005811 0.154 0.03518 0.009922 0.01725 0.004866 0.111 0.05013 0.01414 0.02433 0.006862 0.232 0.06570 0.01853 0.03155 0.008897 0.404 0.05746 0.01620 0.02775 0.007826 0.292 0.04222 0.01191 0.02061 0.005811 0.150 This journal is © The Owner Societies 1999

L-PHENYLALANINE / L-LEUCINE i i f f mL (PHE) mL (LEU) mL (PHE) mL (LEU) H** 0.03074 0.02775 0.01513 0.01366 -0.420 0.04409 0.03980 0.02141 0.01933 -0.821 0.05820 0.05253 0.02786 0.02514 -1.39 0.05071 0.04578 0.02446 0.02208 -1.15 0.03701 0.03341 0.01810 0.01634 -0.70 0.03074 0.02775 0.01513 0.01365 -0.420 0.04409 0.03980 0.02141 0.01933 -0.906 0.05820 0.05253 0.02786 0.02514 -1.44 0.03701 0.03341 0.01810 0.01634 -0.652 0.03074 0.02775 0.01513 0.01366 -0.420 0.04409 0.03980 0.02141 0.01933 -0.858 0.05820 0.05253 0.02786 0.02514 -1.42 0.05071 0.04578 0.02446 0.02208 -1.16 0.04409 0.03980 0.02141 0.01933 -0.833 0.05820 0.05253 0.02786 0.02514 -1.43 0.05071 0.04578 0.02446 0.02208 -1.21

L-PHENYLALANINE / DL-LEUCINE i i f f mL (PHE) mL (LEU) mL (PHE) mL (LEU) H** 0.03180 0.01528 0.01567 0.007352 -0.485 0.04526 0.02175 0.02208 0.01061 -0.961 0.03814 0.01833 0.01871 0.008993 -0.751 0.03180 0.01528 0.01567 0.007532 -0.497 0.04526 0.02175 0.02208 0.01061 -0.997 0.05925 0.02848 0.02862 0.01376 -1.67 0.05185 0.02492 0.02518 0.01210 -1.33 0.03814 0.01833 0.01871 0.008993 -0.762 0.03180 0.01528 0.01567 0.007532 -0.533 0.04526 0.02175 0.02208 0.01061 -1.03 0.05925 0.02848 0.02862 0.01376 -1.69 0.05185 0.02492 0.02518 0.01210 -1.38 0.03814 0.01833 0.01871 0.008993 -0.786 0.03180 0.01528 0.01567 0.007532 -0.485 0.04526 0.02175 0.02208 0.01061 -0.997 0.05925 0.02848 0.02862 0.01376 -1.65 0.05185 0.02492 0.02518 0.01210 -1.33 0.03814 0.01833 0.01871 0.008993 -0.762 This journal is © The Owner Societies 1999

L-PHENYLALANINE / L-ASPARAGINE i i f f mL (PHE) mL (ASN) mL (PHE) mL (ASN) H** 0.03182 0.03461 .01564 0.01701 0.213 0.04530 0.04926 0.02205 0.02398 0.398 0.05190 0.05644 0.02514 0.02734 0.495 0.03817 0.04152 0.01868 0.02031 0.301 0.03182 0.03461 0.01564 0.01701 0.199 0.04530 0.04926 0.02205 0.02398 0.410 0.05930 0.06450 0.02857 0.03108 0.628 0.05190 0.05644 0.02514 0.02734 0.532 0.03817 0.04152 0.01868 0.02031 0.301 0.03182 0.03461 0.01564 0.01701 0.199 0.04530 0.04926 0.02205 0.02398 0.374 0.05930 0.06450 0.02857 0.03108 0.592 0.05190 0.05644 0.02514 0.02734 0.495 0.03817 0.04152 0.01868 0.02031 0.289 0.03182 0.03461 0.01564 0.01701 0.175 0.04530 0.04926 0.02205 0.02398 0.374 0.05930 0.06450 0.02857 0.03108 0.592 0.05190 0.05644 0.02514 0.02734 0.483 0.03817 0.04152 0.01868 0.02031 0.289

DL-PHENYLALANINE / L-ASPARAGINE i i f f mD (PHE) mL (ASN) mD (PHE) mL (ASN) H** 0.01642 0.03337 0.008087 0.01644 0.228 0.02332 0.04739 0.01139 0.02314 0.398 0.03045 0.06189 0.01474 0.02995 0.611 0.02668 0.05423 0.01298 0.02637 0.531 0.01967 0.03999 0.009651 0.01961 0.330 0.01642 0.03337 0.008087 0.01644 0.240 0.02332 0.04739 0.01139 0.02314 0.435 0.03045 0.06189 0.01474 0.02995 0.660 0.02668 0.05423 0.01298 0.02637 0.555 0.01967 0.03999 0.009651 0.01961 0.342 0.01642 0.03337 0.008087 0.01644 0.228 0.02332 0.04739 0.01139 0.02314 0.374 0.03045 0.06189 0.01474 0.02995 0.709 0.02668 0.05423 0.01298 0.02637 0.482 0.01967 0.03999 0.009651 0.01961 0.330 0.01642 0.03337 0.008087 0.01644 0.204 This journal is © The Owner Societies 1999

L-PHENYLALANINE / L-CYSTEINE i i f f mL (PHE) mL (CYS) mL (PHE) mL (CYS) H** 0.04043 0.04855 0.01971 0.02367 -0.345 0.05291 0.06353 0.02554 0.03067 -0.488 0.04631 0.05561 0.02248 0.02699 -0.407 0.04043 0.04855 0.01971 0.02367 -0.333 0.05291 0.06353 0.02554 0.03067 -0.452 0.04631 0.05561 0.02248 0.02699 -0.383 0.03409 0.04093 0.01670 0.02005 -0.240 0.04043 0.04855 0.01971 0.02367 -0.285 0.05291 0.06353 0.02554 0.03067 -0.440 0.04631 0.05561 0.02248 0.02699 -0.359 0.03409 0.04093 0.01670 0.02005 -0.240 0.02842 0.03413 0.01399 0.01680 -0.184 0.04043 0.04855 0.01971 0.02367 -0.273 0.05291 0.06353 0.02554 0.03067 -0.415 0.04631 0.05561 0.02248 0.02699 -0.371 0.03409 0.04093 0.01670 0.02005 -0.252 0.02600 0.02298 0.01279 0.01131 -0.102 0.03690 0.03263 0.01801 0.01592 -0.152 0.04818 0.04260 0.02331 0.02060 -0.224 0.04222 0.03733 0.02052 0.01814 -0.199 0.03114 0.02754 0.01526 0.01350 -0.141 0.02600 0.02298 0.01279 0.01131 -0.106 0.03690 0.03263 0.01801 0.01592 -0.163 0.04818 0.04260 0.02331 0.02060 -0.239 0.04222 0.03733 0.02052 0.01814 -0.207 0.03114 0.02754 0.01526 0.01350 -0.141 0.02600 0.02298 0.01279 0.01131 -0.0990 0.03690 0.03263 0.01801 0.01592 -0.163 0.04818 0.04260 0.02331 0.02060 -0.232 0.04222 0.03733 0.02052 0.01814 -0.199 0.03114 0.02754 0.01526 0.01350 -0.137 0.02600 0.02298 0.01279 0.01131 -0.0912 0.03690 0.03263 0.01801 0.01592 -0.148 0.04818 0.04260 0.02331 0.02060 -0.216 0.04222 0.03733 0.02052 0.01814 -0.176 0.03114 0.02754 0.01526 0.01350 -0.113 This journal is © The Owner Societies 1999

