Safety Data Sheets
Comm Center
Comm Center
02/29/2016 Safety Data Sheet Index Binder: Comm Center - Comm Center
Product Name CAS Number Manufacturer Version Date Page
3M BRAND DESK AND OFFICE CLEANER 3M - Stationery & office Supplies 02/10/2015 3 573
3M Dust Remover AV152A, AV152A-B, 3M - Stationery & office Supplies 11/18/2014 13 AV152B
AIRLIFT LEMON SCENT AIR FRESHENER Spartan Chemical Company, Inc. 05/18/2015 22 (AEROSOL)
Clorox Commercial Solutions Clorox Clean-Up CLOROX SALES COMPANY 06/12/2015 27 Disinfectant Cleaner with Bleach1
Clorox Healthcare Multi-Surface Quat Alcohol Clorox Professional Products 03/26/2015 37 Cleaner Disinfectant Wipes Company
ENDUST FREE NAKOMA PRODUCTS, LLC 05/11/2015 47
Expo White Board Cleaner Newell Rubbermaid 08/05/2015 51
GLANCE NA Johnson Wax Professional 07/25/2007 59
Gum Remover Johnson Wax Professional 03/07/2008 62
KEYSTONE GLASS CLEANER ECOLAB CO. 08/10/2015 65
Lemon SHine Furnature Polish Nyco Products Company 08/16/2005 74
Liquid Hand Dishwashing Detergents and Procter & Gamble - P&G 08/28/2014 76 Antibacterial Hand Soaps Household Care
Lysol Brand II Kills 99.9% of Viruses & Bacteria 77182 Reckitt Benckiser - Morris 04/27/2015 81 Disinfecting Wipes Lemon Lime Blossom Corporate Center IV
Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 92
PALMOLIVE DISHWASHER DETERGENT Colgate-Palmolive Canada Inc. 09/21/2012 100 ECO+ LEMON SPLASH
PLEDGE EVERYDAY CLEANER S.C. Johnson & Son, Inc. 02/25/2015 107 MULTISURFACE - GLADE SHIMMERING SPRUCE
Propanol 71-23-8 The Dow Chemical Company 03/31/2015 118
PURELL Hand Sanitizer GOJO Industries, Inc. 03/19/2015 130
PURELL HAND SANITIZING SPRAY GOJO Industries, Inc. 03/30/2015 145
Super Lube, Multi-Purpose Synthetic Lubricant TIG Distributing, Inc. 03/10/2010 160
Page 2 of 166 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15
Safety Data Sheet
Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13
SECTION 1: Identification
1.1. Product identifier 3M BRAND DESK AND OFFICE CLEANER 573
Product Identification Numbers 70-0061-3328-7, 70-0160-6830-9, 70-0701-7945-5, 70-0704-0450-7, 70-0709-0857-2, 70-0711-2910-3
1.2. Recommended use and restrictions on use
Recommended use Aerosol Cleaner for Office Surfaces, AEROSOL FOAM CLEANER FOR OFFICE SURFACES
1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification Flammable Aerosol: Category 1. Specific Target Organ Toxicity (single exposure): Category 1.
2.2. Label elements Signal word Danger
Symbols Flame | Health Hazard |
Pictograms
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Hazard Statements Extremely flammable aerosol.
Causes damage to organs: cardiovascular system |
Precautionary Statements
Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label).
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal.
2% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt WATER 7732-18-5 86 - 92 ISOBUTANE PROPELLANT 75-28-5 1 - 8 Trade Secret * ISOPROPYL ALCOHOL 67-63-0 3 - 5 Trade Secret * ETHOXYLATED TALL-OIL FATTY ACIDS 61791-00-2 1 - 3 Trade Secret * SODIUM CARBONATE 497-19-8 < 1 ETHANOLAMINE 141-43-5 < 0.5
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
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SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation: Remove person to fresh air. Get medical attention.
Skin Contact: Wash with soap and water. If you feel unwell, get medical attention.
Eye Contact: No need for first aid is anticipated.
If Swallowed: Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that
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Page 5 of 166 3M BRAND DESK AND OFFICE CLEANER 573 02/10/15 can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments ETHANOLAMINE 141-43-5 OSHA TWA:6 mg/m3(3 ppm) ETHANOLAMINE 141-43-5 ACGIH TWA:3 ppm;STEL:6 ppm ISOPROPYL ALCOHOL 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ISOPROPYL ALCOHOL 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin ISOBUTANE PROPELLANT 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles
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Skin/hand protection No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Foam Odor, Color, Grade: White foam, Lemon odor Odor threshold No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point 30 ºF [Test Method: Open Cup] [Details: specific method: D92] Evaporation rate >=1.00 [Ref Std: WATER=1] [Details: product as applied (without propellant)] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % Flammable Limits(UEL) 8.40 % [Details: for isobutane.] Vapor Pressure 31 - 43 psi [@ 70 ºF] [Details: (aerosol can pressure)] Vapor Density No Data Available Density 1 g/ml Specific Gravity Approximately 1 [Ref Std: WATER=1] Solubility In Water 100.00 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Volatile Organic Compounds 55 - 115 g/l Percent volatile 96 - 98 % weight VOC Less H2O & Exempt Solvents 702 - 831 g/l SECTION 10: Stability and reactivity
10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability Stable.
10.3. Possibility of hazardous reactions Hazardous polymerization will not occur.
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10.4. Conditions to avoid Heat Sparks and/or flames
10.5. Incompatible materials Not determined
10.6. Hazardous decomposition products Substance Condition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
May cause additional health effects (see below).
Skin Contact: Contact with the skin during product use is not expected to result in significant irritation.
Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Additional Health Effects:
Single exposure may cause target organ effects: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity Name Route Species Value
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Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg ISOBUTANE PROPELLANT Inhalation- Rat LC50 276,000 ppm Gas (4 hours) ISOPROPYL ALCOHOL Dermal Rabbit LD50 12,870 mg/kg ISOPROPYL ALCOHOL Inhalation- Rat LC50 72.6 mg/l Vapor (4 hours) ISOPROPYL ALCOHOL Ingestion Rat LD50 4,710 mg/kg SODIUM CARBONATE Dermal Rabbit LD50 > 2,000 mg/kg SODIUM CARBONATE Ingestion Rat LD50 2,800 mg/kg ETHANOLAMINE Inhalation- official LC50 estimated to be 10 - 20 mg/l Vapor classifica tion ETHANOLAMINE Dermal Rabbit LD50 1,000 mg/kg ETHANOLAMINE Ingestion Rat LD50 1,720 mg/kg ATE = acute toxicity estimate
Skin Corrosion/Irritation Name Species Value
ISOBUTANE PROPELLANT Professio No significant irritation nal judgeme nt ISOPROPYL ALCOHOL Multiple No significant irritation animal species SODIUM CARBONATE Rabbit No significant irritation ETHANOLAMINE Rabbit Corrosive
Serious Eye Damage/Irritation Name Species Value
ISOBUTANE PROPELLANT Professio No significant irritation nal judgeme nt ISOPROPYL ALCOHOL Rabbit Severe irritant SODIUM CARBONATE Rabbit Corrosive ETHANOLAMINE Rabbit Corrosive
Skin Sensitization Name Species Value ISOPROPYL ALCOHOL Guinea Not sensitizing pig ETHANOLAMINE Guinea Some positive data exist, but the data are not pig sufficient for classification
Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity Name Route Value
ISOBUTANE PROPELLANT In Vitro Not mutagenic ISOPROPYL ALCOHOL In Vitro Not mutagenic ISOPROPYL ALCOHOL In vivo Not mutagenic SODIUM CARBONATE In Vitro Not mutagenic ETHANOLAMINE In Vitro Not mutagenic ETHANOLAMINE In vivo Not mutagenic
Carcinogenicity Name Route Species Value
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ISOPROPYL ALCOHOL Inhalation Rat Some positive data exist, but the data are not sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration ISOPROPYL ALCOHOL Ingestion Some positive developmental data exist, Rat NOAEL 400 during but the data are not sufficient for mg/kg/day organogenesi classification s ISOPROPYL ALCOHOL Inhalation Some positive developmental data exist, Rat LOAEL 9 during but the data are not sufficient for mg/l gestation classification SODIUM CARBONATE Ingestion Not toxic to development Mouse NOAEL 340 during mg/kg/day organogenesi s ETHANOLAMINE Dermal Not toxic to development Rat NOAEL 225 during mg/kg/day organogenesi s ETHANOLAMINE Ingestion Not toxic to development Rat NOAEL 616 during mg/kg/day organogenesi s
Target Organ(s)
Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE Inhalation cardiac Causes damage to organs Multiple NOAEL Not PROPELLANT sensitization animal available species ISOBUTANE Inhalation central nervous May cause drowsiness or Human NOAEL Not PROPELLANT system depression dizziness and available animal ISOBUTANE Inhalation respiratory irritation All data are negative Mouse NOAEL Not PROPELLANT available ISOPROPYL ALCOHOL Inhalation central nervous May cause drowsiness or Human NOAEL Not system depression dizziness available ISOPROPYL ALCOHOL Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not data are not sufficient for available classification ISOPROPYL ALCOHOL Inhalation auditory system Some positive data exist, but the Guinea NOAEL 13.4 24 hours data are not sufficient for pig mg/l classification ISOPROPYL ALCOHOL Ingestion central nervous May cause drowsiness or Human NOAEL Not poisoning system depression dizziness available and/or abuse ETHANOLAMINE Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not and available animal
Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration ISOBUTANE Inhalation kidney and/or Some positive data exist, but the Rat NOAEL 13 weeks PROPELLANT bladder data are not sufficient for 4,500 ppm classification ISOPROPYL ALCOHOL Inhalation kidney and/or Some positive data exist, but the Rat NOAEL 12.3 24 months bladder data are not sufficient for mg/l classification ISOPROPYL ALCOHOL Inhalation nervous system All data are negative Rat NOAEL 12 13 weeks mg/l ISOPROPYL ALCOHOL Ingestion kidney and/or Some positive data exist, but the Rat NOAEL 400 12 weeks bladder data are not sufficient for mg/kg/day classification SODIUM CARBONATE Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.07 3 months
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data are not sufficient for mg/l classification ETHANOLAMINE Inhalation liver | kidney and/or Some positive data exist, but the Multiple NOAEL 5 weeks bladder | respiratory data are not sufficient for animal 0.656 mg/l system classification species ETHANOLAMINE Ingestion hematopoietic Some positive data exist, but the Rat NOAEL Not system | liver | data are not sufficient for available kidney and/or classification bladder | respiratory system
Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations
13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
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15.2. State Regulations Contact 3M for more information.
15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification Health: 1 Flammability: 3 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group: 10-0157-7 Version Number: 27.00 Issue Date: 02/10/15 Supercedes Date: 02/12/13
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M
3M USA SDSs are available at www.3M.com
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Safety Data Sheet
Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09
SECTION 1: Identification
1.1. Product identifier 3M(TM) Dust Remover AV152A, AV152A-B, AV152B
Product Identification Numbers 44-0051-5415-6, 70-0050-0173-3, 70-0050-0269-9, 70-0050-1903-2, 70-0050-2436-2, 70-0050-3890-9, 70-0050-4373-5, 70- 0050-4565-6, 70-0050-4715-7, 70-0050-7309-6, 70-0050-7316-1, 70-0050-7986-1, 70-0050-8052-1, 70-0051-0911-4, 70- 0051-1956-8, 70-0051-2011-1, 70-0051-2013-7, 70-0051-2070-7, 70-0051-3321-3, 70-0051-4224-8, 70-0051-4480-6, 70- 0051-4540-7, 70-0051-6293-1, 70-0051-6628-8, 70-0051-6856-5, 70-0713-0457-3, 70-0713-0458-1, 70-0713-2085-0, 70- 0713-2286-4, 70-0713-5096-4, 70-0713-6798-4, 70-0713-7295-0, 70-0713-8144-9, 70-0713-8166-2, 70-0713-9180-2, 70- 0713-9333-7, 70-0713-9390-7, 70-0714-1472-9, 70-0714-1595-7, 70-0714-2146-8, 70-0714-2147-6, 70-0714-2212-8, 70- 0714-2417-3, 70-0714-2418-1, 70-0714-2419-9, 70-0714-7652-0, 70-0714-8282-5, 70-0714-8283-3, 70-0714-8298-1, 70- 0714-8977-0, 70-0714-9081-0, 70-0714-9437-4, 70-0715-0658-1
1.2. Recommended use and restrictions on use
Recommended use Compressed gas duster.
1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Stationery and Office Supplies Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification Flammable Aerosol: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3.
2.2. Label elements Signal word Danger
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Symbols Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements Flammable aerosol.
May cause drowsiness or dizziness.
Causes damage to organs: cardiovascular system |
Precautionary Statements
Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label).
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
2.3. Hazards not otherwise classified May cause frostbite.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt 1,1-DIFLUOROETHANE 75-37-6 > 99.65 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
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SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation: Remove person to fresh air. Get medical attention.
Skin Contact: Thaw frosted skin with lukewarm water. Do not rub affected area. Get medical attention.
Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If Swallowed: Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture None inherent in this product.
Hazardous Decomposition or By-Products Substance Condition Carbonyl Fluoride During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion
5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions Avoid release to the environment.
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6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling Do not breathe thermal decomposition products. Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1,1-DIFLUOROETHANE 75-37-6 CMRG TWA:1000 ppm 1,1-DIFLUOROETHANE 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles
Skin/hand protection No chemical protective gloves are required.
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Page 16 of 166 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14
Respiratory protection
Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator
For questions about suitability for a specific application, consult with your respirator manufacturer.
Thermal hazards Wear cold insulating gloves/face shield/eye protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties General Physical Form: Gas Odor, Color, Grade: Clear, colorless with slight ethereal odor. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point -13 ºF Flash Point < -50 ºF [Details: consumer aerosol does not exhibit a flame projection, therefore it is not determined to be flammable as defined in 16 CFR, Section 1500.3(c)(6)(viii).] Evaporation rate Not Applicable Flammability (solid, gas) Flammable Aerosol: Category 2. Flammable Limits(LEL) 3.9 % volume Flammable Limits(UEL) 16.9 % volume Vapor Pressure 87 psia [@ 77 ºF] Vapor Density 2.4 [Ref Std: AIR=1] Density 0.9 g/cm3 [Details: Liquid] Specific Gravity 0.9 [Ref Std: WATER=1] [Details: Liquid] Solubility In Water 0.28 % Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 849 ºF Decomposition temperature Not Applicable Viscosity Not Applicable SECTION 10: Stability and reactivity
10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability Stable.
10.3. Possibility of hazardous reactions Hazardous polymerization will not occur.
10.4. Conditions to avoid
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Page 17 of 166 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14
Sparks and/or flames
10.5. Incompatible materials Alkali and alkaline earth metals
10.6. Hazardous decomposition products Substance Condition None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
May cause target organ effects after inhalation.
