NEW MINERAL NAMES Mrcnenr, Tr'r,Nrscnon
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Handbook of Iron Meteorites, Volume 3
Sierra Blanca - Sierra Gorda 1119 ing that created an incipient recrystallization and a few COLLECTIONS other anomalous features in Sierra Blanca. Washington (17 .3 kg), Ferry Building, San Francisco (about 7 kg), Chicago (550 g), New York (315 g), Ann Arbor (165 g). The original mass evidently weighed at least Sierra Gorda, Antofagasta, Chile 26 kg. 22°54's, 69°21 'w Hexahedrite, H. Single crystal larger than 14 em. Decorated Neu DESCRIPTION mann bands. HV 205± 15. According to Roy S. Clarke (personal communication) Group IIA . 5.48% Ni, 0.5 3% Co, 0.23% P, 61 ppm Ga, 170 ppm Ge, the main mass now weighs 16.3 kg and measures 22 x 15 x 43 ppm Ir. 13 em. A large end piece of 7 kg and several slices have been removed, leaving a cut surface of 17 x 10 em. The mass has HISTORY a relatively smooth domed surface (22 x 15 em) overlying a A mass was found at the coordinates given above, on concave surface with irregular depressions, from a few em the railway between Calama and Antofagasta, close to to 8 em in length. There is a series of what appears to be Sierra Gorda, the location of a silver mine (E.P. Henderson chisel marks around the center of the domed surface over 1939; as quoted by Hey 1966: 448). Henderson (1941a) an area of 6 x 7 em. Other small areas on the edges of the gave slightly different coordinates and an analysis; but since specimen could also be the result of hammering; but the he assumed Sierra Gorda to be just another of the North damage is only superficial, and artificial reheating has not Chilean hexahedrites, no further description was given. -
A New Sulfide Mineral (Mncr2s4) from the Social Circle IVA Iron Meteorite
American Mineralogist, Volume 101, pages 1217–1221, 2016 Joegoldsteinite: A new sulfide mineral (MnCr2S4) from the Social Circle IVA iron meteorite Junko Isa1,*, Chi Ma2,*, and Alan E. Rubin1,3 1Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, California 90095, U.S.A. 2Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A. 3Institute of Geophysics and Planetary Physics, University of California, Los Angeles, California 90095, U.S.A. Abstract Joegoldsteinite, a new sulfide mineral of end-member formula MnCr2S4, was discovered in the 2+ Social Circle IVA iron meteorite. It is a thiospinel, the Mn analog of daubréelite (Fe Cr2S4), and a new member of the linnaeite group. Tiny grains of joegoldsteinite were also identified in the Indarch EH4 enstatite chondrite. The chemical composition of the Social Circle sample determined by electron microprobe is (wt%) S 44.3, Cr 36.2, Mn 15.8, Fe 4.5, Ni 0.09, Cu 0.08, total 101.0, giving rise to an empirical formula of (Mn0.82Fe0.23)Cr1.99S3.95. The crystal structure, determined by electron backscattered diffraction, is aFd 3m spinel-type structure with a = 10.11 Å, V = 1033.4 Å3, and Z = 8. Keywords: Joegoldsteinite, MnCr2S4, new sulfide mineral, thiospinel, Social Circle IVA iron meteorite, Indarch EH4 enstatite chondrite Introduction new mineral by the International Mineralogical Association (IMA 2015-049) in August 2015. It was named in honor of Thiospinels have a general formula of AB2X4 where A is a divalent metal, B is a trivalent metal, and X is a –2 anion, Joseph (Joe) I. -
REVISION 1 an Insight at the Inverse Transformation of Realgar Altered By
