Recent Reviews Covers Principally the Early Part of the 2015 Literature

Home , Automated synthesis, Grignard reaction, Organonickel, Organoplatinum

Number 116

compiled by Veronica M. Cornel

Department of Chemistry, Reedley College, 995 Reed Avenue, Reedley, California 93654

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index.

Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted.

This installment of Recent Reviews covers principally the early part of the 2015 literature. Previous installment: J. Org. Chem. 2015, 80(1).

Additional Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in plain text that can be imported into Endnote (using Refer style) and Reference Manager databases.

Regularly Issued Journals and Series Volumes

Accounts of Chemical Research palladium and -Platinum Complexes. 2015, 48(2), 238-47. 1. Kammerer, C.; Prestat, G.; Madec, D.; Poli, 9. Soleilhavoup, M.; Bertrand, G. Cyclic G. Synthesis of γ-Lactams and γ-Lactones via (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes Intramolecular Pd-Catalyzed Allylic Alkylations. on the Rise. 2015, 48(2), 256-66. 2014, 47(12), 3439-47. 10. Stephan, D. W. Frustrated Lewis Pairs: 2. Liu, C.; Liu, D.; Lei, A. Recent Advances of From Concept to Catalysis. 2015, 48(2), 306-16. Transition-Metal Catalyzed Radical Oxidative 11. Seidel, D. The Azomethine Ylide Route to Cross-Couplings. 2014, 47(12), 3459-70. Amine C-H Functionalization: Redox-Versions of 3. Wolstenhulme, J. R.; Gouverneur, V. Classic Reactions and a Pathway to New Asymmetric Fluorocyclizations of Alkenes. 2014, Transformations. 2015, 48(2), 317-28. 47(12), 3560-70. 12. O'Hair, R. A. J.; Rijs, N. J. Gas Phase 4. Han, Y.-F.; Jin, G.-X. Half-Sandwich Studies of the Pesci Decarboxylation Reaction: Iridium- and Rhodium-based Organometallic Arch- Synthesis, Structure, and Unimolecular and Bi- itectures: Rational Design, Synthesis, Character- molecular Reactivity of Organometallic Ions. 2015, ization, and Applications. 2014, 47(12), 3571-9. 48(2), 329-40. 5. Soai, K.; Kawasaki, T.; Matsumoto, A. 13. Chelucci, G.; Baldino, S.; Baratta, W. Asymmetric Autocatalysis of Pyrimidyl Alkanol and Recent Advances in Osmium-Catalyzed Hydrogen- Its Application to the Study on the Origin of ation and Dehydrogenation Reactions. 2015, 48(2), Homochirality. 2014, 47(12), 3643-54. 363-79. 6. Bai, W.-J.; David, J. G.; Feng, Z.-G.; 14. Zhu, C.; Saito, K.; Yamanaka, M.; Akiyama, Weaver, M. G.; Wu, K.-L.; Pettus, T. R. R. The T. Benzothiazoline: Versatile Hydrogen Donor for Domestication of Ortho-Quinone Methides. 2014, Organocatalytic Transfer Hydrogenation. 2015, 47(12), 3655-64. 48(2), 388-98. 7. Zhu, Y.; Cornwall, R. G.; Du, H.; Zhao, B.; 15. Zhang, L.; Cao, Y.; Colella, N. S.; Liang, Y.; Shi, Y. Catalytic Diamination of Olefins via N-N Bredas, J.-L.; Houk, K. N.; Briseno, A. L. Bond Activation. 2014, 47(12), 3665-78. Unconventional, Chemically Stable, and Soluble 8. Vigalok, A. Electrophilic Halogenation- Two-Dimensional Angular Polycyclic Aromatic Reductive Elimination Chemistry of Organo- Hydrocarbons: From Molecular Design to Device Applications. 2015, 48(3), 500-9. 31. Wang, L.-X.; Xiang, J.-F.; Tang, Y.-L. Novel 16. Golder, M. R.; Jasti, R. Syntheses of the DNA Catalysts Based on G-Quadruplex for Organic Smallest Carbon Nanohoops and the Emergence of Synthesis. 2015, 357(1), 13-20. Unique Physical Phenomena. 2015, 48(3), 557-66. 32. Chauhan, P.; Mahajan, S.; Kaya, U.; Hack, D.; 17. Cookson, R.; Barrett, T. N.; Barrett, A. G. Enders, D. Bifunctional Amine-Squaramides: Powerful M. β-Keto-dioxinones and β,δ-Diketo-dioxinones in Hydrogen-Bonding Organocatalysts for Asymmetric Biomimetic Resorcylate Total Synthesis. 2015, Domino/Cascade Reactions. 2015, 357(2-3), 253-81. 48(3), 628-42. 33. Younus, H. A.; Su, W.; Ahmad, N.; Chen, S.; 18. Sears, J. E.; Boger, D. L. Total Synthesis of Verpoort, F. Ruthenium Pincer Complexes: Synthesis Vinblastine, Related Natural Products, and Key and Catalytic Applications. 2015, 357(2-3), 283-330. Analogues and Development of Inspired Method- 34. Hassan, S.; Mueller, T. J. J. Multicomponent ology Suitable for the Systematic Study of Their Syntheses Based upon Copper-Catalyzed Alkyne-Azide Structure-Function Properties. 