DL-PHENYLALANINE / L-CYSTEINE i i f f mD (PHE) mL (CYS) mD (PHE) mL (CYS) H** 0.01089 0.03964 0.005374 0.01956 -0.129 0.01553 0.05652 0.007582 0.02760 -0.253 0.02037 0.07414 0.009835 0.03580 -0.409 0.01780 0.06482 0.008649 0.03149 -0.333 0.01089 0.03964 0.005374 0.01956 -0.146 0.01553 0.05652 0.007582 0.02760 -0.261 0.02037 0.07414 0.009835 0.03580 -0.417 0.01780 0.06482 0.008649 0.03149 -0.341 0.01307 0.04759 0.006420 0.02337 -0.211 0.01089 0.03964 0.005374 0.01956 -0.162 0.01553 0.05652 0.007582 0.02760 -0.257 0.02037 0.07414 0.009835 0.03580 -0.413 0.01780 0.06482 0.008649 0.03149 -0.333 0.01307 0.04759 0.006420 0.02337 -0.211 0.01089 0.03964 0.005374 0.01956 -0.133 0.01552 0.05652 0.007582 0.02760 -0.269 0.02037 0.07414 0.009835 0.03580 -0.421 0.01780 0.06482 0.008649 0.03149 -0.341 0.01260 0.02348 0.006220 0.01159 -0.0843 0.01800 0.03352 0.008781 0.01636 -0.164 0.02066 0.03847 0.01002 0.01866 -0.204 0.01514 0.02820 0.007433 0.01384 -0.129 0.01260 0.02348 0.006220 0.01159 -0.0961 0.01800 0.03352 0.008781 0.01636 -0.160 0.02066 0.03847 0.01002 0.01866 -0.200 0.01514 0.02820 0.007433 0.01384 -0.133 0.01260 0.02348 0.006220 0.01159 -0.0922 0.01800 0.03352 0.008781 0.01636 -0.148 0.02066 0.03847 0.01002 0.01866 -0.184 0.01514 0.02820 0.007433 0.01384 -0.121 0.01260 0.02348 0.006220 0.01159 -0.0804 0.01800 0.03352 0.008781 0.01636 -0.136 0.01514 0.02820 0.007433 0.01384 -0.101 This journal is © The Owner Societies 1999

L-PHENYLALANINE / L-METHIONINE i i f f mL (PHE) mL (MET) mL (PHE) mL (MET) H** 0.02463 0.03202 0.01216 0.01581 -0.302 0.03526 0.04584 0.01719 0.02234 -0.589 0.04644 0.06038 0.02234 0.02904 -0.840 0.04051 0.05267 0.01962 0.02551 -0.780 0.02962 0.03851 0.01454 0.01890 -0.445 0.02463 0.03202 0.01216 0.01581 -0.302 0.03526 0.04584 0.01719 0.02234 -0.578 0.04644 0.06038 0.02234 0.02904 -0.828 0.04051 0.05267 0.01962 0.02551 -0.780 0.02962 0.03851 0.01454 0.01890 -0.445 0.02463 0.03202 0.01216 0.01581 -0.290 0.03526 0.04584 0.01719 0.02234 -0.589 0.04644 0.06038 0.02234 0.02904 -0.828 0.04051 0.05267 0.01962 0.02551 -0.780 0.02962 0.03851 0.01454 0.01890 -0.457 0.02463 0.03202 0.01216 0.01581 -0.290 0.03526 0.04584 0.01719 0.02234 -0.578 0.04644 0.06038 0.02234 0.02904 -0.816 0.04051 0.05267 0.01962 0.02551 -0.768 0.02962 0.03851 0.01454 0.01890 -0.445

L-PHENYLALANINE / D-METHIONINE i i f f mL (PHE) mD (MET) mL (PHE) mD (MET) H** 0.01692 0.02466 0.008362 0.01219 -0.143 0.02422 0.03529 0.01182 0.01722 -0.282 0.02782 0.04054 0.01349 0.01966 -0.381 0.02035 0.02966 0.009997 0.01456 -0.211 0.01692 0.02466 0.008362 0.01219 -0.147 0.02422 0.03529 0.01182 0.01722 -0.294 0.03189 0.04646 0.01536 0.02238 -0.486 0.02782 0.04054 0.01349 0.01966 -0.393 0.02035 0.02966 0.009997 0.01457 -0.227 0.01692 0.02466 0.008362 0.01219 -0.151 0.02422 0.03529 0.01182 0.01722 -0.294 0.03189 0.04646 0.01536 0.02238 -0.478 0.02782 0.04054 0.01349 0.01966 -0.389 0.02035 0.02966 0.009997 0.01457 -0.227 0.01692 0.02466 0.008362 0.01219 -0.151 0.02422 0.03529 0.01182 0.01722 -0.301 0.03189 0.04646 0.01536 0.02238 -0.474 0.02782 0.04054 0.01349 0.01966 -0.389 0.02035 0.02966 0.009997 0.01457 -0.219 This journal is © The Owner Societies 1999

L-PHENYLALANINE / L-CITRULLINE i i f f mL (PHE) mL (CTR) mL (PHE) mL (CTR) H** 0.03157 0.03167 0.01552 0.01557 0.224 0.04524 0.04537 0.02195 0.02202 0.388 0.05967 0.05984 0.02855 0.02863 0.627 0.05202 0.05216 0.02507 0.02514 0.496 0.03799 0.03810 0.01856 0.01862 0.292 0.03157 0.03166 0.01552 0.01557 0.205 0.04524 0.04537 0.02195 0.02202 0.376 0.05967 0.05984 0.02855 0.02863 0.607 0.05202 0.05216 0.02507 0.02514 0.476 0.03799 0.03810 0.01856 0.01862 0.269 0.03157 0.03166 0.01552 0.01557 0.185 0.04524 0.04537 0.02195 0.02202 0.364 0.05967 0.05984 0.02855 0.02863 0.607 0.05202 0.05216 0.02507 0.02514 0.480 0.03799 0.03810 0.01856 0.01862 0.281 0.03157 0.03166 0.01552 0.01557 0.205 0.04524 0.04537 0.02195 0.02202 0.388 0.05967 0.05984 0.02855 0.02863 0.635 0.05202 0.05216 0.02507 0.02514 0.508 0.03799 0.03810 0.01856 0.01862 0.296

DL-PHENYLALANINE / L-CITRULLINE i i f f mD (PHE) mL (CTR) mD (PHE) mL (CTR) H** 0.01524 0.03154 0.007497 0.01552 0.202 0.02181 0.04516 0.01060 0.02194 0.378 0.02872 0.05948 0.01377 0.02851 0.604 0.02506 0.05189 0.01210 0.02505 0.480 0.01833 0.03794 0.008963 0.01856 0.284 0.01524 0.03154 0.007497 0.01552 0.202 0.02181 0.04516 0.01060 0.02194 0.378 0.02873 0.05948 0.01377 0.02851 0.612 0.02506 0.05189 0.01210 0.02505 0.480 0.01833 0.03794 0.008963 0.01856 0.280 0.01524 0.03154 0.007497 0.01552 0.198 0.02181 0.04516 0.01060 0.02194 0.374 0.02873 0.05948 0.01377 0.02851 0.612 0.02506 0.05189 0.01210 0.02505 0.490 0.01833 0.03794 0.008963 0.01856 0.288 0.01524 0.03154 0.007497 0.01552 0.210 0.02181 0.04516 0.01060 0.02194 0.378 0.02873 0.05948 0.01377 0.02851 0.620 0.02506 0.05189 0.01210 0.02505 0.492 0.01833 0.03794 0.008963 0.01856 0.296 This journal is © The Owner Societies 1999

