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(UK only) The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product SAFETY INFORMATION STEWARD® at work. Insecticide – contains 300 g/kg indoxacarb Contains Indoxacarb. May produce an allergic reaction Du Pont (UK) Limited, Crop Protection Products Wedgwood Way, Stevenage. Herts. SG1 4QN WARNING Tel: (01438) 734450 or [email protected] Emergency 24-hour contact: - Telephone: UK 0870 820 0418, Ireland 01 901 4670 England and Wales - National Poisons Information Service 111 Scotland - National Poisons Information Service 08454 24 24 24 PCS No 02603, Ireland: National Poisons Information Centre (01) 809 2166 MAPP No 13149 Harmful if swallowed. date (UK only) This label is May cause damage to organs (nervous system). compliant with the CPA Very toxic to aquatic life with long lasting effects FOR PROFESSIONAL USE ONLY Voluntary Initiative Guidance Do not breathe vapours/spray. Wash hands and face thoroughly after handling. A water dispersibleto granule contain- Do not eat, drink or smoke when using this product. ing 300 g/kg indoxacarb for the IF exposed or if you feel unwell: Call a POISON Centre or doctor/physician. control of caterpillars in , Collect spillage. SPECIMENcauliflower, broccoli, apples, pears Dispose of contents / container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty and various protected fruiting ve - clean containers which can be disposed of as non-hazardous waste. 2015getables and pollen beetle in Winter Do not contaminate water with the product or its container (Do and Spring oilseed rape. not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). To avoid risks to human health and the environment, comply with the instructions for use PCS No 02603, MAPP No 13149 ® DuPont’s registered trademark 250 g ℮ K-34733/31502 - UK / IRELAND

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IMPORTANT INFORMATION FIELD OF USE: For use only as an agricultural/horticultural insecticide FOR PROFESSIONAL USE ONLY Crops Max. Individual dose Max. Latest time of (g product / ha number of application or 100 l water) treatments Cabbage, cauliflower,- broccoli 85 g/ha 3 per crop 1 day before harvest Protected cucumber, courgette, marrow, winter squash, 12.5 g/100 l water 6 per year 1 day before harvest pumpkin, melon, aubergine, tomato and pepper Apples, pears 250 g/ha 3 per year 7 days before harvest Winter and Spring oilseed rape 85 g/ha 1 per crop Before GS 60 (first PCS No 02603, MAPP No 13149 date flowers open stage) A water dispersible granule containing 300 g/kg indoxacarb for the control of caterpillars OTHER SPECIFIC RESTRICTIONS in cabbage, cauliflower, broccoli, apples, pears and various protected fruiting vegetables toWhen applying to protected crops the maximum spray concentration must not exceed 12.5 g and pollen beetle in Winter and Spring oilseed rape. product/100 litres of water (UK only) The (COSHH) Control of Substances Hazardous to Health Regulations may apply (UK only) This product qualifies for inclusion within the Local Environment Risk Assessment for to the use of this product at work. Pesticides (LERAP) scheme for broadcast air-assisted sprayers only. Before each spraying op- SPECIMENeration from a broadcast air-assisted sprayer, either a LERAP must be carried out in accor- Du Pont (UK) Limited, Crop Protection Products dance with CRD’s published guidance or the statutory buffer zone must be maintained. The Wedgwood Way, Stevenage. Herts. SG1 4QN results of the LERAP must be recorded and kept available for three years Tel: (01438) 734450 or [email protected] 2015 (IRL only) – Method of application: Tractor mounted sprayer, Knapsack and Orchard blast sprayer Emergency 24-hour contact: Telephone: UK 0870 820 0418, Ireland 01 901 4670 READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSIS- England and Wales - National Poisons Information Service 111 (UK only) This label is TENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING Scotland - National Poisons Information Service 08454 24 24 24 compliant with the CPA PLANT PROTECTION PRODUCTS Ireland: National Poisons Information Centre (01) 809 2166 Voluntary Initiative Guidance