2015, 48(3), 653-62. Cycloaddition. 2015, 357(4), 617-66. 19. Micalizio, G. C.; Hale, S. B. Reaction 35. Pellissier, H. Enantioselective Titanium- Design, Discovery, and Development as a Found- Catalyzed Cyanation Reactions of Carbonyl Com- ation to Function-Oriented Synthesis. 2015, 48(3), pounds. 2015, 357(5), 857-82. 663-73. 36. Bagal, D. B.; Bhanage, B. M. Recent Advances 20. Reed, J. W.; Hudlicky, T. The Quest for a in Transition Metal-Catalyzed Hydrogenation of Practical Synthesis of Morphine Alkaloids and Their Nitriles. 2015, 357(5), 883-900. Derivatives by Chemoenzymatic Methods. 2015, 37. Munirathinam, R.; Huskens, J.; Verboom, W. 48(3), 674-87. Supported Catalysis in Continuous-Flow Microreactors. 21. Trost, B. M.; Bartlett, M. J. Prophenol- 2015, 357(6), 1093-123. Catalyzed Asymmetric Additions by Spontaneously 38. Yan, G.; Borah, A. J.; Wang, L.; Yang, M. Assembled Dinuclear Main Group Metal Complexes. Recent Advances in Transition Metal-Catalyzed 2015, 48(3), 688-701. Methylation Reactions. 2015, 357(7), 1333-50. 22. Zi, W.; Zuo, Z.; Ma, D. Intramolecular Dearomative Oxidative Coupling of Indoles: A Aldrichimica Acta Unified Strategy for the Total Synthesis of Indoline Alkaloids. 2015, 48(3), 702-11. 39. Kobayashi, S.; Miyamura, H. Polymer-Incar- 23. Liu, Y.; Han, S.-J.; Liu, W.-B.; Stoltz, B. M. cerated Metals. Highly Reactive, Recoverable, and Catalytic Enantioselective Construction of Quat- Multifunctional Nanocluster Catalysts for Organic ernary Stereocenters: Assembly of Key Building Synthesis. 2013, 46(1), 3-19. Blocks for the Synthesis of Biologically Active 40. Subiros-Funosas, R.; Khattab, S. N.; Nieto- Molecules. 2015, 48(3), 740-51. Rodriguez, L.; El-Faham, A.; Albericio, F. Advances in 24. Cornil, J.; Gonnard, L.; Bensoussan, C.; Acylation Methodologies Enabled by Oxyma-Based Serra-Muns, A.; Gnamm, C.; Commandeur, C.; Reagents. 2013, 46(1), 21-40. Commandeur, M.; Reymond, S.; Guerinot, A.; Cossy, 41. Panda, S. S.; Hall, C. D.; Scriven, E.; J. Iron- and Indium-Catalyzed Reactions Toward Katritzky, A. R. Aminoacyl Benzotriazolides: Versatile Nitrogen- and Oxygen-Containing Saturated Reagents for the Preparation of Peptides and Their Heterocycles. 2015, 48(3), 761-73. Mimetics and Conjugates. 2013, 46(2), 43-55. 25. Rury, A. S.; Wiley, T. E.; Sension, R. J. 42. Greco, S. J.; Fiorot, R. G.; Lacerda, V.; dos Energy Cascades, Excited State Dynamics, and Santos, R. B. Recent Advances in the Prins Cyclization. Photochemistry in Cob(III)alamins and Ferric 2013, 46(2), 59-67. Porphyrins. 2015, 48(3), 860-7. 43. van Gemmeren, M.; Lay, F.; List, B. 26. Su, B.; Cao, Z.-C.; Shi, Z.-J. Exploration of Asymmetric Catalysis Using Chiral, Enantiopure Earth-Abundant Transition Metals (Fe, Co, and Ni) Disulfonimides. 2014, 47(1), 3-13. as Catalysts in Unreactive Chemical Bond 44. Wong, G. W.; Landis, C. R. Highly Enantio- Activations. 2015, 48(3), 886-96. selective Hydroformylation of Alkenes by Rhodium- Diazaphospholane Catalysts. 2014, 47(2), 29-38. Advanced Synthesis and Catalysis 45. Zheng, H.; Hall, D. G. Boronic Acid Catalysis: An Atom-Economical Platform for Direct Activation and 27. Zhang, C. Application of Langlois' Reagent in Functionalization of Carboxylic Acids and Alcohols. Trifluoromethylation Reactions. 2014, 356(14-15), 2014, 47(2), 41-51. 2895-906. 28. Diaz-de-Villegas, M. D.; Galvez, J. A.; Angewandte Chemie, International Edition in Badorrey, R.; Lopez-Ram-de-Viu, P. Organocatalysis in English Enantioselective α-Functionalization of 2-Cyanoacet- ates. 2014, 356(16), 3261-88. 46. Zhou, C.-X.; Zhang, W.; You, S.-L. Catalytic 29. Qiu, G.; Kuang, Y.; Wu, J. N-Imide Ylide- Asymmetric Dearomatization Reactions. 2012, Based Reactions: C-H Functionalization, Nucleophilic 51(51), 12662-86. Addition and Cycloaddition. 2014, 356(17), 3483-504. 47. Gong, L.; Chen, L.-A.; Meggers, E. 30. Pace, V.; Holzer, W.; Olofsson, B. Increasing Asymmetric Catalysis Mediated by the Ligand the Reactivity of Amides Towards Organometallic Sphere of Octahedral Chiral-at-Metal Complexes. Reagents: An Overview. 2014, 356(18), 3697-736. 2014, 53(41), 10868-74. 48. Eschenbrenner-Lux, V.; Kumar, K.; Wald- mann, H. The Asymmetric Hetero-Diels-Alder Asymmetric Autocatalysis. 