Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 01
Name of product with its Qty.
NAME OF PROPOSED PRODUCTS: -
No. Name of Product Total Quantity
01 Melamine Formaldehyde / Urea Formaldehyde Resin 1500 Mt/Month
Enclosure: 02
Packing & Final Use of Products
Name of proposed Product Type of Final application of product Packing Melamine Formaldehyde / MS / HDPE Tank For manufacturing of Ply boards, flush door, block board manufacturing . Urea Formaldehyde Resin
Enclosure: 03
Material Safety Data Sheet of Raw Materials
Formaldehyde : -
Formaldehyde
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
IUPAC name[hide]
Methanal
Systematic name[hide]
Methanal
Other names[hide]
Methyl aldehyde Methylene glycol Methylene oxide Formalin Formol
Identifiers
CAS number 50-00-0
PubChem 712
ChemSpider 692
UNII 1HG84L3525
EC number 200-001-8
UN number 2209
DrugBank DB03843
KEGG D00017
MeSH Formaldehyde
ChEBI CHEBI:16842
ChEMBL CHEMBL1255 Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
RTECS number LP8925000
ATCvet code QP53AX19
Beilstein Reference 1209228
Gmelin Reference 445
3DMet B00018
Jmol-3D images Image 1
SMILES
[show]
InChI
[show]
Properties[2]
Molecular formula CH2O
−1 Molar mass 30.03 g mol
Appearance Colorless gas
[1] Density 0.8153 g/cm³ (−20 °C)
Melting point −92 °C (−134 °F; 181 K)
[1] Boiling point −19 °C (−2 °F; 254 K)
Solubility in water 400 g dm−3
log P 0.350
Acidity (pKa) 13.3
Basicity (pKb) 0.7
Dipole moment 2.33 D
Structure
Molecular shape Trigonal planar
Hazards
MSDS MSDS
EU Index 605-001-00-5 Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
EU classification Toxic (T) Corrosive (C)
Carc. Cat. 1
R-phrases R23/24/25 R34 R43 R45
S-phrases (S1/2) S26 S36/37/39 S45S51 S53 S60
NFPA 704
4 3 0
Flash point 64 °C (147 °F; 337 K)
Autoignition temperature 430 °C (806 °F; 703 K)
Explosive limits 7–73%
LD50 100 mg/kg (oral, rat)
Related compounds
Related aldehydes Acetaldehyde ,Butyraldehyde ,Decanal , Heptanal Hexanal, Nonanal, Octadecanal, Octanal Pentanal, Propionaldehyde
Related compounds methanol formic acid
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
1. Melamine
IUPAC name[hide] ---1,3,5-Triazine-2,4,6-triamine
Other names[hide] : 2,4,6-Triamino-s-triazine , Cyanurotriamide, Cyanurotriamine , Cyanuramide
Identifiers
CAS number 108-78-1
PubChem 7955
ChemSpider 7667
UNII N3GP2YSD88
KEGG C08737
ChEBI CHEBI:27915
Jmol-3D images Image 1
Properties
Molecular formula C3H6N6
Molar mass 126.12 g/mol
Appearance White solid
3 Density 1574 kg/m Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
[1] Melting point 345 °C (653 °F; 618 K) (decomposition)
Boiling point Sublimes
Solubility in water 3.240 g/l (20 °C)[1]
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
2. Urea
Names
IUPAC name : Urea
Other names : Carbamide, carbonyl diamide, carbonyldiamine, diaminomethanal, diaminomethanone
Identifiers
CAS Registry 57-13-6
Number
ATC code B05BC02 , D02AE01
ChemSpider 1143
DrugBank DB03904
IUPHAR/BPS 4539
KEGG D00023
PubChem 1176
RTECS number YR6250000
UNII 8W8T17847W Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Properties
Chemical formula CH4N2O
−1 Molar mass 60.06 g·mol
Appearance White solid
3 Density 1.32 g/cm
Melting point 133 to 135 °C (271 to 275 °F; 406 to 408 K)
Solubility in water 1079 g/L (20 °C) , 1670 g/L (40 °C) , 2510 g/L (60 °C) , 4000 g/L (80 °C)
[1] Solubility 500 g/L glycerol, 50g/L ethanol
+ [2] Basicity (pKb) pKBH = 0.18
Structure
Dipole moment 4.56 D
Hazards
Safety data sheet JT Baker
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (Median dose) 8500 mg/kg (oral, rat)
Related compounds
Related ureas Thiourea , Hydroxycarbamide
Related compounds Carbamide peroxide , Urea phosphate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F],
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Material Safety Data Sheet of Finished Goods
Melamine Formaldehyde Glue
Idealized structure of melamine Glue
Identifiers
CAS number 9003 -08-1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Urea Formaldehyde Glue
Idealized structure of urea formaldehyde Glue
Identifiers
CAS number 9011-05-6
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 04 : Name of Raw Material with its Quantity
Sr. Product Raw Material Consumption MT/MT No.
