DOCSLIB.ORG

MAQARIN Natural Analogue Study: Phase III

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
MAQARIN Natural Analogue Study: Phase III SE9900228 Technical Report TR-98-04 Volume IS SVIAQARIN natural analogue study: Phase HI Edited by J A T Smellie December 1998 Svensk Karnbranslehantering AB Swedish Nuclear Fuel and Waste Management Co Box 5864 SE-102 40 Stockholm Sweden Tel 08-459 84 00 +46 8 459 84 00 Fax 08-661 57 19 +46 8 661 57 19 30-26 MAQARIN natural analogue study: Phase III Edited by J.A.T. Smellie December 1998 VOLUME i: Chapters 1-13 VOLUME II: Appendices A-R This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author(s) and do not necessarily coincide with those of the client. Information on SKB technical reports from 1977-1978 (TR 121), 1979 (TR 79-28), 1980 (TR 80-26), 1981 (TR 81-17), 1982 (TR 82-28), 1983 (TR 83-77), 1984 (TR 85-01), 1985 (TR 85-20), 1986 (TR 86-31), 1987 (TR 87-33), 1988 (TR 88-32), 1989 (TR 89-40), 1990 (TR 90-46), 1991 (TR 91-64), 1992 (TR 92-46), 1993 (TR 93-34), 1994 (TR 94-33), 1995 (TR 95-37) and 1996 (TR 96-25) is available through SKB. CONTENTS VOLUME II: Appendices A-R (this volume) page APPENDIX A: A:l Geology and Hydrogeology - Figures A-l to A-14 A:3 APPENDIX B: B:l Well Logs from the Maqarin Area B:3 (Jordan Valley Authorities) APPENDIX C: C:l Hydraulic Data from the Maqarin Area C:3 (Jordan Valley Authorities) APPENDIX D: D:l Geomorphology - Plates D-l to D-7 D:3 APPENDIX E: E:l Inventory of Rock and Mineral Samples E:3 (Compiled by A.E. Milodowski and E.K. Hyslop) APPENDIX F: F:l Groundwater Sampling and Analytical Protocols F:3 F.I Groundwater Sampling Protocol F:3 F.I.I Field Measurements F:4 F.2 Laboratory Analysis of Groundwater Samples F:5 F.2.1 General F:5 F.2.2 pH and Total Alkalinity F:5 F.2.3 Major Cations and Trace Elements F:6 F.2.4 Major and Trace Anions F:6 F.2.5 Fluoride F:6 F.2.6 Total Organic and Inorganic Carbon F:7 F.2.7 Reduced Sulphur F:7 F.2.8 Arsenic and Selenium F:7 F.2.9 Reduced Iron F:7 F.2.10 Ammonium F:8 F.2.11 Orthophosphate F:8 F.3 References F:8 Appendices:3 page APPENDIX G: G:l Mineralogy and Geochemistry - Analytical Methods G:3 G.I General G:3 G.2 Bulk Mineralogical Analysis G:3 G.2.1 Standard Whole-rock Sample Preparation G:3 G.2.2 Acid Leaching G:4 G.2.3 Clay Fraction (<2 |im) Mineralogy G:4 G.2.4 XRD Analysis G:4 G:3 Petrographic Analysis G:4 G.3.1 Backscattered Scanning Electron Microscopy G:5 G.3.2 Electron Microprobe Analysis G:5 G.3.3 Analytical Transmission Electron Microscopy G:5 G.3.4 Laser-Ablation Microprobe - Inductively Coupled Plasma - Mass Spectrometry G:6 G.3.5 Image Analysis G:7 G.3.6 Fission Track Registration Analysis G:7 G.4 Porosimetry Determination G:8 G.4.1 Liquid Resaturation Porosimetry G:8 G.4.2 Pore Size Distribution Measurement G:9 G.5 Chemical Analysis G:10 G.6 Strontium Isotope Analysis G:ll G.7 Uranium Disequilibrium Studies G:ll G.8 References G:12 APPENDIX H: H:l A: ANALYSIS OF INDIVIDUAL ROCK AND MINERAL H:3 COMPONENTS USING: • Analytical Transmission Electron Microscopy (ATEM) • Electron Microprobe Analysis (EMPA) • Laser Ablation Microprobe (LAMP) B: MOLAR PLOTS OF THE DATA H:35 APPENDIX I: 1:1 Mineralogy and Geochemistry - Plates 1-1 to 1-24 1:3 APPENDIX J: J:l Matrix Diffusion Studies in Fractured Clay Biomicrite J:3 Profile C353 J:3 Profile C357 J:25 Profile C358 J:47 Profile C359 J:65 APPENDIX K: K:l Regional Ground water Analyses K:3 (Compiled by