Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary REVISION RECORD Revision Description of Revision No.
0 Summary drafted and issued.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary TABLE OF CONTENTS 1 INTRODUCTION ...... 1 1.1 Background and purpose ...... 1 1.2 Scope ...... 1 1.3 Objectives ...... 2 2 DESCRIPTION OF THE ACTIVITY ...... 3 2.1 Duration and Timing ...... 4 3 DESCRIPTION OF THE ENVIRONMENT ...... 6 4 ENVIRONMENTAL HAZARDS AND CONTROLS...... 7 5 ENVIRONMENTAL MANAGEMENT ...... 18 6 STAKEHOLDER CONSULTATION ...... 18 7 CONTACT DETAILS ...... 20 ATTACHMENT A – DOWNHOLE CHEMICAL DISCLOSURE TABLES AND MATERIAL SAFETY DATA SHEETS (SDS) ...... 21
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary ABBREVIATIONS
ITEMS DEFINITION
AHD Australian Height Datum AHIS Aboriginal Heritage Inquiry System APA APT Parmelia Pty Ltd ATU Aerobic Treatment Unit, septic system BOP Blow Out Preventer DBNGP Dampier to Bunbury Natural Gas Pipeline (PL40) DEC ex. Department of Environment and Conservation (Now DPAW & DER) DER Department of Environment Regulation DFES Department of Fire and Emergency Services DAA Department of Aboriginal Affairs DMP Department of Mines and Petroleum DoW Department of Water DoE Department of the Environment DPAW Department of Parks And Wildlife ED Enerdrill EP Environment Plan ERP Emergency Response Plan ESA Environmentally Sensitive Area ha Hectare IBC Intermediate Bulk Container IBRA Interim Biogeographic Regionalisation for Australia M1 Mondarra well #1 M9 Mondarra well #9 MSF Mondarra Storage Facility MSF OEP Mondarra Gas Storage Facility Operations Environmental Plan (MSF-PL-A-5002_v.2) NES National Environmental Significance SDS Safety data sheet (previously MSDS) NGER Act National Greenhouse and Energy Reporting Act 2007 OSCP Oil Spill Contingency Plan P&A Plug and Abandonment PGERA67 Petroleum and Geothermal Energy Resources Act 1967 PGER(E) Regulations Petroleum and Geothermal Energy Resources (Environment) Regulations PGP Parmelia Gas Pipeline (PL1) PJ Petajoules TVD Total Vertical Depth TJ Terajoule WA Western Australia
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
1 INTRODUCTION
1.1 Background and purpose The Mondarra Storage Facility (MSF) is located within production licence L1. The MSF comprises of a previously extracted gas reservoir being utilised as a gas storage facility. The facility currently has 17.5PJ of usable gas storage capacity and the capability to inject gas at 70TJ/day and withdraw gas at 150TJ/day. The MSF is located within the Shire of Irwin, approximately 350km north of Perth (Figure 2.1). The storage facility is expected to be operational for a period of at least 70 years. Gas from the MSF is transported to the market for use via the existing Parmelia (PL1) and/or Dampier to Bunbury (PL40) natural gas transmission pipelines. APA has recently completed a significant capacity enhancement of the MSF following increased commercial demand for gas storage in the south west of Western Australia (WA). Associated works involved the drilling of two additional wells (Mondarra 6 and 8) and the construction of a new surface facility to allow for gas compression, transfers and processing at the currently permitted 70TJ/day injection and 150TJ/day extraction. In order to meet the required injection and extraction rates a new well is required to replace the old suspended well M1 that was drilled in 1968. Planning for a mew injection and production well is now underway. This will be the Mondarra 9 well (M9). The old suspended M1 well will be plugged and abandoned (P&A). The old M1 well is located approximately 50 metres from M9. These activities are the subject of the M9 Drilling and M1 P&A Environment Plan. A drilling service agreement has been reached between APA and Enerdrill Pty Ltd (ED) to conduct the operations utilising Enerdrill Rig 3 (to drill M9) and Enerdrill Rig 1 (to P&A M1). On-ground site preparation activities for the drilling program are scheduled to commence in October 2015, with drilling operations commencing in late 2015. The M1 P&A operations will follow-immediately after M9 is drilled. The proposed drill site is totally located within the area leased from the freehold landowner for the existing MSF operations. A significant portion of the land to be prepared for the drilling operations is within the currently cleared and compacted pad for the M1 well and associated MSF equipment. The remainder will require the clearing, backfilling and compaction of previously disturbed agricultural land which has been largely cleared of native vegetation for pastoral land use and cropping. Part of the pastoral land to be cleared includes an area less than 1Ha of remnant native vegetation. There are no sensitive environmental receptors in close proximity to, or likely to be affected by the drilling program.
1.2 Scope The M9 Drilling and M1 P&A Environment Plan has been prepared to cover APA’s environment management for the following operations: . Accessing the M9 site and establishing infrastructure to support drilling activities (drill pad, sumps, flare pit, laydown and storage areas). . Mobilising Enerdrill Rig 3 to site, rigging up, drilling and completing an injection and production well (M9) into the Dongara sandstone storage formation. . Demobilising Enerdrill Rig 3 and cleaning-up the site. . Bringing in Enerdrill Rig 1 for the M1 P&A work. M1 is located alongside M9 on the same leased area. . Plugging and abandoning the M1 well, in accordance with a Well Management Plan approved by the DMP.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
. Demobilising and leaving the site ready for future tie-in of M9 to the MSF facility. . Monitoring and rehabilitating sumps and pits associated with the project will take place over a period of time. Rehabilitation to a compacted surface around the well will occur as the sumps dry out and become susceptible to backfilling and compaction. . The drill pad area will not be rehabilitated with top soil and vegetative matter but will remain part of the MSF operational areas. Once the well has been completed, a separate environment plan bridging document will, if necessary, be prepared and lodged with the DMP to cover M9 final completion, testing and flowline tie-in operations to the MSF.
1.3 Objectives The M9 Drilling and M1 P&A EP has been prepared in accordance with the Petroleum and Geothermal Energy Resources Act 1967, the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012 and the Guidelines for the Preparation and Submission of an Environment Plan (DMP, 2012). Furthermore, the EP provides APA with a practical environmental management tool to be implemented as part of the drilling program. The objectives of the project EP are to: . Demonstrate compliance with relevant legislation. . Demonstrate that APA has a clear understanding of how the drilling program will interact with the environment. . Demonstrate that environmental impacts and risks are managed as low as reasonably practicable. . Demonstrate that APA has set appropriate performance objectives, standards and measurement criteria. . Ensure that systems are in place to minimise the environmental impacts associated with the drilling program. The purpose of this EP Summary is to provide information to the general public regarding environmental considerations and management requirements covered in the M9 Drilling and M1 P&A Environment Plan. . This summary document has been prepared in accordance with Regulation 11(7) of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.
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2 DESCRIPTION OF THE ACTIVITY This section describes activities proposed in connection with the Mondarra-9 drilling program and Mondarra-1 plug and abandonment workover, including the location of the drilling area, the indicative timing of well drilling, principles behind well positioning and details of the drilling methods to be used. A summary of project activities is provided in Table 2.1 below. Table 2.1 Summary of project activities Item Detail Company / Permit APT Parmelia Pty Ltd / L1 R1 Mondarra-9 Gas Storage Well Drilling and Mondrra-1 Plug & Project name Abandonment Program. Mondarra Gas Storage Facility (MSF) Onshore Perth Basin approx. 350 km North of Perth / 20km ESE of Location & Tenure Dongara, Western Australia. See maps in attachment. (See Figure 2.1) The M9 drilling lease will be entirely contained on the area of land leased by APT Parmelia Pty Ltd - Certificate of Title 2146 Folio 656 (Deposited Plan 49601), contained within Freehold Lot M356. Well Target Location Latitude: 115° 7'3.37"E (GDA94) Longitude: 29°18'47.75"S Type of drilling program Development drilling (M9) and P&A . Construct the drill pad including laydown areas, flare pit and mud sump (clean soil/gravel will be brought in for infill and sheeting). . Install utilities as required (water lines, water storage tanks, fuel storage, septics for mini-camps). . ED Rig 3 mobilisation and drilling of M9 gas storage well Project summary . Demobilisation of ED Rig 3 and site clean-up . Mobilisation of ED Rig 1 and P&A M1 well . Demobilisation of ED Rig 1 and site clean-up . Rehabilitation to compacted pad status (mud sump and pits only) and monitoring . Access along Pye Road and then existing maintained track over Proposed mobilisation route which APA has access arrangement to the MSF site . Some equipment/personnel will come from MSF . Mondarra Gas Storage Facility (MSF) . Licenced MSF water bore to be used Area infrastructure . Dongara (20km WNW) . ASCO Hovea accommodation approximately 7km along Pye Road . MSF gas storage facility and operating storage wells M6, M8 . M1 well (currently suspended) Existing site infrastructure . M5 currently lower completion P&A . Neighbouring DBNGP & PP infrastructure . Rig pad (Dimensions 140x140m) . On-site accommodation units for senior drilling supervisory personnel Additional infrastructure . On-site storage, office, crib and ablution facilities required . Camp/Accommodation for drilling work force. This will be the ASCO Hovea accommodation camp along Pye Road . Clean gravel for pad will be trucked in.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Drilling rigs, associated drilling equipment, site office, workshops, rig Infrastructure and site camp, spare water storage tank(s), diesel generators, diesel fuel equipment operated and storage tanks, refuelling area, vehicles, lined cuttings and mud sump, stored on the drill pad flare pit, chemical storage areas and waste management areas. Expected drill cuttings Approximately 300m3 volumes (minimum) . 508mm (20’’) to 60 mTVD M9 Drill casing size depth . 340mm (13.3/8”) to 800 mTVD (approximate) . 244mm (9.5/8”) to 2680.7m TVD . 178mm (7”) to 2784.0mTVD M9 Drill mud type . 0-800 m: pre-hydrated bentonite & PAC (and M1 P&A mud type) . 801-2680 m: KCl NaCl PHPA Polymer (See Attachment A for full . 2680-2785 m: Polyamine Polymer (drill in fluid) disclosure)) . Completion Brine: 3% NaCl brine Liquid muds and cuttings allowed to evaporate in a lined and fenced Disposal method for muds sump and then chemically tested for hydrocarbons. If benign, sump will and cuttings be in-filled, when sufficiently dried. . Enerdrill Rig 3 for M9 Drilling Drill rigs . Enerdrill Rig 1 for M1 P&A Timing 24 hours per day, 7 days a week.
2.1 Duration and Timing Site preparation works for the M9 drilling program are scheduled to commence in October 2015, with drilling to commence in December 2015. It is expected that the actual drilling activities may take up to 50 days to complete, with some construction and mobilisation and rehabilitation activities occurring either side of this period. The Mondarra-9 drilling program will be conducted 24 hours per day, 7 days per week. Plug and abandonment of the M1 well is likely to commence two weeks following demobilisation of ED Rig 3 from the M9 site. Indicative durations and timings for each aspect of the drilling program are detailed in Table 2.2. Table 2.2 Mondarra-9 drilling program indicative project schedule Activity Date Duration (Approximate) ED Rig 3 Mobilisation to site Mid Dec 2015 10 days Dreilling of M9 Dec 16 to Feb 16 40 - 50 days ED Rig 3 Demobilisation & Feb 2016 5 days site clean-up ED Rig 1 Mobilisation and M1 Feb 2016 7 days P&A work ED Rig 1 Demobilisation and Feb 2016 2 days site clean-up Site rehabilitation (flare pit if Early 2017 5 days used and mud sump only)
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Figure 2.1 Project location and regional setting, showing location of L1, Mondarra surface area polygon, MSF, M1 and proposed M9 well.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary 3 DESCRIPTION OF THE ENVIRONMENT The M9 and M1 well locations are within the lease boundary of the Mondarra Storage Facility, within previously disturbed agricultural land in the Geraldton Sandplains IBRA region of the Perth Sedimentary Basin. The significant economic activities in the region include primary industries (agriculture and fisheries), oil and gas production, and broad hectare cropping and grazing activities. Other activities in the area include beekeeping and wildflower picking. The site experiences a typical southern Mediterranean climate of mild wet winters and hot dry summers. Site elevation is approximately 80 m Australian Height Datum (AHD), topography is gently undulating with elevation decreasing in a westerly direction between the MSF and the Brand Hwy. The project area is remote from sensitive environmental receptors including Environmentally Sensitive Areas (ESA’s) and areas of National Environmental Significance (NES). The MSF is located entirely within previously disturbed agricultural land. The site is not located within an Environmentally Sensitive Area (ESA). A small pocket of native vegetation is present within the M9 project area. The general condition of native vegetation present within the MSF lease area can be described as stressed, with the majority of individuals presenting discolouration and loss of foliage. Two site flora surveys of the MSF were undertaken during April and September 2006. The remnant vegetation surrounding the MSF was described as being dominated by Banksia menziesii, Banksia attenuata, Calothamnus blepharospermus and Grevillea candelabroides over Baekea sp. Walkaway (P3), Eremaea beaufortioides, Persoonia acicularis, Jacksonia nutans and Petrophile macrostachya intermixed with small shrubs Darwinia pauciflora and Hibertia hypercoides over Mesomelaena pseudostygia, Ecdeiocolea monostachya and grasses.” The majority of grasses recorded were introduced species reflecting the high degree of disturbance from cattle grazing activities. The surveys also identified three Priority 3 (P3) species; Baekea sp. Walkaway, Hakea polyanthema and Verticordia densiflora var. roseostella, all of which were recorded numerous times (>20) in the DPAW Florabase database. No Declared Rare Flora (DRF) were found. The small portion of remnant vegetation that will need to be cleared for the M9 drill pad has been reduced to the smallest areas possible through careful planning of the pad layout and will not significantly impact the regional floristic values. The MSF is not located in close proximity to any rivers, creeks or significant drainage lines. The nearest wetland is Ejarno Spring located approximately 1.5 km west of the site. Groundwater is present in an unconfined superficial aquifer overlying the Yarragadee formation. The water table is at approximately 31 m AHD adjacent the Gingin Scarp, decreasing in a westerly direction. A search of the Department of Indigenous Affairs (DIA) Aboriginal Heritage Inquiry System (AHIS) for heritage sites within close proximity to the MSF was undertaken and there were no registered heritage sites identified intersecting the MSF lease or access routes. In addition the DoE Protected Matters Search confirmed that the MSF and proposed drilling location do not intersect any registered World Heritage Properties or National Heritage Places. There is no significant native fauna habitat which could be impacted by the operations. Although protected fauna are known to reside within the broader region, the activity is within highly disturbed agricultural land and the activity takes place over a limited period, therefore impacts to native fauna are anticipated to be negligible.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary 4 ENVIRONMENTAL HAZARDS AND CONTROLS An ERA addressing the environmental risks associated with the proposed M9 Drilling operations was held on the 30 July 2015. Prior to the workshop taking place, potential environmental aspects and impacts associated with M9 drilling operations were identified using the following sources of information: . DMP documents and guidelines for petroleum activities; . APPEA Code of Environmental Practice; . Specific documents describing MSF operations (i.e. well design basis documents, site layout drawings etc.); . The MSF OEP (MSF-PL-A-5002) . The Mondarra 6 & 7: Well Drilling Environmental Management Plan (MSF-PL-H-1005); . Previous personnel and contractor experience in drilling and gas facility environmental management. These were then risk assessed in addition to other aspects and impacts identified during the workshop. Furthermore, when the scope of the M1 P&A activities was added to the EP, the ERA assessment was subsequently revised with the M1 P&A well engineer in August 2015. It was found that no new environmental aspects could be identified that had not been adequately covered by the M9 ERA workshop. Table 4.1 below provides a summary of aspects and hazards associated with the project, along with preventative and mitigation controls that are implemented to manage the risk to As Low As Reasonably Practicable (ALARP).
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Table 4.1 Summary of environmental aspects, hazards, impacts and management measures (Preventative & Mitigation Controls) identified for the project, along with residual risk classification for each risk or group of risks.
Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
*Speed limit on unsealed road 50 km/hr, 15km/hr around lease. *Impacts on local fauna * Short duration of activity. (respiratory) *All vehicles to remain on existing roads and tracks at all times. Site Access - *Impacts on flora * Contractor project induction. 1 Project vehicles * Dust Generation *Third party nuisance (note: * Dust suppression vehicle will be available. and equipment safety/health excluded from * Minibus will be used for personnel transfer - Reduction in frequency of trips scope) * Rig move plan to be developed and rolled out by ED / APA * Existing MSF TMP will be reviewed and implemented.
* Access protocols are in place, as per existing landholder agreements *Signage i.e. on gates, speed restrictions 50 km/hr. on unsealed access track, 15km/hr around lease. * Temporary fencing will be in place around drilling lease for duration of project. *Disturbance to livestock *Update landholder of upcoming drilling activities. Site Access - * Disturbance to (livestock loss) 2 *Gates to be left as found - gate 6 to be left closed at all times (or asfound) Mobilisation landholder *Impact on agricultural *All vehicles to be parked within dedicated site areas productivity *Hazard and incident reporting via APA reporting system *Site specific HSE inductions which address interactions with pastoral land use *Maintenance and recording of landholder consultation. *Speed limits communicated via contractor induction, signage and traffic management plans
* Access protocols are in place, as per existing landholder agreements *Signage i.e. on gates, speed restrictions 50 km/hr. on unsealed access track, 15km/hr around Site Access - *Inconvenience to surrounding lease. 3 Project vehicles * Road degradation land use - i.e. third party road * Rig move plan to be developed and rolled out by ED / APA and equipment users *Speed limits communicated via contractor induction, signage and travel management plans *Driving according to road conditions (travel management plans for project personnel) *Road maintenance undertaken in response to APA Hazard ID and landholder consultation
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Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
* Small area of remnant vegetation needing to be disturbed. * Majority of disturbance if over degraded/pre-disturbed vegetation. * No sensitive receptor identified in pad areas. Review of previous site surveys reviewed prior to • Loss of native flora conducting any clearing operations. • Impact to listed fauna or Pad * Vegetation clearing * Disturbance area to be clearly surveyed and demarcated prior to works and identified in approved 4 flora. construction (~1 ha) construction plan. • Loss of fauna habitat (drill *APA permitting officer will control start of clearing operations. pad and associated areas) Drilling lease will be fenced off throughout operations. * Cleared vegetation will be removed and topsoil stockpiled separately. * Additional trees planted in agreement with landowner
*Impacts on local fauna (respiratory) Pad * Use of experienced civil contractor. *Impacts on flora (i.e. stomata construction, * Short term duration of project and limited extent of excavation work. blockage, shading, abrasion of 5 sump and other *Dust Generation * If required, water suppression can be brought in. leaf surface or cuticles) excavations. * No drainage lines occurring in area. *Third party nuisance (note: * Cleared vegetation will be removed and topsoil stockpiled separately (<2m topsoil piles) safety/health excluded from scope)
*Acid Sulphate Soil (ASS) Potential *The MSF is located in an area of extremely low probability of acid sulphate soils and hence, Site * Site excavations left problems associated with ASS are not anticipated at this location. 6 *Localised acidic contamination excavations unattended for too * Short duration of project. long *localised and reduced scope of excavation work. *Water logging
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Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard) *M1 is plugged and suspended and only minor amounts of gas may be present in well space. * Emphasis on risk to be raised during rig-up. *M1 infrastructure are signed and fenced. Additional blocks will be installed around well-head to *Accidental vehicle *Uncontrolled gas release to further isolate the wellhead. collision/impact to the atmosphere * PL23 abandonment project completed and signed-off prior to commencing civils (sumps + Operation of wellheads, pipeline, *Ignition/ fuel source for fire conductor) 7 plant and remaining *Gas leaking from well bore *Contractors supervised and inducted to project. equipment infrastructure. *Contribution to greenhouse * On-going well integrity management as per Integrated Production Management Plan (IPMP) effect *Regulatory approvals of initial well design prior to drilling (DMP - Petroleum Division) *PTW, excavation procedures, JHA's and toolbox meetings. *Site access controlled *Contract in place with Alert Disaster Control *Ground disturbing equipment will be clean of soil and organic material upon arrival - written acknowledgement to be provided by contractor(s) *Loss of native flora or * Rig move plan to be developed and rolled out by ED / APA productive food stock (via *Vehicles to remain on designated roads and tracks at all times Site Access - * Weeds: Import, competition for water, *Declared weeds found onsite to be reported to DAFWA 8 Project vehicles export and/or spread nutrients and space) *Weed identification information and management to be available onsite and highlighted to and equipment of weeds. *Poisoning of cattle and/or personnel during site specific inductions native fauna via ingestion *Hazard and incident reporting via APA reporting system * Source of gravel and fill will be certified as clean prior to being brought in - Certification by APA representative.
*Native vegetation largely absent - no phytophthora receptor *No confirmed presence of Phytophthora dieback in vicinity of site area *Vehicles accessing site to remain on designated roads and tracks at all times * Pathogen: Import *Rainfall <500 mm per year limiting survival of phytophthora pathogen and/or spread of Site Access - *Loss of native flora and/or *Sandy soils less prone to clumping and attaching to vehicles sufficient for pathogen transport pathogens and 9 Project vehicles habitat (0.5 ha native flora *Hazard and incident reporting via APA reporting system disease i.e. and equipment and/or habitat if present) *Ground disturbing equipment will be clean of soil and organic material upon arrival - written Phytophthora acknowledgement to be provided by contractor(s) dieback * Rig move plan to be developed and rolled out by ED / APA * Source of gravel and fill will be certified as clean prior to being brought in - Certification by APA representative.
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Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard) *Previous desktop studies have been reviewed, confirming low likelihood of impact to any heritage site. * Aboriginal heritage management to be included in site personnel inductions. * Disturbance to * No works to be undertaken outside of Heritage surveys previously undertaken confirming no Site Access - Indigenous and/or heritage artefacts or areas within MSF lease boundary and along access tracks *Loss of heritage value 10 Project vehicles European heritage * Approved project footprint and site boundary will be clearly defined and fenced off and prevent *Cultural impacts and equipment areas and/or encroachment work. artefacts *All vehicles to remain on existing roads and tracks *Project excavation limited to pre-disturbed areas (sump and pit). * In the unlikely event that heritage artefacts are uncovered, all works are to be halted and DAA contacted for advice. *Site located within cleared agricultural land - minimal fuel available * Liaise with Department of Fire and Emergency Services (DFES) and relevant shire prior to commencing construction activities to ensure activities are adequately planned and managed. * Observe local fire restrictions / and comply with existing DFES exemption (Section 22C) with advice if applicable. *Maintenance of fire response equipment at the site *Maintenance of fire breaks around site; minimum 10 m *Inductions and training which address fire management, fire response and use of fire response equipment *PTW system to be used during hot works *Fire awareness to be reinforced at toolbox meetings Operation of *Fire: *Fire machinery bans communicated via SMS to site personnel plant, * Ignition source for - loss of flora and/or habitat 11 *All machinery and vehicles not in use to be parked in designated areas equipment and fire - loss of agricultural *All stockpiled equipment, materials and waste to be stored in areas of low fire risk personnel productivity *All equipment to be certified and maintained as per machinery and equipment specification *Flammable materials to be removed from areas around ignition sources i.e. welding bays *Vehicles to be equipped with firefighting equipment *Fire emergency response covered in ERP *ER exercises addressing fire response scenarios *Emergency contact details available to all site personnel *Flammable chemicals to be stored as per SDS *Site to be kept neat and tidy and as much as possible free of combustible material *Dedicated smoking areas with ashtrays provided *Hazard and incident reporting via APA reporting system *Equipment operated as intended by competent operators
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Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
*Spills or leaks from *Drilling operations to be undertaken by certified drilling contractor, following strict drilling rig floor, cellar, mud procedures and regular inspections (trip tank, mud management, etc.). tanks and general *Only water-based muds (WBM) will be used. All down-hole chemicals to be DMP approved. surface operations *Cuttings from water-based drilling to be discharged and retained in HD plastic-lined earthen sump on drill pad (Enviro Liner 6030HD to be used). • Accidental release *Drill site is not located in proximity to or on sensitive environmental features like breakaways, • Contamination of soil, surface of drilling cuttings caves, ridges, drainage lines, or significant catchment Drilling / P&A water and/or groundwater, and 12 and muds outside of *Any residual mud on the drill pad to be scraped and returned to the sump upon completion Operations subsequent loss of native flora the sump due to *Testing to be conducted to determine the presence of contaminants (including hydrocarbons) in and fauna. overflow, flooding, the sediment of the sump prior to backfilling. human error, etc. *Any contaminated material to be removed and disposed of offsite by approved contractor. • Burst/leaking hoses *Mud or cuttings around the cellar or the mud pumps will be directed via drainage channels into and seals. the mud sump. • Uncontrolled rig *Sites to be evaluated and remediated in accordance with the requirements of the Contaminated floor runoff. Sites Act 2003 after demobilisation.
* M9 Well will be drilled under DMP approved Well Management Plan, with specific casing and cementing programs * M1 Well will be plugged and abandoned under DMP approved Well Management Plan update with strict casing removal and cementing requirements. *Depleted reservoir is artificially pressurised and monitored - Only gas present. *Drilling rig to have 10000psi blowout preventer (BOP) installed. *Drilling operations undertaken by certified drilling contractor, following drilling procedures and • Hydrocarbons • Contamination of soil, and regular inspections. Drilling / P&A brought to surface in subsequent loss of native flora * Several nearby offset wells have been analysed to understand geological risks and well control 13 Operations the mud system and fauna / habitat. philosophy addressed in Well Management Plan. caused by a well * Unplanned gas venting, *Planning and execution by experienced team with knowledge of local conditions. control incident. emissions. *Approved well management plan, well control and BOP testing procedures. * Approved casing, cementing and mud programme in place, implemented and monitored. * Drilling Emergency Response Plan (ERP) and Spill Response Procedure in place and personnel trained in their implementation. * Sites to be evaluated and remediated in accordance with the requirements of the Contaminated Sites Act 2003 prior to demobilisation/rehabilitation. * No environmental sensitivities in proximity of the site.
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Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard) * M9 Well will be drilled under DMP approved Well Management Plan, with specific casing and cementing programs * M1 Well will be plugged and abandoned under DMP approved Well Management Plan update with strict casing removal and cementing requirements. * Loss of formation * Depleted reservoir is artificially pressurised and monitored - Only gas present fluid to subsurface. * Surface and intermediate casing strings will be cemented to surface (double barrier philosophy). (Well integrity) • Contamination of * Offset wells indicated formation has very small loss to formation potential groundwater, and subsequent * Setting a surface casing string to 800m depth, well below the surface aquifers. Drilling / P&A • Crossflow between loss of native flora and fauna or * Well design includes running a production casing to surface, further improving aquifer protection. 14 Operations fluid strata during impacts to regional * Using drilling muds. Drilling muds are designed to produce a filter cake across permeable drilling (drilling fluid groundwater users. formations that limit flow of drilling mud into aquifers. or formation into * Top hole section drilled with prehydrated bentonite preventing ingress to formation. migration into * Only benign material (Bentonite and polymer sweeps) used in low concentrations in the initial aquifers). mud composition. * All chemicals used to be approved by DMP after being subjected to APA's chemical approval process. * Existing DoW licencing and monitoring requirements for the MSF water bore neighbouring M5 bore.
*Vehicle accident *Speed limit on sealed access road 80km/hr.; unsealed 50km/hr. during chemical *Dangerous Goods transport as per Dangerous Goods Safety (Road and Rail Transport of Non- transport resulting in explosives) Regulations 2007 accidental release Transport of *Road maintenance to ensure roads in best possible condition (e.g. fuel, oils). fuels and *Hazard ID through APA management systems *Localised spill resulting in chemicals to *Spills addressed in ERP and OSCP - Credible spill of contamination of soils and/or 15 and from site - *Traffic management plan <210L (e.g. dropped water (worst case scenario: Chemicals *Emergency service available for response container from Ejarno Spring area). transported in a *Securing and/or tie down of chemical containers vehicle). vehicle to site *Appropriate vehicle use
*Trained and competent drivers -Max. Credible spill *Fuel deliveries by reputable service company with trained drives. 30 000L (e.g. fuel *Vehicle maintenance as per manufactures recommendation tanker roll-over).
