Sedimentary Geology of the Middle Carboniferous of the Donbas Region

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Sedimentary Geology of the Middle Carboniferous of the Donbas Region OPEN Sedimentary geology of the middle SUBJECT AREAS: Carboniferous of the Donbas region GEOLOGY SEDIMENTOLOGY (Dniepr-Donets basin, Ukraine) Douwe J. J. van Hinsbergen1, Hemmo A. Abels1, Wolter Bosch1, Flora Boekhout2, Alexander Kitchka4, Received Maartje Hamers1, Douwe G. van der Meer3, Mark Geluk5 & Randell A. Stephenson6 8 September 2014 Accepted 1Department of Earth Sciences, University of Utrecht, Budapestlaan 4, 3584 CD Utrecht, the Netherlands, 2Institut fu¨r Geologie und 28 January 2015 Pala¨ontologie, Westfa¨lische Wilhelms-Universita¨t, Corrensstrasse 24, 48149 Mu¨nster, 3Nexen Petroleum UK Ltd., Charter Place, Vine Street, Uxbridge, Middlesex, UB8 1JG, United Kingdom, 4SE NaukaNaftogaz Res. Inst., NJSC Naftogaz of Ukraine, 8 Kyivska Published St., 08132 Vyshneve, Ukraine, 5Shell International Exploration and Production B.V., Kessler Park 1, 2288 GS Rijswijk, the 20 March 2015 Netherlands, 6School of Geosciences, Meston Building, King’s College, University of Aberdeen, Aberdeen AB24 3UE, UK. Correspondence and The Paleozoic Dniepr-Donets Basin in Belarus, Ukraine, and Russia forms a major hydrocarbon province. Although well- and seismic data have established a 20 km thick stratigraphy, field-studies of its sediments requests for materials are scarce. The inverted Donbas segment (Ukraine) exposes the middle Carboniferous part of the basin’s should be addressed to stratigraphy. Here, we provide detailed sedimentological data from 13 sections that cover 1.5 of the total of D.J.J.H. (d.j.j. 5 km of the Bashkirian and Moscovian stages and assess the paleoenvironment and paleo-current [email protected]) directions. Middle Carboniferous deposition occurred in a shelf environment, with coal deposition, subordinate fluvial facies, and abundant lower and middle shoreface facies, comprising an intercalated package of potential source and reservoir rocks. Sedimentary facies indicate a paleodepth range from below storm wave base to near-coastal swamp environments. Sedimentation and subsidence were hence in pace, with subtle facies changes likely representing relative sea-level changes. Paleocurrent directions are remarkably consistently southeastward in time and space in the different sedimentary facies across the Donbas Fold Belt, illustrating a dominant sedimentary infill along the basin axis, with little basin margin influence. This suggests that the middle Carboniferous stratigraphy of the Dniepr-Donets basin to the northwest probably contains significant amounts of fluvial sandstones, important for assessing hydrocarbon reservoir potential. he Dniepr-Donets Basin (DDB) forms a major hydrocarbon and coal basin in Eastern Europe with signifi- cant commercial significance1–7, forming a intra-cratonic, deep rift with up to 22 km of sediment1,8 that T underwent its main basin fill history between the late Devonian and Permian9–11. It is located between the Ukrainian Shield to the south and the Voronezh Massif to the north, in the southwest of the East European Craton (EEC; Fig. 1). The basin’s infill is poorly exposed, and knowledge about its sedimentary evolution largely relies on subsurface data. The eastern part of the basin, however, has been inverted in Permian and younger times and forms the Donbas Foldbelt, where Devonian and younger (volcano-) sedimentary rocks of the DDB are exposed12,13. The Donbas Foldbelt is characterised by WNW-ESE trending long-wavelength folds and faults14,15 (Fig. 1). As a result of Permian and/or Late Cretaceous/Paleogene inversion of the Donbas Foldbelt16–19, Carboniferous sedi- ments are exposed. The middle Carboniferous is exposed within the axial zone of the Donbas Foldbelt as well as near the southern margin, where it overlies pre-and syn-rift Devonian to Lower Carboniferous sediments. Outcrops in the Donbas Foldbelt are mainly confined to road and river sections and quarries. We present detailed sedimentological descriptions and paleoenvironmental interpretations from 13 sections covering 1.5 km of a total of ,5 km Bashkirian and Moscovian stratigraphy. We briefly discuss the potential implications of our findings for the sedimentary geology of the DDB farther to the northwest, where exposures of the middle Carboniferous are absent. Geological setting. The DDB overlies an Archean to Lower Proterozoic crystalline basement20,21 and trends NW- SE from Belarus through Ukraine to Russia, connecting with the Karpinsky Swell to the east (Fig. 1). The Donbas segment of the DDB formed at the southern margin of the EEC, which belonged to Laurussia in the Late Paleozoic SCIENTIFIC REPORTS | 5 : 9099 | DOI: 10.1038/srep09099 1 www.nature.com/scientificreports Figure 1 | Geological map of the Donbas Foldbelt, and in