L-GLUTAMINE / L-LEUCINE i i f f mL (GLN) mL (LEU) mL (GLN) mL (LEU) H** 0.02386 0.02490 0.01193 0.01245 -0.0754 0.03443 0.03592 0.01694 0.01767 -0.197 0.04572 0.04770 0.02210 0.02307 -0.334 0.03971 0.04143 0.01938 0.02022 -0.262 0.02881 0.03006 0.01430 0.01492 -0.144 0.02386 0.02490 0.01193 0.01245 -0.109 0.03443 0.03592 0.01694 0.01767 -0.209 0.04572 0.04770 0.02210 0.02307 -0.346 0.03971 0.04143 0.01938 0.02022 -0.274 0.02881 0.03006 0.01430 0.01492 -0.144 0.02386 0.02490 0.01193 0.01245 -0.0979 0.03443 0.03592 0.01694 0.01767 -0.197 0.04572 0.04770 0.02210 0.02307 -0.346 0.03971 0.04143 0.01938 0.02022 -0.274 0.02881 0.03006 0.01430 0.01492 -0.155 0.02386 0.02490 0.01193 0.01245 -0.0867 0.03443 0.03592 0.01694 0.01767 -0.197 0.04572 0.04770 0.02210 0.02307 -0.346 0.03971 0.04143 0.01938 0.02022 -0.274 0.02881 0.03006 0.01430 0.01492 -0.144 0.04572 0.04770 0.02210 0.02307 -0.299 0.004493 0.04909 0.02178 0.02380 -0.320 0.02422 0.02646 0.01195 0.01306 -0.119 0.03439 0.03758 0.01682 0.01838 -0.224 0.04493 0.04909 0.02178 0.02380 -0.376 0.03936 0.04301 0.01917 0.02095 -0.307 0.02902 0.03171 0.01426 0.01558 -0.182 0.02422 0.02646 0.01195 0.01306 -0.139 0.03439 0.03758 0.01682 0.01838 -0.256 0.04493 0.04909 0.02178 0.02380 -0.392 0.03936 0.04301 0.01917 0.02095 -0.315 0.02902 0.03171 0.01426 0.01558 -0.171 0.02422 0.02646 0.01195 0.01306 -0.139 0.03439 0.03758 0.01682 0.01838 -0.208 0.04493 0.04909 0.02178 0.02380 -0.224 0.03936 0.04301 0.01917 0.02095 -0.192 0.02902 0.03171 0.01426 0.01558 -0.123 This journal is © The Owner Societies 1999

D-GLUTAMINE / L-LEUCINE i i f f mD (GLN) mL (LEU) mD (GLN) mL (LEU) H** 0.01733 0.03325 0.008565 0.01643 -0.0512 0.02477 0.04752 0.01210 0.02320 -0.0938 0.03258 0.06249 0.01571 0.03014 -0.152 0.02844 0.05456 0.01381 0.02649 -0.136 0.02083 0.03996 0.01024 0.01964 -0.0836 0.01733 0.03325 0.008565 0.01643 -0.0433 0.02477 0.04752 0.01210 0.02320 -0.0938 0.02844 0.05456 0.01381 0.02649 -0.132 0.02083 0.03996 0.01024 0.01964 -0.0876 0.01733 0.03325 0.008565 0.01643 -0.0473 0.02477 0.04752 0.01210 0.02320 -0.0978 0.03258 0.06249 0.01571 0.03014 -0.160 0.02844 0.05456 0.01381 0.02649 -0.144 0.02083 0.03996 0.01024 0.01964 -0.0916 0.01733 0.03325 0.008565 0.01643 -0.0591 0.02477 0.04752 0.01210 0.02320 -0.113 0.03258 0.06249 0.01571 0.03014 -0.164 0.02844 0.05456 0.01381 0.02649 -0.156 0.02083 0.03996 0.01024 0.01964 -0.0955 This journal is © The Owner Societies 1999

L-LEUCINE / L-ASPARAGINE i i f f mL (LEU) mL (ASN) mL (LEU) mL (ASN) H** 0.04391 0.03968 0.02211 0.01998 -0.154 0.06267 0.05664 0.03121 0.02820 -0.346 0.07190 0.06498 0.03562 0.03219 -0.456 0.05274 0.04766 0.02642 0.02387 -0.221 0.04391 0.03968 0.02211 0.01998 -0.154 0.06267 0.05664 0.03121 0.02820 -0.346 0.07190 0.06498 0.03562 0.03219 -0.456 0.05274 0.04766 0.02642 0.02387 -0.221 0.04391 0.03968 0.02211 0.01998 -0.154 0.06267 0.05664 0.03121 0.02820 -0.346 0.07190 0.06498 0.03562 0.03219 -0.456 0.05274 0.04766 0.02642 0.02387 -0.221 0.04391 0.03968 0.02211 0.01998 -0.154 0.06267 0.05664 0.03121 0.02820 -0.346 0.07190 0.06498 0.03562 0.03219 -0.434 0.05274 0.04766 0.02642 0.02387 -0.221 0.04728 0.03886 0.02377 0.01937 -0.150 0.06797 0.05586 0.03368 0.02768 -0.294 0.08992 0.07391 0.04388 0.03606 -0.575 0.07826 0.06432 0.03850 0.03164 -0.426 0.05698 0.04683 0.02845 0.02338 -0.213 0.04728 0.03886 0.02377 0.01954 -0.132 0.06797 0.05586 0.03368 0.02768 -0.312 0.08992 0.07391 0.04388 0.03606 -0.593 0.07826 0.06432 0.03850 0.03164 -0.440 0.05698 0.04683 0.02845 0.02338 -0.220 0.04728 0.03886 0.02377 0.01954 -0.132 0.06797 0.05586 0.03368 0.02768 -0.316 0.08992 0.07391 0.04388 0.03606 -0.578 0.07826 0.06432 0.03850 0.03164 -0.433 0.05698 0.04683 0.02845 0.02338 -0.209 0.04728 0.03886 0.02377 0.01954 -0.132 0.06797 0.05586 0.03368 0.02768 -0.323 0.08992 0.07391 0.04388 0.03606 -0.582 0.07826 0.06432 0.03850 0.03164 -0.444 0.05698 0.04683 0.02845 0.02338 -0.216 This journal is © The Owner Societies 1999

DL-LEUCINE / L-ASPARAGINE i i f f mD (LEU) mL (ASN) mD (LEU) mL (ASN) H** 0.02547 0.03095 0.01269 0.01542 -0.101 0.03362 0.04085 0.01651 0.02006 -0.178 0.02929 0.03559 0.01450 0.01761 -0.154 0.02138 0.02597 0.01072 0.01303 -0.0774 0.01775 0.02157 0.008965 0.01089 -0.0541 0.02547 0.30950 0.01269 0.01541 -0.108 0.03362 0.04085 0.01651 0.02006 -0.185 0.02992 0.03559 0.01450 0.01761 -0.151 0.02138 0.02597 0.01072 0.01303 -0.0774 0.01775 0.02157 0.008965 0.01089 -0.0541 0.02547 0.03095 0.01269 0.01542 -0.119 0.03362 0.04085 0.01651 0.02006 -0.200 0.02138 0.02597 0.01072 0.013303 -0.0810 0.01775 0.02157 0.008965 0.01089 -0.0541 0.02547 0.03095 0.01269 0.01542 -0.0976 0.03362 0.04085 0.01651 0.02006 -0.171 0.02929 0.03559 0.01450 0.01761 -0.136 0.02138 0.02597 0.01072 0.01303 -0.0667 This journal is © The Owner Societies 1999

L-LEUCINE / L-CYSTEINE i i f f mL (LEU) mL (CYS) mL (LEU) mL (CYS) H** 0.05027 0.04404 0.02443 0.02140 -0.571 0.06610 0.05790 0.03172 0.02779 -0.839 0.05771 0.05055 0.02788 0.02442 -0.683 0.04227 0.03703 0.02067 0.01811 -0.386 0.03517 0.03081 0.01730 0.01515 -0.292 0.05027 0.04404 0.02443 0.02140 -0.477 0.06610 0.05790 0.03172 0.02779 -0.792 0.05771 0.05055 0.02788 0.02442 -0.694 0.04227 0.03703 0.02067 0.01811 -0.398 0.03517 0.03081 0.01730 0.01515 -0.281 0.05027 0.04404 0.02443 0.02140 -0.501 0.06610 0.05790 0.03172 0.02779 -0.804 0.05771 0.05055 0.02788 0.02442 -0.635 0.04227 0.03703 0.02067 0.01811 -0.386 0.03517 0.03081 0.01730 0.01515 -0.269 0.05027 0.04404 0.02443 0.02140 -0.501 0.06610 0.05790 0.03172 0.02779 -0.804 0.05771 0.05055 0.02788 0.02442 -0.671 0.04227 0.03703 0.02067 0.01811 -0.386 0.01932 0.01725 0.009420 0.008412 -0.0827 0.02534 0.02263 0.01222 0.01091 -0.0922 0.02215 0.01978 0.01075 0.009597 -0.0860 0.01626 0.01452 0.007976 0.007122 -0.0424 0.01354 0.01209 0.006677 0.005962 -0.0413 0.01932 0.01725 0.009420 0.008412 -0.0827 0.02534 0.02263 0.01222 0.01091 -0.127 0.02215 0.01978 0.01075 0.009597 -0.109 0.01626 0.01452 0.007976 0.007122 -0.0772 0.01354 0.01209 0.006677 0.005962 -0.0413 0.01932 0.01725 0.009420 0.008412 -0.0827 0.02534 0.02263 0.01222 0.01091 -0.127 0.02215 0.01978 0.01075 0.009597 -0.0977 0.01626 0.01452 0.007976 0.007122 -0.0656 0.01354 0.01209 0.006677 0.005962 -0.0413 0.01932 0.01725 0.009420 0.008412 -0.0827 0.02534 0.02263 0.01222 0.01091 -0.127 0.02215 0.01978 0.01075 0.009597 -0.109 0.01626 0.01452 0.007976 0.007122 -0.0540 This journal is © The Owner Societies 1999

