Assessment of the CMR Potential of Sediments from an Extensive French and Belgian Data Vase ;

ELECTRONIC SUPPLEMENTARY MATERIAL to

SEDIMENTS, SEC 5 • SEDIMENT MANAGEMENT • RESEARCH ATICLE

Development and application of a methodology for screening, on the basis of the carcinogenic (H7), toxic for reproduction (H10) and mutagenic (H11) criteria of the latest European legislation, hazardous vs non-hazardous sediments to be disposed of on land

Christophe Mouvet

Received: 14 October 2010 / Accepted: 17Jule 2011 © Springer-Verlag 2011

Responsible editor: Sabine Apitz

C. Mouvet () BRGM, Environment and Process Division, Avenue C. Guillemin, BP 36009, 45060 Orléans cédex 2, France e-mail: [email protected] Table 1 Organic substances analysed in sediments from the 2007 campaign of the French Surveillance Control Monitoring Network set up by the Water Agencies in compliance with the European Union Water Framework Directive

1,1 dichloro-2,2 bis (p-chlorophenyl) Deisopropyl-desethyl-atrazine Lindane 1,1,1-trichloro-2 (o-chlorophenyl) Deltamethrine Linuron 1,1,1-trichloro-2,2 bis (p-chlorophenyl) Desethyl atrazine Mecoprop 1,1-dichloro-2,2 bis (p-chlorophenyl) Desethyl terbuthylazine Metalaxyl M 3 chloropropene Dibenzo(ah)anthracene Naphtalene 4-tert octylphenol Dicamba Napropamide Acenaphtene Dichloroaniline-2,3 Nicosulfuron Acenaphtylene Dichloroaniline-2,4 4-para-nonylphenol Acetochlore Dichloroaniline-2,5 Nonylphenols Aclonifene Dichloroaniline-2,6 Norflurazone Alachlore Dichloroaniline-3,4 Octabromodiphenylether Aldrine Dichloroaniline-3,5 Octylphenol AMPA (aminomethylphosphonic acid) Dichlorobenzene-1,2 Oxadiazon Anthracene Dichlorobenzene-1,3 Oxadixyl Atrazine Dichlorobenzene-1,4 Pendimethaline Azoxystrobine Dichloroethane-1,1 p-(n-octyl) phenol Benzene Dichloroethane-1,2 Pentabromodiphenyl oxyde Benzo (a) anthracene Dichloroethene-1,1 Pentabromodiphenylether Benzo(a)pyrene Dichloromethane Pentachlorobenzene Benzo(g,h,i)perylene Dichlorophenol-2,4 Pentachlorophenol Benzo(b)fluoranthene Dichlorprop Phenanthrene Benzo(k)fluoranthene Dichlorvos Phosphate de tributyle Bromacil Dieldrine Phoxime Bromoxynil Diflufenicanil Polychlorobiphenyl 28 Bromoxynil octanoate Dimethenamid Polychlorobiphenyl 52 C10-13-chloroalcanes Dimethomorphe Polychlorobiphenyl 77 Carbon tetrachloride Diuron Polychlorobiphenyl 101 Chlorfenvinphos Endosulfan Polychlorobiphenyl 118 Chloro-4 Methylphenol-3 Endosulfan alpha Polychlorobiphenyl 138 Chloroaniline-2 Endosulfan beta Polychlorobiphenyl 153 Chloroaniline-3 endrine Polychlorobiphenyl 180 Chloroaniline-4 Epoxiconazole Procymidone Chlorobenzene Ethofumesate Propyzamide Chloroform Ethyl hexyl phthalate Pyrene Chlormephos Ethylbenzene Pyrimethanil Chloronitrobenzene-1,2 Fenitrothion Rimsulfuron Chloronitrobenzene-1,3 Fenoxycarbe Simazine Chloronitrobenzene-1,4 Fludioxonyl Sulcotrione Chlorophenol-2 Fluoranthene Tebuconazole Chlorophenol-3 Fluorene Tetrachlorethene Chlorophenol-4 Fluroxypyr Tetrachlorobenzene-1,2,4,5 Chloroprene Glyphosate Tetrachloroethane-1,1,2,2 Chlorotoluene-2 Hexachlorobenzene Tetraconazole Chlorotoluene-3 Hexachlorobutadiene Toluene Chlorotoluene-4 Hexachlorocyclohexane alpha Trichlorethene Chlorprophame Hexachlorocyclohexane beta Trichlorobenzene 1,2,3 Chlorpyrifos ethyl Hexachlorocyclohexane delta Trichlorobenzene 1,3,5 Chrysene Hexachloroethane Trichlorobenzene-1,2,4 Clomazone Indeno(1,2,3-cd)pyrene Trichloroethane-1,1,1 Cyprodinil Iprodione Trichloroethane-1,1,2 DDD op' Isodrine Trichlorophenol-2,4,5 DDD pp' Isopropylbenzene Trichlorophenol-2,4,6 DDE op' Kresoxim methyl Triclopyr DDE pp' Lambda-cyhalothrine Trifluraline DDT op' Vinyl chloride DDT pp' Xylene