Skin Contact: Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction.
Eye Contact: Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness.
Ingestion: No health effects are expected.
Target Organ Effects:
Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
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Page 18 of 166 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14 the data are not sufficient for classification.
Acute Toxicity Name Route Species Value Overall product Inhalation- No data available; calculated ATE > 50,000 ppm Gas(4 hr) 1,1-DIFLUOROETHANE Inhalation- Rat LC50 > 437,000 ppm Gas (4 hours) 1,1-DIFLUOROETHANE Ingestion Rat LD50 > 1,500 mg/kg ATE = acute toxicity estimate
Skin Corrosion/Irritation Name Species Value
Serious Eye Damage/Irritation Name Species Value
Skin Sensitization Name Species Value
Respiratory Sensitization Name Species Value
Germ Cell Mutagenicity Name Route Value 1,1-DIFLUOROETHANE In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-DIFLUOROETHANE In vivo Some positive data exist, but the data are not sufficient for classification
Carcinogenicity Name Route Species Value 1,1-DIFLUOROETHANE Inhalation Rat Some positive data exist, but the data are not sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation Not toxic to female reproduction Rat NOAEL 2 years 25,000 ppm 1,1-DIFLUOROETHANE Inhalation Not toxic to male reproduction Rat NOAEL 2 years 25,000 ppm 1,1-DIFLUOROETHANE Inhalation Not toxic to development Rat NOAEL during 50,000 ppm organogenesi s
Target Organ(s)
Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation cardiac Causes damage to organs Human NOAEL Not poisoning sensitization and available and/or abuse animal 1,1-DIFLUOROETHANE Inhalation central nervous May cause drowsiness or Human NOAEL system depression dizziness and 100,000 ppm animal 1,1-DIFLUOROETHANE Inhalation respiratory irritation Some positive data exist, but the Not NOAEL Not not available data are not sufficient for available available
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Page 19 of 166 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14
classification
Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,1-DIFLUOROETHANE Inhalation hematopoietic Some positive data exist, but the Rat NOAEL 2 years system | kidney data are not sufficient for 25,000 ppm and/or bladder | classification respiratory system
Aspiration Hazard Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations
13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
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Page 20 of 166 3M(TM) Dust Remover AV152A, AV152A-B, AV152B 11/18/14
15.2. State Regulations Contact 3M for more information.
15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 3 Flammability: 4 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification Health: 3 Flammability: 4 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group: 19-7982-2 Version Number: 6.00 Issue Date: 11/18/14 Supercedes Date: 06/30/09
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M
3M USA SDSs are available at www.3M.com
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Page 21 of 166 Safety Data Sheet Spartan Chemical Company, Inc.
Revision Date: 18-May-2015
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier Product Name: AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Product Number: 6085 Recommended Use: Air freshener Uses Advised Against: For Industrial and Institutional Use Only
Manufacturer/Supplier: Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee, Ohio 43537 USA 800-537-8990 (Business hours) www.spartanchemical.com
24 Hour Emergency Phone Numbers: Medical Emergency/Information: 888-314-6171 Transportation/Spill/Leak: CHEMTREC 800-424-9300
2. HAZARDS IDENTIFICATION
GHS Classification Flammable Aerosols Category 1 Gases Under Pressure Liquefied gas
GHS Label Elements Signal Word: Danger Symbols:
Hazard Statements: Extremely flammable aerosol. Contains gas under pressure; may explode if heated Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. — No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Response: -Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in a well-ventilated place Disposal: Not Applicable
Hazards Not Otherwise Classified: Not Applicable
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Page 22 of 166 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 ______Other Information: • May cause skin irritation. • May cause eye irritation. • May be harmful if swallowed. • Inhalation of vapors or mist may cause respiratory irritation. • Keep out of reach of children.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-% water 7732-18-5 60-100 N-butane 106-97-8 7-13 petroleum distillates 64742-47-8 5-10 propane 74-98-6 3-7 petroleum distillates 64742-88-7 1-5
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. -Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention. -Inhalation: Move victim to fresh air If breathing is irregular or stopped, administer artificial respiration Administer oxygen if breathing is difficult -Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if you feel unwell. Note to Physicians: Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: Water spray (fog), Foam Specific Hazards Arising from the Extremely flammable aerosol. Exposure to high temperature may cause containers to burst. Chemical: Bursting aerosol containers may be propelled from fire at high speed. Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment and Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full Precautions for Firefighters: protective gear. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water. Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).
7. HANDLING AND STORAGE
Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly after handling.
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Page 23 of 166 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 ______Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 C°. Exposure to high temperature may cause containers to burst. Keep out of the reach of children.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits: . Chemical Name ACGIH TLV OSHA PEL NIOSH N-butane TWA: 1000 ppm (vacated) TWA: 800 ppm TWA: 800 ppm 106-97-8 (vacated) TWA: 1900 mg/m3 TWA: 1900 mg/m3 propane TWA: 1000 ppm TWA: 1000 ppm IDLH: 2100 ppm 74-98-6 TWA: 1800 mg/m3 TWA: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1800 mg/m3
Engineering Controls: Provide good general ventilation. If work practices generate dust, fumes, gas, vapors or mists which expose workers to chemicals above the occupational exposure limits, local exhaust ventilation or other engineering controls should be considered. Personal Protective Equipment Eye/Face Protection: Not required with expected use. Skin and Body Protection: Not required with expected use. Respiratory Protection: Not required with expected use. If occupational exposure limits are exceeded or respiratory irritation occurs, use of a NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section 3 should be considered. General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling. See 29 CFR 1910.132-138 for further guidance.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State: Aerosol Color: Colorless Odor: Lemon pH: 6.0-8.0 Melting Point / Freezing Point: No information available. Boiling Point / Boiling Range: 78 °C / 172 °F (Product without propellant) Flash Point: < -18 °C / < 0 °F (Propellant-estimated) Evaporation Rate: < 1 (Butyl acetate = 1) Flammability (solid, gas) No information available. Upper Flammability Limit: No information available. Lower Flammability Limit: No information available. Vapor Pressure: No information available. Vapor Density: No information available. Specific Gravity: 0.897 (Product without propellant) Solubility(ies): No information available. Partition Coefficient: No information available. Autoignition Temperature: No information available. Decomposition Temperature: No information available. Viscosity: No information available.
10. STABILITY AND REACTIVITY
Reactivity: This material is considered to be non-reactive under normal conditions of use. Chemical Stability: Stable under normal conditions. Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatible Materials: Strong oxidizing agents. Strong acids.
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Page 24 of 166 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 ______Hazardous Decomposition May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors. Products:
11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation. Symptoms of Exposure: -Eye Contact: Pain and redness. -Skin Contact: Drying of the skin. -Inhalation: Nasal discomfort and coughing. -Ingestion: Pain, nausea, vomiting and diarrhea. Immediate, Delayed, Chronic Effects Product Information: Data not available or insufficient for classification.
Target Organ Effects: Central nervous system. Numerical Measures of Toxicity The following acute toxicity estimates (ATE) are calculated based on the GHS document. . ATEmix (oral): 49213 mg/kg ATEmix (dermal): 20804 mg/kg ATEmix (inhalation-gas): 1669319 mg/l
Component Acute Toxicity Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 water > 90 mL/kg ( Rat ) Not Available Not Available 7732-18-5 N-butane Not Available Not Available = 658 mg/L ( Rat ) 4 h 106-97-8 petroleum distillates > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h 64742-47-8 propane Not Available Not Available = 658 mg/L ( Rat ) 4 h 74-98-6 petroleum distillates > 5000 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 5.28 mg/L ( Rat ) 4 h 64742-88-7
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity Chemical Name Algae/Aquatic Plants Fish Toxicity to Crustacea Microorganisms petroleum distillates Not Available 45: 96 h Pimephales Not Available 4720: 96 h Den-dronereides 64742-47-8 promelas mg/L LC50 heteropoda mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static petroleum distillates 450: 96 h 800: 96 h Pimephales Not Available 100: 48 h Daphnia magna 64742-88-7 Pseudokirchneriella promelas mg/L LC50 static mg/L EC50 subcapitata mg/L EC50
Persistence and Degradability: No information available. Bioaccumulation: No information available.
Other Adverse Effects: No information available.
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes: Dispose of in accordance with federal, state and local regulations. Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with federal, state and local regulations. ______
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Page 25 of 166 6085 - AIRLIFT LEMON SCENT AIR FRESHENER (AEROSOL) Revision Date: 18-May-2015 ______
14. TRANSPORT INFORMATION
DOT: UN/ID No: UN1950 Proper Shipping Name: Aerosols Hazard Class: 2.1 Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited quantity and may be shipped as a limited quantity.
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory) All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313 This product does not contain listed substances above the "de minimus" level
SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: No Fire Hazard: No Sudden release of pressure hazard: Yes Reactive Hazard: No
California Proposition 65 This product does not contain any Proposition 65 chemicals
16. OTHER INFORMATION
NFPA Health Hazards: 1 Flammability: 1 Instability: 0 Special: N/A HMIS Health Hazards: 1 Flammability: 2 Physical Hazards: 2
Revision Date: 18-May-2015 Reasons for Revision: No information available.
Disclaimer: The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 26 of 166
SAFETY DATA SHEET
Issuing Date January 5, 2015 Revision Date June 12, 2015 Revision Number 1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox Commercial Solutions® Clorox® Clean-Up® Disinfectant Cleaner with Bleach1
Other means of identification
EPA Registration Number 67619-17
Recommended use of the chemical and restrictions on use
Recommended use Disinfecting bleach spray cleaner
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers For Medical Emergencies, call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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Page 27 of 166 Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin corrosion/irritation Category 3 Serious eye damage/eye irritation Category 2A
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning
Hazard Statements Causes mild skin irritation Causes serious eye irritation
Physical State Liquid Odor Citrus, herbaceous, bleach Appearance Clear, pale yellow
Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses.
Precautionary Statements - Response Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin If skin irritation occurs: Get medical advice/attention.
Precautionary Statements - Storage None
Precautionary Statements - Disposal None
Hazards not otherwise classified (HNOC) The following medical conditions may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, emphysema, or obstructive lung disease.
Unknown Toxicity 0.08% of the mixture consists of ingredient(s) of unknown toxicity
Other information Toxic to aquatic life with long lasting effects
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Page 28 of 166 Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015
Interactions with Other Chemicals Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, or acids to produce hazardous gases, such as chlorine and other chlorinated compounds.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 1 - 5 * Sodium hydroxide 1310-73-2 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists.
Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If irritation develops, call a doctor.
Inhalation Move to fresh air. If breathing is affected, call a doctor.
Ingestion Call a poison control center or doctor immediately. Have person sip a glassful of water if able to swallow. DO NOT induce vomiting unless told to do so by a poison control center or doctor.
Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Stinging and irritation of eyes. Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
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Page 29 of 166 Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical No information available.
Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions See Section 12 for ecological Information.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Products Products containing ammonia, toilet bowl cleaners, rust removers, or acids.
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Page 30 of 166 Clorox Commercial Solutions Clorox® Clean-Up® Disinfectant Cleaner with Bleach1 Revision Date June 12, 2015
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH 3 Sodium hydroxide 3 3 IDLH: 10 mg/m Ceiling: 2 mg/m TWA: 2 mg/m 3 1310-73-2 Ceiling: 2 mg/m Sodium hypochlorite None None None 7681-52-9 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use.
Skin and Body Protection Wear protective gloves and protective clothing.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Liquid Appearance Clear Odor Citrus, herbaceous, bleach
Color Pale yellow Odor Threshold No information available
Property Values Remarks/ Method pH 12.4 - 12.8 None known
Melting/freezing point No data available None known
Boiling point / boiling range No data available None known
Flash Point Not flammable None known
Evaporation rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limits in Air
Upper flammability limit No data available None known
Lower flammability limit No data available None known
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity ~1.03 None known
Water Solubility Soluble in water None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water No data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive Properties Not explosive Oxidizing Properties No data available
Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available
10. STABILITY AND REACTIVITY
Reactivity Reacts with other household chemicals such as products containing ammonia, toilet bowl cleaners, rust removers, or acids to produce hazardous gases, such as chlorine and other chlorinated compounds.
Chemical stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Conditions to avoid None known based on information supplied.
Incompatible materials Products containing ammonia, toilet bowl cleaners, rust removers, vinegar, or acids.
Hazardous Decomposition Products None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Exposure to vapor or mist may irritate respiratory tract.
Eye Contact May cause eye irritation.
Skin Contact Prolonged contact may cause irritation.
Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea.
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - 7681-52-9 Sodium hydroxide - 1350 mg/kg (Rabbit) - 1310-73-2
Information on toxicological effects
Symptoms May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite - Group 3 - - 7681-52-9 IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI).
Aspiration Hazard No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document Not applicable
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12. ECOLOGICAL INFORMATION
Ecotoxicity Toxic to aquatic life with long lasting effects.
Persistence and Degradability No information available.
Bioaccumulation No information available.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT Not restricted.
TDG Not restricted for road or rail.
ICAO Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception.
IATA Not restricted, as per Special Provision A197, Environmentally Hazardous Substance exception.
IMDG/IMO Not restricted, as per IMDG Code 2.10.2.7, Marine Pollutant exception.
15. REGULATORY INFORMATION
Chemical Inventories
TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
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SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No
Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CWA - Reportable CWA - Hazardous Chemical Name CWA - Toxic Pollutants CWA - Priority Pollutants Quantities Substances Sodium hypochlorite 100 lb X 7681-52-9 Sodium hydroxide 1000 lb X 1310-73-2
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Extremely Hazardous Substances Chemical Name Hazardous Substances RQs RQ RQs Sodium hypochlorite RQ 100 lb final RQ 100 lb 7681-52-9 - RQ 45.4 kg final RQ Sodium hydroxide RQ 1000 lb final RQ 1000 lb 1310-73-2 - RQ 454 kg final RQ
EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING: EYE AND SKIN IRRITANT. Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Avoid contact with skin. Wear protective eyewear. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. Harmful if swallowed. For sensitive skin or prolonged use, wear gloves. Vapors may irritate. Avoid prolonged breathing of vapors. Use only in well ventilated areas. Not recommended for use by persons with heart conditions or chronic respiratory problems such as asthma, emphysema or obstructive lung disease.
US State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Sodium hypochlorite X X X X 7681-52-9 Sodium hydroxide X X X X 1310-73-2
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International Regulations
Canada WHMIS Hazard Class D2B - Toxic materials
16. OTHER INFORMATION
NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards -
HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B
Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Revision Date June 12, 2015
Revision Note Revisions Sections 8 and 14.