REVISION 1 An insight at the inverse transformation of realgar altered by light Giovanni Pratesi1,2 and Matteo Zoppi1* 1Museo di Storia Naturale - Sezione Mineralogia e Litologia, Università di Firenze, via La Pira 4, I- 50121 Firenze, Italy. 2Dipartimento di Scienze della Terra, Università di Firenze, via La Pira 4, I-50121 Firenze, Italy. * E-mail: [email protected] ABSTRACT The light-induced alteration of realgar and β-As4S4 is a well known phenomenon but still displays interesting aspects not completely explained. In the transformation from realgar to pararealgar the molecule As4S4 undergoes a structural modification, and ever since the initial studies two important issues have been highlighted: the influence of the oxygen and the reversibility of the process. The previous study on the reversibility of the altered β-As4S4 points out that this polymorph exhibits a dual behaviour. When the light-induced alteration occurs with the presence of the air, pararealgar and arsenolite, along with amorphous material, are the products, while if the air is not present β-As4S4 turns completely into pararealgar. Moreover, when annealing the altered material in the realgar stability fields (220 °C), in the first case pararealgar and amorphous material turn into stoichiometric alacranite, while in the second case the alteration is completely reversible. Similarly, the present study focuses the attention on the question if realgar, when altered by means of the light and when annealed, might behave as β-As4S4 does. These results display that the phenomenon is more complex. The alteration of realgar with the presence of the air yields pararealgar along with arsenolite, a small quantity of uzonite and amorphous material, and when the air is not present pararealgar is the only product. -
Unbroken Meteorite Rough Draft
Space Visitors in Kentucky: Meteorites and Asteroid “Ida.” Most meteorites originate from asteroids. Meteorite Impact Sites in Kentucky Meteorite from Clark County, Ky. Mercury Earth Saturn Venus Mars Neptune Jupiter William D. Ehmann Asteroid Belt with contributions by Warren H. Anderson Uranus Pluto www.uky.edu/KGS Special thanks to Collie Rulo for cover design. Earth image was compiled from satellite images from NOAA and NASA. Kentucky Geological Survey James C. Cobb, State Geologist and Director University of Kentucky, Lexington Space Visitors in Kentucky: Meteorites and Meteorite Impact Sites in Kentucky William D. Ehmann Special Publication 1 Series XII, 2000 i UNIVERSITY OF KENTUCKY Collie Rulo, Graphic Design Technician Charles T. Wethington Jr., President Luanne Davis, Staff Support Associate II Fitzgerald Bramwell, Vice President for Theola L. Evans, Staff Support Associate I Research and Graduate Studies William A. Briscoe III, Publication Sales Jack Supplee, Director, Administrative Supervisor Affairs, Research and Graduate Studies Roger S. Banks, Account Clerk I KENTUCKY GEOLOGICAL SURVEY Energy and Minerals Section: James A. Drahovzal, Head ADVISORY BOARD Garland R. Dever Jr., Geologist V Henry M. Morgan, Chair, Utica Cortland F. Eble, Geologist V Ron D. Gilkerson, Vice Chair, Lexington Stephen F. Greb, Geologist V William W. Bowdy, Fort Thomas David A. Williams, Geologist V, Manager, Steven Cawood, Frankfort Henderson office Hugh B. Gabbard, Winchester David C. Harris, Geologist IV Kenneth Gibson, Madisonville Brandon C. Nuttall, Geologist IV Mark E. Gormley, Versailles William M. Andrews Jr., Geologist II Rosanne Kruzich, Louisville John B. Hickman, Geologist II William A. Mossbarger, Lexington Ernest E. Thacker, Geologist I Jacqueline Swigart, Louisville Anna E. -
STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials. -
Fersman Mineralogical Museum of the Russian Academy of Sciences (FMM)