1 Melamine Formaline 0.710
Resin Melamine 0.290
Poly Vinyl alcohol 0.003
Formic Acid 0.001
Caustic soda (50%) 0.002
2 Urea formaldehyde Formaline 0.710
Resin Industrial Urea 0.290
Poly Vinyl alcohol 0.003
Formic Acid 0.001
Caustic soda (50%) 0.002
Enclosure: 07
Chemical Name & Physical Form of Raw Materials with its storage facility
No. Name of Raw Chemical Name Physical Container MOC of Material Form Type container
1 Technical Grade Urea Carbonyldiamide Solid Bag – 50 Kg HDPE
2 Formaldehyde Methylaldehyde Liquid Tank – 100 KL HDPE / SS (solution)
3 Melamine Melamine Solid Bag – 25 kg Paper Bags
4 Caustic soda Sodium hydroxide Solid Bag – 50 Kg HDPE Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 08
Details of Hazardous Chemicals
The Raw Materials, which are termed as Hazardous Chemicals as per the "Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989", are as listed in below Table
Hazardous Chemicals Reference Maximum quantity that can The Manufacturer, storage & Import of be stored Hazardous chemical Rules 1989
Formaldehyde (solution) Sr. No. 205 (part II, Sch 1 of MSIHCR, 200 KL 1989
DETAILS OF HAZARDOUS CHEMICALS
Name of Toxicity Hazardous Handling & Control Measures Hazardous Characteristics Chemicals (LD50)
Formaldehyde 800 mg/kg In air it is slowly Handling: (solution) oxidize to formic Oral-Rat acid We will store it in MS storage tank. It is powerful We will charge it in Reaction vessel by reducing agent closed pumping system. Explosive reaction We will place this raw material separately from other raw material and from process area. We will avoid direct contact with the workers. During charging only two persons will be present. PersonalProtectiveEquipment
We use chemical goggles, rubber or plastic gloves, protective over clothing.
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 09
Manufacturing Process with Chemical Reactions
Manufacturing Process Of: -
Manufacturing Process of UF-Resin
Take the required quantity of Formalin in the Kettle and raise Ph to8.5 to9.0 using Caustic Solution. Charge required quantity of Urea and maintain the Ph at 8.5 to9.0 Start heating and at 60 0C Charge the required quantity of PVA and maintain the above maintained PH Raise the temperature to around 90-92 0C and reflux for 2 hours. After reflux add acid to bring down the Ph to 5.0 to7.0 Cook until the water tolerance comes to 1:4-5 and flow times 14-16 second. At this stage add Caustic solution to Raise Ph to 8.0 -9.0 Start cooling until the temperature comes down to ambient temperature. Water tolerance ,Solid Content, flow time and Ph should be 1:2-4,47-50 %,18-25 second and 8-9 respectively
NH2 NHCH2OH NHCH2OH
O = C + HCHO O = C + HCHO O = C
NH2 NHCH2OH NH2
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Melamine Formaldehyde Resin
All the raw materials melamine and formaldehyde will be added in Limped reaction vessel. Stirring & heating will be done up to 90 degree C for 1 Hr. Cooling down to 40 degree C. Melamine Formaldehyde Resin will be ready for use in laminated sheets as well as for sell purpose.