2014, 14(1), 70-83. Reaction in the Syntheses of Biologically Relevant 67. Kawai, H.; Shibata, N. Asymmetric Compounds. 2014, 53(42), 11146-57. Synthesis of Agrochemically Attractive Trifluoro- 49. Mak, J. Y. W.; Pouwer, R. H.; Williams, C. methylated Dihydroazoles and Related Compounds M. Natural Products with Anti-Bredt and under Organocatalysis. 2014, 14(6), 1024-40. Bridgehead Double Bonds. 2014, 53(50), 13664-88. 68. Qian, H.; Zhao, W.; Sun, J. Siloxy Alkynes 50. Segawa, Y.; Maekawa, T.; Itami, K. in Annulation Reactions. 2014, 14(6), 1070-85. Synthesis of Extended π-Systems through C-H 69. Lam, H. Y.; Gaarden, R. I.; Li, X. A Journey Activation. 2015, 54(1), 66-81. to the Total Synthesis of Daptomycin. 2014, 14(6), 51. Arnold, P. L.; McMullon, M. W.; Rieb, J.; 1086-99. Kuehn, F. E. C-H Bond Activation by f-Block 70. Streuff, J. Reductive Umpolung Reactions Complexes. 2015, 54(1), 82-100. with Low-Valent Titanium Catalysts. 2014, 14(6), 52. Smith, J. M.; Moreno, J.; Boal, B. W.; Garg, 1100-13. N. K. Cascade Reactions: A Driving Force in 71. Altnoeder, J.; Krueger, K.; Borodin, D.; Akuammiline Alkaloid Total Synthesis. 2015, 54(2), Reuter, L.; Rohleder, D.; Hecker, F.; Schulz, R. A.; 400-12. Nguyen, X. T.; Preiss, H.; Eckhoff, M.; Levien, M.; 53. Marek, I.; Masarwa, A.; Delaye, P.-O.; Suhm, M. A. The Guinness Molecules for the Leibeling, M. Selective Carbon-Carbon Bond Carbohydrate Formula. 2014, 14(6), 1116-33. Cleavage for the Stereoselective Synthesis of Acyclic 72. Tobe, Y. Non-Alternant Non-Benzenoid Systems. 2015, 54(2), 414-29. Aromatic Compounds: Past, Present, and Future. 54. Dong, J. J.; Browne, W. R.; Feringa, B. L. 2015, 15(1), 86-96. Palladium-Catalyzed anti-Markovnikov Oxidation 73. Yu, C.; Jin, Y.; Zhang, W. Shape-Persistent of Terminal Alkenes. 2015, 54(3), 734-44. Arylene Ethynylene Organic Hosts for Fullerenes. 55. Leonori, D.; Aggarwal, V. K. Stereospecific 2015, 15(1), 97-106. Couplings of Secondary and Tertiary Boronic 74. Feng, C.-N.; Hsieh, Y.-C.; Wu, Y.-T. Metal- Esters. 2015, 54(4), 1082-96. Catalyzed Cascade Reactions: Useful Synthetic 56. Fegler, W.; Venugopal, A.; Kramer, M.; Tools for the Preparation of Polycyclic Arenes. 2015, Okuda, J. Molecular Rare-Earth-Metal Hydrides in 15(1), 266-79. Non-Cyclopentadienyl Environments. 2015, 54(6), 75. Zeng, Z.; Wu, J. Stable π-Extended p- 1724-36. Quinodimethanes: Synthesis and Tunable Ground 57. Holland, M. C.; Gilmour, R. Deconstructing States. 2015, 15(1), 322-8. Covalent Organocatalysis. 2015, 54(13), 3862-71. 76. Bettinger, H. F.; Toenshoff, C. The Longest 58. Stephan, D. W.; Erker, G. Frustrated Lewis Acenes. 2015, 15(1), 364-9. Pair Chemistry: Development and Perspectives. 2015, 54(22), 6400-41. Chemical Reviews

Australian Journal of Chemistry 77. Gunanathan, C.; Milstein, D. Bond Activation and Catalysis by Ruthenium Pincer 59. Matesic, L. [18F] Radiochemistry using the Complexes. 2014, 114(24), 12024-87. NanoTek Microfluidic Synthesis System. 2013, 78. Petersen, A. B.; Roennest, M. H.; Larsen, T. 66(11), 1459-60. O.; Clausen, M. H. The Chemistry of Griseofulvin. 60. Wentrup, C. Flash (Vacuum) Pyrolysis 2014, 114(24), 12088-107. Apparatus and Methods. 2014, 67(9), 1150-65. 79. Buchwalter, P.; Rose, J.; Braunstein, P. 61. Chrostowska, A.; Lesniak, S. Recent Multimetallic Catalysis Based on Heterometallic Studies on Flash Vacuum Thermolysis in Tandem Complexes and Clusters. 2015, 115(1), 28-126. with UV-Photoelectron Spectroscopy and Quantum 80. Crabtree, R. H. Deactivation in Homo- Calculations. 2014, 67(9), 1166-73. geneous Transition Metal Catalysis: Causes, Avoid- 62. Brown, J. M. Origins of Stabilization and ance, and Cure. 2015, 115(1), 127-50. Evidence for Charge Delocalization in the 81. Cresswell, A. J.; Davies, S. G.; Roberts, P. Bicyclo[3.2.1]octadienyl Anion and Related Species. M.; Thomson, J. E. Beyond the Balz-Schiemann 2014, 67(9), 1296-300. Reaction: The Utility of Tetrafluoroborates and 63. Wilkinson, S. M.; Banister, S. D.; Kassiou, Boron Trifluoride as Nucleophilic Fluoride Sources. M. Bioisosteric Fluorine in the Clandestine Design 2015, 115(2), 566-611. of Synthetic Cannabinoids. 2015, 68(1), 4-8. 