Table 1. The list of meteorites in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences (FMM). Leninskiy prospect 18 korpus 2, Moscow, Russia, 119071. Pieces Year Mass in Indication Meteorite Country Type in found FMM in MB FMM Seymchan Russia 1967 Pallasite, PMG 500 kg 9 43 Kunya-Urgench Turkmenistan 1998 H5 402 g 2 83 Sikhote-Alin Russia 1947 Iron, IIAB 1370 g 2 Sayh Al Uhaymir 067 Oman 2000 L5-6 S1-2,W2 63 g 1 85 Ozernoe Russia 1983 L6 75 g 1 66 Gujba Nigeria 1984 Cba 2..8 g 1 85 Dar al Gani 400 Libya 1998 Lunar (anorth) 0.37 g 1 82 Dhofar 935 Oman 2002 H5S3W3 96 g 1 88 Dhofar 007 Oman 1999 Eucrite-cm 31.5 g 1 84 Muonionalusta Sweden 1906 Iron, IVA 561 g 3 Omolon Russia 1967 Pallasite, PMG 1,2 g 1 72 Peekskill USA 1992 H6 1,1 g 1 75 Gibeon Namibia 1836 Iron, IVA 120 g 2 36 Potter USA 1941 L6 103.8g 1 Jiddat Al Harrasis 020 Oman 2000 L6 598 gr 2 85 Canyon Diablo USA 1891 Iron, IAB-MG 329 gr 1 33 Gold Basin USA 1995 LA 101 g 1 82 Campo del Cielo Argentina 1576 Iron, IAB-MG 2550 g 4 36 Dronino Russia 2000 Iron, ungrouped 22 g 1 88 Morasko Poland 1914 Iron, IAB-MG 164 g 1 Jiddat al Harasis 055 Oman 2004 L4-5 132 g 1 88 Tamdakht Morocco 2008 H5 18 gr 1 Holbrook USA 1912 L/LL5 2,9g 1 El Hammami Mauritani 1997 H5 19,8g 1 82 Gao-Guenie Burkina Faso 1960 H5 18.7 g 1 83 Sulagiri India 2008 LL6 2.9g 1 96 Gebel Kamil Egypt 2009 Iron ungrouped 95 g 2 98 Uruacu Brazil 1992 Iron, IAB-MG 330g 1 86 NWA 859 (Taza) NWA 2001 Iron ungrouped 18,9g 1 86 Dhofar 224 Oman 2001 H4 33g 1 86 Kharabali Russia 2001 H5 85g 2 102 Chelyabinsk -
LIGHT-INDUCED CHANGES in MOLECULAR ARSENIC SULFIDES Different Steps of the Light Treatment
American Mineralogist, Volume 91, pages 1323–1330, 2006 Light-induced changes in molecular arsenic sulÞ des: State of the art and new evidence by single-crystal X-ray diffraction PAOLA BONAZZI,* LUCA BINDI, GIOVANNI PRATESI, AND SILVIO MENCHETTI Dipartimento di Scienze della Terra, Università di Firenze, via La Pira 4, I-50121 Firenze, Italy ABSTRACT β Light-induced structural changes in single crystals belonging to the -As4S4-As8S9 series and in a β crystal of synthetic -As4S3 were monitored step by step by determining the unit-cell dimensions. A marked increase of unit-cell volume as a function of exposure time was observed for all the crystals β belonging to the -As4S4-As8S9 series except for stoichiometric alacranite (As8S9). No signiÞ cant change β upon long exposures to light was observed for the synthetic -As4S3 crystal. Crystal structure reÞ ne- ments were carried out for crystals with different composition at selected steps of the light-induced process. The structural results clearly showed that the percentage of the As4S5 molecule in the structure increases when a crystal is exposed to light. Therefore, the increment of the unit-cell volume induced by light exposure appears to be related to a random replacement of As4S5 for As4S4 in the structure → according to the reaction 5As4S4 + 3O2 4As4S5 + 2As2O3. The results obtained in the present study combined with a critical review of data previously published indicate that the As4S4 molecule is able to incorporate sulfur to convert to As4S5 upon exposure to light, whereas either As4S3 or As4S5 mol- ecules do not go undergo any modiÞ cation. -
Metallographic Techniques for Iron Meteorites
A Note on Metallographic I Meteorites George F. Vander Metal Physics Research, Carpenter Technology Corporation, Reading, PA 19612 Meteorites are particularly fascinating subjects for metallographic examination, not merely because of their extraterrestial origin, but also because of the rich variety of microstructural constituents encountered. While their structure can be assessed use of the familiar nital and picral etchants used extensively for steels, application of selective etchants, including those that produce selective coloration, greatly increases the amount of infor mation obtained by light microscopy. The article describes efforts to preferentially darken or color microstructural constituents in iron meteorites: kamacite (ferrite), Neumann bands (mechanical twins), taenite (austenite), cohenite (Fe-Ni carbide similar to ce mentite), martensite and schreibersite/rhabdite (Fe-Ni phosphides). The influence of con centration gradients, deformation, and reheating on the structure can be clearly observed by the use of tint etchants. INTRODUCTION iron portion of meteorites, as in the iron meteorites, is opaque to and Meteorites have fascinated engineers and requires reflected-light studies. scientists for many years. Research on me The classification of iron meteorites is a teorites began with mineralogists and ge complex Classification is based on ologists and the major phases and constit macrostructural and microstructural char uents in iron meteorites were identified acteristics or chemical ,-,,..,.,.,,.. -e-,,..,.,,i.