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard) * Hazardous storage area to be established for the project (Hydrocarbon skip bin and bunded IBC's) * No wetlands or watercourses located within 1.2km of site (surface water contamination not credible) * Groundwater >35m below ground *Inductions which specifically address storage and handling of chemicals *SDS available onsite *Spill response equipment, including containment and recovery equipment *Spill kits located in close proximity to areas where chemicals are stored Storage & *Procedure for chemical handling handling of * Accidental release *Spill scenario addressed in ERP and OSCP chemicals and of substance which is *ER exercises addressing environmental aspects liquid wastes - potentially harmful *Hazard and incident reporting via APA reporting system * Localised soil contamination Stored in large to the environment * DMP reporting requirements as per EP and OSCP requirements. *Leaching to groundwater vessels, fuel (diesel, hydraulic oil, * Dedicated bunded area for environmentally hazardous chemicals. 16 table not credible trailer, drilling chemicals,) *Weekly housekeeping checks *Surface water contamination containers, * Transfer spill * Dry chemicals stored on pallets and covered by tarpaulins not credible mud and * Spill during *Internal environmental audit against EP requirements prior to completion of the drilling program. cementing container handling *Trained and competent operators chemicals, etc. (i.e. forklift drop) *APA Environmental awareness package, hazardous chemical handling training modules * Hazardous chemicals transported in accordance with the Dangerous Goods Safety Act 2004 and Code of Practice * For hazardous liquids, the bund holding capacity will be of 110% of the capacity of the maximum capacity of the biggest container within the bund or 25% of the total capacity of all the tanks within the bund whichever is the greatest (as per AS/NZ 1940:2004). * Fuel cartage undertaken by competent contractor only. * Designated refuelling area and drip trays available for other transfers. * Containers & bunds checked regularly to ensure that they are in sound order (weekly HSE inspections) *Inert & putrescible wastes to be removed from site and disposed of at an appropriate class waste *Incorrect *Vermin attraction facility inert/putrescible *Aesthetic impacts *Sealed rubbish bins to be conveniently located onsite Inert and waste storage and *Impacts on surrounding land *Site fence will help prevent spread of windblown rubbish offsite putrescible 17 disposal methods use i.e. stock ingestion resulting *Weekly housekeeping to assess waste disposal methods and clean up litter waste (i.e. general in harm or death *Regular emptying of rubbish bins to skip to prevent overfilling and spillage generation household, organic *Native fauna impacts i.e. harm *Hazard and incident reporting via APA reporting system waste, plastics etc.) due to ingestion, trapping etc. *Inductions addressing general waste management *Operations waste management procedure
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
*Controlled waste skip bins and bunded storage disposal containers will be provided to site for duration of project *Empty chemical containers controlled onsite as per full containers (bunds, drip trays, etc.) *Empty oil, solvent and/or chemical containers removed from site to appropriately classed disposal facility *Localised soil staining *Incorrect storage *Contaminated material removed from site by contractors licensed by DEC under Environmental Storage of *Extremely localised and disposal of Protection (Controlled Waste) Regulations 2004 18 controlled contamination on hardstand empty/waste *Sealed rubbish bins to be conveniently located onsite waste *Water/groundwater impacts chemical containers *Site fenced to prevent spread of windblown rubbish offsite not credible *Weekly housekeeping to assess waste disposal methods and clean up litter *Regular emptying of rubbish bins to skip to prevent overfilling and spillage *Hazard and incident reporting via APA reporting system *Inductions addressing general waste management *Operations waste management procedure
* Recycling/re-use opportunities for scrap metal to be identified as part of project planning *Controlled waste skip bins and bunded storage disposal containers will be provided to site for duration of project *Suspected contaminated material removed from site by contractors licensed by DEC under *Incorrect storage Environmental Protection (Controlled Waste) Regulations 2004 and disposal of *Inert wastes to be removed from site and disposed of at an appropriate class waste facility Removal and *Aesthetic impacts industrial waste (e.g.: *Skip bins and removal trucks will be provided to site. disposal of inert *Incorrect disposal 19 concrete, scrap *Site fenced to prevent spread of windblown rubbish offsite industrial •Potential contamination and metal, plastics, *Weekly housekeeping to assess waste disposal methods and clean up litter material waste management issues. pallets, electrical *Regular emptying of rubbish bins to skip to prevent overfilling and spillage equipment, etc.) *Hazard and incident reporting via APA reporting system *Inductions addressing general waste management *Operations waste management procedure *Materials neatly stockpiled during project * Site inspection to be completed prior to demobilisation (photographs to be taken).
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
*Drill pad will be fenced-off: large animals unable to access EP *Site excavation left *Fence to be maintained to ground level Site *Death of individuals native unattended. * 3 sides of drill sump will be fenced during operations and then closed-off after drilling is 20 excavations fauna. *Fauna or livestock completed. (flare pit, sump) *Death injury to local livestock. entrapment *Sumps and pits will be equipped with fauna egress mats/ramps. * Limited extend and duration of excavations.
* Adequate pad design in civil scope of work. *Once completed, pad will remain and be maintained as part of MSF infrastructure. * Sump and lease will be bunded off (diversion structures) * ATU unit will use fertigation system. *Loss of productive topsoils Site drainage * Topsoil will be pushed aside as part of standard excavation procedure *Gullying/ trenches- 21 (onsite water *Soil erosion *Site area clearly marked/fenced to prevent encroachment of works outside of agreed boundaries disturbance to surrounding erosion) *No water courses or drainage lines traversing site area land use *Short duration of excavation work *Sandy soils- high percolation *Hazard ID via APA incident reporting system to identify repair strategy *Rectify erosion where impacts to the surrounding environment exist
• Disturbance to native fauna, * Existing MSF plant presence and lighting. livestock and landholders. * Identify and consult with potentially affected stakeholders. Presence of drill * 24 hr rig lighting 22 • Temporary local * Direct lighting towards work areas to minimise impact on native fauna. rig * Light emissions concentration of fauna that are * The drill site will be fenced off for duration of project. attracted to light. * Closest homestead is located 2.5 km from drill site.
* Closest homestead is located 2.5 km from drill site. Presence of drill * Noise from rig • Disturbance to native fauna, * Stakeholder consultation to be completed. 23 rig operations livestock and landholders. * Localised and temporary impact * Proximity of existing MSF.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
Risk Aspect (Source Activity/Cause Environmental Impact(s) Controls Item # of Risk) (Hazard)
* Short nature of the drilling program. • Depletion of groundwater * Limited project water requirements (Approximately 5 ML to drill the well), well within area GWL • Unmonitored water reserves. allocations. use. • Impact to farming activities * Water use will be monitored and any waste reported 24 Water Use • Use of water bore and water availability. * Ground Water Licence (GWL171038(3)) in place for taking water from MSF bore. in excess of licenced • Loss of fauna habitat. * Monitor site water bore flow meeter and monitor usage regularly. capacity. • Localised soil salinity * Weekly site HSE inspection to ID water use and wastage. * Pre and post drilling water monitoring ground water quality data will be collected and reviewed.
*Limited and short term nature of D&A project Equipment and *Air emissions - *Diesel usage on site will be reported. machinery Exhaust (e.g.: rig *Record quantities for emissions reporting (PCC) exhaust - All engines, *Pollution *Annual NGERs and NPI reporting 25 other compressors, *Contribution to greenhouse * DMP Quarterly emission report to DMP. (controlled) air generators, effect *Maintenance of equipment to ensure optimal performance and minimization of emissions as per emission machinery & manufactures specifications sources vehicles)
* Well control / * Requirements to flare highly unlikely given nature of drilling program. integrity situation * No gas to be vented except in case of an emergency (e.g., well kick). *Pollution Emergency resulting in * Minimise volume of gas to be flared (where possible) and undertake flaring in accordance with 26 *Contribution to greenhouse flaring / venting unplanned gas Clauses 230, 531 and 613 of Onshore Petroleum Exploration and Production Requirements 1991. effect release or * Obtain approval for flaring from DMP and DFES during restricted burn periods. requirement to flare.
* Loss of combustion * No sensitive receptor (e.g. surface water) in vicinity of the pad. during emergency * Flare pit to be constantly monitored during flaring. * Contamination of flare pit or flaring. * Testing to be conducted to determine the presence of contaminants (including hydrocarbons) in Emergency surrounding area. 27 * Release of the sediment of the sump prior to backfilling. flaring / venting * Contamination of soil, surface produced liquid (oil * Any contaminated material to be removed and disposed of offsite by approved contractor. water. and/or drilling muds) * Sites to be evaluated and remediated in accordance with the requirements of the Contaminated during flaring. Sites Act 2003 prior to demobilisation/rehabilitation.
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary 5 ENVIRONMENTAL MANAGEMENT The environmental management measures required under this EP will be implemented via the APA WA ISO14001 accredited integrated Health, Safety and Environmental Management System (APA HSEQ Management System) which comprises the following elements: . A corporate policy stating APA’s commitment to responsible environmental management; . Clearly stated objectives consistent with this commitment; . Clearly defined roles and responsibilities for personnel to indicate their obligations regarding environmental management; . Appropriate induction and training of personnel; . Monitoring and auditing programs to assess compliance with procedures and the achievement of objectives; . A system of reporting for recording data and notification of relevant personnel; and . Ongoing consultation to seek input from and inform all parties of relevant issues. The APA HSEQ Management System provides for the implementation of all of the requirements outlined in the project EP. The APA Hazard and Incident Reporting System forms part of the APA integrated HSEQ Management System and caters for the reporting, recording and follow up of all safety and environmental hazards and incidents. Personnel who observe, or are involved in a hazard or incident must complete report (APA HSE GP 07.01 T4) describing the circumstances that arose. Completed hazard and incident forms are sent to APA administrative personnel for entry into the APA hazard and incident database. Notification is then sent to the relevant Team Leader or Manager (who has thus far been verbally informed) for follow up and/or investigation if required. Reportable incidents are also forwarded to the Regulatory Manager for regulatory reporting. APA has a comprehensive database of procedures, forms and other guidance materials pertaining to environmental management (Available online at THE HUB). Additional site- specific documentation has also been developed as appropriate. Documents are available to all personnel via the company intranet.
Environmental management measures specific to the project are located in the Environmental Risk Assessment summary table, in section 4 of this document. Details of all chemicals and other substances in or added to any drilling fluids, treatment fluids or introduced into the Mondarra-9 and Mondarra-1 wells are provided Attachment A of this document, along with Material Safety Data Sheets (SDS) for each product to be used. 6 STAKEHOLDER CONSULTATION The following stakeholders have been identified as having an interest in MSF operations, and the associated M9 drilling and M1 P&A program and were consulted with throught the project planning: . DMP has been identified as the Government body responsible for regulation of the MSF operations. Ongoing liaison is undertaken with the DMP Environment Branch, Petroleum Branch and Resources Safety Division. Correspondence comprises emails, telephone calls and face to face meetings (including participation in the project ERA workshop) in addition to reporting as per Section 9. DMP will continue to be kept informed regarding relevant operational items and notified of any material changes to the information provided in the
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary
project EP. Records of correspondence with DMP are maintained and can be made available upon request. . DER has been contacted to discuss the project and it was confirmed that that there are no Part V works approval or licence requirements from DER for drilling a new well into the reservoir at Mondarra. It was confirmed that no further communications with DER are required with regards to the drilling program. . DoW is the Government body responsible for regulation of water extraction for MSF operations. APA will keep DoW informed about extracted water quantities and water quality and level sampling results on an annual basis as per groundwater license requirements (GWL171038(3)). . The Shire of Irwin is the Local Government stakeholder for the MSF. APA maintains regular contact with the Shire as part of an ongoing community consultation program for its operating assets. Contact is made at least annually, and associated records maintained. Liaison with the Shire of Irwin has been ongoing since construction of the Parmelia Pipeline in 1971 and will be maintained as part of the drilling program. . The Shire of Irwin was advised telephonically about the drilling of M9 in August 2015, and it was confirmed that approvals for some of the infrastructure will be required. These applications are to be prepared and approval received before drilling can commence. . The DFES Dongara Emergency Service Unit has been identified as the primary contact in the event of an emergency situation at the MSF or during associated drilling activities. Regular contact is maintained with DFES in Dongara and records of correspondence undertaken are maintained. In addition, DFES is involved in relevant emergency response exercises at the MSF and other locally operated APA facilities. Section 22C and 25A exemptions are in place, covering the operations. . Alert Disaster Control has been engaged by APA to assist in responding to well blow outs at the MSF and this will be extended for the drilling program. A contract is in place and relevant contact details provided in the MSF ER Plan. . Landholders with properties intersecting the MSF lease and the MSF access track are contacted at least annually by APA as part of an ongoing community consultation program for its operating assets. Additional consultation was also undertaken throughout recent site expansion works. . APA has a long history of positive relations with landholders impacted by the MSF which has been ongoing since the construction of the Parmelia Pipeline in 1971. . The owner of Lot M356 was specifically consulted in regards to the upcoming drilling program and signed an agreement relating to required vegetation disturbance for the project. Stakeholder will be kept up to date on progress and any unforeseen changes to the proposal including delays to the commencement or completion of the activity. APA will continue to consult with the relevant government authorities, neighbouring farms and interested persons regarding project activities prior to site mobilisation and throughout the life of the project. Ongoing consultation will be maintained with any interested stakeholders and APA shall promptly track and response to any queries or complaints associated with this or any of its operations, in line with the APA Land Management Plan (320-PL-HEL-0001).
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary 7 CONTACT DETAILS APT Parmelia Pty Ltd is a wholly owned subsidiary of the APA Group (APA), with WA office located in Perth, WA. Address: APA Group Level 5, 233 Adelaide Terrace Perth WA 6000 For further queries regarding Environmental Management of the M9 Drilling and M1 P&A project, please contact Ph.: (08) 6189 4300; or Email: [email protected]
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Mondarra 9 Drilling and Mondarra 1 Plug & Abandonment Program Environmental Plan Document Summary ATTACHMENT A – DOWNHOLE CHEMICAL DISCLOSURE TABLES AND MATERIAL SAFETY DATA SHEETS (SDS)
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Down-Hole Chemical Disclosure Information _ Rev.3 (13/10/2015)
Operator: APT Parmelia Pty Ltd
Project/Wells: Mondarra-9 (M9) Mondarra-1 Plug & Abandonment (M1)
To comply with Regulation 15(9) of the PGER(E) Regulations, details of all chemicals and other substances in or added to any drilling fluids, treatment fluids or introduced into the Mondarra-9 and Mondarra-1 wells are provided in this document. Disclosure information is provided for the following systems (click to access):
1- M9 Water Based Drilling Mud 2- M9 HTB Slurry Cement 3- M9 Class G Slurry Cement 4- M9 Microbond HT Slurry Cement 5- M9 Microbond Slurry Cement 6- M9 Tuned Spacer E+ Cement 7- M9 TSE III Cement 8- M1 Water Base Drilling Mud 9- M1 Class G Slurry Cement
The DMP will be notified of any significant changes or additions to the information provided. Significant changes are defined as:
• Substitution of any product, additive, chemical or other substance. • Proposed use of additional product and new chemicals not previously listed in Appendix E. • Altering a product volume or chemical concentration by more than 5% (of the original values included in Appendix E). • Emergency use of a new chemical A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Drilling Fulid - Water Based Mud
TOTAL VOLUME OF SYSTEM 1,991,348* (L): *Includes 30% Contingency.
B. PRODUCT LIST:
% Product in system Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached Fluid
Water Local Bore Water Base Fluid Water sourced from local aquifer - No hazard. 74.26% N/A
Acute Toxicity: Fish Toxicity 96h LC50: 8-19 g/L (Salmo gairdneri )
Chronic Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of Bentonite / Rheoben Newpark Viscosifier 6.21% Y breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis.
Biodegradation/bioaccumulation: The product is insoluble in water and can be removed by filtration and so is not expected to present a hazard.
Acute Toxicity: In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictalurus punctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l.
Chronic Toxicity: A chronic reproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronic aquatic Shale swelling inhibition (smectite & Potassium Chloride Newpark toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerations the background 4.35% Y illite clays) concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for further investigations of KCl on marine species.
Biodegradation/bioaccumulation: The low concern for the environment is supported by the absence of a bioaccumulation potential for the substance. http://www.inchem.org/documents/sids/sids/KCHLORIDE.pdf This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
Entire Product Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000
< 88% SODIUM CARBOXYMETHYL CELLULOSEas ingredient. Toxicity: LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat)
< 1.8% SODIUM CHLORIDE as ingredient. Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) Drilling Fulid - Water Based Rheopac RD Fluid Loss & Viscosifier LD50 (Intraperitoneal): 2602 mg/kg (mouse) 0.25% Y Mud LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)
< 0.7% SODIUM GLYCOLATE as ingredient. Toxicity: LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat)
Remainder is water.
Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Barite / Rheobar Newpark Weighting Agent 1.44% Y
http://www.inchem.org/documents/ehc/ehc/ehc107.htm
Acute toxicty LC50 (rat, oral): 500<1000 mgl/kg Skeletonema costatum (Algae tox test) EC50, 54,4mg/l Acartia tonsa (Crustacea tox test) LC50, mg/l, 52,4mg/l Scophthalmus maximus juvenile (Fish tox test) LC50, >51,0mg/L
Biodegradation: Prevent swelling clays by blocking the AVAPERM NF Newpark Seawater test OECD 306, 75%. 1.44% Y site for water hydration. Bioaccumulation: OECD 117,Log Pow ≤ 1,36 (0,44 weighted average)
An equivalent product to AVAPERM NF has been registered on the CEFAS Offshore Chemical Notification Scheme with a ‘Gold’ rating & Registration # 24780
Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Rheopac LV / Drispac LV Newpark Fluid Loss 0.75% Y Bioaccumulation: Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
Not expected to bioaccumulate. Xanthan Gum (P) / Flowzan Newpark Vicosifier 0.47% Y
http://www.inchem.org/documents/jecfa/jecmono/v21je13.htm
This product is expected to be of low toxicity.
>98% STARCH Starch B is not harmful to aquatic organisms and does not cause long-term adverse effects in the aquatic environment. Starch is not expected to bioacumulate.
This product also contains Dazomet (ISO) [Tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione], however due to the low levels present, adverse health effects are not anticipated. Starch B Newpark Fluid loss reducer 1.49% Y <1% DAZOMET (ISO)[TETRAHYDRO-3,5-DIMETHYL-1 -,3,5-THIADIAZINE-2-THIONE]
LD50: 180 mg/kg (mouse), 2260 mg/kg (rat) LCLo (inhalation) 8400 mg/m³/4h (rat) LD50 (intraperitoneal) 87 mg/kg (rat) LD50 (subcutaneous) 248 mg/kg (mouse) LDLo (intramuscular) 250 mg/kg (dog) TDLo (oral) 3120 mg/kg/30 days-continuous (rat)
Toxicity: (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg] Encapsulating Agent - provides shale JK-161 LV Newpark Biodegradation/bioaccumulation: 0.25% Y inhibition For the most part, polyacrylamide is resistant to microbial attack, and its degradation is mainly through physical breakdown. Polyacrylamide has been shown to be non-toxic to humans, animals, fish, and plants; the only concern has been the toxicity of its residual monomer (acrylamide) content, which is a known neurotoxin to humans. Polyacrylamide can also degrade to acrylamide under environmental conditions The monomer is bio-degradable and does not accumulate in soils.
WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). pH control-prevents bacteria & Caustic Soda Newpark SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles 0.06% Y corrosion. released to atmosphere should be removed by gravity and/or be rained out. Toxicity: SODIUM SULPHITE (775-83-7): LD50 (Ingestion): 820 mg/kg (mouse) LD50 (Intraperitoneal): 950 mg/kg (mouse) LD50 (Intravenous): 175 mg/kg (mouse) LDLo (Ingestion): 2825 mg/kg (rabbit) Sodium Sulphite Newpark Oxygen Scavenger LDLo (Intravenous): 400 mg/kg (cat) 0.05% Y LDLo (Subcutaneous): 600 mg/kg (rabbit)
Bioaccumulation: Does not bioaccumulate. OCNS category (actual or equivalent chemical) and Registration number. E-3448OCNS category (actual or equivalent chemical) and Registration number. E-3448
WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
Toxicity: Acute Oral Toxicity: 4090 mg/kg (rat). Acute Inhalation Toxicity: 800 mg/m3/2 hours (guinea pig). Soda Ash Newpark pH / Hardness control 0.06% Y LD50 (intraperitoneal): 117 mg/kg (mouse) LD50 (subcutaneous): 2210 mg/kg (mouse) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Bioaccumulation: Does not bioaccumulate.
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Sodium bicarbonate can neutralise the gastric juices in the stomach. During neutralisation, carbon dioxide gas is evolved and may cause stretching of the stomach, and with very large doses possible damage or rupture. Toxicity: LD50 (Ingestion): 3360 mg/kg (mouse) LC50 (inhalation): 4.74 mg/L (rat) Ecotoxicity Sodium Bicarbonate Newpark pH Buffer, Contamination Treatment 0.04% Y LC50 (Oncorhynchus mykiss) = 7.700 mg/l/96hrs. LC50 (Lepomis macrochirus) = 7.100 mg/l/96hrs. EC50 (Crustaceans, Daphnia magna) = 4.100 mg/l/48hrs LOEC (Crustaceans, Daphnia magna) = 3.100 mg/l/48hrs.
Bioaccumulation: Does not bioaccumulate.
May be toxic to fish at moderately high levels (120 ppm is fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which may cause oxygen depletion in large spills. Citric acid occurs naturally in many plants. Citric Acid Newpark pH Buffer 0.04% Y If citric acid is released to water, it is expected to biodegrade rapidly. <18-25% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):
Toxicity: LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr Biocide/Prevents bacterial LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr Idcide-20 Newpark 0.02% Y contamination of the mud LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr Waste Water management EC50 (Activated Sludge) = 24 mg/L/3 hr
Biodegradation: This product is readily biodegradable.
>75% Remainder is water.
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse Circal Y Newpark Bridging & Weighting Agent 1.24% Y environmental effects.
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse Omyacarb-40 Newpark Bridging & Weighting Agent 0.24% Y environmental effects.
Acute Toxicity: Main ingredient Octan-2-OL (>98%); Oral, mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 9300 mg/kg; Oral, rat: LD50 = 200 mg/kg; Water accounts for the remaining <2% of the product.
Biodegradation/bioaccumulation: Defoam-A(I) Newpark Defoamer Aliphatic hydrocarbons behave differently in the environment 0.01% Y depending on their size. WATER: Light aliphatics volatilise rapidly from water (half-life - few hours). Bioconcentration should not be significant. SOIL: Light aliphatics biodegrade quickly in soil and water, heavy aliphatics biodegrade very slowly. ATMOSPHERE: Vapour-phase aliphatics will degrade by reaction with hydroxyl radicals. The manufacturer reports that this product is > 80%biodegradable.
>94% MAGNESIUM OXIDE Toxicity: The LD50 for oral administration of MgO in mice was reported to be 810 mg/kg (Sigma-Aldrich, 2001b). The LD50 for oral administration in rats was reported to be 3870 mg/kg in males and 3990 mg/kg in females (Clydesdale, 1997).
<2.5% SILICA, AMORPHOUS as ingredient. Magox Newpark Temperature stabiliser Toxicity: 0.50% Y LD50 (Ingestion): 3160 mg/kg (rat)
< 3.5% Calcium Oxide as ingredient. Toxicity: LD50 3059 mg/kg (Mouse/Intraperitoneal) This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate
Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Sodium Chloride Newpark Weighting Agent 5.22% Y Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate
Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
68-72% TRIETHANOLAMINE (102-71-6)
Toxicity Data: LC50 (shrimp): > 100 ppm. LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) Filming amine based corrosion LD50 (Skin): > 20 mL/kg (rabbit) Ancor-1 Newpark 0.24% Y inhibitor TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer)
Biodegradation: In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater
Remainder is water.
Toxicity Data: LD50 (Ingestion): 2650 mg/kg (mouse) SAPP is used to deflocculate or disperse LD50 (Intraperitoneal): 1 g/kg (mouse) bentonite muds or fluids with high LD50 (Intravenous): 59 mg/kg (mouse) levels of low gravity solids. LD50 (Subcutaneous): 480 mg/kg (mouse) SAPP Newpark · Treating gumbo clays in surface hole 0.24% Y applications. OCNS category (actual or equivalent chemical) and Registration number E-2449 Health HazardSummary Low toxicity. · Used in spacers prior to cementing to disperse bentonite filter cakes. Biodegradation/bioaccumulation (SAPP): This product is readily biodegradable. It is an edible product.
TOTAL (system products) 98.89% Contingency products * Shaded products are contingent.
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse Limestone LSC Newpark Bridging & Weighting Agent 3.48% Y environmental effects.
Acute Toxicity: LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) Fracseal Fine Newpark Prevent lost circulation LD50 (skin) > 2000 mg/kg (rabbit) 8.70% Y
Biodegradation/bioaccumulation: Main ingredient is Cellulose, an organic material which is readily biodegradable.
Toxicity: Ecotoxicity LC50 (Aquatic species): >100mg/L/96hrs. Non hazardous to aquatic organisms.
Ethylene glycol will mainly exist in the vapour phase in the ambient atmosphere where it will be degraded by reaction with hydroxyl radicals. Expected to MEG / Pipefree M Newpark Agent to free differentially stuck pipe 8.70% Y be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces.
Biodegradation/Bioaccumulation: Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
Cristobalite (14464-46-1) as an ingredient (<5%) TCLo (inhalation) 16 mppcf/8hours/17.9 years (humanfibrosis).
Quartz (Silica Crystalline) (14808-60-7) as an ingredient (<2%) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis).
2-Propenenitrile-1,3- Butadiene Rubber as an ingredient (<50%) LC50 (96 h): >100 mg/L (Oncorhynchus mykiss) LC50 (48 h): >100 mg/L (Daphnia Magna) LC50 (48 h): >100 mg/L (Scenedesmus quadricauda) 8.51% Yes Irwin-01 Exploration Well Chemical Disclosure- Drilling 03/03/2015 Natural Rubber as an ingredient is a natural product (<50%) It is not anticipated to cause adverse environmental effects.
Polyisoprene as an ingredient (<50%) General-purpose rubber used to replace natural rubber Acute Oral LD50 : >2000mg/kg (Rat, LIR-30) Acute Dermal Irritation ( Rabbit ) : Negative ( LIR-30 ) Strata-Vanguard Newpark Bridging Agent Acute Inhalation LC50 : Not Available 8.70% Y
SBR Elastomers as an ingredient (<50%) LD50 (Oral) >5000 mg/kg (rat) LD50 (skin) >20000 mg/kg (rat) LD50 (inhalation) >20000 mg/kg (rat) Cellulose (9004-34-6) as an ingredient is a natural product (<30%) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit). Diatomaceous earth, Flux calcined as an ingredient (<15%) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis). Fullers earth (Bentonite) as an ingredient (<10%) Fish Toxicity 96h LC50: 8-19 g/L (Salmo gairdneri).
Limestone as an ingredient (<10%) Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects.
Polyethylene (9002-88-4) as an ingredient (<5%) LDLo (ingestion) 3000 mg/kg (rat) Magnesium Oxide (1309-48-4) as an ingredient (<1%) TCLo (inhalation) 400 mg/kg (human)
Acute Toxicity:
Calcium Oxide (1305-78-8) as an ingredient (<10%) LD50 3059 mg/kg (Mouse/Intraperitoneal)
Calcium Hydroxide (1305-62-0) as an ingredient (<5%) LD50 (ingestion) 7300 mg/kg (mouse)
Cristobalite (14464-46-1) as an ingredient (<5%) TCLo (inhalation) 16 mppcf/8hours/17.9 years (humanfibrosis)
Quartz (Silica Crystalline) (14808-60-7) as an ingredient (<3%) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) 2-Propenenitrile-1,3- Butadiene Rubber as an ingredient (<50%) LC50 (96 h): >100 mg/L (Oncorhynchus mykiss) LC50 (48 h): >100 mg/L (Daphnia Magna) LC50 (48 h): >100 mg/L (Scenedesmus quadricauda)
Natural Rubber as an ingredient is a natural product (<50%) It is not anticipated to cause adverse environmental effects. Polyisoprene as an ingredient (<50%) General-purpose rubber used to replace natural rubber Acute Oral LD50 : >2000mg/kg (Rat, LIR-30) Acute Dermal Irritation ( Rabbit ) : Negative ( LIR-30 ) Acute Inhalation LC50 : Not Available Frac Attack Newpark Prevent lost circulation 9.93% Y SBR Elastomers as an ingredient (<50%) LD50 (Oral) >5000 mg/kg (rat) LD50 (skin) >20000 mg/kg (rat) LD50 (inhalation) >20000 mg/kg (rat)
SBR Elastomers as an ingredient (<50%) LD50 (Oral) >5000 mg/kg (rat) LD50 (skin) >20000 mg/kg (rat) LD50 (inhalation) >20000 mg/kg (rat)
Cellulose (9004-34-6) as an ingredient is a natural product (<30%) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit).
Diatomaceous earth, Flux calcined as an ingredient (<15%) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis). Fullers earth (Bentonite) as an ingredient (<10%) Fish Toxicity 96h LC50: 8-19 g/L (Salmo gairdneri).
Magnesium Oxide (1309-48-4) as an ingredient (<2%) TCLo (inhalation) 400 mg/kg (human).
Biodegradation/bioaccumulation: This product is not expected to bioaccumulate.
ATMOSPHERE: Vapour phase glycols are expected to degrade fairly rapidly by reaction with hydroxyl radicals (eg half-life 32 hours for propylene glycol). Removal from air by rainfall is possible. WATER: Should degrade relatively rapidly via biodegradation. SOIL: If released to soil, relatively rapid biodegradation should also occur. Leaching to groundwater may occur.
An inhibitor to prevent shales Ecotoxicity: Low toxicity to aquatic organisms. LC50 (96 h) : 1800 mg/l (SCOPHTHALMUS MAXIMUS) EC50 (48 h) : 310 mg/l (ACARTIA TONSA) EC50 (72 containing medium to high smectite h) : 391 mg/l (SKELETONEMA COSTATUM) GLYCHEM MC Newpark 2.61% Y interlayered clay content dispersing into the mud system Persistence / Degradability: Biodegradation BOD5 : N.D. % ThOD Water : Readily biodegradable in water (Test: 69%, 28d, OECD 301D) Soil : T ½: N.D. days Bioaccumulative potential: log Pow : 0.436 (OECD 107); BCF : N.D. (Slightly or not bioaccumulative)
Mobility: The product is involatile and water soluble and will partition to the aqueous phase. The product will dissolve rapidly in water. If released to soil it will evaporate at a low rate.
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Additional ingredient toxicity value(s): GLYCEROL (GLYCERINE) (56-81-5) High performance lubricant in any type LD50 (intraperitoneal) 4420 mg/kg (rat) New100N Newpark 1.74% Y of water based mud. LD50 (intravenous) 4250 mg/kg (mouse) LD50 (subcutaneous) 91 mg/kg (mouse) TDLo (oral) 1428 mg/kg (human) Ingredient GLYCEROL (GLYCERINE) 4090 mg/kg (mouse) GLYCEROL (GLYCERINE) 4090 mg/kg (mouse)
100% Celllulose. This product is a natural product and is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
Acute Toxicity: LC50 (inhalation) > 5800 mg/m³/4 hours (rat) Bridging agent & loss circulation LD50 (ingestion) > 5000 mg/kg (rat) Sandseal Newpark 0.86% Y material LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit)
Biodegradation/bioaccumulation: Main ingredient is Cellulose, an organic material which is readily biodegradable.
