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MSDS -- SIG Centerfire Ammunition

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MSDS -- SIG Centerfire Ammunition Safety Data Sheet _____________________________________________________ Section 1. Identification Product Identifier used on the label: PISTOL V-CROWN ELITE AMMUNITION™: 380 Auto, .38 Special, 38 Super +P, 9 mm Luger, 357 Mag, 357 SIG, 40 S&W, 10 mm, 44 Special, 44 Mag, 45 Auto, 45 Colt. Other means of identification: Cartridges, Small Arms, Center Fire Pistol and Rifle Ammunition Recommended use of the chemical and restrictions on use: CAUTION! Explosive. Keep away from heat. Do not subject to mechanical shock. Particles from firing may be harmful if inhaled. Do not take internally. Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party: SIG SAUER, Inc. 72 Pease Blvd. Newington, NH 03801 1-(603) 610-3000 Emergency phone number: IN EVENT OF EMERGENCY (Spill, Leak, Fire, Exposure, Accident) CALL CHEMTREC DAY OR NIGHT (800) 424-9300 In Washington, D.C. 483-7616 Outside Continental USA (202) 483-7616 Product Name: V-Crown Elite Ammunition™ – Rev.1 – Date: June 1, 2015 Page 1 of 17 Centerfire Pistol and Rifle Ammunition Safety Data Sheet _____________________________________________________ Section 2. Hazard(s) Identification Classification of the Substance or Mixture: Explosive 1.4S H204 Acute Tox. 3 (Oral) H301 Acute Tox. 4 (Inhalation) H332 Repr. 1A H360 STOT RE 2 H373 Label Elements: Hazard Pictograms: Signal Word: DANGER Hazard Statements: H204 – Fire or projection hazard H301 – Toxic if swallowed H332 – Harmful if inhaled H360 – May damage fertility or unborn child H373 – May cause damage to organs through prolonged or repeated exposure. Precautionary Statements: P202 – Do not handle until all safety precautions have been read and understood P210 – Keep away from heat/sparks/open flames/hot surfaces. –No smoking. P234 – Keep only in original container. P250 – Do not subject to grinding/shock/friction. P260 – Do not breathe dust/fume/gas/mist vapors/spray. P264 – Wash…thoroughly after handling. P270 – Do not eat, drink or smoke when using this product P271 – Use only outdoors or in a well-ventilated area. P273 – Avoid release to the environment. P280 – Wear protective gloves/protective clothing/eye protection/face protection. P284 – Wear respiratory protection. P285 – In case of inadequate ventilation wear respiratory protection. P301 – If swallowed (acute toxicity, oral) P304 – If inhaled (acute toxicity, inhalation) P308 – If exposed or concerned (reproductive toxicity) P310 – Immediately call a POISON CENTER or doctor/ physician. Product Name: V-Crown Elite Ammunition™ – Rev.1 – Date: June 1, 2015 Page 2 of 17 Centerfire Pistol and Rifle Ammunition Safety Data Sheet _____________________________________________________ Precautionary Statements: P311 – Call a POISON CENTER or doctor/physician (Continued) P312 – Call a POISON CENTER or doctor/physician If you feel unwell. P313 – Get medical advice/attention. P320 - Specific treatment is urgent (see Section 4) P321 – Specific treatment (see Section 4) P330 – Rinse mouth. P340 – Remove victim to fresh air and keep at rest in a position comfortable for breathing. P370 – In case of fire (Explosives) P374 – Fight fire with normal precautions from a reasonable distance. P401 – Store in accordance with local/regional/national/ International regulations. P403+P233 – Store in a well ventilated place. Keep container tightly closed. P501-Dispose of contents according to local, regional, National, territorial, provincial, and international regulations. Other Hazards: General: Explosive. Keep away from heat. Do not subject to mechanical shock. Particles from firing may be harmful if inhaled. Do not take internally. Lead and barium are toxic metals that may be released during the firing of primers. Care should be taken in the cleaning of range facilities to minimize the exposure potential to lead and barium. Persons engaged in this activity should wear protective clothing with an appropriate respirator. Range operators should refer to OSHA 1910.1025 for details pertaining to the handling of lead in the work environment.. Eye: Contact with large volumes of smoke may cause minor eye irritation. Skin: Elemental and inorganic lead compounds are not absorbed through the skin. Ingestion: Acute ingestion of lead may occur from poor personal hygiene associated with the handling of lead bearing materials. The effects of lead ingestion would be similar to those listed under acute inhalation in addition to gastrointestinal irritation. Chronic ingestion of lead may occur from poor personal hygiene associated with the handling of lead bearing materials. The effects of lead ingestion would be similar to those listed under chronic inhalation. Note: Wash hands thoroughly with