DL-LEUCINE / L-CISTEINE i i f f mD (LEU) mL (CYS) mD (LEU) mL (CYS) H** 0.02145 0.01949 0.01045 0.009494 -0.169 0.02463 0.02238 0.01193 0.01084 -0.189 0.01804 0.01639 0.008842 0.008034 -0.126 0.01501 0.01364 0.007398 0.006722 -0.0693 0.02145 0.01949 0.01045 0.009494 -0.192 0.02821 0.02563 0.01357 0.01233 -0.278 0.02463 0.02238 0.01193 0.01084 -0.246 0.01804 0.01639 0.008842 0.008034 -0.160 0.01501 0.01364 0.007398 0.006722 -0.0806 0.02145 0.01949 0.01045 0.009494 -0.180 0.02821 0.02563 0.01357 0.01233 -0.278 0.02463 0.02238 0.01193 0.01084 -0.235 0.01804 0.01639 0.008842 0.008034 -0.160 0.01501 0.01364 0.007398 0.006722 -0.0693 0.02145 0.01949 0.01045 0.009494 -0.180 0.02821 0.02563 0.01357 0.01233 -0.266 0.02463 0.02238 0.01193 0.01084 -0.223 0.01804 0.01639 0.008842 0.008034 -0.138

L-LEUCINE / L-METHIONINE i i f f mL (LEU) mL (MET) mL (LEU) mL (MET) H** 0.01939 0.03717 0.009727 0.01864 -0.284 0.02773 0.05316 0.01374 0.02634 -0.703 0.03186 0.06106 0.01569 0.03008 -0.876 0.02332 0.04469 0.01163 0.02229 -0.505 0.01939 0.03717 0.009727 0.01864 -0.318 0.02774 0.05316 0.01374 0.02634 -0.658 0.03650 0.06996 0.01786 0.03423 -1.10 0.03186 0.06106 0.01569 0.03008 -0.888 0.02332 0.04469 0.01163 0.02229 -0.516 0.01939 0.03717 0.009727 0.01864 -0.307 0.02774 0.05316 0.01374 0.02634 -0.680 0.03186 0.06106 0.01569 0.03008 -0.888 0.02332 0.04469 0.01163 0.02229 -0.471 0.01939 0.03717 0.009727 0.01864 -0.352 0.02774 0.05316 0.01374 0.02634 -0.658 0.03650 0.06996 0.01786 0.03423 -1.10 0.03186 0.06106 0.01569 0.03008 -0.865 0.02332 0.04469 0.01163 0.02229 -0.516 This journal is © The Owner Societies 1999

L-LEUCINE / D-METHIONINE i i f f mL (LEU) mD (MET) mL (LEU) mD (MET) H** 0.01737 0.03752 0.008707 0.01880 -0.329 0.02488 0.05374 0.01231 0.02659 -0.599 0.03279 0.07082 0.01601 0.03458 -1.02 0.02898 0.06257 0.01424 0.03075 -0.787 0.01737 0.03752 0.008707 0.01880 -0.306 0.02488 0.05374 0.01231 0.02659 -0.610 0.03279 0.07082 0.01601 0.03458 -0.986 0.02898 0.06257 0.01424 0.03075 -0.787 0.02090 0.04514 0.01041 0.02249 -0.468 0.01737 0.03752 0.008707 0.01880 -0.272 0.02488 0.05374 0.01231 0.02659 -0.622 0.03279 0.07082 0.01601 0.03458 -0.974 0.02898 0.06257 0.01424 0.03075 -0.775 0.02090 0.04514 0.01041 0.02249 -0.480 0.01737 0.03752 0.008707 0.01880 -0.317 0.02488 0.05374 0.01231 0.02659 -0.610 0.03279 0.07082 0.01601 0.03458 -0.974 0.02898 0.06257 0.01424 0.03075 -0.764 0.02090 0.04514 0.01041 0.02249 -0.457

L-LEUCINE + L-CITRULLINE i i f f mL (LEU) mL (CTR) mL (LEU) mL (CTR) H** 0.02338 0.03954 0.01157 0.01957 -0.176 0.04391 0.07426 0.02122 0.03589 -0.647 0.03885 0.06570 0.01888 0.03194 -0.503 0.02810 0.04752 0.01383 0.02339 -0.262 0.02338 0.03954 0.01157 0.01957 -0.180 0.03341 0.05650 0.01634 0.02764 -0.375 0.04391 0.07426 0.02122 0.03589 -0.655 0.03885 0.06570 0.01888 0.03194 -0.507 0.02810 0.04752 0.01383 0.02339 -0.265 0.02338 0.03954 0.01157 0.01957 -0.188 0.04391 0.07426 0.02122 0.03589 -0.651 0.03885 0.06570 0.01888 0.03194 -0.515 0.02810 0.04752 0.01383 0.02339 -0.269 0.02338 0.03954 0.01157 0.01957 -0.184 0.03341 0.05650 0.01634 0.02764 -0.371 0.04391 0.07426 0.02122 0.03589 -0.647 0.03885 0.06570 0.01888 0.03194 -0.503 0.02810 0.04752 0.01383 0.02339 -0.262 This journal is © The Owner Societies 1999

DL-LEUCINE / L-CITRULLINE i i f f mD (LEU) mL (CTR) mD (LEU) mD (CTR) H** 0.01653 0.02459 0.008225 0.01223 -0.116 0.02356 0.03505 0.01160 0.01726 -0.274 0.03088 0.04595 0.01505 0.02239 -0.487 0.02701 0.04018 0.01323 0.01969 -0.391 0.01984 0.02952 0.009824 0.01462 -0.225 0.01653 0.02459 0.008225 0.01224 -0.158 0.02356 0.03505 0.01160 0.01726 -0.296 0.03088 0.04595 0.01505 0.02239 -0.498 0.02701 0.04018 0.01323 0.01969 -0.402 0.01984 0.02952 0.009824 0.01462 -0.235 0.01653 0.02459 0.008225 0.01224 -0.158 0.02356 0.03505 0.01160 0.01726 -0.306 0.03088 0.04595 0.01505 0.02239 -0.498 0.02701 0.04018 0.01323 0.01969 -0.402 0.01653 0.02459 0.008225 0.01224 -0.137 0.02356 0.03505 0.01160 0.01726 -0.274 0.02701 0.04018 0.01323 0.01969 -0.370 0.01984 0.02952 0.009824 0.01462 -0.203

L-PHENYLALANINE / L-TRYPTOPHAN i i f f mL (PHE) mL (TRP) mL (PHE) mL (TRP) H** 0.02262 0.009261 0.01118 0.004578 0.137 0.03235 0.01324 0.01580 0.006467 0.273 0.04256 0.01742 0.02052 0.008401 0.453 0.03715 0.01521 0.01834 0.007383 0.348 0.02720 0.01113 0.01337 0.005472 0.193 0.02262 0.009261 0.01118 0.004578 0.141 0.03235 0.01324 0.01580 0.006467 0.265 0.04256 0.01742 0.02052 0.008402 0.445 0.03715 0.01521 0.01803 0.007383 0.340 0.02720 0.01113 0.01337 0.005472 0.189 0.02262 0.009261 0.01118 0.004578 0.133 0.03235 0.01324 0.01580 0.006467 0.261 0.04256 0.01742 0.02052 0.008402 0.437 0.03715 0.01521 0.01803 0.007383 0.332 0.02720 0.01113 0.01337 0.005472 0.181 0.02262 0.009261 0.01118 0.004578 0.133 0.03235 0.01324 0.01580 0.006467 0.261 0.04256 0.01742 0.02052 0.008402 0.445 0.03715 0.01521 0.01803 0.007383 0.336 0.02720 0.01113 0.01337 0.005472 0.185 This journal is © The Owner Societies 1999