E. Salameh) Appendices :4 page APPENDIX L: L:l Geochemistry and Mineralogy of Rocks from the Maqarin Area L:3 (Compiled by H.N. Khoury) APPENDIX M: M:l Hydrogeochemical Modelling: Groundwater Chemical Data Set M:3 (Compiled by H.N. Waber) APPENDIX N: N:l Zeolite Thermodynamic Data N:3 (Compiled by D. Savage) APPENDIX O: 0:1 Colloid Repulsion by the Filter O:3 APPENDIX P: P:l Colloids: Filtrate Chemistry Data Set P:3 APPENDIX Q: Q:l Western Springs Catchment Area: Chemistry of Near- surface Groundwaters Collected from a Variety of Springs, Domestic Water Sources and Waste Water Disposal Locations Q:3 (E. Salameh and HJSI. Khoury) APPENDIX R: R:l The Nature and Use of Cement in Repository Construction and the Relevance of the Maqarin Analogue Study R:3 (F. Karlsson and B. Lagerblad) R.I Background R:3 R.2 Cementitious Repository Materials R:3 R.2.1 Different Types of Concrete R:4 R.2.2 Concrete Properties R:4 R.3 Old Concrete R:7 R.3.1 Structure of Old Cement Paste R: 7 R.3.2 Pore Water Leaching R:8 R.4 Natural Analogues R:9 R.4.1 Background R:9 R.4.2 The Maqarin Analogue R:10 R.4.3 Cement Minerals R:10 R.4.4 Water/rock Interaction of Cement Phases R: 10 R.4.5 High pH Water R:ll R.4.6 Hyperalkaline Plume R:ll R.4.7 Colloids R:ll R.4.8 Conclusions R:12 R.5 References R:12 Appendices :5 CONTENTS VOLUME I: Chapters 1-13 page EXECUTIVE SUMMARY 19 1 INTRODUCTION 35 2 GEOLOGY AND HYDROGEOLOGY OF THE MAQARIN AREA 39 (7/JV. Khoury, E. Salameh, M. Mazurek and W.R. Alexander) 3 GEOMORPHOLOGY OF THE MAQARIN AREA 71 (A.F. Pitty) 4 SITE DESCRIPTION, SAMPLING PROGRAMME AND GROUNDWATER ANALYSIS 105 (A.E. Milodowski, E.K. Hyslop, JA.T. Smellie, E. Salameh and H.N. Khoury) 5 MINERALOGY, PETROLOGY AND GEOCHEMISTRY 135 (A.E. Milodowski, E.K. Hyslop, JM. Pearce, P.D. Wetlon, SJ. Kemp, G. Longworth, E. Hodginson and C.R. Hughes) 6 HYDROGEOCHEMISTRY OF THE MAQARIN AREA 181 <HM. Waber, /.£>. Clark, E. Salameh and D. Savage) 7 GEOCHEMICAL MODELLING OF HYPERALKALINE WATER/ROCK INTERACTIONS 237 (A.V. Chambers, A. Haworth, D. Ilett, CM. Linklaler and CJ. Tweed) 8 ZEOLITE OCCURRENCE, STABILITY AND BEHAVIOUR 281 (D. Savage) 9 ORGANIC CHEMISTRY OF THE BITUMINOUS MARLS 317 (S. Geyer,]. Porschmann, G. Hanschman, W. Geyer, F-D. Kopinke, W. Boehlmann and P. Fritz) 10 THE PRODUCTION OF COLLOIDS AT THE CEMENT/HOST ROCK INTERFACE 333 (P.D. Wetton, J.M. Pearce, W.R. Alexander, A.E. Milodowski, S. Reeder, J. Wragg and E. Salameh) 11 CULTURABILITY AND 16S rRNA GENE DIVERSITY OF MICRO-ORGANISMS IN THE HYPERALKALINE GROUNDWATERS OF MAQARIN 367 (K. Pedersen, J. Arlinger, A-C. Erlandson and L. Hallbeck) Appendices:6 page 12 MAQARIN: IMPLICATIONS TO REPOSITORY PERFORMANCE ASSESSMENT 389 13 CONCLUSIONS 397 left BLANK Lmaia, Appendices:7 APPENDIX A Geology and Hydrogeology Figures A-l to A-14 NEXT PA@E(S) I I I |— E 231 600 231600 232 00 232 200 232 400 —N 236 00 100 m -237400 Figure A-l. Contours showing the top of the Amman Formation (modified after Harza, 1982). Appendix A: 3 (r, I// V*--. / / /~U0V I'/ /// • • /. •v . ~~^_ • ^y / '"X/ ; / h .. / ^ / / / 7-///1. 