the inset, the location of the Donbas in the regional East European structural framework (modified from Stovba and Stephenson31). and was located at near-equatorial latitudes during the Early Carbo- A post-rift sag sequence is bounded by pre-Carboniferous and niferous moving to ,15u northerly latitudes in the Permian22–25. pre-Triassic unconformities12. Following the first stages of rift react- Towards the southeast, the width and thickness of the basin fill, the ivation in the Visean, the Ukrainian shield was covered by a thin layer intensity of inversion-related deformation, the degree of metamorphism of upper Visean and younger sediments. A large volume of fluvial of its exposed sediments, as well as the degree of syn-rift volcanic clastic material was transported by river systems from the northwest activity increase26. Basin inversion occurred in two or three phases in along the basin axis, prograding into a deeper water basin that existed Permo-Triassic and Late Cretaceous-Early Cenozoic time16–19. since Devonian time39. Serpukhovian and younger Carboniferous Shortening of the Donbas Foldbelt may be Permian27–30 or Late sediments commonly consist of cyclothems of marine limestone or Cretaceous-Early Cenozoic in age31,32. Inversion occurred along shale at the bottom to coal and paleosol beds at the top and form the WNW-ESE rift-bounding faults, and formed a central ‘Main focus of this study40. Anticline’33 flanked by gentle folds. To the north, the Donbas Foldbelt During the Carboniferous and much of the Early Permian, the borders the Voronezh Massif (Fig. 1) along large thrusts and reverse DDB gradually subsided. The rate of subsidence was high; the thick- faults; in the south the contact of the Donbas Foldbelt with the ness of the Carboniferous-Lower Permian, dominantly clastic stra- Ukrainian Shield is formed by reverse faults8,32. tigraphy increases from 2–3 km in the northwest to about 11 km in Sedimentation in the DDB started in Middle Devonian time with the southeast of the basin. Increased aridity and relative sea level fall deposition of pre-rift sediments under platform conditions. Judging during the early Permian resulted in deposition of red beds, carbo- from the absence of marginal facies, and based on low-temperature nates, and evaporites16,41–44. Upper Permian sedimentary rocks are geochronology, that platform originally extended far beyond the absent and post-Permian deposits are fluvio-lacustrine to shallow present limits of the basin34,35. The main rifting phase that formed marine clastics and carbonates with a maximum thickness of ,2– the DDB started in the Late Devonian (370–363 Ma36,37 and was 2.5 km12. associated with basement doming and mafic to intermediate mag- The Carboniferous stratigraphy of the Donbas region studied here matism13. Devonian rifting led to widespread salt-deposition, has been divided into lithostratigraphical suites45. Four suites are reflected by local diapirs in the Donbas Foldbelt38. Salt formations recognized in the Mississippian, nine in the Early and Middle probably filled deep-water basins, and were preceded by deposition Pennsylvanian (or Bashkirian and Moscovian; Fig. 2). The ‘middle’ of organic-rich anoxic shales and carbonates2. Uppermost Devonian Carboniferous is more than 5 km thick (,3 km Bashkirian and 2– rocks formed large sub-aqueous clastic fans along the southern basin 2.5 km of Moscovian12,46,47). Limestone beds form regional markers margin and containing shales interbedded in coarser clastics. A total in the successive suites and have been labelled with a letter from the thickness of 4–5 km of the syn-rift basin infill was estimated2. Latin alphabet accordingly. Smaller or regionally less coherent lime- SCIENTIFIC REPORTS | 5 : 9099 | DOI: 10.1038/srep09099 2 www.nature.com/scientificreports stone beds within suites were assigned subscript successive numbers (Fig. 2). Additional subdivision has been made on the basis of the fossil content of the succession. Biozones have been coded differently from the suites, and the boundaries do not all correspond with the suite boundaries (Fig. 2). Biostratigraphy and suites subdivision form the basis for correlation of the Donbas stratigraphy to the Western European and American stratigraphies48. Results Thirteen sections in the Donbas region were studied in detail (Figs. 1, 2, 3), covering over 1.5 of the total of ,5 km of middle Carboniferous stratigraphy (Fig. 2). The studied sections together represent the majority of available outcrops of Bashkirian and Moscovian stra- tigraphy in the area. Extensive descriptions of each section are given in the Supplementary Material, with detailed sedimentary logs, descriptions, field photographs and section locations. Here, we briefly describe the sections in stratigraphic order. The oldest part of the stratigraphy was studied in the
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