L-PHENYLALANINE / D-TRYPTOPHAN i i f f mL (PHE) mD (TRP) mL (PHE) mD (TRP) H** 0.01873 0.007452 0.009268 0.003687 0.0810 0.02678 0.01065 0.01309 0.005209 0.159 0.03523 0.01401 0.01701 0.006766 0.277 0.03075 0.01223 0.01494 0.005946 0.205 0.02252 0.008958 0.01108 0.004407 0.111 0.01873 0.007452 0.009268 0.003687 0.0889 0.02678 0.01065 0.01309 0.005209 0.167 0.03523 0.01401 0.01701 0.006766 0.273 0.03075 0.01223 0.01494 0.005946 0.205 0.02252 0.008958 0.01108 0.004407 0.119 0.01873 0.007452 0.009268 0.003687 0.0889 0.02678 0.01065 0.01309 0.005209 0.151 0.03523 0.01001 0.01701 0.006766 0.261 0.03075 0.01223 0.01494 0.005946 0.193 0.02252 0.008958 0.01108 0.004407 0.107 0.01873 0.007452 0.009268 0.003687 0.0810 0.02678 0.01065 0.01309 0.005209 0.151 0.03523 0.01401 0.01701 0.006766 0.253 0.03075 0.01223 0.01494 0.005946 0.193 0.02252 0.008958 0.01108 0.004407 0.107

L-GLUTAMINE / L-TRYPTOPHAN i i f f mL (GLN) mL (TRP) mL (GLN) mL (TRP) H** 0.01827 0.01273 0.008803 0.006136 0.431 0.01596 0.01112 0.007738 0.005393 0.345 0.01390 0.009689 0.006780 0.004726 0.268 0.01827 0.01273 0.008804 0.006136 0.431 0.01596 0.01112 0.007738 0.005393 0.337 0.01390 0.009689 0.006780 0.004726 0.253 0.01596 0.01112 0.007738 0.005393 0.341 0.01390 0.009689 0.006780 0.004726 0.241 0.01827 0.01273 0.008804 0.006136 0.423 0.01596 0.01112 0.007738 0.005393 0.345 0.01390 0.009689 0.006780 0.004726 0.245 0.01827 0.01273 0.008804 0.006136 0.435 0.01596 0.01112 0.007738 0.005393 0.349 This journal is © The Owner Societies 1999

L-GLUTAMINE / D-TRYPTOPHAN i i f f mL (GLN) mD (TRP) mL (GLN) mD (TRP) H** 0.01151 0.009183 0.005575 0.004448 0.223 0.01514 0.01208 0.007242 0.005778 0.352 0.01322 0.01054 0.006364 0.005078 0.282 0.01151 0.009183 0.005575 0.004448 0.219 0.01514 0.01208 0.007242 0.005778 0.352 0.01322 0.01054 0.006364 0.005077 0.286 0.01151 0.009183 0.005575 0.004448 0.226 0.01514 0.01208 0.007242 0.005778 0.368 0.01322 0.01054 0.006364 0.00507 0.282 0.01151 0.009183 0.005575 0.004448 0.223 0.01514 0.01208 0.007242 0.005778 0.364 0.01322 0.01054 0.006364 0.005770 0.294 0.01151 0.009183 0.005575 0.004448 0.242 0.01514 0.01208 0.007242 0.005778 0.368 0.01322 0.01054 0.006364 0.005077 0.314

L-LEUCINE / L-TRYPTOPHAN i i f f mL (LEU) mL (TRP) mL (LEU) mL (TRP) H** 0.02503 0.01286 0.01223 0.006284 0.106 0.02175 0.01118 0.01072 0.005509 0.0761 0.01579 0.008115 0.007911 0.004066 0.0353 0.01308 0.006724 0.006605 0.003394 0.0276 0.01886 0.009694 0.009371 0.004846 0.0709 0.02503 0.01286 0.01223 0.006284 0.120 0.02175 0.01118 0.01072 0.005509 0.0761 0.01308 0.006724 0.006605 0.003394 0.0242 0.01886 0.009694 0.009371 0.004816 0.0638 0.02503 0.01286 0.01223 0.006284 0.117 0.02175 0.01118 0.01072 0.005009 0.0761 0.01579 0.008115 0.007911 0.004066 0.0282 0.01886 0.009694 0.009371 0.004816 0.0567 0.02503 0.01286 0.01223 0.006284 0.117 0.02175 0.01118 0.01072 0.005509 0.0796 0.01579 0.008115 0.007911 0.004066 0.0317 This journal is © The Owner Societies 1999

L-LEUCINE / D-TRYPTOPHAN i i f f mL (LEU) mD (TRP) mL (LEU) mD (TRP) H** 0.009407 0.005753 0.004490 0.002836 0.0414 0.01301 0.008220 0.006340 0.004005 0.0689 0.01711 0.01081 0.008233 0.005201 0.0931 0.01494 0.009436 0.007236 0.004571 0.0923 0.01094 0.006914 0.005365 0.003389 0.0503 0.009107 0.005753 0.004490 0.002836 0.0114 0.01301 0.008220 0.006340 0.004005 0.0498 0.01711 0.01081 0.008232 0.005201 0.114 0.01494 0.009436 0.007236 0.004571 0.0866 0.01094 0.006914 0.005365 0.003389 0.0279 0.009107 0.005753 0.004490 0.002836 0.0381 0.01301 0.008220 0.006340 0.004005 0.0588 0.01711 0.01081 0.008233 0.005201 0.106 0.01494 0.009436 0.007236 0.004571 0.0866 0.01094 0.006914 0.005365 0.003389 0.0603 0.009104 0.005753 0.004490 0.002836 0.0358 0.01301 0.008220 0.006340 0.004005 0.0565 0.01711 0.01081 0.008233 0.005201 0.120 0.01494 0.009436 0.007236 0.004571 0.0945 0.01094 0.006914 0.005365 0.003389 0.0581

L-ASPARAGINE / L-TRYPTOPHAN i i f f mL (ASN) mL (TRP) mL (ASN) mL (TRP) H** 0.008368 0.006429 0.004180 0.003211 0.123 0.01220 0.009373 0.005962 0.004581 0.227 0.01639 0.01259 0.007822 0.006010 0.382 0.01415 0.01087 0.006838 0.005254 0.298 0.01015 0.007800 0.005019 0.003856 0.169 0.008368 0.006429 0.004180 0.003211 0.0999 0.01220 0.009374 0.005962 0.004581 0.215 0.01639 0.01259 0.007822 0.006010 0.370 0.01415 0.01087 0.006838 0.005254 0.286 0.01015 0.007800 0.005019 0.003856 0.157 0.008368 0.006429 0.004180 0.003211 0.111 0.01220 0.009373 0.005962 0.004581 0.215 0.01639 0.01259 0.007822 0.006010 0.382 0.01415 0.01087 0.006838 0.005254 0.298 0.01015 0.007800 0.005019 0.003856 0.169 0.008368 0.006429 0.004180 0.003211 0.111 0.01220 0.009373 0.005962 0.004581 0.227 0.01639 0.01259 0.007822 0.006010 0.382 0.01415 0.01087 0.006838 0.005254 0.310 0.01015 0.007800 0.005019 0.003856 0.157 This journal is © The Owner Societies 1999