300m f ffjr-H- 1^4NN >& /' i / / / Figure A-2. Projected top of the Bituminous Marl Formation (modified after Harza, 1982). Appendix A:4 •N 237 200 \ 0 10On E 231100 E 232 400 Figure A-3. Contours showing the base of the Maqarin basalts (modified after Harza, 1982, and Jordan Valley Authorities, 1980). Appendix A:5 E231 E232 E23 3 E234 E235 E23 6 N239 — N235- J O R O A N \ N 233" \ _\ I Figure A-4. Location of cross-sectional profiles (5-7) from the Maqarin area. Appendix A:6 SECTION 5 500 RESIDUAL SOIL CHALKY LIMESTONE FORMATION 100 0 ilTUMINOUS MARL FORMATION AMMAN FORMATION SECTION 6 500 ITUMINOUS MARL FORMATION AMMAN FORMATION SECTION 7 CHERT MARKER BED r r • ITIJMINOUS MARL FORMATION Figure A-5. Cross-sectional profiles (5-7) from the Maqarin area (see Figure A-4). WES! E«t e ii; ooo El» 500 )00r- E iii 500 . 300 ISO Metamorphic Unit / Cement Zone a- Bituminous Marl Formation _*— Amman Formation .100 .100 -ISO Figure A-6. Integrated W-E cross-sectional profile through the Maqarin area (modified after Harza, 1982). SOUTH NORTH 4C0, ! . 4C0 CHALKY LIMESTONE FORMATION MORPHIC UNIT / CEMENT LONE ( b r e c elated and altered )/ ZONE OF BITUMINOUS MARL BITUMINOUS MARL FORMATIO 0 50 METRES Figure A-7. Integrated S-N cross-sectional profile through the Maqarin area (modified after Harza, 1982). E 231.600 E232.000 E 233-800 50 100 Figure A-8. Contoured top of the unaltered Bituminous Marl Formation at Maqarin (modified after Harza, 1982, and Jordan Valley Authorities, 1980). Appendix A: 10 I I 0 5 1pm E 1 ' 231 950 E 232 000 Figure A-9. Location of cross-sectional profiles (A-E) illustrating the distribution of the Metamorphic Unit/Cement Zone (Zones A-C; see text) in the Maqarin area at elevation of Adit A-7 (after Harza, 1982). Appendix A: 11 I S 15 S-62 ' 5-50 1 ^ m 180 Basalt ——-~ 170 160 150 140 i -"" ZONE B Top of Bituminous Marl / base \ c of alteration —.— -—— o CD & 1=1 & m> B I T U M I N C US MAR L FORMA r i o N (weathered) 100 Zo ie of severely we ithered Bituminous IU arl 90 0 5 1pm H 80 F I s h B i t u m i n o u s M a r 1 E 230.000 E231-950 E231.900 1 1 1 Figure A-10.
Load more

Recommended publications
  • The Mineralogical Magazine
    THE MINERALOGICAL MAGAZINE AND JOURNAL OF THE MINERALOGICAL SOCIETY ~._---_.~----- -~---- No. 138. September, 1932. Vol. XXIII. On bultfonteinite, n, new fluorine-bearing hydrous calcium silicate from South Africa. By JOHN PARRY1 (chemical study), ALPHEUS F. WILLIAMS, De Beers Consolidated Mines, Kimberley, Union of South Africa, and F. E. WRIGHT (crystallographical and optical study), Geophysical Laboratory, Carnegie Institution of Washington, D.C.. [Read June 7,1932.] ----- HIS new mineral was first found by a miner named Cann in 1903 T or 1904 on the 480-foot level of the Bultfontein mine at Kim- berley. It occurred, associated with calcite, apophyllite, and natrolite, in a large' horse' of dolerite and shale fragments enclosed in kim- berlite. This huge inclusion, several hundred feet in height, un- doubtedly formed part of the country-rock that now encloses the kimberlite pipe. The specimens of the new mineral were considered to be natrolite and were presented to Mr. A. F. Williams. Several years later the same mineral was found by Mr. C. E. Adams in the Dutoitspan mine, which is located about half a mile from the Bult- fontein mine; he presented his specimens tothe MacGregor Museum at Kimberley. Recently, Mr. Miller, Underground Manager of the Jagers- fontein mine in Orange River Colony, discovered the new mineral in that mine, which is located 100 miles south-east of Kimberley. 1 Mr. John Parry, Chief Chemist of the De Beers Consolidated Mines at Kim. berley, died on October 6, 1931. M 146 J. PARRY, A. F. WILLIAMS,AND F. E. WRIGHT ON After the description of the new mineral afwillite1 had been pub- lished, Mr.