82. Campbell, M. G.; Ritter, T. Modern Carbon- 64. Waring, P.; Chai, C. L. L. The Multiple Fluorine Bond Forming Reactions for Aryl Fluoride Properties of Gliotoxin and Other Epipolythio- Synthesis. 2015, 115(2), 612-33. dioxopiperazine Metabolites. 2015, 68(2), 178-83. 83. Charpentier, J.; Fruh, N.; Togni, A. 65. Malins, L. R.; Payne, R. J. Synthetic Amino Electrophilic Trifluoromethylation by Use of Hyper- Acids for Applications in Peptide Ligation- valent Iodine Reagents. 2015, 115(2), 650-82. Desulfurization Chemistry. 2015, 68(4), 521-37. 84. Liu, X.; Xu, C.; Wang, M.; Liu, Q. Trifluoro- methyltrimethylsilane: Nucleophilic Trifluorometh- The Chemical Record ylation and Beyond. 2015, 115(2), 683-730. 85. Xu, X.-H.; Matsuzaki, K.; Shibata, N. 66. Soai, K.; Kawasaki, T.; Matsumoto, A. The Synthetic Methods for Compounds Having CF3-S Origins of Homochirality Examined by Using Units on Carbon by Trifluoromethylation, Trifluoro- methylthiolation, Triflylation, and Related Reac- 103. Frihed, T. G.; Bols, M.; Pedersen, C. M. tions. 2015, 115(2), 731-64. Synthesis of L-Hexoses. 2015, 115(9), 3615-76. 86. Ni, C.; Hu, M.; Hu, J. Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorin- Chemical Society Reviews ation and Fluoroalkylation Reagents for Organic Synthesis. 2015, 115(2), 765-825. 104. Boehler, E.; Warneke, J.; Swiderek, P. 87. Yang, X.; Wu, T.; Phipps, R. J.; Toste, F. D. Control of Chemical Reactions and Synthesis by Low- Advances in Catalytic Enantioselective Fluorin- Energy Electrons. 2013, 42(24), 9219-31. ation, Mono-, Di-, and Trifluoromethylation, and 105. Klajn, R. Spiropyran-Based Dynamic Trifluoromethylthiolation Reactions. 2015, 115(2), Materials. 2014, 43(1), 148-84. 826-70. 106. Vesely, J.; Rios, R. Enantioselective 88. Fustero, S.; Simon-Fuentes, A.; Barrio, P.; Methodologies using N-Carbamoyl Imines. 2014, 43(2), Haufe, G. Olefin Metathesis Reactions with Fluor- 611-30. inated Substrates, Catalysts, and Solvents. 2015, 107. Properzi, R.; Marcantoni, E. Construction 115(2), 871-930. of Heterocyclic Structures by Trivalent Cerium Salts 89. Ahrens, T.; Kohlmann, J.; Ahrens, M.; Promoted Bond Forming Reactions. 2014, 43(3), 779-91. Braun, T. Functionalization of Fluorinated 108. Cavitt, M. A.; Phun, L. H.; France, S. Molecules by Transition-Metal-Mediated C-F Bond Intramolecular Donor-Acceptor Cyclopropane Ring- Activation to Access Fluorinated Building Blocks. Opening Cyclizations. 2014, 43(3), 804-18. 2015, 115(2), 931-72. 109. Carroll, M. P.; Guiry, P. J. P,N Ligands in 90. Nenajdenko, V. G.; Muzalevskiy, V. M.; Asymmetric Catalysis. 2014, 43(3), 819-33. Shastin, A. V. Polyfluorinated Ethanes as Versatile 110. Luo, Y.; Pan, X.; Yu, X.; Wu, J. Double Fluorinated C2-Building Blocks for Organic Carbometallation of Alkynes: An Efficient Strategy for Synthesis. 2015, 115(2), 973-1050. the Construction of Polycycles. 2014, 43(3), 834-46. 91. Boltalina, O. V.; Popov, A. A.; Kuvychko, I. 111. Nitschke, J. R. Supramolecular and V.; Shustova, N. B.; Strauss, S. H. Perfluoro- Dynamic Covalent Reactivity. 2014, 43(6), 1798-9. alkylfullerenes. 2015, 115(2), 1051-105. 112. Cera, L.; Schalley, C. A. Supramolecular 92. Savoie, P. R.; Welch, J. T. Preparation and Reactivity in the Gas Phase: Investigating the Intrinsic Utility of Organic Pentafluorosulfanyl-Containing Properties of Non-Covalent Complexes. 2014, 43(6), Compounds. 2015, 115(2), 1130-90. 1800-12. 93. Vizer, S. A.; Sycheva, E. S.; Al Quntar, A. 113. Black, S. P.; Sanders, J. K. M.; Stefan- A. A.; Kurmankulov, N. B.; Yerzhanov, K. B.; kiewicz, A. R. Disulfide Exchange: Exposing Supra- Dembitsky, V. M. Propargylic Sulfides: Synthesis, molecular Reactivity Through Dynamic Covalent Properties, and Application. 2015, 115(3), 1475-502. Chemistry. 2014, 43(6), 1861-72. 94. Jia, Y.; Li, J. Molecular Assembly of Schiff 114. Ji, Q.; Lirag, R. C.; Miljanic, O. S. Base Interactions: Construction and Application. Kinetically Controlled Phenomena in Dynamic Combin- 2015, 115(3), 1597-621. atorial Libraries. 2014, 43(6), 1873-84. 95. Guo, X.-X.; Gu, D.-W.; Wu, Z.; Zhang, W. 115. Yoshizawa, M.; Klosterman, J. K. Copper-Catalyzed C-H Functionalization Reactions: Molecular Architectures of Multi-Anthracene Assem- Efficient Synthesis of Heterocycles. 2015, 115(3), blies. 2014, 43(6), 1885-98. 1622-51. 