100% Vegetable Material. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small Quickseal / Kwikseal F / M / C Newpark Lost circulation material 1.74% Y quantities. Not expected to bioaccumulate.
40-60% POLYETHYLENE GLYCOL Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h. LD50 Rat oral > 3.2 g/kg
40-55% OCTAN-2-OL Defoam-AP 400 Newpark Defoamer Toxicity: LD50 (ingestion) 33750 mg/kg (rat) 0.01% Y
ATMOSPHERE: Vapour phase glycols are expected to degrade fairly rapidly by reaction with hydroxyl radicals (eg half-life 32 hours for propylene glycol). Removal from air by rainfall is possible. WATER: Should degrade relatively rapidly via biodegradation. SOIL: If released to soil, relatively rapid biodegradation should also occur. Leaching to groundwater may occur.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities Safework Australia Ecotoxicity: LC50: > 1.800 mg/l Exposure time: 96 h Species: Scophthalmus maximus (Flatfish, Flounder) High temperature fluid loss control Driscal D Newpark Toxicity to daphnia and other aquatic invertebrates: > 10000 MG/KG Exposure time: 10 Days Species: Corophium spp (Sediment Reworker) 0.28% Y agent EC50: 2.859 mg/l Exposure time: 72 h Skeletonema costatum (Marine Algae) This material is not expected to be readily biodegradable.
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. High temperature fluid loss control SPA Newpark Toxicity (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis Bahia = 48HR LC50 = 16.2 mg/L. Menidia Beryllina = 48hr LC50 = 34.2 mg/L. 0.56% Y agent Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia Costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia Tonsa = 48hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg] Toxicity: > 5000 mg/kg (rat) This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. The notified polymer is not toxic to fish (rainbow trout), aquatic invertebrates (daphnia magna) and marine invertebrates (acartia tonsa) under test conditions. Geovis Newpark High temperature viscosifier 0.25% Y Biodegradation/Bioaccumulation: Considered readily biodegradable. No experimental results provided. However, based on the molecular weight, water solubility and Kow value the notified polymer is not expected to bioaccumulate.
NICNAS has accessed this product. More information on http://www.nicnas.gov.au/__data/assets/pdf_file/0015/10509/STD1193FR.pdf
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.
Acute Toxicity : Carboxymethyl Starch 100% Oral, mouse: LD50 = >27 gm/kg; Oral, rabbit: LD50 = >27 gm/kg; Oral, rat: LD50 = 27000 mg/kg; Skin, rabbit: LD50 = >2 gm/kg;
Biodegradation/bioaccumulation: No information provided. Not expected to bioaccumulate. High temperature fluid loss control This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to Gagetrol Newpark agent, highly crosslinked substituted 1.70% Y bioaccumulate. Low toxicity - low irritant. starch Not classified as an eye irritant. Contact may cause mild irritation and lacrimation. This product is not known to be a skin or respiratory sensitiser.
No evidence of mutagenic effects.
Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects.
STOT – single exposure: No known effects from this product. STOT – repeated: No known effects from this product.
PRODUCT: Toxicity: LC50 (shrimp): > 100 ppm. Biodegradation/Bioaccumulation: The substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method. In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater.
Polymer stabiliser which effectively >60% TRIETHANOLAMINE (102-71-6) reduces the degradation of polymers at Toxicity Data: high temperatures LC50 (shrimp): > 100 ppm. LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer) 10-30% DIETHANOLAMINE (111-42-2) Toxicity: TEA Newpark LD50 (intramuscular) 1500 mg/kg (rat) 0.24% Y LD50 (intraperitoneal) 120 mg/kg (rat) LD50 (intravenous) 778 mg/kg (rat) LD50 (subcutaneous) 2200 mg/kg (rat) LDLo (oral) 3 g/kg (rat) Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Brachydario rerio 96hr LC50 3.6mg/L, Daphnia pulex 48hr EC50 2.39mg/L Scenedesmus subspicatus 72hr EC50 2.2mg/L. Biodegradability: (OECD 301D) 46%.
<10% ETHANOLAMINE Toxicity: LD50/LC50: Draize test, rabbit, eye: 250 ug Severe; Oral, mouse: LD50 = 700 mg/kg; Oral, rabbit: LD50 = 1 gm/kg; Oral, rat: LD50 = 1720 mg/kg; Skin, rabbit: LD50 = 1 mL/kg;
Harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity: DIETHANOLAMINE (111-42-2) LD50 (intramuscular) 1500 mg/kg (rat) LD50 (intraperitoneal) 120 mg/kg (rat) Dirt Magnet Newpark Well displacement fluid / Surfactant LD50 (intravenous) 778 mg/kg (rat) 1.74% Y LD50 (subcutaneous) 2200 mg/kg (rat) LDLo (oral) 3 g/kg (rat) Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Brachydario rerio 96hr LC50 3.6mg/L, Daphnia pulex 48hr EC50 2.39mg/L, Scenedesmus subspicatus 72hr EC50 2.2mg/L. Biodegradability: (OECD 301D) 46%.
TOTAL (with contingency 150.11% products) C. CHEMICAL LIST:
Ingredients (ie: Chemicals within Drilling Fluids) CAS Number Mass Mix Water N/A 75.29% Bentonite 1302-78-9 6.09% Potassium Chloride 7447-40-7 4.35% Calcium Carbonate 471-34-1 2.26% Sodium Chloride 7647-14-5 5.22% Barium Sulphate 7727-43-7 1.39% Hexanedinitrile 111-69-3 0.67% Hydrocloric acid 7647-01-0 0.27% SODIUM CARBOXYMETHYL CELLULOSE 9004-32-4 0.88% SODIUM GLYCOLATE 2836-32-0 0.07% Xanthan Gum 11138-66-2 0.47% DAZOMET (ISO)[TETRAHYDRO-3,5-DIMETHYL-1,3,5-THIA 533-74-4 208-576-7 <1% 533-74-4 0.01% STARCH 9005-25-8 1.46% Acrylamide, Sodium Acrylate Copolymer 25987-30-8 0.25% Quartz (Silica Crystalline) 14808-60-7 0.19% Sodium Hydroxide 1310-73-2 0.06% Sodium Carbonate 497-19-8 0.06%
Sodium Sulphite 7757-83-7 0.05% Sodium Bicarbonate 144-55-8 0.04% Citric Acid, Anhydrous 77-92-9 0.01% Sodium Glycolate 2836-32-0 0.005% Tetrakis (Hydroxymethyl) Phosphonium Sulphate 55566-30-8 0.003% Octan-2-Ol 123-96-6 0.005% Calcium Oxide 1305-78-8 0.017% Magnesium Oxide 1309-48-4 0.467% Silica, Amorphous 7631-86-9 0.012% DISODIUM PYROPHOSPHATE 7758-16-9 0.235% TRIETHANOLAMINE 102-71-6 0.168% TOTAL 100.00% Cellulose 9004-34-6 10.4% Ethylene Glycol 107-21-1 8.70% 2-Propenenitrile, polymer with 1,3-butadiene Rubber 9003-18-3 3.35% Natural Rubber 9006-04-6 2.98% Rubber - SBR elastomers (derived from recycled automotive tyres) 9003-55-8 2.79% Polyisoprene 9003-31-0 0.56% Diatomaceous Earth 68855-54-9 2.79% Calcium Hrdroxide 1305-62-0 0.10% Fuller's earth 8031-18-3 1.49% Cristobalite 14464-46-1 0.47% DIATOMACEOUS EARTH, FLUX CALCINED 68855-54-9 1.30% Polyethylene 9002-88-4 0.47% Poly(oxy-1,2-ethanediyl), alpha-butyl-omega-hydroxy 9004-77-7 2.61% GLYCEROL (GLYCERINE) 56-81-5 0.52% POLYGLYCEROL 25618-55-7 1.04% Vegetable Materials NC 0.01% Organic Fibre NC 0.01% Polyethylene Glycol 25322-68-3 0.01%
Driscal® D Polymer 1112534, 1016818 14808-60-7 / 5165-97-9 0.28%
Acrylate - Acrylamide Copolymer 9003-04-7 0.56% D-glucurono-6-deoxy-l-manno-d-glucan, Acetate, calcium magnesium potassium sodium Salt 595585-15-2 0.17% CARBOXYMETHYL STARCH 9057-06-1 1.70%
Triethanolamine 102-71-6 0.19% Diethanolamine 111-42-2 0.02% Ethanolamine 141-43-5 0.02% COCONUT DIETHANOLAMIDE 68603-42-9 1.04% DIETHANOLAMINE 111-42-2 0.10%
TOTAL Contingency Chemicals 43.69% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - HTB Slurry
TOTAL VOLUME OF SYSTEM (L): 127,176*
*Includes 30% Contingency.
B. PRODUCT LIST:
% Product in Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached system Fluid Fresh water Local Bore Water Mix water Water sourced from local aquifer - No hazard. 9.755% N/A
CONSTITUENT 1 (≤65%): After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Cement- Class G + 35% SSA-1 Halliburton Cement 61.355% Yes Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics CONSTITUENT 2 (≤35%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1) CONSTITUENT 1 (≤1%): Effect concentrations in the aquatic environment are attributable to a change in pH value Freshwater Acute Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. Cement Additive CONSTITUENT 2 (≤60%): Gascon 469 Halliburton 6.2137% Yes Stabiliser Freshwater Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; LOLI]; Freshwater Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI]; Freshwater Acute Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 3 (≤100%): Water Only - No Hazard
CFR-3L is CFR-3 in solution Log Pow: <0 (OECD 117) CFR-3L Halliburton Friction Reducer Biodegradation(28 Days): 5% (Marine BODIS) 0.7081% Yes Acute Algae Toxicity 72h EC50: >3300 mg/L (Skeletonema costatum) Acute Crustacean Toxicity 48h LC50: 1687 mg/L (Acartia tonsa)
HALAD 413 (HALAD 413L is HALAD 413 in solution): Log Pow: <0 – 3.5 (OECD 117) Biodegradation(28 Days): 6.1% (OECD 306) Halad-413L Halliburton Fluid Loss Additive Acute Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) 5.32610% Yes Acute Crustacean Toxicity 48h LC50: >2000 mg/L (Acartia tonsa) HALAD 413L: Acute Fish Toxicity 96h LC50: >1000 mg/L (Scophthalmus maximus)
FULL PRODUCT Biodegradation(28 Days): 39% (OECD306) SCR-100L Halliburton Cement Retarder Acute Algae Toxicity 72h EC50: >3300 mg/L (Skeletonema costatum) 1.1701% Yes Acute Crustacean Toxicity 48h LC50: >2000 mg/L (Acartia tonsa) Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air entrainment Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton 0.1121% Yes into cement slurry Funded Study]; Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; CONSTITUENT 1 (≤60%):
""SiO2" is a stable substance. In the environment it occurs in different modifications and it is one of the most abundant materials on the Earth's surface."" Biodegrability is "not applicable" for silica since it is inorganic. Additionally, "bioaccumulation is not expected." Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum); Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia); Acute Fish Toxicity 96h LC50 5000 mg/L (Brachydanio rerio); Light weight cement Source: IUCLID 2000 SILICALITE LIQUID Halliburton 13.9204% Yes additive CONSTITUENT 2 (≤60%): Water only - No hazard. CONSTITUENT 3 (≤1%):
LC50(96h): > 1000 mg/L (Brachydanio rerio) LC50(24h): >1000 mg/L (Daphnia magna) LC50(10d): 50566 mg/kg (Corophium volutator)
TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Product is an inert, man-made glass-fibre material and not intrinsically hazardous, with WellLife 734 Halliburton Cement Enhancer 0.9090% bioaccumultion/biogredataion levels analogous to silica. After hardening withing cement mixture, it should present no ecotoxicity risks.
CONSTITUENT 1 (≤60%): Water Only - No Hazard. CONSTITUENT 2 (≤60%): Freshwater Acute Algae Toxicity 72h EC50: 51.4 mg/L (Pseudokirchneriella subcapitata) [ECHA]; HR-25L Halliburton Cement Retarder 0.5309% Yes Freshwater Acute Crustacean Toxicity 48h EC50: 93.3 mg/L (Daphnia magna) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: > 100 mg/L (Danio rerio) [ECHA]; Bioaccumulation Log Pow: 0.24 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 85 % [ECHA];
TOTAL (system products) 100.00% C. CHEMICAL LIST:
Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%) Mix Water NA 9.75507% Portland cement 65997-15-1 36.12404% Water in Product 7732-18-5 19.95400% Crystalline silica, quartz 14808-60-7 19.45140% Silica, amorphous 7631-86-9 7.56552% Silica, amorphous - fumed 7631-86-9 3.37705% Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated1344-09-8 1.44733% Glass, oxide 473268-27-8 0.82334% Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.63593% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 8061-51-6 0.38484% Tartaric acid 40104-76-5 0.28852% Rape Oil 87-69-4 0.10154% Sodium hydroxide 8002-13-9 0.05628% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 1310-73-2 0.01261% Monopropylene glycol monooleate 1330-80-9 0.01015% Sorbitan, monopalmitate 26266-57-9 0.00508% Aluminium stearate 637-12-7 0.00508% FD&C Blue 1 3844-45-9 0.00106% 2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.00106% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Class G Slurry
TOTAL VOLUME OF SYSTEM 127,176* (L):
*Includes 30% Contingency.
B. PRODUCT LIST: % Product in system Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached Fluid Local Bore Fresh water Mix water Water sourced from local aquifer - No hazard. 10.274% N/A Water CONSTITUENT 1 (≤100%):
After hardening with water or moisture, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Cement- Class G Halliburton Cement Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L 61.228% Yes Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics
CONSTITUENT 2 (≤10%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1) CONSTITUENT 1 (≤60%): Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Cement Additive Econolite Liquid Halliburton Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus); 9.132% Yes Stabiliser Source: IUCLID 2000 Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable CONSTITUENT 2 (≤100%): Water only - No hazard.
CONSTITUENT 1 (≤1%): Effect concentrations in the aquatic environment are attributable to a change in pH value Freshwater Acute Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2 (≤60%): Cement Additive Freshwater Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; Gascon 469 Halliburton 8.371% Yes Stabiliser LOLI]; Freshwater Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI]; Freshwater Acute Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 3 (≤100%): Water Only - No Hazard
CONSTITUENT 1 (≤100%): Water Only - No Hazard CONSTITUENT 2 (≤60%): Marine Water Acute Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton HR-6L Halliburton Cement Retarder 1.3150% Yes Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Acute Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1687 mg/L (Acartia tonsa) [Halliburton Funded Study]; CFR-3L Halliburton Friction Reducer 0.9540% Yes Freshwater Acute Fish Toxicity 48h LC50: 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];
Marine Water Acute Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Acute Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Halad-413L Halliburton Fluid Loss Additive Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [OSPAR]; 7.1750% Yes Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study];
FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton entrainment into 0.1510% Yes Funded Study]; cement slurry Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; CONSTITUENT 1 (≤100%): Acute Algae Toxicity 96h EC50 : 22 mg/L (Pseudokirchneriella subcapitata) Acute Fish Toxicity Data 96h LC50 : >1000 mg/L (Salmo gairdneri) Acute Crustacean Toxicity 48h EC50: 480 mg/L (Daphnia magna) CONSTITUENT 2 (≤60%): D-AIR 3000L Halliburton Defoamer Acute Fish Toxicity 96h LC50: 1700 mg/L (Lepomis macrochirus); 0.1752% Yes CONSTITUENT 3 (≤30%):
Component is a synthetic surface modified Amorphous Silica (CAS #: 7631-86-9); Fish and Invertebrate toxicity testing with Amorphous Silica have shown low hazard for this component. Source: OECD SIDS TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Product is an inert, man-made glass-fibre material and not intrinsically hazardous, with WellLife 734 Halliburton Cement Enhancer 1.2250% bioaccumultion/biogredataion levels analogous to silica. After hardening withing cement mixture, it should present no ecotoxicity risks.
TOTAL (system products) 100.00%
C. CHEMICAL LIST:
Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%)
Mix Water NA 9.755069% Portland Cement 65997-15-1 51.483861% Water in Product 7732-18-5 22.350300% Sodium silicate 1344-09-8 4.607210% Silica, amorphous - fumed 7631-86-9 4.223276% Crystalline silica, quartz 14808-60-7 2.574193% Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, 473268-27-8 1.809939% sodium bisulfite-terminated Glass, oxide 65997-17-3 1.030047% Sodium lignosulphate 8061-51-6 0.663434% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.481305% Alkenes, C15-C18 93762-80-2 0.147281% Rape Oil 8002-13-9 0.126969% Polypropylene glycol 25322-69-4 0.088368% Sodium hydroxide 1310-73-2 0.070388% Silica, amorphous precipitated 67762-90-7 0.044184% Monopropylene glycol monooleate 1330-80-9 0.012697% Sorbitan, monopalmitate 26266-57-9 0.006348% Aluminium stearate 637-12-7 0.006348% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Microbond HT Slurry
TOTAL VOLUME OF SYSTEM 79,494 * (L):
*Includes 30% Contingency.
B. PRODUCT LIST:
% Product in Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached system Fluid
Fresh water Local Bore Water Mix water Water sourced from local aquifer - No hazard. 26.14% N/A CONSTITUENT 1 (≤100%):
After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 Cement- Class G + 35% SSA- mg/L Halliburton Cement 64.40% Yes 1 Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics
CONSTITUENT 2 (≤100%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1) CONSTITUENT 1 (≤1%): Effect concentrations in the aquatic environment are attributable to a change in pH value Freshwater Acute Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2 (≤60%): Cement Additive Freshwater Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; Gascon 469 Halliburton 1.16% Yes Stabiliser LOLI]; Freshwater Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI]; Freshwater Acute Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 3 (≤100%): Water Only - No Hazard
Marine Water Acute Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1687 mg/L (Acartia tonsa) [Halliburton Funded Study]; CFR-3L Halliburton Friction Reducer 0.74% Yes Freshwater Acute Fish Toxicity 48h LC50: 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];
Marine Water Acute Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Acute Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Halad-413L Halliburton Fluid Loss Additive Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [OSPAR]; 1.40% Yes Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study]; Marine Water Acute Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [Halliburton SCR-100L Halliburton Cement Retarder Funded Study]; 0.79% Yes Marine Water Acute Fishn Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 14% [Halliburton Funded Study];
Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) Fluid Loss Additive for [Halliburton Funded Study]; Halad-344 Halliburton 0.24% Yes high temperature Bioaccumulation Log Pow: <0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];
FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton entrainment into 0.1177% Yes Funded Study]; cement slurry Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study];
TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Product is an inert, man-made glass-fibre material and not intrinsically hazardous, with WellLife 734 Halliburton Cement Enhancer 0.24% Yes bioaccumultion/biogredataion levels analogous to silica. After hardening withing cement mixture, it should present no ecotoxicity risks.
No data was available in the IUCLID for this component, as "magnesium ions are a major MICROBOND HT Halliburton Cement Additive component of all natural waters". 4.77% Yes Component Source: IUCLID 2000
TOTAL (system products) 100.00% C. CHEMICAL LIST:
Maximum Ingredients (ie: Chemicals within cement system) CAS number Mass fraction in System (%)
Mix Water N/A 26.1419% Portland cement 65997-15-1 40.8526% Crystalline silica, quartz 14808-60-7 21.9975% Magnesium Oxide 1309-48-4 4.6556% Water in Product 7732-18-5 3.7145% Silica, amorphous - fumed 7631-86-9 0.6820% Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.4603% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.4352% Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, 473268-27-8 0.4092% N,N-dimethylacrylamide copolymer calcium salt 103115-52-2 0.2328% Glass, oxide 65997-17-3 0.2328% Rape Oil 8002-13-9 0.1149% Sodium sulfate 7757-82-6 0.0116% Lecithins 8002-43-5 0.0116% Calcium hydroxide 1305-62-0 0.0116% Monopropylene glycol monooleate 1330-80-9 0.0115% Sodium hydroxide 1310-73-2 0.0114% Sorbitan, monopalmitate 26266-57-9 0.0057% Aluminium stearate 637-12-7 0.0057% FD&C Blue 1 3844-45-9 0.0008% 2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.0008% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Microbond Slurry
TOTAL VOLUME OF 127,190 * SYSTEM (L): *Includes 30% Contingency.
B. PRODUCT LIST:
% Product in Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached system Fluid
Fresh water Local Bore Water Mix water Water sourced from local aquifer - No hazard. 25.46% N/A
CONSTITUENT 1 (≤100%):
After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Cement- Class G Halliburton Cement Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics 62.17% Yes Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics
CONSTITUENT 2 (≤10%):
Carcinogenicity: Classified as a human carcinogen (IARC Group 1) CONSTITUENT 1 (≤1%):
Effect concentrations in the aquatic environment are attributable to a change in pH value Freshwater Acute Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
Gascon 469 Halliburton Cement Additive Stabiliser CONSTITUENT 2 (≤30%): 1.52% Yes
Freshwater Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; LOLI]; Freshwater Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI]; Freshwater Acute Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 3 (≤100%): Water only - No hazard
CONSTITUENT 1 (≤100%): Water Only - No Hazard CONSTITUENT 2 (≤60%): Marine Water Acute Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton HR-6L Halliburton Cement Retarder 1.07% Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study];
Marine Water Acute Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1687 mg/L (Acartia tonsa) [Halliburton Funded CFR-3L Halliburton Friction Reducer Study]; 0.97% Yes Freshwater Acute Fish Toxicity 48h LC50: 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study]; Marine Water Acute Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Acute Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Halad-413L Halliburton Fluid Loss Additive Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [OSPAR]; 1.82% Yes Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study];
Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Fluid Loss Additive for Funded Study]; Halad-344 Halliburton 0.31% Yes high temperature Bioaccumulation Log Pow: <0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];
FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air entrainment Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton 0.1534% Yes into cement slurry Funded Study]; Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; CONSTITUENT 1 (≤100%):
Freshwater Acute Algae Toxicity 72h EC50: > 61.1 mg/L (Pseudokirchneriella subcapitata) [ECHA]; Freshwater Acute Crustacean Toxicity 48h LC50: 14.5 mg/L (Daphnia magna) [ECHA] (similar substance); Freshwater Acute Fish Toxicity 96h LC50: > 3.5 mg/L (Danio rerio) [ECHA]; Bioaccumulation Fish BCF: 1.2-74.4 (Lepomis macrochirus) [ECHA]; Barite Halliburton Weighting Agent Biodegradation: Substance is inorganic - biodegradation is not applicable. 0.00% Yes CONSTITUENT 2 (≤10%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Product is an inert, man-made glass-fibre material and not intrinsically hazardous, with WellLife 734 Halliburton Cement Enhancer 0.31% bioaccumultion/biogredataion levels analogous to silica. After hardening withing cement mixture, it should present no ecotoxicity risks. Yes
CONSTITUENT 1 (≤ 100%): Freshwater Acute Algae Toxicity 72h EC50: > 100 mg/L (Selenastrum capricornutum) [OECD SIDS]; Freshwater Acute Crustacean Toxicity 48h EC50: > 100 mg/L (Daphnia magna) [OECD SIDS]; Freshwater Acute Fish Toxicity 96h EC50: > 100 mg/L (Oryzias latipes) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2 (≤ 30%): Freshwater Acute Algae Toxicity 72h EC50: 3.6 mg/L (Desmodesmus subspicatus) [ECHA]; Freshwater Acute Crustacean Toxicity 48h EC50: 5.4 mg/L (Daphnia magna) [ECHA]; Freshwater Acute Fish Toxicity 96h EC50: > 100 mg/L (Danio rerio) [ECHA]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 3 (≤ 10%): Effect concentrations in the aquatic environment are attributable to a change in pH value. Microbond Halliburton Expander Freshwater Acute Crustacean Toxicity 48h EC50: 49.1 mg/L (Daphnia magna) [ECHA]; 6.22% Yes Marine Water Acute Crustacean Toxicity 96h LC50: 158 mg/L (Crangon septemspinosa) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 50.6 mg/L (Oncorhynchus mykiss) [ECHA]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 4 (≤ 5%): Freshwater Acute Algae Toxicity 96h EC50: 650 mg/L (Navicula seminulum) [US EPA ECOTOX]; Freshwater Acute Crustacean Toxicity 48h EC50: 1020 mg/L (Ceriodaphnia dubia) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 7100 mg/L (Lepomis macrochirus) [ECHA]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
TOTAL (system products) 100.00%
C. CHEMICAL LIST:
Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%)
Mix Water N/A 25.4561% Portland cement 65997-15-1 55.9407% Calcium sulfate dihydrate 10101-41-4 5.5940% Water in Product 7732-18-5 4.5031% Crystalline silica, quartz 14808-60-7 2.7970% Calcium aluminate 12042-68-1 1.6782% Silica, amorphous - fumed 7631-86-9 0.8195% Sodium Lignosulfonate 8061-51-6 0.5769% Calcium hydroxide 1305-62-0 0.5734% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.5229% Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2- 473268-27-8 0.4917% propenenitrile, sodium bisulfite-terminated N,N-dimethylacrylamide copolymer calcium salt 103115-52-2 0.2797% Glass, oxide 65997-17-3 0.2797% Sodium bicarbonate 144-55-8 0.2797% Rape Oil 8002-13-9 0.1380% Sodium sulfate 7757-82-6 0.0140% Lecithins 8002-43-5 0.0140% Monopropylene glycol monooleate 1330-80-9 0.0138% Sodium hydroxide 1310-73-2 0.0137% Sorbitan, monopalmitate 26266-57-9 0.0069% Aluminium stearate 637-12-7 0.0069% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Tuned Spacer E+
TOTAL VOLUME OF 15,897 * SYSTEM (L): *Includes 30% Contingency.
B. PRODUCT LIST:
% Product in Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached system Fluid Water supplied by Fresh water Mix water Water sourced from local aquifer - No hazard. 99.22% N/A APA CONSTITUENT 1 (≤60%): Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Cement Additive Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus); Econolite Liquid Halliburton 0.4426% Yes Stabiliser Source: IUCLID 2000 PLONOR Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable CONSTITUENT 2 (≤100%): Water Only - No Hazard
FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton entrainment into 0.0007% Yes Funded Study]; cement slurry Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; Acute Fish Toxicity 96hr LC50 76000mg/L @ 96 hr Species Oncorhynchus mykiss EPA Ref# 869 Barite Halliburton Weighting Agent 48hr LC50 >30lb/gal (>3594790mg/L) Report no BL8279 Species Pimephales promelas (fish) 0.2466% Yes 48hr LC50 >30lb/bbl (>85556mg/L) Report BL8377 Species Daphnia pulex (Water Flea – crustacean) Bioassay testing where LC50/EC50: >100 mg/L
CONSTITUENT 1 (≤100%): Component is naturally occuring and not intrinsically hazardous.
CONSTITUENT 2 (≤10%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 3 (≤1%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. TUNED SPACER E+ Halliburton Mud/Cement Spacer 0.09020% Yes CONSTITUENT 4 (≤1%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Environment Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Environment Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 5 (≤30%): Freshwater Acute Crustacean Toxicity 48h NOELr: 1000 mg/L (Daphnia magna) [US EPA HPVIS] (similar substance); (similar substance); Freshwater Acute Fish Toxicity 48h LC50: 7300 mg/L (Oncorhynchus mykiss) [US EPA ECOTOX]; Bioaccumulation Log Kow: -3.45 [EPISUITE] (similar substance); Freshwater Biodegradation 10d: 29 % [US EPA HPV Haz. Char. Doc.] (similar substance);
CONSTITUENT 6 (≤10%): Component is naturally occuring and not intrinsically hazardous. Natural form of Amorphous Silica (CAS #: 7631-86-9). Fish and Invertebrate toxicity testing with Amorphous Silica have shown low hazard for this component.
TOTAL (system 100.00% products)
C. CHEMICAL LIST: Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%) Mix Water NA 99.23044172% Water in Product 7732-18-5 0.32398322% Barite 13462-86-7 0.21231847% Sodium silicate 1344-09-8 0.19435931% Bentonite 1302-78-9 0.02640342% Sodium Lignosulfonate 8061-51-6 0.00792103% Welan gum 72121-88-1 0.00264034% Crystalline silica, quartz 14808-60-7 0.00079210% Rape Oil 8002-13-9 0.00051027% Crystalline silica, tridymite 15468-32-3 0.00026403% Crystalline silica, cristobalite 14464-46-1 0.00026403% Monopropylene glycol monooleate 1330-80-9 0.00005103% Sorbitan, monopalmitate 26266-57-9 0.00002551% Aluminium stearate 637-12-7 0.00002551% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Tuned Spacer III
TOTAL VOLUME OF SYSTEM (L): 15,897 *
*Includes 30% Contingency.
B. PRODUCT LIST:
% Product in system Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached Fluid Fresh water Water supplied by APA Mix water Water sourced from local aquifer - No hazard. 99.23% N/A CONSTITUENT 1 (≤60%): Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus); Econolite Liquid Halliburton Cement Additive Stabiliser 0.4427% Yes Source: IUCLID 2000 PLONOR Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable CONSTITUENT 2 (≤100%): No Hazard FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air entrainment into Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton 0.0007% Yes cement slurry Funded Study]; Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study];
Acute Fish Toxicity 96hr LC50 76000mg/L @ 96 hr Species Oncorhynchus mykiss EPA Ref# 869 Barite Halliburton Weighting Agent 48hr LC50 >30lb/gal (>3594790mg/L) Report no BL8279 Species Pimephales promelas (fish) 0.2456% Yes 48hr LC50 >30lb/bbl (>85556mg/L) Report BL8377 Species Daphnia pulex (Water Flea – crustacean) Bioassay testing where LC50/EC50: >100 mg/L CONSTITUENT 1 (≤30%): Marine Water Acute Algae Toxicity 72h EC50: > 10000 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: > 10000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Acute Fish Toxicity 96h LC50: > 5600 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Constituent is a clay mineral of soil and therefore biodegradability is not applicable. Constituent is a clay mineral of soil and therefore bioaccumulation is not applicable.