    [Show full text]
  • Olmiite, Camn[Sio3(OH)](OH), the Mn-Dominant Analogue of Poldervaartite, a New Mineral Species from Kalahari Manganese Fields (Republic of South Africa)
    Mineralogical Magazine, April 2007, Vol. 71(2), pp. 193–201 Olmiite, CaMn[SiO3(OH)](OH), the Mn-dominant analogue of poldervaartite, a new mineral species from Kalahari manganese fields (Republic of South Africa) 1, 2 3 4 1 1 P. BONAZZI *, L. BINDI ,O.MEDENBACH ,R.PAGANO ,G.I.LAMPRONTI AND S. MENCHETTI 1 Dipartimento di Scienze della Terra, Universita` degli Studi di Firenze, Via La Pira, 4, I-50121, Firenze, Italy 2 Museo di Storia Naturale, sezione di Mineralogia, Universita` di Firenze, Via La Pira 4, I-50121 Firenze, Italy 3 Institut fu¨r Geologie, Mineralogie und Geophysik, Ruhr-Universita¨t Bochum, Universita¨tsstraße 150, D-44780 Bochum, Germany 4 P.O. Box 37, I-20092 Cinisello, Milano, Italy [Received 10 April 2007; Accepted 12 July 2007] ABSTRACT Olmiite, ideally CaMn[SiO3(OH)](OH), is a newly identified mineral from the N’Chwaning II mine of the Kalahari manganese fields (Republic of South Africa), which occurs as a product of hydrothermal alteration associated with poldervaartite, celestine, sturmanite, bultfonteinite and hematite. The mineral occurs as wheat-sheaf aggregates consisting of pale to intense reddish pink minute crystals. Olmiite is transparent with vitreous lustre, and exhibits deep-red fluorescence under short-wave UV-light. The mineral is brittle, with irregular fracture. Streak is white and Mohs hardness is 5À5Ý. No cleavage was observed. The measured density (pycnometer method) is 3.05(3) g/cm3. The calculated density is 3.102 g/cm3 or 3.109 g/cm3 using the unit-cell volume from single-crystal or powder data, respectively. Olmiite is biaxial positive, with refractive indices a = 1.663(1), b = 1.672(1), g = 1.694(1) (589 nm), 2Vmeas = 71.8(1)º, 2Vcalc = 66(8)º.
    [Show full text]
  • New Mineral Names*
    American Mineralogist, Volume 71, pages 227-232, 1986 NEW MINERAL NAMES* Pers J. Dulw, Gsoncr Y. CHao, JonN J. FrrzperRrcr, RrcHeno H. LaNcr-nv, MIcHeer- FrerscHnn.aNo JRNBIA. Zncznn Caratiite* sonian Institution. Type material is at the Smithsonian Institu- tion under cataloguenumbers 14981I and 150341.R.H.L. A. M. Clark, E. E. Fejer, and A. G. Couper (1984) Caratiite, a new sulphate-chlorideofcopper and potassium,from the lavas of the 1869 Vesuvius eruption. Mineralogical Magazine, 48, Georgechaoite* 537-539. R. C. Boggsand S. Ghose (1985) GeorgechaoiteNaKZrSi3Or' Caratiite is a sulphate-chloride of potassium and copper with 2HrO, a new mineral speciesfrom Wind Mountain, New Mex- ideal formula K4Cu4Or(SO4).MeCl(where Me : Na and,zorCu); ico. Canadian Mineralogist, 23, I-4. it formed as fine greenacicular crystalsin lava of the 1869 erup- S. Ghose and P. Thakur (1985) The crystal structure of george- tion of Mt. Vesuvius,Naples, Italy. Caratiite is tetragonal,space chaoite NaKZrSi3Or.2HrO. Canadian Mineralogist, 23, 5-10. group14; a : 13.60(2),c : a.98(l) A, Z:2.The strongestlines of the powder partern arc ld A, I, hkll: 9.61(l00Xl l0); Electron microprobe analysis yields SiO, 43.17, 7-xO229.51, 6.80(80X200); 4.296(60X3 I 0); 3.0I 5( 100b)(a 20,32r); 2.747 (7 0) NarO 7.42,IGO I1.28, HrO 8.63,sum 100.010/0,corresponding (4 I t); 2.673(60X5 I 0); 2.478(60)(002); 2. 3 8 8(70Xa 3 l, 50I ); to empirical formula Na, orl(oru(Zro rrTio o,Feo o,)Si, or Oe' 2.