Reference 1103369/50546003.004
General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 36 of 166
SAFETY DATA SHEET
Issuing Date March 26, 2015 Revision Date New Revision Number 0
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox Healthcare® Multi-Surface Quat Alcohol Cleaner Disinfectant Wipes
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended use Moistened disinfecting wipes
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers For Medical Emergencies call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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2. HAZARDS IDENTIFICATION
Classification
This product is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Serious eye damage/eye irritation Category 2B Flammable liquids Category 3
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Warning
Hazard statements Causes eye irritation Flammable liquid and vapor
Appearance Clear, colorless liquid Physical State Thin liquid absorbed into Odor Solvent, alcohol
absorbed into white, non-woven wipes non-woven wipes
Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear eye protection such as safety glasses.
Precautionary Statements - Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water. In case of fire: Use dry chemical, carbon dioxide (CO2), foam, or water spray to extinguish.
Precautionary Statements - Storage Store in a well-ventilated place. Keep cool.
Precautionary Statements - Disposal Dispose of contents in accordance with all applicable federal, state, and local regulations.
Hazards not otherwise classified (HNOC) Inhalation of high concentrations of vapor or mist may cause irritation of the respiratory tract, headaches, dizziness, nausea, vomiting, and malaise. Ingestion of liquid may cause central nervous system depression, gastrointestinal irritation, nausea, vomiting, and diarrhea.
Unknown Toxicity No information available.
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Other information Toxic to aquatic life with long lasting effects.
Interactions with Other Chemicals Can react with strong oxidizers, inorganic acids, and halogens.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight % Trade Secret Isopropyl alcohol 67-63-0 15 - 25 * n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 85409-23-0 0.1 - 0.2 * ammonium chloride n-Alkyl (5% C12, 60% C14, 30% C16, 5% C18) 53516-76-0 0.1 - 0.2 * dimethyl benzyl ammonium chloride * The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
General Advice Show this safety data sheet to the doctor in attendance.
Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice.
Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor.
Inhalation Move to fresh air. If breathing problems develop, call a doctor.
Ingestion Drink a glassful of water. Call a doctor or poison control center.
Protection of First-aiders Remove all ignition sources. Use personal protective equipment as required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and Liquid may cause eye irritation. Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Dry chemical, carbon dioxide (CO2), foam, or water spray.
Unsuitable Extinguishing Media Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical Alcohol flames may not be readily visible. Vapors are heavier than air and may travel to source of ignition and flash back. Vapors may form explosive mixtures with air.
Hazardous Combustion Products Oxides of carbon.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep containers cool with water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Eliminate all potential sources of ignition. Take precautionary measures against static discharges.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions Prevent entry into surface water or sanitary sewers. See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up Eliminate all potential sources of ignition, and ventilate area. Absorb and containerize. Do not flush into surface water or sanitary sewer system.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage Store in accordance all applicable regulations and fire codes. Keep containers tightly closed in a cool, well-ventilated place away from heat, sparks, open flames, and hot surfaces.
Incompatible Products Strong oxidizers, inorganic acids, and halogens.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH IDLH - 2000 ppm (10% LEL) Isopropyl alcohol TWA - 200 ppm TWA - 400 ppm TWA - 400 ppm 67-63-0 STEL - 400 ppm STEL - 500 ppm n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl ammonium chloride None None None 85409-23-0 n-Alkyl (5% C12, 60% C14, 30% C16, 5% C18) dimethyl benzyl ammonium chloride None None None 53516-76-0 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection None required for normal use. If splashes are likely to occur, wear safety glasses.
Skin and Body Protection No special protective equipment required.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Thin liquid absorbed into non-woven wipes Appearance Clear liquid absorbed into non-woven Odor Solvent, alcohol
wipes
Color Colorless liquid - white non-woven Odor Threshold No information available
wipes
Property Values Remarks/ Method pH ~7.5 None known
Melting/freezing point No data available None known
Boiling point / boiling range No data available None known
Flash Point ~30°C (liquid, closed cup) None known
Evaporation rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limits in Air
Upper flammability limit No data available None known
Lower flammability limit No data available None known
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity ~0.95 (liquid) None known
Water Solubility Complete (liquid) None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water No data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive Properties Not explosive Oxidizing Properties No data available
Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available
10. STABILITY AND REACTIVITY
Reactivity Can react with strong oxidizers, inorganic acids, and halogens.
Chemical stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None known.
Conditions to avoid Keep away from heat, sparks, open flames, and hot surfaces.
Incompatible materials Strong oxidizers, inorganic acids, and halogens.
Hazardous Decomposition Products None known.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Inhalation of high concentrations of vapor or mist may cause irritation of the respiratory tract, headaches, dizziness, nausea, vomiting, and malaise.
Eye Contact Liquid may cause irritation.
Skin Contact Prolonged or repeated use may cause dryness and/or slight irritation.
Ingestion Ingestion of liquid may cause central nervous system depression, gastrointestinal irritation, nausea, vomiting, and diarrhea.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Isopropyl alcohol 4.4 g/kg (Rat) 12.9 g/kg (Rabbit) 16000 (Rat, 8 h) 67-63-0
Information on toxicological effects
Symptoms Liquid may cause redness and tearing of eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA Isopropyl alcohol - Group 3 - X 67-63-0 2-Butoxyethanol - Group 3 - - 111-76-2 IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans; Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Reproductive Toxicity
STOT - single exposure No information available.
STOT - repeated exposure No information available. Chronic Toxicity No information available. Target Organ Effects Eyes, central nervous system (CNS), respiratory system.
Aspiration Hazard Not an aspiration hazard.
Numerical measures of toxicity - Product Information No information available.
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12. ECOLOGICAL INFORMATION
Ecotoxicity Toxic to aquatic life with long lasting effects.
Daphnia Magna (Water Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Flea) 96h LC50: = 9640 mg/L 96h EC50: > 1000 mg/L (Pimephales promelas) 96h Isopropyl alcohol (Desmodesmus subspicatus) LC50: = 11130 mg/L 48h EC50: 13299 mg/L 67-63-0 72h EC50: > 1000 mg/L (Pimephales promelas) 96h (Desmodesmus subspicatus) LC50: > 1400000 µg/L (Lepomis macrochirus)
Persistence and Degradability No information available.
Bioaccumulation
Chemical Name Log Pow Isopropyl alcohol 0.05 67-63-0
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT Not regulated per 49CFR 173.150(e)(2) - Aqueous solution of alcohol containing 24 percent or less alcohol by volume, no less than 50% water, and no other hazardous material is not subject to the requirements of the subchapter.
TDG Exempted from regulations per TDG Regulations Part 1.36(b).
ICAO Not regulated per ICAO Special Provision A58 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations.
IATA Not regulated per IATA Special Provision A58 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations.
IMDG/IMO Not regulated per IMDG Special Provision 144 - An aqueous solution containing 24% or less alcohol by volume is not subject to these regulations.
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15. REGULATORY INFORMATION
Chemical Inventories
TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.
EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
CAUTION: Harmful if inhaled or absorbed through skin. Causes moderate eye irritation. Avoid breathing vapors and contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before reuse.
US State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Isopropyl alcohol X X X X 67-63-0 2-Butoxyethanol X X X 111-76-2
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International Regulations
Canada WHMIS Hazard Class B2 - Flammable liquid
16. OTHER INFORMATION
NFPA Health Hazard 1 Flammability 3 Instability 0 Physical and Chemical Hazards -
HMIS Health Hazard 1 Flammability 3 Physical Hazard 0 Personal Protection -
Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Revision Date New
Revision Note New
Reference 1204522/202911.001
General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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Page 46 of 166 SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: ENDUST FREE Product Code: 507050 COMPANY NAME: NAKOMA PRODUCTS LLC ADDRESS : 8407 S. 77th Avenue Bridgeview, IL 60455
EMERGENCY PHONE : 855-363-8781 INFORMATION PHONE : 855-363-8781 Product Use: Dusting aid
2. HAZARDS IDENTIFICATION
CLASSIFICATION
Flammable aerosol 2 Gas under pressure Liquefied gas
SIGNAL WORD: Warning
Hazard Statements
Flammable aerosol Contains gas under pressure; may explode if heated Precautionary Statements
Keep away from heat/sparks/open flames/hot surfaces – No smoking Do not spray on an open flame or other ignition source Pressurized container – Do not pierce or burn, even after use IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Dispose of contents/container to comply with all local, state, and federal regulations
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Percent
WATER 7732-18-5 56.70 PROCESSED PARAFINNIC FLUIDS 8042-47-5 19.40 ISOPARAFINNIC SOLVENT 64742-47-8 13.50 BUTANE 106-97-84 7.40 PROPANE 74-98-6 2.60
4. FIRST AID MEASURES
INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get medical attention.
SDS for: 507050 Page 1 of 4 Printed: 5/25/2015 Page 47 of 166 EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes. Get medical attention.
SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists.
INGESTION: Not a likely route of exposure.
Most important symptoms/effects, acute and delayed: Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness.
Indication of immediate medical attention and special treatment needed: None known.
5. FIRE FIGHTING MEASURES
Suitable and unsuitable extinguishing media: Foam, Alcohol foam, CO2, Dry chemical, Water fog. Water spray may be ineffective.
Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when exposed to extreme heat and discharge contents. Liquid content of container will not support combustion. Overexposure to decomposition products may cause a health hazard. Symptoms may not be readily apparent. Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other toxic fumes.
Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus. If water is used, fog nozzles are preferred.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate area. Remove all sources of ignition.
Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed containers for disposal.
7. HANDLING AND STORAGE
Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for additional information.
Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas. .Do not store above 120 F.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits WATER Not established Not established 7732-18-5 PROCESSED PARAFINNIC PEL-TWA: Mist 5 mg/m3 TLV-TWA: Mist 5 mg/m3 FLUIDS 8042-47-5 ISOPARAFINNIC8042-47-5 SOLVENT Not established Not established 64742-47-8 BUTANE Not established TWA: 1000 ppm 74-98-6 PROPANE Not established TWA: 1000 ppm 74-98-6
SDS for: 507050 Page 2 of 4 Printed: 5/25/2015 Page 48 of 166 Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors. General dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable limit and lel below stated limit.
Individual protection measures:
Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas, use approved chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits.
Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact.
Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield should be used if indicated.
Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other clothing is recommended. Eye washes and safety showers in the workplace are recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Aerosol product Odor: None
Vapor Pressure: Not determined Odor threshold: Not determined
Vapor Density: Heavier than air pH: Not applicable
Density: 0.876937333 Melting point: Not determined
Freezing point: Not determined Solubility: Not determined
Boiling point: N/A Flash point: Not determined
Evaporation rate: Slower than ether Flammability: Level 1 Aerosol
Explosive Limits: Not applicable Partition coefficient (n- Not determined octanol/water):
Autoignition temperature: Not determined Decomposition temperature: Not determined
Viscosity: Not determined
10. STABILITY AND REACTIVITY
Reactivity: Not reactive under normal conditions of use.
Chemical stability: Stable under normal storage and handling conditions.
Possibility of hazardous reactions: None known.
Incompatible materials: No data
Hazardous decomposition products:
No data
11. TOXICOLOGICAL INFORMATION Long-term toxicological studies have not been conducted for this product.
12. ECOLOGICAL INFORMATION
Long-term ecological studies have not been conducted for this product.
SDS for: 507050 Page 3 of 4 Printed: 5/25/2015 Page 49 of 166 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections of this document for hazard cautionary information.
14. TRANSPORT INFORMATION By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited Quantity provisions. Commodity shipping description: Cleaning compound, NOI
By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 .1, LTD QTY
By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 .1, LTD QTY (packing instruction Y203 applies. 15. REGULATORY INFORMATION All ingredients are either listed on the TSCA inventory or are exempt
16. OTHER INFORMATION
Date revised: 2015-05-11 Revision 0
Date Printed: 2015-05-25
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE.
SDS for: 507050 Page 4 of 4 Printed: 5/25/2015 Page 50 of 166 SAFETY DATA SHEET
Section 1. Identification Product name : Expo White Board Cleaner
Material uses : Cleaning solutions.
Manufacturer : Newell Rubbermaid 3500 Lacey Road, 10th Floor Downers Grove, IL 60515 USA 800-323-0749 or 630-829-2500
Emergency telephone : CHEMTREC (U.S. and Canada) 1-800-424-9300 number (with hours of operation)
Section 2. Hazards identification OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Classification of the : Not classified. substance or mixture
GHS label elements Signal word : Not applicable Hazard statements : No known significant effects or critical hazards. Precautionary statements General : Read label before use. If medical advice is needed, have product container or label at hand. Prevention : Not applicable.
Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Hazards not otherwise : None known. classified
Section 3. Composition/information on ingredients Substance/mixture : Mixture
Ingredient name % CAS number 3-butoxypropan-2-ol 2 - 5 5131-66-8 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8 Page 51 of 166 Expo White Board Cleaner Section 3. Composition/information on ingredients Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. from the chemical Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 2/8 Page 52 of 166 Expo White Board Cleaner Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None.
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 3/8 Page 53 of 166 Expo White Board Cleaner Section 8. Exposure controls/personal protection Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Liquid. Color : Clear. Odor : Not available. Odor threshold : Not available. pH : Not available. Melting point : Not available. Boiling point : Not available. Flash point : Not available. Burning time : Not applicable. Burning rate : Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : Not available. Relative density : Not available. Solubility : Not available. Solubility in water : Not available. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. SADT : Not available. Viscosity : Not available.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 4/8 Page 54 of 166 Expo White Board Cleaner Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions
Conditions to avoid : No specific data.
Incompatible materials : No specific data.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure 3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg - Irritation/Corrosion No known significant effects or critical hazards. Sensitization No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Specific target organ toxicity (single exposure) No known significant effects or critical hazards. Specific target organ toxicity (repeated exposure) No known significant effects or critical hazards. Aspiration hazard No known significant effects or critical hazards.
Information on the likely : Not available. routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 5/8 Page 55 of 166 Expo White Board Cleaner Section 11. Toxicological information Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Route ATE value Dermal 63798.6 mg/kg
Section 12. Ecological information Toxicity No known significant effects or critical hazards.
Persistence and degradability No known significant effects or critical hazards.
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential 3-butoxypropan-2-ol 1.2 - low
Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 6/8 Page 56 of 166 Expo White Board Cleaner Section 14. Transport information
DOT TDG Mexico IMDG IATA Classification Classification Classification UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated.
UN proper - - - - - shipping name Transport - - - - - hazard class(es)
Packing group - - - - - Environmental No. No. No. No. No. hazards Additional - - - - - information
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Section 15. Regulatory information U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted. SARA 311/312 Classification : Not applicable. Composition/information on ingredients Name % Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard 3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No.
California Prop. 65 This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm.