CONSTITUENT 2 (≤10%): Freshwater Acute Algae Toxicity 72h EC50: > 10000 mg/L (Scenedesmus subspicatus) [OECD SIDS] (similar substance); Freshwater Acute Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [OECD SIDS] (similar substance); Freshwater Acute Fish Toxicity 72h LC50: > 10000 mg/L (Cyprinus carpio) [LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 3 (≤5%): Component is naturally occuring and not intrinsically hazardous. Natural form of Amorphous Silica (CAS #: 7631-86-9). Fish and Invertebrate toxicity testing with Amorphous Silica have shown low hazard for this component. TUNED SPACER III Halliburton Mud/Cement Spacer 0.09020% Yes CONSTITUENT 4 (≤1%): Freshwater Acute Crustacean Toxicity 48h EC50: > 50 mg/L (Daphnia magna) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: > 100 mg/L (Pimephales promelas) [ECHA]; Freshwater Acute Plant Toxicity 72h EC50: 990 mg/L (Lactuca sativa) [ECHA]; Bioaccumulation BCF: 3.2 [ECHA]; Freshwater Biodegradation 28d: 97 % [ECHA];
CONSTITUENT 5 (≤100%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 6 (≤1%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
TOTAL (system products) 100.01% C. CHEMICAL LIST: Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%) Mix Water NA 99.22089370% Water in Product 7732-18-5 0.31616632% Sodium silicate 1344-09-8 0.18966991% Barite 13462-86-7 0.17539889% Crystalline silica, quartz 14808-60-7 0.06441958% Sepiolite 63800-37-3 0.01932587% Diatomaceous earth 61790-53-2 0.00644196% Welan gum 72121-88-1 0.00322098% Crystalline silica, cristobalite 14464-46-1 0.00322098% Citric acid 77-92-9 0.00064420% Rape Oil 8002-13-9 0.00049801% Monopropylene glycol monooleate 1330-80-9 0.00004980% Sorbitan, monopalmitate 26266-57-9 0.00002490% Aluminium stearate 637-12-7 0.00002490% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-9
SYSTEM: Cementing - Tuned Spacer III
TOTAL VOLUME OF SYSTEM (L): 15,897 *
*Includes 30% Contingency.
B. PRODUCT LIST:
% Product in Product Name Supplier Purpose Ecotoxicity Information (summary) SDS Attached system Fluid Fresh water Water supplied by APA Mix water Water sourced from local aquifer - No hazard. 99.23% N/A CONSTITUENT 1 (≤60%): Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Cement Additive Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus); Econolite Liquid Halliburton 0.4427% Yes Stabiliser Source: IUCLID 2000 PLONOR Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable CONSTITUENT 2 (≤100%): No Hazard FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton NF-6 Halliburton entrainment into 0.0007% Yes Funded Study]; cement slurry Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study]; Acute Fish Toxicity 96hr LC50 76000mg/L @ 96 hr Species Oncorhynchus mykiss EPA Ref# 869 Barite Halliburton Weighting Agent 48hr LC50 >30lb/gal (>3594790mg/L) Report no BL8279 Species Pimephales promelas (fish) 0.2456% Yes 48hr LC50 >30lb/bbl (>85556mg/L) Report BL8377 Species Daphnia pulex (Water Flea – crustacean) Bioassay testing where LC50/EC50: >100 mg/L
CONSTITUENT 1 (≤30%): Marine Water Acute Algae Toxicity 72h EC50: > 10000 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: > 10000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Acute Fish Toxicity 96h LC50: > 5600 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Constituent is a clay mineral of soil and therefore biodegradability is not applicable. Constituent is a clay mineral of soil and therefore bioaccumulation is not applicable.
CONSTITUENT 2 (≤10%): Freshwater Acute Algae Toxicity 72h EC50: > 10000 mg/L (Scenedesmus subspicatus) [OECD SIDS] (similar substance); Freshwater Acute Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [OECD SIDS] (similar substance); Freshwater Acute Fish Toxicity 72h LC50: > 10000 mg/L (Cyprinus carpio) [LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 3 (≤5%): Component is naturally occuring and not intrinsically hazardous. Natural form of Amorphous Silica (CAS #: 7631-86-9). Fish and Invertebrate toxicity testing with Amorphous Silica have shown low hazard for this component. TUNED SPACER III Halliburton Mud/Cement Spacer 0.09020% Yes CONSTITUENT 4 (≤1%): Freshwater Acute Crustacean Toxicity 48h EC50: > 50 mg/L (Daphnia magna) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: > 100 mg/L (Pimephales promelas) [ECHA]; Freshwater Acute Plant Toxicity 72h EC50: 990 mg/L (Lactuca sativa) [ECHA]; Bioaccumulation BCF: 3.2 [ECHA]; Freshwater Biodegradation 28d: 97 % [ECHA];
CONSTITUENT 5 (≤100%): CONSTITUENT 5 (≤100%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
CONSTITUENT 6 (≤1%): Freshwater Acute Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Acute Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.
TOTAL (system products) 100.01%
C. CHEMICAL LIST: Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%) Mix Water NA 99.22089370% Water in Product 7732-18-5 0.31616632% Sodium silicate 1344-09-8 0.18966991% Barite 13462-86-7 0.17539889% Crystalline silica, quartz 14808-60-7 0.06441958% Sepiolite 63800-37-3 0.01932587% Diatomaceous earth 61790-53-2 0.00644196% Welan gum 72121-88-1 0.00322098% Crystalline silica, cristobalite 14464-46-1 0.00322098% Citric acid 77-92-9 0.00064420% Rape Oil 8002-13-9 0.00049801% Monopropylene glycol monooleate 1330-80-9 0.00004980% Sorbitan, monopalmitate 26266-57-9 0.00002490% Aluminium stearate 637-12-7 0.00002490% A. SYSTEM DETAILS:
OPERATOR: APA
PROJECT/WELL: Mondarra-1 Plug and Abandonment
SYSTEM: Cementing - Class G Slurry
TOTAL VOLUME OF SYSTEM (L): 6,360*
*Includes 30% Contingency.
B. PRODUCT LIST:
Product Name Supplier Purpose Ecotoxicity Information (summary) % Product in system Fluid SDS Attached Fresh water Local Bore Water Mix water Water sourced from local aquifer - No hazard. 10.274% N/A CONSTITUENT 1 (≤100%):
After hardening with water or moisture, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Cement- Class G Halliburton Cement Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics 61.228% Yes Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics
CONSTITUENT 2 (≤10%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1) CONSTITUENT 1 (≤60%):
Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Econolite Liquid Halliburton Cement Additive Stabiliser Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus); 9.132% Yes Source: IUCLID 2000 Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable
CONSTITUENT 2 (≤100%): Water only - No hazard.
CONSTITUENT 1 (≤1%): Effect concentrations in the aquatic environment are attributable to a change in pH value Freshwater Acute Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Acute Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2 (≤60%): Gascon 469 Halliburton Cement Additive Stabiliser 8.371% Yes Freshwater Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; LOLI]; Freshwater Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI]; Freshwater Acute Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 3 (≤100%): Water Only - No Hazard
CONSTITUENT 1 (≤100%): Water Only - No Hazard CONSTITUENT 2 (≤60%): HR-6L Halliburton Cement Retarder 1.3150% Yes Marine Water Acute Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Pow: < 0 [Halliburton Funded Study];
Marine Water Acute Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Acute Crustacean Toxicity 48h LC50: 1687 mg/L (Acartia tonsa) [Halliburton Funded Study]; CFR-3L Halliburton Friction Reducer Freshwater Acute Fish Toxicity 48h LC50: 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg]; 0.9540% Yes Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];
Marine Water Acute Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Acute Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Halad-413L Halliburton Fluid Loss Additive Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [OSPAR]; 7.1750% Yes Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study];
FULL PRODUCT Marine Water Acute Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Reduces air entrainment into NF-6 Halliburton Marine Water Acute Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton Funded Study]; 0.1510% Yes cement slurry Marine Water Acute Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study];
CONSTITUENT 1 (≤100%): Acute Algae Toxicity 96h EC50 : 22 mg/L (Pseudokirchneriella subcapitata) Acute Fish Toxicity Data 96h LC50 : >1000 mg/L (Salmo gairdneri) Acute Crustacean Toxicity 48h EC50: 480 mg/L (Daphnia magna) CONSTITUENT 2 (≤60%): D-AIR 3000L Halliburton Defoamer Acute Fish Toxicity 96h LC50: 1700 mg/L (Lepomis macrochirus); 0.1752% Yes CONSTITUENT 3 (≤30%):
Component is a synthetic surface modified Amorphous Silica (CAS #: 7631-86-9); Fish and Invertebrate toxicity testing with Amorphous Silica have shown low hazard for this component. Source: OECD SIDS
TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Product is an inert, man-made glass-fibre material and not intrinsically hazardous, with bioaccumultion/biogredataion WellLife 734 Halliburton Cement Enhancer 1.2250% levels analogous to silica. After hardening withing cement mixture, it should present no ecotoxicity risks. TOTAL (system products) 100.00% C. CHEMICAL LIST:
Maximum Mass Ingredients (ie: Chemicals within cement system) CAS number fraction in System (%) Mix Water NA 9.755069% Portland Cement 65997-15-1 51.483861% Water in Product 7732-18-5 22.350300% Sodium silicate 1344-09-8 4.607210% Silica, amorphous - fumed 7631-86-9 4.223276% Crystalline silica, quartz 14808-60-7 2.574193%
Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated 473268-27-8 1.809939%
Glass, oxide 65997-17-3 1.030047% Sodium lignosulphate 8061-51-6 0.663434% Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.481305% Alkenes, C15-C18 93762-80-2 0.147281% Rape Oil 8002-13-9 0.126969% Polypropylene glycol 25322-69-4 0.088368% Sodium hydroxide 1310-73-2 0.070388% Silica, amorphous precipitated 67762-90-7 0.044184% Monopropylene glycol monooleate 1330-80-9 0.012697% Sorbitan, monopalmitate 26266-57-9 0.006348%
Aluminium stearate 637-12-7 0.006348% 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name XANTHAN GUM (P) Synonym(s) NEWZAN D • XANTHAN GUM (BIOPOLYMER)
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • VISCOSITY MODIFIER
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content XANTHAN GUM 11138-66-2 234-394-2 >87% WATER 7732-18-5 231-791-2 <13%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities Eye wash facilities and safety shower should be available.
Page 1 of 6 SDS Date: 10 Feb 2015 PRODUCT NAME XANTHAN GUM (P)
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
Page 2 of 6 SDS Date: 10 Feb 2015 PRODUCT NAME XANTHAN GUM (P)
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance LIGHT BEIGE POWDER Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 1.5 Solubility (water) MISCIBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
Page 3 of 6 SDS Date: 10 Feb 2015 PRODUCT NAME XANTHAN GUM (P)
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
Page 4 of 6 SDS Date: 10 Feb 2015 PRODUCT NAME XANTHAN GUM (P)
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 10 Feb 2015 PRODUCT NAME XANTHAN GUM (P)
Revision history Revision Description 1.3 Added Synonym. 1.2 Standard SDS Review 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1.3 SDS date: 10 February 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 10 Feb 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name TRIETHANOLAMINE Synonym(s) RHEOCHEM TRIETHANOLAMINE
1.2 Uses and uses advised against Use(s) CHEMICAL INTERMEDIATE • LABORATORY REAGENT • SOLVENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Serious Eye Damage / Eye Irritation: Category 1 Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
2.2 Label elements Signal word DANGER
Pictograms
Hazard statement(s) H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. Prevention statement(s) P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P314 Get medical advice/attention if you feel unwell. Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
Page 1 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk TRIETHANOLAMINE CAS: 102-71-6 Not Available Not Available >60% EC: 203-049-8 DIETHANOLAMINE CAS: 111-42-2 Acute Tox. 4, H302 Xn;R22, Xi;R38, 10 to <30% EC: 203-868-0 Skin Irrit. 2, H315 Xi;R41, Xn;R48/22 Eye Dam. 1, H318 STOT RE 2, H373 ETHANOLAMINE CAS: 141-43-5 Acute Tox. 4, H302 Xn;R20/21/22, <10% EC: 205-483-3 Acute Tox. 4, H312 C;R34 Skin Corr. 1B, H314 Acute Tox. 4, H332
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
Page 2 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C2 Combustible Liquid (AS1940).
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Diethanolamine (h) SWA (AUS) 3 13 -- -- Ethanolamine SWA (AUS) 3 7.5 6 15 Triethanolamine SWA (AUS) -- 5 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CLEAR LIQUID Odour MILD AMMONIACAL ODOUR Flammability CLASS C2 COMBUSTIBLE Flash point 190°C
Page 3 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
9.1 Information on basic physical and chemical properties Boiling point 335°C Melting point 12°C Evaporation rate < 0.01 (n-Butyl acetate = 1) pH 10.5 (1 % Solution) Vapour density 4.80 (Air = 1) Specific gravity 1.12 Solubility (water) SOLUBLE Vapour pressure < 1 kPa @ 20°C Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature 375°C Decomposition temperature NOT AVAILABLE Viscosity 450 cP @ 25°C Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Hazardous polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Also incompatible with organic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper, brass and aluminium.
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. LD50 (oral) = 2200 mg/kg (rabbit). Skin Contact may result in mild irritation, redness, pain and rash. Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization Triethanolamine has been reported to cause allergic contact dermatitis in humans. It is not known to cause respiratory sensitisation. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3). Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in exposure breathing difficulties. STOT – repeated Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure. exposure Aspiration This product is not expected to present an aspiration hazard.
Page 4 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability The substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid. Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of to approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Xn Harmful Risk phrases R41 Risk of serious damage to eyes. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Safety phrases S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S39 Wear eye/face protection.
Page 5 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 6 of 7 SDS Date: 25 Jul 2014 PRODUCT NAME TRIETHANOLAMINE
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 25 July 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 25 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name STRATA-VANGUARD Synonym(s) STRATA VANGUARD
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CRISTOBALITE 14464-46-1 238-455-4 <5% QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <2% 2-PROPENENITRILE-1,3-BUTADIENE RUBBER 9003-18-3 618-357-1 <50% NATURAL RUBBER 9006-04-6 232-689-0 <50% POLYISOPRENE 9003-31-0 618-362-9 <50% SBR ELASTOMERS 9003-55-8 618-370-2 <50% CELLULOSE 9004-34-6 232-674-9 <30% DIATOMACEOUS EARTH, FLUX CALCINED 68855-54-9 272-489-0 <15% FULLERS EARTH 8031-18-3 617-052-0 <10% LIMESTONE (CALCIUM CARBONATE) 1317-65-3 215-279-6 <10% POLYETHYLENE 9002-88-4 618-339-3 <3% MAGNESIUM OXIDE 1309-48-4 215-171-9 <1%
Page 1 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME STRATA-VANGUARD
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters No fire or explosion hazard exists.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
Page 2 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME STRATA-VANGUARD
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- -- Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- -- Cristobalite SWA (AUS) -- 0.1 -- -- Magnesium oxide (fume) SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a Powered Air Purifying Respirator (PAPR) with Class P3 (Particulate) filter or a Full-face Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance TAN COLOURED POWDER Odour MILD ODOUR Flammability NON FLAMMABLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.3 (5% Suspension) Vapour density NOT AVAILABLE Specific gravity 2.1 Solubility (water) INSOLUBLE Vapour pressure 1 mm Hg @ 20°C Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
Page 3 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME STRATA-VANGUARD
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid contact with incompatible substances.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid). Also incompatible with oxygen difluoride, chlorine and trifluoride.
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicological effects from this product. Based on available data, the classification criteria are not met. Skin Not classified as a skin irritant. Contact may result in mechanical irritation. Eye Not classified as an eye irritant. Contact may result in mechanical irritation. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficient respirable silica in this product to be classified as a carcinogen. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated Adverse health effects associated with silica, such as the development of silicosis (lung fibrosis), is not exposure anticipated unless chronic (i.e. prolonged and repeated) exposure to silica quartz dust occurs. Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradability Not applicable.
12.3 Bioaccumulative potential This product is not expected to bioaccumulate.
12.4 Mobility in soil This product has low mobility in soil.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required).
Page 4 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME STRATA-VANGUARD
Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME STRATA-VANGUARD
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.3 Standard SDS Review. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 06 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 06 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name STARCH B Synonym(s) PREGEL STARCH • STARCH (API 13A SECTION 16)
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content DAZOMET (ISO)[TETRAHYDRO-3,5-DIMETHYL-1,3,5-THIA 533-74-4 208-576-7 <1% DIAZINE-2-THIONE] STARCH 9005-25-8 232-679-6 >98%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation Due to product form / nature of use, an inhalation hazard is not anticipated. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to product form and application, ingestion is considered unlikely. First aid facilities No information provided.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 3.4 PRODUCT NAME STARCH B
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Starch (a) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 3.4 PRODUCT NAME STARCH B
8.2 Exposure controls Engineering controls No special precautions are normally required when handling this product. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF WHITE POWDER Odour ODOURLESS Flammability COMBUSTIBLE Flash point > 125°C Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 5 - 8 Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) DISPERSIBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information Bulk density 550 - 700 kg/m3
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product:
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 3.4 PRODUCT NAME STARCH B
This product is expected to be of low toxicity. This product contains Dazomet (ISO) [Tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione], however due to the low levels present, adverse health effects are not anticipated. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) DAZOMET (ISO)[TETRAHYDRO-3,5-DIMETHYL-1 180 mg/kg (mouse) 2260 mg/kg (rat) -- ,3,5-THIADIAZINE-2-THIONE] Additional ingredient toxicity value(s): DAZOMET (ISO) [TETRAHYDRO-3,5-DIMETHYL-1,3,5-THIADIAZINE-2-THIONE] (533-74-4) LCLo (inhalation) 8400 mg/m³/4h (rat) LD50 (intraperitoneal) 87 mg/kg (rat) LD50 (subcutaneous) 248 mg/kg (mouse) LDLo (intramuscular) 250 mg/kg (dog) TDLo (oral) 3120 mg/kg/30 days-continuous (rat) Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Starch B is not harmful to aquatic organisms and does not cause long-term adverse effects in the aquatic environment. This product contains Dazomet (ISO) [Tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione], however due to the low levels present, adverse environmental effects are not anticipated.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal No special precautions are required for the disposal of this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 3.4 PRODUCT NAME STARCH B
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for a hazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is sometimes necessary.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 3.4 PRODUCT NAME STARCH B
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 3.4 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SPA Synonym(s) SODIUM POLYACRYLATE
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content ACRYLATE - ACRYLAMIDE COPOLYMER - - 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME SPA
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition. As with many solids, any dust that is generated may be explosive if mixed with air in critical proportions and in the presence of a source of ignition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Acrylamide SWA (AUS) -- 0.03 -- --
Biological limits No Biological Limit Value allocated.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME SPA
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CREAM GRANULAR SOLID Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 0.8 Solubility (water) 10 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles 5 - 10 %
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME SPA
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. This product may contain trace amounts of residual acrylamide, which is classified as a probable human carcinogen (IARC Group 2A). However, due to the very low levels present, adverse health effects are not anticipated with normal use. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product is not classified as causing aspiration.
12. ECOLOGICAL INFORMATION
12.1 Toxicity (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis Bahia = 48HR LC50 = 16.2 mg/L. Menidia Beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia Costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia Tonsa = 48hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME SPA
14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information ACRYLIC - ACRYLAMIDE RESINS: These resins are generally of low toxicity. Toxicity increases with presence of significant concentrations of acrylic - acrylamide monomers. These monomers have been linked with the development of skin sensitisation.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME SPA
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SODIUM SULPHITE Synonym(s) SODIUM SULFITE
1.2 Uses and uses advised against Use(s) ANTIOXIDANT • FOOD PRESERVATIVE • LABORATORY REAGENT • PAPER INDUSTRY • PHOTOGRAPHIC DEVELOPER • REDUCING AGENT • WATER TREATMENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements Signal word None allocated.
Pictograms None allocated. Hazard statement(s) AUH031 Contact with acids liberates toxic gas Prevention statement(s) None allocated. Response statement(s) None allocated. Storage statement(s) None allocated. Disposal statement(s) None allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
Page 1 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
Ingredient Identification Classification Content GHS Risk SODIUM CARBONATE CAS: 497-19-8 Eye Irrit. 2A, H319 Xi;R36 <0.1% EC: 207-838-8 SODIUM SULPHITE CAS: 7757-83-7 Not Available Not Available >97% EC: 231-821-4 SODIUM SULPHATE CAS: 7757-82-6 Not Available Not Available <2.5% EC: 231-820-9 WATER CAS: 7732-18-5 Not Available Not Available <0.1% EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgent hospital treatment is likely to be needed. If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower are recommended.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
Page 2 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a Full-face Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE CRYSTALLINE SOLID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 9.0 to 10.5 Vapour density NOT AVAILABLE Specific gravity 2.6 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE
Page 3 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
9.1 Information on basic physical and chemical properties Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid). Sensitive to air and moisture.
10.6 Hazardous decomposition products May evolve toxic gases (sulphur oxides) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard May be harmful. This product has the potential to cause adverse health effects with over exposure. Use safe summary work practices to avoid eye or skin contact and inhalation. Some individuals are hypersensitive to sulphites and may experience respiratory problems following exposure. Individuals known to be hypersensitive or with existing respiratory problems (eg asthma) are advised to avoid exposure. Eye Low irritant. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possible corneal damage. Inhalation Low irritant. Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing. Some individuals are hypersensitive to sulphites, and may experience asthma like symptoms (wheezing and shortness of breath) immediately following exposure. Skin Low irritant. Contact may result in irritation, redness, rash and dermatitis. Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea and vomiting. Well tolerated due to the oxidation of sulphites in the body to sulphates, however with large quantities sulphurous acid is formed. Some individuals may have an allergic reaction. The acute oral LD50 (male rat) is 3.56 g/kg/14 days. Toxicity data SODIUM CARBONATE (497-19-8) LC50 (inhalation) 800 mg/m³/2 hours (guinea pig) LD50 (ingestion) 4090 mg/kg (rat) LD50 (intraperitoneal) 117 mg/kg (mouse) LD50 (subcutaneous) 2210 mg/kg (mouse) SODIUM SULPHITE (7757-83-7) LD50 (ingestion) 820 mg/kg (mouse) LD50 (intraperitoneal) 950 mg/kg (mouse) LD50 (intravenous) 175 mg/kg (mouse) LDLo (ingestion) 2825 mg/kg (rabbit) LDLo (intravenous) 400 mg/kg (cat) LDLo (subcutaneous) 600 mg/kg (rabbit) SODIUM SULPHATE (7757-82-6) LD50 (ingestion) 5989 mg/kg (mouse) LD50 (intravenous) 1220 mg/kg (rabbit) LDLo (intravenous) 1220 mg/kg (mouse) TDLo (ingestion) 14 g/kg (mouse - 8-12 days pregnant)
Page 4 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
SODIUM SULPHATE (7757-82-6) TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait until reaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite (reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorb with sand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewer with large excess of water. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes T Toxic Risk phrases R31 Contact with acids liberates toxic gas.
Page 5 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
Safety phrases S25 Avoid contact with eyes. S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for a hazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is sometimes necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 1.4 Standard SDS Review 1.3 Standard SDS Review 1.2 Standard SDS Review Standard SDS Review 1.1 Standard SDS Review 1.0 Initial SDS creation
Page 6 of 7 SDS Date: 20 Jun 2014 PRODUCT NAME SODIUM SULPHITE
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1.4 SDS date: 20 June 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 20 Jun 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SODIUM BICARBONATE Synonym(s) BAKING SODA • BICARBONATE OF SODA • CARBONIC ACID, MONOSODIUM SALT • MONOSODIUM CARBONATE • SODIUM ACID CARBONATE • SODIUM HYDROGEN CARBONATE
1.2 Uses and uses advised against Use(s) PH CONTROL
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SODIUM BICARBONATE 144-55-8 205-633-8 >99%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities should be available. Eye wash facilities and safety shower are recommended.
4.2 Most important symptoms and effects, both acute and delayed No adverse health effects expected if the product is handled in accordance with the SDS and the product label.
Page 1 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SODIUM BICARBONATE
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packages are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Sodium Bicarbonate (total dust) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
Page 2 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SODIUM BICARBONATE
PPE Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point 854°C Evaporation rate NOT AVAILABLE pH 8 (1% Solution) Vapour density NOT AVAILABLE Specific gravity 2.533 Solubility (water) 170 g/L @ 25°C Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Sodium bicarbonate can neutralise the gastric juices in the stomach. During neutralisation, carbon dioxide gas is evolved and may cause stretching of the stomach, and with very large doses possible damage or rupture. Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.
Page 3 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SODIUM BICARBONATE
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity This product is not classified as a mutagen. Carcinogenicity This product is not classified as a carcinogen. Reproductive This product is not classified as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Page 4 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SODIUM BICARBONATE
Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 5 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SODIUM BICARBONATE
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 06 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 06 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SODA ASH Synonym(s) SODA ASH DENSE • SODIUM CARBONATE
1.2 Uses and uses advised against Use(s) DRILLING AID
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification(s) Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H319 Causes serious eye irritation. Prevention statement(s) P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. Storage statement(s) None allocated.
Disposal statement(s) None allocated.
2.3 Other hazards No information provided.
Page 1 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME SODA ASH
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SODIUM CARBONATE 497-19-8 207-838-8 >97%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed Irritating to the eyes and skin.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
Page 2 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME SODA ASH
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point 854°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 2.533 Solubility (water) 170 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
Page 3 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME SODA ASH
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicological effects from this product. Based on available data, the classification criteria are not met. Acute Oral Toxicity: 4090 mg/kg (rat). Acute Inhalation Toxicity: 800 mg/m3/2 hours (guinea pig). Skin Contact may result in irritation, redness, rash and dermatitis. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity This product is not classified as a mutagen. Carcinogenicity This product is not classified as a carcinogen. Reproductive This product is not classified as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. However, over exposure may result in irritation exposure of the nose and throat, with coughing. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
Page 4 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME SODA ASH
13.1 Waste treatment methods Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R36 Irritating to eyes. Safety phrases S22 Do not breathe dust. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME SODA ASH
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 29 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 29 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SAPP Synonym(s) DISODIUM DIHYDROGEN PYROPHOSPHATE • DISODIUM PYROPHOSPHATE
1.2 Uses and uses advised against Use(s) ACIDIFIER • BUFFERING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk DISODIUM PYROPHOSPHATE CAS: 7758-16-9 Not Available Not Available 100% EC: 231-835-0
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities and safety shower should be available.
Page 1 of 6 SDS Date: 28 Jul 2014 PRODUCT NAME SAPP
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (phosphorus oxides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Ventilate area where possible.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Nuisance dust SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 28 Jul 2014 PRODUCT NAME SAPP
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE POWDER Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point > 600°C Evaporation rate NOT AVAILABLE pH 4.5 (1% Solution) Vapour density NOT AVAILABLE Specific gravity 1.35 - 1.41 Solubility (water) 119 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve toxic gases (phosphorus oxides) when heated to decomposition.
Page 3 of 6 SDS Date: 28 Jul 2014 PRODUCT NAME SAPP
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard Low toxicity. Use safe work practices to avoid eye or skin contact and inhalation. summary Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Skin Low to moderate irritant. Prolonged or repeated contact may result in irritation and rash. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Ingestion of large quantities may also result in serious disturbances in calcium metabolism. Toxicity data DISODIUM PYROPHOSPHATE (7758-16-9) LD50 (ingestion) 2650 mg/kg (mouse) LD50 (intraperitoneal) 1 g/kg (mouse) LD50 (intravenous) 59 mg/kg (mouse) LD50 (subcutaneous) 480 mg/kg (mouse)
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
Page 4 of 6 SDS Date: 28 Jul 2014 PRODUCT NAME SAPP
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 5 of 6 SDS Date: 28 Jul 2014 PRODUCT NAME SAPP
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 28 July 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 28 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SAND SEAL FINE Synonym(s) SAND SEAL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content VEGETABLE MATERIALS - - 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities No information provided.
Page 1 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SAND SEAL FINE
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SAND SEAL FINE
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance TAN POWDER Odour MILD ODOUR Flammability NON FLAMMABLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.3 (5% Suspension) Vapour density NOT AVAILABLE Specific gravity 0.35 Solubility (water) INSOLUBLE Vapour pressure 1 mm Hg @ 20°C Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SAND SEAL FINE
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
Page 4 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SAND SEAL FINE
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 06 Jan 2015 PRODUCT NAME SAND SEAL FINE
Revision history Revision Description 3.0 Converted to GHS. 2.0 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 3 SDS date: 06 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 06 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name SALT Synonym(s) FLOSSY SALT • HALITE • NACL • SODIUM CHLORIDE
1.2 Uses and uses advised against Use(s) CHLORIDE SOURCE • DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk SODIUM CHLORIDE CAS: 7647-14-5 Not Available Not Available >98% EC: 231-598-3 INORGANIC SALT(S) Not Available Not Available Not Available <0.8% WATER CAS: 7732-18-5 Not Available Not Available <0.8% EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Page 1 of 6 SDS Date: 24 Jul 2014 PRODUCT NAME SALT
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Under normal conditions of use, adverse health effects are not anticipated. This product is generally considered to be of low toxicity.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate fire protection systems.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Page 2 of 6 SDS Date: 24 Jul 2014 PRODUCT NAME SALT
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance TRANSLUCENT TO WHITE GRANULES OR POWDER Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 1413°C Melting point 801°C Evaporation rate NOT AVAILABLE pH 7 (1% Solution) Vapour density NOT AVAILABLE Specific gravity 2.163 Solubility (water) 357 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
Page 3 of 6 SDS Date: 24 Jul 2014 PRODUCT NAME SALT
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid) and alkalis (eg. sodium hydroxide).