L-ASPARAGINE / D-TRYPTOPHAN i i f f mL (ASN) mD (TRP) mL (ASN) mD (TRP) H** 0.008253 0.006769 0.004156 0.003409 0.115 0.01191 0.009771 0.005901 0.004840 0.234 0.01583 0.01298 0.007704 0.006319 0.392 0.01374 0.01127 0.006752 0.005538 0.295 0.009965 0.008274 0.004980 0.004085 0.174 0.008253 0.006769 0.004156 0.003409 0.104 0.01191 0.006771 0.005901 0.004840 0.210 0.01374 0.01127 0.006752 0.005538 0.283 0.009965 0.008174 0.004980 0.004085 0.162 0.008253 0.006769 0.004156 0.003409 0.104 0.01191 0.009771 0.005901 0.004840 0.210 0.01583 0.01298 0.007704 0.006319 0.392 0.01374 0.01127 0.006752 0.005538 0.295 0.009965 0.008174 0.004980 0.004085 0.174 0.008253 0.006769 0.004156 0.003409 0.115 0.01191 0.006771 0.005901 0.004840 0.234 0.01583 0.01298 0.007704 0.006319 0.404 0.01374 0.01127 0.006752 0.005538 0.295 0.009965 0.008174 0.004980 0.004085 0.174

L-TRYPTOPHAN / L-CYSTEINE i i f f mL (TRP) mL (CYS) mL (TRP) mL (CYS) H** 0.008785 0.02059 0.004451 0.01043 0.134 0.01259 0.02950 0.006296 0.01475 0.291 0.01659 0.03889 0.008190 0.01919 0.489 0.01447 0.03391 0.007192 0.01685 0.399 0.01057 0.02477 0.005324 0.01248 0.233 0.008785 0.02059 0.004451 0.01043 0.163 0.01259 0.02950 0.006296 0.01476 0.295 0.01659 0.03889 0.008190 0.01919 0.482 0.01447 0.03391 0.007192 0.01685 0.388 0.01057 0.02477 0.005324 0.01248 0.222 0.008785 0.02059 0.004451 0.01043 0.174 0.01259 0.02950 0.006296 0.01475 0.316 0.01659 0.03889 0.008190 0.01919 0.515 0.01447 0.03391 0.007192 0.01685 0.406 0.01057 0.02477 0.005324 0.01248 0.244 0.008785 0.02059 0.004451 0.01043 0.177 0.01259 0.02950 0.006296 0.01475 0.316 0.01659 0.03889 0.008190 0.01919 0.511 0.01447 0.03391 0.007192 0.01685 0.406 0.01057 0.02477 0.005324 0.01248 0.233 This journal is © The Owner Societies 1999

D-TRYPTOPHAN / L-CYSTEINE i i f f mD (TRP) mL (CYS) mD (TRP) mL (CYS) H** 0.007121 0.02215 0.003606 0.01122 0.129 0.01019 0.03171 0.005099 0.01586 0.223 0.01343 0.04176 0.006630 0.02062 0.355 0.01171 0.03643 0.005823 0.01811 0.286 0.008565 0.02664 0.004312 0.01341 0.161 0.007121 0.02215 0.003606 0.01122 0.129 0.01019 0.03171 0.005099 0.01586 0.219 0.01343 0.04176 0.006630 0.02062 0.351 0.01171 0.03643 0.005823 0.01811 0.278 0.008565 0.02664 0.004312 0.01341 0.161 0.007121 0.02215 0.003606 0.01122 0.125 0.01019 0.03171 0.005099 0.01586 0.219 0.01343 0.04176 0.006630 0.02062 0.359 0.01171 0.03643 0.005823 0.01811 0.282 0.008565 0.02664 0.004312 0.01341 0.161 0.007121 0.02215 0.003606 0.01122 0.132 0.01019 0.03171 0.005099 0.01586 0.211 0.01343 0.04176 0.006630 0.02062 0.348 0.01171 0.03643 0.005823 0.01811 0.274 0.008565 0.02664 0.004312 0.01341 0.158

L-TRYPTOPHAN / L-METHIONINE i i f f mL (TRP) mL (MET) mL (TRP) mL (MET) H** 0.007951 0.01594 0.004045 0.008110 0.107 0.01136 0.02277 0.005713 0.01145 0.199 0.01492 0.02993 0.007420 0.01488 0.340 0.01304 0.02414 0.006521 0.01307 0.263 0.009554 0.01916 0.004834 0.009693 0.147 0.007951 0.01594 0.004045 0.008110 0.106 0.01136 0.02277 0.005713 0.01145 0.201 0.01493 0.02993 0.007420 0.01488 0.334 0.01304 0.02614 0.006521 0.01307 0.256 0.009554 0.01916 0.004834 0.009693 0.142 0.007951 0.01594 0.004045 0.008110 0.113 0.01136 0.02277 0.005713 0.01145 0.214 0.01493 0.02993 0.007420 0.01488 0.353 0.01304 0.02614 0.006521 0.01307 0.274 0.009554 0.01916 0.004834 0.009693 0.158 0.007951 0.01594 0.004045 0.008110 0.106 0.01136 0.02277 0.005713 0.01145 0.208 0.01493 0.02993 0.007420 0.01488 0.346 0.01304 0.02614 0.006521 0.01307 0.272 0.009554 0.01916 0.004834 0.009693 0.160 This journal is © The Owner Societies 1999

L-TRYPTOPHAN / D-METHIONINE i i f f mL (TRP) mD (MET) mL (TRP) mD (MET) H** 0.01036 0.01671 0.005224 0.008421 0.171 0.01488 0.02399 0.007397 0.01192 0.327 0.01967 0.03171 0.009633 0.01553 0.556 0.01713 0.02761 0.008454 0.01363 0.425 0.01248 0.02012 0.006251 0.01008 0.234 0.01036 0.01671 0.005224 0.008421 0.176 0.01488 0.02399 0.007397 0.01192 0.341 0.01967 0.03171 0.009633 0.01553 0.563 0.01713 0.02761 0.008454 0.01363 0.436 0.01248 0.02012 0.006251 0.01008 0.238 0.01036 0.01671 0.005224 0.008421 0.173 0.01488 0.02399 0.007397 0.01192 0.338 0.01967 0.03171 0.009633 0.01553 0.571 0.01713 0.02761 0.008454 0.01363 0.440 0.01248 0.02012 0.006251 0.01008 0.243 0.01036 0.01671 0.005224 0.008421 0.173 0.01488 0.02399 0.007397 0.01192 0.336 0.01967 0.03171 0.009633 0.01553 0.572 0.01713 0.02761 0.008454 0.01363 0.442 0.01248 0.02012 0.006251 0.01008 0.232

L-TRYPTOPHAN / L-CITRULLINE i i f f mL (TRP) mL (CTR) mL (TRP) mL (CTR) H** 0.007041 0.01556 0.003559 0.007868 0.187 0.01011 0.02235 0.005040 0.01114 0.364 0.01336 0.02953 0.006564 0.01451 0.597 0.01163 0.02571 0.005760 0.01273 0.479 0.008481 0.01875 0.004259 0.009415 0.276 0.007041 0.01556 0.003559 0.007868 0.195 0.01011 0.02235 00.005040 0.01114 0.406 0.01336 0.02953 0.006564 0.01451 0.612 0.01163 0.02571 0.005760 0.01273 0.479 0.008481 0.01875 0.004259 0.009415 0.276 0.007041 0.01556 0.003559 0.007868 0.191 0.01011 0.02235 0.005040 0.01114 0.368 0.01336 0.02953 0.006564 0.01451 0.601 0.01163 0.02571 0.005760 0.01273 0.475 0.008481 0.01875 0.004259 0.009415 0.265 0.007041 0.01556 0.003559 0.007868 0.214 0.01336 0.02953 0.006564 0.01451 0.589 0.01163 0.02571 0.005760 0.01273 0.475 0.008481 0.01875 0.004259 0.009415 0.273 This journal is © The Owner Societies 1999