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SAFETY PRECAUTIONS (Ireland only) Broadcast air-assisted sprayers - To protect aquatic organisms respect an unsprayed buffer zone of 15m to surface water bodies. OPERATOR PROTECTION Engineering control of operator exposure must be used where reasonably practicable in STORAGE AND DISPOSAL addition to the following personal protective equipment: KEEP AWAY FROM FOOD DRINK AND FEEDING STUFFS WEAR SUITABLE PROTECTIVE GLOVES AND SUITABLE PROTECTIVE RESPIRATORY KEEP OUT OF REACH OF CHILDREN PROTECTIVE EQUIPMENT (disposable filtering facepiece to EN 149 FFP2, or equivalent) KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place when handling the product DO NOT RE-USE -CONTAINER FOR ANY OTHER PURPOSE WEAR SUITABLE PROTECTIVE GLOVES when during application by broadcast air-assisted sprayer. However, engineering controls may replace personal protective equipment if a COSHH assessment shows that they provide an equal or higher standard of protection. TAKE OFF IMMEDIATELY all contaminated clothing DIRECTIONS FOR USE WHEN USING DO NOT EAT, DRINK OR SMOKE. IMPORTANT: This information is approved as part of the Product Label. All instructions IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). within this section must be read carefully in order to obtain safe and successful use of this product. ENVIRONMENTAL PROTECTION date (UK only) DO NOT ALLOW DIRECT SPRAY from broadcast air-assisted sprayers to fall within RESTRICTIONS 15 m of the top of the bank of a static or flowing water body, unless a Local Environment Risk Steward must not be applied to any crop suffering from stress as a result of drought, Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 5 m of the top waterlogging,to low temperatures, pest or disease attack, nutrient or lime deficiency or other of a ditch which is dry at the time of application. Aim spray away from water. factors reducing crop growth. (UK only) This product qualifies for inclusion within the Local Environment Good agricultural practice suggests that Steward should be used when bees are less Risk Assessment for Pesticides (LERAP) scheme for broadcast air-assistedSPECIMENactive (i.e. early morning or late evening). sprayers only. Before each spraying operation from a broadcast air-assisted sprayer, either a LERAP must be carried out in accordance with CRD’s CONTROL published guidance or the statutory buffer zone must be maintained. The 2015Steward is an oxadiazine (IRAC group 22) insecticide used for the moderate control of results of the LERAP must be recorded and kept available for three years. pollen beetle (Meligethes spp.) and the larvae of various Lepidopteran (caterpillar) species. Activity is by ingestion and contact. The product also shows ovicidal efficacy against some DO NOT CONTAMINATE WATER WITH THE PRODUCT OR ITS CONTAINER. Do not clean application species. Paralysis of the pest occurs within a few hours of exposure and results in equipment near surface water/ Avoid contamination via drains from farmyards and roads. cessation of movement and feeding. Optimal effectiveness takes 6-7 days. K-34733/31502 - UK / IRELAND - PAGE 5