Canada WHMIS (Canada) : Not controlled under WHMIS (Canada). Canadian lists Canadian NPRI : The following components are listed: Propylene glycol butyl ether CEPA Toxic substances : None of the components are listed. Canada inventory : All components are listed or exempted. Section 16. Other information
History Date of issue/Date of : 8/5/2015 revision Date of previous issue : No previous validation Version : 1 Prepared by : Product Safety.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 7/8 Page 57 of 166 Expo White Board Cleaner Section 16. Other information Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient UN = United Nations Indicates information that has changed from previously issued version.
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 8/8 Page 58 of 166
MATERIAL SAFETY DATA SHEET
Glance NA HMIS NFPA Personal protective equipment Health 1 1 Fire Hazard 0 0 None / Aucune / Ninguno Reactivity 0 0 Version Number: 2 Preparation date: 2007-07-25 1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Glance NA
MSDS #: MS0200011 Product Code: 3361936, 3172641 Recommended use: Cleaning product. This product is intended to be diluted prior to use.
Manufacturer, importer, supplier: US Headquarters Canadian Headquarters JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc. 8310 16th St. 2401 Bristol Circle Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1 Phone: 1-888-352-2249 Phone: 1-800-668-3131 MSDS Internet Address: www.johnsondiversey.com
Emergency telephone number: 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN.
Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None known. Ingestion: None known.
3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - Rat Rabbit Sodium lauryl sulfate 151-21-3 1 - 5% Not available Not available Not available Ethyl alcohol 64-17-5 0.1 - 1.5% Not available Not available Not available
4. FIRST AID MEASURES
Eye contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin contact: Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: None known. Unusual hazards: None known. Specific methods: No special methods required
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available
Glance NA 1 of 3
Page 59 of 166 6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment Environmental precautions Clean up affected area with water. and clean-up methods:
7. HANDLING AND STORAGE
Handling: Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate.
Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Ingredient(s) CAS # ACGIH OSHA Mexico Ethyl alcohol 64-17-5 1000 ppm (TWA) 1000 ppm (TWA) 1000 ppm (TWA) 1900 mg/m3 (TWA) 1900 mg/m3 (TWA)
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid Bulk density: No information available pH: >7.0 7.0 Dilution pH: No information available. Appearance: Aqueous solution Vapor density: No information available Color: Blue Evaporation Rate No information available Odor: Characteristic Boiling point/range: Not determined Specific gravity: .999 Melting point/range: Not determined Density: 8.35 Decomposition temperature: Not determined VOC: 0.25 Autoignition temperature: No information available Flash point: >200°F >93.3°C Partition coefficient (n-octanol/water): No information available Solubility: Soluble Solubility in other solvents: No information available Viscosity: No information available Elemental Phosphorus: 0.0 %P
10. STABILITY AND REACTIVITY
Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: None known. Conditions to avoid: Do not freeze.
11. TOXICOLOGICAL INFORMATION
Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3
Chronic toxicity: None known
Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known
HAZARDOUS COMPONENTS Ingredient(s) CAS # NTP IARC OSHA Ethyl alcohol 64-17-5 X 1 X
Glance NA 2 of 3
Page 60 of 166 12. ECOLOGICAL INFORMATION
Environmental Information: No data available
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC).
U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK: Water 7732-18-5 - - - - Sodium lauryl sulfate 151-21-3 - - - - Alcohol ethoxylates 68439-46-3 - - - - Ethyl alcohol 64-17-5 X X X X Sodium lauryl ether sulfate 9004-82-4 - - - -
CERCLA/ SARA CAA HAP/CAA ODS/CWA Priority Pollutants: None
SARA 311/312 Hazard Categories Immediate: X Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: -
Canada WHMIS hazard class: Non-controlled.
Ingredient(s) CAS # NPRI Ethyl alcohol 64-17-5 X
16. OTHER INFORMATION
Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Glance NA 3 of 3
Page 61 of 166
MATERIAL SAFETY DATA SHEET
GUM REMOVER HMIS NFPA Personal protective equipment Health 1 1 Fire Hazard 0 0 None / Aucune / Ninguno Reactivity 00 Version Number: 1 Preparation date: 2008-03-07 1. PRODUCT AND COMPANY IDENTIFICATION
Product name: GUM REMOVER
MSDS #: 126330001 Product Code: 05257, 04198 Recommended use: Carpet Care.
Manufacturer, importer, supplier: US Headquarters Canadian Headquarters JohnsonDiversey, Inc. JohnsonDiversey - Canada, Inc. 8310 16th St. 2401 Bristol Circle Sturtevant, Wisconsin 53177-0902 Oakville, Ontario L6H 6P1 Phone: 1-888-352-2249 Phone: 1-800-668-3131 MSDS Internet Address: www.johnsondiversey.com
Emergency telephone number: 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN.
Principle routes of exposure: Eye contact. Skin contact. Inhalation. Eye contact: May be mildly irritating to eyes. Skin contact: May be mildly irritating to skin. Inhalation: None Ingestion: None known.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation - Rat (mg/kg) Rabbit 1,1,1,2-tetrafluoroethane 811-97-2 90 - 100% Not available Not available Not available Pentane 109-66-0 10 - 20% Not available =3000 mg/kg =364 g/m3 (4 h)
4. FIRST AID MEASURES
Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Skin contact: Flush immediately with plenty of water. If irritation develops, get medical attention. Inhalation: No specific first aid measures are required. Ingestion: No specific first aid measures are required. Aggravated Medical Conditions: None known.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards: Aerosol product - Containers may rocket or explode in heat of fire. Unusual hazards: None known Specific methods: Aerosol Product - Containers may rocket or expode in heat of fire.
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available
GUM REMOVER 1 of 3
Page 62 of 166 6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment Environmental precautions Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a and clean-up methods: water rinse for final clean-up.
7. HANDLING AND STORAGE
Handling: Avoid contact with skin and eyes. Do not spray towards face . CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Use only in well- ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Do not pierce or burn, even after use. Do not pierce or burn, even after use . KEEP OUT OF REACH OF CHILDREN. NFPA 30B Level 1 Aerosol .
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate.
Personal Protective Equipment Eye protection: No special requirements under normal use conditions. Hand protection: No special requirements under normal use conditions Skin and body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Ingredient(s) CAS # ACGIH OSHA Mexico Pentane 109-66-0 600 ppm (TWA) 1000 ppm (TWA) 760 ppm (STEL) 2950 mg/m3 (TWA) 2250 mg/m3 (STEL) 600 ppm (TWA) 1800 mg/m3 (TWA)
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Aerosol Bulk density: No information available pH: Not applicable Dilution pH: Not applicable Appearance: Aerosol Vapor density: No information available Color: Clear Colorless Evaporation Rate No information available Odor: Hydrocarbon Boiling point/range: Not determined Specific gravity: 1.11 Melting point/range: Not determined Density: 9.30 lbs/gal Decomposition temperature: Not determined VOC: 10% * Autoignition temperature: No information available Flash point: >200°F >93.3°C Partition coefficient (n-octanol/water): No information available Solubility: Insoluble Solubility in other solvents: No information available Viscosity: No information available Elemental Phosphorus: 0 %P
* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508
10. STABILITY AND REACTIVITY
Stability: The product is stable Polymerization: Hazardous polymerization does not occur Hazardous decomposition products: None reasonably foreseeable. Materials to avoid: direct sunlight . Conditions to avoid: Strong sunlight for prolonged periods..
11. TOXICOLOGICAL INFORMATION
Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg Component Information: See Section 3
Chronic toxicity: None known
Specific effects Carcinogenic effects: None known Mutagenic effects: None known Reproductive toxicity: None known Target organ effects: None known
GUM REMOVER 2 of 3
Page 63 of 166 12. ECOLOGICAL INFORMATION
Environmental Information: No data available
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), New Zealand (NZIoC), China (IECSC).
U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK: Pentane 109-66-0 XXXX 1,1,1,2-tetrafluoroethane 811-97-2 - X - -
CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: - Delayed: - Fire: - Reactivity: - Sudden Release of Pressure: X
Canada WHMIS hazard class: A Compressed gases.
16. OTHER INFORMATION
Reason for revision: Not applicable Prepared by: NAPRAC Additional advice: None
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
GUM REMOVER 3 of 3
Page 64 of 166 SAFETY DATA SHEET
KEYSTONE GLASS CLEANER
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : KEYSTONE GLASS CLEANER
Other means of identification : Not applicable.
Recommended use : Glass Cleaner
Restrictions on use : Reserved for industrial and professional use.
Product dilution information : 3.13 % - 6.25 %
Company : Ecolab Co. 5105 Tomken Road Mississauga, Ontario Canada L4W 2X5 1-800-352-5326
Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) information
Issuing date : 08/10/2015
Section: 2. HAZARDS IDENTIFICATION
GHS Classification Product AS SOLD Eye irritation : Category 2B
Product AT USE DILUTION Not a hazardous substance or mixture.
GHS Label element Product AS SOLD Signal Word : Warning
Hazard Statements : Causes eye irritation.
Precautionary Statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
Product AT USE DILUTION Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations.
Product AS SOLD Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
914266-04 1 / 9
Page 65 of 166 SAFETY DATA SHEET KEYSTONE GLASS CLEANER
Product AS SOLD Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%) d-glucopyranose, oligomeric, decyl octyl glycosides 68515-73-1 5 - 10
Product AT USE DILUTION
No hazardous ingredients
Section: 4. FIRST AID MEASURES
Product AS SOLD In case of eye contact : Rinse with plenty of water.
In case of skin contact : Rinse with plenty of water.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
If inhaled : Get medical attention if symptoms occur.
Protection of first-aiders : No special precautions are necessary for first aid responders.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and and effects, both acute and symptoms. delayed
Product AT USE DILUTION In case of eye contact : Rinse with plenty of water.
In case of skin contact : Rinse with plenty of water.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
If inhaled : Get medical attention if symptoms occur.
Section: 5. FIREFIGHTING MEASURES
Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing : None known. media
Specific hazards during : Not flammable or combustible. firefighting
Hazardous combustion : Decomposition products may include the following materials: products Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus
Special protective equipment : Use personal protective equipment.
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for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be methods disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Risk of explosion. : Not available.
Section: 6. ACCIDENTAL RELEASE MEASURES
Product AS SOLD Personal precautions, : Refer to protective measures listed in sections 7 and 8. protective equipment and emergency procedures
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Product AT USE DILUTION Personal precautions, : Refer to protective measures listed in sections 7 and 8. protective equipment and emergency procedures
Environmental precautions : No special environmental precautions required.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non- containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Product AS SOLD Advice on safe handling : Wash hands thoroughly after handling.
Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers.
Storage temperature : 5 °C to 50 °C
Product AT USE DILUTION Advice on safe handling : Wash hands after handling. For personal protection see section 8.
Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers.
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Product AS SOLD Components with workplace control parameters Contains no substances with occupational exposure limit values.
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Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Personal protective equipment
Eye protection : No special protective equipment required.
Hand protection : No special protective equipment required.
Skin protection : No special protective equipment required.
Respiratory protection : No personal respiratory protective equipment normally required.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.
Product AT USE DILUTION Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Personal protective equipment
Eye protection : No special protective equipment required.
Hand protection : No special protective equipment required.
Skin protection : No special protective equipment required.
Respiratory protection : No personal respiratory protective equipment normally required.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Colour : blue blue Odour : Perfumes, fragrances Perfumes, fragrances pH : 10.9, 100 % 7.2 - 7.9 Flash point : Not applicable., Does not sustain combustion. Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and : 100 °C boiling range Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.99 - 1.05 Water solubility : soluble
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Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available Viscosity, kinematic : no data available Explosive properties : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : no data available VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Product AS SOLD Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use. reactions
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition : Decomposition products may include the following materials: products Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact exposure
Potential Health Effects
Product AS SOLD Eyes : Causes eye irritation.
Skin : Health injuries are not known or expected under normal use.
Ingestion : Health injuries are not known or expected under normal use.
Inhalation : Health injuries are not known or expected under normal use.
Chronic Exposure : Health injuries are not known or expected under normal use.
Product AT USE DILUTION Eyes : Health injuries are not known or expected under normal use.
Skin : Health injuries are not known or expected under normal use.
Ingestion : Health injuries are not known or expected under normal use.
Inhalation : Health injuries are not known or expected under normal use.
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Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Product AS SOLD Eye contact : Redness, Irritation
Skin contact : No symptoms known or expected.
Ingestion : No symptoms known or expected.
Inhalation : No symptoms known or expected.
Product AT USE DILUTION Eye contact : No symptoms known or expected.
Skin contact : No symptoms known or expected.
Ingestion : No symptoms known or expected.
Inhalation : No symptoms known or expected.
Toxicity
Product AS SOLD Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : no data available Acute dermal toxicity : no data available Skin corrosion/irritation : no data available Serious eye damage/eye : Mild eye irritation irritation Respiratory or skin : no data available sensitization Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute dermal toxicity : d-glucopyranose, oligomeric, decyl octyl glycosides LD50 rabbit: > 2,000 mg/kg
Section: 12. ECOLOGICAL INFORMATION
Product AS SOLD Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.
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Product Toxicity to fish : no data available Toxicity to daphnia and other : no data available aquatic invertebrates Toxicity to algae : no data available Components Toxicity to algae : d-glucopyranose, oligomeric, decyl octyl glycosides 72 h EC50: 18 mg/l
Persistence and degradability Taking into consideration the properties of several components, the product is estimated to be biodegradable according to OECD classification.
Bioaccumulative potential no data available
Mobility in soil no data available
Other adverse effects no data available
Section: 13. DISPOSAL CONSIDERATIONS
Product AS SOLD Disposal methods : Diluted product can be flushed to sanitary sewer.
Disposal considerations : Dispose of in accordance with local, state, and federal regulations.
Product AT USE DILUTION Disposal methods : Diluted product can be flushed to sanitary sewer.
Disposal considerations : Dispose of in accordance with local, state, and federal regulations.
Section: 14. TRANSPORT INFORMATION
Product AS SOLD
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport (TDG) Not dangerous goods
Sea transport (IMDG/IMO) Not dangerous goods
Product AT USE DILUTION Not intended for transport.
Section: 15. REGULATORY INFORMATION
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This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR.
The components of this product are reported in the following inventories:
Switzerland. New notified substances and declared preparations : not determined
United States TSCA Inventory : On TSCA Inventory
Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.
Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory
New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On the inventory, or in compliance with the inventory
Japan. ENCS - Existing and New Chemical Substances Inventory : On the inventory, or in compliance with the inventory
Japan. ISHL - Inventory of Chemical Substances (METI) : not determined
Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory
Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory
China Inventory of Existing Chemical Substances : On the inventory, or in compliance with the inventory
Section: 16. OTHER INFORMATION
Product AS SOLD NFPA: HMIS III: Flammability
HEALTH 1
0 Instability
1 0 FLAMMABILITY 0
Health
PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Product AT USE DILUTION
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NFPA: HMIS III: Flammability
HEALTH 0
0 Instability
0 0 FLAMMABILITY 0
Health
PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Issuing date : 08/10/2015 version : 1.1 Prepared by : Regulatory Affairs 1-800-352-5326
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
914266-04 9 / 9
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5332 Dansher Road Countryside, Illinois 60525
MATERIAL SAFETY DATA SHEET
Revision Date: 8/16/2005 MSDS No: N-051
Emergency Phones: 708-579-8100 (NYCO) 800-424-9300 (CHEMTREC)
PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations.