10.6 Hazardous decomposition products May evolve toxic gases when strongly heated.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Contact may result in mild irritation and rash. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer if additional information is required. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Page 4 of 6 SDS Date: 24 Jul 2014 PRODUCT NAME SALT
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 24 Jul 2014 PRODUCT NAME SALT
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 24 July 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 24 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name RHEOPAC R/LV/UL/RD/LVD Synonym(s) RHEOPAC LV • RHEOPAC R • RHEOPAC UL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SODIUM CARBOXYMETHYL CELLULOSE 9004-32-4 618-378-6 >88%
WATER 7732-18-5 231-791-2 <10%
SODIUM CHLORIDE 7647-14-5 231-598-3 <1.8%
SODIUM GLYCOLATE 2836-32-0 212-730-9 <0.7%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
SDS Date: 17 Apr 2015 Page 1 of 6 Version No: 1.4 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
SDS Date: 17 Apr 2015 Page 2 of 6 Version No: 1.4 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE OR YELLOWISH POWDER/GRANULES Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.0 to 8.5 (1 % solution) Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
SDS Date: 17 Apr 2015 Page 3 of 6 Version No: 1.4 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data available on the ingredients: SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat) Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential Not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
13. DISPOSAL CONSIDERATIONS
SDS Date: 17 Apr 2015 Page 4 of 6 Version No: 1.4 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 17 Apr 2015 Page 5 of 6 Version No: 1.4 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 17 Apr 2015 Page 6 of 6 Version No: 1.4 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name RHEOPAC R/LV/UL/RD/LVD Synonym(s) RHEOPAC LV • RHEOPAC R • RHEOPAC UL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk SODIUM CARBOXYMETHYL CELLULOSE CAS: 9004-32-4 Not Available Not Available >88% EC: 618-378-6 WATER CAS: 7732-18-5 Not Available Not Available <10% EC: 231-791-2 SODIUM CHLORIDE CAS: 7647-14-5 Not Available Not Available <1.8% EC: 231-598-3 SODIUM GLYCOLATE CAS: 2836-32-0 Not Available Not Available <0.7% EC: 212-730-9
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Page 1 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Page 2 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE OR YELLOWISH POWDER/GRANULES Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 6.0 to 8.5 (1 % solution) Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
Page 3 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer if additional information is required. Legislation Dispose of in accordance with relevant local legislation.
Page 4 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME RHEOPAC R/LV/UL/RD/LVD
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 1.2 Standard SDS Review 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1.2 SDS date: 20 June 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 20 Jun 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name QUICKSEAL (F,M,C) Synonym(s) QUICKSEAL
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CELLULOSE 9004-34-6 232-674-9 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
Page 1 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Difficult to extinguish once burning.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Moisten with water to prevent a dust hazard and place in sealable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach of children.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
Page 2 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance YELLOW TO BROWN SOLID Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT RELEVANT Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 7 to 8 Vapour density NOT AVAILABLE Specific gravity 0.9 - 1.2 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrate and sodium nitrite.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats). Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats). Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat). Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash. Eye Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness and lacrimation. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Low toxicity to aquatic organisms.
12.2 Persistence and degradability This product is readily biodegradable.
12.3 Bioaccumulative potential This product is not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reuse where possible. No special precautions are normally required when handling this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user
Page 4 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 13 Feb 2015 PRODUCT NAME QUICKSEAL (F,M,C)
Revision history Revision Description 2.3 Standard SDS Review. 2.2 Standard SDS Review. 2.1 Provided Ingredient CAS No. 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2.3 SDS date: 13 February 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 13 Feb 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name POTASSIUM CHLORIDE Synonym(s) KCL • MURIATE OF POTASH • POTASH • SYLVITE
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • FERTILISER • INHIBITOR
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk POTASSIUM CHLORIDE CAS: 7447-40-7 Not Available Not Available >97% EC: 231-211-8
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
Page 1 of 6 SDS Date: 25 Jul 2014 PRODUCT NAME POTASSIUM CHLORIDE
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
Page 2 of 6 SDS Date: 25 Jul 2014 PRODUCT NAME POTASSIUM CHLORIDE
PPE Eye / Face At high dust levels, wear dust-proof goggles. Hands With prolonged use, wear PVC or rubber or cotton gloves. Body With prolonged use, wear coveralls. Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE SOLID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 1413°C Melting point 773°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 2.0 Solubility (water) 340 g/L @ 20°C Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible (potentially explosive) with oxidising agents (eg. hypochlorites).
10.6 Hazardous decomposition products May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed. Oral Toxicity: An oral LD50 in rats of 2600 mg/kg was reported for potassium chloride. Skin Not classified as a skin irritant. Contact may result in mild irritation and rash. Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation.
Page 3 of 6 SDS Date: 25 Jul 2014 PRODUCT NAME POTASSIUM CHLORIDE
Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, and exposure potassium is rapidly excreted by the body, however this product does have the potential to cause cardiovascular disorders. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Page 4 of 6 SDS Date: 25 Jul 2014 PRODUCT NAME POTASSIUM CHLORIDE
Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Page 5 of 6 SDS Date: 25 Jul 2014 PRODUCT NAME POTASSIUM CHLORIDE
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 25 July 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 25 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name POLYDRILL Synonym(s) POLY DRILL
1.2 Uses and uses advised against Use(s) ADDITIVE • DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content SULPHONATED ORGANIC POLYMER - - 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities Eye wash facilities and safety shower should be available.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME POLYDRILL
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME POLYDRILL
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance RED BROWN POWDER Odour CHARACTERISTIC ODOUR Flammability COMBUSTIBLE Flash point NOT RELEVANT Boiling point > 370°C Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 7 to 9 (150 g/L) Vapour density NOT AVAILABLE Specific gravity 1.8 Solubility (water) 320 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product:
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME POLYDRILL
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) SULPHONATED ORGANIC POLYMER > 5000 mg/kg (rat) -- -- Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability This product is not readily biodegradable.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME POLYDRILL
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME POLYDRILL
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2 Product Name PIPE FREE M
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Supplier name RHEOCHEM LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Emergency 1800 127 406 (Australia); 011 64 3 3530199 (International) Web site http://www.rheochem.com.au/ Synonym(s) PIPEFREE M Use(s) ANTIFREEZE • BRAKE FLUID • FOAM • HEAT TRANSFER AGENT • HUMECTANT • LEATHER INDUSTRY • PAINT • SOLVENT • TEXTILE CHEMICAL SDS date 29 January 2013
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA RISK PHRASES R22 Harmful if swallowed. SAFETY PHRASES S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
UN number None Allocated DG class None Allocated Packing group None Allocated Subsidiary risk(s) None Allocated Hazchem code None Allocated
3. COMPOSITION/ INFORMATION ON INGREDIENTS Ingredient Identification Classification Content ETHYLENE GLYCOL CAS: 107-21-1 Xn;R22 100% EC: 203-473-3
4. FIRST AID MEASURES
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Advice to doctor Treat symptomatically. First aid facilities Eye wash facilities and safety shower are recommended.
Page 1 of 5 SDS Date: 29 Jan 2013 Product Name PIPE FREE M
5. FIRE FIGHTING MEASURES
Flammability Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Vapour may form explosive mixtures with air. Fire and explosion Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways. Hazchem code None Allocated
6. ACCIDENTAL RELEASE MEASURES
Personal precautions Wear Personal Protective Equipment (PPE) as detailed in Section 8 of this SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
Environmental precautions Prevent product from entering drains and waterways.
Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
References See Sections 8 and 13 for exposure controls and disposal.
7. STORAGE AND HANDLING
Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, alkalis, phosphorus pentasulphide, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C1 Combustible Liquid (AS1940). Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Ethylene glycol (particulate) SWA (AUS) -- 10 -- -- Ethylene glycol (vapour) SWA (AUS) 20 52 40 104
Biological limits No biological limit allocated. Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear rubber or butyl or neoprene gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
Page 2 of 5 SDS Date: 29 Jan 2013 Product Name PIPE FREE M
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance VISCOUS CLEAR COLOURLESS LIQUID Odour ODOURLESS Flammability CLASS C1 COMBUSTIBLE Flash point 110°C (cc) Boiling point 197°C Melting point -13°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density 2.2 (Air =1) Specific gravity 1.12 Solubility (water) SOLUBLE Vapour pressure 0.05 mm Hg @ 20°C Upper explosion limit 12.8 % Lower explosion limit 3.2 % Autoignition temperature 314°C Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Partition coefficient NOT AVAILABLE % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
Chemical stability Stable under recommended conditions of storage. Conditions to avoid Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources. Material to avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), alkalis (eg. hydroxides) and phosphorus pentasulphide. Hazardous Decomposition May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Products Hazardous Reactions Polymerization is not expected to occur.
11. TOXICOLOGICAL INFORMATION
Health Hazard Harmful - irritant. This product has the potential to cause adverse health effects with over exposure. Summary Use safe work practices to avoid eye or skin contact and inhalation. At room temperature ethylene glycol has a low vapour pressure and therefore an inhalation hazard is not anticipated unless heated or sprayed. Chronic exposure may result in kidney and central nervous system (CNS) damage. Eye Irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Harmful. Over exposure may result in mild respiratory irritation. High level exposure may result in headache, nausea, dizziness and central nervous system (CNS) depression. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. Ingestion Harmful. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, drowsiness and unconsciousness. Chronic exposure may result in kidney damage. Aspiration may result in chemical pneumonitis and pulmonary oedema. Toxicity data ETHYLENE GLYCOL (107-21-1) LC50 (inhalation) 10 876 mg/kg (rat) LD50 (ingestion) 1650 mg/kg (cat) LD50 (skin) 9530 ug/kg (rabbit) LDLo (ingestion) 398 mg/kg (human) TCLo (inhalation) 10,000 mg/m³ (human - cough) TDLo (ingestion) 5500 mg/kg (child - anaesthesia)
12. ECOLOGICAL INFORMATION
Toxicity LC50 (Aquatic species): >100mg/L/96hrs. Non hazardous to aquatic organisms.
Persistence and degradability Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms.
Page 3 of 5 SDS Date: 29 Jan 2013 Product Name PIPE FREE M
Bioaccumulative potential No information provided.
Mobility in soil Expected to be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces.
Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of by controlled incineration, by licensed or competent personnel. Contact the manufacturer for additional information. Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
UN number None Allocated None Allocated None Allocated Proper shipping name None Allocated None Allocated None Allocated
DG class/ Division None Allocated None Allocated None Allocated Subsidiary risk(s) None Allocated None Allocated None Allocated Packing group None Allocated None Allocated None Allocated Hazchem code None Allocated
15. REGULATORY INFORMATION
Poison schedule Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Inventory Listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information ETHYLENE GLYCOL: Has been reported to cause teratogenic and mutagenic effects, however the doses recorded for these effects are extremely high. For example experimental rat studies by the oral route have shown that ingestion of 8.5 g/kg by pregnant rats in their 6-15 day of gestation caused teratogenic effects. This equates to the ingestion of 500 ml of ethylene glycol by a 60 kg women for similar effects to occur. Exposure at such levels is not reported in industry.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
STORAGE OF COMBUSTIBLE LIQUIDS. Combustible liquids with a flash point between 61°C and 150°C are required to be stored as for flammable liquids (Dangerous Goods Class 3) under AS 1940. [Refer to Australian Standard 1940, Storage and Handling of Flammable and Combustible Liquids, for full storage guidelines].
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
Page 4 of 5 SDS Date: 29 Jan 2013 Product Name PIPE FREE M
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons TLV Threshold Limit Value TWA/OEL Time Weighted Average or Occupational Exposure Limit
Revision history Revision Description 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Revision: 1.1 SDS Date: 29 January 2013 End of SDS
Page 5 of 5 SDS Date: 29 Jan 2013 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name NEW 100N Synonym(s) NEW100N
1.2 Uses and uses advised against Use(s) DRILLING FLUID
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content POLYGLYCEROL 25618-55-7 - 30 to 60% WATER 7732-18-5 231-791-2 Remainder GLYCEROL (GLYCERINE) 56-81-5 200-289-5 10 to 30%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities No information provided.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME NEW 100N
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Eliminate all sources of ignition.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Glycerin mist (a) SWA (AUS) -- 10 -- --
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME NEW 100N
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance VISCOUS DARK BROWN LIQUID Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 176°C Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 7 to 8.5 Vapour density NOT AVAILABLE Specific gravity 1.16 to 1.25 Solubility (water) SOLUBLE Vapour pressure < 4 mm Hg @ 20°C Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME NEW 100N
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) GLYCEROL (GLYCERINE) 4090 mg/kg (mouse) -- -- Additional ingredient toxicity value(s): GLYCEROL (GLYCERINE) (56-81-5) LD50 (intraperitoneal) 4420 mg/kg (rat) LD50 (intravenous) 4250 mg/kg (mouse) LD50 (subcutaneous) 91 mg/kg (mouse) TDLo (oral) 1428 mg/kg (human) Skin Not classified as a skin irritant. Contact may cause temporary mild skin irritation. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization Not classified as causing skin or respiratory sensitisation. Mutagenicity Not classified as a mutagen. Carcinogenicity Not classified as a carcinogen. Reproductive Not classified as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not classified as causing aspiration.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME NEW 100N
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME NEW 100N
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2
Product Name MEG
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name RHEOCHEM LTD Address 11 Alacrity Place, Henderson, WA, AUSTRALIA, 6166 Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Emergency 1800 127 406 (Australia); 011 64 3 3530199 (International) Web Site http://www.rheochem.com.au/
Synonym(s) 1,2-DIHYDROXYETHANE • 1,2-ETHANEDIOL • ETHYLENE GLYCOL • MONOETHYLENE GLYCOL
Use(s) ANTIFREEZE • BRAKE FLUID • FOAM • HEAT TRANSFER MEDIUM • HUMECTANT • LEATHER INDUSTRY • PAINT • SOLVENT • TEXTILE CHEMICAL SDS Date 01 Nov 2010 2. HAZARDS IDENTIFICATION CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA RISK PHRASES R22 Harmful if swallowed. SAFETY PHRASES S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated 3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Formula CAS No. Content ETHYLENE GLYCOL C2-H6-O2 107-21-1 100% 4. FIRST AID MEASURES Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air- line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Advice to Doctor Treat symptomatically. First Aid Facilities Eye wash facilities and safety shower are recommended.
Page 1 of 5 RMT Reviewed: 04 Nov 2010 Printed: 04 Nov 2010
Product Name MEG
5. FIRE FIGHTING MEASURES Flammability Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Vapour may form explosive mixtures with air. Fire and Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind Explosion and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways. Hazchem Code None Allocated 6. ACCIDENTAL RELEASE MEASURES Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of all unprotected personnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustible absorbant material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Prevent spill entering drains or waterways. 7. STORAGE AND HANDLING Storage Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, phosphorus pentasulphide, sodium hydroxide, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C1 Combustible Liquid (AS1940). Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Exposure Stds Ingredient Reference TWA STEL Ethylene glycol (vapour) SWA (AUS) 20 ppm 52 mg/m3 40 ppm 104 mg/m3
Biological Limits No biological limit allocated.
Engineering Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is Controls recommended. Maintain vapour levels below the recommended exposure standard. PPE Wear splash-proof goggles, neoprene or butyl or rubber gloves and coveralls. Where an inhalation risk exists, wear: a Type A (Organic vapour) respirator. If spraying, wear: a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance VISCOUS CLEAR COLOURLESS Solubility (water) SOLUBLE LIQUID Odour ODOURLESS Specific Gravity 1.12 pH NOT AVAILABLE % Volatiles NOT AVAILABLE Vapour Pressure 0.05 mm Hg @ 20°C Flammability CLASS C1 COMBUSTIBLE Vapour Density 2.2 (Air =1) Flash Point 110°C (cc) Boiling Point 197°C Upper Explosion Limit 12.8 % Melting Point -13°C Lower Explosion Limit 3.2 % Evaporation Rate NOT AVAILABLE Autoignition Temperature 314°C
Page 2 of 5 RMT Reviewed: 04 Nov 2010 Printed: 04 Nov 2010
Product Name MEG
10. STABILITY AND REACTIVITY Chemical Stability Stable under recommended conditions of storage. Conditions to Avoid Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources. Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), alkalis (eg. hydroxides) and phosphorus pentasulphide. Hazardous May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Decomposition Products Hazardous Reactions Polymerization is not expected to occur. 11. TOXICOLOGICAL INFORMATION Health Hazard Moderate toxicity. This product has the potential to cause adverse health effects with over exposure. Use safe Summary work practices to avoid eye or skin contact and inhalation. At room temperature ethylene glycol has a low vapour pressure and therefore an inhalation hazard is not anticipated unless heated or sprayed. Chronic exposure may result in kidney and central nervous system (CNS) damage. Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low irritant. Over exposure may result in mild respiratory irritation. High level exposure may result in headache, nausea, dizziness and central nervous system (CNS) depression. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. Ingestion Moderate toxicity. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, drowsiness and unconsciousness. Chronic exposure may result in kidney damage. Aspiration may result in chemical pneumonitis and pulmonary oedema. Toxicity Data ETHYLENE GLYCOL (107-21-1) LC50 (Inhalation): 10 876 mg/kg (rat) LD50 (Ingestion): 1650 mg/kg (cat) LD50 (Skin): 9530 ug/kg (rabbit) LDLo (Ingestion): 398 mg/kg (human) TCLo (Inhalation): 10,000 mg/m3 (human - cough) TDLo (Ingestion): 5500 mg/kg (child - anaesthesia) 12. ECOLOGICAL INFORMATION Environment Ethylene glycol will mainly exist in the vapour phase in the ambient atmosphere where it will be degraded by reaction with hydroxyl radicals. Expected to be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces. Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms. Ecotoxicity LC50 (Aquatic species): >100mg/L/96hrs. Non hazardous to aquatic organisms.
13. DISPOSAL CONSIDERATIONS Waste Disposal Dispose of by controlled incineration, by licensed or competent personnel. Contact the manufacturer for additional information. Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name None Allocated UN No. None Allocated DG Class None Allocated Subsidiary Risk(s) None Allocated Packing Group None Allocated Hazchem Code None Allocated
15. REGULATORY INFORMATION Poison Schedule Classified as a Schedule 6 (S6) Poison using the criteria in the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
Page 3 of 5 RMT Reviewed: 04 Nov 2010 Printed: 04 Nov 2010
Product Name MEG
16. OTHER INFORMATION Additional ETHYLENE GLYCOL: Has been reported to cause teratogenic and mutagenic effects, however the doses Information recorded for these effects are extremely high. For example experimental rat studies by the oral route have shown that ingestion of 8.5 g/kg by pregnant rats in their 6-15 day of gestation caused teratogenic effects. This equates to the ingestion of 500 ml of ethylene glycol by a 60 kg women for similar effects to occur. Exposure at such levels is not reported in industry.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
STORAGE OF COMBUSTIBLE LIQUIDS. Combustible liquids with a flash point between 61°C and 150°C are required to be stored as for flammable liquids (Dangerous Goods Class 3) under AS 1940. [Refer to Australian Standard 1940, Storage and Handling of Flammable and Combustible Liquids, for full storage guidelines].
ABBREVIATIONS: ACGIH - American Conference of Industrial Hygienists. ADG - Australian Dangerous Goods. BEI - Biological Exposure Indice(s). CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. EC No - European Community Number. HSNO - Hazardous Substances and New Organisms. IARC - International Agency for Research on Cancer. mg/m3 - Milligrams per Cubic Metre. NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. RTECS - Registry of Toxic Effects of Chemical Substances. STEL - Short Term Exposure Limit. SWA - Safe Work Australia. TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a Chem Alert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this Chem Alert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made. Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS. Prepared By Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Page 4 of 5 RMT Reviewed: 04 Nov 2010 Printed: 04 Nov 2010
Product Name MEG
SDS Date01 Nov 2010 End of Report
Page 5 of 5 RMT Reviewed: 04 Nov 2010 Printed: 04 Nov 2010 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name MAGNESIUM OXIDE Synonym(s) CALCINED MAGNESIA • MAGNESIA • MAGOXI16 / 27 - PRODUCT CODE
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • PH INDICATOR
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CALCIUM OXIDE 1305-78-8 215-138-9 <3.5% MAGNESIUM OXIDE 1309-48-4 215-171-9 >94% SILICA, AMORPHOUS 7631-86-9 231-545-4 <2.5%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME MAGNESIUM OXIDE
First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve magnesium oxides when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure product is adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium oxide SWA (AUS) -- 2 -- -- Fumed silica (respirable dust) SWA (AUS) -- 2 -- -- Magnesium oxide (fume) SWA (AUS) -- 10 -- --
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME MAGNESIUM OXIDE
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE GRANULES Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 3600°C Melting point 2800°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 3.6 - 3.7 Solubility (water) SLIGHTLY SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles 0 %
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME MAGNESIUM OXIDE
10.5 Incompatible materials Incompatible (violently) with interhalogens (e.g. bromine pentafluoride, chlorine trifluoride) and phosphorus pentachloride. May ignite or explode when heated with aluminium powder. Also incompatible with acids (e.g. nitric acid) and dampness as material hydrates.
10.6 Hazardous decomposition products May evolve magnesium oxides when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) SILICA, AMORPHOUS 3160 mg/kg (rat) -- -- Skin Contact may result in irritation, redness, rash and dermatitis. Eye Contact may result in irritation, lacrimation, pain and redness. Sensitization This product is not classified as causing skin or respiratory sensitisation. Mutagenicity This product is not classified as a mutagen. Carcinogenicity This product is not classified as a carcinogen. Reproductive This product is not classified as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability The methods for determining the biological degradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential Not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, cover with moist sand, vermiculite or similar to avoid dust hazard and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information if disposing of large quantities (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME MAGNESIUM OXIDE
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: Strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME MAGNESIUM OXIDE
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name LIMESTONE LSC/L80 Synonym(s) CALCIUM CARBONATE • STONE DUST
1.2 Uses and uses advised against Use(s) BRIDGING AGENT • WEIGHTING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <1% CALCIUM CARBONATE 471-34-1 207-439-9 >96%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
Page 1 of 6 SDS Date: 23 Jan 2015 PRODUCT NAME LIMESTONE LSC/L80
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters No fire or explosion hazard exists.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up If spilt, collect and reuse where possible. Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 23 Jan 2015 PRODUCT NAME LIMESTONE LSC/L80
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Wear a Class P3 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point 825°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 2.7 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts.
Page 3 of 6 SDS Date: 23 Jan 2015 PRODUCT NAME LIMESTONE LSC/L80
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation and rash. Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficient respirable silica in this product to be classified as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Chronic exposure to respirable silica may result in pulmonary fibrosis (silicosis). However, given the low exposure levels present, over exposure is not anticipated. Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects.
12.2 Persistence and degradability Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle.
12.3 Bioaccumulative potential This product does not bioaccumulate.
12.4 Mobility in soil Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Page 4 of 6 SDS Date: 23 Jan 2015 PRODUCT NAME LIMESTONE LSC/L80
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. If not used in a closed system, local exhaust ventilation is recommended to control exposure. Provide eye wash and safety shower in close proximity to points of potential exposure. Where the potential for an inhalation risk exists, an approved respirator may be required. Do not eat, store, consume food, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 23 Jan 2015 PRODUCT NAME LIMESTONE LSC/L80
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.2 Standard SDS Review 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 23 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 23 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name JK-161 LV Synonym(s) JK - 161 LV • RHEOCHEM JK-161 LV
1.2 Uses and uses advised against Use(s) ENCAPSULATING AGENT • HIGH PERFORMANCE WBM
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk ACRYLAMIDE, SODIUM ACRYLATE CAS: 25085-02-3 Not Available Not Available >90% COPOLYMER EC: 607-529-1 WATER CAS: 7732-18-5 Not Available Not Available Remainder EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting.
Page 1 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME JK-161 LV
First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Acrylamide SWA (AUS) -- 0.03 -- --
Biological limits No Biological Limit Value allocated.
Page 2 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME JK-161 LV
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE GRANULAR SOLID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 0.8 Solubility (water) 10 g/L Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
Page 3 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME JK-161 LV
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard Low toxicity. Use safe work practices to avoid eye or skin contact and inhalation. This product may contain summary trace amounts of residual acrylamide, which is classified as a probable human carcinogen (IARC Group 2A). However, due to the very low levels present, adverse health effects are not anticipated with normal use. Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Allergic reactions are possible. Ingestion Low toxicity. Ingestion is considered unlikely due to product form. However, ingestion via hand-mouth transfer may result in gastrointestinal irritation, nausea and vomiting. Maintain good personal hygiene standards. Toxicity data No LD50 data available for this product.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis Bahia = 48HR LC50 = 16.2 mg/L. Menidia Beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia Costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia Tonsa = 48hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
Page 4 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME JK-161 LV
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information ACRYLIC - ACRYLAMIDE RESINS These resins are generally of low toxicity. Toxicity increases with presence of significant concentrations of acrylic - acrylamide monomers. These monomers have been linked with the development of skin sensitisation.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 20 Jun 2014 PRODUCT NAME JK-161 LV
Revision history Revision Description 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1.1 SDS date: 20 June 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 20 Jun 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name IDCIDE-20 Synonym(s) IDCIDE 20
1.2 Uses and uses advised against Use(s) BIOCIDE • DRILLING FLUID ADDITIVE • WATER TREATMENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Skin Sensitization: Category 1 Skin Corrosion/Irritation: Category 2 Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictograms
Hazard statement(s) H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Prevention statement(s) P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment is advised - see first aid instructions. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before re-use.
Page 1 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk TETRAKIS(HYDROXYMETHYL)PHOSPHONI CAS: 55566-30-8 Not Available Not Available 18 to 25% UM SULPHATE EC: 259-709-0 WATER CAS: 7732-18-5 Not Available Not Available Remainder EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible.
Page 2 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear a faceshield and splash-proof goggles. Hands Wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Not required under normal conditions of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance COLOURLESS TO PALE YELLOW LIQUID Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point > 100°C Melting point < 0°C Evaporation rate AS FOR WATER pH 3.0 to 3.5 Vapour density NOT AVAILABLE Specific gravity 1.08 Solubility (water) SOLUBLE
Page 3 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
9.1 Information on basic physical and chemical properties Vapour pressure 18 mm Hg @ 20°C Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles > 60 % (Water)
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure. summary Upon dilution, the potential for adverse health effects may be reduced. Eye Irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Irritant. Contact may result in irritation. May cause sensitisation by skin contact. Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea. Toxicity data TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8) LD50 (ingestion) 248 mg/kg (rat) TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)
Page 4 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
12. ECOLOGICAL INFORMATION
12.1 Toxicity 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr
Waste Water management EC50 (Activated Sludge) = 24 mg/L/3 hr
12.2 Persistence and degradability This product is readily biodegradable.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For larger amounts, contact the manufacturer for additional information. Prevent contamination of drains or waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)].
Page 5 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Hazard codes Xi Irritant Risk phrases R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact.
Safety phrases S23 Do not breathe gas/fumes/vapour/spray (where applicable). S24/25 Avoid contact with skin and eyes. S36 Wear suitable protective clothing. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. If not used in a closed system, local exhaust ventilation is recommended to control exposure. Provide eye wash and safety shower in close proximity to points of potential exposure. Where the potential for an inhalation risk exists, an approved respirator may be required. Do not eat, store, consume food, tobacco or drink in areas where product is used.
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 6 of 7 SDS Date: 28 Jul 2014 PRODUCT NAME IDCIDE-20
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 28 July 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 28 Jul 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name GLYCHEM MC/DCP 208 Synonym(s) DCP 208 • GLYCHEM - MC • GLYCHEM-MC (FORMERLY)
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • MUD INHIBITOR • SHALE INHIBITOR
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification(s) Serious Eye Damage / Eye Irritation: Category 1
2.2 Label elements Signal word DANGER
Pictogram(s)
Hazard statement(s) H318 Causes serious eye damage. Prevention statement(s) P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. Storage statement(s) None allocated.
Disposal statement(s) None allocated.
2.3 Other hazards No information provided.
Page 1 of 6 SDS Date: 28 Aug 2014 PRODUCT NAME GLYCHEM MC/DCP 208
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk POLY(OXY-1,2-ETHANEDIYL),ALPHA-BUTY CAS: 9004-77-7 Not Available Not Available 100% L-OMEGA-HYDROXY EC: 500-012-0
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed Irritating to the eyes.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
Page 2 of 6 SDS Date: 28 Aug 2014 PRODUCT NAME GLYCHEM MC/DCP 208
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate fire protection systems.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proof extraction ventilation is recommended.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Not required under normal conditions of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance COLOURLESS LIQUID Odour MILD ODOUR Flammability CLASS C1 COMBUSTIBLE Flash point 142°C Boiling point 278°C Melting point -35°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 0.989 Solubility (water) SOLUBLE Vapour pressure 0.33 hPa @ 25°C Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature 202°C Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE
Page 3 of 6 SDS Date: 28 Aug 2014 PRODUCT NAME GLYCHEM MC/DCP 208
9.1 Information on basic physical and chemical properties Odour threshold NOT AVAILABLE 9.2 Other information Freezing point < -12°C
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid shock, friction, heavy impact, heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), alkalis (eg. sodium hydroxide), heat and ignition sources.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Acute Oral Toxicity: LD50 (rat) = 2630 mg/kg. Acute Dermal Toxicity: LD50 (rat) = 3540 mg/kg. Acute Inhalation Toxicity: Not relevant, expert judgement. Skin Not classified as a skin irritant. Contact may result in mild irritation and dermatitis. Eye Classified as irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not expected to cause organ effects from single exposure. exposure STOT – repeated Not expected to cause organ effects from repeated exposure. However, repeated exposure to some glycols exposure may result in liver and kidney damage. Aspiration This product is not classified as causing aspiration.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Low toxicity to aquatic organisms.
12.2 Persistence and degradability Biodegradation BOD5 : N.D. % ThOD Water : Readily biodegradable in water (Test: 69%, 28d, OECD 301D) Soil : T ½: N.D. days.