Insect resistance Protected cucumber (gherkin), courgette (zucchini), marrow, winter squash, pumpkin, When insecticides with the same mode of action are used repeatedly over several years melon, aubergine, tomato and pepper to control the same species in the same field, naturally-occurring resistant strains may Pests controlled: Golden twin-spot (Chrysodeixis chalcites), Beet armyworm survive a correctly applied treatment, propagate, and become dominant in that field. An (Spodoptera exigua), Cabbage moth (Mamestra brassicae), Tomato moth insect can be resistant if the product applied under recommended conditions does not (Lacanobia oleracea), Silver y-moth (Autographa gamma) and other work well. Some (e.g. Cydia pomonella) have developed resistance to commercially Plusia species and leafrollers. available products. When resistance occurs, recommended rates fail to suppress the pest Dose: 0.0125% w/v (12.5 g/100 L of water) population below economic thresholds. Timing: - Treat as soon as the first caterpillars (damage) are detected. Subsequent It is important that the grower considers the following: treatments may be applied at 8 –14 day intervals as required. • Alternate the use of Steward with products with a different mode of action than indoxacarb. • Monitor insect populations and apply Steward when locally determined economic Apples and pears thresholds are reached. More than one application may be necessary for any infestation. Pests controlled: Steward will provide moderate control of Marbled orchard tortrix (Hedya • Follow the directions for use as mentioned on this label, regarding dose, interval and nubiferana), Large fruit tree tortrix (Archips podana), Rose tortrix optimum application timing. (Archips rosana), Straw-coloured tortrix ( spectrana), Dark fruit Growers should consult the IRAG website for further information on the current resistance datetree tortrix (Pandemis heparana), Bud moth (Spilonota ocellana), management strategy for pollen beetle. Summer fruit tortrix (Adoxyphyes orana), Codling moth (Cydia pomonella), Winter moth (Operopthtera brumata) and Orthosia spp. Dose:to A rate of 250 g/ha should be used for trees of 3.75 m height in a single row CROPS system, 3.25 m height in a 2 or 3 row system and 2.25 m in a 5 row system. Steward may be applied to the following crops: Where tree height and/or canopy density is reduced, the dose (and Cabbage, cauliflower and broccoli water volume) should be adjusted in accordance with an appropriate SPECIMEN dose adjustment scheme, for example PACE. However, if reducing the Pests controlled: Cabbage whites (Pieris spp.), Cabbage moth (Mamestra brassicae), dose according to tree height or canopy density, do not use less than Garden pebble moth (Evergestis forficalis), Cabbage leafroller 170 g/ha. Consult your specialist advisor for further information. Further (Clepsis spectrana) and Diamondback moth (Plutella xylostella2015). information on the PACE scheme is available from HDC, or see the HDC Dose: 85 g/ha in 200 l/ha using boom sprayer. fact sheet available from HSE’s website Timing: Treat when first caterpillars are detected or 7-10 days after trapping http://www.pesticides.gov.uk/HDC.pdf of the first adults in pheromone traps. Subsequent treatments may be Timing: Apply at egg-hatch. Subsequent treatments may be applied at 10 –14 applied at 8 –14 day intervals as required. day intervals. K-34733/31502 - UK / IRELAND - PAGE 6

Winter and Spring oilseed rape Pest controlled: Steward offers moderate control of Pollen beetle (Meligethes spp.) Dose 85 g/ha in 200 l/ha using boom sprayer. Timing Apply when pollen beetles are present and reaching threshold levels. Application may be made before GS 60 first flowers open growth stage.

MIXING Before using Steward, make sure that the spraying equipment is clean. Steward mixes - easily with water, but the following mixing procedure should be followed: Quarter fill the spray tank with clean water, start the agitation and add the required quantity of Steward directly to the tank without prior creaming. Continue agitation while topping up the tank and while spraying. (IRL only) Follow the Good practice guide for empty pesticide containers.

SPRAY TANK CLEAN-OUT Immediately after application, completely drain spray equipment. Thoroughly rinse sprayer date and flush the hoses, boom and nozzles with clean water. Loosen and physically remove visible deposits. Remove and clean nozzles, screens and strainers. Flush the entire system with clean water. Take all necessary safety precautions when cleaning equipment. Do to not clean near wells or water sources. Consult label tank cleanup procedures for all tank mix partners and be sure to use the most rigorous procedure recommended.SPECIMEN NOTICE TO BUYER All goods supplied by us are of a high grade and we believe them to be suitable for any purpose for which we expressly supply them, but as we cannot exercise control2015 over their mixing or use, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use. K-34733/31502 - UK / IRELAND - PAGE 7

SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 and 453/2010 Telephone: +44 (0) 1438 734 000 STEWARD® E-mail address: [email protected] 1.4. Emergency telephone number Version 5.0 (replaces: Version 4.0) Emergency telephone number: UK 0870 820 0418, Ireland 01 901 4670 Revision Date 28.04.2014 Ref. 130000000325 This Safety Data Sheet adheres to the standards and regulatory requirements SECTION 2: Hazards- identification of Great Britain and may not meet the regulatory requirements in other 2.1. Classification of the substance or mixture countries. This Safety Data Sheet adheres to the standards and regulatory requirements of the Republic of Ireland and may not meet the regulatory Acute toxicity, Category 4: H302: Harmful if swallowed. requirements of other countries. Specific target organ toxicity - single exposure, Category 2: H371: May cause damage to organs. (Nervous system)