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 10
Mass Balance of each Products
Melamine formaldehyde
Mass balance
Formalin: 710 Kgs Formic Acid : 1Kgs Melamine : 290 Kgs
PVA - 3 kg
Caustic soda – 2 kg
STAGE-1 STAGE-2
0 Temp raised 91 to94 Maintain temp 95 C
For 75 minute
Melamine formaldehyde
Resin 1000 Kgs
Evaporation Loss : 5 kg
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Urea formaldehyde
Mass balance
Formalin: 710 Kgs Formic Acid : 1Kgs Industrial Urea : 290 Kgs
PVA - 3 kg
Caustic soda – 2 kg
STAGE-1 STAGE-2
0 Temp raised 91 to 94 Maintain temp 95 C
For 75 minute
Urea formaldehyde
Resin 1000 Kgs
Evaporation Loss : 5 kg
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 11
Details of Water Consumption & Waste Water Generation.
Water Consumption (Lit/Day) Wastewater generation (Lit/Day)
Domestic 1000 Domestic 1000
Industrial Industrial
Process 500 Process Nil
Cooling Tower 5000 Cooling Tower Nil
Gardening 1500 Gardening Nil
Total 8000 Total 1000
For proposed Project total water consumption will be 8,000L/Day. This water is met from MIDC water supply. Domestic wastewater will be discharge to soak pit via septic tank system.
• There will be no industrial effluent generated from proposed products. • The cooling blow down will be used in process water. • So, there will no effluent generated from our unit as we will be using water for manufacture. Hence we will achieve zero discharge. • We will provide for Water Harvesting and use all rain water of Roof tops of Sheds and Buildings ( apprx 500 sq. mts ) for water harvesting.
Details of Flue Gas Emission & Process Gas Emission
No. Stack Capacity Stack APC Pollutants attached Height Measures To (Meter) SPM SO2 NOx
01 Boiler 4,00,000 K Cal 20 mtr ----- < 150 < 100 < 50 ppm mg/NM3 ppm
03 DG set 25 KVA 9 meter ---- < 150 < 100 < 50 ppm mg/NM3 ppm Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Type of Process Gas Emission:- There will be no process emission from our proposed manufacturing activity.
Fuel Details: Sr.No Name of Fuel Quantity
1 Diesel 100 Lts / month
2 Wood waste / Agri Waste 30 Ton per month
Enclosure: 12
Details of Flue Gas Emission & Process Gas Emission
No. Stack Capacity Stack APC Pollutants attached Height Measures To (Meter) SPM SO2 NOx
01 Boiler 4,00,000 K Cal 20 mtr ----- < 150 < 100 < 50 ppm mg/NM3 ppm
03 DG set 25 KVA 9 meter ---- < 150 < 100 < 50 ppm mg/NM3 ppm
Type of Process Gas Emission:- There will be no process emission from our proposed manufacturing activity.
Fuel Details: Sr.No Name of Fuel Quantity
1 Diesel 100 ltr / month
2 FO / LDO / Wood waste 30 ton / month
Enclosures for Proposed unit of M/s. Shree Vinayak Enterprises, Kurkumbh
Enclosure: 13 Details of Hazardous Waste generation with its Management
Sr. No. Type of Waste Total Quantity of Waste
With Category No. MT/Month
01 Discarded Container (Cat. No.33.3) 6.0 MT/ Year
02 Used Oil (Cat. No. 5.1) 15 Liters / Year
MANAGEMENT OF HAZARDOUS WASTES
No. Type of Source of Collection Treatment Storage Disposal Waste Generation
01 Discarded Raw material ------Solid waste Return back Containers section storage area to raw /Bags material supplier / authorized recycler.
02 Used Oil Lubrication of H.D.P.E. --- Solid waste Sell to plant registered machineries Carboys storage area recycler
Enclosure: 15 Names & Address of Partners
No. Name of Partner Address
01 Surya Prakash Somani OAK – A104, Salrpuria Greenage, Bomannahalli, Hosur Road. Bengaluru – 560114. Karnataka 02 Chandra Prakash Somani At/Po. Khannagar, Kuruda, Balasore – 756060. Odisha