116. Zhang, G.; Mastalerz, M. Organic Cage 96. Alonso, C.; Martinez de Marigorta, E.; Compounds - From Shape-Persistency to Function. Rubiales, G.; Palacios, F. Carbon Trifluoromethyl- 2014, 43(6), 1934-47. ation Reactions of Hydrocarbon Derivatives and 117. Wilson, A.; Gasparini, G.; Matile, S. Heteroarenes. 2015, 115(4), 1847-935. Functional Systems with Orthogonal Dynamic Covalent 97. Huang, L.; Arndt, M.; Goossen, K.; Heydt, Bonds. 2014, 43(6), 1948-62. H.; Goossen, L. J. Late Transition Metal-Catalyzed 118. Su, X.; Aprahamian, I. Hydrazone-Based Hydroamination and Hydroamidation. 2015, 115(7), Switches, Metallo-Assemblies and Sensors. 2014, 43(6), 2596-697. 1963-81. 98. Boyarskiy, V. P.; Bokach, N. A.; Luzyanin, 119. Schulze, B.; Schubert, U. S. Beyond Click K. V.; Kukushkin, V. Y. Metal-Mediated and Metal- Chemistry - Supramolecular Interactions of 1,2,3- Catalyzed Reactions of Isocyanides. 2015, 115(7), Triazoles. 2014, 43(8), 2522-71. 2698-779. 120. Parker, D. S. N.; Mebel, A. M.; Kaiser, R. 99. Brown, C. J.; Toste, F. D.; Bergman, R. G.; I. The Role of Isovalency in the Reactions of the Cyano Raymond, K. N. Supramolecular Catalysis in Metal- (CN), Boron Monoxide (BO), Silicon Nitride (SiN), and Ligand Cluster Hosts. 2015, 115(9), 3012-35. Ethynyl (C2H) Radicals with Unsaturated Hydro- 100. Golets, M.; Ajaikumar, S.; Mikkola, J.-P. carbons Acetylene (C2H2) and Ethylene (C2H4). 2014, Catalytic Upgrading of Extractives to Chemicals: 43(8), 2701-13. Monoterpenes to "EXICALS". 2015, 115(9), 3141-69. 121. Lundberg, H.; Tinnis, F.; Selander, N.; 101. Bauer, I.; Knoelker, H.-J. Iron Catalysis Adolfsson, H. Catalytic Amide Formation from Non- in Organic Synthesis. 2015, 115(9), 3170-387. Activated Carboxylic Acids and Amines. 2014, 43(8), 102. Yang, L.; Huang, H. Transition-Metal- 2714-42. Catalyzed Direct Addition of Unactivated C-H 122. Lopez, F.; Mascarenas, J. L. [4+2] and Bonds to Polar Unsaturated Bonds. 2015, 115(9), [4+3] Catalytic Cycloadditions of Allenes. 2014, 43(9), 3468-517. 2904-15. 123. Caneque, T.; Truscott, F. M.; Rodriguez, Approach. 2014, 43(14), 4968-88. R.; Maestri, G.; Malacria, M. Electrophilic Activation of 144. Hong, Y. J.; Tantillo, D. J. How Cyclo- Allenenes and Allenynes: Analogies and Differences butanes are Assembled in Nature - Insights from between Bronsted and Lewis Acid Activation. 2014, Quantum Chemistry. 2014, 43(14), 5042-50. 43(9), 2916-26. 145. Xie, J.; Pan, C.; Abdukader, A.; Zhu, C. 124. Wang, Z.; Xu, X.; Kwon, O. Phosphine Gold-Catalyzed C(3)-H Bond Functionalization. 2014, Catalysis of Allenes with Electrophiles. 2014, 43(9), 43(15), 5245-56. 2927-40. 146. Cai, J.; Sessler, J. L. Neutral CH and 125. Yang, W.; Hashmi, A. S. K. Mechanistic Cationic CH Donor Groups as Anion Receptors. 2014, Insights Into the Gold Chemistry of Allenes. 2014, 43(17), 6198-213. 43(9), 2941-55. 147. Morrill, L. C.; Smith, A. D. Organo- 126. Tius, M. A. Allene Ether Nazarov Cycliz- catalytic Lewis Base Functionalisation of Carboxylic ation. 2014, 43(9), 2979-3002. Acids, Esters and Anhydrides via C1-Ammonium or 127. Le Bras, J.; Muzart, J. Palladium- Azolium Enolates. 2014, 43(17), 6214-26. Catalysed Inter- and Intramolecular Formation of C-O 148. Mateo-Alonso, A. Pyrene-Fused Pyraza- Bonds from Allenes. 2014, 43(9), 3003-40. acenes: From Small Molecules to Nanoribbons. 2014, 128. Soriano, E.; Fernandez, I. Allenes and 43(17), 6311-24. Computational Chemistry: From Bonding Situations to 149. Zhang, F.; Spring, D. R. Arene C-H Reaction Mechanisms. 2014, 43(9), 3041-105. Functionalisation Using a Removable/Modifiable or a 129. Alcaide, B.; Almendros, P.; Aragoncillo, C. Traceless Directing Group Strategy. 2014, 43(20), 6906- Cyclization Reactions of Bis(Allenes) for the Synthesis 19. of Polycarbo(Hetero)Cycles. 2014, 43(9), 3106-35. 150. Xin, B.; Hao, J. Imidazolium-Based Ionic 130. Munoz, M. P. Silver and Platinum- Liquids Grafted on Solid Surfaces. 2014, 43(20), 7171- Catalyzed Addition of O-H and N-H bonds to Allenes. 87. 2014, 43(9), 3164-83. 151. Sanchez-Rosello, M.; Acena, J. L.; Simon- 131. Januszewski, J. A.; Tykwinski, R. R. Fuentes, A.; del Pozo, C. A General Overview of the Synthesis and Properties of Long [n]Cumulenes (n ≥ 5). Organocatalytic Intramolecular Aza-Michael Reaction. 