    [Show full text]
  • New Mineral Names*,†
    American Mineralogist, Volume 101, pages 2570–2573, 2016 New Mineral Names*,† DMITRIY I. BELAKOVSKIY1, OLIVIER C. GAGNE2, AND YULIA UVAROVA3 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba, R3T 2N2, Canada 3CSIRO Mineral Resources, CSIRO, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia IN THIS ISSUE This New Mineral Names has entries for 9 new mineral species, including dmisokolovite, geschieberite, imayoshiite, palladosilicide, plášilite, raisaite, shchurovskyite, svornostite, and vanackerite. GESCHIEBERITE* AND SVORNOSTITE* 3.681 (18; 311), 3.403 (12; 013), 3.304 (15; 401,113), 3.006 (17; 122). The unit-cell parameters refined from powder-diffraction data are: a = J. Plášil, J. Hloušek, A.V. Kasatkin, R. Škoda, M. Novàk and J. Čejka 13.786(5), b = 7.278(3), c = 11.536(4) Å, V = 1157.4 Å3. Single-crystal (2015) Geschieberite, K (UO )(SO ) (H O) , a new uranyl sulfate 2 2 4 2 2 2 X-ray diffraction data collected on a crystal of size 0.19 × 0.11 × 0.09 mm mineral from Jáchymov. Mineralogical Magazine, 79(1), 205–216. refined to R = 0.028 for 1882 unique reflections with I ≥ 3σ(I) shows J. Plášil, J. Hloušek, A.V. Kasatkin, M. Novák, J. Čejka and L. Lapčák 1 geschieberite is orthorhombic, Pna2 , with a = 13.7778(3), b = 7.2709(4), (2015) Svornostite, K Mg[(UO )(SO ) ] ∙8H O , a new uranyl sulfate 1 2 2 4 2 2 2 c = 11.5488(2) Å, V = 1156.92 Å3, Z = 4.
    [Show full text]
  • Bultfonteinite Ca2sio2(OH; F)4 C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Triclinic
    Bultfonteinite Ca2SiO2(OH; F)4 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Triclinic. Point Group: 1: As radiating prismatic acicular crystals and radial spherules, to 2 cm. Twinning: Interpenetrating on 100 and 010 ; polysynthetic. f g f g Physical Properties: Cleavage: Good on 100 and 010 . Fracture: Conchoidal. Hardness = 4.5 D(meas.) = 2.73 D(calc.) =f2.74g f g Optical Properties: Transparent. Color: Pale pink to colorless. Luster: Vitreous. Optical Class: Biaxial (+). Orientation: Z 0 c = 27±{29± on 010 ; Z 0 c = 46±{48± on 100 . Dispersion: r > v; barely perceptibl^e. ® = 1.587(2) f ¯ =g [1.59^0] ° = 1.597(2) f g 2V(meas.) = 70± Cell Data: Space Group: P 1: a = 10.992(4) b = 8.185(2) c = 5.671(1) ® = 93±570 ¯ = 90±190 ° = 89±510 Z = 4 X-ray Powder Pattern: Bultfontein mine, Kimberley, South Africa. 1.93 (100), 8.12 (60), 2.92 (60), 2.88 (60), 2.037 (50), 4.06 (40), 3.50 (40) Chemistry: (1) (2) SiO2 26.50 24.06 B2O3 0.02 Al2O3 0.72 1.37 CaO 54.20 53.59 Na2O 0.04 F 8.81 7.90 + H2O 10.78 H2O¡ 0.75 H2O 13.36 CO2 4.65 P2O5 0.02 O = F 3.71 3.33 ¡ 2 Total 99.88 99.85 (1) Bultfontein mine, Kimberley, South Africa. (2) Fuka, Japan; corresponds to (Ca2:04 (Si0:96Al0:06)§=1:02O2:13[(OH)2:87F1:00]§=3:87: Occurrence: In a large \horse" of diabase and shale fragments in a kimberlite pipe (Bultfontein mine, Kimberley, South Africa); in a contact zone in thermally metamorphosed limestone (Crestmore, California, USA).