-ir'n and named prior to Henry Clifton Sorby's Ga, Ge, Ir contents). The two "UQYIPn,,, first observation in 1863 of the microstruc tunately. are consistent. In terms, ture of polished and etched manmade met there are three categories of iron meteo- als. Iron meteorites are but one of several rites-hexahedrites, and general categories of meteorites. -
Tnp Avrerrcar{ Mrxerar,Ocrsr
Tnp AvrERrcAr{ MrxERAr,ocrsr JOURNAL OF THE MINERALOGICAL SOCIETY OF AMERICA Vor. 16 JANUARY,1931 No. I A MICROSCOPIC INVESTIGATION OF MOLYBDENITE ORE FROM CLIMAX, COLORADO Llovn W. Sraprrs ann Cnanr,ns W. Coor, University of Michi,gan. It is a well known fact that although the occurrenceof molybde_ num minerals is widespread, the deposits of economic value are very few; the one at Climax, Colorado, being the largest known deposit. A microscopic study of a large suite of specimensfrom this d.e_ posit was undertaken in the hope that it might shed some light on the origin of this very important ore body. It is, therefoie, not the purpose of this paper to present a detailed description of the many sectionsstudied, but rather to record those observations which may possibly have a bearing on the question of the origin of the deposit. Loc,q.rroNaNo DBvrr,opMENT The camp of the Climax Molybdenum Company is located on the top of the continental Divide at Fremont pass, about fifteen miles northeast of Leadville. The town of climax has an altitude of 11,300 feet, and the present working tunnel is about one mile east of the village at an altitude of. 12,200feet. There is a glacial cirque or amphitheater which opens toward the northwest at Fremont Pass and is bounded on the northeast by Bartlett Moun_ tain and on the southwest by ceresco Mountain. rt is on the south- west flank of Bartlett Mountain that the principal outcrop of the ore occurs. The Climax region was first prospected becauseof the discovery of rich gold placers in the district. -
Cape York: the Extraordinary Mineralogy of an Ordinary Iron Meteorite and Its Implication for the Genesis of III AB Irons
Geochemical Journal, Vol. 11, pp. 207 to 217, 1977 207 Cape York: The extraordinary mineralogy of an ordinary iron meteorite and its implication for the genesis of III AB irons A. KRACHER,1 G. KURATI and V. F. BUCHWALD2 Division of Mineralogy and Petrology, Natural History Museum, A-1014 Vienna, Austria' and Department of Metallurgy, Technical University of Denmark, DK-2800 Lyngby, Denmark2 (Received July 1, 1977) A study of accessory minerals in the Cape York iron meteorite has been carried out with the electron microprobe. Phases analyzed include chromite, sphalerite, two closely related potassium-bearing sulfides, silica, and native copper. In addition, four phosphate minerals were found: One chemically similar to buchwaldite, but rather rich in iron, one corresponding to terrestrial maricite, and two more, which seem to be new minerals on the basis of microprobe analysis. Evidence from the composition of accessory minerals as well as texture elucidates some details of the fractional crystallization of the group III AB parent melt. A modification of the fractional crystallization model is therefore proposed. We suggest that sulfide nodules have originated as droplets of an immiscible sulfur-rich liquid that continuously segregated from the parent melt during crystallization of the metal. The modified model also explains the Ni/Cr anticorrelation and the high abundance of sulfur in group III AB irons which could not be satisfactorily explained by previous models. INTRODUCTION the compilation of alpha factors by ALBEE and RAY (1970). For other minerals a correction program by The Cape York iron meteorite is the second WEINKE et al. (1974) based on standard ZAF-correc largest recovered iron, and the largest meteorite tion procedures was used. -