2014, 43(9), 3184-203. 2014, 43(21), 7430-53. 132. Ros, A.; Fernandez, R.; Lassaletta, J. M. 152. Weaver, J. F.; Hakanoglu, C.; Antony, A.; Functional Group Directed C-H Borylation. 2014, Asthagiri, A. Alkane Activation on Crystalline Metal 43(10), 3229-43. Oxide Surfaces. 2014, 43(22), 7536-47. 133. Sambiagio, C.; Marsden, S. P.; Blacker, A. 153. Rousseau, R.; Dixon, D. A.; Kay, B. D.; J.; McGowan, P. C. Copper Catalysed Ullmann Type Dohnalek, Z. Dehydration, Dehydrogenation and Chemistry: From Mechanistic Aspects to Modern Condensation of Alcohols on Supported Oxide Catalysts Development. 2014, 43(10), 3525-50. Based on Cyclic (WO3)3 and (MoO3)3 Clusters. 2014, 134. Bohne, C. Supramolecular Dynamics. 43(22), 7664-80. 2014, 43(12), 4037-50. 154. Cornella, J.; Zarate, C.; Martin, R. Metal- 135. Yang, C.; Inoue, Y. Supramolecular Catalyzed Activation of Ethers via C-O Bond Cleavage: Photochirogenesis. 2014, 43(12), 4123-43. A New Strategy for Molecular Diversity. 2014, 43(23), 136. Bibal, B.; Mongin, C.; Bassani, D. M. 8081-97. Template Effects and Supramolecular Control of 155. Roscales, S.; Csaky, A. G. Transition- Photoreactions in Solution. 2014, 43(12), 4179-98. Metal-Free C-C Bond Forming Reactions of Aryl, 137. Cho, H. Y.; Morken, J. P. 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Index

Acetylene, radical reactions, 120 Aminothiadiazoles, 258 sustainable metals, 331 Activation strain model, 142 Ammonium ylides, nitrile Catalysts, Fe, Co, Ni, 26 Acyl transfer reactions, stabilized, 343 Catenanes, 139 mechanism, 207 Anthracene, multi-complexes, 115 C-C bond cleavage, selective, 53 Acylation, oxyma reagent, 40 Antibiotic peptide daptomycin C-H activation, f-block, 51 Alcohols, functionalization, 45 synthesis, 69 CH hydrogen bond donors, 146 Aldehydes, dehydroformylation, Aromatics, C-H functionalization, Chalcone synthons, 224 300 149 Chelation catalysis, 327 preparation, alkene double deprotonation, 297 Chiral metal centers, octahedral, hydroformylation, 44 nonalternant, nonbenzenoid, 47 Alkaloids, akuammiline, 72 Chiroptical spectra, 184 synthesis, 52 Artemisinin synthesis, 279 Coinage metal complex, 264 enantioselective synthesis, Aryl propargylic alcohols, 220 dipolar cycloaddition, 260 290 Aryl(di)azinylmethanes, 344 Combinatorial libraries, dynamic, morphine, 20 Asymmetric autocatalysis, 114 Alkenes, addition, homochirality, 66 Conhydrine, 345 stereochemistry, 163 Asymmetric conjugate addition, Copper(II) bromide, 329 bromofunctionalization, 183 170 Criegee intermediates, OH C-H bond fluorination, 161 Asymmetric synthesis, 339 radicals, 294 C-H catalyzed addition, 102 Autocatalysis, enantioselective, Cross coupling reactions, 284 diamination, 7 162 Cross coupling, reductive, Ti, 70 fluorocyclization, 3 Automated synthesis, 306 Cryptand hosts, 354 terminal, anti-Markovnikov Aza Diels-Alder reaction, 210 Cucurbituril, 187 oxidation, 54 Aza-Michael reaction, Cumulenes, long, 131 Alkoxy radicals, 309 intramolecular, 151 Cyanation, enantioselective, 35 Alkoxyallenes, 126 Aziridinyl ligands, 230 Cyanoacetates, functionalization, Alkyl(methyl)maleic anhydrides, Azomethine ylides, 11 28 346 Benzofuroindoles, 240 Cyclic alkyl amino carbenes, 9 Alkynes, annulation, Au, 285 Benzofuropyrroles, 240 Cyclobutanes, in nature, 144 azide cycloaddition, 34 Benzothiazoline, 14 Cyclometalation, 225 carboalkoxylation, Au, 285 Benzylamine derivatives, 296 Cyclopropane ring, in natural C-H bond fluorination, 161 Bicyclic nitroimidazodihydrooxaz- products, 213 hydroamination, anti oles, 256 Cyclopropane ring-opening Markovnikov, 233 Bicyclooctadienyl anion, 62 cyclizations, 108 metathesis, Au, 285 Bimolecular reactions, Dearomatization, asymmetric, 46 Alkynylcarbinols, 275 supramolecular control, 234 Deoxyheptoses, 211 Allenenes, 123 Bis(iodozincio)methane, 334 Dicyanomethyleneindandione Allenes, annulation, with Bis-metallative alkene coupling, reactant, 257 phosphines, 124 137 Dienes, 1,6-, cyclization, 325 chiral, 352 Borepin rings,aromaticity, 270 Diethylzinc, 311 C-O bond formation, Pd, 127 Boron trifluoride, 81 Dihydrodiazaboroles, 199 computational chemistry, 128 Boronated synthons, 306 Dipyridophenazine ligands, 197 cyclization, 129 Boronic