SECTION I - PRODUCT IDENTITY PRODUCT NAME: Lemon Shine Furnature Polish Formula: Lemon oil and silicone emulsion with hydrocarbon propellant for use on furnature Chemical Type: Lemon oil and silicone emulsion
HMIS RATINGS Health = 1 (Slight) Flammability = 2 (Moderate) Reactivity = 0 (Minimal) Protection = A (Safety Glasses)
SECTION II - HAZARDOUS INGREDIENTS CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Propane 1-5% 1000 ppm No CAS No. 74-98-6 n-Butane 1-5% 600 ppm No CAS No. 106-97-8
SECTION III - CHEMICAL AND PHYSICAL Appearance and Odor: Lemon Odor, Cone Spray Boiling Point: N/A Evaporation Rate (Ether = 1): <1 Melting Point: N/A pH: 10.0-11.0 Spec. Gravity (H20 = 1): <1 Water Solubility: 10% Vapor Density (Air = 1): >1 Vapor Pressure (psig): 117 @ 130F
SECTION IV - FIRE AND EXPLOSION HAZARDS Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flash Point (Method): <0F (Propellant) None even until boiling (Conc) Explosion Limits: Upper: 9.5 Lower: 1.9 Extinguishing Media: Carbon Dioxide, foam and/or dry chemical may be used. Special Firefighting Procedures and Hazards: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At evelated temperatures (over 54C or 130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening or container structure.
SECTION V - REACTIVITY INFORMATION Stable: Unstable: Precautions: Incompatibility: Avoid heat, open flame and oxidizing agents. Hazardous Decomposition Products: Carbon Monoxide in small amounts and additional toxic chemicals may be formed in small amounts Conditions to Avoid: Do not store above 54C or 130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Hazardous Polymerization: Occurs: Does Not Occur:
Form N051 Page 1
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SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID
Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. Skin: Remove contaminated clothing. Flush skin with water followed by washing with soap and water. If irritation occurs, get medical attention. Do not use clothing until cleaned. Eyes: Flush eyes with plents of water for 15 minutes while holding eye lids wide open. Get medical attention if irritation persists. Ingestion: Get medical attention.
Most likely routes of entry: Inhilation, eyes, and skin
Other Important Medical or Precautionary Information: None
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all sources of ignition and ventilate area. Soak up spill wiht an inert absorbent and place into a designed disposal container. Consult local regulatory agency for proper disposition of material.
Storage and Handling: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as level 1 Aerosol (NFPA 30B)
Waste Disposal: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gass is expelled. Dispose of container in acordance with local, state, and federal regulations.
Empty Containers: Dispose in accordance with local, state, and federal regulations.
Other Precautions: Please read and follow the directions on the product label; THey are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect you health.
SECTION VIII - REGULATORY INFORMATION Respiratory Protection: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sect. II), use a NIOSH approved repirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions. Mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation. Eye Protection: Chemical safety glasses are recommended. Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact. Work/Hygienic Practices: Ensure stict sanityar conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and 1910.133. Reportable for SARA Title III, S.313 (Form R):
The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use.
Form N025 Page 2
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The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: RQ1405032/ RQ1405221/ RQ1402590/ / RQ1309178(AB) Issue Date: 08/28/2014 Supersedes: RQ1311865/RQ1312426/RQ1400299/RQ1400459/RQ1402104 Issue Date: 06/08/2014
SECTION I - PRODUCT IDENTIFICATION Identity: Liquid Hand Dishwashing Detergents and Antibacterial Hand Soaps Brand: ULTRA DAWN Finished Products Covered: Ultra Dawn Original [96849942] Lemon [96866886] Pomegranate Awakening [96869507] Apple Ocrchard Harverst [96915999]
Orange Dishwashing Liquid/Antibacterial Hand Soap [99488499] Apple Blossom Dishwashing Liquid/Antibacterial Hand Soap [96528376]
Dawn Pure Essentials Sparkling Mist [96866925] Citrus Infusion [96866926]
Dawn Escape Hawaiian Pineapple [96866893] Thai Dragonfruit [96866890] New Zealand Springs [96866897] Mediteranean Lavender [96866914] Fuji Cherry Blossom [96866916] Caribbean Breeze [96866921] Malibu Sunrise [96866924]
P&G Telephone Number: 1-800-725-3296 or call Local Poison Control Center or your physician.
SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Ingestion may cause transient gastrointestinal irritation. Eye Contact: May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Inhalation: N/A
Ultra Dawn Hand Dishwashing Liquids and Antibacterial Hand Soaps Page 1 of 5
Page 76 of 166 Signs and Symptoms of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Inhalation: N/A Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS Ingredients listed on the product label are: biodegradable surfactants and no phosphate. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: COMMON COMPOSITI CHEMICAL NAME CAS RN LD50/LC50 NAME ON RANGE LD50(oral, rat) – 7.06 Ethyl alcohol Ethanol 64-17-5 1 - 5% g/kg
Alcohol Ethoxysulfate, Sodium Laureth 68585-34-2 LD50 (oral, rat) - >2g/kg sodium salt Sulfate 10-30% total anionic Alcohol Sulfates, sodium Sodium Lauryl surfactant 68585-47-7 LD50 (oral, rat) - >2g/kg salt Sulfate Amines, C10-16 Alkyl Dimethyl LD50 (oral, rat) - 1.33 70592-80-2 1 - 5% alkyldimethyl, N-oxides Amine Oxide g/kg These substances are listed because in their pure bulk form they meet the OSHA and/or WHMIS definition of hazardous. Any hazards associated with this finished product are listed in Section II of this MSDS.
SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If symptoms persist or recur, seek medical attention. Inhalation: N/A Other: Consumer product package has the following precautionary statement on the back label: “For external use only. Keep out of the reach of children. If Dawn gets in eyes, rinse thoroughly with water. If swallowed, drink a glass of water to dilute.”
SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: The liquid hand dishwashing detergents have a flashpoint of 115-135°F (46.1-57.2°C) Pensky-Martens (Closed cup). However, the detergents do not sustain combustion according to ASTM D4206. Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: N/A Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media:
Suitable: CO2, water or dry chemical may be used. Unsuitable: N/K Protection of Firefighters: Specific Hazards Arising from the Material: None.
SECTION VI - ACCIDENTAL RELEASE MEASURES
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Page 77 of 166 Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer - First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read “Waste Disposal Method” below for further information.
SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: No special precautions necessary. Precautions To B e Taken in Storage: No special precautions necessary.
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm OSHA Z-1 PEL 1000 ppm Engineering Controls: N/A Personal Protective Equipment (PPE): N/A Eye/Face Protection: None required with normal household use. Industrial Setting: For splash protection, use chemical goggles. Eye wash fountain is recommended. Skin Protection: None required with normal household use. Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: No special precautions for casual exposure. Ventilation Local Exhaust: None required with normal consumer use. Special: None Industrial (General): Normal/general dilution ventilation is acceptable. Other: None
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Clear, Flash Point (Method Used): 115-135°F (46.1-57.2°C) opaque or colored liquids. Pensky-Martens (Closed cup) but do not sustain combustion according to ASTM D4206. Odor: Perfumed Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Complete Physical State: Liquid hand dishwashing solution Decomposition Temperature: N/K Vapor Pressure (mm Hg): N/K Evaporation Rate (nBuOAc=1): N/K Vapor Density (Air=1): N/K Specific Gravity/Density: ca. 1 Boiling Point: N/K Melting/Freezing Point: ~ 30 °F (-1.1°C) Partition Coefficient (n-octanol/water): N/K pH (10% solution): 9 Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State or Federal level
SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: None known Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known
SECTION XI - TOXICOLOGICAL INFORMATION
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Page 78 of 166 Liquid hand dishwashing detergents have a relatively low order of toxicity, may cause transient irritation and are expected to be emetic. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished product is not carcinogenic. NTP: No IARC: No OSHA: No
SECTION XII - ECOLOGICAL INFORMATION All surfactants are readily biodegradable.
SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS
Non Household Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill.
California Hazardous Waste: Not hazardous, in accordance with 22 CCR 66261.20 through 22 CCR 66261.24
Household Use: Household product is safe for disposal down the drain during detergent use or in the trash. Dispose of empty bottle in the trash or recyle where facilities exist.
SECTION XIV - TRANSPORT INFORMATION Products covered by this MSDS, in their original form, are not regulated for transportation. Ground Transport (US DOT): Not regulated Air Transport (IATA): Not regulated Marine/Water Transport (IMDG): Not regulated
SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. This product is not subject to warning labeling under California Proposition 65. EPA Reg. No.: Not Applicable
This product contains the following SARA 313/302/304/311/312 chemicals: None
This product contains the following CERCLA chemicals: Chemical Name CAS Number Max Range in Product (%) Ethanol 64-17-5 5.0%
State Right-to-Know: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists:
MAX STATE INGREDIENT CAS RN LEVEL IL MA NJ PA RI Ethanol 64-17-5 1.0 % X X X X X
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance
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Page 79 of 166 Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.
P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all- inclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product.
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Page 80 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM SAFETY DATA SHEET Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes Lemon Lime Blossom 1. Product and company identification Product name : Lysol Brand II Kills 99.9% of Viruses & Bacteria Disinfecting Wipes Lemon Lime Blossom Distributed by : Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 973 404 2600
Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 905 283 7000
Emergency telephone : 1-800-338-6167 number (Medical) Emergency telephone : 1-800-424-9300 (U.S. & Canada) CHEMTREC number (Transport) Outside U.S. and Canada (North America), call Chemtrec:703-527-3887 Website: : http://www.rbnainfo.com
Product use : Surface Disinfectant. This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration.
This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS.
SDS # : D0314689 v6.0 Formulation #: : (e0002-078) 0314159 v3.0 (1934-064A) 8184600 v1.0 (2096-032F) 8169597 v1.0 (1934-064A) 8029609 v1.0 EPA ID No. : 777-114 DIN # : 02359014 UPC Code / Sizes : Lemon & Lime Blossom: 19200 84460 4 (9 Wet Wipes 7" X 8" sheets) 19200 81145 3 (35 Wet Wipes 7" X 8" sheets) 19200 77182 5 (80 Wet Wipes 7" X 8" sheets) 19200 78849 6 (110 Wet Wipes 7" X 8" sheets) 19200 84383 6 (24 Wet Wipes 8.4" X 10" sheets) 19200 84384 6 (54 Wet Wipes 8.4" X 10" sheets)
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 1/11 Lime Blossom) Page 81 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 2. Hazards identification
Classification of the : Not classified substance or mixture
GHS label elements Hazard pictograms : Not applicable. Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Supplemental label : None known. elements Hazards not otherwise : None known. classified 3. Composition/information on ingredients Substance/mixture : Mixture Ingredient name % CAS number Ethyl alcohol 1 - 2.5 64-17-5 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : May cause eye irritation upon direct contact with eyes. Inhalation : No known significant effects or critical hazards. Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 2/11 Lime Blossom) Page 82 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 4. First aid measures Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11) 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media
Specific hazards arising : No specific fire or explosion hazard. from the chemical Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 3/11 Lime Blossom) Page 83 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 6. Accidental release measures
Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8).
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure controls/personal protection Control Occupational exposure limits Ingredient name Exposure limits Ethyl alcohol ACGIH TLV (United States, 6/2013). STEL: 1000 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours. Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 4/11 Lime Blossom) Page 84 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 8. Exposure controls/personal protection Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. 9. Physical and chemical properties
Appearance Physical state : Solid. [Presaturated Wipes] Color : Presaturated Wipes (Clear. liquid)
Odor : Characteristic. Odor threshold : Not available. pH : 10.5 [liquid preparations] Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: >93.3°C (>199.9°F) liquid preparations Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : Not available. Relative density : 0.985 [liquid preparations] Solubility : Not available. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 5/11 Lime Blossom) Page 85 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : Do not use with other products. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Ethyl alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - *Lysol® Disinfectant Wipes LC50 Inhalation Vapor Rat >2.04 mg/l 24 hours Lemon Lime Blossom LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Ethyl alcohol Eyes - Moderate irritant Rabbit - 0.066666667 - minutes 100 milligrams Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Eyes - Moderate irritant Rabbit - 100 - microliters Eyes - Severe irritant Rabbit - 500 - milligrams Skin - Mild irritant Rabbit - 400 - milligrams Skin - Moderate irritant Rabbit - 24 hours 20 - milligrams *Lysol® Disinfectant Wipes Skin - Slight irritant Rabbit 1.5 - - Lemon Lime Blossom Eyes - Cornea opacity Rabbit 0 - - Conclusion/Summary Skin : Non-irritant to skin. Eyes : Non-irritating to the eyes. Information is based on toxicity test result of a similar product. Sensitization Product/ingredient name Route of Species Result exposure *Lysol® Disinfectant Wipes skin Guinea pig Not sensitizing Lemon Lime Blossom Conclusion/Summary Skin : Non-sensitizer to skin.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 6/11 Lime Blossom) Page 86 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 11. Toxicological information Mutagenicity Not available. Carcinogenicity Not available. Classification Product/ingredient name OSHA IARC NTP Ethyl alcohol - 1 -
Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Not available.
Specific target organ toxicity (repeated exposure) Not available.
Aspiration hazard Not available.
Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact : May cause eye irritation upon direct contact with eyes. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 7/11 Lime Blossom) Page 87 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 11. Toxicological information Potential chronic health effects Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Not available.
12. Ecological information Toxicity Product/ingredient name Result Species Exposure Ethyl alcohol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours franciscana - Larvae Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks Larvae
Persistence and degradability Not available.
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential Ethyl alcohol -0.35 - low
Mobility in soil Soil/water partition : Not available. coefficient (KOC)
Other adverse effects : No known significant effects or critical hazards.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 8/11 Lime Blossom) Page 88 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 14. Transport information Not a DOT controlled material (United States). Not a TDG-controlled material. This preparation is not classified as dangerous according to international transport regulations (ADR/RID, IMDG or ICAO/IATA). 15. Regulatory information
U.S. Federal regulations : TSCA 4(a) proposed test rules: Quaternary ammonium compounds, benzyl- C12-16-alkyldimethyl, chlorides TSCA 8(a) PAIR: 2-(4-tert-butylbenzyl)propionaldehyde; bornan-2-one; 2-methylpropan- 2-ol; nonanal; octanal; dodecanal; decanal; 2-methylundecanal; cinnamaldehyde; 3-p- cumenyl-2-methylpropionaldehyde; α-hexylcinnamaldehyde; 2-benzylideneheptanal TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.
Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List II Chemicals : Not listed (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found.
SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable. Composition/information on ingredients
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 9/11 Lime Blossom) Page 89 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 15. Regulatory information Name % Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard Ethyl alcohol 1 - 2.5 Yes. No. No. Yes. No.
State regulations Massachusetts : The following components are listed: ETHYL ALCOHOL New York : None of the components are listed. New Jersey : The following components are listed: ETHYL ALCOHOL; ALCOHOL Pennsylvania : The following components are listed: DENATURED ALCOHOL
Label elements Signal word: : CAUTION Hazard statements : May cause eye irritation. Precautionary measures : Avoid contact with eyes. Wash hands after use. 16. Other information Hazardous Material : Information System (U.S.A.) Health 1 Flammability 0 Physical hazards 0 Personal protection B Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection : Association (U.S.A.)
0 Flammability Health 1 0 Instability/Reactivity Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 10/11 Lime Blossom) Page 90 of 166 Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM D0314689 v6.0 16. Other information Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
Date of issue : 27/04/2015. Date of previous issue : 21/04/2015 Version : 6 Prepared by : Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: 201-476-7770
Revision comments : Addition of formula numbers and separated by fragrance. Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
RB is a member of the CSPA Product Care Product Stewardship Program.
Code # : D0314689 (Lemon SDS # : D0314689 v6.0 Date of issue : 27/04/2015. 11/11 Lime Blossom) Page 91 of 166
Safety Data Sheet Office Max Compressed Gas Duster
Section 1. Identification
Product Identifier Office Max Compressed Gas Duster Synonyms OM96090, OM96091, OM96092, OM04736, OM04737 Manufacturer Stock N/A Numbers Product Cas 75-37-6
Recommended use Dust Removal Uses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal.
Manufacturer Contact Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA
Phone Emergency Phone Fax (908) 707-4900 (800) 498-7192 N/A
Section 2. Hazards Identification
Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas Signal Word Warning Pictogram
Hazard Statements Contains gas under pressure; may explode if heated Flammable gas Precautionary Statements Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use. Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C Disposal N/A
Page 1 of 8 Page 92 of 166 General Keep out of reach of children
Ingredients of unknown 0% toxicity
Hazards not Otherwise N/A Classified
No Data Available
Section 3. Ingredients
CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 %
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-Aid Measures
General Advice Never give anything by mouth to an unconscious person. When symptoms persist or in all cases of doubt, seek medical advice. Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion Is not considered a potential route of exposure. Most important Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation symptoms/effects, acute and in the chest, heart thumping, apprehension, feeling of fainting, dizziness or delayed weakness. Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to Physician Because of possible disturbances of cardiac rhythm catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution.
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Section 5. Fire Fighting Measures
Suitable Extinguishing Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2) Media Unsuitable Extinguishing No applicable data available. Media Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back. Special protective Use personal protective equipment. Wear neoprene gloves during cleaning up equipment for firefighters work after a fire. Exposure to decompositon products may be a hazard to health. Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray.
Section 6. Accidental Release Measures
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8. Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect. Accidental Release Wear self-contained breathing apparatus (SCBA). Measures
Section 7. Handling and Storage
Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice. Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders. Dust Explosion class Not applicable Storage Keep container tightly closed and in a dry, well-ventilated location. Store in original container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as directed. Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle.
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Section 8. Exposure Controls/Personal Protection
Occupational Exposure Ingredient Name ACGIH TLV OSHA PEL STEL Limits Ethane, 1,1-difluoro- N/A N/A N/A Personal Protective N/A Equipment Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed. Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite. Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing. Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite. General Hygiene Handle in accordance with good industrial hygiene and safety practices. Considerations
Page 4 of 8 Page 95 of 166
Section 9. Physical and Chemical Properties
Physical State Gas Color Clear Odor slight, ether- like Odor Threshold No applicable data available Solubility Water - Slightly Partition coefficient Water/n-octanol N/A VOC% N/A Viscosity No applicable data available Specific Gravity 0.91 Density lbs/Gal 0.9 Pounds per Cubic Foot N/A Flash Point <-58°F (<-50° C) FP Method N/A Ph Neutral Melting Point No applicable data available Boiling Point -13 °F (-25 ° C) Boiling Range N/A LEL 3.9 UEL 16.9 Evaporation Rate No applicable data available Flammability Flammable Decomposition Temperature N/A Auto-ignition Temperature No applicable data available Vapor Pressure 5,960 KPa at 77F (25C) Vapor Density 2.4 at 77F (25C) (Air=1)
Section 10. Stability and Reactivity
Reactivity Stable under recommended storage conditions. Chemical Stability The product is chemically stable under recommended storage conditions. Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees C Incompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered metals, powdered metal salts. Hazardous Decomposition Decomposition products are hazardous. This material can be decomposed by high Products temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride.
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Section 11. Toxicological Information
Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm rat Component analysis - Oral 1,1-Difluoroethane - 1500 mg/kg rat LD50 Effects of Acute Exposure - Contact with liquid may cause frostbite Eye Effects of Acute Exposure - Contact with liquid may cause frostbite Skin Effects of Acute Exposure - Excessive intentional inhalation may cause respiratory tract irritation and central Inhalation nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation. Effects of Acute Exposure - Not a normal route of exposure Ingestion Sensitization Non-hazardous by WHMIS/OSHA criteria. Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen. Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects. Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity. Teratogenicity Animal testing showed no developmental toxicity. Further Information Cardiac sensitization threshold limit: 405000 mg/m3
Section 12. Ecological Information
Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l
Section 13. Disposal
Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container. Contaminated Packaging Not Available
Page 6 of 8 Page 97 of 166 Section 14. Transport Information
UN Number 1030 UN Proper Shipping Name 1,1-Difluoroethane DOT Classification 2.1 Packing Group N/A Packaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at 908-707-4900. Transportation of Dangerous Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Goods (TDG - Canada) Packaging Exceptions: Limited quantity (containers up to 125mL) IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg. IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030. Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine.
Section 15. Regulatory Information
Canadian Federal This product has been classified in accordance with the hazard criteria of the Regulations Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS Status Controlled WHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable Gas TSCA On the inventory, or in compliance with the inventory. SARA 313 Regulated This material does not contain any chemical components with known CAS Chemical(s) numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. NJ Right to Know Regulated Substances on the New Jersey Workplace Hazardous Substance List present at a Chemical(s) concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane. California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Canada Domestic This product is listed on the DSL inventory list and complies with the inventory Substances List (DSL) requirements administered by the governing country.
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Section 16. Other Information
Revision Date 4/28/2015 Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Prepared By Falcon Safety Products, Inc. 908-707-4900
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PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH
This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.0 Revision Date 09/21/2012 Print Date 10/03/2012
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : PALMOLIVE DISHWASHER DETERGENT ECO+ LEMON SPLASH MSDS Number 200000011882 CAS-No. : Not applicable - product is a mixture General Use : Home care A formulated dishwashing liquid
Company : Colgate-Palmolive Canada Inc. Two Morneau Shepell Centre, 6th Fl. 895 Don Mills Road Toronto, Ontario, M3C 1W3, Canada Telephone : Emergency telephone : For emergencies involving spill, leak, fire, exposure or number accident call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.
Medical Emergency For MEDICAL EMERGENCIES involving this product call: (24HR): (888) 489-3861
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview Form : Viscous liquid Appearance : White Odour : Characteristic
Potential Health Effects Eye contact : Causes eye irritation on direct contact.
Skin contact : May cause skin irritation upon prolonged contact.
Inhalation : Overexposure may cause respiratory tract irritation.
Ingestion : Harmful if swallowed.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components OSHA-REGULATED COMPONENTS (present at a concentration of > or = 1%) Chemical Name CAS-No. Concentration *
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
SODIUM CARBONATE 497-19-8 5.00 - 10.00 SODIUM SILICATE 1344-09-8 1.00 - 5.00 SODIUM BISULFITE 68479-09-4 1.00 - 5.00 TERMINATED SODIUM POLYACRYLATE SODIUM HYDROXIDE 1310-73-2 1.00 - 5.00 SODIUM HYPOCHLORITE 7681-52-9 1.00 - 5.00 NO. 2 SODIUM 1.00 - 5.00 POLYACRYLATE *All concentrations are present by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Carcinogenicity: Listed Carcinogens: The following components, present at a concentration of > or = 0.1%, are listed as carcinogens or potential carcinogens by either the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), OSHA or ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
SECTION 4. FIRST AID MEASURES
First aid procedures Eye contact : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists.
Skin contact : Flush skin with large amounts of water. If irritation develops and persists, get medical attention.
Inhalation : Remove victim to fresh air. Get medical attention, if symptoms persist.
Ingestion : Drink 8 ounces of clear water. Get medical attention.
SECTION 5. FIREFIGHTING MEASURES
Flammable properties Flash point : Remarks: no data available
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
Fire fighting Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or media carbon dioxide.
Protective equipment and precautions for firefighters Special protective : Self-contained breathing apparatus and full protective clothing equipment for firefighters should be worn when fighting chemical fires.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use personal protection recommended in Section 8 of the MSDS.
Methods for containment / : Cover with inert, absorbent material and remove to disposal Methods for cleaning up container. Spill area may be slippery. Flush with plenty of water.
SECTION 7. HANDLING AND STORAGE
Storage Requirements for storage : Store at controlled room temperature at 20-25°C (68-77°F). areas and containers
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines Components with workplace control parameters Chemical CAS- Value Exposure Source Notes Name No. Limits SODIUM 1310-73- Ceiling 2 mg/m3 ACGIH HYDROXIDE 2
Ceil_Ti 2 mg/m3 NIOSH/GUIDE me
PEL 2 mg/m3 OSHA_TRANS
Ceiling 2 mg/m3 Z1A
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
Engineering Controls : In an industrial work environment, no special precautions or control measures are required.
Personal protective equipment Protective measures : In an industrial work environment, if a splash is likely, chemical goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.
General Hygiene : In an industrial work environment, avoid eye and prolonged Considerations skin contact.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Viscous liquid Appearance : White
Odour : Characteristic
Flash point : Note: no data available
pH : Approximate 12.5
Density : Approximate1.16 g/cm3
Viscosity, dynamic : Approximate4,500 mPa.s
SECTION 10. STABILITY AND REACTIVITY
Materials to avoid : Remarks: Strong oxidizing agents
Hazardous decomposition : Note: None known. products Hazardous reactions : Hazardous polymerisation does not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
a component of the hazard determination used to prepare the statements in Section 3 of the MSDS.
SECTION 12. ECOLOGICAL INFORMATION
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Further information : Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environment agency for specific rules). Do not dump in sewers, any body of water or on the ground.
SECTION 14. TRANSPORT INFORMATION
DOT : Not regulated.
TDG : Not regulated.
IATA : Not regulated.
IMDG : Not regulated.
SECTION 15. REGULATORY INFORMATION
US Regulations
RCRA Information : Not listed
SARA
Section 302 Extremely Hazardous : Not listed Substances (40 CFR 355, Appendix A)
Section 313 Toxic Release Inventory : Not listed (40 CFR 372)
CERCLA Hazardous Substance List : 9761 lbs (40 CFR 302.4) - Reportable Quantity
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
SODIUM HYPOCHLORITE
62406 lbs
SODIUM HYDROXIDE
325154 lbs
Benzene
Clean Air Act
Clean Air Act 111 Standards of : SODIUM HYPOCHLORITE Performance for New Stationary Sources PROPYLENE GLYCOL Benzene
Clean Water Act
Clean Water Act Section 307(a)(1) : ZINC CHLORIDE Toxic Pollutants Benzene
Clean Water Act Section 311 : SODIUM HYDROXIDE Hazardous Substances (40 CFR 117.3) ZINC CHLORIDE Benzene
State Regulations
Massachusetts Right-To- : SODIUM HYDROXIDE Know List SODIUM HYPOCHLORITE
Benzene
New Jersey Right-To- : WATER Know List SODIUM CARBONATE
SODIUM SILICATE
SODIUM BISULFITE TERMINATED SODIUM POLYACRYLATE
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This industrial Material Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 0.0 Revision Date 00/00/0000 Print Date 10/03/2012
SODIUM HYDROXIDE
SODIUM HYPOCHLORITE
Pennsylvania Right-To- : WATER Know List SODIUM CARBONATE
SODIUM SILICATE
SODIUM HYDROXIDE
SODIUM HYPOCHLORITE
Canada
Canadian Workplace Hazardous Materials : SODIUM CARBONATE Information System (WHMIS) Listed Material SODIUM HYDROXIDE SODIUM HYPOCHLORITE
Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.
Other Information
TSCA Section 8(b) Status : All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.
SECTION 16. OTHER INFORMATION
Further information
MSDS Number : 200000011882 Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate- Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss resulting from the use of the material.
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Safety Data Sheet according to Hazard Communication Standard; 29 CFR 1910.1200
PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
1. PRODUCT AND COMPANY IDENTIFICATION
Product information Product name : PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™
Recommended use : Hard Surface Cleaner
Manufacturer, importer, : S.C. Johnson & Son, Inc. supplier 1525 Howe Street Racine WI 53403-2236
Telephone : +18005585252 Emergency telephone : 24 Hour Medical Emergency Phone: (866)231-5406 number 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
2. HAZARDS IDENTIFICATION Classification of the substance or mixture
Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Gases under pressure Compressed gas Contains gas under pressure; may explode if heated.
Labelling
Hazard symbols Gas cylinder
Signal word Warning
Hazard statements Contains gas under pressure; may explode if heated.
Precautionary statements Protect from sunlight. Store in a well-ventilated place. Other hazards : None identified
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Revision Date 02/25/2015 SDS Number 350000019958
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 1.00 - 5.00 The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact : No special requirements
Skin contact : No special requirements
Inhalation : No special requirements.
Ingestion : No special requirements
5. FIREFIGHTING MEASURES
Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or media carbon dioxide.
Specific hazards during : Aerosol Product - Containers may rocket or explode in heat of firefighting fire.
Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
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PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Remove all sources of ignition. Wash thoroughly after handling.
Environmental : Outside of normal use, avoid release to the environment. precautions
Methods and materials : Sweep up and shovel into suitable containers for disposal. for containment and Clean residue from spill site. cleaning up
7. HANDLING AND STORAGE
Handling Precautions for safe : Avoid contact with skin, eyes and clothing. handling For personal protection see section 8. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection : Normal measures for preventive fire protection. against fire and explosion
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits Components CAS-No. mg/m3 ppm Non- Basis standard units Ethyl alcohol 64-17-5 1,900 mg/m3 1,000 ppm - OSHA TWA
Ethyl alcohol 64-17-5 - 1,000 ppm - ACGIH STEL
Personal protective equipment Respiratory protection : No special requirements.