    [Show full text]
  • Shin-Skinner January 2018 Edition
    Page 1 The Shin-Skinner News Vol 57, No 1; January 2018 Che-Hanna Rock & Mineral Club, Inc. P.O. Box 142, Sayre PA 18840-0142 PURPOSE: The club was organized in 1962 in Sayre, PA OFFICERS to assemble for the purpose of studying and collecting rock, President: Bob McGuire [email protected] mineral, fossil, and shell specimens, and to develop skills in Vice-Pres: Ted Rieth [email protected] the lapidary arts. We are members of the Eastern Acting Secretary: JoAnn McGuire [email protected] Federation of Mineralogical & Lapidary Societies (EFMLS) Treasurer & member chair: Trish Benish and the American Federation of Mineralogical Societies [email protected] (AFMS). Immed. Past Pres. Inga Wells [email protected] DUES are payable to the treasurer BY January 1st of each year. After that date membership will be terminated. Make BOARD meetings are held at 6PM on odd-numbered checks payable to Che-Hanna Rock & Mineral Club, Inc. as months unless special meetings are called by the follows: $12.00 for Family; $8.00 for Subscribing Patron; president. $8.00 for Individual and Junior members (under age 17) not BOARD MEMBERS: covered by a family membership. Bruce Benish, Jeff Benish, Mary Walter MEETINGS are held at the Sayre High School (on Lockhart APPOINTED Street) at 7:00 PM in the cafeteria, the 2nd Wednesday Programs: Ted Rieth [email protected] each month, except JUNE, JULY, AUGUST, and Publicity: Hazel Remaley 570-888-7544 DECEMBER. Those meetings and events (and any [email protected] changes) will be announced in this newsletter, with location Editor: David Dick and schedule, as well as on our website [email protected] chehannarocks.com.
    [Show full text]
  • Bultfonteinite from Crestmore, California
    BULTFONTEINITE FROM CRESTMORE, CALIFORNIA Josneu Munoocu, Univers,ityoJ CaliJornia at Los Angeles, Los Angeles, Cal iJorn i a. AssrRlcr The rare mineral bultfonteinite has been found in the contact zone at Cresrmore, California, in association with afwillite and scawtite. It occurs with these as microscopic, twinned individuals, much finer grained than the enclosing minerals. Opticai and micro- chemical observations indicated that it is bultfonteinite, and this is confirmed by r-ray powder pattern, which matches that of the t1'pe material. This is the first locality for this mineral outside of South Africa The powder pattern shows the following spacings and intensities for the strongest lines: 8.16 A-7; 3.51 A-5; 3.+O A-5; 2.92 A-1O;2.385 A-10; -1.93 A-10. X-ray measurements on a crystal sliver from the type locality give cell-dimensions and ansles as follows: ao:8.34A bo:11.18A co:5.68A I:88'24/ p :86" 06' v:90o 00' These agree very closely with morphological measurements by Wright, provided his o and b axes are exchanged, and the value for the new D axis is doubled. The transformation formula, Wright to Murdoch is0I0/20O/0f1. The rare mineral Bultfonteinite was discoveredabout 1903 or 1904 in the Bultfontein mine, in the Kimberley District, South Africa. Several years later it appeared in the Dutoitspan mine in the same district, and shortly before 1932 it was found also at the Jagersfontein mine in the Orange River Colony, somehundred miles southeastof Kimberley. When first collected, it was thought to be natrolite, but was later recognized by A.
    [Show full text]
  • New Mineral Names*,†
    American Mineralogist, Volume 100, pages 1319–1332, 2015 New Mineral Names*,† FERNANDO CÁMARA1, OLIVIER C. GAGNÉ2, DMITRIY I. BELAKOVSKIY3 AND YULIA UVAROVA4 1Dipartimento di Scienze della Terrá, Universitá di degli Studi di Torino, Via Valperga Caluso, 35-10125 Torino, Italy 2Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada 3Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 4Mineral Resources Flagship, CSIRO, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia IN THIS ISSUE This New Mineral Names has entries for 25 new minerals, including alcaparrosaite, bastnäsite-(Nd), calciolangbeinite, chovanite, chromio-pargasite (ehimeite), chukhrovite-(Ca), dzhuluite, eltyubyuite, ferrisepiolite, hereroite, hielscherite, iseite, itsiite, jakobssonite, kazanskiite, meisserite, nashite, omsite, schindlerite, tanohataite, tazzoliite, vapnikite, vladkrivovichevite, wernerbaurite, and wopmayite. ALCAPARROSAITE* r < v. The optical orientation is X = b; Y ^ c = 27° in the obtuse A.R. Kampf, S.J. Mills, R.M. Housley, P.A. Williams, and M. angle β. No pleochroism was observed. The average of 4 electron 4+ 3+ probe analyses gives [wt% (range)]: Na2O 0.32 (0.16–0.51), K2O Dini (2012) Alcaparrosaite, K3Ti Fe (SO4)4O(H2O)2, a new hydrophobic Ti4+ sulfate from Alcaparrosa, Chile. Mineralogi- 20.44 (20.30–20.67), Fe2O3 11.58 (11.41–11.71), TiO2 11.77 cal Magazine, 76(4), 851–861. (11.54–12.18), P2O5 0.55 (0.48–0.68), SO3 47.52 (46.57–48.06), H2O 5.79 (calculated from structure refinement); total 97.97 wt%. 4+ 3+ 4+ This gives the empirical formula (K2.89Na0.07)Σ2.96Ti0.98Fe0.97(S0.99 Alcaparrosaite (IMA 2011-024), ideally K3Ti 3+ P0.01O4)4O0.72(OH)0.28(H2O)2 based on 19 O pfu.