acid catalysts, 45 Dirhodium carboxylates, 186 cycloaddition, 122 Boronic esters, coupling, 55 Disulfonimides, chiral, 43 cylization, 126 Borylation, regioselective, 132 Diterpenoids, 276 gold chemistry, 125 Bridgehead alkenes, natural aromatic abietane, 360 N-H bond addition, 130 products, 49 neodolastane, 277 O-H bond addition, 130 Buckybowls, 288 DNA quadruplex catalysts, 31 Allenophanes, 185 Cannabinoids, synthesis, 63 Enamide derivatives, 335 Allenylsilanes, 317 Carbacycles, six membered, Enantioselective synthesis, 182 Allenynes, 123 domino synthesis, 228 Epidithiodioxopiperazines, 272 Allylic alcohols, transposition, 138 Carbamoyl imines, Epipolythiodioxopiperazine Allylic alkylation, 170 enantioselective, 106 metabolites, 64 Allylpyrroles, hydroformylation, Carbenes, reactive, 244 Epoxidation, asymmetric, 188 181 Carbocycles, three membered, 186 Ethers, C-O bond cleavage, 154 Amide synthesis, 121 Carbohydrates, enantioselective, Ethylene, radical reactions, 120 Amides, with organometallic 235 Exicals, 100 reagents, 30 stability, 71 Flash vacuum pyrolysis, 60 Amination, asymmetric, 348 Carbolines, tetracyclic, 175 Flash vacuum thermolysis, UPS, electrophilic, 342 Carbon nanohoops, 16 61 Amines, C-H functionalization, 11 Carbonates, allyl alkyl, 308 Fluorinated alcohols, 246 squaramides, domino Carbonylation, with formic acid, Fluorination, 87, 89, 249 reactions, 32 315 aromatics, 82 Amino acids, disubstituted, 361 Carboxylic acids, hydrogenation, Fluorine pyrazoles, 251 Aminocatalysis, 165 289 Fluoroalkylation, non Aminoglycosides, synthesis, 236 reduction, Fe, 201 electrophylic, 200 Aminoketoamides, 217 functionalization, 45, 147 with S, 86 Aminophosphonic acids, 359 Catalysis, substrate-selective, 158 Formic acid dehydrogenation, 166 Free radicals, 332 synthesis, aqueous, 177 Nitrilimines, dipolar Frustrated Lewis pairs, 10, 58 trifluromethyl-, 291 cycloaddition, 206 Fullerenes, 265 Indolizidines, from allylpyrroles, Nitroarenes, nucleophilic aryne inclusion compounds, 181 substitution, 179 73 Indolylphosphines, 202 Nitrogen ligands, catalysis, 109 Function-oriented synthesis, 19 Infrared spectroscopy, reaction Nitrogen tetrasubstituted carbon, Furans, fused, synthesis, 320 dynamics, 301 348 Gas-phase reaction rates, 298 Intermolecular ene-reactions, 341 Nitroglycals, 236 Gliotoxin metabolites, 64 Ionic liquids, functionalized, 219 Nonacene, synthesis, 76 Glycerol solvent, 157 imadazolium, 150 Non-innocent ligands of Al, 166 Glycol cleavage, 351 solvent control, 283 Nucleoside analog, entecavir, 226 Gold carbenes and carbenoids, 171 Iron catalysis, 101 Olefin metathesis, with fluorine, Gold complexes, amides and Isocyanide multicomponent 88 carboxylic acids, 194 reactions, 237 Organic cage compounds, 116 Gold, C-H bond activation, 145 Isocyanides, 98 Organoboronic acids, C-C bond Grignard reaction, halogenated Ketodioxinones, resorcylate formation, 155 Silicon pyrimidine, 252 synthesis, 17 chemistry, 156 Griseofulvin, 78 Ketoheptoses, 227 Organocatalysis, design strategy, Guanidine, cyclic, natural Ketosulfones, 229 57 products, 357 Kinetic resolution allylic supported, microreactor, 37 Guanidines, 223 substrates, 180 Organolithium reagents, 281 Halogen bond activation, 195 Lactams, functionalized, 313 Organometallics, from halides, Halogen bond symmetry, 269 Lactams, γ-, 209 350 Harmicine, 175 synthesis, 1 Ir, Rh, half-sandwich, 4 Heteraspiroalkanes, 337 Lactones, γ-, synthesis, 1 Pesci decarboxylation, 12 Heterocycles, Cu C-H Lewis acidity, boron compounds, Organonickel complexes, 305 functionalization, 95 188, 192 Organopalladium, reductive Fe catalyst, 24 Limonene epoxide, 100 elimination, 8 ketene aminals, 336 Low energy electrons, 104 Organoplatinum, reductive N-, from imides and ylides, 29 Luminescent molecules, 199 elimination, 8 ring opening, organoboron, Lyconadins, synthesis, 319 Ortho-quinone methides, 6 310 Marcocyclization, Pd, natural Osmium-catalyzed hydrogenation, synthesis, 214 products, 356 13 trifluoromethylation, 96 Masked unsaturated amides, 168 Oxadiazoles, azolyl, 255 using fluorinated alcohols, Masked unsaturated esters, 168 Oxazoles, synthesis, 243 246 Massadine synthesis, 295 Oxazolones, 222 with cerium salts, 107 Mechanistic elucidation, 