SECTION 1: Identification of the substance/mixture and of the company/undertaking Chronic aquatic toxicity, Category 1: H410: Verydate toxic to aquatic life with long lasting effects. 1.1. Product identifier Harmful R22: Harmful if swallowed. Product name: STEWARD® Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long- to term adverse effects in the aquatic environment. Synonyms: DPX-MP062 30WG 2.2. Label elements 1.2. Relevant identified uses of the substance or mixture and uses SPECIMENadvised against Use of the Substance/Mixture: Insecticide 1.3. Details of the supplier of the safety data sheet 2015 Company: Du Pont (UK) Limited Wedgwood Way Stevenage, Herts. SG1 4QN United Kingdom Exclamation mark Health hazard Environment K-34733/31502 - UK / IRELAND - PAGE 8

Warning SECTION 3: Composition/information on ingredients H302 Harmful if swallowed. H371 May cause damage to organs. (Nervous system) 3.1. Substances H410 Very toxic to aquatic life with long lasting effects. not applicable

Special labelling of certain substances and mixtures: 3.2. Mixtures EUH401 To avoid risks to human health and the environment, comply with the instructions for use. - Contains: Indoxacarb / EUH208: May produce an allergic reaction. P260 Do not breathe vapours. P260 Do not breathe spray. Indoxacarb (CAS-No.173584-44-6) P264 Wash hands and face thoroughly after handling. T; R25 Acute Tox. 3; H301 30 % P270 Do not eat, drink or smoke when using this product. R48/25 Acute Tox. 4; H332 P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/ physician. Xi; R43 Skin Sens. 1B; H317 P391 Collect spillage. N; R50/53 STOT RE 1; H372 P501 Dispose of contents/ container to a licensed hazardous-waste disposal dateXn; R20 Aquatic Acute 1; H400 contractor or collection site except for empty clean containers which can be Aquatic Chronic 1; H410 disposed of as non-hazardous waste. to Special labelling of certain substances and mixtures: The above products are REACH compliant; Registration number(s) may not be provided Restricted to professional users because substance(s) are exempted, not yet registered under REACH or are registered under another regulatory process (biocide uses, plant protection products), etc. SP 1 Do not contaminate water with the product or its containerSPECIMEN (Do not clean application equipment near surface water/Avoid contamination via drains For the full text of the R-phrases mentioned in this Section, see Section 16. from farmyards and roads). 2015For the full text of the H-Statements mentioned in this Section, see Section 16. 2.3. Other hazards SECTION 4: First aid measures This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very 4.1. Description of first aid measures bioaccumulating (vPvB). General advice: Never give anything by mouth to an unconscious person. K-34733/31502 - UK / IRELAND - PAGE 9

For specialist advice physicians should contact the National Poisons Extinguishing media which shall not be used for safety reasons: High volume water jet, Information Service: Tel. 111 for England and Wales and Tel. 08454 24 24 24 (contamination risk) for Scotland. For specialist advice contact the National Poisons Information Service: 5.2. Special hazards arising from the substance or mixture Tel. (01) 837 9964 (Healthcare Professionals) or (01) 809 2166 (Public Poisons Specific hazards during firefighting: Hazardous decomposition products formed under fire Information Line - 8am-10pm). conditions. Carbon dioxide (CO2) Nitrogen oxides (NOx) Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician. Skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately 5.3. Advice for -firefighters with soap and plenty of water. In the case of skin irritation or allergic Special protective equipment for firefighters: Wear self-contained breathing apparatus reactions see a physician. Wash contaminated clothing before re-use. and protective suit. Eye contact: If easy to do, remove contact lens, if worn. Hold eye open and rinse slowly Further information: Prevent fire extinguishing water from contaminating surface water or and gently with water for 15-20 minutes. If eye irritation persists, consult a the ground water system. Collect contaminated fire extinguishing water separately. This specialist. must not be discharged into drains. Fire residues and contaminated fire extinguishing water Ingestion: Obtain medical attention. DO NOT induce vomiting unless directed to do so must be disposed of in accordance with local regulations. by a physician or poison control center. If victim is conscious: Rinse mouth (on small fires)date If area is heavily exposed to fire and if conditions permit, let fire burn itself out with water. since water may increase the area contaminated. Cool containers/tanks with water spray. 4.2. Most important symptoms and effects, both acute and delayed to Symptoms: No cases of human intoxication are known and the symptoms of experimental SECTION 6: Accidental release measures intoxication are not known. 4.3. Indication of any immediate medical attention and special treatmentSPECIMEN needed 6.1. Personal precautions, protective equipment and emergency procedures Treatment: Treat symptomatically. Personal precautions: Control access to area. Keep people away from and upwind of spill/leak. Avoid dust formation. Avoid breathing dust. Use personal protective equipment. 2015 Refer to protective measures listed in sections 7 and 8. SECTION 5: Firefighting measures 6.2. Environmental precautions 5.1. Extinguishing media Environmental precautions: Prevent further leakage or spillage if safe to do so. Use appropriate Suitable extinguishing media: Water spray, Foam, Dry chemical, Carbon dioxide (CO2) container to avoid environmental contamination. Do not flush into surface water or sanitary K-34733/31502 - UK / IRELAND - PAGE 10 sewer system. Do not allow material to contaminate ground water system. Local authorities working solution as soon as possible - Do not store. Provide appropriate exhaust ventilation should be advised if significant spillages cannot be contained. If the spill area is porous, at places where dust is formed. Wash hands before breaks and immediately after handling the contaminated material must be collected for subsequent treatment or disposal. If the the product. Remove and wash contaminated clothing before re-use. Avoid exceeding of product contaminates rivers and lakes or drains inform respective authorities. the given occupational exposure limits (see section 8).