The Meteoritical Bulletin, No. 99, April 2012*
The Meteoritical Bulletin, No. 99, April 2012* Laurence A.J. GARVIE Center for Meteorite Studies, Arizona State University, Tempe, Arizona 85287-1404, USA. Abstract – This issue of the Meteoritical Bulletin reports on 1075 meteorites divided between 468 non-Antarctic and 607 Antarctic meteorites. Written descriptions are given for eight falls (Fuhe, Kemer, Lorton, Mason Gully, Mifflin, Red Canyon Lake, Varre-Sai, and Whetstone Mountains). Particularly notable are descriptions and chemical data for 42 new iron meteorites, many of which are unpaired. Also reported are seven Martian meteorites totaling 1447.1 g (four non-Antarctic) and 14 lunar meteorites totaling 9451 g (10 non-Antarctic). Other noteworthy meteorites include NWA 5958, a C3.0-ung with an extremely 16O-rich bulk oxygen isotopic composition; Sayh al Uhaymir 493, an ungrouped achondrite with significant ferric iron, and Northwest Africa 6704, an unusual ungrouped achondrite characterized by relatively ferroan mafic silicate minerals with oxygen isotopic composition that plots within the field for acapulcoites-lodranites. Also reported are two new dense collection areas: Biduna Blowhole in Australia and Stump Spring in the United States. Antarctic meteorites reported include those recovered by the ANSMET (US) and NIPR (Japan) meteorite recovery programs. *Prepared by the Nomenclature Committee of the Meteoritical Society under the Editorship of L. Garvie. Members for 2011 are M Grady, R Greenwood, J Grossman (Database editor), H Haack, C Herd (Chair), W Hsu, T Mikouchi, S Mostefaoui, S Murty, P Rochette, A Ruzicka, C Smith (Secretary), M Weisberg, K Welten, L Welzenbach. Further information can be found at http://meteoriticalsociety.org/bulletin/TermExpirations2012.htm E1 INTRODUCTION composition for the olivine (Fa23-25 average 24, sd=1) than for the The Meteoritical Bulletin is the announcement for meteorite pyroxene (average Fs19, sd=4). -
Smithite Agass2 C 2001-2005 Mineral Data Publishing, Version 1
Smithite AgAsS2 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals commonly equant, {100}, {001}, {111}, {111}, and a dozen other forms; also tabular on {100}, to 3 mm; pseudohexagonal. Physical Properties: Cleavage: Perfect on {100}. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 1.5–2 VHN = n.d. D(meas.) = 4.88 D(calc.) = 4.926 Optical Properties: Transparent; becoming opaque on exposure to light, then translucent in thin splinters. Color: Scarlet, vermilion, pink; becoming red-orange on exposure to light. Streak: Vermilion. Luster: Adamantine. Optical Class: Biaxial (–). Pleochroism: Slight in transmitted light. Orientation: Y = b; Z ∧ c = 6.5◦. Dispersion: Strong. n = 3.27(9) 2V(meas.) = ∼65◦ R1–R2: (400) 40.7–44.0, (420) 40.0–43.2, (440) 39.3–42.4, (460) 38.7–41.5, (480) 37.9–40.4, (500) 37.0–39.2, (520) 36.0–38.0, (540) 35.0–36.6, (560) 33.8–35.4, (580) 32.7–34.7, (600) 32.0–34.0, (620) 31.4–33.4, (640) 31.0–32.9, (660) 30.6–32.4, (680) 30.4–31.8, (700) 30.1–31.4 Cell Data: Space Group: A2/a. a = 17.23 b = 7.78 c = 15.19 β = 101◦120 Z=24 X-ray Powder Pattern: Synthetic. 2.82 (100), 3.21 (80), 2.72 (60), 1.953 (50), 1.701 (40), 1.661 (40), 1.608 (40) Chemistry: (1) (2) Ag 43.9 43.69 As 28.9 30.34 Sb 0.4 S 26.0 25.97 Total 99.2 100.00 (1) Binntal, Switzerland.