D-TRYPTOPHAN / L-CITRULLINE i i f f mD (TRP) mL (CTR) mD (TRP) mL (CTR) H** 0.007062 0.02007 0.003565 0.01013 0.250 0.01019 0.02895 0.005060 0.01438 0.457 0.01352 0.03843 0.006604 0.01877 0.712 0.01175 0.03338 0.005789 0.01645 0.605 0.008524 0.02422 0.004271 0.01214 0.334 0.007062 0.02007 0.003565 0.01013 0.232 0.01019 0.02895 0.005060 0.01438 0.476 0.01352 0.03843 0.006604 0.01877 0.716 0.01175 0.03338 0.005789 0.01645 0.568 0.008524 0.02422 0.004271 0.01214 0.327 0.007062 0.02007 0.003665 0.01013 0.236 0.01019 0.02895 0.005060 0.01438 0.461 0.01352 0.03843 0.006604 0.01877 0.735 0.01175 0.03338 0.005789 0.01645 0.583 0.008524 0.02422 0.004271 0.01214 0.334 0.007062 0.02007 0.003565 0.01013 0.239 0.01019 0.02895 0.005060 0.01438 0.450 0.01352 0.03843 0.006604 0.01877 0.751 0.01175 0.03338 0.005789 0.01645 0.602 0.008524 0.02422 0.004271 0.01214 0.361

L-PHENYLALANINE / GLYCINE i i f f mL (PHE) m (GLY) mL (PHE) mL (GLY) H** 0.02278 0.06708 0.01129 0.03325 0.112 0.03719 0.1095 0.01827 0.05379 0.256 0.04180 0.1230 0.02048 0.06029 0.350 0.02723 0.08017 0.01346 0.03963 0.172 0.02278 0.06708 0.01129 0.03325 0.112 0.03719 0.1095 0.01827 0.05379 0.256 0.04180 0.1231 0.02048 0.06029 0.350 0.02278 0.06708 0.01129 0.03325 0.112 0.03719 0.1095 0.01827 0.05379 0.294 0.04180 0.1231 0.02048 0.06029 0.350 0.02723 0.08017 0.01346 0.03963 0.172 This journal is © The Owner Societies 1999

D-GLUTAMINE / GLYCINE i i f f mL (GLN) m (GLY) mL (GLN) m (GLY) H** 0.01452 0.04628 0.007139 0.02276 0.202 0.02077 0.06620 0.01009 0.03215 0.367 0.02734 0.08714 0.01311 0.04178 0.548 0.02386 0.07604 0.01152 0.03671 0.464 0.01746 0.05564 0.008534 0.02720 0.281 0.01452 0.04628 0.007139 0.02276 0.191 0.02077 0.06620 0.01009 0.03215 0.355 0.02734 0.08714 0.01311 0.04178 0.548 0.02386 0.07604 0.01152 0.03671 0.476 0.01746 0.05564 0.008534 0.02720 0.269 0.01452 0.04628 0.007139 0.02276 0.191 0.02077 0.06620 0.01009 0.03215 0.367 0.02734 0.08714 0.01311 0.04178 0.584 0.02386 0.07604 0.01152 0.03671 0.488 0.01746 0.05564 0.008534 0.02720 0.305 0.01452 0.04628 0.007139 0.02276 0.226 0.02077 0.06620 0.01009 0.03215 0.414 0.02734 0.08714 0.01311 0.04178 0.584 0.02386 0.07604 0.01152 0.03671 0.488 0.01746 0.05564 0.008534 0.02720 0.305

L -ASPARAGINE / GLYCINE i f mL (ASN) mL(GLY) mL (ASN) mf(GLY) H** 0.01033 0.04676 0.005080 0.0230 0.236 0.01473 0.06670 0.007167 0.0324 0.424 0.01933 0.08752 0.009300 0.0421 0.661 0.01690 0.07650 0.008177 0.0370 0.542 0.01240 0.05615 0.006068 0.0275 0.331 0.01033 0.04676 0.005080 0.0230 0.248 0.01473 0.06670 0.007167 0.0324 0.436 0.01933 0.08752 0.009300 0.0421 0.673 0.01690 0.07650 0.008177 0.0370 0.566 0.01240 0.05615 0.006068 0.0275 0.331 0.01033 0.04676 0.005080 0.0230 0.236 0.01473 0.06670 0.007167 0.0324 0.436 0.01933 0.08752 0.009300 0.0421 0.661 0.01690 0.07652 0.008177 0.0370 0.566 0.01240 0.05615 0.006068 0.0275 0.343 0.01033 0.04676 0.005080 0.0230 0.236 0.01473 0.06670 0.007167 0.0324 0.424 0.01933 0.08752 0.009300 0.0421 0.709 0.01690 0.07650 0.008177 0.0370 0.602 0.01240 0.05615 0.006068 0.0275 0.355 This journal is © The Owner Societies 1999

L-CYSTEINE / GLYCINE i f f mL (CYS) mL(GLY) mL (CYS) m (GLY) H** 0.0400 0.02938 0.02006 0.01473 0.134 0.0667 0.04896 0.03279 0.02408 0.387 0.0754 0.05539 0.03686 0.02707 0.513 0.0481 0.03534 0.02398 0.01761 0.263 0.0400 0.02938 0.02006 0.01473 0.157 0.0667 0.04896 0.03279 0.02408 0.410 0.0754 0.05539 0.03686 0.02707 0.467 0.0481 0.03534 0.02398 0.01761 0.263 0.0400 0.02938 0.02006 0.01473 0.123 0.0667 0.04896 0.03279 0.02408 0.410 0.0754 0.05539 0.03686 0.02707 0.536 0.0481 0.03534 0.02398 0.01761 0.218

L-METHIONINE / GLYCINE i i f f mL (MET) m (GLY) mL (MET) m (GLY) H** 0.02612 0.03663 0.01315 0.01844 0.121 0.04356 0.06109 0.02150 0.03016 0.254 0.04930 0.06914 0.02418 0.03391 0.309 0.03142 0.04407 0.01572 0.02205 0.151 0.02612 0.03663 0.01315 0.01844 0.0764 0.04356 0.06109 0.02150 0.03016 0.232 0.04930 0.06914 0.02418 0.03391 0.309 0.03142 0.04407 0.01572 0.02205 0.140 0.02612 0.03663 0.01315 0.01844 0.0988 0.04356 0.06109 0.02150 0.03016 0.254 0.04930 0.06914 0.02418 0.03391 0.309 0.03142 0.04407 0.01572 0.02205 0.151 This journal is © The Owner Societies 1999

L-CITRULLINE / GLYCINE i i f f mL (CTR) m (GLY) mL (CTR) m GLY) H** 0.01690 0.03561 0.008306 0.01750 0.189 0.02413 0.05083 0.01172 0.02469 0.320 0.03169 0.06675 0.01522 0.03205 0.470 0.02769 0.05832 0.01338 0.02818 0.393 0.02031 0.04277 0.009924 0.02090 0.250 0.01690 0.03561 0.008306 0.01750 0.166 0.02413 0.05083 0.01172 0.02469 0.296 0.03169 0.06675 0.01522 0.03205 0.446 0.02769 0.05832 0.01338 0.02818 0.381 0.02031 0.04277 0.009924 0.02090 0.238 0.01690 0.03561 0.008306 0.01750 0.166 0.02413 0.05083 0.01172 0.02469 0.284 0.03169 0.06675 0.01522 0.03205 0.434 0.02769 0.05832 0.01338 0.02818 0.369 0.02031 0.04277 0.009924 0.02090 0.226 0.01690 0.03561 0.008306 0.01750 0.166 0.02413 0.05083 0.01172 0.02469 0.296 0.03169 0.06675 0.01522 0.03205 0.446 0.02769 0.05832 0.01338 0.02818 0.381 0.02031 0.04277 0.009924 0.02090 0.238 This journal is © The Owner Societies 1999