6.3. Methods and materials for containment and cleaning up Advice on protection against fire and explosion: Keep away from heat and sources of ignition. Avoid dust formation in confined areas. During processing, dust may form Methods for cleaning up: Clean-up methods - small spillage Soak up with inert absorbent explosive mixture in air. material. - Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean-up 7.2. Conditions for safe storage, including any incompatibilities methods - large spillage Avoid dust formation. Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal Requirements for storage areas and containers: Store in original container. Keep in according to local regulations (see section 13). Large spills should be collected properly labelled containers. Keep containers tightly closed in a dry, cool and well- mechanically (remove by pumping) for disposal. ventilated place. Store in a place accessible by authorized persons only. Keep out of the Collect leaking liquid in sealable (metal/plastic) containers. Collect and contain contaminated reach of children. Keep away from food, drink and animal feedingstuffs. absorbent and dike material for disposal. Advice on common storage: No special restrictions on storage with other products. Other information: Never return spills in original containers for re-use. Dispose of in Other data: date Stable under recommended storage conditions. accordance with local regulations. 7.3. Specific end use(s) 6.4. Reference to other sections to Plant protection products subject to Regulation (EC) No 1107/2009. For personal protection see section 8., For disposal instructions see section 13. SPECIMEN SECTION 7: Handling and storage SECTION 8: Exposure controls/personal protection 7.1. Precautions for safe handling 20158.1. Control parameters Advice on safe handling: Use only according to our recommendations. Use only clean If sub-section is empty then no values are applicable. equipment. Avoid contact with skin, eyes and clothing. Do not breathe dust or spray mist. Wear personal protective equipment. For personal protection see section 8. Prepare the 8.2. Exposure controls working solution as given on the label(s) and/or the user instructions. Use prepared Engineering measures: Ensure adequate ventilation, especially in confined areas. K-34733/31502 - UK / IRELAND - PAGE 11