12.3 Bioaccumulative potential Bioaccumulative potential: log Pow : 0.436 (OECD 107); BCF : N.D. (Slightly or not bioaccumulative).
12.4 Mobility in soil The product is involatile and water soluble and will partition to the aqueous phase. The product will dissolve rapidly in water. If released to soil it will evaporate at a low rate.
Page 4 of 6 SDS Date: 28 Aug 2014 PRODUCT NAME GLYCHEM MC/DCP 208
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, mix with sand and dispose of to approved landfill. For larger quantities, dissolve in flammable solvent and incinerate at an approved facility equipped with after burner and scrubber. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R41 Risk of serious damage to eyes. Safety phrases S2 Keep out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S39 Wear eye/face protection. S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
Page 5 of 6 SDS Date: 28 Aug 2014 PRODUCT NAME GLYCHEM MC/DCP 208
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 3.1 Standard SDS Review. 3.0 Converted to GHS. 2.0 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 3.1 SDS date: 28 August 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 28 Aug 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name GEOVIS Synonym(s) DIUTAN GUM
1.2 Uses and uses advised against Use(s) VISCOSITY MODIFIER
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content D-GLUCURONO-6-DEOXY-L-MANNO-D-GLUCAN, 595585-15-2 - >50% ACETATE, CALCIUM MAGNESIUM POTASSIUM SODIUM SALT
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form. First aid facilities No information provided.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME GEOVIS
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled and tightly closed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME GEOVIS
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE TO TAN POWDER Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NON VOLATILE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature 351°C Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles 0 %
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME GEOVIS
11.1 Information on toxicological effects Acute toxicity Information available for the product: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) D-GLUCURONO-6-DEOXY-L-MANNO-D-GLUCA > 5000 mg/kg (rat) -- -- N, ACETATE, CALCIUM MAGNESIUM POTASSIUM SODIUM SALT Skin Not classified as a skin irritant. Contact may result in mild irritation. The hydrophilic nature of the notified polymer in powder form can contribute to mechanical irritation and collection in the eyes when dust is generated. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. The hydrophilic nature of the notified polymer in powder form can contribute to mechanical irritation and collection on the skin when dust is generated. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. The hydrophilic nature of the notified polymer in powder form can exposure contribute to mechanical irritation and collection in the airways when dust is generated. STOT – repeated No known effects from this product. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity The notified polymer is not toxic to fish (rainbow trout), aquatic invertebrates (daphnia magna) and marine invertebrates (acartia tonsa) under test conditions.
12.2 Persistence and degradability Considered readily biodegradable.
12.3 Bioaccumulative potential No experimental results provided. However, based on the molecular weight, water solubility and Kow value the notified polymer is not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME GEOVIS
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME GEOVIS
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name GAGETROL Synonym(s)
1.2 Uses and uses advised against Use(s) DRILLING AID
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CARBOXYMETHYL STARCH 9057-06-1 - 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation Due to product form / nature of use, an inhalation hazard is not anticipated. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to product form and application, ingestion is considered unlikely. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Adverse effects not expected from this product under normal conditions of use.
SDS Date: 02 Jun 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME GAGETROL
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Use engineering controls to eliminate potential dust exposure.
SDS Date: 02 Jun 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME GAGETROL
PPE Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body Not required under normal conditions of use. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour SLIGHT ODOUR Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 9.0 to 10.5 (4 % solution) Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Skin Not classified as a skin irritant. Contact may result in mild irritation. Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation. Sensitization This product is not known to be a skin or respiratory sensitiser.
SDS Date: 02 Jun 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME GAGETROL
Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single No known effects from this product. exposure STOT – repeated No known effects from this product. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential Not expected to bioaccumulate.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal No special precautions are required for the disposal of this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)].
SDS Date: 02 Jun 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME GAGETROL
Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS Date: 02 Jun 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME GAGETROL
[ End of SDS ]
SDS Date: 02 Jun 2015 Page 6 of 6 Version No: 2.2 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name FRACSEAL FINE/MEDIUM Synonym(s) FRACSEAL F • FRACSEAL FINE • FRACSEAL M • FRACSEAL MEDIUM
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CELLULOSE 9004-34-6 232-674-9 100%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin Exposure is considered unlikely. Skin irritation is not anticipated. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to product form and application, ingestion is considered unlikely. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.
Page 1 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may form explosive mixtures with air.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Moisten with water to prevent a dust hazard and place in sealable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for damage to containers.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance YELLOW TO BROWN SOLID Odour ODOURLESS Flammability COMBUSTIBLE Flash point NOT AVAILABLE Boiling point NOT AVAILABLE Melting point 500°C to 518°C Evaporation rate NOT AVAILABLE pH 6.5 to 7.5 Vapour density NOT AVAILABLE Specific gravity 0.9 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral LD50 (rat) is > 5000 mg/kg. Dermal LD50 (rabbit) is > 2000 mg/kg. LC50 (rat) is 510 mg/m³/2 hours. Skin Not classified as a skin irritant. Eye Not classified as an eye irritant. Contact may cause mild discomfort. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity No evidence of mutagenic effects. Carcinogenicity No evidence of carcinogenic effects. Reproductive No evidence of reproductive effects. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reuse where possible. No special precautions are normally required when handling this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user
Page 4 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Page 5 of 6 SDS Date: 25 Nov 2014 PRODUCT NAME FRACSEAL FINE/MEDIUM
Revision history Revision Description 3.2 Standard SDS Review. 3.1 Standard SDS Review. 3.0 Converted to GHS. 2.0 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 3.2 SDS date: 25 November 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 25 Nov 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name FRAC ATTACK Synonym(s) FRAC-ATTACK
1.2 Uses and uses advised against Use(s) LOST CIRCULATION MATERIAL
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification(s) Skin Corrosion/Irritation: Category 2 Serious Eye Damage / Eye Irritation: Category 1 Specific Target Organ Systemic Toxicity (Single Exposure): Category 3
2.2 Label elements Signal word DANGER
Pictogram(s)
Hazard statement(s) H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. Prevention statement(s) P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Page 1 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment is advised - see first aid instructions. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before re-use. Storage statement(s) P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content CALCIUM OXIDE 1305-78-8 215-138-9 <10% CALCIUM HYDROXIDE 1305-62-0 215-137-3 <5% CRISTOBALITE 14464-46-1 238-455-4 <5% QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <3% 2-PROPENENITRILE-1,3-BUTADIENE RUBBER 9003-18-3 618-357-1 <50% NATURAL RUBBER 9006-04-6 232-689-0 <50% POLYISOPRENE 9003-31-0 618-362-9 <50% SBR ELASTOMERS 9003-55-8 618-370-2 <50% CELLULOSE 9004-34-6 232-674-9 <30% DIATOMACEOUS EARTH 61790-53-2 612-383-7 <15% FULLERS EARTH 8031-18-3 617-052-0 <12% MAGNESIUM OXIDE 1309-48-4 215-171-9 <2%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
Page 2 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium hydroxide SWA (AUS) -- 5 -- -- Calcium oxide SWA (AUS) -- 2 -- -- Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- -- Cristobalite SWA (AUS) -- 0.1 -- -- Diatomaceous earth (uncalcined) (a) SWA (AUS) -- 10 -- -- Magnesium oxide (fume) SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No biological limit values have been entered for this product.
Page 3 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance BROWN/GREY POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT RELEVANT Melting point NOT AVAILABLE Evaporation rate NON VOLATILE pH ALKALINE Vapour density NOT AVAILABLE Specific gravity 2.10 Solubility (water) NEGLIGIBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT RELEVANT
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
10.6 Hazardous decomposition products May evolve Fluorine, Oxygen Difluoride, Chlorine, Trifluoride and Hydrofluoric Acid when heated to decomposition.
Page 4 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are not met. Skin Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possible burns. Sensitization This product is not classified as causing skin or respiratory sensitisation. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficient respirable silica in this product to be classified as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, with exposure coughing. STOT – repeated Chronic exposure to crystalline silica may cause lung fibrosis (silicosis), however due to the low levels of exposure crystalline silica in this product, chronic health effects are not anticipated with normal use. Aspiration Not relevant.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
Page 5 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes.
Safety phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 6 of 7 SDS Date: 05 Feb 2015 PRODUCT NAME FRAC ATTACK
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.6 Standard SDS Review 1.5 Standard SDS Review 1.4 Standard SDS Review. 1.3 Standard SDS Review. 1.2 Standard SDS Review. 1.1 Standard SDS Review. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 05 February 2015 [ End of SDS ]
Page 7 of 7 SDS Date: 05 Feb 2015 MATERIAL SAFETY DATA SHEET
Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information Trade name : Driscal® D Polymer Material : 1112534, 1016818
Company : Drilling Specialties Company 10001 Six Pines Drive The Woodlands, TX 77380
Local : Chevron Phillips Chemicals Australia P/L Suite 409 685 Burke Road Camberwell, Victoria Australia 3124
MSDS Requests: 852-29784899 Technical Information: 61 3 8080 5700 Hours of operation: 8.30a.m - 5.00p.m.
Emergency telephone:
Health: 866.442.9628 (North America) 1.832.813.4984 (International) 61 3 8080 5700 (Australia)
Transport: North America: CHEMTREC 800.424.9300 or 703.527.3887 Asia: +800 CHEMCALL (+800 2436 2255) China: 0532.8388.9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Chemcare Asia: Tel: +65 6848 9048 - Mob: +65 8382 9188 - Fax: +65 6848 9013 South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
GHS Classification Not a dangerous substance or mixture according to the Globally Harmonized System (GHS).
MSDS Number:100000066569 1/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
GHS-Labeling Not a dangerous substance or mixture according to the Globally Harmonized System (GHS).
SECTION 3: Composition/information on ingredients
Synonyms : High Temperature Polymer
Molecular formula : Mixture
Contains no hazardous ingredients according to GHS. :
Remarks : Contains no hazardous ingredients according to GHS.
SECTION 4: First aid measures
General advice : No hazards which require special first aid measures.
If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : Not applicable
Autoignition temperature : No data available
Special protective : Wear self contained breathing apparatus for fire fighting if equipment for fire-fighters necessary.
Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Fire and explosion : Provide appropriate exhaust ventilation at places where dust is protection formed.
Hazardous decomposition : No data available. products
SECTION 6: Accidental release measures
MSDS Number:100000066569 2/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
Personal precautions : Avoid dust formation.
Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
SECTION 7: Handling and storage
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area.
Advice on protection : Provide appropriate exhaust ventilation at places where dust is against fire and explosion formed.
Storage
Requirements for storage : Electrical installations / working materials must comply with the areas and containers technological safety standards.
Advice on common storage : No materials to be especially mentioned.
SECTION 8: Exposure controls/personal protection
Engineering measures Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a supplied-air NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure.
Hand protection : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Safety glasses. Eye wash bottle with pure water.
MSDS Number:100000066569 3/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : General industrial hygiene practice.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties Appearance Form : Powder Physical state : Solid Color : White Odor : No odor
Safety data Flash point : Not applicable
Lower explosion limit : No data available
Upper explosion limit : No data available
Oxidizing properties : no
Autoignition temperature : No data available
Molecular formula : Mixture
Molecular Weight : Not applicable
pH : Not applicable
Pour point : No data available
Boiling point/boiling range : No data available
Vapor pressure : No data available
Relative density : 1,44
Water solubility : Soluble
Partition coefficient: n- : POW: < 3 octanol/water Viscosity, kinematic : No data available
Relative vapor density : No data available
Evaporation rate : No data available
SECTION 10: Stability and reactivity
MSDS Number:100000066569 4/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
Chemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions Conditions to avoid : No data available.
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Driscal® D Polymer Acute oral toxicity : LD50: not known
Driscal® D Polymer Acute inhalation toxicity : LC50: not known
Driscal® D Polymer Acute dermal toxicity : LD50: not known
Driscal® D Polymer Skin irritation : No skin irritation
Driscal® D Polymer Eye irritation : No eye irritation
Driscal® D Polymer Aspiration toxicity : No aspiration toxicity classification.
Driscal® D Polymer Further information : No data available.
SECTION 12: Ecological information
Ecotoxicity effects
Toxicity to fish : LC50: > 1.800 mg/l Exposure time: 96 h Species: Scophthalmus maximus (Flatfish, Flounder)
Toxicity to daphnia and : > 10000 MG/KG other aquatic invertebrates Exposure time: 10 Days Species: Corophium spp (Sediment Reworker)
Toxicity to bacteria : EC50: 2.859 mg/l Exposure time: 72 h Species: Skeletonema costatum (Marine Algae)
Elimination information (persistence and degradability)
MSDS Number:100000066569 5/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
Biodegradability : This material is not expected to be readily biodegradable.
Additional ecological : No data available information
SECTION 13: Disposal considerations
The information in this MSDS pertains only to the product as shipped. Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14: Transport information The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the MSDS and the bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. MSDS Number:100000066569 6/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
Major Accident Hazard : 96/82/EC Update: 2003 Legislation Directive 96/82/EC does not apply
National legislation Standard for the Uniform : No poison schedule number allocated Scheduling of Medicines and Poisons
Notification status Europe REACH : On the inventory, or in compliance with the inventory United States of America US.TSCA : On TSCA Inventory Canada DSL : All components of this product are on the Canadian DSL list. Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : Not in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : On the inventory, or in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory
SECTION 16: Other information
NFPA Classification : Health Hazard: 0 Fire Hazard: 1 Reactivity Hazard: 0 1
0 0
MSDS Number:100000066569 7/8
MATERIAL SAFETY DATA SHEET Driscal® D Polymer Version 1.5 Revision Date 2012-10-31
Further information Legacy MSDS Number : 244990
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions.
The information in this MSDS pertains only to the product as shipped. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of LD50 Lethal Dose 50% Government Industrial Hygienists AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect Substances Level DSL Canada, Domestic Substances NFPA National Fire Protection Agency List NDSL Canada, Non-Domestic NIOSH National Institute for Occupational Substances List Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health Scenario Tool Administration EOSCA European Oilfield Specialty PEL Permissible Exposure Limit Chemicals Association EINECS European Inventory of Existing PICCS Philippines Inventory of Chemical Substances Commercial Chemical Substances MAK Germany Maximum Concentration PRNT Presumed Not Toxic Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act. IARC International Agency for Research TLV Threshold Limit Value on Cancer IECSC Inventory of Existing Chemical TWA Time Weighted Average Substances in China ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act New Chemical Substances KECI Korea, Existing Chemical UVCB Unknown or Variable Composition, Inventory Complex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50%
MSDS Number:100000066569 8/8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name DIRT MAGNET Synonym(s) DIRT MAGNET E
1.2 Uses and uses advised against Use(s) SOLVENT • SURFACTANT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS GHS classification(s) Serious Eye Damage / Eye Irritation: Category 1 Aquatic Toxicity (Chronic): Category 2 Flammable Liquids: Category 4 Skin Corrosion/Irritation: Category 2 Acute Toxicity: Oral: Category 4
2.2 Label elements Signal word DANGER
Pictogram(s)
Hazard statement(s) H227 Combustible liquid. H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects. Prevention statement(s) P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.
SDS Date: 02 Jun 2015 Page 1 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment is advised - see first aid instructions. P330 Rinse mouth. P362 Take off contaminated clothing and wash before re-use. P370 + P378 In case of fire: Use appropriate media for extinction. P391 Collect spillage. Storage statement(s) P403 + P235 Store in a well-ventilated place. Keep cool. Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content COCONUT DIETHANOLAMIDE 68603-42-9 271-657-0 30 to 60% DIETHANOLAMINE 111-42-2 203-868-0 1 to 6% NON HAZARDOUS INGREDIENTS Not Available Not Available Remainder
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. May evolve ammonia and nitrogen oxides when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
SDS Date: 02 Jun 2015 Page 2 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
5.4 Hazchem code •3Z •3 Alcohol Resistant Foam is the preferred firefighting medium but, if it is not available, normal foam can be used. Z Wear full fire kit and breathing apparatus. Contain spill and run-off.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should have appropriate ventilation systems.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Diethanolamine (h) SWA (AUS) 3 13 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. In a laboratory situation, wear a laboratory coat. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
SDS Date: 02 Jun 2015 Page 3 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance AMBER LIQUID Odour SLIGHT ODOUR Flammability CLASS C1 COMBUSTIBLE Flash point 82°C Boiling point > 80°C Melting point < 0°C Evaporation rate NOT AVAILABLE pH 9 - 10 Vapour density NOT AVAILABLE Specific gravity 0.924 Solubility (water) EMULSIFIES Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Information available for the product: Harmful if swallowed, in contact with skin, and/or if inhaled. Information available for the ingredient(s):
Oral Toxicity Dermal Toxicity Inhalation Toxicity Ingredient (LD50) (LD50) (LC50) DIETHANOLAMINE 620 uL/kg (rat) 7640 uL/kg (rabbit) --
SDS Date: 02 Jun 2015 Page 4 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
Additional ingredient toxicity value(s): DIETHANOLAMINE (111-42-2) LD50 (intramuscular) 1500 mg/kg (rat) LD50 (intraperitoneal) 120 mg/kg (rat) LD50 (intravenous) 778 mg/kg (rat) LD50 (subcutaneous) 2200 mg/kg (rat) LDLo (oral) 3 g/kg (rat) Skin Irritating to the skin. Contact may result in irritation, redness, rash and dermatitis. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single May cause respiratory irritation. Over exposure to vapours may result in irritation of the nose and throat, with exposure coughing. High level exposure may result in breathing difficulties. STOT – repeated Not expected to cause organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Brachydario rerio 96hr LC50 3.6mg/L, Daphnia pulex 48hr EC50 2.39mg/L, Scenedesmus subspicatus 72hr EC50 2.2mg/L.
12.2 Persistence and degradability (OECD 301D) 46%.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil Insoluble in water.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For large quantities, contact the manufacturer/supplier for additional information. Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
SDS Date: 02 Jun 2015 Page 5 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number 3082 3082 3082 14.2 Proper ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY Shipping Name HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE, LIQUID, N.O.S. LIQUID, N.O.S. LIQUID, N.O.S.
14.3 Transport 9 9 9 hazard class 14.4 Packing Group III III III 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code •3Z GTEPG 9C1 EMS F-A, S-F
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes N Dangerous for the environment Xi Irritant Xn Harmful Risk phrases R22 Harmful if swallowed. R38 Irritating to skin. R41 Risk of serious damage to eyes. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.
Safety phrases S23 Do not breathe gas/fumes/vapour/spray (where applicable). S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S38 In case of insufficient ventilation, wear suitable respiratory equipment. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
SDS Date: 02 Jun 2015 Page 6 of 7 Version No: 2.3 PRODUCT NAME DIRT MAGNET
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 02 Jun 2015 Page 7 of 7 Version No: 2.3 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name DEFOAM AP 400 Synonym(s) DEFOAMER
1.2 Uses and uses advised against Use(s) DEFOAM IN DRILLING FLUIDS
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk POLYETHYLENE GLYCOL CAS: 25322-68-3 Not Available Not Available 45 to 60% EC: 500-038-2 OCTAN-2-OL CAS: 123-96-6 Not Available Not Available 40 to 55% EC: 204-667-0
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
Page 1 of 6 SDS Date: 20 Aug 2014 PRODUCT NAME DEFOAM AP 400
First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
Page 2 of 6 SDS Date: 20 Aug 2014 PRODUCT NAME DEFOAM AP 400
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CLEAR COLOURLESS LIQUID Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 7 to 8 (5% solution) Vapour density NOT AVAILABLE Specific gravity 1.00 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
Page 3 of 6 SDS Date: 20 Aug 2014 PRODUCT NAME DEFOAM AP 400
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard Low toxicity - low irritant. This product has the potential to irritate mucous membranes. Use safe work summary practices to avoid eye or skin contact and inhalation. Due to the low vapour pressure of this product, an inhalation hazard is not anticipated with normal use. Chronic exposure to some glycols may result in liver and kidney damage. Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Toxicity data POLYETHYLENE GLYCOL (25322-68-3) LD50 (ingestion) 33750 mg/kg (rat)
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects ATMOSPHERE: Vapour phase glycols are expected to degrade fairly rapidly by reaction with hydroxyl radicals (eg half-life 32 hours for propylene glycol). Removal from air by rainfall is possible. WATER: Should degrade relatively rapidly via biodegradation. SOIL: If released to soil, relatively rapid biodegradation should also occur. Leaching to groundwater may occur.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For larger amounts, contact the manufacturer for additional information. Prevent contamination of drains or waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
Page 4 of 6 SDS Date: 20 Aug 2014 PRODUCT NAME DEFOAM AP 400
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACE EXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 20 Aug 2014 PRODUCT NAME DEFOAM AP 400
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 1.0 Initial SDS Creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1 SDS date: 20 August 2014 [ End of SDS ]
Page 6 of 6 SDS Date: 20 Aug 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name DEFOAM A (I) Synonym(s) DEFOAM-A (I)
1.2 Uses and uses advised against Use(s) COMPLETION FLUID • DRILLING FLUID
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS GHS classification(s) Skin Corrosion/Irritation: Category 2 Specific Target Organ Systemic Toxicity (Single Exposure): Category 3 Flammable Liquids: Category 4 Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H227 Combustible liquid. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Prevention statement(s) P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection.
SDS Date: 13 Apr 2015 Page 1 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment is advised - see first aid instructions. P332 + P337 + P313 If skin or eye irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before re-use. P370 + P378 In case of fire: Use appropriate media for extinction. Storage statement(s) P403 + P233 + P235 Store in a well-ventilated place. Keep cool. Keep container tightly closed. P405 Store locked up. Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content OCTAN-2-OL 123-96-6 204-667-0 >98%
WATER 7732-18-5 231-791-2 Remainder
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
SDS Date: 13 Apr 2015 Page 2 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Eliminate all sources of ignition.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should have appropriate ventilation systems. Store as a Class C1 Combustible Liquid (AS1940).
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear splash-proof goggles. Hands Wear nitrile or neoprene gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
SDS Date: 13 Apr 2015 Page 3 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance CLEAR LIQUID Odour SLIGHT ODOUR Flammability CLASS C1 COMBUSTIBLE Flash point 88°C (cc) Boiling point 180°C Melting point -39°C Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density 4.5 (Air = 1) Specific gravity 0.87 Solubility (water) INSOLUBLE Vapour pressure 1 mm Hg @ 33°C Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles 100 %
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure. summary Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in central nervous system (CNS) effects. Eye Irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Irritant. Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposure may result in nausea, dizziness and drowsiness. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. Ingestion May be harmful. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, dizziness and drowsiness. Aspiration or inhalation may cause chemical pneumonitis and pulmonary oedema. Toxicity data No LD50 data available for this product.
SDS Date: 13 Apr 2015 Page 4 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
12. ECOLOGICAL INFORMATION
12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Incinerate where available. For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Xn Harmful Risk phrases R36/37/38 Irritating to eyes, respiratory system and skin. R67 Vapours may cause drowsiness and dizziness.
Safety phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36 Wear suitable protective clothing.
SDS Date: 13 Apr 2015 Page 5 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
WORK PRACTICES - SOLVENTS: Organic solvents may present both a health and flammability hazard. It is recommended that engineering controls should be adopted to reduce exposure where practicable (for example, if using indoors, ensure explosion proof extraction ventilation is available). Flammable or combustible liquids with explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The control of undesirable static electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for control procedures.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
SDS Date: 13 Apr 2015 Page 6 of 7 Version No: 2.1 PRODUCT NAME DEFOAM A (I)
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 13 Apr 2015 Page 7 of 7 Version No: 2.1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name CITRIC ACID Synonym(s) 2-HYDROXY-1,2,3-PROPANETRICARBOXYLIC ACID • CITRIC ACID ANHYDROUS • CITRIC ACID MONOHYDRATE
1.2 Uses and uses advised against Use(s) INDUSTRIAL APPLICATIONS
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Skin Corrosion/Irritation: Category 2 Serious Eye Damage / Eye Irritation: Category 2A Specific Target Organ Systemic Toxicity (Single Exposure): Category 3
2.2 Label elements Signal word WARNING
Pictograms
Hazard statement(s) H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Prevention statement(s) P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Page 1 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
Response statement(s) P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTRE or doctor/physician if you feel unwell. P321 Specific treatment is advised - see first aid instructions. P362 Take off contaminated clothing and wash before re-use. Storage statement(s) P403 + P233 Store in a well-ventilated place. Keep container tightly closed (applies if the substance is volatile so as to generate a hazardous atmosphere). P405 Store locked up. Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk CITRIC ACID CAS: 77-92-9 Not Available Not Available >99% EC: 201-069-1 WATER CAS: 7732-18-5 Not Available Not Available <1% EC: 231-791-2
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
4.2 Most important symptoms and effects, both acute and delayed Acute: Irritating to the eyes and skin. Delayed: No information available.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
Page 2 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8. Ventilate area where possible.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE CRYSTALLINE POWDER Odour ODOURLESS Flammability COMBUSTIBLE Flash point 174°C Boiling point 175°C (Decomposes) Melting point 153°C Evaporation rate NOT AVAILABLE pH 2.2 (0.1M Solution)
Page 3 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
9.1 Information on basic physical and chemical properties Vapour density NOT AVAILABLE Specific gravity 1.665 Solubility (water) 1330 kg/m³ @ 20°C Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature 345°C Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites) and alkalis (eg. sodium hydroxide).
10.6 Hazardous decomposition products May evolve carbon oxides and hydrocarbons when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Oral Toxicity: LD50: 3000 mg/kg (rat). Inhalation Toxicity: No reliable data available. Dermal Toxicity: No reliable data available. Skin Classified as irritating to the skin. Contact may result in irritation, redness, rash and dermatitis. Eye Classified as irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization This product is not classified as causing skin or respiratory sensitisation. However, citric acid has the potential to cause allergic effects. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, with exposure coughing. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
Page 4 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects WATER: If citric acid is released to water, it is expected to biodegrade rapidly. May be toxic to fish at moderately high levels (120 ppm is fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which may cause oxygen depletion in large spills. Citric acid occurs naturally in many plants.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Neutralise with lime, anion exchanger or similar. For small amounts absorb with sand or similar and dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R36/37/38 Irritating to eyes, respiratory system and skin. Safety phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S37/39 Wear suitable gloves and eye/face protection. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
Page 5 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
16. OTHER INFORMATION
Additional information PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Page 6 of 7 SDS Date: 20 Aug 2014 PRODUCT NAME CITRIC ACID
Revision: 2 SDS date: 20 August 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 20 Aug 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name CAUSTIC SODA Synonym(s) SODA LYE • SODIUM HYDROXIDE SOLID
1.2 Uses and uses advised against Use(s) MANUFACTURE OF CHEMICALS • REAGENT • SCRUBBING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Skin Corrosion/Irritation: Category 1A
2.2 Label elements Signal word DANGER
Pictograms
Hazard statement(s) H314 Causes severe skin burns and eye damage. Prevention statement(s) P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P321 Specific treatment is advised - see first aid instructions. P363 Wash contaminated clothing before reuse. Storage statement(s) P405 Store locked up.
Page 1 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content GHS Risk SODIUM HYDROXIDE CAS: 1310-73-2 Skin Corr. 1A, H314 C;R35 >98% EC: 215-185-5 SILICA, AMORPHOUS CAS: 7631-86-9 Not Available Not Available 0.003% EC: 231-545-4
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator where an inhalation risk exists. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed Causes severe skin burns and eye damage.
4.3 Immediate medical attention and special treatment needed CORROSIVE POISONING TREATMENT: Immediate treatment preferably in a hospital is mandatory. In treating corrosive poisoning, DO NOT INDUCE VOMITING; DO NOT ATTEMPT GASTRIC LAVAGE; and DO NOT ATTEMPT TO NEUTRALISE THE CORROSIVE SUBSTANCE. Vomiting will increase the severity of damage to the oesophagus as the corrosive substance will again come in contact with it. Attempting gastric lavage may result in perforating either the oesophagus or stomach. Immediately dilute the corrosive substance by having the patient drink milk or water. If the trachea has been damaged tracheostamy may be required. For oesophageal burns begin broad-spectrum antibiotics and corticosteroid therapy. Intravenous fluids will be required if oesophageal or gastric damage prevents ingestion of liquids. Long-range therapy will be directed toward preventing or treating oesophageal scars and strictures.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (nitrogen oxides). May evolve flammable ammonia and hydrogen gas if strongly heated.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code 2X 2 Water Fog (or fine water spray if fog unavailable) X Full protective clothing including Self Contained Breathing apparatus.
Page 2 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems. Store between 15°C and 25°C. Unsuitable storage containers: aluminium, tin or zinc.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Fumed silica (respirable dust) SWA (AUS) -- 2 -- -- Sodium hydroxide (peak limitation) SWA (AUS) -- 2 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear a faceshield and dust-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls and rubber boots and a PVC apron. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear an Air-line respirator or a Full-face Class P3 (Particulate) respirator.
Page 3 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance WHITE DELIQUESCENT PEARLS Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 1390°C Melting point 318°C Evaporation rate NOT AVAILABLE pH 13.5 (1 % solution) Vapour density NOT AVAILABLE Specific gravity 2.12 Solubility (water) 1110 kg/m³ @ 20°C Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), metals, heat and ignition sources.
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are not met. Skin Causes severe burns. Contact may result in irritation, redness, pain, rash, dermatitis and possible burns. Eye Causes severe burns. Contact may result in irritation, lacrimation, pain, redness and corneal burns with possible permanent damage. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in exposure breathing difficulties.