soap and water before eating or smoking. Inhalation: Inhalation of gases and particulates produced while firing ammunition may result in mild throat, eye, upper respiratory and lung irritation. The irritant effects may lead to lung symptoms such as bronchitis. An over exposure to gases or particulates, as a result of lead in the particulates, may also cause: anemia; nervous system symptoms which may include irritability, headache, restlessness, fatigue, muscle Product Name: V-Crown Elite Ammunition™ – Rev.1 – Date: June 1, 2015 Page 3 of 17 Centerfire Pistol and Rifle Ammunition Safety Data Sheet _____________________________________________________ Inhalation: weakness, muscle tremor, convulsions, loss of memory, visual and (Continued) hearing disturbances, loss of coordination; gastrointestinal effects such as vomiting, colic, diarrhea or constipation; circulatory symptoms such as a drop in blood pressure; reproductive effects including fertility problems, birth defects, miscarriages and possible kidney damage. Prolonged repeated over exposure to fired cartridge gases and particulates, as a result of lead in the particulates, may result in elevated blood lead levels and elevated zinc protoporphyrin levels. Symptoms of chronic overexposure to lead may include: anemia; lead lines on the gums; nervous system symptoms which may include irritability, headache, restlessness, fatigue, muscle weakness (i.e. wrist drop), muscle tremor, convulsions, loss of memory, visual and hearing disturbances, loss of coordination; gastrointestinal effects such as weight loss, vomiting, colic, diarrhea, constipation; circulatory symptoms such as a drop in blood pressure; reproductive effects including fertility problems, birth defects, miscarriages and possible kidney damage. If acute or chronic symptoms should appear, contact a physician. Blood lead and zinc protoporphryn levels are recommended and should be monitored as per OSHA 1910.1025. Product Name: V-Crown Elite Ammunition™ – Rev.1 – Date: June 1, 2015 Page 4 of 17 Centerfire Pistol and Rifle Ammunition Safety Data Sheet _____________________________________________________ Section 3. Composition/Information on Ingredients Common Name CAS Number Weight. % Range Bullet *Lead or Lead Core Lead 7439-92-1 30 - 60% *Copper Jacket Copper 7440-50-8 0 – 1% *Zinc (As Zinc Oxide) Zinc 7440-66-6 0 -0.25% 1314-13-2 *Antimony Antimony 7440-36-0 0 - 3% Cartridge Case *Brass (As Zinc & Copper) Copper See above 25 – 40% (see above) Zinc 1 – 15% *Nickel Plated Brass Nickel 7440-02-0 0 – 1% (As Nickel) *Tin/Cobalt Alloy Tin 7440-31-5 <0.1% (As Tin and Cobalt) (overcoat atop nickel plate) *Tin/Cobalt Alloy Cobalt 7440-48-4 <0.1% (As Tin and Cobalt) (overcoat atop nickel plate) *Lead Lead See above <0.1% Propellant Nitrocellulose Cellulose Nitrate 9004-70-0 0.5 – 12% Nitrocotton Gun Cotton *Nitroglycerine Trinitroglycerin 55-63-0 0 - 7% Glyceryl Trinitrate Graphite - synthetic Graphite Powder 7782-42-5 0 – 0.25% Primer *Lead Styphnate (As Lead) Basic Lead 12403-82-6 <0.1% Styphnate Tetracene Tetracene 109-27-3 <0.1% *Barium Nitrate (As Barium) Barium Salt 7440-39-3 <0.1% Nitrobarite Barium Dinitrate Bismuth Trioxide (as Bismuth) Bismuth oxide, 1304-76-3 <0.1% Bismuth yellow *Antimony Sulfide Antimonous Sulfide 7440-36-0 <0.1% (As antimony) Diantimony Trisulfide *Aluminum Aluminum 7429-90-5 <0.1% Nitrocellulose (see above) See above See above <0.1% *Nitroglycerine (see above) See above See above <0.1% *Indicates toxic chemical(s) subject to the reporting requirements of section 313 of title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR 372. Product Name: V-Crown Elite Ammunition™ – Rev.1 – Date: June 1, 2015 Page 5 of 17 Centerfire Pistol and Rifle Ammunition Safety Data Sheet _____________________________________________________ Section 4. First Aid Measures Description of First Aid Measures: Eye Contact: Rinse with water for 15 minutes. Seek medical attention. Skin Contact: Wash exposed areas thoroughly with soap and water. Remove contaminated clothing. Wash contaminated clothing prior to use. Inhalation: Remove person to fresh air. Monitor victim and seek medical attention if symptoms do not improve. Ingestion: Do not induce vomiting. Seek medical attention immediately. Description of the Most Important Symptoms or Effects: Inhalation: Potentially fatal if inhaled. Ingestion: Toxic if swallowed. Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Chronic exposure: May damage fertility. May cause adverse health effects to unborn child. May cause damage to organs through prolonged or repeated exposure. Immediate Medical Care and Special Treatment: No applicable information Section 5. Fire Fighting Measures Extinguishing Media: Suitable: Water Not appropriate: CO2, Dry chemical Specific Hazards During
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