Fluid Dynamics: Physical ideas, the Navier-Stokes equations, and applications to lubrication flows and complex fluids

Howard A. Stone Division of Engineering & Applied Sciences Harvard University

A presentation for AP298r Monday, 5 April 2004 Outline

• Part I: elementary ideas – A role for mechanical ideas – Brief picture tour: small to large lengths scales; fast and slow flows; gases and liquids • Continuum hypothesis: material and transport properties Newtonian fluids (and a brief word about rheology) stress versus rate of strain; pressure and density variations; Reynolds number; Navier-Stokes eqns, additional body forces; interfacial tension: statics, interface deformation, gradients • Part II: Prototypical flows: pressure and shear driven flows; instabilities; oscillatory flows • Part III: Lubrication and thin film flows • Part IV: Suspension flows - sedimentation, effective , an application to biological membranes

Applied Physics 298r A fluid dynamics tour 2 5 April 2004 From atoms to atmospheres: mechanics in the physical sciences • classical mechanics – particle and rigid body dynamics • celestial mechanics – motion of stars, planets, comets, ... • quantum mechanics – atoms and clusters of atoms Isaac Newton • statistical mechanics 1642–1727 – properties of large numbers Continuum mechanics:: (materials viewed as continua)

electrodynamics solid mechanics fluid mechanics

Applied Physics 298r A fluid dynamics tour 3 5 April 2004 A fluid dynamicist’s view of the world* ** ***

Snow avalanche Galaxies Mathematics Astrophysics Engineering aeronautical Geophysics biomedical Fluid chemical dynamicist environmental mechanical Chemistry Biology Physics

* after theme of H.K. Moffatt ** http://zebu.uoregon.edu/messier.html *** Courtesy of H. Huppert

Applied Physics 298r A fluid dynamics tour 4 5 April 2004 Fluid motions occur in many forms around us: Here is a short tour (Water) Big Little Waves Waves waves

Ship waves

Ref.: An Album of Fluid Motion, M. Van Dyke

Applied Physics 298r A fluid dynamics tour 5 5 April 2004 Flow and design in sports

Cycles and cycling Yacht design and the America’s Cup (importance of the keel)

http://www.sgi.com/features/2000/jan/cup/ Rebecca Twig, Winning Jan. 1996

Bicycling Feb. 1996

Applied Physics 298r A fluid dynamics tour 6 5 April 2004 Swimming (large and small)

Micro-organisms: flagella, cilia

Running on water

Rowing

Basilisk or Jesus lizard

Ref: McMahon & Bonner,On Size and Speed vs. # of rowers? Life; Alexander Exploring Biomechanics T.A. McMahon, Science (1971)

Applied Physics 298r A fluid dynamics tour 7 5 April 2004 Small fluid drops ( is important) Water issuing from a millimeter-sized nozzle (3 images on right: different oscillation frequencies given to liquid; ref: Van Dyke, An Album of Fluid Motion)

Bubble ink jet printer (Olivetti) also: deliver reagents to DNA (bio-chip) arrays

Three-dimensional printing -- MIT (Prof. E. Sachs & colleagues)

Hagia Sophia (‘original’ in Istanbul Turkey)

*This url is no longer 5 inches working -mea Applied Physics 298r A fluid dynamics tour 8 5 April 2004 *http://www.olivision.com/powerpoint/OlivettiPrinter/sld003.htm .… and a pretty picture ….

A dolphin blowing a toroidal bubble

Applied Physics 298r A fluid dynamics tour 9 5 April 2004 Elementary Ideas I

• A brief tour of basic elements leading through the governing partial differential equations

• Physical ideas, dimensionless parameters

Applied Physics 298r A fluid dynamics tour 10 5 April 2004 Elementary Ideas II

Applied Physics 298r A fluid dynamics tour 11 5 April 2004 Elementary Ideas III

Applied Physics 298r A fluid dynamics tour 12 5 April 2004 Elementary Ideas IV

Applied Physics 298r A fluid dynamics tour 13 5 April 2004 Elementary Ideas V

4. and Newtonian fluids

Applied Physics 298r A fluid dynamics tour 14 5 April 2004 Elementary Ideas VI

5. On to the equations of motion

Applied Physics 298r A fluid dynamics tour 15 5 April 2004 Elementary Ideas VII

Applied Physics 298r A fluid dynamics tour 16 5 April 2004 Elementary Ideas VIII

The Reynolds number

Osborne Reynolds • Newton’s second law: (1842–1912) mass.acceleration = å forces

Forces (pressure) Friction from surrounding acting on fluid to fluid which resists motion: cause motion viscosity (µ)

High Reynolds number flow Low Reynolds number flow

U L

Emphasizes ratio of inertial r UL inter-relation of effects to viscous Re = size, speed, effects in the flow m viscosity

Applied Physics 298r A fluid dynamics tour 17 5 April 2004 Elementary Ideas IX

Applied Physics 298r A fluid dynamics tour 18 5 April 2004 Quiz 1

• Consider the rise height of a liquid on a plane.

• Use dimensional arguments to show that the rise height is proportional to the capillary length.

Applied Physics 298r A fluid dynamics tour 19 5 April 2004 PART II: Prototypical Flows I

Steady pressure-driven flow

Applied Physics 298r A fluid dynamics tour 20 5 April 2004 Prototypical Flows II

Additional effects when the mean free path of the fluid is comparable to the geometric dimensions

GAS FLOW IN A MICROCHANNEL: COMPRESSIBLE FLOW WITH SLIP

REF: ARKILIC, SCHMIDT & BREUER

Applied Physics 298r A fluid dynamics tour 21 5 April 2004 Prototypical Flows III

Even simple flows suffer dynamical instabilities!