Page 4 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site. Contact the manufacturer for additional information. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number 1823 1823 1823 14.2 Proper SODIUM HYDROXIDE, SOLID SODIUM HYDROXIDE, SOLID SODIUM HYDROXIDE, SOLID Shipping Name
14.3 Transport 8 8 8 hazard class 14.4 Packing Group II II II 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code 2X GTEPG 8A1 EMS F-A, S-B
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Page 5 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes C Corrosive Risk phrases R35 Causes severe burns. Safety phrases S1/2 Keep locked up and out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S37/39 Wear suitable gloves and eye/face protection. S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACE EXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 6 of 7 SDS Date: 19 Aug 2014 PRODUCT NAME CAUSTIC SODA
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2 SDS date: 19 August 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 19 Aug 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name CALCIUM CARBONATE Synonym(s) ABGRIT • CIRCAL • LIMESTONE • MARBLE • OMYACAL • OMYACARB • RHEOCARB • STONEDUST
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • WEIGHTING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA 2.2 Label elements No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <1% CALCIUM CARBONATE 471-34-1 207-439-9 >96%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities No information provided.
Page 1 of 6 SDS Date: 07 Jan 2015 PRODUCT NAME CALCIUM CARBONATE
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters No fire or explosion hazard exists.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up If spilt, collect and reuse where possible. Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No Biological Limit Value allocated.
Page 2 of 6 SDS Date: 07 Jan 2015 PRODUCT NAME CALCIUM CARBONATE
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Eye / Face Wear dust-proof goggles. Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 840°C (Decomposes) Melting point 825°C Evaporation rate NOT AVAILABLE pH 9 Vapour density NOT AVAILABLE Specific gravity 2.7 Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization will not occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts. Incompatible with oxidising agents (e.g. hypochlorites).
Page 3 of 6 SDS Date: 07 Jan 2015 PRODUCT NAME CALCIUM CARBONATE
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. LD50 (Ingestion) = 6450 mg/kg (rat). Skin Not classified as a skin irritant. Contact may result in mild irritation, redness and rash. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization This product is not known to be a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Insufficient data available to classify as a carcinogen. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Not classified as causing organ effects from repeated exposure. Chronic exposure to respirable silica may exposure result in pulmonary fibrosis (silicosis). However, given the low levels present, over exposure is not anticipated. Aspiration This product does not present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects.
12.2 Persistence and degradability Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle.
12.3 Bioaccumulative potential This product does not bioaccumulate.
12.4 Mobility in soil Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
12.5 Other adverse effects Avoid contamination of waterways.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Council landfill. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
Page 4 of 6 SDS Date: 07 Jan 2015 PRODUCT NAME CALCIUM CARBONATE
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes None allocated. Risk phrases None allocated. Safety phrases None allocated. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. If not used in a closed system, local exhaust ventilation is recommended to control exposure. Provide eye wash and safety shower in close proximity to points of potential exposure. Where the potential for an inhalation risk exists, an approved respirator may be required. Do not eat, store, consume food, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 5 of 6 SDS Date: 07 Jan 2015 PRODUCT NAME CALCIUM CARBONATE
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.2 Standard SDS Review Standard SDS Review 2.1 Standard SDS Review. 2.0 Converted to GHS. 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2.2 SDS date: 07 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 07 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name BENTONITE POWDER / RHEOBEN Synonym(s) BENTONITE (API 13A SECTION 9) • NEWGEL • RHEOBEN
1.2 Uses and uses advised against Use(s) DRILLING FLUID
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification(s) Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H373 May cause damage to organs through prolonged or repeated exposure. Prevention statement(s) P260 Do not breathe dust/fume/gas/mist/vapours/spray. Response statement(s) P314 Get medical advice/attention if you feel unwell. Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
Page 1 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME BENTONITE POWDER / RHEOBEN
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 2 to 10% BENTONITE 1302-78-9 215-108-5 90 to 98% SODA ASH - - 2 to 4%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due to product form and application, ingestion is considered unlikely. First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed Chronic exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing and breathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases if strongly heated.
5.3 Advice for firefighters Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Moisten with water to prevent a dust hazard and place in sealable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
Page 2 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME BENTONITE POWDER / RHEOBEN
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packaging are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance BROWN POWDER Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT RELEVANT Melting point 1100°C to 1200°C (Fusion Point) Evaporation rate NOT RELEVANT pH NOT RELEVANT Vapour density NOT RELEVANT Specific gravity 2.7 Solubility (water) INSOLUBLE Vapour pressure NOT RELEVANT Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT RELEVANT Autoignition temperature NOT RELEVANT Decomposition temperature NOT RELEVANT Viscosity NOT RELEVANT Explosive properties NOT EXPLOSIVE Oxidising properties NON OXIDISING Odour threshold NOT RELEVENT
Page 3 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME BENTONITE POWDER / RHEOBEN
9.2 Other information Bulk density ~ 0.9 kg/L
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).
10.6 Hazardous decomposition products May evolve toxic gases if heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are not met. Skin Not classified as a skin irritant. Contact may result in mild irritation and dermatitis. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization The available data is not considered sufficient for classification as a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1). However there is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis. Therefore preventing the onset of silicosis will also reduce the cancer risk. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodular exposure lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principal symptoms of silicosis are coughing and breathlessness. Aspiration This product is not expected to present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity No information provided.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects The main component/s of this product are not anticipated to cause any adverse effects to plants or animals.
Page 4 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME BENTONITE POWDER / RHEOBEN
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reuse where possible. No special precautions are normally required when handling this product. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xn Harmful Risk phrases R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Safety phrases S22 Do not breathe dust. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: Strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
Page 5 of 6 SDS Date: 29 Jan 2015 PRODUCT NAME BENTONITE POWDER / RHEOBEN
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.1 Included bulk density. 2.0 Converted to GHS. 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 2.1 SDS date: 29 January 2015 [ End of SDS ]
Page 6 of 6 SDS Date: 29 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name BARITE POWDER Synonym(s) BARITE (API 13A SECTION 7) • NEWBAR • RHEOBAR
1.2 Uses and uses advised against Use(s) DRILLING FLUID ADDITIVE • WEIGHTING AGENT
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification(s) Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H373 May cause damage to organs through prolonged or repeated exposure. Prevention statement(s) P260 Do not breathe dust/fume/gas/mist/vapours/spray. Response statement(s) P314 Get medical advice/attention if you feel unwell. Storage statement(s) None allocated.
Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
Page 1 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content QUARTZ (CRYSTALLINE SILICA) 14808-60-7 238-878-4 <3% BARIUM SULPHATE 7727-43-7 231-784-4 >89%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities should be available.
4.2 Most important symptoms and effects, both acute and delayed Chronic exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing and breathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
Page 2 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Barium sulphate SWA (AUS) -- 10 -- -- Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
Biological limits No Biological Limit Value allocated.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.
PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance OFF-WHITE POWDER Odour ODOURLESS Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT RELEVANT Melting point > 1300°C Evaporation rate NOT RELEVANT pH 8.2 (20% Slurry) Vapour density NOT RELEVANT Specific gravity 4.20 Solubility (water) INSOLUBLE Vapour pressure NOT RELEVANT Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT RELEVANT Autoignition temperature NOT RELEVANT Decomposition temperature NOT RELEVANT Viscosity NOT RELEVANT
Page 3 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
9.1 Information on basic physical and chemical properties Explosive properties NOT EXPLOSIVE Oxidising properties NON OXIDISING Odour threshold NOT RELEVENT 9.2 Other information Bulk density ~1.5 kg/L
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites).
10.6 Hazardous decomposition products May evolve toxic gases (sulphur oxides) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are not met. Skin Not classified as a skin irritant. Contact may result in mild irritation and dermatitis. Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. Sensitization The available data is not considered sufficient for classification as a skin or respiratory sensitiser. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1). However there is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis. Therefore preventing the onset of silicosis will also reduce the cancer risk. Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Not classified as causing organ effects from single exposure. exposure STOT – repeated Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodular exposure lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principal symptoms of silicosis are coughing and breathlessness. Aspiration This product is not expected to present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity Fish toxicity: LC50 (Rainbow trout) = 7500 ppm/96 hour.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
Page 4 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
12.5 Other adverse effects This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xn Harmful Risk phrases R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Safety phrases S22 Do not breathe dust. S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
Page 5 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 2.2 Included bulk density. 2.1 Amended Product Name and Synonyms. 2.0 Converted to GHS. 1.1 Standard SDS Review 1.0 Initial SDS creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Page 6 of 7 SDS Date: 29 Jan 2015 PRODUCT NAME BARITE POWDER
Revision: 2.2 SDS date: 29 January 2015 [ End of SDS ]
Page 7 of 7 SDS Date: 29 Jan 2015 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name AVAPERM NF Synonym(s) F003132 - SDS CODE
1.2 Uses and uses advised against Use(s) INHIBITOR IN DRILLING FLUIDS
1.3 Details of the supplier of the safety data sheet Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA GHS classification Acute Toxicity: Oral: Category 4 Acute Toxicity: Skin: Category 4 Skin Corrosion/Irritation: Category 2 Serious Eye Damage / Eye Irritation: Category 2A Specific Target Organ Systemic Toxicity (Single Exposure): Category 3
2.2 Label elements Signal word WARNING
Pictograms
Hazard statement(s) H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Prevention statement(s) P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Page 1 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
Response statement(s) P301 + P312 IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment is advised - see first aid instructions. P330 Rinse mouth. P332 + P337 + P313 If skin or eye irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before re-use. Storage statement(s) P403 + P233 Store in a well-ventilated place. Keep container tightly closed (applies if the substance is volatile so as to generate a hazardous atmosphere). P405 Store locked up. Disposal statement(s) P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient Identification Classification Content HYDROGENATED HEXANEDINITRILE Not Available 35 to 70% CHLORIDE WATER CAS: 7732-18-5 30 to 65% EC: 231-791-2
Ingredient Notes This product is mixture of 30-50% Hexanedinitrile, 5-20% Hydrochloric acid (as pH corrector) and water. Hydrochloric acid is used to neutralise hexanedinitrile to become the salt with slightly alkali (pH 9-11).
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities and safety shower are recommended.
4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to decomposition.
Page 2 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in Section 8 of this SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards No exposure standards have been entered for this product.
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Page 3 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance LIQUID Odour PUNGENT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point 100°C (Approximately) Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH 9 to 10 Vapour density NOT AVAILABLE Specific gravity 1.00 to 1.10 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Hazardous polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Incompatible with Isocyanates, aldehydes, ketones, anhydrides, phenols, nitrates, halogenated compounds.
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Health hazard Harmful - irritant. This product has the potential to cause adverse health effects with over exposure. Use summary safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in irritation to the eyes, skin and respiratory system. Eye Irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Irritant. Over exposure to vapours may result in respiratory irritation, nausea, dizziness and headache. High level exposure may result in drowsiness and breathing difficulties. Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. Ingestion Harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain, diarrhoea, headache, dizziness and drowsiness with large quantities. Toxicity data No LD50 data available for this product.
Page 4 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
12. ECOLOGICAL INFORMATION
12.1 Toxicity This product is registered on Offshore Chemical Notification Scheme Gold, Gold, Gold for HQ Band 17.5", 12.25" and 8.5" respectively.
12.2 Persistence and degradability No information provided.
12.3 Bioaccumulative potential No information provided.
12.4 Mobility in soil No information provided.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. For larger amounts, contact the manufacturer for additional information. Prevent contamination of drains or waterways as aquatic life may be threatened and environmental damage may result. Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN number None Allocated None Allocated None Allocated 14.2 UN proper shipping name None Allocated None Allocated None Allocated 14.3 Transport hazard classes DG class None Allocated None Allocated None Allocated Subsidiary risk(s) None Allocated None Allocated None Allocated 14.4 Packing group None Allocated None Allocated None Allocated 14.5 Environmental hazards None Allocated 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Xi Irritant Xn Harmful Risk phrases R21/22 Harmful in contact with skin and if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. Safety phrases S1/2 Keep locked up and out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
Page 5 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt. EUROPE:EINECS (European Inventory of Existing Chemical Substances) All components are listed on EINECS, or are exempt.
16. OTHER INFORMATION
Additional information The manufacturer indicates the product is mixture of 30-50% Hexanedinitrile, 5-20% Hydrochloric acid (as pH corrector) and water. Hydrochloric acid is used to neutralise hexanedinitrile to become the salt with slightly alkali (pH 9-11).
AMINE: CAUTION THIS PRODUCT CONTAINS AN AMINE. DO NOT ADD NITRITES or other NITROSATING AGENTS to this product due to the potential for NITROSAMINE formation. Nitrosamines are potent carcinogens and some have been shown to cause severe acute (heart, brain, blood, liver - kidney) damage as well as chronic effects (reproductive effects, liver - lung and kidney tumours).
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACE EXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Page 6 of 7 SDS Date: 08 Apr 2014 PRODUCT NAME AVAPERM NF
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number GHS Globally Harmonized System IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit PEL Permissible Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Revision history Revision Description 1.0 Initial SDS Creation
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Revision: 1 SDS date: 08 April 2014 [ End of SDS ]
Page 7 of 7 SDS Date: 08 Apr 2014 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name ANCOR 1 Synonym(s) CORROSION INHIBITOR
1.2 Uses and uses advised against Use(s) BRINE • CORROSION INHIBITOR • DRILLING FLUID ADDITIVE • OIL AND GAS INDUSTRY
1.3 Details of the supplier of the product Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA Telephone +61 8 9410 8200 Fax +61 8 9410 8299 Website www.newpark.com
1.4 Emergency telephone number(s) Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS GHS classification(s) Serious Eye Damage / Eye Irritation: Category 2A
2.2 Label elements Signal word WARNING
Pictogram(s)
Hazard statement(s) H319 Causes serious eye irritation. Prevention statement(s) P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response statement(s) P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. Storage statement(s) None allocated.
Disposal statement(s) None allocated.
2.3 Other hazards No information provided.
SDS Date: 06 May 2015 Page 1 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures Ingredient CAS Number EC Number Content TRIETHANOLAMINE 102-71-6 203-049-8 68 to 72% NON HAZARDOUS INGREDIENTS Not Available Not Available 28 to 32%
4. FIRST AID MEASURES
4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting. First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.
4.3 Immediate medical attention and special treatment needed Treat symptomatically.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.
5.2 Special hazards arising from the substance or mixture Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code None allocated.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area where possible. Contact emergency services where appropriate.
6.2 Environmental precautions Prevent product from entering drains and waterways.
6.3 Methods of cleaning up Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal.
6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
SDS Date: 06 May 2015 Page 2 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills. Store as a Class C1 Combustible Liquid (AS1940).
7.3 Specific end use(s) No information provided.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters Exposure standards TWA STEL Ingredient Reference ppm mg/m³ ppm mg/m³ Triethanolamine SWA (AUS) -- 5 -- --
Biological limits No biological limit values have been entered for this product.
8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE Eye / Face Wear splash-proof goggles. Hands Wear PVC or rubber gloves. Body Wear coveralls. Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties Appearance COLOURLESS LIQUID Odour SLIGHT ODOUR Flammability CLASS C1 COMBUSTIBLE Flash point > 100°C Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity 1.1 Solubility (water) SOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT AVAILABLE Lower explosion limit NOT AVAILABLE Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE
SDS Date: 06 May 2015 Page 3 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
9.1 Information on basic physical and chemical properties Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE 9.2 Other information % Volatiles NOT AVAILABLE
10. STABILITY AND REACTIVITY
10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.
10.2 Chemical stability Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions Hazardous polymerization is not expected to occur.
10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), nitrites, heat and ignition sources.
10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. Toxicity Data available for the ingredient: TRIETHANOLAMINE (102-71-6): LD50 (Ingestion): 2200 mg/kg (rabbit) LD50 (Intraperitoneal): 1450 mg/kg (mouse) LD50 (Skin): > 20 mL/kg (rabbit) TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer) Skin Contact may result in mild irritation, redness, pain and rash. Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact. Sensitization Triethanolamine has been reported to cause allergic contact dermatitis. It is not known to cause respiratory sensitisation. Mutagenicity Insufficient data available to classify as a mutagen. Carcinogenicity Triethanolamine is not classifiable as to its carcinogenicity to humans (IARC Group 3). Reproductive Insufficient data available to classify as a reproductive toxin. STOT – single Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in exposure breathing difficulties. STOT – repeated Not classified as causing organ effects from repeated exposure. exposure Aspiration This product is not expected to present an aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1 Toxicity LC50 (shrimp): > 100 ppm.
12.2 Persistence and degradability In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks).
12.3 Bioaccumulative potential Not expected to bioaccumulate.
SDS Date: 06 May 2015 Page 4 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
12.4 Mobility in soil In soil, residual triethanolamine may leach to groundwater.
12.5 Other adverse effects No information provided.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid. Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT (ADG) (IMDG / IMO) (IATA / ICAO)
14.1 UN Number None Allocated None Allocated None Allocated 14.2 Proper None Allocated None Allocated None Allocated Shipping Name
14.3 Transport None Allocated None Allocated None Allocated hazard class 14.4 Packing Group None Allocated None Allocated None Allocated 14.5 Environmental hazards No information provided 14.6 Special precautions for user Hazchem code None Allocated
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals. The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous Substances [NOHSC: 1008(2004)]. Hazard codes Xi Irritant Risk phrases R36 Irritating to eyes. Safety phrases S36 Wear suitable protective clothing. Inventory listing(s) AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.
16. OTHER INFORMATION
Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.
SDS Date: 06 May 2015 Page 5 of 6 Version No: 2.2 PRODUCT NAME ANCOR 1
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average
Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au. [ End of SDS ]
SDS Date: 06 May 2015 Page 6 of 6 Version No: 2.2
MATERIAL SAFETY DATA SHEET Product Trade Name: WellLife™ 734
Revision Date: 12-Apr-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 New Zealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: WellLife™ 734 Synonyms: None Chemical Family: Inorganic UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Enhancer
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Contains no hazardous Mixture 60 - 100% Not applicable Not applicable Not applicable substances WellLife™ 734 Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview No significant hazards expected.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation Under normal conditions, first aid procedures are not required.
Skin Under normal conditions, first aid procedures are not required.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Not applicable.
Special Protective Equipment for Not applicable. Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary None known. Measures
Procedure for Cleaning / Scoop up and remove. Absorption
7. HANDLING AND STORAGE
Handling Precautions Material is slippery underfoot. Keep floors clean of spills.
Storage Information Store in a dry location. Product has a shelf life of 60 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls None known.
Respiratory Protection Not normally necessary.
WellLife™ 734 Page 2 of 6 Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: White to Variable Odor: Odorless pH: Not Determined Specific Gravity @ 20 C (Water=1): 2.6 Density @ 20 C (kg/l): 2.48 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): 1200 Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to None known. Avoid)
Hazardous Decomposition None known. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
WellLife™ 734 Page 3 of 6 Sympotoms related to exposure Inhalation None known.
Skin Contact None known.
Eye Contact May cause mechanical irritation to eye.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Draize Rating (Eye): 1.3/110 (Rabbit) Practically Non-irritating Draize Rating (Skin): 0.5/8.0 (Rabbit) Non-Irritating
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not biodegradable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:TLM96: > 1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
WellLife™ 734 Page 4 of 6 Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
WellLife™ 734 Page 5 of 6 Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
WellLife™ 734 Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: WellLife™ 665
Revision Date: 09-Feb-2012 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: WellLife™ 665 Synonyms: None Chemical Family: Polymer UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Polymer Proprietary 60 - 100% Not applicable Not applicable Not applicable
WellLife™ 665 Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye irritation. Airborne dust may be explosive.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation Move person to fresh air.
Skin Wash with soap and water.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices are required to minimize this potential.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary None known. Measures
Procedure for Cleaning / Scoop up and remove. Absorption
7. HANDLING AND STORAGE
Handling Precautions Avoid creating or inhaling dust. Avoid dust accumulations.
Storage Information Store away from oxidizers. Store in a cool, dry location.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
WellLife™ 665 Page 2 of 6 Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Color: Off white Odor: Odorless pH: Not Determined Specific Gravity @ 20 C (Water=1): 1.0 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): 236 Flash Point Method: COC Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to Strong oxidizers. Avoid)
Hazardous Decomposition Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
WellLife™ 665 Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation None known.
Skin Contact Prolonged or repeated contact may cause slight skin irritation.
Eye Contact May cause mild eye irritation.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
WellLife™ 665 Page 4 of 6 14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
WellLife™ 665 Page 5 of 6 Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
WellLife™ 665 Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: TUNED SPACER III CONCENTRATE
Revision Date: 23-Jun-2011 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Trade Name: TUNED SPACER III CONCENTRATE Synonyms: None Chemical Family: Ethoxylated nonylphenol Application: Cement Additive
Manufacturer/Supplier Halliburton Energy Services P.O. Box 1431 Duncan, Oklahoma 73536-0431 Emergency Telephone: (281) 575-5000
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA Ethoxylated nonylphenol 60 - 100% Not applicable Not applicable
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May be absorbed through the skin.
4. FIRST AID MEASURES
Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
TUNED SPACER III CONCENTRATE Page 1 of 6 5. FIRE FIGHTING MEASURES
Flash Point/Range (F): 200Min: > 341 Flash Point/Range (C): Not DeterminedMin: > 172 Flash Point Method: PMCC Autoignition Temperature (F): Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (%): Not Determined
Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
NFPA Ratings: Health 2, Flammability 1, Reactivity 0 HMIS Ratings: Health 2, Flammability 1, Reactivity 0
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wear appropriate respirator when opening containers. Wash hands after use. Launder contaminated clothing before reuse.
Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use. Product has a shelf life of 12 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation.
Respiratory Protection Organic vapor respirator.
Hand Protection Impervious rubber gloves.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Clear colorless to pale yellow
TUNED SPACER III CONCENTRATE Page 2 of 6 9. PHYSICAL AND CHEMICAL PROPERTIES Odor: Mild aromatic pH: 5-7 Specific Gravity @ 20 C (Water=1): 1.02 Density @ 20 C (lbs./gallon): 8.50 Bulk Density @ 20 C (lbs/ft3): Not Determined Boiling Point/Range (F): Not DeterminedMin: > 482 Boiling Point/Range (C): Not DeterminedMin: > 250 Freezing Point/Range (F): 0 Freezing Point/Range (C): -18 Vapor Pressure @ 20 C (mmHg): < 0.1 Vapor Density (Air=1): > 1 Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): < 0.01 Solubility in Water (g/100ml): Not Determined Solubility in Solvents (g/100ml): Not Determined VOCs (lbs./gallon): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistrokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong acids. Strong alkalis. Strong oxidizers. Avoid)
Hazardous Decomposition Toxic fumes. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause respiratory irritation. May cause central nervous system depression including headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.
Skin Contact May cause moderate skin irritation. May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.
Eye Contact Causes severe eye irritation which may damage tissue.
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting, nausea, and diarrhea.
Aggravated Medical Conditions Skin disorders. Lung disorders.
Chronic Effects/Carcinogenicity May contain ethylene oxide in the headspace of the drum. Ethylene oxide is a cancer and reproductive hazard.
TUNED SPACER III CONCENTRATE Page 3 of 6 Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: > 2500 mg/kg (Rat)
Dermal Toxicity: LD50: 2830 mg/kg (Rabbit)
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
DOT Not restricted
Canadian TDG Not restricted
ADR Not restricted
Air Transportation TUNED SPACER III CONCENTRATE Page 4 of 6 ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
EPA SARA Title III Extremely Not applicable Hazardous Substances
EPA SARA (311,312) Hazard Acute Health Hazard Class
EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372: Ethoxylated Nonylphenol (9016-45-9)
EPA CERCLA/Superfund Not applicable. Reportable Spill Quantity
EPA RCRA Hazardous Waste If product becomes a waste, it does NOT meet the criteria of a hazardous waste as Classification defined by the US EPA.
California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.
MA Right-to-Know Law Does not apply.
NJ Right-to-Know Law Does not apply.
PA Right-to-Know Law Does not apply. Canadian Regulations
Canadian DSL Inventory All components listed on inventory or are exempt.
WHMIS Hazard Class D2B Toxic Materials
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS Not applicable
TUNED SPACER III CONCENTRATE Page 5 of 6 Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
TUNED SPACER III CONCENTRATE Page 6 of 6 MATERIAL SAFETY DATA SHEET Product Trade Name: TUNED SPACER E+
Revision Date: 16-Sep-2013
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: TUNED SPACER E+ Synonyms: None Chemical Family: Mineral UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Spacer
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA WES Bentonite 1302-78-9 60 - 100% Not applicable Not applicable TWA: 1 mg/m3 Crystalline silica, quartz 14808-60-7 1 - 5% TWA: 0.1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3 TUNED SPACER E+ Page 1 of 7 Crystalline silica, 14464-46-1 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3 cristobalite Crystalline silica, tridymite 15468-32-3 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 0.05 mg/m3
Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview
DANGER! - CHRONIC HEALTH HAZARD Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.
Risk Phrases R49 May cause cancer by inhalation. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
HSNO Classification 6.7A Known or presumed human carcinogens 6.9A Toxic to human target organs or systems
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Treat symptomatically.
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons None known.
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters for fire fighting personnel.
TUNED SPACER E+ Page 2 of 7 6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Use appropriate protective equipment. Avoid creating and breathing dust. Measures
Environmental Precautionary None known. Measures
Procedure for Cleaning / Collect using dustless method and hold for appropriate disposal. Consider Absorption possible toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuse empty container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures below applicable exposure limits.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), or equivalent respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered before reuse. Use precautionary measures to avoid creating dust when removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: White to light straw Odor: Odorless pH: Not Determined Specific Gravity @ 20 C (Water=1): 2.65 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/M3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined TUNED SPACER E+ Page 3 of 7 Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): 5 Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Avoid)
Hazardous Decomposition Oxides of sulfur. Carbon monoxide and carbon dioxide. Amorphous silica may Products transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Acute Toxicity Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may also have serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact May cause eye irritation. Skin Contact May cause mechanical skin irritation. Ingestion None known
TUNED SPACER E+ Page 4 of 7 Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The National Toxicology Program classifies respirable crystalline silica as "Known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and other internal organs) and kidney disease.
Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Bentonite 1302-78-9 5000 mg/kg ( Rat ) No data available No data available Crystalline silica, quartz 14808-60-7 500 mg/kg ( Rat ) No data available No data available Crystalline silica, 14464-46-1 No data available No data available No data available cristobalite Crystalline silica, 15468-32-3 No data available No data available No data available tridymite
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity: Not determined Acute Algae Toxicity: Not determined
Ecotoxicity Substance Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water Microorganisms Flea) Bentonite 1302-78-9 No information available TLM96: 10000 ppm No information available No information available (Oncorhynchus mykiss) Crystalline silica, 14808-60-7 No information available No information available No information available No information available quartz Crystalline silica, 14464-46-1 No information available No information available No information available No information available cristobalite Crystalline silica, 15468-32-3 No information available No information available No information available No information available tridymite
12.2 Persistence and degradability No information available
12.3 Bioaccumulative potential No information available
12.4 Mobility in soil TUNED SPACER E+ Page 5 of 7 No information available
12.5 Results of PBT and vPvB assessment No information available.
12.6 Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification T - Toxic.
Crystalline silica is not classified as a carcinogen in EU Council Directives 67/548/EEC and 88/379/EEC.
Risk Phrases R49 May cause cancer by inhalation. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
TUNED SPACER E+ Page 6 of 7 Safety Phrases S53 Avoid exposure - obtain special instructions before use. S22 Do not breathe dust. S38 In case of insufficient ventilation wear suitable respiratory equipment.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable
Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
TUNED SPACER E+ Page 7 of 7
MATERIAL SAFETY DATA SHEET Product Trade Name: SILICALITE LIQUID
Revision Date: 22-Feb-2012 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: SILICALITE LIQUID Synonyms: None Chemical Family: Blend UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: None Application: Light Weight Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC OEL Silica, amorphous - fumed 7631-86-9 30 - 60% 2 mg/m3 Not applicable 2 mg/m3
SILICALITE LIQUID Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye irritation.
Risk Phrases None
HSNO Classification Not Determined
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Not applicable.
Special Protective Equipment for Not applicable. Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary None known. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing.
Storage Information Keep container closed when not in use. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
SILICALITE LIQUID Page 2 of 6 Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Dark gray Odor: Odorless pH: 6- 8 Specific Gravity @ 20 C (Water=1): 1.37 Density @ 20 C (kg/l): 1.397 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): 100 Freezing Point/Range (C): 0 Pour Point/Range (C): Not Determined Flash Point/Range (C): 100 Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): 22.9 Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Miscible Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to None known. Avoid)
Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or Products cristobalite (1470 C).
Additional Guidelines Not Applicable
SILICALITE LIQUID Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye and skin contact.
Inhalation None known.
Skin Contact Practically Non-toxic by Skin Contact.
Eye Contact May cause mild eye irritation.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Ames Test: Negative Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
SILICALITE LIQUID Page 4 of 6 14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of This product does not comply with NZIOC Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
SILICALITE LIQUID Page 5 of 6 Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
SILICALITE LIQUID Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: SCR-100L
Revision Date: 12-Apr-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: SCR-100L Synonyms: None Chemical Family: Anionic Polymer UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Retarder
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Contains no hazardous Mixture 60 - 100% Not applicable Not applicable Not applicable substances
SCR-100L Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye irritation.
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing.
Storage Information Store away from oxidizers. Store in a dry location. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
SCR-100L Page 2 of 6 Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator is recommended: Dust/mist respirator. (N95, P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Blue Odor: Odorless pH: 3 - 4 (28%) Specific Gravity @ 20 C (Water=1): 1.16 Density @ 20 C (kg/l): 1.16 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): -4 Pour Point/Range (C): Not Determined Flash Point/Range (C): Not DeterminedMin: > 93 Flash Point Method: PMCC Autoignition Temperature (C): 520 Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: ~60 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): 15-30 (25C) Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Avoid)
Hazardous Decomposition Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
SCR-100L Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation May cause respiratory irritation.
Skin Contact May cause mild skin irritation.
Eye Contact May cause mild eye irritation.
Ingestion Irritation of the mouth, throat, and stomach.