Provide for appropriate exhaust ventilation and dust collection Spray application - outdoor: Tractor / sprayer with hood: No at machinery. personal body protection normally required. Contains no substances with occupational exposure limit values. Tractor / sprayer without hood: Full protective clothing Type 4 (EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345). Eye protection: Safety glasses with side-shields conforming to EN166 Backpack / knapsack sprayer: Full protective clothing Type 4 Hand protection: Material: Nitrile rubber (EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345). Glove thickness: 0.3 mm Spray application - indoor: Motorized greenhouse sprayer: Full Glove length: Standard glove type. - protective clothing Protection index: Class 6 Type 4 (EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO Wearing time: > 480 min 20345). The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from Backpack / knapsack sprayer: Full protective clothing Type 4 it. Please observe the instructions regarding permeability and (EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345). breakthrough time which are provided by the supplier of the Mechanical automatized spray application in closed tunnel: No gloves. Also take into consideration the specific local conditions personal body protection normally required. under which the product is used, such as the danger of cuts, date abrasion, and the contact time. The suitability for a specific When exceptional circumstances would require an access to workplace should be discussed with the producers of the to the treated area before the end of re-entry periods, wear full protective gloves. Gloves must be inspected prior to use. Gloves protective clothing Type 6 (EN 13034), nitrile rubber gloves class should be discarded and replaced if there is any indication of 2 (EN 374) and nitrile rubber boots (EN 13832-3 / EN ISO 20345). degradation or chemical breakthrough. Gauntlets shorter than To optimize the ergonomy it may be recommended to use cotton 35 cm long shall be worn under the combinationSPECIMEN sleeve. Before underwear when wearing some fabrics. Take advice from removing gloves clean them with soap and water. supplier. Garment materials that are resistant to both water vapour and air will maximise wearing comfort. Materials should Skin and body protection: Manufacturing and processing work: Full protective2015 clothing be robust to maintain the integrity and barrier in use. The Type 5 (EN 13982-2) permeation resistance of the fabric must be verified Mixer and loaders must wear: Full protective clothing Type 5 + 6 independently of the « type » protection recommended, to (EN ISO 13982-2/ EN 13034) Rubber apron Nitrile rubber boots ensure an appropriate performance level of the material (EN 13832-3 / EN ISO 20345). adequate to the corresponding agent and type of exposure. K-34733/31502 - UK / IRELAND - PAGE 12

Protective measures: The type of protective equipment must be selected according to Spray application - indoor: Motorized greenhouse sprayer: Half the concentration and amount of the dangerous substance at the mask with a particle filter P1 (EN 143). specific workplace. All chemical protective clothing should be Mechanical automatized spray application in closed tunnel: No visually inspected prior to use. Clothing and gloves should be personal respiratory protective equipment normally required. replaced in case of chemical or physical damage or if contaminated. Only protected handlers may be in the area during application. SECTION 9: Physical and chemical properties Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing. 9.1. Information on- basic physical and chemical properties Keep working clothes separately. Contaminated work clothing Form: dry, free flowing granules should not be allowed out of the workplace. Wash hands and face Colour: dark brown before breaks and immediately after handling the product. When using do not eat, drink or smoke. Keep away from food, drink and Odour: mild, woody animal feedingstuffs. Remove clothing/PPE immediately if material Odour Threshold: not determined gets inside. For environmental protection remove and wash all pH: 7.5 at 10 g/l (20 °C) contaminated protective equipment before re-use. Wash Melting point/range:date Not available for this mixture. thoroughly and put on clean clothing. Dispose of rinse water in Flash point: not applicable accordance with local and national regulations. Flammability (solid, gas): Does not sustain combustion., Method: Respiratory protection: Manufacturing and processing work: Half mask with a particle to Flammability (solids) filter FFP1 (EN149) Thermal decomposition: Not available for this mixture. Mixer and loaders must wear: Half mask with a particle filter FFP1 Auto-ignition temperature: not auto-flammable (EN149) SPECIMENOxidizing properties: The product is not oxidizing. Method: Directive 67/548/EEC, Annex V, A.17. Spray application - outdoor: Tractor / sprayer with hood: No personal respiratory protective equipment normally2015 required. Explosive properties: Not explosive Tractor / sprayer without hood: Half mask with a particle filter FFP1 Lower explosion limit/ lower flammability limit: Not available for this mixture. (EN149) Upper explosion limit/ upper flammability limit: Not available for this mixture. Backpack / knapsack sprayer: Half mask with a particle filter P1 Vapour pressure: Not available for this mixture. (EN 143). Relative density: 0.8 K-34733/31502 - UK / IRELAND - PAGE 13