D-TRYPTOPHAN / GLYCINE i i f f mD (TRP) m (GLY) mD (TRP) m GLY) H** 0.007393 0.02608 0.003648 0.01287 0.182 0.01056 0.03724 0.005151 0.01817 0.333 0.01387 0.04892 0.006687 0.02359 0.526 0.01211 0.04273 0.005878 0.02073 0.419 0.008881 0.03133 0.004360 0.01538 0.206 0.007393 0.02608 0.003649 0.01287 0.159 0.01056 0.03724 0.005151 0.01817 0.309 0.01387 0.04892 0.006687 0.02359 0.514 0.01211 0.04273 0.005878 0.02073 0.407 0.008882 0.03133 0.004360 0.01538 0.202 0.007393 0.02608 0.003649 0.01287 0.167 0.01056 0.03724 0.005151 0.01817 0.317 0.01387 0.04892 0.006687 0.02359 0.518 0.01211 0.04273 0.005878 0.02073 0.415 0.008882 0.03133 0.004360 0.01538 0.206 0.007393 0.02608 0.003649 0.01287 0.178 0.01056 0.03724 0.005151 0.01817 0.329 0.01387 0.04892 0.006687 0.02359 0.522 0.01211 0.04273 0.005878 0.02073 0.423 0.008882 0.03133 0.004360 0.01538 0.210 0.006655 0.09583 0.003277 0.04718 0.341 0.009502 0.1368 0.004625 0.06660 0.632 0.01090 0.1570 0.005278 0.07599 0.822 0.007995 0.1151 0.003915 0.05637 0.521 0.006655 0.09583 0.003277 0.04718 0.361 0.009502 0.1368 0.004625 0.06660 0.632 0.01090 0.1570 0.005278 0.07599 0.782 0.007995 0.1151 0.003915 0.05637 0.521 0.006655 0.09583 0.003277 0.04718 0.321 0.009502 0.1368 0.004626 0.06660 0.632 0.01090 0.1570 0.005278 0.07599 0.782 0.007995 0.1151 0.003915 0.05637 0.561 0.006655 0.09583 0.003277 0.04718 0.321 0.009502 0.1368 0.004626 0.06660 0.592 0.01090 0.1570 0.005278 0.07599 0.822 0.007995 0.1151 0.003915 0.05637 0.522 0.007258 0.05234 0.003572 0.02576 0.253 0.01040 0.07498 0.005051 0.03642 0.470 0.01371 0.09883 0.006567 0.04735 0.733 0.01195 0.08618 0.005768 0.04159 0.617 0.008733 0.06297 0.004272 0.03080 0.385 0.007258 0.05234 0.003572 0.02576 0.265 0.01040 0.07498 0.005051 0.03642 0.471 0.01371 0.09883 0.006567 0.04735 0.745 This journal is © The Owner Societies 1999

0.01195 0.08618 0.005768 0.04159 0.605 0.008733 0.06297 0.004272 0.03080 0.361 0.007258 0.05234 0.003572 0.02576 0.253 0.01040 0.07498 0.005051 0.03642 0.482 0.01371 0.09883 0.006567 0.04735 0.745 0.01195 0.08618 0.005768 0.04159 0.605 0.008733 0.06297 0.004272 0.03080 0.373 0.007258 0.05234 0.003572 0.02576 0.253 0.01040 0.07498 0.005051 0.03642 0.482 0.01371 0.09883 0.006567 0.04735 0.757 0.01195 0.08618 0.005768 0.04159 0.629 0.008733 0.06297 0.004272 0.03080 0.361

L-PHENYLALANINE / FORMAMIDE i i f f mL (PHE) m (FA) mL (PHE) m (FA) H** 0.02671 0.02837 0.01334 0.01417 0.0305 0.03841 0.04080 0.01891 0.02008 0.0808 0.05083 0.05400 0.02463 0.02617 0.143 0.04423 0.04698 0.02161 0.02296 0.0828 0.03219 0.03420 0.01597 0.01697 0.0301 0.02671 0.02837 0.01334 0.01417 0.0305 0.03841 0.04080 0.01891 0.02008 0.0692 0.05083 0.05399 0.02463 0.02617 0.143 0.04423 0.04698 0.02161 0.02296 0.0946 0.03219 0.03420 0.01597 0.01697 0.0301 0.02671 0.02837 0.01334 0.01417 0.0305 0.03841 0.04080 0.01891 0.02008 0.0692 0.05083 0.05399 0.02463 0.02617 0.155 0.04423 0.04698 0.02161 0.02296 0.0946 0.03219 0.03420 0.01597 0.01697 0.0417 0.02671 0.02837 0.01334 0.01417 0.0305 0.03841 0.04080 0.01891 0.02008 0.0808 0.05083 0.05399 0.02463 0.02617 0.155 0.04423 0.04698 0.02161 0.02296 0.0946 0.03219 0.03420 0.01597 0.01697 0.0417 This journal is © The Owner Societies 1999

L-LEUCINE / FORMAMIDE i i f f mL (LEU) m (FA) mL (LEU) m (FA) H** 0.01559 0.02990 0.007787 0.01493 -0.0343 0.02443 0.04302 0.01103 0.02116 -0.0893 0.02970 0.05696 0.01438 0.02758 -0.167 0.02584 0.04955 0.01262 0.02419 -0.122 0.01880 0.03605 0.009322 0.01788 -0.0656 0.01559 0.02990 0.007787 0.01493 -0.0343 0.02243 0.04302 0.01103 0.02116 -0.0893 0.02970 0.05696 0.01438 0.02758 -0.167 0.02584 0.04955 0.01262 0.02419 -0.132 0.01880 0.03605 0.009322 0.01788 -0.0764 0.01560 0.02990 0.007787 0.01493 -0.0451 0.02243 0.04302 0.01103 0.02116 -0.111 0.02970 0.05696 0.01438 0.02758 -0.178 0.02584 0.04955 0.01262 0.02419 -0.145 0.01880 0.03605 0.009322 0.01788 -0.0658 0.01559 0.02990 0.007787 0.01493 -0.0344 0.02243 0.04302 0.01103 0.02116 -0.100 0.02970 0.05696 0.01438 0.02758 -0.167 0.02584 0.04955 0.01262 0.02419 -0.133 0.01880 0.03605 0.009322 0.01788 -0.0548

D-TRYPTOFAN / UREA i f f mD (TRP) m(UREA) mD (TRP) m (UREA) H** 0.007037 0.008288 0.003555 0.004186 0.112 0.01013 0.01193 0.005040 0.005935 0.211 0.01342 0.01581 0.006572 0.007740 0.341 0.01167 0.01375 0.005763 0.006787 0.269 0.008487 0.009995 0.004256 0.005012 0.155 0.007037 0.008288 0.003555 0.004186 0.112 0.01013 0.01193 0.005040 0.005935 0.204 0.01342 0.01581 0.006572 0.007740 0.334 0.01167 0.01375 0.005763 0.006787 0.258 0.008487 0.009995 0.004256 0.005012 0.155 0.007037 0.008288 0.003555 0.004186 0.109 0.01013 0.01193 0.005040 0.005935 0.204 0.01342 0.01581 0.006572 0.007740 0.337 0.01167 0.01375 0.005763 0.006787 0.254 0.008487 0.009995 0.004256 0.005012 0.144 0.007037 0.008288 0.003555 0.004186 0.109 0.01013 0.01193 0.005040 0.005935 0.207 0.01342 0.01581 0.006572 0.007740 0.330 0.01167 0.01375 0.005763 0.006787 0.265 0.008487 0.009995 0.004256 0.005012 0.155 This journal is © The Owner Societies 1999

L-TRYPTOFAN / FORMAMIDE i i f f mL (TRP) m (FA) mL (TRP) m (FA) H** 0.01254 0.01697 0.006143 0.008316 0.290 0.006599 0.008932 0.003330 0.004507 0.101 0.009481 0.01283 0.004716 0.006384 0.180 0.01254 0.01697 0.003143 0.008316 0.301 0.01091 0.01477 0.005391 0.007297 0.237 0.007951 0.01076 0.003985 0.005394 0.140 0.006599 0.008932 0.003330 0.004507 0.101 0.009481 0.01283 0.004716 0.006384 0.184 0.01254 0.01697 0.006143 0.008316 0.286 0.01091 0.01477 0.005391 0.007297 0.230 0.007951 0.01076 0.003985 0.005394 0.140 0.006599 0.008932 0.003330 0.004507 0.101 0.009481 0.01283 0.004716 0.006384 0.184 0.01254 0.01697 0.006143 0.008316 0.293 0.01091 0.01477 0.005391 0.007297 0.234 0.007951 0.01076 0.003985 0.005394 0.143 0.006599 0.008932 0.003330 0.004507 0.104 0.009481 0.01283 0.004716 0.006384 0.184 0.01254 0.01697 0.006143 0.008316 0.293 0.01091 0.01477 0.005391 0.007297 0.234 0.007951 0.01076 0.003985 0.005394 0.143

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