    [Show full text]
  • Cost-Effective Cementitious Material Compatible with Yucca Mountain Repository Geochemistry
    ORNL/TM-2004/296 Cost-Effective Cementitious Material Compatible with Yucca Mountain Repository Geochemistry December 2004 Prepared by Les Dole1 Catherine Mattus1 Mostafa Fayek2 Lawrence M. Anovitz1 Juan J. Ferrada1 David J. Wesolowski1 Don Olander3 Don A. Palmer1 Lee R. Riciputi1 Lætitia Delmau1 Sergé Ermichev4* Vyacheslav I. Shapovalov4* ___________________ 1 Oak Ridge National Laboratory, 2 University of Tennessee, 3 University of California Berkeley, 4 MINATOM VNIIEF, Sarov, * funded by ISTC programs ORNL/TM-2004/296 COST-EFFECTIVE CEMENTITIOUS MATERIAL COMPATIBLE WITH YUCCA MOUNTAIN REPOSITORY GEOCHEMISTRY December 2004 Les Dole1 , Catherine Mattus1, Mostafa Fayek2, Lawrence M. Anovitz1, Juan J. Ferrada1, David J. Wesolowski1, Don Olander3, Don A. Palmer1, Lee R. Riciputi1, Lætitia Delmau1, Sergé Ermichev4*, Vyacheslav I. Shapovalov4* 1 Oak Ridge National Laboratory, 2 University of Tennessee, 3 University of California Berkeley, 4 MINATOM VNIIEF, Sarov, *funded by ISTC programs. Contact: Les Dole, 865-576-4319, [email protected], Nuclear Science and Technology Division, Oak Ridge National Laboratory Prepared by OAK RIDGE NATIONAL LABORATORY P.O. Box 2008 Oak Ridge, Tennessee 37831-6254 managed by UT-Battelle, LLC for the U.S. DEPARTMENT OF ENERGY under contract DE-AC05-00OR22725 TABLE OF CONTENTS List of Figures .............................................................................................................................................vii List of Tables ...............................................................................................................................................ix
    [Show full text]
  • Lsosh20, a New Mineral from Fuka, Okayama Prefecture, Japan
    Clinotobermorite, CaSSi6(O,OH)lSoSH20, a new mineral from Fuka, Okayama Prefecture, Japan C. HENMI Department of Earth Sciences, Faculty of Science, Okayama University, Okayama 700 Japan AND 1. KUSACHI Department of Earth Sciences, Faculty of Education, Okayama University, Okayama 700 Japan Abstract Clinotobermorite, CasSi6(0,OHhs.5H20, has been found as a vein-forming mineral in gehlenite- spurrite skarns at Fuka, Okayama Prefecture. It is associated with tobermorite, piombierite, apophyllite, and calcite. The cIinotobermorite is colourless or white and occurs as tabular or acicular crystals. It is monoclinic with the space group Ce or C2le. The unit cell dimensions are a 11.331, b 7.353, c 22.67 A, ~ 96.59°. Microtwinning and stacking disorder on (001) are observed. On heating the cIinotobermorite at 300°C, the 002 spacing is reduced from 11.3 to 9.3 A. Its refractive indices are IX1.575, ~1.580, y 1.585, and the density 2.58 g/cm3 (meas.), 2.69 g/cm3 (calc). The Moh's hardness is 4.5. Calculation of the analytical data on the basis of six tetrahedral cations shows that this mineral has a simplified chemical formula Cas.3Si6(0,OH,F)1s.5H20. The chemical composition and the unit cell are closely related to those of tobermorite. It is most likely that clinotobermorite is a low-temperature polymorph of tobermorite. KEYWORDS:clinotobermorite, new mineral, tobermorite, Okayama Prefecture, Japan. Introduction morite. The mineral species and its name have TOBERMORITE (11.3 A tobermorite), plombier- been approved by the Commission on New ite (14 A tobermorite), tacharanite (12.6 A Minerals and Mineral Names, International tobermorite), riversideite (9.3 A tobermorite) Mineralogical Association, in May 1990.