304 Oxidative cross-coupling, Fe, Co, 2 Hetero-Diels-Alder reaction, 48 Medicinal chemistry, high Oxobenzopyran carboxaldehydes, Heterogeneous foldamers, 238 throughput synthesis, 299 259 Heterosuperbenzenes, 167 Metal oxide, C-H bond activation, Oxoindolinylidene thiazolidinones, Hexoses, L-, synthesis, 103 152 176 Homogeneous catalysis, Metallacycle-mediated cross Pentafluorosulfanyl compounds, deactivation, 80 coupling, 19 92 Hybridization structure reactivity Metallocenophanes, strained, 266 Peptide desulfurization, 65 control, 268 Methane, high-resolution Peptide ligation, 65 Hydrazone, switches, sensors, 118 spectroscopy, 307 Peptidomimetics, with aminoacyl Hydrides, rare-earth, 56 Methylation, metal catalyzed, 38 benzotriazole, 41 Hydroamidation, 97 Microflow technology, 318 Perfluoroalkyl phosphorus Hydroamination, 97 Microwaves, in cycloaddition, 216 compounds, 245 Hydrogen atom transfer, 159 Molecular cages, porous, 212 Perfluoroalkylfullerenes, 91 Hydroperoxyalkyl radical, 302 Molybdenum oxide catalysts, 153 Peroxide, asymmetric Hydrophophination, 190 Monoterpene ligands, 164 sulfoxidation, 188 Hydroxylation, 188 Morphine alkaloids, 20 Phosphinates, synthesis, 221 Hypervalent iodine, 193 Multimetallic catalysis, 79 Phosphinic amides, 221 Imidazoles, fused, 353 Nanocluster catalyst, 39 Phosphorus ligands, catalysis, 109 sulfonyl azide, 321 Nanoporous catalysts, 208 Photochemistry, 25, 267 Imidazolium salt, 173 Naphthopyranones, 282 Photochirogenesis, Imines, from amines, 232 Naphthoquinone, 324 supramolecular, 135 hydrogenation, 191 Natural product synthesis, Photoreactions, template effects, reactions, 205 organocatalysis, 271 136 toxins, 280 strategies, 314 Pi systems, extended, 50 Indenofluorenes, biradicals, 286 N-Heterocyclic carbenes, metallic, Pinene epoxide, 100 Indium(III) chloride, 312 263 Piperidines, synthesis with Fe, 24 Indole alkaloids, synthesis, 22 Nitrenoids, amination, 169 Polyacenes, aromaticity, 203 Indole coupling, 22 Nitrile hydration, 261 Polyaromatic hydrocarbons, 204 Indolequinones, 355 nanoparticles, 196 Polycycles, from alkynes, 110 Indoles, Friedel-Crafts, 215 Nitrile hydrogenation, 36 Polycyclic aromatics, 75 synthesis, 179 Nitriles, from amines, 326 angular, 15 BN substituted, 167 Silyl ether lithiation, 333 Thiadiazines, hydrogenated, 178 cascade reaction, 74 Silyl ketene imines and aldehydes, Thiourea ligands, 338 sublimation, 253 156 Thioxothiazolidinone, 316 Polyfluorinated ethanes, 90 Spiro iminoindolines, synthesis, Transition structures aromaticity, Polymer supported catalysts, 292 242 141 Polysaccharides, microwave Spiro oxindoles, synthesis, 242 Triazoles, click chemistry, 119 reactions, 293 Spirooxindoles, 254 denitrogenative Prins cyclization, 42 Spiropyran, 105 transformation, 349 Propargylallene derivatives, 231 Steroid tetracyclic core, synthesis, ligands, 197 Propargylic sulfides, 93 239 ylides, 241 Prophenol ligands, 21 Sulfides, alkynyl silyl, 328 Trifluoromethyl isoxazolines, 67 Pyranose based ligands, 262 Sulfur dioxide, 347 Trifluoromethyl pyrrolines, 67 Pyrazaacenes, 148 Superacidic carbon acid, 248 Trifluoromethylation, 27, 83 Pyrazole diazonium salt, 174 Supramolecules, 134 87,160, 189 Pyridines, from malononitrile, 218 catalysis, 99 alkynes, 172 Pyrimidyl alkanol, asymmetric disulfide exchange, 113 Trifluoromethylpyranones, 247, autocatalysis, 5 dynamic covalent reactivity, 250 Pyrophosphorylation, 323 111 Trifluoromethylthiolation, 85, 87 Pyrrolizidine alkaloids, 274 dynamic covalent reactivity, Triphenylphosphine, Quaternary Stereocenters, 23 117 carbonylation, 322 Quinodimethanes, 75 gas phase, 112 Triterpenoids, 278 Quinones, 330 polymerization, 303 Tungsten oxide catalysts, 153 Radiochemistry, 59 Synthesis strategies, 340 Ullmann chemistry, Cu, 133 Reactivity patterns, 143 Terpenoids, 100 Umpolung reaction, Ti, 70 Resorcylate synthesis, 17 cyclic, prenyl, 273 Vanadium enantioselective Ruthenium pincer complex, 33 Tetrafluoroborates, 81 reactions, 198 Ruthenium pincer complexes, 77 Tetrahydropyrans, synthesis with Vinblastine, 18 Sceptrin synthesis, 295 Fe, 24 Zethrenes, 287 Schiff base interactions, 94 Tetrazole ylides, 241 Zinc, chiral catalysts, 358 Siloxy alkynes, annulation, 68 Thiacalixarenes, 140