Ref. D. Acheson Applied Physics 298r A fluid dynamics tour 22 5 April 2004 Prototypical Flows IV

Applied Physics 298r A fluid dynamics tour 23 5 April 2004 Lubrication Flows I

Applied Physics 298r A fluid dynamics tour 24 5 April 2004 Lubrication Flows II

Applied Physics 298r A fluid dynamics tour 25 5 April 2004 Lubrication Flows III

Applied Physics 298r A fluid dynamics tour 26 5 April 2004 Quiz 2

• Consider pressure-driven flow in a rectangular channel of height h and width w with h<< w.

• Find an approximate expression for the flow rate through the channel.

• If the permeability is the ratio of the µu/(∆p/L), find the permeability of such a rectangular channel.

Applied Physics 298r A fluid dynamics tour 27 5 April 2004 Lubrication Flows IV

Applied Physics 298r A fluid dynamics tour 28 5 April 2004 Lubrication Flows V

Applied Physics 298r A fluid dynamics tour 29 5 April 2004 Lubrication Flows VI

Time-dependent geometries

Applied Physics 298r A fluid dynamics tour 30 5 April 2004 Lubrication Flows VII

Applied Physics 298r A fluid dynamics tour 31 5 April 2004 Lubrication Flows VIII

Applied Physics 298r A fluid dynamics tour 32 5 April 2004 Lubrication Flows IX

Applied Physics 298r A fluid dynamics tour 33 5 April 2004 Suspension Flows I

Applied Physics 298r A fluid dynamics tour 34 5 April 2004 Suspension Flows II

Applied Physics 298r A fluid dynamics tour 35 5 April 2004 Suspension Flows III

Applied Physics 298r A fluid dynamics tour 36 5 April 2004 Suspension Flows IV

Applied Physics 298r A fluid dynamics tour 37 5 April 2004 Suspension Flows IV

Brownian motion and diffusion: The Stokes-Einstein equation

• A typical diffusive displacement 2()2txtDt= in time τ are∪ linked by (distance)2 D τ. btkTDζ=6btkTDaπµ=25cmt 10secliqtD−∪ 21cm10secgastD−∪ Diffusion coefficient: Stokes-Einstein equation • Translation diffusion of spherical particles • Einstein: related thermal fluctuations to mean square displacement; with resistivity: ζ = force/velocity

where ζ = F/U

• Stokes: ζ = 6πµa µ=fluid viscosity

Stokes-Einstein equation a F,U • Typical magnitudes (small molecules in water):

… can also investigate other shapes, rotational diffusion

Applied Physics 298r A fluid dynamics tour 38 5 April 2004 Suspension Flows VI

Applied Physics 298r A fluid dynamics tour 39 5 April 2004 Suspension Flows VII

Ref. Stone & Ajdari 1996

Applied Physics 298r A fluid dynamics tour 40 5 April 2004 Marangoni Flows: Surface-driven motions

Applied Physics 298r A fluid dynamics tour 41 5 April 2004 More on thermally-driven flows

Applied Physics 298r A fluid dynamics tour 42 5 April 2004 Gradients in surface tension: Marangoni stresses

• Local value of surface tension is altered by change of temperature or surfactant concentration

low high air tension Fluid dragged tension from low to liquid high tension

• Contaminants typically lower surface tension • Example: alcohol and water surfactants: amphiphilic molecules

Hydrocarbon tail air water Polar head group

Courtesy of Professor Maria Teresa Carlo Marangoni Aristodemo, Florence, and Dr. Raffaele (1840–1925) Savino, Naples

Applied Physics 298r A fluid dynamics tour 43 5 April 2004 Gradients in surface tension: Marangoni stresses

• Local value of surface tension is altered by change of temperature or surfactant concentration

low high air tension Fluid dragged tension from low to liquid high tension

• Contaminants typically lower surface tension • Example: alcohol and water surfactants: amphiphilic molecules (soap)

Hydrocarbon tail air water Polar head group

Courtesy of Professor Maria Teresa Carlo Marangoni Aristodemo, Florence, and Dr. Raffaele (1840–1925) Savino, Naples

Applied Physics 298r A fluid dynamics tour 44 5 April 2004 Wine tears An example of the Marangoni effect

Evaporation from thin film

high surface tension

low surface tension

Applied Physics 298r A fluid dynamics tour 45 5 April 2004 Wine tears An example of the Marangoni effect

Evaporation from thin film

high surface tension Marangoni stress low surface tension

Applied Physics 298r A fluid dynamics tour 46 5 April 2004 In fact: an improved history

• Fluid motions due to gradients in surface were first properly described by James Thomson in 1855 On certain curious motions observable at the surfaces of wine and other alcoholic liquors

• James Thomson was the older brother of William Thomson (who will appear later in the talk)

Applied Physics 298r A fluid dynamics tour 47 5 April 2004 Conclusions

• Continuum descriptions of fluid-like systems begin with momentum statement involving stress (Cauchy equation) • For Newtonian fluids the starting point is the Navier-Stokes equations which is commonly studied assuming the density and viscosity are constant • Common geometric configurations, including thin films, are well studied and ammenable to analysis • Many common features among areas of complex fluids, suspensions, lubricating films, etc.

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