    [Show full text]
  • [email protected] 1–408–923–6800
    www.minresco.com [email protected] 1–408–923–6800 Systematic Mineral List ABERNATHYITE - Rivieral, Lodeve, Herault Dept., France ABHURITE - Wreck of SS Cheerful, 14 Miles NNW of St. Ives, Cornwall, England ACANTHITE – Alberoda, Erzgebirge, Saxony, Germany ACANTHITE – Brahmaputra Vein, Alberoda, Schlema-Hartenstein District, Erzgebirge, Saxony, Germany ACANTHITE – Centennial Eureka Mine, Tintic District, Juab County, Utah ACANTHITE – Horn Silver Mine, near Frisco, Beaver County, Utah ACANTHITE – Ingleterra Mine, Santa Eulalia, Chihuahua, Mexico ACANTHITE – Pribram-Trebsco, Central Bohemia, Czech Republic ACANTHITE – Tombstone, Cochise County, Arizona ACHTARAGDITE - Achtaragda River/Wilui River District, Sakha Republic (Yakutia), Russian Fed. ADAMITE Var. Cuproadamite – Kintore Opencut, Broken Hill, New South Wales, Australia ADAMITE Var. Cuproadamite - Mine de Cap-Garonne, near Hyers, Dept. Var, France ADAMITE Var. Cuproadamite - Tsumcorp Mine, Tsumeb, Namibia ADAMITE Var. Cuproadamite – Zinc Hill, Darwin, Inyo County, California ADAMITE Var. Manganoan Adamite – El Potosi Mine, Santa Eulalia, Chihuahua, Mexico ADREALITE – Moorba Cave, Jurien Bay, W.A., Australia AEGIRINE Var. Blanfordite - Tirodi Mines, Madhya Pradesh, Central Provinces, India T AENIGMATITE – Chibiny (Khibina) Massif, Kola Peninsula, Russia AERINITE - Estopinan, Pyrenees Mountains, Huesca Province, Spain AESCHYNITE-(Y) (Priorite) – Arendal, Aust-Adger, Norway AFGHANITE – Casa Collina, Pitigliano, Grosseto, Tuscany (Toscana), Italy AFGHANITE - Laacher See Region, Ettringen,
    [Show full text]
  • Nchwaningite, Mn~+Si03(OH)2'H20, a New Pyroxene-Related Chain Silicate from the N'chwaning Mine, Kalahari Manganese Field, South Africa
    American Mineralogist. Volume 80, pages 377-386, 1995 Nchwaningite, Mn~+Si03(OH)2'H20, a new pyroxene-related chain silicate from the N'chwaning mine, Kalahari manganese field, South Africa DANIEL NYFELER, THOMAS ARMBRUSTER Laboratorium rur chemische und mineralogische Kristallographie, Universitiit Bern, Freiestrasse 3, CH-3012 Bern, Switzerland ROGER DIXON Museum of the Geological Survey, PB X1l2, 0001 Pretoria, South Africa VLADIMIR BERMANEC Department of Mineralogy and Petrology of Faculty of Science, University of Zagreb, Demetrova I, 41000 Zagreb, Croatia ABSTRACT Nchwaningite, Mn~+ Si03(OH)2' H20, is an orthorhombic chain silicate [space group Pea2" Z = 4, a = 12.672(9), b = 7.217(3), e = 5.341(2) A], occurring as aggregates shaped like pin cushions, together with calcite, bultfonteinite, and chlorite at N'chwaning mine, located in the Kalahari manganese field, northern Cape Province, South Africa. The ag- gregates consist of light brown, transparent needles, which average 1.0 x 0.1 x 0.05 mm in size. Nchwaningite is named after the mine N'chwaning II, where it was found first. Nchwaningite is biaxially negative with the refractive indices ex= 1.681(2), fJ = 1.688(2), b, Y = a, Z = c. Nchwaningite 'Y= 1.690(2), 2 ~ = 54.4(4)°. The optical orientation is X = has two perfect cleavages parallel to (010) and (100). The calculated density is 3.202 glcm3. The chemical composition, as determined by electron microprobe analyses, indicates mi- nor substitutions of Mg for Mn. The crystal structure, including H positions, was solved and refined from X-ray single- crystal data to R = 2.14%, Rw = 2.91%.
    [Show full text]