Hand protection : No special requirements.
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Eye protection : No special requirements.
Skin and body protection : No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : aerosol Compressed gas
Color : clear
Odor : Woody
Odour Threshold : No data available
pH : 6.0 - 7.0 at (20 °C)
Melting point/freezing point : No data available
Initial boiling point and : No data available boiling range
Flash point : does not flash
Evaporation rate : No data available
Flammability (solid, gas) : Does not sustain combustion.
Upper/lower flammability or : No data available explosive limits
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Revision Date 02/25/2015 SDS Number 350000019958
Vapour pressure : similar to water
Vapour density : No data available
Relative density : 0.99 g/cm3 at 20 °C
Solubility(ies) : completely soluble
Partition coefficient: n- : No data available octanol/water
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, dynamic : similar to water
Viscosity, kinematic : similar to water
Oxidizing properties : No data available
Volatile Organic : 1.9 % - additional exemptions may apply Compounds *as defined by US Federal and State Consumer Product Total VOC (wt. %)* Regulations
Other information : None identified : No data available
10. STABILITY AND REACTIVITY
Possibility of hazardous : If accidental mixing occurs and toxic gas is formed, exit area 5/11
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reactions immediately. Do not return until well ventilated.
Conditions to avoid : Direct sources of heat.
Incompatible materials : Do not mix with bleach or any other household cleaners. Strong bases
Hazardous decomposition : Thermal decomposition can lead to release of irritating gases products and vapours.
11. TOXICOLOGICAL INFORMATION
Emergency Overview : Warning
Acute oral toxicity : LD50 Calculated > 5,000 mg/kg
Acute inhalation toxicity : No data available
Acute dermal toxicity : LD50 Calculated > 2,000 mg/kg
GHS Properties Classification Routes of entry Acute toxicity No classification proposed -
Skin corrosion/irritation No classification proposed -
Serious eye No classification proposed - damage/eye irritation Skin sensitisation No classification proposed -
Respiratory No classification proposed - sensitisation Germ cell mutagenicity No classification proposed -
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PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
Carcinogenicity No classification proposed -
Reproductive toxicity No classification proposed -
Specific target organ No classification proposed - toxicity - single exposure Specific target organ No classification proposed - toxicity - repeated exposure Aspiration hazard No classification proposed -
Aggravated Medical : None known. Condition
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.
Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions.
Toxicity to fish Components End point Species Value Exposure time Ethyl alcohol flow- Pimephales promelas 14,200 96 h through (fathead minnow) mg/l test LC50
Toxicity to aquatic invertebrates Components End point Species Value Exposure time Ethyl alcohol static test Daphnia magna (Water 48 h EC50 flea) 7/11
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PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
2 mg/l
NOEC Daphnia magna 9.6 mg/l 9 d
Toxicity to aquatic plants Components End point Species Value Exposure time Ethyl alcohol Static Chlorella vulgaris (Fresh 275 mg/l 72 h EC50 water algae)
Persistence and degradability Component Biodegradation Exposure Summary time Ethyl alcohol 97 % 28 d Readily biodegradable
Bioaccumulative potential
Component Bioconcentration Partition Coefficient n- factor (BCF) Octanol/water (log) Ethyl alcohol 3.2 estimated -0.35 Measured
Mobility
Component End point Value
Ethyl alcohol No data available
PBT and vPvB assessment Component Results Ethyl alcohol Not fulfilling PBT and vPvB criteria
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Other adverse effects : None known.
13. DISPOSAL CONSIDERATIONS
Consumer may discard empty container in trash, or recycle where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport Sea transport Air transport UN number 1950 1950 1950 UN proper UN 1950 AEROSOLS, UN 1950 UN 1950 AEROSOLS, shipping name non-flammable, 2.2 AEROSOLS, non- non-flammable, 2.2 flammable, 2.2 Transport hazard 2.2 2 2.2 class(es) Packing group - - -
Environmental - - - hazards Special Limited quantities Limited quantities Limited quantities precautions for derogation may be derogation may be derogation may be user applicable to this applicable to this applicable to this product, please check product, please product, please check transport documents. check transport transport documents. documents.
15. REGULATORY INFORMATION
Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
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PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.
16. OTHER INFORMATION HMIS Ratings Health 0
Flammability 0
Reactivity 0
NFPA Ratings Health 0
Fire 0
Reactivity 0
Special -
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
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PLEDGE® EVERYDAY CLEANER MULTISURFACE - GLADE® SHIMMERING SPRUCE™ Version 1.1 Print Date 03/04/2015
Revision Date 02/25/2015 SDS Number 350000019958
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
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SAFETY DATA SHEET THE DOW CHEMICAL COMPANY
Product name: Propanol Issue Date: 03/31/2015 Print Date: 07/31/2015
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.
1. IDENTIFICATION
Product name: Propanol
Recommended use of the chemical and restrictions on use Identified uses: Industrial solvent. Chemical intermediate. We recommend that you use this product in a manner consistent with the listed use. If your intended use is not consistent with the stated use, please contact your sales or technical service representative.
COMPANY IDENTIFICATION THE DOW CHEMICAL COMPANY 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES
Customer Information Number: 800-258-2436 [email protected]
EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 800-424-9300 Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable liquids - Category 3 Serious eye damage - Category 1 Specific target organ toxicity - single exposure - Category 3
Label elements Hazard pictograms
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12 company of Dow Page 118 of 166 Product name: Propanol Issue Date: 03/31/2015
Signal word: DANGER!
Hazards Flammable liquid and vapour. Causes serious eye damage. May cause drowsiness or dizziness.
Precautionary statements Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection.
Response IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.
Disposal Dispose of contents/ container to an approved waste disposal plant.
Other hazards no data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms: propan-1-ol This product is a substance.
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Component CASRN Concentration
Propanol 71-23-8 100.0%
4. FIRST AID MEASURES
Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Wash off with plenty of water.
Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.
Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed Notes to physician: Maintain adequate ventilation and oxygenation of the patient. Chemical eye burns may require extended irrigation. Obtain prompt consultation, preferably from an ophthalmologist. The decision of whether to induce vomiting or not should be made by a physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire.
Special hazards arising from the substance or mixture
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Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide.
Unusual Fire and Explosion Hazards: Container may vent and/or rupture due to fire. When product is stored in closed containers, a flammable atmosphere can develop. Electrically ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures above flash point; see Section 9.
Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Use caution and test if material is burning before entering area. Material burns with invisible flame.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Evacuate area. Refer to section 7, Handling, for additional precautionary measures. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible. Collect in suitable and properly labeled containers. Large spills: Pump with explosion-proof equipment. If available, use foam to smother or supress. Ground and bond all containers and handling equipment. See Section 13, Disposal Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Keep away from heat, sparks and flame. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on
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or near empty containers. Never use air pressure for transferring product. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Do not get in eyes. Avoid breathing vapor. Do not swallow. Avoid contact with skin and clothing. Wash thoroughly after handling. No smoking, open flames or sources of ignition in handling and storage area. Keep container closed. Use only with adequate ventilation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Keep container closed.
Storage stability Storage Period: Steel drums. 24 Month Bulk 12 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure limits are listed below, if they exist. Component Regulation Type of listing Value/Notation Propanol ACGIH TWA 100 ppm OSHA Z-1 TWA 500 mg/m3 200 ppm
Exposure controls Engineering controls: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.
Individual protection measures Eye/face protection: Use chemical goggles. If exposure causes eye discomfort, use a full- face respirator. Skin protection Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Natural rubber (“latex”). Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”). Polyethylene. Ethyl vinyl alcohol laminate (“EVAL”). Polyvinyl chloride (“PVC” or “vinyl”). Viton. Avoid gloves made of: Polyvinyl alcohol (“PVA”). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-
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pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. The following should be effective types of air-purifying respirators: Organic vapor cartridge.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical state Liquid. Color Colorless Odor Mild Odor Threshold No test data available pH No test data available Melting point/range -127 °C ( -197 °F) Literature Freezing point -127 °C ( -197 °F) Literature Boiling point (760 mmHg) 97 °C ( 207 °F) at 100.32 kPa Literature Flash point closed cup 24 °C ( 75 °F) DIN 51755 Evaporation Rate (Butyl Acetate 1.3 Literature = 1) Flammability (solid, gas) Not applicable to liquids Lower explosion limit 2.1 % vol Literature Upper explosion limit 13.7 % vol Literature Vapor Pressure 15 mmHg at 20 °C (68 °F) Literature Relative Vapor Density (air = 1) 2.1 Literature Relative Density (water = 1) 0.805 at 20 °C (68 °F) / 20 °C Literature Water solubility 100 % at 20 °C (68 °F) Literature Partition coefficient: n- log Pow: 0.25 Measured octanol/water Auto-ignition temperature 400 °C (752 °F) at 1,013 hPa Literature Decomposition temperature No test data available Kinematic Viscosity 2.3 mm2/s at 25 °C (77 °F) Literature Explosive properties no data available Oxidizing properties no data available Molecular weight 60.10 g/mol Molecular formula C3H7OH Percent volatility No test data available Saturated vapour concentration No test data available Volatile Organic Compounds 805 g/L Literature
NOTE: The physical data presented above are typical values and should not be construed as a specification.
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10. STABILITY AND REACTIVITY
Reactivity: no data available
Chemical stability: Stable.
Possibility of hazardous reactions: Polymerization will not occur.
Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Avoid static discharge.
Incompatible materials: Avoid contact with: Aldehydes. Halides. Halogenated organics. Halogens. Strong acids. Strong oxidizers.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Carbon monoxide. Carbon dioxide.
11. TOXICOLOGICAL INFORMATION
Toxicological information on this product or its components appear in this section when such data is available.
Acute toxicity Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
LD50, Rat, > 2,000 mg/kg
Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts.
LD50, Rabbit, male, 4,032 mg/kg OECD Test Guideline 402
Acute inhalation toxicity Prolonged excessive exposure may cause adverse effects. May cause respiratory irritation and central nervous system depression. Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness.
LC50, Rat, male and female, 4 Hour, vapour, > 33.8 mg/l OECD Test Guideline 403
Skin corrosion/irritation Prolonged exposure not likely to cause significant skin irritation. May cause drying and flaking of the skin. May cause more severe response on covered skin (under clothing, gloves).
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Serious eye damage/eye irritation May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur. Vapor may cause eye irritation experienced as mild discomfort and redness.
Sensitization Did not cause allergic skin reactions when tested in guinea pigs. Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization: No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure) May cause drowsiness or dizziness. Route of Exposure: Inhalation
Specific Target Organ Systemic Toxicity (Repeated Exposure) In animals, effects have been reported on the following organs: Central nervous system. Liver.
Carcinogenicity Available data are inadequate to evaluate carcinogenicity. Did not cause cancer in animal skin painting studies.
Teratogenicity At extremely high concentrations, n-propanol has been reported to cause birth defects in rats. At progressively lower concentrations there were no birth defects. These concentrations exceed relevant human dose levels.
Reproductive toxicity In animal studies, has been shown to interfere with fertility in males. Effects are reversible. These concentrations exceed relevant human dose levels.
Mutagenicity In vitro genetic toxicity studies were negative in some cases and positive in other cases. Animal genetic toxicity studies were inconclusive
Aspiration Hazard May be harmful if swallowed and enters airways.
12. ECOLOGICAL INFORMATION
Ecotoxicological information on this product or its components appear in this section when such data is available.
Toxicity Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
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LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 4,555 mg/l, OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates LC50, scud Gammarus sp., static test, 48 Hour, 1,000 mg/l
EC50, Daphnia magna (Water flea), static test, 48 Hour, 3,644 mg/l, OECD Test Guideline 202 or Equivalent
Acute toxicity to algae/aquatic plants EC50, Pseudokirchneriella subcapitata (green algae), static test, 48 Hour, Growth rate inhibition, 9,170 mg/l
Toxicity to bacteria IC50, activated sludge, static test, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic aquatic toxicity Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), 21 d, number of offspring, > 100 mg/l
Persistence and degradability Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. 10-day Window: Pass Biodegradation: 83 % Exposure time: 5 d Method: OECD Test Guideline 301D or Equivalent 10-day Window: Pass Biodegradation: 83 - 92 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 2.40 mg/mg
Biological oxygen demand (BOD) Incubation BOD Time 5 d 58 - 64 % 10 d 76 % 20 d 75 - 94 %
Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: Ozone. Atmospheric half-life: 23 Hour Method: Estimated.
Bioaccumulative potential Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.25 Measured
Mobility in soil Potential for mobility in soil is very high (Koc between 0 and 50).
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Partition coefficient(Koc): 3 Estimated.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device.
14. TRANSPORT INFORMATION
DOT Proper shipping name Propyl alcohol, normal UN number UN 1274 Class 3 Packing group III
Classification for SEA transport (IMO-IMDG): Proper shipping name PROPYL ALCOHOL, NORMAL UN number UN 1274 Class 3 Packing group III Marine pollutant No Transport in bulk Consult IMO regulations before transporting ocean bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code
Classification for AIR transport (IATA/ICAO): Proper shipping name Propyl alcohol, normal UN number UN 1274 Class 3 Packing group III
This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.
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15. REGULATORY INFORMATION
OSHA Hazard Communication Standard This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Fire Hazard Acute Health Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) Section 103 This material does not contain any components with a CERCLA RQ.
Pennsylvania Worker and Community Right-To-Know Act: The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting. Components CASRN Propanol 71-23-8
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances knownto the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.
United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
:
16. OTHER INFORMATION
Hazard Rating System NFPA Health Fire Reactivity 2 3 0
Revision Identification Number: 101234211 / A001 / Issue Date: 03/31/2015 / Version: 3.4
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Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.
Legend ACGIH USA. ACGIH Threshold Limit Values (TLV) OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants TWA 8-hour, time-weighted average
Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer- specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/19/2015 46955-00003 Date of first issue: 01/13/2015
SECTION 1. IDENTIFICATION
Product name : PURELL® Hand Sanitizer
Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc.
Address : One GOJO Plaza, Suite 500 Akron OH 44311
Telephone : 1 (330) 255-6000
Emergency telephone : 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer
Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Flammable liquids : Category 3
Eye irritation : Category 2A
GHS Label element Hazard pictograms :
Signal Word : Warning
Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation.
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/19/2015 46955-00003 Date of first issue: 01/13/2015
Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol 64-17-5 >= 50 - < 70 Propan-2-ol 67-63-0 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.
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Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms : Causes serious eye irritation. and effects, both acute and delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet media
Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides ucts
Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Remove all sources of ignition. protective equipment and Use personal protective equipment. emergency procedures Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
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Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.
Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid : Do not store with the following product types: Strong oxidizing agents
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Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm NIOSH REL 980 mg/m3 ST 500 ppm NIOSH REL 1,225 mg/m3 TWA 400 ppm OSHA Z-1 980 mg/m3 Biological occupational exposure limits Ingredients CAS-No. Control Biological Sam- Permissible Basis parameters specimen pling concentratio time n Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH shift at BEI end of work- week Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and
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use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.
Hand protection Material : Impervious gloves
Material : Flame retardant gloves
Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment: Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear, Colorless to pale yellow
Odor : citrus
Odor Threshold : No data available
pH : 6.0 - 9.2
Melting point/freezing point : No data available
Initial boiling point and boiling : No data available range
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Flash point : 25 °C
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Density : 0.89 g/cm3
Solubility(ies) Water solubility : soluble
Partition coefficient: n- : Not applicable octanol/water
Autoignition temperature : No data available
Decomposition temperature : The substance or mixture is not classified self-reactive.
Viscosity Viscosity, kinematic : 1,000 - 35,000 mm2/s (20 °C)
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Flammable liquid and vapor. tions Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known. products
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SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method
Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor
Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation
Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation
Propan-2-ol: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation Causes serious eye irritation. Ingredients:
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Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405
Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization.
Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative
Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative
Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative
Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative
Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative
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Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative
IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative
Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative
STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness.
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STOT-repeated exposure Not classified based on available information. Repeated dose toxicity
Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y
Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.6 mg/l aquatic invertebrates Exposure time: 9 d (Chronic toxicity)
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h
Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l aquatic invertebrates Exposure time: 24 h
Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l
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Version Revision Date: MSDS Number: Date of last issue: 02/10/2015 1.2 03/19/2015 46955-00003 Date of first issue: 01/13/2015
Exposure time: 8 d
Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h
Persistence and degradability
Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d
Propan-2-ol: Biodegradability : Result: rapidly degradable
Bioaccumulative potential
Ingredients: Ethanol: Partition coefficient: n- : log Pow: -0.35 octanol/water
Propan-2-ol: Partition coefficient: n- : log Pow: 0.05 octanol/water
Mobility in soil No data available Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.
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(Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.
Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard
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Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313:
Propan-2-ol 67-63-0 3.013 %
US State Regulations
Pennsylvania Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 50 - 70 % Water 7732-18-5 30 - 50 % Propan-2-ol 67-63-0 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories: AICS : All ingredients listed or exempt.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III: Flammability
HEALTH 2 3 Instability
2 0 FLAMMABILITY 3 Health
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD compile the Material Safety eChem Portal search results and European Chemicals Agen- Data Sheet cy, http://echa.europa.eu/
Revision Date : 03/19/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
US / Z8
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SECTION 1. IDENTIFICATION
Product name : PURELL® Hand Sanitizing Spray
Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc.
Address : One GOJO Plaza, Suite 500 Akron OH 44311
Telephone : 1 (330) 255-6000
Emergency telephone : 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer
Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Flammable liquids : Category 3
Eye irritation : Category 2A
GHS Label element Hazard pictograms :
Signal Word : Warning
Hazard Statements : H226 Flammable liquid and vapor. H319 Causes serious eye irritation.
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Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol 64-17-5 >= 70 - < 90 Propan-2-ol 67-63-0 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.
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Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms : Causes serious eye irritation. and effects, both acute and delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet media
Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides ucts
Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Remove all sources of ignition. protective equipment and Use personal protective equipment. emergency procedures Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
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Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.
Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid : Do not store with the following product types: Strong oxidizing agents
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Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 STEL 1,000 ppm ACGIH Propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm NIOSH REL 980 mg/m3 ST 500 ppm NIOSH REL 1,225 mg/m3 TWA 400 ppm OSHA Z-1 980 mg/m3 Biological occupational exposure limits Ingredients CAS-No. Control Biological Sam- Permissible Basis parameters specimen pling concentratio time n Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH shift at BEI end of work- week Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and
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use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.
Hand protection Material : Impervious gloves
Material : Flame retardant gloves
Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment: Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear, Colorless to pale yellow
Odor : citrus
Odor Threshold : No data available
pH : 5.5 - 9.0
Melting point/freezing point : No data available
Initial boiling point and boiling : No data available range
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Flash point : 25.50 °C
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Density : 0.8740 g/cm3
Solubility(ies) Water solubility : soluble
Partition coefficient: n- : Not applicable octanol/water
Autoignition temperature : No data available
Decomposition temperature : The substance or mixture is not classified self-reactive.
Viscosity Viscosity, kinematic : 1,000 - 17,000 mm2/s (20 °C)
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Flammable liquid and vapor. tions Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known. products
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SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor
Propan-2-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation
Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation
Propan-2-ol: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation Causes serious eye irritation. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405
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Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization.
Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative
Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative
Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative
Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative
Propan-2-ol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative
Carcinogenicity Not classified based on available information. Ingredients: Propan-2-ol:
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Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative
IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative
Propan-2-ol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative
STOT-single exposure Not classified based on available information. Ingredients: Propan-2-ol: Assessment: May cause drowsiness or dizziness.
STOT-repeated exposure Not classified based on available information. Repeated dose toxicity
Ingredients: Ethanol:
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Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y
Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients: Ethanol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.6 mg/l aquatic invertebrates Exposure time: 9 d (Chronic toxicity)
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h
Propan-2-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l aquatic invertebrates Exposure time: 24 h
Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l Exposure time: 8 d
Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h
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Persistence and degradability
Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d
Propan-2-ol: Biodegradability : Result: rapidly degradable
Bioaccumulative potential
Ingredients: Ethanol: Partition coefficient: n- : log Pow: -0.35 octanol/water
Propan-2-ol: Partition coefficient: n- : log Pow: 0.05 octanol/water
Mobility in soil No data available Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 IATA-DGR
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UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : Flammable Liquids Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR UN/ID/NA number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.
Class : 3 Packing group : III Labels : FLAMMABLE LIQUID ERG Code : 127 Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
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SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313:
Propan-2-ol 67-63-0 3.4086 %
US State Regulations
Pennsylvania Right To Know Ethanol 64-17-5 70 - 90 % Water 7732-18-5 20 - 30 % Propan-2-ol 67-63-0 1 - 5 % New Jersey Right To Know Ethanol 64-17-5 70 - 90 % Water 7732-18-5 20 - 30 % Propan-2-ol 67-63-0 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories: REACH : All ingredients (pre-)registered or exempt.
TSCA : All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
DSL : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
AICS : All ingredients listed or exempt.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III: Flammability
HEALTH 2 3 Instability
2 0 FLAMMABILITY 3 Health
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD compile the Material Safety eChem Portal search results and European Chemicals Agen- Data Sheet cy, http://echa.europa.eu/
Revision Date : 03/30/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in- formation and belief at the date of its publication. The information is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro- vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un- less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in- cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
US / Z8
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Page 159 of 166 Super Lube, Multi-Purpose Synthetic Lubricant part number TY25733 Material Safety Data Sheet Issue Date: October 27, 2008 Revised Date: March 10, 2010 Reason: Add HMIS codes.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Common Name: Super Lube, Multi-Purpose Synthetic Lubricant part number TY25733 Product use: Lubricant
Manufactured For: Contact Information: TIG Distributing Telephone: 641-752-7876 P.O. Box 535 Marshalltown, IA 50158
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW Physical state: Aerosol WHMIS hazard class: A, B.5 Color: Translucent HMIS codes: Fire - 3 Odor: Aliphatic Health - 2 Reactance - 0 Other - 0
DANGER: F+ EXTREMELY FLAMMABLE CONTENTS UNDER PRESSURE VAPOR MAY CAUSE FLASH FIRE HARMFUL IF INHALED CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health E ects Inhalation: Vapors and mists will irritate the respiratory tracts and nasal passages. Overexposure may cause nervous system depression. Extreme overexposure may resu ltin unconsciousness and possibly death. Skin contact: Irritating to skin. Eye contact: Contact with eyes will cause irritation. Ingestion: Not expected under normal conditions of use.
Existing conditions aggravated None generally recognized. by exposure:
See Section 11 for additional toxicological information. Page 1 of 7
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components % ACGIH TLV OSHA PEL OTHER
N-Heptane <80 400 ppm TWA 2000 mg/m³ TWA None 142-82-5 500 ppm STEL 500 ppm TWA
Xn, Xi, F+, N; R12-38-51/53-65-67 Additional information: For the wording of the listed risk phrases refer to section 16.
Other components
Polyalphaole n <13 5mg/m³ TWA (mist :) 5mg/m³ TW A (mist :) None 68037-01-4 10mg/m³ STEL (mist :)
White mineral oil (petroleum) <7 5mg/m³ TWA (mist :) 5mg/m³ TWA (mist :) None 8042-47-5 10mg/m³ STEL (mist :)
Antioxidant <0.5 Not established Not established None 41484-35-9
Fumed Silica <3 10mg/m³ TWA 6mg/m³ TWA None 68611-44-9
Polytetra uoroethylene <1 Not established Not established None 9002-84-0
Polyglycol <0.5 AIHA WEEL 025322-69-4 is 50 ppm Total 10mg/m³ aerosol only
Proprietary Additives <0.5 Not established Not established None
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. Restore breathing.
Skin contact: retfA tcatnoc htiw ,niks hsaw yletaidemmi htiw elp nty of water. Immediately ush skin with plenty of water (using soap, if available). Get medical attention if symptoms develop and persist.
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Eye contact: esniR yletaidemmi htiw ytnelp fo ,retaw osla rednu the eyelids, for at least 15 minutes. Get medical attention.
Ingestion: Do not induce vomiting. Get medical attention immediately.
Notes to physician: Treatment:
5. FIRE-FIGHTING MEASURES
Flash point: Not available
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: 1.1 (vol %)
Flammable/Explosive limits-upper %: 7.0 (vol %)
Extinguishing media: Carbon dioxide (CO2). Dry chemical. Foam.
Special re ghting procedures: Water spray may be ine ective. Water should be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.
Unusual re or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat.
Hazardous combustion products: Oxides of carbon.
Sensitivity to mechanical impact: Not available
Sensitivity to static discharge: Not available
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: No information available
Clean-up methods: Remove all ignition sources. Ventilate area. Soak up with inert absorbent.
7. HANDLING AND STORAGE
Handling: esU ylno htiw etauqeda .noitalitnev diovA tcatnoc with eyes, skin and clothing. Do not breathe mist or vapors.
Storage: oD ton ,erutcnup ,etarenicni ro esopxe ot tarepmet ures above 48.9° C (120° F). Heat from sunlight, radiators,
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stoves, hot water, and other heat sources could cause containers to burst.
Incompatible products: None reasonably foreseeable.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls: Local exhaust ventilation is recommended when general ventilation is not su cient to control airborne contamination below occupational exposure limits.
Respiratory protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH.
Skin protection: Chemical resistant, impermeable gloves.
Eye/face protection: Safety glasses with side-shields.
See Section 3 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Aerosol Color: Translucent Odor: Aliphatic Odor Threshold: Not available Vapor pressure: 5.0 – 5.5 BAR @ 20° C pH: Not applicable Boiling point/range: Not available Melting point/range: Not available Speci c gravity: Not available Vapor density: Heavier than air Evaporation rate: Faster than ether Solubility in water: Not soluble Partition coe cient (n-octano/water): Not available VOC content: 77.0%
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None under normal use.
Incompatibility: None known.
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Conditions to avoid: Heat, ames and sparks.
11. TOXICOLOGICAL INFORMATION
Product toxicity data: Not available
Toxicologically synergistic products: Not available
Refer to the following for irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity.
Ingredient Toxicity Data & Carcinogen Status
Hazardous LD50s & LC50s Other LD50s NTP IARC OSHA ACGIH- components and LC50s Carcinogen Carcinogen Carcinogen Carcinogen n-Heptane Inhalation LC50 None No No No No 142-82-5 (Rat) = 103 g/m³ Other components Polyalphaole n None None No No No No Proprietary White mineral Oral LD50 (Rat) None No No No No Oil (petroleum) >5000 mg/kg 8042-47-5 Antioxidant Oral LD50 (Rat) None No No No No 41484-35-6 >5000 mg/kg Dermal LD50(Rabbit) >3000 mg/kg Inhalation LC50 (Rat) >3.5 mg/m³ Fumed Silica Oral LD50 (Rat) None No No No No 68611-44-9 >5000 mg/kg Polytetra- Not determined None No No No No uoroethylene 9002-84-0 Polyglycol Oral LD50 (Rats) None No No No No 025322-69-4 >10,000 mg/kg Dermal LD50 (Rabbit) >10,000 mg/kg
Literature Referenced Target Organ & Other Health E ects
stnenopmoc suodrazaH stnenopmoc htlaeH tegraT/stceffE snagrO n-Heptane Central nervous system, irritant 142-82-5 Other components
Polyalphaole n No target organs Proprietary White mineral oil (petroleum) Irritant Page 5 of 7
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8042-47-5 Antioxidant No target organs 41484-35-6 Fumed Silica Nuisance dust, irritant to eyes and skin 68611-44-6 Polytetra uoroethylene Irritant 9002-84-0 Polyglycol No target organs 025322-69-4
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of in accordance with federal and local regulations.
14. TRANSPORT INFORMATION
Transportation of Dangerous Goods – Ground: Proper shipping name: Consumer Commodity, ORM-D Hazardous class or division: None Identi cation number: None Packing group: None
International Air Transportation (ICAO/IATA): Proper shipping name: Aerosols, Flammable Hazardous class or division: 2.1 Identi cation number: UN 1950 Packing group: Y203 Exceptions: (Not more than 500 ml) May qualify as Consumer Commodity ID8000
Water Transportation (IMO/IMDG): Proper shipping name: Aerosols, LTD. QTY. Hazardous class or division: 2 Identi cation number: UN 1950 Packing group: None Marine pollutant: None
15. REGULATORY INFORMATION
Labeling according to EU guidelines: The product has been classi ed and marked in accordance with EU Directives/Ordinance on Hazardous Materials.
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Code letter and hazard designation of product: F+ Extremely ammable.
Risk phrases: 12 Extremely ammable. 52/53 Harmful to aquatic organisms, may cause long- term adverse e ects in the aquatic environment. 67 Vapors may cause drowsiness and dizziness.
Safety phrases: 3/7 Keep container tightly closed in a cool place. 16 Keep away from sources of ignition-No smoking. 23 Do not breathe fumes/aerosol. 51 Use only in well ventilated areas.
Special labeling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn even after use. Keep out of reach of children.
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
SECTION 16: OTHER INFORMATION
This product contains a chemical known to the state of California to cause cancer/reproductive harm.
This product has been classi ed in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the informati on required by the Controlled Product Regulations.
Relevant R-phrases: 11 Highly ammable 38 Irritating to skin. 51/53 Toxic to aquatic organisims, may cause long-term adverse e ects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 67 Vapors may cause drowsiness and dizziness.
Data prepared by Environment protection department.
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