Aggravated Medical Conditions Skin disorders.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
SCR-100L Page 4 of 6 Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases Not classified
Safety Phrases Not classified
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
SCR-100L Page 5 of 6 Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
SCR-100L Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: NF-6
Revision Date: 10-Apr-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: NF-6 Synonyms: None Chemical Family: Blend UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Defoamer
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Vegetable oil Proprietary 60 - 100% 10 mg/m3 Not applicable Not applicable Aluminum stearate 637-12-7 1 - 5% 10 mg/m3 Not applicable 2 mg/m3
NF-6 Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause mild eye, skin, and respiratory irritation. May be harmful if swallowed.
Risk Phrases None
HSNO Classification 9.1D Slightly harmful in the aquatic environment
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Carbon dioxide, dry chemical, foam.
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.
Storage Information Store away from oxidizers. Keep container closed when not in use.
NF-6 Page 2 of 6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in areas without good cross ventilation.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator is recommended: Organic vapor respirator with a dust/mist filter. (A2P2/P3)
Hand Protection Polyvinylchloride gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Yellow Odor: Mild pH: Not Determined Specific Gravity @ 20 C (Water=1): 0.93 Density @ 20 C (kg/l): 0.93 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): 182 Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): >170 Flash Point Method: Not Determined Autoignition Temperature (C): 385 Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Disperses Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to Strong oxidizers. Avoid)
NF-6 Page 3 of 6 Hazardous Decomposition Hydrocarbons. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation None known.
Skin Contact May cause mild skin irritation. May cause an allergic skin reaction.
Eye Contact May cause mild eye irritation.
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Readily biodegradable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
NF-6 Page 4 of 6 13. DISPOSAL CONSIDERATIONS
Disposal Method Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable
NF-6 Page 5 of 6 Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
NF-6 Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: MICROBOND EXPANDING ADDITIVE
Revision Date: 03-Apr-2014
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: MICROBOND EXPANDING ADDITIVE Synonyms: None Chemical Family: Mineral UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. HAZARDS IDENTIFICATION
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Hazard Overview May cause severe eye irritation. May cause skin irritation.
MICROBOND EXPANDING ADDITIVE Page 1 of 6 Classification Xi - Irritant.
Risk Phrases R38 Irritating to skin. R41 Risk of serious damage to eyes.
Safety Phrases S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes.
HSNO Classification 6.3A Irritating to the skin 6.4A Irritating to the eye
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA WES Calcium aluminate 12042-68-1 10 - 30% Not applicable Not applicable 10 mg/m3 Calcium hydroxide 1305-62-0 10 - 30% TWA: 5 mg/m3 TWA: 5 mg/m3 TWA: 5 mg/m3 Non-Hazardous Substance to Total of 100%
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must not be used for safety reasons None known.
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters for fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Use appropriate protective equipment. Avoid creating and breathing dust. Measures
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures MICROBOND EXPANDING ADDITIVE Page 2 of 6 Procedure for Cleaning / Scoop up and remove. Absorption
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.
Storage Information Store in a cool, dry location.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: Light red Odor: Odorless pH: Not Determined Specific Gravity @ 20 C (Water=1): 3.2 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/M3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): >600 Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
MICROBOND EXPANDING ADDITIVE Page 3 of 6 Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to None known. Avoid)
Hazardous Decomposition Oxides of sulfur. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Acute Toxicity Inhalation May cause respiratory irritation. Eye Contact May cause severe eye irritation. Skin Contact May cause skin irritation. Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Calcium aluminate 12042-68-1 > 2000 mg/kg (Rat) (similar > 2000 mg/kg (Rat) (similar No data available substance) substance) Calcium hydroxide 1305-62-0 7340 mg/kg (Rat) >2500 mg/kg (Rabbit) No data available > 2000 mg/kg (Rat)
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity: Not determined Acute Algae Toxicity: Not determined
Ecotoxicity Substance Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Calcium aluminate 12042-68-1 EC50(72h): 3.6 mg/L LC50(96h): >100 mg/L EC50(3h): > 1000 mg/L EC50(48h): 5.4 mg/L (Desmodesmus (Danio rerio) (Activated sludge of a (Daphnia magna) subspicatus) predominantly domestic NOEC(72h): 2.6 mg/L sewage) (Desmodesmus subspicatus)
MICROBOND EXPANDING ADDITIVE Page 4 of 6 Calcium hydroxide 1305-62-0 EC50(72h): 184.57 mg/L TLM96: 100-500 ppm EC50(3h): 300.4 mg/L TLM96: 478,520 ppm (Pseudokirchnerella (Oncorhynchus mykiss) (respiration rate) (Mysidopsis bahia) subcapitata) 33.884 mg/L (Clarias (activated sludge of a EC50(48h): 49.1 mg/L gariepinus) predominantly domestic (Daphnia magna) LC50(96h): 50.6 mg/L sewage) LC50:(96h): 158 mg/L (Oncorhynchus mykiss) (Crangon septemspinosa) LC50(96h): 457 mg/L NOEC(14d): 32 mg/L (Gasterosteus aculeatus) (Crangon septemspinosa)
12.2 Persistence and degradability
Substances Persistence and Degradability Calcium aluminate The methods for determining biodegradability are not applicable to inorganic substances. Calcium hydroxide The methods for determining biodegradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential No information available
12.4 Mobility in soil No information available
12.5 Results of PBT and vPvB assessment No information available.
12.6 Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
MICROBOND EXPANDING ADDITIVE Page 5 of 6 Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of This product does not comply with NZIOC Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Xi - Irritant.
Risk Phrases R38 Irritating to skin. R41 Risk of serious damage to eyes.
Safety Phrases S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable
Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
MICROBOND EXPANDING ADDITIVE Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: MICROBOND HT CEMENT
Revision Date: 01-Feb-2012 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: MICROBOND HT CEMENT Synonyms: None Chemical Family: Metal oxide UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: None Application: Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC OEL Magnesium oxide 1309-48-4 60 - 100% 10 mg/m3 10 mg/m3 10 mg/m3
MICROBOND HT CEMENT Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and respiratory irritation.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Not applicable.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary None known. Measures
Procedure for Cleaning / Scoop up and remove. Absorption
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.
Storage Information Store in a cool, dry location. Store in a cool well ventilated area. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
MICROBOND HT CEMENT Page 2 of 6 Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator is recommended: Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: White to Light gray Odor: Odorless pH: 10.5 Specific Gravity @ 20 C (Water=1): 3.46 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: 0 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): 40.32 Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to None known. Avoid)
Hazardous Decomposition None known. Products
Additional Guidelines Not Applicable
MICROBOND HT CEMENT Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause mild respiratory irritation.
Skin Contact None known.
Eye Contact May cause mechanical irritation to eye.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
MICROBOND HT CEMENT Page 4 of 6 14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of This product does not comply with NZIOC Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
MICROBOND HT CEMENT Page 5 of 6 Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
MICROBOND HT CEMENT Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: HR-25L
Revision Date: 14-May-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: HR-25L Synonyms: None Chemical Family: Organic acid UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Retarder
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Tartaric acid 87-69-4 30 - 60% Not applicable Not applicable Not applicable
HR-25L Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation.
Risk Phrases R41 Risk of serious damage to eyes.
HSNO Classification 8.3A Corrosive to ocular tissue 9.3C Harmful to terrestrial vertebrates
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Neutralize to pH of 6-8. Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing before reuse.
Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use. Product has a shelf life of 60 months.
HR-25L Page 2 of 6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Light yellow-green Odor: Odorless pH: 1.7 Specific Gravity @ 20 C (Water=1): 1.2 Density @ 20 C (kg/l): 1.2 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): 103 Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: 60 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Strong alkalis. Avoid)
Hazardous Decomposition Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable HR-25L Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation May cause respiratory irritation.
Skin Contact May cause skin irritation.
Eye Contact May cause moderate eye irritation.
Ingestion Irritation of the mouth, throat, and stomach.
Aggravated Medical Conditions Skin disorders.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
HR-25L Page 4 of 6 13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Xi - Irritant.
Risk Phrases R41 Risk of serious damage to eyes.
Safety Phrases S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable
HR-25L Page 5 of 6 Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
HR-25L Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: HR-6L
Revision Date: 02-May-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: HR-6L Synonyms: None Chemical Family: Lignosulfonate UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Retarder
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Modifed lignosulfonate Proprietary 30 - 60% Not applicable Not applicable Not applicable
HR-6L Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and respiratory irritation.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.
Storage Information Store away from oxidizers. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
HR-6L Page 2 of 6 Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Dark brown Odor: Molasses pH: 9.5 Specific Gravity @ 20 C (Water=1): 1.21 Density @ 20 C (kg/l): 1.208 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not DeterminedMin: > 98 Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Avoid)
Hazardous Decomposition Oxides of sulfur. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
HR-6L Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation May cause mild respiratory irritation.
Skin Contact None known.
Eye Contact May cause mild eye irritation.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Slowly biodegradable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method This product is not regarded as hazardous waste. Dispose in accordance with local regulations.
Contaminated Packaging Follow all applicable national or local regulations. HR-6L Page 4 of 6 14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
HR-6L Page 5 of 6 Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
HR-6L Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: HALAD® 413L CEMENT ADDITIVE
Revision Date: 02-May-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: HALAD® 413L CEMENT ADDITIVE Synonyms: None Chemical Family: Polymer UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Fluid Loss Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Acrylic polymer Proprietary 10 - 30% Not applicable Not applicable Not applicable HALAD® 413L CEMENT ADDITIVE Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview No significant hazards expected.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary None known. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing.
Storage Information Store away from oxidizers. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
HALAD® 413L CEMENT ADDITIVE Page 2 of 6 Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product. Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial Hygienist or other qualified professional.
Not normally needed. But if significant exposures are possible then the following respirator is recommended: Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Brown-black Odor: Sweet pH: 7.5 Specific Gravity @ 20 C (Water=1): 1.1 Density @ 20 C (kg/l): 1.098 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Miscible Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Avoid) HALAD® 413L CEMENT ADDITIVE Page 3 of 6 Hazardous Decomposition Oxides of nitrogen. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation None known.
Skin Contact None known.
Eye Contact None known.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: > 5000 mg/kg (Rat)
Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)
Inhalation Toxicity: Not determined
Primary Irritation Effect: Draize Rating (Skin): 0.09/8.0 (Rabbit) Practically Non-irritating
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Slowly biodegradable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
HALAD® 413L CEMENT ADDITIVE Page 4 of 6 13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory Product contains one or more components not listed on inventory. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product does not comply with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
HALAD® 413L CEMENT ADDITIVE Page 5 of 6 Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
HALAD® 413L CEMENT ADDITIVE Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: GASCON 469
Revision Date: 26-Mar-2014
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: GASCON 469 Synonyms: None Chemical Family: Blend UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. HAZARDS IDENTIFICATION
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Hazard Overview May cause mild eye irritation. May cause mild skin irritation.
GASCON 469 Page 1 of 6 Classification None
Risk Phrases None
Safety Phrases S24/25 Avoid contact with skin and eyes.
HSNO Classification 6.3B Mildly irritating to the skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA WES Contains no hazardous Mixture 60 - 100% Not applicable Not applicable Not applicable substances Non-Hazardous Substance to Total of 100%
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must not be used for safety reasons None known.
Special Exposure Hazards Not applicable.
Special Protective Equipment Not applicable. for Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Use appropriate protective equipment. Measures
Environmental Precautionary None known. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert Absorption materials. Scoop up and remove.
GASCON 469 Page 2 of 6 7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.
Storage Information Store in a cool well ventilated area. Keep from excessive heat. Keep from freezing. Keep container closed when not in use. Store in non-rusting containers. Product has a shelf life of 12 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Transparent Odor: Odorless pH: 10 Specific Gravity @ 20 C (Water=1): 1.1 Density @ 20 C (kg/l): 1.098 Bulk Density @ 20 C (kg/M3): Not Determined Boiling Point/Range (C): 100 Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: 80 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): 10 Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
GASCON 469 Page 3 of 6 Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Strong acids. Avoid)
Hazardous Decomposition None known. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Acute Toxicity Inhalation May cause mild respiratory irritation. Eye Contact May cause mild eye irritation. Skin Contact May cause mild skin irritation. Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous Mixture No data available No data available No data available substances
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity: Not determined Acute Algae Toxicity: Not determined
Ecotoxicity Substance Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Contains no Mixture No information available No information available No information available No information available hazardous substances
12.2 Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential Does not bioaccumulate
12.4 Mobility in soil No information available
12.5 Results of PBT and vPvB assessment No information available.
GASCON 469 Page 4 of 6 12.6 Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified Risk Phrases Not classified
Safety Phrases S24/25 Avoid contact with skin and eyes.
16. OTHER INFORMATION
GASCON 469 Page 5 of 6 The following sections have been revised since the last issue of this SDS Not applicable
Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
GASCON 469 Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: ECONOLITE LIQUID
Revision Date: 17-Jan-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substance or Preparation
Product Trade Name: ECONOLITE LIQUID Synonyms: None Chemical Family: Silicate UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: S5 Application: Light Weight Cement Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance CAS Number Percent Australia New Zealand ACGIH TLV-TWA NOHSC WES Sodium silicate 1344-09-8 35-49 Not determined Not determined Not applicable
ECONOLITE LIQUID Page 1 of 6 Non-hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if swallowed.
Risk Phrases R34 Causes burns.
HSNO Classification Not Determined
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Unsuitable Extinguishing Media None known
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use Appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways or low areas. Measures
Procedure for Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Cleaning/Absorption Neutralise to pH of 6-8. Scoop up and remove. Do NOT spread spilled product with water.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapours. Wash hands after use. Launder contaminated clothing before reuse. Avoid breathing mist.
Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed when not in use. ECONOLITE LIQUID Page 2 of 6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation.
Respiratory Protection Dust/mist respirator. (N95,P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Full protective clothing.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Colour: Clear to hazy Odour: Slightly soapy pH: 11.2 Specific Gravity @ 20 C (Water=1): 1.4 Density @ 20 C (kg/l): 1.4 Bulk Density @ 20 C (kg/l): Not Determined Boiling Point/Range (C): 101 Freezing Point/Range (C): -1 Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapour Pressure @ 20 C (mmHg): Not Determined Vapour Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate = 1): Not determined. Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C Not Determined (centipoise): Viscosity, Kinematic @ 20 C Not Determined (centistokes): Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerisation: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong acids. Amphoteric metals such as aluminium, magnesium, lead, tin, or zinc. Avoid)
ECONOLITE LIQUID Page 3 of 6 Hazardous Decomposition Toxic fumes. Products
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation Causes severe respiratory irritation.
Skin Contact May cause skin burns.
Eye Contact May cause eye burns.
Ingestion Causes burns of the mouth, throat and stomach.
Aggravated Medical Conditions Skin disorders.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: 2000-3000 mg/kg (Rat)
Dermal Toxicity: Not determined.
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity: Not determined
Genotoxicity: Not determined
Reproductive/Development Not determined al Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not Determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
ECONOLITE LIQUID Page 4 of 6 13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed. EINECS Inventory All components are listed on the inventory.
Classification C - Corrosive.
Risk Phrases R34 Causes burns.
Safety Phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 Wear suitable protective clothing.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS: Not applicable
ECONOLITE LIQUID Page 5 of 6 Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Product Stewardship at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
ECONOLITE LIQUID Page 6 of 6 SAFETY DATA SHEET
D-AIR 3000L
Revision Date: 17-Feb-2015 Revision Number: 16
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
1.1. Product Identifier Product Name D-AIR 3000L
Other means of Identification Synonyms: None Product Code: HM003191
Recommended use of the chemical and restrictions on use Recommended Use Defoamer Uses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300 E-Mail address: [email protected]
Emergency phone number 61 (08) 9455 8300
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
______Page 1 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______Signal Word Not Hazardous
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains Substances CAS Number Alkenes Proprietary
Other hazards which do not result in classification None known
Australia Classification For the full text of the R/H-phrases mentioned in this Section, see Section 16
Classification Not Classified Risk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - Australia Alkenes Proprietary 60 - 100%
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration.
Symptoms caused by exposure May cause lung damage if swallowed.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures Suitable extinguishing equipment
______Page 2 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Extinguishing media which must not be used for safety reasons None known.
Specific hazards arising from the chemical Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.
6.2. Environmental precautions None known.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 24 months. Other Guidelines No information available
8. Exposure Controls/Personal Protection Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Alkenes Proprietary Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Respiratory Protection Not normally necessary.
Hand Protection None known. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls No information available
______Page 3 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Liquid Color: Opaque Odor: Hydrocarbon Odor Threshold: No information available
Property Values Remarks/ - Method pH: 5.5-7.9 Freezing Point/Range No data available Melting Point/Range No data available Boiling Point/Range No data available Flash Point > 121 °C PMCC Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 0.92 Water Solubility Insoluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not applicable 10.2. Chemical Stability Stable 10.3. Possibility of Hazardous Reactions Will Not Occur 10.4. Conditions to Avoid None anticipated 10.5. Incompatible Materials Strong oxidizers. 10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/Effects May cause lung damage if swallowed.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Alkenes Proprietary > 5000 mg/kg (Rat) (similar > 2000 mg/kg (Rat) (similar > 2.1 mg/L (Rat) substance) substance)
______Page 4 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______
Immediate, delayed and chronic health effects from exposure Inhalation May cause central nervous system depression including headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.
Eye Contact May cause mild eye irritation. Skin Contact May cause mild skin irritation. Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Exposure Levels No data available
Interactive effects None known.
Data limitations No data available
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data No data available
Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Alkenes Proprietary EC50(72h): > 1000 mg/L LL50(96h): > 1000 mg/L No information available EC50(48h): > 1000 mg/L (Selenastrum (Oncorhynchus mykiss) (Daphnia magna) (similar capicomutum) (similar (similar substance) substance) substance) LL50(96h): > 10000 mg/L (Scopthalmus maximus) (similar substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability Alkenes Proprietary Readily biodegradable (77 - 81% @ 28d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow Alkenes Proprietary > 7
______Page 5 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______12.4. Mobility in soil No information available
12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approved incinerator according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulations Not applicable
14. Transport Information
Transportation Information UN Number: Not restricted UN Proper Shipping Name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals EINECS Inventory This product, and all its components, complies with EINECS US TSCA Inventory All components listed on inventory or are exempt. Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 17-Feb-2015
______Page 6 / 7 D-AIR 3000L Revision Date: 17-Feb-2015 ______Revision Note Update to Format SECTION: 2
Full text of R-phrases referred to under Sections 2 and 3 None
Full text of H-Statements referred to under sections 2 and 3 None
Additional information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used Not applicable
Key literature references and sources for data www.ChemADVISOR.com/ NZ CCID
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
______Page 7 / 7
MATERIAL SAFETY DATA SHEET Product Trade Name: CEMENT - CLASS G + 35% SSA-1
Revision Date: 29-Apr-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substance or Preparation
Product Trade Name: CEMENT - CLASS G + 35% SSA-1 Synonyms: None Chemical Family: Cement UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: None Application: Cement
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance CAS Number Percent Australia New Zealand ACGIH TLV-TWA NOHSC WES Portland cement 65997-15-1 60 - 100% TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 1 mg/m3 Crystalline silica, quartz 14808-60-7 30 - 60% TWA: 0.1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3
CEMENT - CLASS G + 35% SSA-1 Page 1 of 7 Non-hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD May cause eye, skin and respiratory irritation.
DANGER! - CHRONIC HEALTH HAZARD Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.
Risk Phrases R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R49 May cause cancer by inhalation. R37/38 Irritating to respiratory system and skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
HSNO Classification Not Determined
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media None - does not burn.
Unsuitable Extinguishing Media None known
Special Exposure Hazards Not applicable.
Special Protective Equipment for Not applicable. Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use Appropriate protective equipment. Avoid creating and breathing dust.
CEMENT - CLASS G + 35% SSA-1 Page 2 of 7 Environmental Precautionary None known. Measures
Procedure for Collect using dustless method and hold for appropriate disposal. Consider possible Cleaning/Absorption toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf life of 24 months
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures below applicable exposure limits listed in Section 2.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), or equivalent respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered before reuse. Use precautionary measures to avoid creating dust when removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Colour: Grey Odour: Odourless pH: 12.4 Specific Gravity @ 20 C (Water=1): Not Determined Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/l): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapour Pressure @ 20 C (mmHg): Not Determined
CEMENT - CLASS G + 35% SSA-1 Page 3 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Vapour Density (Air=1): Not Determined Percent Volatiles: 0 Evaporation Rate (Butyl Acetate = 1): Not determined. Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C Not Determined (centipoise): Viscosity, Kinematic @ 20 C Not Determined (centistokes): Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerisation: Will Not Occur
Conditions to Avoid Keep away from any contact with water.
Incompatibility (Materials to Hydrofluoric acid Avoid)
Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or Products cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may also have serious chronic health effects (See Chronic Effects/Carcinogenicity" subsection below). "
Skin Contact Can dry skin. May cause an allergic skin reaction. May cause alkali burns with confined contact.
Eye Contact May cause severe eye irritation.
Ingestion None known
Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not be exposed to quartz dust.
CEMENT - CLASS G + 35% SSA-1 Page 4 of 7 Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The National Toxicology Program classifies respirable crystalline silica as Known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2).
" There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and other internal organs) and kidney disease.
Other Information For further information consult Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages 761-768 (1997)."
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined.
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity: Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997).
Genotoxicity: Not determined
Reproductive/Development Not determined al Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not Determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined CEMENT - CLASS G + 35% SSA-1 Page 5 of 7 Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed. EINECS Inventory All components are listed on the inventory.
Classification T - Toxic. Xi - Irritant.
Risk Phrases R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R49 May cause cancer by inhalation. R37/38 Irritating to respiratory system and skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Safety Phrases S2 Keep out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S24/25 Avoid contact with skin and eyes.
CEMENT - CLASS G + 35% SSA-1 Page 6 of 7 16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS: Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Product Stewardship at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
CEMENT - CLASS G + 35% SSA-1 Page 7 of 7
MATERIAL SAFETY DATA SHEET Product Trade Name: CEMENT - CLASS G
Revision Date: 29-Apr-2013 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: CEMENT - CLASS G Synonyms: None Chemical Family: Cement UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Allocated Poisons Schedule: None Allocated Application: Cement
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC WES Portland cement 65997-15-1 60 - 100% TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 1 mg/m3 Crystalline silica, quartz 14808-60-7 <3 TWA: 0.1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3
CEMENT - CLASS G Page 1 of 7 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD May cause eye, skin, and respiratory irritation.
DANGER! - CHRONIC HEALTH HAZARD Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.
Risk Phrases R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. R37/38 Irritating to respiratory system and skin.
HSNO Classification 6.1E (Inhalation) Acutely Toxic Substances 8.2C Corrosive to dermal tissue if exposed for greater than 1 hour 8.3A Corrosive to ocular tissue 6.5B Contact sensitisers 6.7A Known or presumed human carcinogens 6.9A Toxic to human target organs or systems
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media None - does not burn.
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Not applicable.
Special Protective Equipment for Not applicable. Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust. CEMENT - CLASS G Page 2 of 7 Environmental Precautionary None known. Measures
Procedure for Cleaning / Collect using dustless method and hold for appropriate disposal. Consider possible Absorption toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures below applicable exposure limits.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), or equivalent respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered before reuse. Use precautionary measures to avoid creating dust when removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: Gray Odor: Odorless pH: 12.4 Specific Gravity @ 20 C (Water=1): 3.14 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not Determined Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined
CEMENT - CLASS G Page 3 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: 0 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Not Determined Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid Keep away from any contact with water.
Incompatibility (Materials to Hydrofluoric acid. Avoid)
Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or Products cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may also have serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection below).
Skin Contact Can dry skin. May cause an allergic skin reaction. May cause alkali burns with confined contact.
Eye Contact May cause severe eye irritation.
Ingestion None known
Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not be exposed to quartz dust.
CEMENT - CLASS G Page 4 of 7 Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The National Toxicology Program classifies respirable crystalline silica as "Known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and other internal organs) and kidney disease.
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages 761-768 (1997).
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997).
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined CEMENT - CLASS G Page 5 of 7 Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercial waste collection.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Xi - Irritant.
Risk Phrases R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. R37/38 Irritating to respiratory system and skin.
CEMENT - CLASS G Page 6 of 7 Safety Phrases S2 Keep out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S24/25 Avoid contact with skin and eyes.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
CEMENT - CLASS G Page 7 of 7
MATERIAL SAFETY DATA SHEET Product Trade Name: CFR-3L
Revision Date: 22-Feb-2012 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: CFR-3L Synonyms: None Chemical Family: Blend UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: None Application: Friction Reducer
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC OEL Sulfonic acid salt 30 - 60% Not applicable Not applicable Not applicable
CFR-3L Page 1 of 6 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and skin irritation.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for Fire-Fighters fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment.
Environmental Precautionary Prevent from entering sewers, waterways, or low areas. Measures
Procedure for Cleaning / Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Absorption Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing.
Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
CFR-3L Page 2 of 6 Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Color: Red Odor: Musty pH: 7 Specific Gravity @ 20 C (Water=1): 1.17 Density @ 20 C (kg/l): 1.17 Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): Not DeterminedMin: > 98 Flash Point Method: PMCC Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: 67 Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Soluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): Not Determined Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to Strong oxidizers. Avoid)
Hazardous Decomposition Oxides of sulfur. Carbon monoxide and carbon dioxide. Products
Additional Guidelines Not Applicable
CFR-3L Page 3 of 6 11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation None known.
Skin Contact May cause skin irritation.
Eye Contact May cause mild eye irritation.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: 8670 mg/kg (Rat)
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
CFR-3L Page 4 of 6 14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of This product does not comply with NZIOC Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
CFR-3L Page 5 of 6 Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
CFR-3L Page 6 of 6
MATERIAL SAFETY DATA SHEET Product Trade Name: BARITE
Revision Date: 03-Aug-2012 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd. 53-55 Bannister Road Canning Vale WA 6155 Australia
ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300
Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: BARITE Synonyms: None Chemical Family: Mineral UN Number: None Dangerous Goods Class: None Subsidiary Risk: None Hazchem Code: None Poisons Schedule: None Application: Weight Additive
Prepared By Chemical Compliance Telephone: 1-580-251-4335 e-mail: [email protected]
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia New Zealand ACGIH TLV-TWA NOHSC OEL Barium sulfate 7727-43-7 60 - 100% 10 mg/m3 10 mg/m3 10 mg/m3 Crystalline silica, quartz 14808-60-7 1 - 5% 0.1 mg/m3 0.2 mg/m3 0.025 mg/m3
BARITE Page 1 of 7 Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD May cause eye, skin, and respiratory irritation. May be harmful if swallowed.
DANGER! - CHRONIC HEALTH HAZARD Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.
This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.
Risk Phrases None
HSNO Classification 6.7A Substances that are known or presumed human carcinogens. 6.9A Substances that are toxic to human target organs or systems.
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must None known. not be used for safety reasons
Special Exposure Hazards Not applicable.
Special Protective Equipment for Not applicable. Fire-Fighters
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures Use appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary None known. Measures BARITE Page 2 of 7 Procedure for Cleaning / Collect using dustless method and hold for appropriate disposal. Consider possible Absorption toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuse empty container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures below applicable exposure limits listed in Section 2.
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered before reuse. Use precautionary measures to avoid creating dust when removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid Color: Pink to tan to gray Odor: Odorless pH: Not Determined Specific Gravity @ 20 C (Water=1): 4.23 Density @ 20 C (kg/l): Not Determined Bulk Density @ 20 C (kg/m3): Not Determined Boiling Point/Range (C): Not Determined Freezing Point/Range (C): Not Determined Pour Point/Range (C): Not Determined Flash Point/Range (C): > 100 Flash Point Method: Not Determined Autoignition Temperature (C): Not Determined Flammability Limits in Air - Lower (g/m3): Not Determined Flammability Limits in Air - Lower (%): Not Determined Flammability Limits in Air - Upper (g/m3): Not Determined Flammability Limits in Air - Upper (%): Not Determined
BARITE Page 3 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure @ 20 C (mmHg): Not Determined Vapor Density (Air=1): Not Determined Percent Volatiles: Not Determined Evaporation Rate (Butyl Acetate=1): Not Determined Solubility in Water (g/100ml): Insoluble Solubility in Solvents (g/100ml): Not Determined VOCs (g/l): Not Determined Viscosity, Dynamic @ 20 C (centipoise): Not Determined Viscosity, Kinematic @ 20 C (centistokes): Not Determined Partition Coefficient/n-Octanol/Water: Not Determined Molecular Weight (g/mole): 233.4 Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to None known. Avoid)
Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or Products cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may also have serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection below).
Skin Contact None known.
Eye Contact May cause mild eye irritation.
Ingestion May produce nervous system effects such as feeling of weakness, unsteady walk, and dilation of blood vessels. May affect the heart and cardiovascular system.
Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not be exposed to quartz dust.
BARITE Page 4 of 7 Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The National Toxicology Program classifies respirable crystalline silica as "Known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and other internal organs) and kidney disease.
Prolonged inhalation of fine barium sulfate dusts form harmless nodular granules in lung, an affliction called baritosis. Baritosis produces no symptoms of bronchitis or emphysema, and lung functioning is not affected although dyspnea, upon exertion, may occur. The nodulation disappears if exposure is stopped.
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages 761-768 (1997).
Toxicity Tests
Oral Toxicity: LD50: >15000 mg/kg (Rat)
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997).
Genotoxicity: Not determined
Reproductive / Not determined Developmental Toxicity:
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not determined
BARITE Page 5 of 7 Ecotoxicological Information
Acute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss) Acute Crustaceans Toxicity:Not determined Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt. New Zealand Inventory of All components listed on inventory or are exempt. Chemicals US TSCA Inventory All components listed on inventory or are exempt. EINECS Inventory This product, and all its components, complies with EINECS
Classification Crystalline silica is not classified as a carcinogen in EU Council Directives 67/548/EEC and 88/379/EEC.
Risk Phrases None
Safety Phrases None
BARITE Page 6 of 7 16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS Not applicable Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre 0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton representative.
For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
BARITE Page 7 of 7