Bulk density: 800 kg/m3 SECTION 11: Toxicological information Water solubility: not determined Partition coefficient: n-octanol/water: not applicable 11.1. Information on toxicological effects Viscosity, kinematic: not determined Acute oral toxicity Relative vapour density: Not available for this mixture. LD50 / rat male: 1,876 mg/kg Evaporation rate: Not available for this mixture. Method: OECD Test Guideline 401 Information source:- Internal study report (Data on the product itself) 9.2. Other information LD50 / rat female : 687 mg/kg Method: OECD Test Guideline 401 Phys.-chem./other information: No other data to be specially mentioned. Information source: Internal study report (Data on the product itself) Acute inhalation toxicity LC50 / 4 h rat : > 5.6 mg/l Method: OECD Test Guideline 403 SECTION 10: Stability and reactivity Information source: Internal study report (Data on the product itself) 10.1. Reactivity: No hazards to be specially mentioned. Acute dermaldate toxicity LD50 / rat : > 5,000 mg/kg 10.2. Chemical stability: The product is chemically stable under recommended conditions Method: OECD Test Guideline 402 of storage, use and temperature. Informationto source: Internal study report (Data on the product itself) Skin irritation 10.3. Possibility of hazardous reactions: No dangerous reaction known under conditions of rabbit normal use. Polymerization will not occur. No decomposition if stored andSPECIMEN applied as directed. Result: No skin irritation Method: OECD Test Guideline 404 10.4. Conditions to avoid: To avoid thermal decomposition, do not overheat. Under severe Information source: Internal study report (Data on the product itself) dusting conditions, this material may form explosive mixtures in air. 2015 Eye irritation 10.5. Incompatible materials: No materials to be especially mentioned. rabbit Result: No eye irritation 10.6. Hazardous decomposition products: Hydrogen fluoride Method: OECD Test Guideline 405 Hydrogen chloride gas Information source: Internal study report (Data on the product itself) K-34733/31502 - UK / IRELAND - PAGE 14

Sensitisation Aspiration hazard guinea pig Maximisation Test (GPMT) The mixture does not have properties associated with aspiration hazard potential. Result: Animal test did not cause sensitization by skin contact. Method: OECD Test Guideline 406 Information source: Internal study report (Data on the product itself) Repeated dose toxicity SECTION 12: Ecological information Oral - feed rat Exposure time: 90 d 12.1. Toxicity Method: OECD Test Guideline 408 Toxicity to fish - No significant toxicological effects in 90 day studies were found below the recommended guidance values for classification., Information source: Internal study report LC50 / 96 h / Oncorhynchus mykiss (rainbow trout): 1.8 mg/l Mutagenicity assessment Method: OECD Test Guideline 203 Indoxacarb Information source: Internal study report (Data on the product itself) Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Animal Toxicity to aquatic plants testing did not show any mutagenic effects. EbC50 / 72 h / Pseudokirchneriella subcapitata (green algae): > 1.2 mg/l Carcinogenicity assessment Method: OECDdate Test Guideline 201 Indoxacarb Information source: Internal study report (Data on the product itself) Animal testing did not show any carcinogenic effects. Toxicityto to aquatic invertebrates Toxicity to reproduction assessment EC50 / 48 h / Daphnia magna (Water flea): 1.7 mg/l Indoxacarb Method: OECD Test Guideline 202 Animal testing did not show any effects on fertility. No toxicity to reproductionSPECIMENInformation source: Internal study report (Data on the product itself) STOT - single exposure Toxicity to other organisms Central nervous system LD50 / Colinus virginianus (Bobwhite quail): 508 mg/kg The substance or mixture is classified as specific target organ toxicant, single2015 exposure, Method: US EPA Test Guideline OPP 71-1 category 2. Information source: Internal study report (Data on the product itself) STOT - repeated exposure LD50 / 48 h / Apis mellifera (bees): 0.00160 mg/kg The substance or mixture is not classified as specific target organ toxicant, repeated Method: OEPP/EPPO Test Guideline 170 exposure. Oral Information given is based on data obtained from similar product. K-34733/31502 - UK / IRELAND - PAGE 15

SECTION 13: Disposal- considerations

13.1. Waste treatment methods Product: In accordance with local and national regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. The product should not be allowed to enter drains, water courses or the soil. Contaminateddate packaging: Do not re-use empty containers.