Table 2 Literature review on the speciation in sediments of trace elements analysed in routine monitoring programs Geochemical fraction Trace element Exchangeable / Oxyhydroxides Organic matter/ Residual Total carbonates Oxides sulfides (%) (mg kg-1) Reference (%) (%) (%) As Blute et al. 2009 46 / n. d. 20 / 13 n. d. / 12. < 5 70 - 650 Gault et al. 2003 8 / 2 72 18 n. d. 107 Azcue & Nriagu 1995 3 / 4 n. d. / 57 3 / - 33 680 Maher 1984 3.5 / 2 Σ = 20 12 / n. d. 50 17 Haus et al. 2008  20 /  2 29 Σ  12 50 100 - 270 Jay et al. 2005 34 / - 16 / 6 - / 47 4 130 Harrington et al. 1998 Σ = 10 6 / 73 6 11 - 568

Cd Liu et al. 2008 14 / 31 27 Σ = 21,8 6 1,1 Loska & Wiechula 2002 5 / 18 11 12 / 42 ? 23,6 Pardo et al. 1990 4 / 14 47 Σ = 23,8 13 1,1 Martin et al. 1996 ? / 13 18 77 / < 1 4 8,9 Vaithiyanathan et al 1993 25 / 28 28 Σ = 15 4 4,7 O’Day et al. 2000 † 0 / 100 ‡ 244 - 764

Co Akcay et al. 2003 ? / 1 - 10 41 - 68 Σ = 19 -23 6 -28 30 - 40 Baruah et al. 1996 ? / < 5 40 - 50 Σ  5 40 - 50 19 -150 Yuan et al. 2004 Σ  5 - 11 5 - 18 Σ = 5 - 10 61 - 90 8 -15

Cr Lam et al. 1997 11 / 4 39 Σ = 46 Set as 0 35 - 116 Graham et al. 2009 < 0,4 / 2 -8 50 – 61 Σ = 5 - 16 27 - 35 68 - 1050 Akcay et al. 2003 6 / 13 33 – 36 Σ = 6 – 9 38 – 43 175 - 212 Fytianos and Lourantou 2004 5 / 10 20 Σ = 40 22 20 - 32 Tokalioglu et al. 2000 Σ < 1 < 1 Σ = 43 57 10 O’Day et al. 2000 + + - / - ‡ 244 - 764 Yuan et al. 2004 Σ < 1 < 1 1 - 5 95 - 99 88 - 136

Ni Lam et al. 1997 10 / 34 19 Σ = 36 Set as 0 16 - 35 Pardo et al. 1990 4 / 16 14 Σ = 54 12 6 - 85 Akcay et al. 2003 0,2 – 6 / 7 - 12 20 - 30 16 – 22 43 -46 106 - 315 Baruah et al. 1996 Σ  5 20 - 25 Σ  5 70 - 80 18 - 102 Tokalioglu et al. 2000 5 / 6 5 Σ = 49 37 30 Yuan et al. 2004 Σ < 2 < 2 Σ  5 81 - 94 18 - 42

† Results based on spectroscopic methods ‡ : The residual fraction is determined solely on operational basis in chemical sequential extraction; it does not have an equivalent in spectroscopic methods n. a.: not analysed n. d.: not determined Bold type: dominant fraction; the sum (Σ) of all fractions may not equal 100 % because our data analysis provides mean values from different samples Table 2 (cntd.) Literature review on the speciation in sediments of trace elements analysed in routine monitoring programs

Geochemical fraction Trace element Exchangeable / Oxyhydroxides Organic matter/ Residual Total carbonates Oxides sulfides (%) (mg kg-1) Reference (%) (%) (%)

Pb Galvez-Cloutier and Dubé 0 / 12 31 Σ = 5 49 600 1998 Savonina et al. 2006 Σ = 0 31 Σ = 22 32 176 O’Day et al. 2000 - / + + - ‡ 213 - 1269 Reboreda & Caçador 2007 Σ  5 % 7 – 19 Σ = 50 – 60 2 – 20 20 - 150 Akcay et al. 2003 Σ = 1 – 3 28 – 40 Σ = 17 – 20 24 -34 107 - 149 Tokalioglu et al. 2000 Σ = 5 4 Σ = 53 38 18 Baruah et al. 1996 0 / < 2 40 – 60 Σ  5 30 – 50 8 - 32 Mortimer & Rae 2000 < 5 / 25 0 Σ = 70 n. a. 30 Yuan et al. 2004 Σ  5 < 5 Σ = 12 – 66 29 - 62 20 - 45 Fytianos and Lourantou 2004 5 / 30 10 - 15 Σ = 30 17 13

Zn O’Day et al. 2000 + + - / 80 ‡ 288 -890 Peltier et al. 2005 + (16 ?) + (16 ?) - / 60 ‡ 427 Panfili et al. 2005 10 40 - / 50 ‡ 4 700 Akcay et al. 2003 0,6 – 0,9 / 6 – 8 38 – 49 Σ = 34 – 45 2 – 10 143 - 158 Yuan et al. 2004 Σ  5 < 5 - 23 Σ  5 73 - 96 35 - 125 Tokalioglu et al. 2000 Σ = 3 10 Σ = 60 27 25 - 56 Isaure et al. 2001 + - / + ‡ 6 600

† Results based on spectroscopic methods ‡ : The residual fraction is determined solely on operational basis in chemical sequential extraction; it does not have an equivalent in spectroscopic methods n. a.: not analysed n. d.: not determined Bold type: dominant fraction; the sum (Σ) of all fractions may not equal 100% because the data analysis provides mean values from different samples

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