SECTIONto 14: Transport information

ADR SPECIMEN14.1. UN number: 3077 14.2. UN proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Indoxacarb) 2015 14.3. Transport hazard class(es): 9 14.4. Packing group: III 14.5. Environmental hazards: For further information see Section 12. 14.6. Special precautions for user: Tunnel restriction code: (E) K-34733/31502 - UK / IRELAND - PAGE 16

IATA_C work of pregnant workers. Take note of Directive 98/24/EC on the 14.1. UN number: 3077 protection of the health and safety of workers from the risks related to 14.2. UN proper shipping name: Environmentally hazardous substance, solid, n.o.s. chemical agents at work. Take note of Directive 96/82/EC on the control (Indoxacarb) of major-accident hazards involving dangerous substances. Take note 14.3. Transport hazard class(es): 9 of Directive 2000/39/EC establishing a first list of indicative occupational 14.4. Packing group: III exposure limit values. 14.5. Environmental hazards : For further information see Section 12. 14.6. Special precautions for user: ICAO / IATA cargo aircraft only 15.2. Chemical Safety- Assessment A Chemical Safety Assessment is not required for this/these products IMDG The mixture is registered as a plant protection product under Regulation (EC) No. 1107/2009. 14.1. UN number: 3077 Refer to the label for exposure assessment information. 14.2. UN proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Indoxacarb) 14.3. Transport hazard class(es): 9 SECTION 16: Other information 14.4. Packing group: III 14.5. Environmental hazards : Marine pollutant Text of R-phrasesdate mentioned in Section 3 14.6. Special precautions for user: no data available R20 Harmful by inhalation. R25 Toxic if swallowed. 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code R43to May cause sensitisation by skin contact. not applicable R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed. SPECIMENR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects SECTION 15: Regulatory information in the aquatic environment. 15.1. Safety, health and environmental regulations/legislation specific for the2015 substance Full text of H-Statements referred to under section 3. or mixture H301 Toxic if swallowed. Other regulations: The product is classified as dangerous in accordance with Regulation H317 May cause an allergic skin reaction. (EC) No. 1272/2008. Take note of Dir 94/33/EC on the protection of young H332 Harmful if inhaled. people at work. Take note of Dir 92/85/EEC on the safety and health at H372 Causes damage to organs through prolonged or repeated exposure.

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H400 Very toxic to aquatic life. NOEC No Observed Effect Concentration H410 Very toxic to aquatic life with long lasting effects. NOEL No Observed Effect Level Other information: professional use OECD Organisation for Economic Co-operation and Development OPPTS Office of Prevention, Pesticides and Toxic Substances Abbreviations and acronyms PBT Persistent, Bioaccumulative and Toxic STEL Short term exposure limit ADR European Agreement concerning the International Carriage of TWA time weighted average Dangerous Goods by Road vPvB very Persistent and very Bioaccumulative ATE Acute toxicity estimate - CAS-No. Chemical Abstracts Service number Further information CLP Classification, Labelling and Packaging Before use read DuPont's safety information. Take notice of the directions of use on the label. EbC50 Concentration at which 50% reduction of biomass is observed EC50 Median effective concentration ® Registered trademark of E.I. du Pont de Nemours and Company EN European Norm EPA Environmental Protection Agency ErC50 Concentration at which a 50% inhibition of growth rate is observed EyC50 Concentration at which 50 % inhibition of yield is observed The informationdate provided in this Safety Data Sheet is correct to the best of our knowledge, IATA_C International Air Transport Association (Cargo) information and belief at the date of its publication. The information given is designed only IBC International Bulk Chemical Code as a guide for safe handling, use, processing, storage, transportation, disposal and release ICAO International Civil Aviation Organization andto is not to be considered a warranty or quality specification. The above information ISO International Standard Organization relates only to the specific material(s) designated herein and may not be valid for such IMDG International Maritime Dangerous Goods material(s) used in combination with any other materials or in any process or if the material LC50 Median Lethal Concentration SPECIMENis altered or processed, unless specified in the text. LD50 Median Lethal Dose LOEC Lowest Observed Effect Concentration LOEL Lowest observable effect level 2015 MARPOL International Convention for the Prevention of Marine Pollution from Ships n.o.s. Not Otherwise Specified NOAEC No Observed Adverse Effect Concentration NOAEL No observed adverse effect level

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